KR20170011987A - Halogen free flame-retardant crosslinked polyolefin insulation wire - Google Patents
Halogen free flame-retardant crosslinked polyolefin insulation wire Download PDFInfo
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- KR20170011987A KR20170011987A KR1020160033023A KR20160033023A KR20170011987A KR 20170011987 A KR20170011987 A KR 20170011987A KR 1020160033023 A KR1020160033023 A KR 1020160033023A KR 20160033023 A KR20160033023 A KR 20160033023A KR 20170011987 A KR20170011987 A KR 20170011987A
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- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
- H01B7/29—Protection against damage caused by extremes of temperature or by flame
- H01B7/295—Protection against damage caused by extremes of temperature or by flame using material resistant to flame
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
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- C09K21/00—Fireproofing materials
- C09K21/02—Inorganic materials
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- H—ELECTRICITY
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- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
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- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/307—Other macromolecular compounds
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- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
- H01B7/29—Protection against damage caused by extremes of temperature or by flame
- H01B7/292—Protection against damage caused by extremes of temperature or by flame using material resistant to heat
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- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/66—Substances characterised by their function in the composition
- C08L2666/84—Flame-proofing or flame-retarding additives
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Abstract
Description
The present invention relates to a halogen-free flame-retardant crosslinked polyolefin insulation wire. More specifically, the present invention relates to a resin composition which is environmentally friendly, has excellent flame retardancy and pourable properties, is excellent in heat resistance, water resistance, insulation properties, cold resistance and oil resistance, Halogen flame retardant polyolefin bridged insulated wires which can suppress the blooming effect of elution of white powder into the flame retardant polyolefin.
Electric wires used for general electrical work or electrical equipment wiring, indoor wiring, etc., have excellent heat resistance, flame retardancy, water resistance, chemical resistance, insulation, cold resistance and oil resistance .
In addition, the wires for indoor wiring such as electric lamps, electric heaters, etc. are installed in a way that they are drawn out from a certain point such as a ceiling, a wall, , Where the wires leading into the interior of the ceiling, walls and floors are transported through conduits made of a material such as PVC, which protects them and guides them until their withdrawal.
If the electric wire transferred through the conduit has excessive flexibility or stiffness, it may be difficult to transfer and it may be difficult to transfer due to friction with the inner wall of the conduit or with other wires drawn together. Particularly, when the electric wire is transported through the conduit in a curved region according to the structure of a building, a ceiling of a facility, a wall, a floor, and the like, further transportation may be difficult.
Therefore, the electric wire has flexibility and stiffness suitable for transportation, and minimizes the friction between the electric wire and the inner wall of the electric wire or other electric wire to be fed together, thereby improving the waterproofing property of the electric wire. The coefficient of friction must be sufficiently low. In addition, in order to improve the installation performance of the electric wire, there is a case where the surface of the electric wire is coated with lubricating oil or the like and the installation work is carried out. In this case, the insulating layer constituting the electric wire should have improved oil resistance against the lubricating oil and the like.
Heat-resistant PVC insulation wire which is conventionally used for indoor wiring and the like is a wire insulated with a PVC resin containing a heat-resistant plasticizer. The PVC resin is excellent in heat resistance, flame retardancy, chemical resistance, water resistance, On the other hand, it has a relatively low maximum allowable temperature of the wire, it is not only harmful to human body but also causes environmental problems such as generation of toxic gas during burning for disposal of electric wire, and thus it is regulating use thereof.
Non-halogen flame retardant polyolefin bridged insulated wires have been developed and used to replace heat resistant vinyl insulated wires having the above problems. The non-halogen flame retardant polyolefin bridged insulated electric wire is an electric wire insulated with a non-halogen insulating resin to which a flame retardant is added, and is environmentally friendly because it uses a non-halogen insulating resin.
However, since the non-halogen flame retardant polyolefin bridged insulated wire is higher in price than the conventional heat resistant vinyl insulated wire and the flame retardant added to ensure flame retardancy corresponding to the conventional PVC resin, the surface friction coefficient of the insulating layer increases, Is greatly reduced. Furthermore, a certain amount of CMB (color master batch) is added to the insulating layer for the purpose of identifying a specific color for identification with other adjacent wires. For this reason, by adding CMB, There is a problem of deterioration.
On the other hand, when the conventional insulating composition includes additives such as an antioxidant and a lubricant, white or gray powder containing the additive is dissolved and remains on the surface of the insulating layer during extrusion molding to form an insulating layer of the cable. resulting in poor appearance of the cable, deterioration of workability, and the like.
Therefore, it is environmentally friendly, has excellent flame retardancy and durability, and satisfies the characteristics such as heat resistance, water resistance, insulation, cold resistance and oil resistance at the same time. Further, after extrusion and crosslinking to form an insulating layer, white powder There is a serious demand for a wire for indoor wiring that can suppress the blooming phenomenon that is eluted.
An object of the present invention is to provide an environmentally friendly non-halogen flame retardant polyolefin insulated electric wire.
It is another object of the present invention to provide a halogen-free flame retardant polyolefin insulated electric wire excellent in flame retardancy and durability.
It is another object of the present invention to provide a halogen-free flame retardant polyolefin insulated electric wire which can simultaneously satisfy characteristics such as heat resistance, water resistance, insulation, cold resistance and oil resistance.
Further, it is an object of the present invention to provide a non-halogen flame retardant polyolefin crosslinked insulation cable capable of suppressing the blooming phenomenon of the insulating layer.
In order to solve the above problems,
Non-halogen flame retardant bridging insulating wire for indoor wiring, comprising: a conductor; And an insulating layer formed by crosslinking the conductor and an insulating composition comprising a halogen-free resin as a base resin, wherein the insulating composition includes an antioxidant and a flame retardant, and the antioxidant has a melting point of 90 ° C Halogen-free flame-retardant bridged insulated electric wire, wherein the insulation layer comprises an insulation inner layer and an insulation outer layer, and the insulation outer layer further comprises a pigment for color implementation and a further activator for improving the installation property.
