KR950006539B1 - The printing method of silicone to leather sheet - Google Patents
The printing method of silicone to leather sheet Download PDFInfo
- Publication number
- KR950006539B1 KR950006539B1 KR1019920003674A KR920003674A KR950006539B1 KR 950006539 B1 KR950006539 B1 KR 950006539B1 KR 1019920003674 A KR1019920003674 A KR 1019920003674A KR 920003674 A KR920003674 A KR 920003674A KR 950006539 B1 KR950006539 B1 KR 950006539B1
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- South Korea
- Prior art keywords
- silicone
- leather
- printing
- mixed
- printed
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M1/00—Inking and printing with a printer's forme
- B41M1/26—Printing on other surfaces than ordinary paper
- B41M1/38—Printing on other surfaces than ordinary paper on wooden surfaces, leather, or linoleum
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
Abstract
내용 없음.No content.
Description
본 발명은 천연가죽이나 폴리우레탄, PVC 코팅지등 인조가죽의 표면 즉, 신발의 깔창이나 핸드백, 자동차 안전벨트등의 제품표면에 실리콘으로 무늬나 문자를 인쇄할 수 있게 하여 그 인쇄면을 중후하고 고급스럽게 함과 동시에 실리콘의 특성으로 그 촉감을 매우 부드럽게 한 가죽지에 대한 실리콘의 인쇄방법에 관한 것이다.The present invention makes it possible to print patterns or texts on the surface of artificial leather such as natural leather, polyurethane, PVC coated paper, that is, the surface of products such as shoe insoles, handbags, car seat belts, etc. The present invention relates to a method of printing silicone on leather paper which is softened at the same time as the characteristics of silicone.
종래, 천연가죽이나 폴리우레탄, PVC코팅지의 인조가죽에는 실리콘과의 친화력이 없어 실리콘을 도포하여도 도포된 실리콘층이 그 표면으로부터 쉽게 분리되어 버리므로 실리콘인쇄를 할 수가 없어 결국 천연가죽이나, 폴리우레탄, PVC코팅지의 인조가죽으로된 신발깔창이나 핸드백, 지갑, 자동차, 안전벨트등의 표면에 통상의 유성도료로서 프린팅하거나 금박 또는 은박으로된 별도의 라벨을 부착하였던 것이어서, 그 인쇄면에서 광택이 나게되어 고급스럽지 못하고, 쉽게 싫증을 느끼게 되는 결점이 있었으며, 또는 그 표면이 매끈거리게 되어 신체와 자주 접촉되는 제품으로서 촉감이 부드럽지 못해 좋지 않을뿐 아니라 특히 구두깔창등의 경우에는 그 인쇄면에 의해 발바닥이 미끄러운 유동성을 갖게 되어 스타킹등을 흘러내리게 하는 원인이 되는 결점이 있었고, 또한 별도의 라벨을 부착하는 경우에도 사용도중 분리가 쉽게 되어 외관상 좋지 않은 결점이 있었다.Conventionally, artificial leather of natural leather, polyurethane, and PVC coated paper has no affinity with silicone, and even though the applied silicon layer is easily separated from the surface, silicon printing cannot be performed. The surface of shoe insoles, handbags, purses, automobiles, seat belts made of urethane and PVC coated papers were printed as ordinary oil paints, or a separate label made of gold or silver foil was applied. There was a flaw that was not luxurious and easy to get tired, or that the surface became smooth and frequently touched with the body. The sole which has slippery fluidity and causes the stockings to flow down Was points, and is separated during use, even when attached to a separate label easily had a defect in appearance is not good.
본 발명은 천연가죽이나 폴리우레탄 등의 인조가죽지 표면에 문자나 모양을 인쇄함에 있어서 전기한바와 같은 결점을 제거코저 발명한 것으로서, 상기 천연가죽이나 폴리우레탄, 또는 PVC등과 친화력이 없는 실리콘에 시란제로 조성된 첨가물을 혼합하여 친화력을 갖게함으로서 부드럽고 유연한 특성의 실리콘을 상기 폴리우레탄등의 표면에 인쇄될수 있게하므로서 촉감이 뛰어나면서 무광택의 인쇄층을 형성하여 제품을 고급화시킬 수 있게한 가죽지에 대한 실리콘의 인쇄방법을 제공코저한 것이다.The present invention has been invented to remove the drawbacks as described above in the printing of letters and shapes on the surface of artificial leather, such as natural leather or polyurethane, the silicone leather does not have affinity with the natural leather, polyurethane, PVC, etc. By adding additives formulated with langues to give affinity, the soft and flexible silicone can be printed on the surface of the polyurethane and the like, and the feel is excellent and the matte print layer is formed to enhance the product. To provide a method of printing silicon.
