SG11201408160TA - Phosphinyl guanidine compounds, metal salt complexes, catalyst systems, and their use to oligomerize or polymerize olefins - Google Patents
Phosphinyl guanidine compounds, metal salt complexes, catalyst systems, and their use to oligomerize or polymerize olefinsInfo
- Publication number
- SG11201408160TA SG11201408160TA SG11201408160TA SG11201408160TA SG11201408160TA SG 11201408160T A SG11201408160T A SG 11201408160TA SG 11201408160T A SG11201408160T A SG 11201408160TA SG 11201408160T A SG11201408160T A SG 11201408160TA SG 11201408160T A SG11201408160T A SG 11201408160TA
- Authority
- SG
- Singapore
- Prior art keywords
- international
- salt complexes
- catalyst systems
- phosphinyl guanidine
- texas
- Prior art date
Links
- 150000003839 salts Chemical class 0.000 title abstract 6
- 239000002184 metal Substances 0.000 title abstract 5
- 150000001336 alkenes Chemical class 0.000 title abstract 4
- 239000003054 catalyst Substances 0.000 title abstract 4
- -1 Phosphinyl guanidine compounds Chemical class 0.000 title 1
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical class NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 abstract 3
- OGHNLHBJKILTCF-UHFFFAOYSA-N NC(N)=N[PH2]=O Chemical compound NC(N)=N[PH2]=O OGHNLHBJKILTCF-UHFFFAOYSA-N 0.000 abstract 3
- 235000008331 Pinus X rigitaeda Nutrition 0.000 abstract 2
- 235000011613 Pinus brutia Nutrition 0.000 abstract 2
- 241000018646 Pinus brutia Species 0.000 abstract 2
- 239000000126 substance Substances 0.000 abstract 2
- 241000870566 Astronium fraxinifolium Species 0.000 abstract 1
- 206010007134 Candida infections Diseases 0.000 abstract 1
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 abstract 1
- 208000007027 Oral Candidiasis Diseases 0.000 abstract 1
- 241000287411 Turdidae Species 0.000 abstract 1
- 201000003984 candidiasis Diseases 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 abstract 1
- 230000003606 oligomerizing effect Effects 0.000 abstract 1
- 230000008520 organization Effects 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/189—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms containing both nitrogen and phosphorus as complexing atoms, including e.g. phosphino moieties, in one at least bidentate or bridging ligand
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/26—Catalytic processes with hydrides or organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/20—Olefin oligomerisation or telomerisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
- B01J2531/62—Chromium
Abstract
(12) INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization International Bureau (43) International Publication Date 12 December 2013 (12.12.2013) WIPOIPCT (10) International Publication Number WO 2013/184579 A1 (51) International Patent Classification: B01J31/18 (2006.01) (21) International Application Number: (22) International Filing Date: (25) Filing Language: (26) Publication Language: PCT/US2013/043 902 3 June 2013 (03.06.2013) English English (30) Priority Data: 13/490,319 6 June 2012 (06.06.2012) (71) Applicant: CHEVRON PHILLIPS CHEMICAL COM PANY LP [US/US]; 10001 Six Pines Drive, The Wood lands, Texas 77380 (US). (72) Inventors; and (71) Applicants SYDORA, : Orson [CA/US]; 2518 Oakdale Street, Houston, Texas 77004 (US). SMALL, Brooke [US/US]; 3135 Beaver Glen Dr, Kingwood, Texas 77339 (US). CARNEY, Michael [US/US]; S 8410 Thrush Dr., Eau Claire, Wisconsin 54701 (US). (81) Designated States (unless otherwise indicated, for every kind of national protection available)'. AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IS, JP, KE, KG, KN, KP, KR, KZ, LA, LC, LK, LR, LS, LT, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. Ug (84) Designated States (unless otherwise indicated, for every kind of regional protection available)'. ARIPO (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, SZ, TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG). Published: — with international search report (Art. 21(3)) (74) Agent: JOLLY (32736), Lynda; Chevron Phillips Chem ical Company LP, 10001 Six Pines Drive, The Woodlands, Texas 77380 (US). 