Here, the content of the flame retardant is 100 to 180 parts by weight based on 100 parts by weight of the base resin.
Further, the present invention provides a non-halogen flame retardant bridging insulated electric wire characterized in that the thickness of the insulating outer layer is 50 to 500 탆.
The present invention also provides a halogen-free flame retardant crosslinked insulated electric wire, characterized in that the flame retardant includes magnesium hydroxide (Mg (OH) 2 ) or aluminum hydroxide (Al (OH) 3 ).
Further, the flame retardant is surface-treated with at least one surface modifier selected from the group consisting of vinyl silane, titanate-based coupling agent, stearic acid, oleic acid and aminopolysiloxane.
On the other hand, the non-halogen flame retardant crosslinked insulated electric wire is characterized in that the crosslinking is a number crossing.
The present invention also provides a halogen-free flame-retardant crosslinked insulated electric wire, characterized in that the base resin comprises a polyolefin-based resin and a polyolefin elastomer.
The present invention provides a halogen-free flame-retardant crosslinked insulated wire, wherein the polyolefin-based resin comprises low-density polyethylene (LDPE).
The present invention also provides a halogen-free flame-retardant crosslinked insulated wire characterized in that the content of the polyolefin-based resin is 25 to 70 parts by weight based on 100 parts by weight of the base resin.
On the other hand, the antioxidant provides a halogen-free flame-retardant crosslinked insulated electric wire, which comprises a phenol-based, amine-based, quinone-based antioxidant, or a combination thereof.
The non-halogen flame retardant crosslinked insulated wire according to claim 1, wherein the antioxidant is 0.05 to 5 parts by weight based on 100 parts by weight of the base resin.
The present invention also provides a halogen-free flame-retardant bridging insulating wire, wherein the insulating composition comprises at least one internal lubricant selected from the group consisting of paraffin wax and olefin wax.
Here, the content of the internal lubricant is 0.3 to 7 parts by weight based on 100 parts by weight of the base resin, and provides the halogen-free flame-retardant crosslinked insulated wire.
The external lubricant may include at least one external lubricant selected from the group consisting of a fatty acid series, a fatty acid salt, a fatty acid amide, a silicone lubricant and a special grade wax.
Also, the content of the external lubricant is 0.3 to 5 parts by weight based on 100 parts by weight of the base resin, and the non-halogen flame retardant crosslinked insulated wire is provided.
The insulating composition further comprises 0.5 to 5 parts by weight of a pigment based on 100 parts by weight of the base resin.
Further, the insulating composition comprises 0.5 to 5 parts by weight of a crosslinking agent based on 100 parts by weight of the base resin, and provides the halogen-free flame-retardant crosslinked insulated electric wire.
Here, the crosslinking agent may be an organic silane such as vinyltrimethoxysilane, vinyltriethoxysilane or vinyltrimethoxyethoxysilane; And dicumyl peroxide, benzoyl peroxide, lauryl peroxide, t-butyl cumyl peroxide, di (t-butylperoxyisopropyl) benzene, 2,5-dimethyl- ) Hexane or an organic peroxide-based cross-linking agent of di-t-butyl peroxide. The present invention also provides a halogen-free flame retardant crosslinked insulated electric wire.
In addition, the insulating composition may include metal carboxylates of dibutyltin dilaurate, tin octoate, tin acetate, lead naphthenate or zinc octoate; Organometallic compounds of titanium esters and chelates or tetrabutyl titanate; Organic bases of ethylamine, hexylamine or piperidine; Or at least one condensation catalyst selected from the group consisting of a mineral acid or an acid of a fatty acid.
And a total content of the inner lubricant and the outer lubricant is higher in the insulating outer layer than in the insulating inner layer.
On the other hand, as a non-halogen flame retardant crosslinked insulated electric wire for indoor wiring, a conductor; And an insulation layer surrounding the conductor and having a number of insulating compositions including a halogen-free resin as a base resin, the insulation composition further comprising an antioxidant, a flame retardant, a pigment, and an external lubricant, Wherein the antioxidant has a melting point of not higher than the crosslinking temperature of the insulating layer + 5 DEG C and the external lubricant and the pigment are contained in a region of 50 to 500 mu m in thickness from the surface of the insulating layer, (Mg (OH) 2 ) or aluminum hydroxide (Al (OH) 3 ) surface-treated with at least one surface modifying agent selected from the group consisting of a nitrate-based coupling agent, stearic acid, oleic acid and aminopolysiloxane, Is 100 to 180 parts by weight based on 100 parts by weight of the base resin.
Further, as a non-halogen flame retardant bridging insulated electric wire for indoor wiring, a conductor; And an insulating layer surrounding the conductor and formed by crosslinking an insulating composition comprising a halogen-free resin as a base resin, wherein the insulating composition further comprises an antioxidant, a flame retardant, a pigment, and an external lubricant, Wherein the antioxidant has a melting point of 90 占 폚 or less and the external lubricant and the pigment are contained in a region radially inwardly from the surface of the insulating layer in a range of 50 to 500 占 퐉.
Here, the flame retardant may be magnesium hydroxide (Mg (OH) 2 ) or aluminum hydroxide (Al (OH) 2 ) surface-treated with at least one surface modifier selected from the group consisting of vinylsilane, titanate-based coupling agent, stearic acid, oleic acid and aminopolysiloxane ) 3 ), and the content of the flame retardant is 100 to 180 parts by weight based on 100 parts by weight of the base resin.
