NO341450B1 - Improved process and reactor for drying a mixture containing solid or semi-solids. - Google Patents

Improved process and reactor for drying a mixture containing solid or semi-solids. Download PDF

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Publication number
NO341450B1
NO341450B1 NO20150407A NO20150407A NO341450B1 NO 341450 B1 NO341450 B1 NO 341450B1 NO 20150407 A NO20150407 A NO 20150407A NO 20150407 A NO20150407 A NO 20150407A NO 341450 B1 NO341450 B1 NO 341450B1
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Norway
Prior art keywords
mixture
reaction chamber
accordance
rotor
bed
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Application number
NO20150407A
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Norwegian (no)
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NO20150407A1 (en
Inventor
Stein Kyrre Monsen
Saeed Bikass
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Thermtech Holding As
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Filing date
Publication date
Application filed by Thermtech Holding As filed Critical Thermtech Holding As
Priority to NO20150407A priority Critical patent/NO341450B1/en
Publication of NO20150407A1 publication Critical patent/NO20150407A1/en
Publication of NO341450B1 publication Critical patent/NO341450B1/en

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F26DRYING
    • F26BDRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
    • F26B3/00Drying solid materials or objects by processes involving the application of heat
    • F26B3/02Drying solid materials or objects by processes involving the application of heat by convection, i.e. heat being conveyed from a heat source to the materials or objects to be dried by a gas or vapour, e.g. air
    • F26B3/06Drying solid materials or objects by processes involving the application of heat by convection, i.e. heat being conveyed from a heat source to the materials or objects to be dried by a gas or vapour, e.g. air the gas or vapour flowing through the materials or objects to be dried
    • F26B3/08Drying solid materials or objects by processes involving the application of heat by convection, i.e. heat being conveyed from a heat source to the materials or objects to be dried by a gas or vapour, e.g. air the gas or vapour flowing through the materials or objects to be dried so as to loosen them, e.g. to form a fluidised bed
    • F26B3/092Drying solid materials or objects by processes involving the application of heat by convection, i.e. heat being conveyed from a heat source to the materials or objects to be dried by a gas or vapour, e.g. air the gas or vapour flowing through the materials or objects to be dried so as to loosen them, e.g. to form a fluidised bed agitating the fluidised bed, e.g. by vibrating or pulsating
    • F26B3/0923Drying solid materials or objects by processes involving the application of heat by convection, i.e. heat being conveyed from a heat source to the materials or objects to be dried by a gas or vapour, e.g. air the gas or vapour flowing through the materials or objects to be dried so as to loosen them, e.g. to form a fluidised bed agitating the fluidised bed, e.g. by vibrating or pulsating by mechanical means, e.g. vibrated plate, stirrer
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F26DRYING
    • F26BDRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
    • F26B11/00Machines or apparatus for drying solid materials or objects with movement which is non-progressive
    • F26B11/12Machines or apparatus for drying solid materials or objects with movement which is non-progressive in stationary drums or other mainly-closed receptacles with moving stirring devices
    • F26B11/16Machines or apparatus for drying solid materials or objects with movement which is non-progressive in stationary drums or other mainly-closed receptacles with moving stirring devices the stirring device moving in a vertical or steeply-inclined plane
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F26DRYING
    • F26BDRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
    • F26B3/00Drying solid materials or objects by processes involving the application of heat
    • F26B3/32Drying solid materials or objects by processes involving the application of heat by development of heat within the materials or objects to be dried, e.g. by fermentation or other microbiological action
    • F26B3/36Drying solid materials or objects by processes involving the application of heat by development of heat within the materials or objects to be dried, e.g. by fermentation or other microbiological action by using mechanical effects, e.g. by friction
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F26DRYING
    • F26BDRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
    • F26B5/00Drying solid materials or objects by processes not involving the application of heat
    • F26B5/04Drying solid materials or objects by processes not involving the application of heat by evaporation or sublimation of moisture under reduced pressure, e.g. in a vacuum
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F26DRYING
    • F26BDRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
    • F26B5/00Drying solid materials or objects by processes not involving the application of heat
    • F26B5/08Drying solid materials or objects by processes not involving the application of heat by centrifugal treatment

