KR20220167546A - Method for producing chlorine dioxide solution with improved long-term stability and sterilization activity, chlorine dioxide solution prepared thereby, and packaging box containing the same - Google Patents
Method for producing chlorine dioxide solution with improved long-term stability and sterilization activity, chlorine dioxide solution prepared thereby, and packaging box containing the same Download PDFInfo
- Publication number
- KR20220167546A KR20220167546A KR1020210076652A KR20210076652A KR20220167546A KR 20220167546 A KR20220167546 A KR 20220167546A KR 1020210076652 A KR1020210076652 A KR 1020210076652A KR 20210076652 A KR20210076652 A KR 20210076652A KR 20220167546 A KR20220167546 A KR 20220167546A
- Authority
- KR
- South Korea
- Prior art keywords
- solution
- chlorine dioxide
- purified water
- weight
- dioxide solution
- Prior art date
Links
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 title claims abstract description 175
- 239000004155 Chlorine dioxide Substances 0.000 title claims abstract description 87
- 235000019398 chlorine dioxide Nutrition 0.000 title claims abstract description 87
- 238000004806 packaging method and process Methods 0.000 title claims abstract description 31
- 230000007774 longterm Effects 0.000 title claims abstract description 20
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 17
- 230000001954 sterilising effect Effects 0.000 title claims abstract description 17
- 238000004659 sterilization and disinfection Methods 0.000 title claims description 13
- 230000000694 effects Effects 0.000 title claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 48
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 45
- 239000008213 purified water Substances 0.000 claims abstract description 43
- UKLNMMHNWFDKNT-UHFFFAOYSA-M sodium chlorite Chemical compound [Na+].[O-]Cl=O UKLNMMHNWFDKNT-UHFFFAOYSA-M 0.000 claims abstract description 31
- 229960002218 sodium chlorite Drugs 0.000 claims abstract description 31
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims abstract description 19
- 239000000243 solution Substances 0.000 claims description 79
- 238000003756 stirring Methods 0.000 claims description 32
- 238000002156 mixing Methods 0.000 claims description 26
- 230000000844 anti-bacterial effect Effects 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 6
- 241000894006 Bacteria Species 0.000 abstract description 8
- 241000711573 Coronaviridae Species 0.000 abstract description 6
- 235000011007 phosphoric acid Nutrition 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 7
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 6
- 239000000460 chlorine Substances 0.000 description 6
- 229910052801 chlorine Inorganic materials 0.000 description 6
- 238000004061 bleaching Methods 0.000 description 5
- 241000588724 Escherichia coli Species 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 239000000645 desinfectant Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- XPPKVPWEQAFLFU-UHFFFAOYSA-N diphosphoric acid Chemical compound OP(O)(=O)OP(O)(O)=O XPPKVPWEQAFLFU-UHFFFAOYSA-N 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 241000193830 Bacillus <bacterium> Species 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- XTEGARKTQYYJKE-UHFFFAOYSA-N chloric acid Chemical compound OCl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-N 0.000 description 2
- 229940005991 chloric acid Drugs 0.000 description 2
- TVWHTOUAJSGEKT-UHFFFAOYSA-N chlorine trioxide Chemical compound [O]Cl(=O)=O TVWHTOUAJSGEKT-UHFFFAOYSA-N 0.000 description 2
- SAUMVKNLVQDHMJ-UHFFFAOYSA-N dichlorine trioxide Inorganic materials ClOCl(=O)=O SAUMVKNLVQDHMJ-UHFFFAOYSA-N 0.000 description 2
- YWEUIGNSBFLMFL-UHFFFAOYSA-N diphosphonate Chemical compound O=P(=O)OP(=O)=O YWEUIGNSBFLMFL-UHFFFAOYSA-N 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 230000014509 gene expression Effects 0.000 description 2
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 2
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 2
- DLYUQMMRRRQYAE-UHFFFAOYSA-N phosphorus pentoxide Inorganic materials O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 229940005657 pyrophosphoric acid Drugs 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 244000063299 Bacillus subtilis Species 0.000 description 1
- 235000014469 Bacillus subtilis Nutrition 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- BYMMIQCVDHHYGG-UHFFFAOYSA-N Cl.OP(O)(O)=O Chemical compound Cl.OP(O)(O)=O BYMMIQCVDHHYGG-UHFFFAOYSA-N 0.000 description 1
- 241000588722 Escherichia Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 241000589516 Pseudomonas Species 0.000 description 1
- 241001103617 Pseudomonas aeruginosa ATCC 15442 Species 0.000 description 1
- 241000607142 Salmonella Species 0.000 description 1
- 241000293869 Salmonella enterica subsp. enterica serovar Typhimurium Species 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 235000015278 beef Nutrition 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 231100000357 carcinogen Toxicity 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- MAYPHUUCLRDEAZ-UHFFFAOYSA-N chlorine peroxide Inorganic materials ClOOCl MAYPHUUCLRDEAZ-UHFFFAOYSA-N 0.000 description 1
- 230000001332 colony forming effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 235000021323 fish oil Nutrition 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000001963 growth medium Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical group [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- OBSZRRSYVTXPNB-UHFFFAOYSA-N tetraphosphorus Chemical compound P12P3P1P32 OBSZRRSYVTXPNB-UHFFFAOYSA-N 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 150000007521 triprotic acids Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B11/00—Oxides or oxyacids of halogens; Salts thereof
- C01B11/02—Oxides of chlorine
- C01B11/022—Chlorine dioxide (ClO2)
- C01B11/023—Preparation from chlorites or chlorates
- C01B11/024—Preparation from chlorites or chlorates from chlorites
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
- A61L2/16—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using chemical substances
- A61L2/18—Liquid substances or solutions comprising solids or dissolved gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D81/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
- B65D81/24—Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Food Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Epidemiology (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
본 발명은 장기 안정성과 살균활성이 향상된 이산화염소 용액의 제조방법, 이에 의해 제조된 이산화염소 용액 및 이를 포함하는 포장박스에 관한 것으로서, 더욱 상세하게는 장기간 보관 및 유통이 가능하고 살균활성이 향상된 이산화염소 용액을 제조할 수 있고, 상기 이산화염소 용액을 포함하여 코로나 바이러스 등과 같은 유해균을 일정 기간 동안 사멸시켜 안전하고 위생적인 포장박스를 제조할 수 있는 장기 안정성과 살균활성이 향상된 이산화염소 용액의 제조방법, 이에 의해 제조된 이산화염소 용액 및 이를 포함하는 포장박스에 관한 것이다.The present invention relates to a method for preparing a chlorine dioxide solution with improved long-term stability and bactericidal activity, a chlorine dioxide solution prepared thereby, and a packaging box containing the same, and more particularly, to a method for producing a chlorine dioxide solution with improved bactericidal activity and long-term storage and distribution. Method for producing a chlorine dioxide solution with improved long-term stability and sterilization activity capable of producing a chlorine solution and killing harmful bacteria such as corona virus for a certain period of time including the chlorine dioxide solution to manufacture a safe and hygienic packaging box , It relates to a chlorine dioxide solution prepared thereby and a packaging box containing the same.