Also, the antioxidant is a phenol-based, amine-based, quinone-based antioxidant, or a combination thereof, and is contained in an amount of 0.05 to 5 parts by weight based on 100 parts by weight of the base resin. Provides an insulated wire.
The external lubricant may include at least one selected from the group consisting of a fatty acid series, a fatty acid salt, a fatty acid amide, a silicone lubricant and a special grade wax. The content of the external lubricant may be 0.3 to 10 Halogen-free flame-retardant bridged insulated electric wire.
Further, the content of the pigment is 0.5 to 5 parts by weight based on 100 parts by weight of the base resin, and provides the halogen-free flame-retardant crosslinked insulated wire.
Also, the insulating composition may include at least one internal lubricant selected from the group consisting of paraffin wax and olefin ga wax, and the content of the internal lubricant is 0.3 to 7 parts by weight based on 100 parts by weight of the base resin. , Non-halogen flame-retardant bridged insulated wires.
The insulating composition includes 0.5 to 5 parts by weight of a crosslinking agent based on 100 parts by weight of the base resin, and the crosslinking agent is selected from the group consisting of vinyltrimethoxysilane, vinyltriethoxysilane or vinyltrimethoxyethoxysilane organosilane; And dicumyl peroxide, benzoyl peroxide, lauryl peroxide, t-butyl cumyl peroxide, di (t-butylperoxyisopropyl) benzene, 2,5-dimethyl- ) Hexane or an organic peroxide-based cross-linking agent of di-t-butyl peroxide. The present invention also provides a halogen-free flame retardant crosslinked insulated electric wire.
Further, the base resin may include a polyolefin resin and a polyolefin elastomer, the polyolefin resin may include low density polyethylene (LDPE), and the content of the polyolefin resin may be 25 to 70 parts by weight based on 100 parts by weight of the base resin. Based flame retardant insulated wire.
1 is a cross-sectional view schematically showing a cross-sectional structure of a non-halogen flame retardant polyolefin bridged insulated electric wire according to an embodiment of the present invention.
2 is a cross-sectional view schematically showing a cross-sectional structure of a non-halogen flame retardant polyolefin bridged insulated electric wire according to another embodiment of the present invention.
3 is a cross-sectional view schematically showing a cross-sectional structure of a non-halogen flame retardant polyolefin bridged insulated electric wire according to another embodiment of the present invention.
FIG. 4 is a schematic view of a virtual installation work environment for evaluating the non-halogen flame retardant polyolefin bridging insulation wire according to the present invention.
FIG. 5 is a schematic view showing a virtual installation work environment for measuring a static friction coefficient of a halogen-free flame-retardant polyolefin bridged insulated electric wire according to the present invention.
FIG. 6 is a schematic view of another hypothetical work environment for measuring the static friction coefficient and the coefficient of dynamic friction of the halogen-free flame-retardant polyolefin bridged insulated wire according to the present invention.
FIG. 7 is a schematic view showing a bundle of non-halogen flame retardant polyolefin bridged insulated electric wires according to the present invention and 100 bundles packaged therein.
Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings. However, the present invention is not limited to the embodiments described herein but may be embodied in other forms. Rather, the embodiments disclosed herein are provided so that this disclosure will be thorough and complete, and will fully convey the concept of the invention to those skilled in the art. Like reference numerals designate like elements throughout the specification.
1 is a cross-sectional view schematically showing a cross-sectional structure of a non-halogen flame retardant polyolefin bridged insulated electric wire according to an embodiment of the present invention. As shown in FIG. 1A, the non-halogen flame-retardant polyolefin bridged insulated wire according to the present invention may comprise a
The
The
The non-halogen flame retardant polyolefin bridged insulated electric wire according to the present invention is used when it is used for indoor wiring such as electric lamps, electric heating lamps, etc., And the electric wire drawn to the inside of the ceiling, the wall, and the floor is made of a material such as PVC, which protects the electric wire and guides the electric wire until the electric wire is pulled out. It is transported through a conduit.
If the flexibility of the wire to be conveyed through the conduit is excessively excessive or its stiffness is excessively large, it may be difficult to transfer the wire, and also by friction with the inner wall of the conduit or other wires Transport can be difficult. Particularly, when the electric wire is transported through the conduit in a curved region according to the structure of a building, a ceiling of a facility, a wall, a floor, and the like, further transportation may be difficult.
Therefore, when the halogen-free flame-retardant polyolefin bridged insulated wire according to the present invention is used for indoor wiring, it is required to balance the flexibility and stiffness accurately controlled in order to ensure excellent installation property, Based flame retardant polyolefin bridged insulated wire is determined by the elasticity of the non-halogen flame retardant polyolefin bridged insulated wire.
The elasticity of the non-halogen flame retardant polyolefin bridging insulating wire is determined by the modulus of elasticity of the
Therefore, in the halogen-based flame retardant polyolefin bridged insulated electric wire according to the present invention, when the halogen-free flame retardant polyolefin bridged insulated electric wire is used for indoor wiring, the modulus of elasticity of the
The insulating
Since the polymer resin is mostly an electrically insulating material, the electrically insulating polymer resin is not particularly limited if it satisfies the basic physical properties required for an insulating layer of a cable used for indoor wiring and the like. The electrically insulating polymer resin may be, for example, a polyolefin resin such as polyethylene, polypropylene and the like, preferably polyethylene.
The polyethylene may be an ultra low density polyethylene (ULDPE), a low density polyethylene (LDPE), a linear low density polyethylene (LLDPE), a medium density polyethylene (MDPE), a high density polyethylene (HDPE), or a combination thereof. And may be low-density polyethylene (LDPE) in terms of forming an insulating layer of the polyolefin bridged insulated electric wire. The polyethylene may be a homopolymer, a random or block copolymer of ethylene and an? -Olefin such as propylene, 1-butene, 1-pentene, 1-hexene or 1-octene, or a combination thereof.