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  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Microbiology (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Biomedical Technology (AREA)
  • Biotechnology (AREA)
  • Drying Of Solid Materials (AREA)

Description

Field of invention
The present invention relates to a process for drying a mixture containing temperature sensitive solids or semi-solids and evaporable liquid or liquids in a reactor with a reaction chamber. Further, the invention relates to a reactor for processing of a mixture comprising temperature sensitive solids or semi-solids and evaporable liquid or liquids.
Background of the invention
Friction dryers can be used for separation of evaporable liquids from a mixture of compounds, for instance for the separation of oil from a mixture of solid and liquid compounds, or for the drying of water from water containing materials. The friction between the feeding mixture and the impact means generates thermal energy, i.e. heat that evaporates evaporable liquid components in the mixture.
It is known to use rotational frictions dryers that establishes a fluidized bed of feed material in the rotating chamber.
GB2165259A describes a method of separating oil, water and other evaporable liquid for drilling mud or the like. W098/39368 describes a process for thermal and catalytic decomposition and depolymerization of low-grade organic substance. N0329915 describes a method for separating oil, water and other components that can be evaporated from an oil-containing material by evaporation. The evaporation is achieved at a lower temperature than the atmospheric boiling point of the component, due to the utilization of the gas phase established by evaporation of a second component. US3456708 describes a process where a temperature-sensitive or fragile particulate material associated with an evaporable liquid is dried in a drying pan.
The temperature of the fluidized bed often needs to be set to a temperature that does not reduce the quality of the treated material.
It is thus an object of the present invention to provide an improved process where the solids are sensitive to high temperatures depending on their properties and application.
More specifically, it is an object of the present invention to define an efficient process to dry a mixture containing solids (for example rubber, composites, offal, bio wastes, organic products and organics by products), liquids (for example oil, water) and any gases.
Summary of the invention
A first aspect of the present invention relates to a process for drying a mixture comprising temperature sensitive solids or semi-solids and evaporable liquid or liquids in a reactor with a reaction chamber, wherein the process comprises: a) feeding said mixture into said reaction chamber, wherein said reaction chamber comprises a rotor with impact means, b) rotating said rotor within said reaction chamber to form a bed of feed mixture, c) extracting a portion of the liquid by centrifugal force to decrease the thermal
energy needed to dry the mixture,
d) degassing the fed mixture by vacuum
e) effect friction between the mixture bed and the impact means by contacting
the means of the rotating rotor with the mixture bed, and wherein the mixture bed is
heated by the thermal energy created by the friction between the means and the mixture bed, and
d) wherein the pressure of the reaction chamber is between -0.95 barg and -0.01 barg (i.e. vacuum), wherein vacuum used to enhance the feeding to the reaction
chamber by sucking the feed inside the chamber.
In a preferred embodiment comprises said mixture solids selected from the group consisting of rubber, composites, offal, bio wastes, organic products and organics by products.
In a preferred embodiment is said liquid an oil.
In a preferred embodiment is the liquid water.
In a preferred embodiment is the pressure in the reaction chamber between -0.6 and
-0,01 barg or is between -0.5 and -0,01 barg.
In a preferred embodiment is the pressure in the reaction chamber is from -0.6 to -0.5 barg.
In a preferred embodiment is the offal fish waste, and wherein the liquids are water and oil, and wherein the temperature of the reaction chamber is preferably from 70 to 150 and more preferably from 75 to 95 °C
In a preferred embodiment is the temperature of the reaction chamber from 90 to 95
°C.
In a preferred embodiment are the solid particles introduced into the reaction chamber to increase the friction and/or heat transfer between the rotor and the mixture bed, and between said solid particles and solid particles in the mixture bed.
In a preferred embodiment are the solid particles sand, glass or metal pieces.
In a preferred embodiment is a portion of said solid particles a constituent of the feed mixture.
In a preferred embodiment is the feeding mixture preheated.
In a preferred embodiment are said impact means extensions on the rotor, such as discs, propellers, arms or blades.
In a preferred embodiment is the connection between the rotor and the impact means fixed, hinged, removable or adjustable.
In a preferred embodiment is the reaction temperature 10-20% below the boiling temperature of the evaporable liquid.