0\ l> oo i-H cn i-H o CJ (54) Title: PHOSPHINYL GUANIDINE COMPOUNDS, METAL SALT COMPLEXES, CATALYST SYSTEMS, AND THEIR USE TO OLIGOMERIZE OR POLYMERIZE OLEFINS (57) Abstract: The present application relates to N -phosphinyl guanidine meial 2 salt complexes. The present application also relates to catalyst systems comprising N -phosphinyl guanidine metal 2 salt complexes and processes for making catalyst systems comprising N ~phosphinyi guanidine metal 2 salt complexes. The present application also relates to utilizing N'-phosphinyl guanidine metal salt complexes in processes of oligomerizing or polymerizing olefins.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/490,319 US8865610B2 (en) | 2012-06-06 | 2012-06-06 | Phosphinyl guanidine compounds, metal salt complexes, catalyst systems, and their use to oligomerize or polymerize olefins |
| PCT/US2013/043902 WO2013184579A1 (en) | 2012-06-06 | 2013-06-03 | Phosphinyl guanidine compounds, metal salt complexes, catalyst systems, and their use to oligomerize or polymerize olefins |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SG11201408160TA true SG11201408160TA (en) | 2015-01-29 |
Family
ID=48652334
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SG11201408160TA SG11201408160TA (en) | 2012-06-06 | 2013-06-03 | Phosphinyl guanidine compounds, metal salt complexes, catalyst systems, and their use to oligomerize or polymerize olefins |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US8865610B2 (en) |
| EP (1) | EP2858750B1 (en) |
| JP (2) | JP6301319B2 (en) |
| KR (1) | KR102088076B1 (en) |
| CN (1) | CN104394986B (en) |
| CA (1) | CA2875654C (en) |
| SG (1) | SG11201408160TA (en) |
| WO (1) | WO2013184579A1 (en) |
| ZA (1) | ZA201408933B (en) |
Families Citing this family (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2626596T3 (en) | 2009-12-31 | 2017-07-25 | Chevron Phillips Chemical Company Lp | Phosphorylamine compounds, metal complexes, catalytic systems and their use to oligomerize or polymerize olefins |
| US8865610B2 (en) | 2012-06-06 | 2014-10-21 | Chevron Phillips Chemical Company Lp | Phosphinyl guanidine compounds, metal salt complexes, catalyst systems, and their use to oligomerize or polymerize olefins |
| US9175109B1 (en) | 2014-05-20 | 2015-11-03 | Chevron Phillips Chemical Company Lp | Oligomerization processes and polymer compositions produced therefrom |
| US9120826B1 (en) * | 2014-06-02 | 2015-09-01 | Chevron Phillips Chemical Company Lp | Olefin hydroboration |
| US9505675B2 (en) | 2015-02-09 | 2016-11-29 | Chevron Phillips Chemical Company Lp | Deactivation of a process by-product |
| WO2017010998A1 (en) | 2015-07-14 | 2017-01-19 | Chevron Phillips Chemical Company Lp | Olefin compositions |
| US10513473B2 (en) | 2015-09-18 | 2019-12-24 | Chevron Phillips Chemical Company Lp | Ethylene oligomerization/trimerization/tetramerization reactor |
| US10519077B2 (en) | 2015-09-18 | 2019-12-31 | Chevron Phillips Chemical Company Lp | Ethylene oligomerization/trimerization/tetramerization reactor |
| US9707549B1 (en) | 2016-05-26 | 2017-07-18 | Chevron Phillips Chemical Company Lp | Ethylene oligomerization catalyst systems using chemically-treated solid oxides |