Since the low density polyethylene (LDPE) has a lower crystallinity than other polyethylene, it has excellent loading properties for additives such as a flame retardant and is produced without using a catalyst unlike other polyethylene. It is even better.
The insulating composition may include a polyolefin elastomer (POE) such as propylene-ethylene rubber (EPR) and propylene-ethylene-diene rubber (EPDM), a styrene- Styrene-butadiene rubber (SBR) such as styrene-ethylene-ethylene-propylene-styrene copolymer and styrene-butylene-styrene copolymer, ethylene vinyl acetate (EVA) (about 15 to 40% by weight of vinyl acetate) As shown in FIG.
The polyolefin elastomer, styrene butadiene rubber (SBR), ethylene vinyl acetate (EVA) and the like (hereinafter referred to as " polyolefin elastomer ") has poor mechanical properties and low melting point as compared with the polyolefin, The degree of crystallinity is low, which improves loading properties for additives such as flame retardants. Thus, the polyolefin elastomer or the like can further improve the flexibility, bending property, impact resistance, cold resistance, etc. of the insulating
When the total heat absorbing amount required for melting the base resin is about 30 to < RTI ID = 80 J / g. Here, when the total endothermic amount required for melting the base resin is less than about 30 J / g, the heat resistance of the insulating composition may be poor, while about 80 J / g, the flexibility, elongation percentage, etc. of the insulating composition may be insufficient.
The blending ratio of the polyolefin resin and the polyolefin elastomer contained as the base resin of the insulating composition is not particularly limited and may be appropriately selected within a range satisfying physical properties such as the later-described insulation property of the insulating composition, , The content of the polyolefin resin may be 25 to 70 parts by weight based on 100 parts by weight of the base resin.
If the content of the polyolefin resin is less than 25 parts by weight, the mechanical properties and heat resistance of the insulating layer may be lowered. On the other hand, when the amount of the polyolefin resin is more than 70 parts by weight, the compatibility of the insulating composition and the flame retardant may be greatly reduced.
In the non-halogen-based flame-retardant polyolefin-crosslinked insulated wire according to the present invention, the insulation composition for forming the insulating
As the flame retardant, magnesium hydroxide (Mg (OH) 2 ) in the metal hydroxide flame retardant is superior in heat resistance to other metal hydroxide flame retardants, and suppresses the generation of bubbles even in heat generation due to high-speed extrusion of the insulating
In general, inorganic particles such as magnesium hydroxide as the flame retardant are hydrophilic with high surface energy, whereas base resins such as polyolefin have hydrophobic properties with low surface energy, so that the inorganic particles have poor dispersibility with respect to the base resin And the electrical characteristics may be adversely affected. Therefore, in order to solve such a problem, inorganic particles such as magnesium oxide can be surface-treated with vinylsilane, stearic acid, oleic acid, aminopolysiloxane, titanate-based coupling agent and the like, preferably surface-treated with vinylsilane .
When the inorganic particles are surface-treated with vinylsilane or the like, an alkoxy group such as vinylsilane is attached by chemical bonding or physical bonding to the surface of inorganic particles such as magnesium hydroxide by hydrolysis and condensation reaction, and the surface- The particles react with the base resin to ensure excellent dispersibility.
Particularly, the vinyl silane as the surface treatment agent for the inorganic particles is excellent in the effect of improving the dispersibility of the inorganic particles as compared with other surface treatment agents, and further, the number of the insulating compositions does not deteriorate the cross- , 30 in terms of realizing a stable insulation resistance. The advantages of vinylsilane as a surface treatment agent for the inorganic particles, in particular, the stable insulation resistance of the insulating
The content of the flame retardant may be a sufficient flame retardancy of the insulating composition, for example, a flame retardancy that satisfies the standard KS C 60332-1. For example, the content may be about 100 To 180 parts by weight. If the content of the flame retardant is less than about 100 parts by weight, the flame retardancy of the insulating composition may be insufficient, while if it exceeds about 180 parts by weight, the molding processability such as flexibility, elongation, .
On the other hand, when inorganic particles such as magnesium hydroxide and aluminum hydroxide are included in the insulating composition forming the insulating
In the non-halogen flame retardant polyolefin crosslinked insulated wire according to the present invention, the insulating composition forming the insulating
However, as the crosslinking method of the crosslinked polyolefin (XLPO), there is a problem that crosslinking is performed in a high-temperature and high-pressure steam tube of a crosslinking method, and thus additional facilities and cost are required. In the irradiation crosslinking method, There is a problem in that the water exchange method is preferable.
The cross-linking agent may be an organosilane such as vinyltrimethoxysilane, vinyltriethoxysilane, or vinyltrimethoxyethoxysilane, preferably having high reactivity, so that crosslinking efficiency Particularly preferred vinyltrimethoxysilane, or in the case of the chemical crosslinking method, dicumylperoxide, benzoylperoxide, laurylperoxide, t-butylcumylperoxide, di (t-butylperoxyisopropyl) Organic peroxide-based cross-linking agents such as dimethyl-2,5-di (t-butylperoxy) hexane and di-t-butyl peroxide, preferably dicumyl peroxide with low cost and excellent crosslinking efficiency.
In particular, when the crosslinking agent is an organosilane such as vinyltrimethoxysilane, the base resin grafts vinylsilane through reaction with the crosslinking agent and is exposed to moisture or moisture in the presence of a condensation catalyst, . Thus, the insulating composition may further comprise a suitable condensation catalyst for the number of the base resins.