A second aspect of the present invention relates to a reactor for processing of a mixture comprising temperature sensitive solids or semi-solids and evaporable liquid or liquids, wherein the reactor comprises;
a) a reaction chamber with one or more fed inlets for said mixture, wherein the mixture enters into the chamber by a feed pump enhanced by sucking created by
vacuum, and one or more vapor outlets for evaporable reaction products of said liquid or liquids,
b) a rotor within the reaction chamber, wherein the rotor rotates and establishes a mixture bed, and wherein the rotor is equipped with one or more impact means
which is in contact with the mixture bed, and wherein the friction between the impact means and the mixture bed transfers thermal energy to the mixture bed, and
c) a pressure lowering means adapted to establish reduced pressure, preferable vacuum inside the reaction chamber, wherein the pressure of the reaction chamber is
between -0.95 barg and -0.01 barg, and
e) a liquid outlet for transferring on of a portion of the liquid extracted from the mixture out of the reaction chamber.
In a preferred embodiment are the impact means in the form of discs, propellers, arms or blades, or a combination thereof.
In a preferred embodiment is the connection between the rotor and the impact means fixed, hinged, removable or adjustable.
In a preferred embodiment has the reactor one or more inlets for adding of solid particles.
Detailed description of the invention
The inventors of the present invention have shown that it is possible to preserve the quality of solids (for example, fish wastes) by reducing the process pressure in a drying mill. It is an advantage to easily degasify the feed by creating vacuum environment. At the same time the drying process can get benefit from centrifugal forces.
Thus, the present invention provides a process and an apparatus which are capable of drying a mixture containing solids, liquids and gasses in any ratio. Examples of such compounds can be rubber, composites, offal, bio wastes, organic products and organics by products.
The concept is to establish an efficient condition in the reaction chamber so that low temperature evaporating takes place, in order to dry the solids in the above mentioned mixture.
The process may be enhanced by additives such as catalysts,Chemicals, solids and liquids prior to or during the process.
The process occurs in one or more chamber(s) which may be in parallel or series. The mixture (hereinafter referred to as the "feed" or "feed material" or "feed mixture") enters into the chamber(s) by a feed pump enhanced by sucking created by vacuum. Then a portion of liquids is separated by centrifugal forces and discharged from the chamber. The next step is degasifying the feed by the vacuum. The degasified gas is mainly air which may affect negatively on the dried solids at higher temperatures. The feed is heated then to a desired temperature. It may be preheated as well.
As mentioned, the process occurs under a vacuum condition. The required vacuum pressure depends on the desired result. For example the pressure can be between 0.05 barg and 0.99 barg.
The preheating temperature, the heating rate, the process temperature and any other parameters depend on the desired result and can be determined by a skilled person.
The chamber(s) has/have at least a rotor and/or a shaft (impact means) that may, for example have discs, propellers, arms, blades with any connection in between; fixed,
hinged, removable or adjustable. A portion of the liquid in the feed is extracted by the centrifugal force created by the rotor.
The vacuum is degassing the feed that makes the final dried solids quality higher. Then the feed mixture is heated by friction generated by the rotor/shaft. The rotation may make a fluidized bed with large surface for efficient transfer of the thermal energy. Heating may be supplied from other sources in order to maintain the process temperature or any other reason. For example the rotor/shaft or the chamber may be heated by other sources and/or the feed can be preheated.
The friction between the feed mixture in the fluidized bed and the impact means may be enhanced by adding solids such as sand, glass or metal pieces to the feed prior to or inside the chamber(s). The solids may remain in the chamber(s) or may exit the chamber. The retention time depends on process conditions, composition of the solids and desired result.
The apparatus has one or more inlet(s) and outlet(s) to feed in feed mixture and transport out all the phases (solids, liquids and gasses/vapour).
This process/apparatus may be used independently, in connection with, or as an integrated part of another process(es)/apparatus(es) onshore or offshore.
A preferred embodiment of the reactor according to the invention is shown in figure 1.
Figure 1 is a schematic drawing of a reactor 10 with a reaction chamber 12 with inlets 22 for feeding a feed material, and an outlet24 for evaporated material and an outlet