| US10414698B2 (en) * | 2016-05-27 | 2019-09-17 | Chevron Phillips Chemical Company Lp | Reduced polymer formation for selective ethylene oligomerizations |
| US10414699B2 (en) * | 2016-05-27 | 2019-09-17 | Chevron Phillips Chemical Company Lp | Process improvements in selective ethylene oligomerizations |
| US10329212B2 (en) * | 2016-05-27 | 2019-06-25 | Chevron Phillips Chemical Company Lp | Reduced polymer formation for selective ethylene oligomerizations |
| US10196328B2 (en) | 2016-06-02 | 2019-02-05 | Chevron Phillips Chemical Company Lp | Catalyst systems and ethylene oligomerization method |
| US9944661B2 (en) | 2016-08-09 | 2018-04-17 | Chevron Phillips Chemical Company Lp | Olefin hydroboration |
| EP3519470B1 (en) * | 2016-09-30 | 2020-10-21 | Dow Global Technologies Llc | Phosphaguanidine group iv metal olefin polymerization catalysts |
| BR112019005928B1 (en) * | 2016-09-30 | 2022-12-20 | Dow Global Technologies Llc | PHOSPHAGANANIDINE COMPOUND, METAL-BINDER COMPLEX, BIPHENYL-PHOSPHAGANANIDINE COMPOUND, POLYMERIZATION CATALYST, PHOSPHAGUANANIDINE NAPHTHAlene COMPOUND AND POLYMERIZATION CATALYST |
| JP6974448B2 (en) * | 2016-09-30 | 2021-12-01 | ダウ グローバル テクノロジーズ エルエルシー | Bis-linked phosphaguanidine Group IV metal complex and olefin polymerization catalyst produced from it |
| US10232339B2 (en) | 2017-06-06 | 2019-03-19 | Chevron Phillips Chemical Company Lp | Fouling protection for an oligomerization reactor inlet |
| US10493442B2 (en) | 2017-09-22 | 2019-12-03 | Chevron Phillips Chemical Company Lp | Fluorinated N2-phosphinyl amidine compounds, chromium salt complexes, catalyst systems, and their use to oligomerize ethylene |
| US10183960B1 (en) | 2017-09-22 | 2019-01-22 | Chevron Phillips Chemical Company Lp | Perfluorohydrocarbyl-N2-phosphinyl amidine compounds, chromium salt complexes, catalyst systems, and their use to oligomerize ethylene |
| US10294171B2 (en) | 2017-09-22 | 2019-05-21 | Chevron Phillips Chemical Company Lp | Carbonyl-containing perfluorohydrocarbyl-N2-phosphinyl amidine compounds, chromium salt complexes and their use to oligomerize ethylene |
| US10464862B2 (en) | 2017-09-28 | 2019-11-05 | Chevron Phillips Chemical Company Lp | Oligomerization reactions using aluminoxanes |
| WO2019074303A1 (en) * | 2017-10-11 | 2019-04-18 | 롯데케미칼 주식회사 | Catalyst system for olefin oligomerization and method for preparing olefin oligomer by using same |
| US10807921B2 (en) * | 2017-12-01 | 2020-10-20 | Chevron Phillips Chemical Company Lp | Catalyst systems and ethylene oligomerization method |
| US11267909B2 (en) | 2020-07-15 | 2022-03-08 | Chevron Phillips Chemical Company Lp | Oligomerization catalyst system activation and related ethylene oligomerization processes and reaction systems |
| CN113209985B (en) * | 2021-04-08 | 2022-04-26 | 西南化工研究设计院有限公司 | Catalyst for removing trace olefin in dimethyl ether through hydrogenation, preparation method and application |
| US11859041B2 (en) | 2021-08-16 | 2024-01-02 | Chevron Phillips Chemical Company Lp | Modulating co-monomer selectivity using non-covalent dispersion interactions in group 4 olefin polymerization catalysts |
| US11583843B1 (en) | 2021-11-08 | 2023-02-21 | Chevron Phillips Chemical Company, Lp | Chromium phosphinyl isoindole amidine complexes for tetramerization of ethylene |
| US11492305B1 (en) | 2021-11-08 | 2022-11-08 | Chevron Phillips Chemical Company, Lp | Chromium phosphinyl hydroisoindole amidine complexes for tetramerization of ethylene |
| US11505513B1 (en) | 2021-11-08 | 2022-11-22 | Chevron Phillips Chemical Company, Lp | Chromium bicyclic phosphinyl amidine complexes for tetramerization of ethylene |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4228883A1 (en) | 1992-08-29 | 1994-03-03 | Basf Ag | Phillips catalyst for the polymerization of â-olefins |