이하, 본 발명의 요지를 실시예에 의하여 설명한다.EMBODIMENT OF THE INVENTION Hereinafter, the summary of this invention is demonstrated by an Example.
먼저 프린트용 실리콘을 조성키위하여 주재료로서 액상의 접착성 실리콘 수지를 사용하는 것인데, 본 발명의 실시예에서는 주제와 경화제가 혼합형성된 도레이 다우사의 액상실리콘(상품명 : DY6020)을 사용하였다.First, a liquid adhesive silicone resin is used as a main material to form a silicone for printing. In the embodiment of the present invention, liquid silicone (trade name: DY6020) of Toray Dow Co., Ltd., in which a main material and a curing agent are mixed and used, is used.
전기한 주재료인 실리콘수지에 첨가물을 혼합교반 조성하되, 그, 혼합조성물의 조성비는 중량비로서 주재료 실리콘수지를 약 98%로 하고, 접착보강제로서 시란화합물인 메치토리메톡시시란[CH3Si(OCH3)Cl]을 0.5%, 가료제로서 시란카플링제인 γ-메타쿠리톡시프로필메칠메톡시시란[CH2=C(CH3)COO(CH2)3Si(CH3)(OCH3)2]을 0.5%, 통상의 세라믹 미분말을 1%첨가하여, 교반혼합하여 프린트용 실리콘을 조성하였다. 상기 조성물에 대하여 필요로 하는 색상의 안료를 섞어 이를 도료로 형성하는 것인데, 여기에서 필요에 따라 안료의 양을 가감조절하여 필요로 하는 색상을 얻을 수 있으나 안료가 많은 경우에는 색상의 선명도는 높으나 접착성이 저하되고 반대로 안료가 적은 경우에는 반대의 현상이 일어나므로 그 첨가량이 혼합조성물이 중량대비로서 약 3-15%가 적당하고 본 발명의 실시예에서는 약 7.5%를 사용하였다. 이와 같이 완성된 도료를 통상의 인쇄방법 즉, 로울 전사식이나 실크인쇄등의 방법으로 표현코자하는 무늬나 문자를 신발깔창등의 천연가죽이나, 폴리우레탄지등에 인쇄한후 120℃정도의 온도로서 3-4분간 가열하여 경화시켜 실리콘 인쇄를 마치는 것이다.The additives are mixed and stirred in the silicone resin, which is the main material described above, and the composition ratio of the mixed composition is about 98% by weight of the main material silicone resin, and the methoxy trimethoxysilane (CH 3 Si), which is a silane compound, is used as an adhesion promoter. (OCH 3 ) Cl] 0.5%, γ-methacryloxypropylmethylmethoxysilane (CH 2 = C (CH 3 ) COO (CH 2 ) 3 Si (CH 3 ) 3 O (OCH) 3 ) 2 ] was added 0.5% and ordinary ceramic fine powder 1%, and stirred and mixed to form a silicone for printing. Mixing the pigment of the color required for the composition to form it as a paint, where it is possible to obtain the required color by adjusting the amount of the pigment as needed here, but in the case of a large number of pigments, the sharpness of the color is high but the adhesion On the contrary, when the property is lowered and the pigment is small, the opposite phenomenon occurs, so that the amount of the mixed composition is about 3-15% by weight, and about 7.5% was used in the embodiment of the present invention. Thus, the finished paint is printed on a natural leather such as a shoe insole or polyurethane paper after printing a pattern or a character to be expressed by a conventional printing method, that is, a roll transfer type or silk printing method. Heat and cure 3-4 minutes to finish silicone printing.