이산화염소(Chlorine dioxide)는 염소와 산소로 이루어진 화합물로서, 분자식은 ClO2이며, 과산화염소(Chlorine peroxide)라고 불리기도 한다.Chlorine dioxide is a compound composed of chlorine and oxygen. Its molecular formula is ClO 2 and is also called chlorine peroxide.
이러한 이산화염소는 어는점이 -59℃이고 끓는점이 11℃인 상온에서 녹황색을 띄는 기체이고, 약간의 염소냄새가 나며 물과 에테르 등에 잘 녹는데, 상기 이산화염소는 강력한 산화력(산화상태 : +4)으로 살균효과를 가지므로, 살균 소독제로 널리 사용되고 있다.Chlorine dioxide is a greenish-yellow gas at room temperature with a freezing point of -59°C and a boiling point of 11°C, has a slight chlorine odor, and is easily soluble in water and ether. Since it has a sterilizing effect, it is widely used as a sterilization disinfectant.
이러한 이산화염소는 유기물을 산화시키지 않는 장점을 가지고 있는데, 예를 들어, Trihalomethane(THM), 할로아세틱산(HAAs) 및 기타 염소화 유기화합물을 생성하지 않는다.This chlorine dioxide has the advantage of not oxidizing organic matter, for example, it does not produce trihalomethane (THM), haloacetic acid (HAAs) and other chlorinated organic compounds.
또한, 상기 이산화염소는 넓은 pH 범위에서 살균효능을 유지하는 장점이 있고, 부산물로 인한 발암물질 등의 생성이 없고 빛에 의해 쉽게 분해되는 환경친화적 특성 때문에 염소계 소독제의 대체약품으로 활용도가 급속히 확대되고 있으며, 현재 우리나라에서는 환경부 고시(1999-73호)로서 먹는물 관리법에서 살균소독제로 인정(1ppm 이하 사용)되고 있다.In addition, the chlorine dioxide has the advantage of maintaining sterilization efficacy in a wide pH range, and its utilization as an alternative to chlorine-based disinfectants is rapidly expanding due to its environmentally friendly characteristics that it does not produce carcinogens due to by-products and is easily decomposed by light Currently, in Korea, it is recognized as a disinfectant (used below 1ppm) in the Drinking Water Management Act as a notification by the Ministry of Environment (No. 1999-73).
또한, 상기 이산화염소는 다양한 분야에서 사용되고 있는데, 예를 들어, i) 종이, 펄프, 섬유의 표백, ii) 우지, 어유 등의 정제 또는 표백, iii) 물의 소독 및 냄새 제거, iv) 녹말, 밀가루 등의 표백 및 품질 개선 등 다양한 분야에 사용되고 있다.In addition, the chlorine dioxide is used in various fields, for example, i) bleaching of paper, pulp, and fiber, ii) purification or bleaching of beef tallow, fish oil, etc., iii) disinfection and odor removal of water, iv) starch and flour It is used in various fields such as bleaching and quality improvement.
그러나 이러한 이산화염소는 열에 대해서 매우 불안정하며, 열이 가해질 경우 산소와 염소로 분해될 수 있다. 또한, 빛에 대해서도 매우 불안정하여 분해되며, 이 경우 산소, 염소 외에 삼산화 염소를 생성하고, 수분이 존재할 경우 삼산화 염소, 하이포아염소산, 아염소산, 염소산, 과염소산을 생성한다.However, this chlorine dioxide is very unstable to heat and can be decomposed into oxygen and chlorine when heat is applied. In addition, it is very unstable to light and decomposes. In this case, chlorine trioxide is generated in addition to oxygen and chlorine, and when moisture is present, chlorine trioxide, hypochlorous acid, hypochlorous acid, chloric acid, and perchloric acid are generated.
또한, 수소와의 혼합물은 가열하면 폭발하며, 황, 인, 황화물 등과는 접촉하면 폭발하고, 수은, 암모니아와 반응하지만 황산과는 반응하지 않고 흡수되며, 물에 매우 잘 녹아 황갈색의 수용액을 만든다. 상기 수용액은 어두운 곳에서는 안정하지만 빛에 의해서 분해되어 염산과 염소산을 생성한다.In addition, a mixture with hydrogen explodes when heated, explodes when it comes in contact with sulfur, phosphorus, sulfide, etc., reacts with mercury and ammonia, but does not react with sulfuric acid and is absorbed, and dissolves very well in water to form a yellow-brown aqueous solution. The aqueous solution is stable in the dark, but is decomposed by light to produce hydrochloric acid and chloric acid.
이에 본 발명자는 전술한 문제점을 보완하고 상온에서 불안정한 이산화염소에 대해 장기 안정성을 확보하여 장기간 보관 및 유통이 가능한 이산화염소 용액을 제조할 수 있고, 상기 이산화염소 용액을 포함하여 코로나 바이러스 등과 같은 유해균을 일정 기간 동안 사멸시켜 안전하고 위생적인 포장박스를 제조할 수 있음을 확인하고 본 발명을 완성하였다.Accordingly, the present inventors can supplement the above-mentioned problems and secure long-term stability against chlorine dioxide, which is unstable at room temperature, to prepare a chlorine dioxide solution that can be stored and distributed for a long time, including the chlorine dioxide solution, to prevent harmful bacteria such as coronaviruses. It was confirmed that a safe and hygienic packaging box can be manufactured by killing for a certain period of time, and the present invention was completed.