26 for dried or cleansed material. The reaction chamber also contains an liquid outlet 27 for removal of liquid extracted from the mixture. The reactor 10 contains a rotor 14 within the reaction chamber 12, and the rotor is equipped with a plural of impact means 16. These impact means 16 can be discs, propellers, arms and blades, and can be, with regard to the rotating rotor, fixed, hinged, removable or adjustable.
Rotation of the rotor 14 will effect contact between the feed material and the impact means, and the rotation and the friction established will create a fluidized bed 18. The temperature in the fluidized bed 18 will increase and evaporable liquids will evaporate.
The reaction chamber 12 of the reactor according to the invention has one or more means 25 for regulating the pressure of the reaction chamber 12. The reactor 10 is thus capable of conducting a process according to the invention, i.e. a process where the reaction (separation or removal of oil or liquids) takes place at a reduced temperature at reduced pressure. The term "reduced temperature" means that the temperature of the process can be lower than the normal temperature at atmospheric pressure.
Experimental section
The aim of this study was to find out whether the reaction temperature could be decreased sufficiently during drying of a fish waste product to produce a dried fish meal. The prior art teaches that the process temperature should be 10-20 degrees centigrade higher than the boiling temperature of the liquid to evaporate from the waste in order to dry the solids efficiently.
Several test samples were dried in a friction dryer. A friction dryer converts kinetic energy to thermal energy by creating friction in the waste. A drive unit sets a series of shaft mounted hammer arms (impact means) in motion inside a cylinder shaped process chamber (also referred to as the hammer mill or just the mill). The waste material was forced towards the inner wall of the process chamber where the kinetic energy from the rotating arms will be transformed to heat by friction. Liquids in the waste material evaporate and leave the chamber, and new waste is pumped in. Solids are discharged through an output. The hottest spot in the process is the waste itself, and the liquid is under influence of the process temperature for maximum a few seconds. A representative example of such a friction dryer is the TCC<®>from Thermtech, Norway.
The test samples used in this example are various waste products from the fish farming industry, i.e. fish waste products. The main object of the experiments is to provide an efficient drying, i.e. removal of water as the liquid component.
Drying of fish waste materials represents a considerable problem relating to the "gluey" characteristics of the material. During drying, i.e. removal of water, and also for removal of fish oil, within certain ranges of dry material to moisture a glue zone is established, and the particles of the waste material will dump together, making problems for the drying equipment and reduces product quality and drying efficiency.
It is known from the prior art that the glue phase can be avoided by introducing only small amounts of waste material into the friction dryer, so that the waste material is rapidly dried in contact with the fluidized bed of the heated material.
The results obtained by the present invention show that the glue phase also can be avoided by using a process temperature that is actually lower than the boiling temperature of liquid that shall be evaporated (i.e. water in the context of drying a waste material).
The results show that the reaction temperature can be reduced by about 10-20% of the boiling temperature, and by about 20-30 % of the temperature used in prior art friction dryers when the pressure is lowered to -0.5 to -0.6 barg.
In the context of the present invention, the term "barg" is defined as a unit of gauge pressure, i.e. pressure in bars above ambient or atmospheric pressure.
Since many biological substances are sensitive to high temperatures, this lowering of the reaction temperature will also provide a better, and less decomposed end product.
Example 1 - Evaporation of water from fish waste products
Various fish waste materials were dried;
- White fish fillet cuttings
- White fish entrails (without liver)
- Defatted salmon entrails
The waste material is ground in a mill with a mesh diameter of 8 mm, and is pumped to the reaction chamber of a friction dryer. The rotor with the hammer arms (impact means) is rotated and a bed of waste material is formed on the inner wall of the reaction chamber. The temperature of the bed increases due to the transfer of kinetic energy to thermal energy in the waste bed, and water in the added waste material will rapidly evaporate in contact with the heated waste bed.
The various fish waste test samples were tested at different temperatures in the reaction chamber, and at different pressures, especially at normal atmospheric pressure and at various levels of reduced pressure (vacuum) as indicated in the
tables below.
The results given in the table below show that the temperature for evaporation of water from the moist fish waste material can be reduced from 110-120 °C (as known from the prior art) to temperatures below 95 °C, more preferable 90 °C, and more preferable 85 °C when the pressure is reduced to a range of -0.4 to -0.5 barg.