The condensation catalyst may be selected from metal carboxylates such as dibutyltin dilaurate, tin octoate, tin acetate, lead naphthenate and zinc octoate, titanium esters and chelates, organometallic compounds such as tetrabutyl titanate, , Hexylamine, piperidine and the like, or acids such as mineral acids and fatty acids, and the content of the condensation catalyst may be 0.01 to 0.2 parts by weight based on 100 parts by weight of the base resin.
The content of the crosslinking agent may be selected so that the gel fraction of the insulating composition after crosslinking is 50 to 90%. When the gel fraction of the insulating composition after crosslinking is less than 50%, the heat resistance, hotset, etc. of the insulating composition may be insufficient due to insufficient degree of crosslinking, while when it exceeds 90%, the crosslinking degree is excessively excessive, Scorch due to premature crosslinking can occur. The content of the crosslinking agent may be, for example, 0.5 to 5 parts by weight based on 100 parts by weight of the base resin.
In the non-halogen flame-retardant polyolefin bridged insulated electric wire according to the present invention, the insulating composition for forming the insulating
The antioxidant functions to inhibit the oxidation of the polymer resin contained in the insulating composition and may be used as an antioxidant such as phenol, amine or quinone, preferably a phenol antioxidant or an amine-based antioxidant And may contain an inhibitor. Here, the phenolic antioxidant as the antioxidant is more effective in suppressing discoloration of the internal lubricant and the like in the insulating composition, and the amine antioxidant further improves the insulation resistance of the insulating layer formed by the insulating composition .
The solubility of the antioxidant may vary greatly depending on the temperature of the insulating composition. Specifically, the lower the temperature of the insulating composition, the lower the solubility of the antioxidant. The solubility of the antioxidant is significantly lowered at the time of crosslinking at a relatively lower temperature than the extrusion temperature of the insulating composition after the extrusion, and the antioxidant is eluted to the surface of the insulating
In addition, the blooming phenomenon is particularly problematic when the insulating composition includes an external lubricant to be described later, because in the process of moving the external activator to the surface of the insulating
On the other hand, the present inventors have found that when the melting point of the antioxidant is lower than the crosslinking temperature of the insulating layer + 5 ° C or lower, preferably lower than the crosslinking temperature, the blooming phenomenon on the surface of the insulating
For example, when the melting point of the antioxidant is 90 ° C or lower and the melting point of the antioxidant is less than the crosslinking temperature of the insulating layer + 5 ° C, 20, and 30), the phase of the antioxidant is changed from a solid phase to a liquid phase at the time of crosslinking after the extrusion of the insulating composition, .
Accordingly, in the non-halogen flame-retardant polyolefin bridged insulating cable according to the present invention, the insulating composition forming the insulating
The internal lubricant may include a paraffin wax or an olefin wax, or a fatty acid type, a fatty acid amide type, an ester type, a silicone type internal lubricant, etc. Preferably, the base lubricant is compatible with the olefinic resin An excellent paraffin wax or an olefin wax, and performs the function of improving the compatibility of the polymer resin contained in the insulating composition and other additives.
The content of the internal lubricant may be about 0.3 to 7 parts by weight based on 100 parts by weight of the base resin. When the content of the internal lubricant is less than about 0.3 part by weight, the compatibility of the polymer resin with other additives may be greatly lowered On the other hand, if it exceeds 7 parts by weight, the mechanical properties, heat resistance, etc. of the insulating layer formed by the insulating composition may be significantly lowered.
The moisture absorbent may be calcium oxide, calcium chloride, silica gel, activated alumina or the like, and absorbs moisture in the insulating composition to suppress the deterioration of physical properties due to bubbling during extrusion of the insulating composition. The amount of the moisture absorber may be about 0.1 to 3 parts by weight based on 100 parts by weight of the base resin. When the amount of the moisture absorber is less than 0.1 parts by weight, the effect of adding the moisture absorber may be insignificant. The electrical characteristics of the insulating composition may be deteriorated.
In the non-halogen flame retardant polyolefin bridged insulated electric wire according to the present invention, the insulating composition forming the insulating
1A, when the non-halogen flame retardant polyolefin bridging insulating wire according to the present invention includes only the insulating
1B, when the non-halogen flame-retardant polyolefin bridged insulated wire according to the present invention includes an insulating
The content of the external lubricant may be 0.3 to 10 parts by weight, preferably 1 to 5 parts by weight, based on 100 parts by weight of the base resin of the insulating
If the content of the external lubricant is less than 0.3 parts by weight, the surface friction coefficient of the insulating
An external lubricant which reduces the coefficient of friction of the insulating
Here, the vehicle may be defined to include all components except for the principal component in the master batch. For example, in an external lubricant master batch, the vehicle includes all resins except for external lubricants, and other additives, and in the pigment master batch, the vehicle may be defined to include all resins except pigments and other additives.