본 발명은 장기간 보관 및 유통이 가능하고 살균활성이 향상된 이산화염소 용액을 제조할 수 있고, 상기 이산화염소 용액을 포함하여 코로나 바이러스 등과 같은 유해균을 일정 기간 동안 사멸시켜 안전하고 위생적인 포장박스를 제조할 수 있는 장기 안정성과 살균활성이 향상된 이산화염소 용액의 제조방법, 이에 의해 제조된 이산화염소 용액 및 이를 포함하는 포장박스를 제공하는데 있다.The present invention can manufacture a chlorine dioxide solution that can be stored and distributed for a long period of time and has improved sterilization activity, and can manufacture a safe and hygienic packaging box by killing harmful bacteria such as corona virus for a certain period of time including the chlorine dioxide solution. It is to provide a method for producing a chlorine dioxide solution with improved long-term stability and bactericidal activity, a chlorine dioxide solution prepared thereby, and a packaging box containing the same.
본 발명이 해결하고자 하는 다양한 과제들은 이상에서 언급한 과제들에 제한되지 않으며, 언급되지 않은 또 다른 과제들은 아래의 기재로부터 당업자에게 명확하게 이해될 수 있을 것이다.Various problems to be solved by the present invention are not limited to the above-mentioned problems, and other problems not mentioned will be clearly understood by those skilled in the art from the following description.
본 발명에 따른 장기 안정성과 살균활성이 향상된 이산화염소 용액의 제조방법은 정제수 및 아염소산나트륨을 혼합한 후 교반하여 1차 용액을 제조하고, 상기 1차 용액에 인산 및 이산화염소수를 혼합한 후 교반하여 2차 용액을 제조하며, 상기 2차 용액에 정제수를 혼합한 후 교반하여 이산화염소 용액을 제조한다.In the method for preparing a chlorine dioxide solution with improved long-term stability and bactericidal activity according to the present invention, purified water and sodium chlorite are mixed and stirred to prepare a first solution, and phosphoric acid and chlorine dioxide are mixed with the first solution. A secondary solution is prepared by stirring, and purified water is mixed with the secondary solution, followed by stirring to prepare a chlorine dioxide solution.
상기 정제수 및 아염소산나트륨을 혼합한 후 교반하여 1차 용액을 제조하는 단계에서, 상기 정제수 및 아염소산나트륨은 각각 정제수 90 내지 100 중량부 및 아염소산나트륨 5 내지 15 중량부의 중량 비율로 혼합되고, 상기 정제수 및 아염소산나트륨의 혼합물을 교반기에서 1 내지 3시간 동안 교반하여 진행될 수 있다.In the step of preparing a first solution by mixing the purified water and sodium chlorite and then stirring them, the purified water and sodium chlorite are mixed in a weight ratio of 90 to 100 parts by weight of purified water and 5 to 15 parts by weight of sodium chlorite, respectively, The mixture of the purified water and sodium chlorite may be stirred in a stirrer for 1 to 3 hours.
상기 1차 용액에 인산 및 이산화염소수를 혼합한 후 교반하여 2차 용액을 제조하는 단계에서는, 상기 1차 용액 전체 함량 100 중량부에 대해 인산 4 내지 8 중량부 및 이산화염소수 20 내지 30 중량부의 중량 비율로 혼합한 후 30 내지 100분 동안 교반하여 2차 용액을 제조할 수 있다.In the step of preparing a secondary solution by mixing phosphoric acid and chlorine dioxide in the primary solution and then stirring to prepare the secondary solution, 4 to 8 parts by weight of phosphoric acid and 20 to 30 parts by weight of chlorine dioxide are added to 100 parts by weight of the total amount of the primary solution. After mixing in a negative weight ratio, a secondary solution may be prepared by stirring for 30 to 100 minutes.
상기 2차 용액에 정제수를 혼합한 후 교반하여 이산화염소 용액을 제조하는 단계에서는, 상기 1차 용액 전체 함량 100 중량부에 대해, 정제수 10 내지 30 중량부의 중량 비율로 혼합한 후 30 내지 100분 동안 교반하여 이산화염소 용액을 제조할 수 있다.In the step of mixing purified water with the secondary solution and stirring to prepare a chlorine dioxide solution, 10 to 30 parts by weight of purified water is mixed with respect to 100 parts by weight of the total content of the primary solution, and then mixed for 30 to 100 minutes. A chlorine dioxide solution may be prepared by stirring.
또한, 본 발명은 상기한 방법으로 제조된 이산화염소 용액을 포함한다.In addition, the present invention includes a chlorine dioxide solution prepared by the above method.
또한, 본 발명에 따른 장기 안정성과 살균활성이 향상된 이산화염소 용액이 포함된 포장박스는 포장박스 전체 함량 중에서 이산화염소 용액은 1 내지 10 중량%의 중량 비율로 포함되고, 상기 이산화염소 용액은, 정제수 및 아염소산나트륨을 혼합한 후 교반하여 1차 용액을 제조하고, 상기 1차 용액에 인산 및 이산화염소수를 혼합한 후 교반하여 2차 용액을 제조하며, 상기 2차 용액에 정제수를 혼합한 후 교반하여 제조된다.In addition, in the packaging box containing the chlorine dioxide solution with improved long-term stability and sterilization activity according to the present invention, the chlorine dioxide solution is included in a weight ratio of 1 to 10% by weight of the total content of the packaging box, and the chlorine dioxide solution is purified water And sodium chlorite is mixed and stirred to prepare a first solution, phosphoric acid and chlorine dioxide are mixed with the first solution, stirred to prepare a second solution, and purified water is mixed with the second solution. It is prepared by stirring.
상기 정제수 및 아염소산나트륨을 혼합한 후 교반하여 1차 용액을 제조하는 단계에서, 상기 정제수 및 아염소산나트륨은 각각 정제수 90 내지 100 중량부 및 아염소산나트륨 5 내지 15 중량부의 중량 비율로 혼합되고, 상기 정제수 및 아염소산나트륨의 혼합물을 교반기에서 1 내지 3시간 동안 교반하여 진행될 수 있다.In the step of preparing a first solution by mixing the purified water and sodium chlorite and then stirring them, the purified water and sodium chlorite are mixed in a weight ratio of 90 to 100 parts by weight of purified water and 5 to 15 parts by weight of sodium chlorite, respectively, The mixture of the purified water and sodium chlorite may be stirred in a stirrer for 1 to 3 hours.