Claims (19)

1. A process for drying a mixture comprising temperature sensitive solids or semi-solids and evaporable liquid or liquids in a reactor (10) with a reaction chamber (12), wherein the process comprises: a) feeding said mixture into said reaction chamber (12), wherein said reaction chamber comprises a rotor (14) with impact means (16), b) rotating said rotor (14) within said reaction chamber (12) to form a bed of feed mixture (18), c) extracting a portion of the liquid by centrifugal force to decrease the thermal energy needed to dry the mixture, d) degassing the fed mixture by vacuum e) effect friction between the mixture bed (18) and the impact means (16) by contacting the means (16) of the rotating rotor (14) with the mixture bed (18), and wherein the mixture bed (18) is heated by the thermal energy created by the friction between the means (16) and the mixture bed (18), and d) wherein the pressure of the reaction chamber (12) is between -0.95 barg and -0.01 barg (i.e. vacuum), and wherein vacuum is used to enhance the feeding to the reaction chamber (12) by sucking the feed inside the chamber.
2. A process in accordance with claim 1, wherein said mixture comprises solids selected from the group consisting of rubber, composites, offal, bio wastes, organic products and organics by products.
3. A process in accordance with claim 1, wherein said liquid is an oil.
4. A process in accordance with claim 1, wherein said liquid is water.
5. A process in accordance with claim 1, wherein the pressure in the reaction chamber is between -0.6 and -0.01 barg or is between -0.5 and -0.01 barg.
6. A process in accordance with any of the preceding claims, wherein the pressure in the reaction chamber is from -0.6 to -0.5 barg.
7. A process in accordance with claim 2, wherein the offal is fish waste, and wherein the liquids are water and oil, and wherein the temperature of the reaction chamber is preferably from 70 to 150 and more preferably from 75 to 95 °C
8. A process in accordance with claim 7, wherein the temperature of the reaction chamber is from 90 to 95 °C.
9. A process in accordance with any of the preceding claims, wherein solid particles are introduced into the reaction chamber to increase the friction and/or heat transfer between the rotor and the mixture bed, and between said solid particles and solid particles in the mixture bed.
10. A process in accordance with claim 9, wherein said solid particles are sand, glass or metal pieces.
11. A process in accordance with any of the claims 9-10, wherein a portion of said solid particles is a constituent of the feed mixture.
12. A process in accordance with any of the preceding claims, wherein the feeding mixture is preheated.
13. A process in accordance with any of the preceding claims, wherein said impact means (16) are extensions on the rotor, such as discs, propellers, arms or blades.
14. A process in accordance with claim 1, wherein the connection between the rotor and the impact means is fixed, hinged, removable or adjustable.
15. A process in accordance with claim 1, wherein the reaction temperature is 10-20% below the boiling temperature of the evaporable liquid.
16. A reactor (10) for processing of a mixture comprising temperature sensitive solids or semi-solids and evaporable liquid or liquids, wherein the reactor comprises; a) a reaction chamber (12) with one or more fed inlets (22) for said mixture, wherein the mixture enters into the chamber (12) by a feed pump enhanced by sucking created by vacuum, and one or more vapor outlets (24) for evaporable reaction products of said liquid or liquids, b) a rotor (14) within the reaction chamber (12), wherein the rotor (14) rotates and establishes a mixture bed (18), and wherein the rotor (14) is equipped with one or more impact means (16) which is in contact with the mixture bed (18), and wherein the friction between the impact means (16) and the mixture bed (18) transfers thermal energy to the mixture bed (18), and c) a pressure lowering means (25) adapted to establish reduced pressure, preferable vacuum inside the reaction chamber (12), wherein the pressure of the reaction chamber (12) is between -0.95 barg and -0.01 barg, and e) a liquid outlet (27) for transferring on of a portion of the liquid extracted from the mixture out of the reaction chamber (12).
17. A reactor (10) in accordance with claim 16, wherein the impact means (16) is in the form of discs, propellers, arms or blades, or a combination thereof.
18. A reactor (10) in accordance with claim 17, wherein the connection between the rotor (14) and the impact means (16) is fixed, hinged, removable or adjustable.
19. A reactor (10) in accordance with any of the claims 16-18, wherein the reactor has one or more inlets (28) for adding of solid particles.
NO20150407A 2015-04-08 2015-04-08 Improved process and reactor for drying a mixture containing solid or semi-solids. NO341450B1 (en)