The external lubricant may include, for example, a fatty acid, a fatty acid salt, a fatty acid amide, a silicone lubricant, a special grade wax and the like having a polar group such as a hydroxyl group (-OH) and a carboxyl group (-COOH) In addition to the function of lowering the coefficient of surface friction of the insulating
The external lubricant may be added in the form of a master batch to the insulating
The content of the pigment may be 0.5 to 5 parts by weight, preferably 2 to 3 parts by weight based on 100 parts by weight of the base resin of the insulating
If the content of the pigment is less than 0.5 parts by weight, it may be difficult to realize a desired color of the insulating
The non-halogen flame-retardant polyolefin bridged insulated wire according to the present invention has an insulating
When the non-halogen flame-retardant polyolefin bridged insulated wire according to the present invention has a double structure of the insulating
In the present invention, when the thickness of the insulating layer (20) substantially including the external lubricant and the pigment or the thickness of the insulating outer layer (30) is less than about 50 탆, the insulating layer (20) In order to realize the color of the insulating layer, it is necessary to add an excessive amount of the pigment, and when the pigment is added in the form of a pigment master batch, the flame retardancy of the non-halogen flame retardant polyolefin bridged insulated electric wire may be deteriorated. On the other hand, when the thickness of the insulating
In the non-halogen flame-retardant polyolefin bridged insulated electric wire according to the present invention, the insulating composition for forming the insulating
2 is a cross-sectional view schematically showing a cross-sectional structure of a non-halogen flame retardant polyolefin bridged insulated electric wire according to another embodiment of the present invention. As shown in FIG. 2, the insulating
The number of the
3 is a cross-sectional view schematically showing a cross-sectional structure of a non-halogen flame retardant polyolefin bridged insulated electric wire according to another embodiment of the present invention. As shown in FIG. 3, the non-halogen flame retardant polyolefin bridged insulated wire according to the present invention may be formed by integrally extruding a plurality of, for example, two or three conductors simultaneously. In this case, when a plurality of electric wires are laid together, it is possible to solve the problem that the installation property is lowered due to the friction between adjacent electric wires, and also the insulating
Fig. 4 is a schematic view showing a virtual installation work environment for evaluating the non-halogen flame retardant polyolefin bridging insulation wire installation property.
As shown in FIG. 4, the virtual installation work environment has six bent portions bent at right angles and rounded at corners, and has a length of 1 m, a width of 9 m, and an inner diameter of 16 mm flame retardant polyolefin crosslinked insulated wire inserted into the PVC corrugated tube is pulled out together with a push-pull gauge at a 45 ° vertical upward direction from the one end of the PVC corrugated tube. , The tensile strength required for the non-halogen flame retardant polyolefin bridged insulated electric wire can be evaluated by measuring the tensile force required five times and calculating the average value thereof.
As a result of evaluating the non-halogen flame retardant polyolefin bridged insulated wire insulation under the hypothetical installation environment of several hundred times or more, the present inventors have confirmed that the above evaluation method most appropriately reflects the actual installation environment of the wire, The results of the evaluation of the durability of the concrete show very high reliability.
According to the method for evaluating the non-halogen flame retardant polyolefin bridging insulating wire (HFIX) under the virtual installation work environment as shown in Fig. 4, the installation property can be 1 to 11 kgf, and the above- Can be different. For example, with respect to three strands of a conductor having a conductor cross-sectional area of 1.5 mm < 2 >, the instability measured by the above evaluation method is 1 to 3 kgf, 2 to 6 kgf, and the two-wire strand having a conductor cross-sectional area of 4 mm < 2 > may have a settleability of 3 to 11 kgf as measured by the above evaluation method.
In this case, when the installation property according to the standard of the electric wire is below the reference value, the surface of the electric wire excessively slips more than necessary, and the packaging work for carrying the electric wire, that is, the electric wire bundle forming process is extremely difficult, It is impossible to form the wire with a height higher than a certain level, so that the efficiency of carrying the wire can be extremely reduced. On the other hand, when the installation property according to the standard of the wire exceeds the reference value, Can be inefficient.
FIG. 5 is a schematic view of a virtual installation work environment used in measurement of a static friction coefficient for evaluating the non-halogen flame retardant polyolefin bridged insulation wire for installation. Specifically, FIGS. 5A and 5B schematically show the virtual installation environment viewed from the side and the front, respectively.
As shown in Fig. 5, a hypothetical working environment was such that one strand of a conductor having a conductor cross-sectional area of 2.5 mm2 was placed in a semi-tubular structure having an inner diameter of 16 mm and made of steel, and then a load of 30 N It is possible to indirectly evaluate the installation property of the electric wire by measuring the static friction coefficient at the instant when the electric wire is pulled and moved in the direction of the structure.
As a result of measuring the coefficient of static friction of the non-halogen flame retardant polyolefin bridged insulated electric wire under a virtual installation environment of several hundred times or more, the present inventors found that the static friction coefficient of the electric wire measured by the above- , The static friction coefficient of the electric wire measured by the above evaluation method shows very high reliability.
The coefficient of static friction according to the method of evaluating the non-halogen flame retardant polyolefin bridged insulated wire under the virtual installation work environment as shown in Fig. 5 may be 1 or less, preferably 0.05 to 0.5.
If the static friction coefficient is less than 0.05, the surface of the electric wire excessively slips more than necessary, and it is extremely difficult to perform a packaging operation for carrying the electric wire, that is, to form a wire bundle. Particularly, The efficiency of transporting the electric wire can be extremely reduced. On the other hand, if the electric wire is more than 1, the electric wire can not be installed properly and the electric wire installation work may be inefficient.
6 is a schematic view showing another hypothetical installation work environment used for measuring static friction coefficient and dynamic friction coefficient for evaluating the non-halogen flame retardant polyolefin bridging insulating wire laying property.
As shown in FIG. 6, two strands of the non-halogen flame retardant polyolefin bridged insulated wire according to the present invention are placed on a wagon of an aluminum alloy (Al5051) at a predetermined interval, for example, 30 to 40 mm, And one end of each of the two specimens was fixed to a force measuring sensor while pulling the wagon at a speed of 1.0 mm / s to the opposite side of the position where the force measuring sensor was located, The static friction coefficient and the dynamic friction coefficient of the specimen with respect to the carton material are measured by measuring the force applied to the force measuring sensor by the friction between the two specimen pieces and the cart, .
The static friction coefficient and the dynamic friction coefficient are measured five times per second (5 times / s), and the highest friction coefficient is defined as a static friction coefficient after the wagon starts moving, and the static friction coefficient is measured And the average of the friction coefficient measured for 3 seconds after the point of time of 3 seconds was taken as the coefficient of dynamic friction.