상기 1차 용액에 인산 및 이산화염소수를 혼합한 후 교반하여 2차 용액을 제조하는 단계에서는, 상기 1차 용액 전체 함량 100 중량부에 대해 인산 4 내지 8 중량부 및 이산화염소수 20 내지 30 중량부의 중량 비율로 혼합한 후 30 내지 100분 동안 교반하여 2차 용액을 제조할 수 있다.In the step of preparing a secondary solution by mixing phosphoric acid and chlorine dioxide in the primary solution and then stirring to prepare the secondary solution, 4 to 8 parts by weight of phosphoric acid and 20 to 30 parts by weight of chlorine dioxide are added to 100 parts by weight of the total amount of the primary solution. After mixing in a negative weight ratio, a secondary solution may be prepared by stirring for 30 to 100 minutes.
상기 2차 용액에 정제수를 혼합한 후 교반하여 이산화염소 용액을 제조하는 단계에서는, 상기 1차 용액 전체 함량 100 중량부에 대해, 정제수 10 내지 30 중량부의 중량 비율로 혼합한 후 30 내지 100분 동안 교반하여 이산화염소 용액을 제조할 수 있다.In the step of mixing purified water with the secondary solution and stirring to prepare a chlorine dioxide solution, 10 to 30 parts by weight of purified water is mixed with respect to 100 parts by weight of the total content of the primary solution, and then mixed for 30 to 100 minutes. A chlorine dioxide solution may be prepared by stirring.
기타 실시 예들의 구체적인 사항들은 상세한 설명에 포함되어 있다.Details of other embodiments are included in the detailed description.
본 발명은 장기간 보관 및 유통이 가능하고 살균활성이 향상된 이산화염소 용액을 제조할 수 있고, 상기 이산화염소 용액을 포함하여 코로나 바이러스 등과 같은 유해균을 일정 기간 동안 사멸시켜 안전하고 위생적인 포장박스를 제조할 수 있다.The present invention can manufacture a chlorine dioxide solution that can be stored and distributed for a long period of time and has improved sterilization activity, and can manufacture a safe and hygienic packaging box by killing harmful bacteria such as corona virus for a certain period of time including the chlorine dioxide solution. can
본 발명의 기술적 사상의 실시예는, 구체적으로 언급되지 않은 다양한 효과를 제공할 수 있다는 것이 충분히 이해될 수 있을 것이다.It will be fully understood that embodiments of the technical idea of the present invention can provide various effects not specifically mentioned.
본 발명의 이점 및 특징, 그리고 그것들을 달성하는 방법은 상세하게 후술되어 있는 실시예를 참조하면 명확해질 것이다. 그러나 본 발명은 여기서 설명되는 실시예들에 한정되지 않고 다른 형태로 구체화될 수도 있다. 오히려, 여기서 소개되는 실시예들은 개시된 내용이 철저하고 완전해질 수 있도록 그리고 당업자에게 본 발명의 사상이 충분히 전달될 수 있도록 하기 위해 제공되는 것이다.The advantages and features of the present invention, and how to achieve them, will become clear with reference to the detailed description of the embodiments below. However, the present invention is not limited to the embodiments described herein and may be embodied in other forms. Rather, the embodiments introduced herein are provided so that the disclosed content will be thorough and complete and the spirit of the present invention will be sufficiently conveyed to those skilled in the art.
본 출원에서 사용한 용어는 단지 특정한 실시예를 설명하기 위해 사용된 것으로, 본 발명을 한정하려는 의도가 아니다. 단수의 표현은 문맥상 명백하게 다르게 뜻하지 않는 한, 복수의 표현을 포함한다.Terms used in this application are only used to describe specific embodiments, and are not intended to limit the present invention. Singular expressions include plural expressions unless the context clearly dictates otherwise.
다르게 정의되지 않는 한, 기술적이거나 과학적인 용어를 포함해서 여기서 사용되는 모든 용어들은 본 발명이 속하는 기술 분야에서 통상의 지식을 가진 자에 의해 일반적으로 이해되는 것과 동일한 의미가 있다. 일반적으로 사용되는 사전에 정의되어 있는 것과 같은 용어들은 관련 기술의 문맥상 가지는 의미와 일치하는 의미가 있는 것으로 해석되어야 하며, 본 출원에서 명백하게 정의하지 않는 한, 이상적이거나 과도하게 형식적인 의미로 해석되지 않는다.Unless defined otherwise, all terms used herein, including technical or scientific terms, have the same meaning as commonly understood by one of ordinary skill in the art to which the present invention belongs. Terms such as those defined in commonly used dictionaries should be interpreted as having meanings consistent with the meanings in the context of the related art, and unless explicitly defined in this application, they should not be interpreted in ideal or excessively formal meanings. don't
이하, 본 발명에 따른 장기 안정성과 살균활성이 향상된 이산화염소 용액의 제조방법에 대하여 바람직한 실시예를 들어 상세하게 설명한다.Hereinafter, a method for preparing a chlorine dioxide solution with improved long-term stability and bactericidal activity according to the present invention will be described in detail with reference to preferred embodiments.
본 발명에 따른 장기 안정성과 살균활성이 향상된 이산화염소 용액을 제조하기 위하여, 먼저, 정제수 및 아염소산나트륨을 혼합한 후 교반하여 1차 용액을 제조할 수 있다.In order to prepare a chlorine dioxide solution with improved long-term stability and bactericidal activity according to the present invention, first, purified water and sodium chlorite may be mixed and then stirred to prepare a primary solution.