위와 같은 실시예로 인쇄된 실리콘인쇄면은 실리콘에 첨가된 첨가물인 메칠토리메톡시시란 및 γ-메탈쿠리톡시프로필메칠메톡시시란에 의해 실리콘이 경화와 동시에 가죽지의 조직속으로 침투되게하여 친화력을 가짐과 함께 접착보강력을 갖게하여 천연가죽지나 폴리우레탄 또는 PVC코팅지등의 표면에서 분리되지 않고 장기간 견고하게 인쇄층의 역활을 할 수 있는 것이며, 첨가물중의 세라믹분말은 이미 공지된 바와 같이 원적외선을 방사함으로서 천연가죽지 또는 인조가죽지가 사용되는 제품인 신발깔창, 지갑, 자동차용 안전벨트등의 인쇄용으로 사용하여 항상 신체와 밀접한 부위에서 원적외선이 방사되게함으로 인쇄의 효과와 함께 건강증진의 효과도 볼 수 있는 일석이조의 효과도 있는 것이다.The silicon printed surface printed in the above embodiment was allowed to penetrate into the tissue of the leather at the same time as the silicone was cured by the addition of methyltoroxymethoxysilane and γ-metallic methoxypropylmethylmethoxysilane, which were added to the silicone. It has affinity and adhesion reinforcement, so that it can play the role of printing layer for a long time without being separated from the surface of natural leather, polyurethane or PVC coated paper, and the ceramic powder in the additives as already known. By radiating far infrared rays, it is used for printing insoles, wallets, automobile seat belts, etc., which are made of natural or artificial leather, so that far-infrared rays are radiated from the area close to the body. There is also the effect of one stone two birds to see.
또한 무광택이며 부드러운 실리콘 자체의 특성에 의하여 그 인쇄면이 종래 유성도료나 금은박지와는 달리 반짝거리지 않아 외관상 중후하고 고급스런 분위기를 자아내는 것이며 특히 부드러운 질감으로 인하여 촉감이 매우 부드럽고 신발깔창등의 인쇄용으로 사용할 경우는 미끄럽지 않아 구두내의 발의 유동성까지 막아주어 스타킹이 흘러내리는등의 결점도 방지할 수 있는 것이다.Also, due to the nature of matte and soft silicone itself, its printed surface does not shine like conventional oil paint or gold and silver foil, giving off a dignified and luxurious atmosphere in appearance. Especially, it is very soft to the touch due to its soft texture. If it is used, it is not slippery, so it prevents the fluidity of the foot in the shoe and prevents the faults such as stockings falling down.
또한 본 발명의 인쇄발명을 전기한 가죽제품이외의 섬유제품에 적용하는 경우에도 인쇄면의 부드러운 질감등으로 더욱 고급스러운 제품을 제조할 수 있어 다방면에서 사용할 수 있는 것이다.In addition, even when applied to textile products other than the leather products described in the printing invention of the present invention can be produced in a more luxurious product, such as a soft texture of the printing surface can be used in various fields.
이상과 같이 본 발명은 천연가죽이나 폴리우레탄, PVC 등의 인조가죽지는 물론 각종 섬유원단등에 대하여 실리콘으로 문자나 모양을 인쇄될 수 있게 하여 외관상 무늬면을 중후하고 고급스럽게함과 동시에 신체에 접촉되는 인쇄면의 촉감을 연하고 부드럽게하여 제품을 고급화할 수 있는 효과가 있는 것이다.As described above, the present invention enables to print letters or shapes with natural leather, polyurethane, PVC, etc. as well as various textile fabrics, so that the surface of the pattern is profound and luxurious and at the same time in contact with the body. It has the effect of making the product more advanced by softening and softening the printed surface.
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Application Number | Priority Date | Filing Date | Title |
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KR1019920003674A KR950006539B1 (en) | 1992-03-05 | 1992-03-05 | The printing method of silicone to leather sheet |
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KR1019920003674A KR950006539B1 (en) | 1992-03-05 | 1992-03-05 | The printing method of silicone to leather sheet |
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KR930019426A KR930019426A (en) | 1993-10-18 |
KR950006539B1 true KR950006539B1 (en) | 1995-06-16 |
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KR1019920003674A KR950006539B1 (en) | 1992-03-05 | 1992-03-05 | The printing method of silicone to leather sheet |
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KR100484044B1 (en) * | 2001-12-27 | 2005-04-20 | 최낙희 | Printing method of leather surface |
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- 1992-03-05 KR KR1019920003674A patent/KR950006539B1/en not_active IP Right Cessation
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KR930019426A (en) | 1993-10-18 |
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