The present inventors have measured the static friction coefficient and the dynamic coefficient of friction of the halogen-free flame-retardant polyolefin bridged insulated electric wire under virtual installation environments of several hundred times or more, and as a result, the static friction coefficient and the dynamic coefficient of friction of the electric wire measured by the above- , The static friction coefficient and the dynamic friction coefficient of the electric wire measured by the above evaluation method show very high reliability.
6, the static friction coefficient according to the method for evaluating the non-halogen flame retardant polyolefin bridged insulated electric wire with respect to the laying ability can be 0.40 or less, preferably 0.35 or less, and the coefficient of dynamic friction is 0.28 or less , Preferably 0.25 or less. Here, when the static friction coefficient is more than 0.40 or the dynamic coefficient of friction is more than 0.28, the installation of the electric wire is insufficient and the electric wire installation work may be inefficient.
The present invention relates to a bundle of the halogen-free flame retardant polyolefin bridged insulated electric wire, wherein Fig. 7a schematically shows one of the bundles of the electric wire, Fig. 7b shows the bundle of 100 electric wire bundles Which is a schematic view of packaging.
As shown in FIG. 7A, the
Meanwhile, the non-halogen flame retardant polyolefin bridged insulated electric wire can be packaged and transported by stacking the electric wire bundles 100 shown in FIG. 7A on the
The
When the surface of the insulating
Therefore, the present inventors have found that the standard of the electric wire bundle, that is, the height (h) and the outer diameter (D) of the electric wire bundle can be calculated according to the following Equations 1 and 2 according to the standard of the electric wire, By satisfying the condition, it is possible to facilitate the packaging process of the electric wire and improve the transportation efficiency, thereby completing the invention relating to the electric wire bundle.
[Equation 1]
h = name
In the above equation (1)
a is from 20 to 50;
&Quot; (2) "
D = bh + c
In Equation (2)
b is from 0.4 to 0.6, and c is from 250 to 300.
For example, for a bundle of wires having a cross-sectional area d of 1.5 mm2, the height h may be 60 to 70 mm and the outer diameter D may be 290 to 310 mm, and the cross- d) the bundle of wires having a diameter of 2.5 mm 2 may have a height h of 75 to 85 mm and an outer diameter D of 300 to 320 mm and the bundle of wires having a cross sectional area d of 4 mm 2 The height h may be 100 to 110 mm and the outer diameter D may be 310 to 330 mm. When the bundle of wires has the above-described standard, as shown in FIG. 7B, when 100 bundles are packed, It is possible to maintain a stable state such that the bundles do not spread or collapse with each other, so that the packaging process of the electric wire is easy and the transportation efficiency can be improved.
[Example]
1. Evaluation of blooming phenomenon
(Width: 100 mm, length: 100 mm, thickness: 1.5 mm) and a cable specimen (outer diameter: 3.5 mm, inner diameter: 1.7 mm) of each of the examples and comparative examples as shown in Table 1 below, . Specifically, an insulating composition was prepared using a twin screw extruder, and the insulating sheet and the insulating layer were extruded at a temperature of 180 to 230 캜 at a retention time of not more than 5 minutes in the extruder, and crosslinked in a water bath at 70 to 85 캜 for 6 hours Samples of the insulation specimens and 2.5SQ non-halogen flame retardant polyolefin bridged insulated wires according to the examples and comparative examples, respectively, were produced. The unit of the content shown in Table 1 below is parts by weight.
- Resin: Polyethylene
- Flame retardant: Magnesium hydroxide
- Antioxidant 1: Phenolic antioxidant (melting point: 110 to 125 ° C)
- Antioxidant 2: Phenolic antioxidant (melting point: 50 to 55 DEG C)
- internal lubricant 1: stearamide
- internal lubricant 2: polyethylene wax
- condensation catalyst: dibutyltin dilaurate master batch
The blooming phenomenon of the insulation specimens and the cable specimens according to each of the Examples and Comparative Examples prepared in the above Production Example was visually observed. When blooming phenomenon was observed, white powder components were analyzed by infrared analysis. The evaluation results are shown in Table 2 below.
(Strong, medium, none)
Stearamide
Stearamide
As shown in Table 2, in the case of Comparative Examples 1 and 2, the antioxidant having a melting point lower than the crosslinking temperature in the range of 70 占 폚 or 85 占 폚, which is relatively lower than the temperature during extrusion after extrusion of the insulating specimen and the cable insulating layer, It was confirmed that the blooming phenomenon that the resurfacer was eluted from the insulating specimen or the insulating layer was caused.
On the other hand, it was confirmed that Examples 1 and 2, in which the melting point of the antioxidant was controlled to be lower than the crosslinking temperature, suppressed the blooming phenomenon.
2. Estimation of settlement property and static friction coefficient
An insulating composition according to each of Examples and Comparative Examples was prepared at the components and mixing ratios shown in Table 3 below. Specifically, an insulating composition was prepared using a twin screw extruder, and the insulating inner layer and the insulating outer layer of the example and the insulating layer of the comparative example were respectively extruded at a temperature of 180 to 230 캜 within a retention time of 5 minutes or less in the extruder, To prepare insulating layer specimens and non-halogen flame retardant polyolefin crosslinked insulating wire specimens according to the examples and comparative examples, respectively. The unit of the content shown in Table 3 below is parts by weight.
Inner layer
Outer layer
Stranded wire: Stranded wire of 7 wire strands
Resin 1: Low density polyethylene
Resin 2: Polyolefin elastomer
Resin 3: High density polyethylene
Crosslinking agent: vinyltrimethoxysilane
Flame retardant: Magnesium hydroxide
Antioxidants: Phenolic antioxidants
Condensation catalyst: dibutyl tin dilaurate
Pigment: Pigment Masterbatch (CMB)
Lubricant: Silicone master batch (SMB)
1) Estimation of putting property
(4SQ) or three strands (1.5SQ or 2.5SQ) of the HFIX specimen of each of the embodiment and the comparative example inserted in the PVC corrugated pipe in the virtual installation work environment as shown in Fig. The pulling force of the wire was evaluated by repeatedly measuring the pulling force required for withdrawal by using a push-pull gauge at 45 ° vertically above the terminal and measuring the average value five times. The evaluation results are shown in Table 4 below.