상기 단계에서 상기 정제수 및 아염소산나트륨은 각각 정제수 90 내지 100 중량부 및 아염소산나트륨 5 내지 15 중량부의 중량 비율로 혼합되고, 상기 정제수 및 아염소산나트륨의 혼합물을 교반기에서 1 내지 3시간 동안 교반함으로써 진행될 수 있다.In the above step, the purified water and sodium chlorite are mixed in a weight ratio of 90 to 100 parts by weight of purified water and 5 to 15 parts by weight of sodium chlorite, respectively, and the mixture of the purified water and sodium chlorite is stirred in a stirrer for 1 to 3 hours. can proceed
상기 아염소산나트륨의 화학식은 NaClO2이고, 분자량은 90.5이며, 폭발성과 약한 흡습성을 지닌 백색의 결정성 분말로, 130~140℃의 온도에서 분해되며, 상기 아염소산나트륨의 구조식은 하기와 같이 나타낼 수 있다.The chemical formula of the sodium chlorite is NaClO 2 , the molecular weight is 90.5, it is a white crystalline powder with explosive properties and weak hygroscopicity, and it decomposes at a temperature of 130 to 140 ° C. The structural formula of the sodium chlorite is represented as follows: can
상기 아염소산나트륨은 공업적으로는 이산화염소에 수산화나트륨과 환원제(탄소·과산화수소 등)를 가하고, 다시 수산화칼슘을 작용시켜서 제조될 수 있는데, 이산화염소를 수산화나트륨만으로 반응시키면 염소산나트륨이 동시에 생긴다.The sodium chlorite can be industrially produced by adding sodium hydroxide and a reducing agent (carbon, hydrogen peroxide, etc.) to chlorine dioxide, and then reacting calcium hydroxide with it.
무수염은 약간 조해성(潮解性)이 있으며, 물에 녹아 알칼리성을 보이고, 수용액은 산성인 상태에서 분해하여 이산화염소를 생성하는데, 이 때문에 표백작용이 있어 펄프·섬유제품(특히, 합성섬유)·식품의 표백, 수도물의 살균에 사용될 수 있다.Anhydrous salt is slightly deliquescent and shows alkalinity when dissolved in water, and the aqueous solution decomposes in an acidic state to generate chlorine dioxide, which has a bleaching effect, so that pulp, textile products (especially synthetic fibers), It can be used for bleaching food and sterilizing tap water.
[아염소산나트륨 구조식][Sodium chlorite structural formula]
다음으로, 상기 1차 용액에 인산 및 이산화염소수를 혼합한 후 교반하여 2차 용액을 제조할 수 있다.Next, a secondary solution may be prepared by mixing phosphoric acid and chlorine dioxide in the primary solution and then stirring.
상기 단계에서는 상기 1차 용액 전체 함량 100 중량부에 대해 인산 4 내지 8 중량부 및 이산화염소수 20 내지 30 중량부의 중량 비율로 혼합한 후 30 내지 100분 동안 교반함으로써 2차 용액을 제조할 수 있다.In the above step, a secondary solution can be prepared by mixing 4 to 8 parts by weight of phosphoric acid and 20 to 30 parts by weight of chlorine dioxide solution in a weight ratio with respect to 100 parts by weight of the total content of the first solution and then stirring for 30 to 100 minutes. .
상기 인산(Phosphoric acid)은 오산화인(phosphorus pentoxide)의 가수분해로 만들어지는 산으로서, 넓은 범주에서는 인 산소산(phosphorus oxyacid)의 일종인데, 상기 인산의 원료가 되는 오산화인은 [P2O5]의 실험식으로 표기하지만, 실제 분자식은 [P4O10]이며, 하기의 [반응식 1]과 같이 백린(white phosphorus; P4)과 산소의 반응을 통해 얻을 수 있다. 이와 같은 산화 과정을 통해 인은 가장 높은 +5의 산화수를 갖게 된다.Phosphoric acid is an acid made by hydrolysis of phosphorus pentoxide , and is a kind of phosphorus oxyacid in a wide range. Although expressed as an empirical formula, the actual molecular formula is [P 4 O 10 ], and can be obtained through the reaction of white phosphorus (P 4 ) and oxygen as shown in [Scheme 1] below. Through this oxidation process, phosphorus has the highest oxidation number of +5.
[반응식 1][Scheme 1]
[반응식 2][Scheme 2]
상기 [반응식 2]를 참조하면, 오산화인 가수분해 반응의 생성물인 H3PO4는 인산의 가장 단순한 형태로 오쏘인산(orthophosphoric acid, 또는 오르토인산)이라고 부르며, 상기 오쏘인산 두 분자의 축합반응으로 파이로인산(pyrophosphoric acid, ; 피로인산, 이인산, 혹은 초성인산으로도 불린다)이 얻어질 수 있다.Referring to [Reaction Scheme 2], H 3 PO 4 , which is a product of phosphorus pentoxide hydrolysis, is called orthophosphoric acid (or orthophosphoric acid) in the simplest form of phosphoric acid, and is formed by a condensation reaction of two molecules of orthophosphoric acid. Pyrophosphoric acid (also called pyrophosphoric acid, diphosphoric acid, or superphosphoric acid) can be obtained.
정제된 인산은 상온에서 결정성이 있는 고체(녹는점: 42.3℃)로 밀도는 2.030g/cm3(25℃ 기준)이고, 인산은 446g/100mL 정도로 물에 녹으며(14.95℃ 기준), 수용액에서 삼양성자산(triprotic acid)으로 작용하여 양성자를 세 개까지 내놓고, H3PO4 -, HPO4 2-, PO4 3-의 세 가지 음이온을 만들 수 있다.Refined phosphoric acid is a crystalline solid (melting point: 42.3℃) at room temperature and has a density of 2.030g/cm 3 (at 25℃). It can act as a triprotic acid to release up to three protons and form three anions: H 3 PO 4 - , HPO 4 2- , and PO 4 3- .
상기 이산화염소수(aqueous chlorine dioxide)는 예를 들어, 파우더 형태의 아염소산나트륨 및 염화수소 용액을 이용하여 제조할 수 있으며, 아염소나트륨 용액 및 염화수소 용액을 이용하여 제조할 수 있으나 이에 한정되지 않고, 또한, 상기 이산화염소수는 30 내지 100ppm의 농도일 수 있다.The chlorine dioxide (aqueous chlorine dioxide) can be prepared, for example, using sodium chlorite and hydrogen chloride solution in powder form, and can be prepared using sodium chlorine solution and hydrogen chloride solution, but is not limited thereto, In addition, the chlorine dioxide solution may have a concentration of 30 to 100 ppm.
상기 이산화염소수는 독성이 강하지 않고 안전하며 오염을 일으키지 않아 친환경적이며, 강한 산화작용의 특징을 지님에 따라 정수의 살균처리제나 종이 섬유 식품 등의 표백제 또는 탈취제로 사용되고 있다.The chlorine dioxide water is safe, non-toxic, environmentally friendly because it does not cause contamination, and is used as a disinfectant for purified water or as a bleaching agent or deodorizer for paper fiber foods, etc., as it has strong oxidizing properties.