| US5912202A (en) | 1997-01-10 | 1999-06-15 | Union Carbide Chemicals & Plastics Technology Corporation | Olefin polymerization catalyst composition having increased activity |
| DE60331252D1 (en) | 2002-12-20 | 2010-03-25 | Sasol Tech Pty Ltd | TRIMERIZATION OF OLEFINES |
| US20070043181A1 (en) | 2005-08-19 | 2007-02-22 | Knudsen Ronald D | Methods of preparation of an olefin oligomerization catalyst |
| US7285607B2 (en) | 2004-05-18 | 2007-10-23 | Sasol, Chemical Industries, Limited | Polymerisation of olefinic compounds |
| EP1756024B1 (en) | 2004-06-18 | 2018-08-15 | Sasol Technology (Pty) Ltd | Oligomerisation of olefinic compounds in an aliphatic medium |
| BRPI0613432A2 (en) | 2005-07-12 | 2011-01-11 | Sasol Tech Pty Ltd | oligomerization of olefinic compounds in the presence of a dilute metal-containing activator |
| CN100443178C (en) | 2006-03-10 | 2008-12-17 | 中国石油天然气股份有限公司 | Catalyst composition of ethylene oligomerization and the application |
| US7378537B2 (en) | 2006-07-25 | 2008-05-27 | Chevron Phillips Chemical Company Lp | Olefin oligomerization catalysts and methods of using same |
| CA2583007C (en) | 2007-03-29 | 2015-03-31 | Nova Chemicals Corporation | Amino phosphine |
| EP2155391B1 (en) | 2007-05-28 | 2018-07-04 | Sasol Technology (PTY) Limited | Two stage activation of oligomerisation catalyst and oligomerisation of olefinic compounds in the presence of an oligomerisation catalyst so activated |
| EP2239056B1 (en) * | 2009-04-09 | 2011-07-20 | Saudi Basic Industries Corporation | Catalyst composition and process for oligomerization of ethylene |
| ES2626596T3 (en) | 2009-12-31 | 2017-07-25 | Chevron Phillips Chemical Company Lp | Phosphorylamine compounds, metal complexes, catalytic systems and their use to oligomerize or polymerize olefins |
| US20120172645A1 (en) | 2010-12-29 | 2012-07-05 | Chevron Phillips Chemical Company Lp | Olefin Oligomerization catalysts and Methods of Making and Using Same |
| US8865610B2 (en) | 2012-06-06 | 2014-10-21 | Chevron Phillips Chemical Company Lp | Phosphinyl guanidine compounds, metal salt complexes, catalyst systems, and their use to oligomerize or polymerize olefins |
-
2012
- 2012-06-06 US US13/490,319 patent/US8865610B2/en active Active
-
2013
- 2013-06-03 SG SG11201408160TA patent/SG11201408160TA/en unknown
- 2013-06-03 KR KR1020147033878A patent/KR102088076B1/en active IP Right Grant
- 2013-06-03 JP JP2015516093A patent/JP6301319B2/en active Active
- 2013-06-03 CN CN201380029425.9A patent/CN104394986B/en active Active
- 2013-06-03 EP EP13729865.9A patent/EP2858750B1/en active Active
- 2013-06-03 WO PCT/US2013/043902 patent/WO2013184579A1/en active Application Filing
- 2013-06-03 CA CA2875654A patent/CA2875654C/en active Active
-
2014
- 2014-12-05 ZA ZA2014/08933A patent/ZA201408933B/en unknown
-
2018
- 2018-01-24 JP JP2018009296A patent/JP6437145B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| EP2858750B1 (en) | 2019-03-13 |
| US8865610B2 (en) | 2014-10-21 |
| WO2013184579A1 (en) | 2013-12-12 |
| KR102088076B1 (en) | 2020-03-12 |
| CN104394986A (en) | 2015-03-04 |
| CN104394986B (en) | 2017-02-22 |
| KR20150023334A (en) | 2015-03-05 |
| JP2015521586A (en) | 2015-07-30 |
| JP6437145B2 (en) | 2018-12-12 |
| US20130331629A1 (en) | 2013-12-12 |
| EP2858750A1 (en) | 2015-04-15 |
| CA2875654A1 (en) | 2013-12-12 |
| JP2018076371A (en) | 2018-05-17 |
| JP6301319B2 (en) | 2018-03-28 |
| CA2875654C (en) | 2021-04-06 |
| ZA201408933B (en) | 2016-09-28 |
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