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NO20150407A NO341450B1 (en) 2015-04-08 2015-04-08 Improved process and reactor for drying a mixture containing solid or semi-solids.

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NO341450B1 true NO341450B1 (en) 2017-11-13

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Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015156679A1 (en) * 2014-04-08 2015-10-15 Thermtech Holding As Improved process and reactor for drying a mixture containing solid or semi-solids
NO345361B1 (en) * 2019-04-08 2020-12-21 Thermtech Holding As Fluidized bed reactor apparatus and a method for processing organic material using a fluidized bed reactor apparatus
SE2030275A1 (en) * 2020-01-15 2021-10-18 Cassandra Ltd Reactor with radial clearance
NO20220506A1 (en) * 2022-05-03 2023-11-06 Thermtech Holding As Process for Treating a Mixture of Solid Material and Liquids, Composition Obtainable by the Process, and Use of the Composition

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3456708A (en) * 1964-12-07 1969-07-22 Atomenergi Ab Drying of powder
GB2165259A (en) * 1984-10-08 1986-04-09 Olav Ellingsen A method of recovering oil from material
WO1998039368A1 (en) * 1997-03-03 1998-09-11 Ivan Madar Process for thermal and/or catalytic decomposition and/or depolymerization of low-grade organic substances and device for carrying out the process
NO329915B1 (en) * 2001-05-16 2011-01-24 Thermtech As Process and apparatus for drying oil-containing materials
WO2015156679A1 (en) * 2014-04-08 2015-10-15 Thermtech Holding As Improved process and reactor for drying a mixture containing solid or semi-solids

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3456708A (en) * 1964-12-07 1969-07-22 Atomenergi Ab Drying of powder
GB2165259A (en) * 1984-10-08 1986-04-09 Olav Ellingsen A method of recovering oil from material
WO1998039368A1 (en) * 1997-03-03 1998-09-11 Ivan Madar Process for thermal and/or catalytic decomposition and/or depolymerization of low-grade organic substances and device for carrying out the process
NO329915B1 (en) * 2001-05-16 2011-01-24 Thermtech As Process and apparatus for drying oil-containing materials
WO2015156679A1 (en) * 2014-04-08 2015-10-15 Thermtech Holding As Improved process and reactor for drying a mixture containing solid or semi-solids

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