이어서, 상기 2차 용액에 정제수를 혼합한 후 교반하여 이산화염소 용액을 제조할 수 있다.Subsequently, a chlorine dioxide solution may be prepared by mixing purified water with the secondary solution and then stirring.
상기 단계에서는 상기 1차 용액 전체 함량 100 중량부에 대해, 정제수 10 내지 30 중량부의 중량 비율로 혼합한 후 30 내지 100분 동안 교반함으로써 이산화염소 용액을 제조할 수 있다.In the above step, a chlorine dioxide solution may be prepared by mixing in a weight ratio of 10 to 30 parts by weight of purified water with respect to 100 parts by weight of the total content of the primary solution and then stirring for 30 to 100 minutes.
본 발명에 따라 제조된 장기 안정성과 살균활성이 향상된 이산화염소 용액은 포장박스에 적용되어 코로나 바이러스 등과 같은 유해균을 일정 기간 동안 사멸시켜 안전하고 위생적인 포장박스를 제조할 수 있는데, 상기 포장박스 전체 함량 중에서 상기 이산화염소 용액은 1 내지 10 중량%의 중량 비율로 포함될 수 있다.The chlorine dioxide solution with improved long-term stability and sterilization activity prepared according to the present invention can be applied to a packaging box to kill harmful bacteria such as corona virus for a certain period of time to manufacture a safe and hygienic packaging box. Among them, the chlorine dioxide solution may be included in a weight ratio of 1 to 10% by weight.
이때, 상기 이산화염소 용액은 상기 포장박스의 표면에 도포되어 사용되거나, 또는 포장박스를 제조하기 위한 원료에 혼합되어 포함될 수 있는데, 상기 이산화염소 용액을 포장박스에 도포 또는 원료에 혼합하는 방법은 다양할 수 있는바, 설명의 편의 및 본 발명의 기술적 사상의 명확성을 위하여 이에 대한 구체적인 설명은 생략하기로 한다.At this time, the chlorine dioxide solution may be used by being applied to the surface of the packaging box, or may be mixed with raw materials for manufacturing the packaging box. There are various methods of applying the chlorine dioxide solution to the packaging box or mixing it with raw materials. As possible, detailed descriptions thereof will be omitted for convenience of description and clarity of the technical idea of the present invention.
이하, 본 발명에 따른 이산화염소 용액을 포함하는 포장박스에 대하여 더욱 구체적으로 설명하기로 한다.Hereinafter, the packaging box containing the chlorine dioxide solution according to the present invention will be described in more detail.
< 실시예 >< Example >
먼저, 정제수 552kg 및 아염소산나트륨 48kg을 교반기에 투입한 후 2시간 동안 교반하여 1차 용액을 제조하였다.First, 552 kg of purified water and 48 kg of sodium chlorite were put into a stirrer and stirred for 2 hours to prepare a primary solution.
다음으로, 상기 1차 용액에 인산 36kg 및 인산화염소수 150kg을 혼합한 후 60분 동안 교반함으로써 2차 용액을 제조하였다.Next, a second solution was prepared by mixing 36 kg of phosphoric acid and 150 kg of chlorine phosphate solution with the first solution and stirring for 60 minutes.
그 다음으로, 상기 2차 용액에 정제수 100kg을 혼합한 후 60분 동안 교반함으로써 이산화염소 용액을 제조하였다.Next, a chlorine dioxide solution was prepared by mixing 100 kg of purified water with the secondary solution and stirring for 60 minutes.
이어서, 상기 이산화염소 용액의 함량이 포장박스 전체 함량 중에서 5 중량%가 되도록 계량한 후 상기 포장박스 표면에 도포하였다.Subsequently, the content of the chlorine dioxide solution was measured to be 5% by weight of the total content of the packaging box, and then applied to the surface of the packaging box.
< 비교예 ><Comparative Example>
포장박스를 준비한 후 이를 비교예에 따른 포장박스로 사용하였다.After preparing the packaging box, it was used as a packaging box according to Comparative Example.
이때, 비교예에 따른 포장박스에는 이산화염소 용액을 도포하지 않았다.At this time, the chlorine dioxide solution was not applied to the packaging box according to the comparative example.
1. 살균 시험 - 11. Sterilization test - 1
상기 실시예와 비교예에 따라 제조된 포장박스를 이용하여 사용균주 Escherichia coil ATCC 25922 및 Pseudomonas aeruginosa ATCC 15442을 이용하여 항균 시험을 수행하였으며, 그 결과를 하기의 [표 1]에 나타내었다.An antibacterial test was performed using the used strains Escherichia coil ATCC 25922 and Pseudomonas aeruginosa ATCC 15442 using the packaging boxes prepared according to the above Examples and Comparative Examples, and the results are shown in [Table 1] below.
상기 [표 1]을 참조하면, 비교예에 따른 포장박스는 시간이 경과함에 따라 세균이 증가하고 있으나, 실시예에 따른 포장박스는 세균이 감소하는 것을 확인할 수 있었다.Referring to [Table 1], it was confirmed that the number of bacteria increased over time in the packaging box according to the comparative example, but the number of bacteria decreased in the packaging box according to the example.
여기서, 농도의 단위 중 CFU는 Colony Forming Unit를 의미하며 40p는 0.04mL를 의미한다.Here, among the units of concentration, CFU means Colony Forming Unit and 40p means 0.04mL.
2. 살균 시험 - 22. Sterilization test - 2
상기 실시예에 따라 제조된 포장박스 시편을(5×5mm)을 준비하여 바실러스균(Bacillus subtilis ), 대장균(Escherichiaocli) 및 살모넬라균(Salmonella typhimurium ) 배양액을 대상으로 페이퍼디스크(Paper disk) 법을 이용하여 항균성을 조사하였고, 그 결과를 하기 [표 2]에 제시하였다.Prepare a packaging box specimen (5 × 5 mm) prepared according to the above embodiment and use the paper disk method for Bacillus subtilis, Escherichia coli and Salmonella typhimurium culture medium The antibacterial properties were investigated, and the results are presented in [Table 2].
상기 [표 2]를 참조하면, 실시예에 따라 제조된 포장박스는 바실러스균, 대장균 및 살모네라균 모두에 대하여 항균활성이 우수함을 확인할 수 있었다.Referring to [Table 2], it was confirmed that the packaging boxes manufactured according to the examples had excellent antibacterial activity against all of Bacillus, Escherichia coli and Salmonera.
이상, 본 발명의 바람직한 일 실시예를 설명하였지만, 본 발명이 속하는 기술분야에서 통상의 지식을 가진 자라면 본 발명이 그 기술적 사상이나 필수적인 특징을 변경하지 않고서 다른 구체적인 형태로 실시될 수 있다는 것을 이해할 수 있을 것이다. 그러므로 이상에서 기술한 일 실시예는 모든 면에서 예시적인 것이며 한정적이 아닌 것으로 이해해야만 한다.Although the preferred embodiment of the present invention has been described above, those skilled in the art will understand that the present invention can be implemented in other specific forms without changing the technical spirit or essential features. You will be able to. Therefore, one embodiment described above should be understood as illustrative in all respects and not limiting.
Claims (7)
상기 1차 용액에 인산 및 이산화염소수를 혼합한 후 교반하여 2차 용액을 제조하며,
상기 2차 용액에 정제수를 혼합한 후 교반하여 이산화염소 용액을 제조하는 것을 특징을 하는 장기 안정성과 살균활성이 향상된 이산화염소 용액의 제조방법.
Purified water and sodium chlorite were mixed and stirred to prepare a primary solution,
Phosphoric acid and chlorine dioxide are mixed with the first solution and stirred to prepare a second solution,
Method for producing a chlorine dioxide solution with improved long-term stability and bactericidal activity, characterized in that the secondary solution is mixed with purified water and stirred to prepare a chlorine dioxide solution.
상기 정제수 및 아염소산나트륨을 혼합한 후 교반하여 1차 용액을 제조하는 단계에서, 상기 정제수 및 아염소산나트륨은 각각 정제수 90 내지 100 중량부 및 아염소산나트륨 5 내지 15 중량부의 중량 비율로 혼합되고, 상기 정제수 및 아염소산나트륨의 혼합물을 교반기에서 1 내지 3시간 동안 교반하여 진행되는 것을 특징으로 하는 장기 안정성과 살균활성이 향상된 이산화염소 용액의 제조방법.
According to claim 1,
In the step of preparing a first solution by mixing the purified water and sodium chlorite and then stirring them, the purified water and sodium chlorite are mixed in a weight ratio of 90 to 100 parts by weight of purified water and 5 to 15 parts by weight of sodium chlorite, respectively, Method for producing a chlorine dioxide solution with improved long-term stability and bactericidal activity, characterized in that the mixture of the purified water and sodium chlorite is stirred in a stirrer for 1 to 3 hours.
상기 1차 용액에 인산 및 이산화염소수를 혼합한 후 교반하여 2차 용액을 제조하는 단계에서는, 상기 1차 용액 전체 함량 100 중량부에 대해 인산 4 내지 8 중량부 및 이산화염소수 20 내지 30 중량부의 중량 비율로 혼합한 후 30 내지 100분 동안 교반하여 2차 용액을 제조하는 것을 특징으로 하는 장기 안정성과 살균활성이 향상된 이산화염소 용액의 제조방법.
According to claim 2,
In the step of preparing a secondary solution by mixing phosphoric acid and chlorine dioxide in the primary solution and then stirring to prepare the secondary solution, 4 to 8 parts by weight of phosphoric acid and 20 to 30 parts by weight of chlorine dioxide are added to 100 parts by weight of the total amount of the primary solution. A method for producing a chlorine dioxide solution with improved long-term stability and bactericidal activity, characterized in that the secondary solution is prepared by stirring for 30 to 100 minutes after mixing in a negative weight ratio.
상기 2차 용액에 정제수를 혼합한 후 교반하여 이산화염소 용액을 제조하는 단계에서는, 상기 1차 용액 전체 함량 100 중량부에 대해, 정제수 10 내지 30 중량부의 중량 비율로 혼합한 후 30 내지 100분 동안 교반하여 이산화염소 용액을 제조하는 것을 특징으로 하는 장기 안정성과 살균활성이 향상된 이산화염소 용액의 제조방법.
According to claim 3,
In the step of mixing purified water with the secondary solution and stirring to prepare a chlorine dioxide solution, 10 to 30 parts by weight of purified water is mixed with respect to 100 parts by weight of the total content of the primary solution, and then mixed for 30 to 100 minutes. A method for producing a chlorine dioxide solution with improved long-term stability and bactericidal activity, characterized in that the chlorine dioxide solution is prepared by stirring.
A chlorine dioxide solution with improved long-term stability and bactericidal activity, characterized in that it is prepared by any one method selected from claims 1 to 4.
상기 이산화염소 용액은, 정제수 및 아염소산나트륨을 혼합한 후 교반하여 1차 용액을 제조하고, 상기 1차 용액에 인산 및 이산화염소수를 혼합한 후 교반하여 2차 용액을 제조하며, 상기 2차 용액에 정제수를 혼합한 후 교반하여 제조된 것을 특징으로 하는 장기 안정성과 살균활성이 향상된 이산화염소 용액이 포함된 포장박스.
Of the total content of the packaging box, the chlorine dioxide solution is included in a weight ratio of 1 to 10% by weight,
The chlorine dioxide solution is prepared by mixing purified water and sodium chlorite and stirring to prepare a first solution, mixing phosphoric acid and chlorine dioxide with the first solution and stirring to prepare a second solution, A packaging box containing a chlorine dioxide solution with improved long-term stability and sterilization activity, characterized in that it is prepared by mixing purified water with the solution and then stirring it.
상기 정제수 및 아염소산나트륨을 혼합한 후 교반하여 1차 용액을 제조하는 단계에서, 상기 정제수 및 아염소산나트륨은 각각 정제수 90 내지 100 중량부 및 아염소산나트륨 5 내지 15 중량부의 중량 비율로 혼합되고, 상기 정제수 및 아염소산나트륨의 혼합물을 교반기에서 1 내지 3시간 동안 교반하여 진행되며,
상기 1차 용액에 인산 및 이산화염소수를 혼합한 후 교반하여 2차 용액을 제조하는 단계에서는, 상기 1차 용액 전체 함량 100 중량부에 대해 인산 4 내지 8 중량부 및 이산화염소수 20 내지 30 중량부의 중량 비율로 혼합한 후 30 내지 100분 동안 교반하여 2차 용액을 제조하고,
상기 2차 용액에 정제수를 혼합한 후 교반하여 이산화염소 용액을 제조하는 단계에서는, 상기 1차 용액 전체 함량 100 중량부에 대해, 정제수 10 내지 30 중량부의 중량 비율로 혼합한 후 30 내지 100분 동안 교반하여 이산화염소 용액을 제조하는 것을 특징으로 하는 장기 안정성과 살균활성이 향상된 이산화염소 용액이 포함된 포장박스.According to claim 6,
In the step of preparing a first solution by mixing the purified water and sodium chlorite and then stirring them, the purified water and sodium chlorite are mixed in a weight ratio of 90 to 100 parts by weight of purified water and 5 to 15 parts by weight of sodium chlorite, respectively, The mixture of the purified water and sodium chlorite is stirred in a stirrer for 1 to 3 hours,
In the step of preparing a secondary solution by mixing phosphoric acid and chlorine dioxide in the primary solution and then stirring to prepare the secondary solution, 4 to 8 parts by weight of phosphoric acid and 20 to 30 parts by weight of chlorine dioxide are added to 100 parts by weight of the total amount of the primary solution. After mixing in a negative weight ratio, stirring for 30 to 100 minutes to prepare a secondary solution,
In the step of mixing purified water with the secondary solution and stirring to prepare a chlorine dioxide solution, 10 to 30 parts by weight of purified water is mixed with respect to 100 parts by weight of the total content of the primary solution, and then mixed for 30 to 100 minutes. A packaging box containing a chlorine dioxide solution with improved long-term stability and sterilization activity, characterized in that the chlorine dioxide solution is prepared by stirring.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020210076652A KR20220167546A (en) | 2021-06-14 | 2021-06-14 | Method for producing chlorine dioxide solution with improved long-term stability and sterilization activity, chlorine dioxide solution prepared thereby, and packaging box containing the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020210076652A KR20220167546A (en) | 2021-06-14 | 2021-06-14 | Method for producing chlorine dioxide solution with improved long-term stability and sterilization activity, chlorine dioxide solution prepared thereby, and packaging box containing the same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20220167546A true KR20220167546A (en) | 2022-12-21 |
Family
ID=84536645
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020210076652A KR20220167546A (en) | 2021-06-14 | 2021-06-14 | Method for producing chlorine dioxide solution with improved long-term stability and sterilization activity, chlorine dioxide solution prepared thereby, and packaging box containing the same |
Country Status (1)
| Country | Link |
|---|---|
| KR (1) | KR20220167546A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100973826B1 (en) | 2008-06-23 | 2010-08-04 | 고려대학교 산학협력단 | Methods to produce chlorine dioxide solution increased storability and bactericidal activity |
| KR20190108905A (en) | 2018-03-16 | 2019-09-25 | 주식회사 그린팜바이오 | Composition comprising long-term stable chlorine dioxide and method for preparing thereof |
| KR102147093B1 (en) | 2019-12-04 | 2020-08-25 | 송정영 | A Room Temperature Stable Chlorine Dioxide Composite And The Fabrication Method Thereof |
-
2021
- 2021-06-14 KR KR1020210076652A patent/KR20220167546A/en not_active Application Discontinuation
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100973826B1 (en) | 2008-06-23 | 2010-08-04 | 고려대학교 산학협력단 | Methods to produce chlorine dioxide solution increased storability and bactericidal activity |
| KR20190108905A (en) | 2018-03-16 | 2019-09-25 | 주식회사 그린팜바이오 | Composition comprising long-term stable chlorine dioxide and method for preparing thereof |
| KR102147093B1 (en) | 2019-12-04 | 2020-08-25 | 송정영 | A Room Temperature Stable Chlorine Dioxide Composite And The Fabrication Method Thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US6068861A (en) | Concentrated aqueous bromine solutions and their preparation | |
| JP2019073540A (en) | Method for producing aqueous solution containing chlorous acid to be used as disinfectant | |
| CN110040688B (en) | Preparation method of stable chlorine dioxide solution | |
| JP2008505083A (en) | Stable bromine oxide composition for inhibiting biofouling, and method for producing and using the same | |
| CA2568324A1 (en) | Water treatment | |
| EP1618786B1 (en) | Composition for bactericide production and process for producing organic peracid | |
| KR101286088B1 (en) | Method for Preparing Hypochlorous Acid Water with High Stability | |
| KR20220167546A (en) | Method for producing chlorine dioxide solution with improved long-term stability and sterilization activity, chlorine dioxide solution prepared thereby, and packaging box containing the same | |
| CN111771909A (en) | Disinfecting composition and preparation method thereof | |
| CN113080200A (en) | Chlorine dioxide disinfectant without reactivation and preparation method thereof | |
| KR20200002336A (en) | The manufacturing method of aqeous chlorine dioxide | |
| KR20190108905A (en) | Composition comprising long-term stable chlorine dioxide and method for preparing thereof | |
| KR101550308B1 (en) | Disinfectant method that can determine the degree of sterilization and a product of using it | |
| CN115363025A (en) | Efficient stable sodium hypochlorite disinfectant and preparation method thereof | |
| US20100221361A1 (en) | Stable oxidizing bromine composition, method of manufacture and use thereof for biofouling control | |
| KR101505466B1 (en) | Method of preparing sterilization composition having improved microbicidal activity and sterilization method using the composition | |
| CN112889818A (en) | Method for preparing composite quaternary ammonium salt disinfectant effervescent tablet | |
| AU2015203851A1 (en) | Process for producing aqueous chlorous acid solution for use as disinfectant | |
| JP4047300B2 (en) | Method for producing organic peracid | |
| CN1943359A (en) | Method for preparing sterilizing and alga killing agent | |
| Kunigk et al. | Influence of temperature and pH on the decomposition kinetics of peracetic acid in aqueous solutions | |
| KR970000300B1 (en) | Process for the preparation of stabilized chlorine dioxide | |
| CN114766506B (en) | Chlorine dioxide disinfectant and preparation method and application thereof | |
| CN113383789B (en) | Hypochlorous acid aqueous solution and preparation method and application thereof | |
| US20240156099A1 (en) | Composition for generation of chlorine dioxide for use as sanitizer |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| E902 | Notification of reason for refusal | ||
| E902 | Notification of reason for refusal |