2) Evaluation of static friction coefficient
The static friction coefficient at the moment when the electric wire is pulled in the direction of one side of the structure in a state where a load of 30 N is applied on the electric wire specimen of Example 5 disposed in the half tubular steel structure in the virtual installation work environment as shown in FIG. . The evaluation results are shown in Table 4 below.
3) Evaluation of static friction coefficient and dynamic friction coefficient
A Universal Testing Machine (manufactured by Withlab Co., Ltd., product name: WL2100) was applied to each of the wire specimens of Examples 3, 5 and 7 and the wire specimens of Comparative Examples 3, 5 and 7 in a virtual installation work environment as shown in Fig. Were used to evaluate the static friction coefficient and the dynamic friction coefficient. Specifically, two strands of wire specimens of Examples 3, 5, and 7 or Comparative Examples 3, 5, and 7 were placed on a wagon of an aluminum alloy (Al 5051) at a distance of 35 mm from each other. One end of each of the two specimens was fixed to a Universal Testing Machine (product name: WL2100, manufactured by Withlab Co., Ltd.), which is a force measuring device, and the other end of the two test pieces was driven by a driving motor The drive wheel is disposed so as to wind the thread fixed to the cart to pull the cart at a speed of 1.0 mm / s, and measure the force applied to the force measuring device by the friction between the test piece and the cart, And dynamic friction coefficient were measured.
(Fig. 5)
Static friction
6)
Dynamic friction
6)
As shown in Table 4, the electric wire specimen of the embodiment according to the present invention includes external lubricant in the insulated outer layer so that it can be installed at a level of 11 kgf or less for all the wire standards, 1 or less for a virtual installation environment shown in FIG. 5 The static friction coefficient and the static friction coefficient of 0.35 or less and the dynamic friction coefficient of 0.25 or less under another hypothetical installation environment shown in Fig. 6 are realized, It was confirmed that the electric wire specimens including the single-wire conductors of Examples 3, 5 and 7 significantly lowered the putting performance.
3. Other properties evaluation
The following properties of the insulation layer specimen and the wire specimen of Example 5 were evaluated. The evaluation results are shown in Table 5 below.
1) Hot / Set evaluation
According to standard KS C 60811-2-1, an insulating layer according to Example 5 was weighed in a weight of about 70 mm in an oven at a temperature of 200 ° C. After 15 minutes, the increase rate and weight were removed and left in the oven for 5 minutes And the hot / set heat resistance was evaluated by measuring the rate of increase in length from the initial value after shrinking sufficiently at room temperature.
2) Evaluation of tensile strength / elongation at room temperature and after heating
The tensile strength and elongation at room temperature of the insulating layer specimen according to Example 5 were measured in accordance with Specification KS C 60811-1-2, and the tensile strength and elongation after storage in an oven at 135 ° C for 136 hours were measured, / Stretched ratio.
3) Evaluation of flame retardancy
After placing the wire specimen of Example 5 vertically in a chamber according to standard KS C 60332-1 and applying a flame to the wire specimen for about 1 minute in the direction of about 45 from the bottom, The flame retardancy was evaluated by measuring the length of the unburned portion when the flame was turned off.
4) Evaluation of insulation
A wire specimen of Example 5 having a length of about 15 m according to Specification KS C 3341 was placed in a water bath at 90 DEG C for 1 hour and a DC voltage was applied between the conductor of the wire specimen and the insulating layer at 500 V for 1 minute, The short-term insulation resistance was evaluated.
Further, the electric wire specimen according to Example 5 was stored in a water bath at 50 DEG C for one week, and then a voltage of 1.6 kV was applied for 4 hours. After that, the electric wire specimen was stored for one week in a water bath at 50 DEG C, , The long-term insulation resistance was evaluated by measuring the resistance of the insulating layer after applying the DC voltage at 500 V for 1 minute.
5) Evaluation of heat distortion
The thermal deformation was evaluated by measuring the rate of change in thickness by applying a constant load to the insulating layer specimen according to Example 5 at 90 캜 for 4 hours in accordance with Specification KS C 3341.
6) Cold resistance evaluation
The cold resistance was evaluated by measuring whether the wire specimen according to Example 5 was rolled in the reference rod for 4 hours at -15 ° C according to the standard KS C 3341 and whether the wire specimen was cracked due to the bending of the wire specimen and the low temperature .
7)
The degree of smoke generation was evaluated by measuring the generation of smoke by the light transparency of the smoke generated after the flame was generated in the bundle of wire specimens of Example 5 according to Specification KS C 3341.
8) Evaluation of oil resistance
The oil resistance was evaluated by measuring the reduction ratio of the tensile strength / elongation after changing the initial tensile strength and elongation from the initial value after immersing the insulating layer specimen according to Example 5 in IRM 902 oil at 70 占 폚.
As shown in Table 5, it was confirmed that the non-halogen flame retardant polyolefin crosslinked insulated wire according to the present invention satisfies the target value by simultaneously improving heat resistance, mechanical properties, flame retardancy, insulation, cold resistance and oil resistance.
It will be apparent to those skilled in the art that various modifications and variations can be made in the present invention without departing from the spirit or scope of the invention as defined in the appended claims. You can do it. It is therefore to be understood that the modified embodiments are included in the technical scope of the present invention if they basically include elements of the claims of the present invention.
10: conductor 20: insulating layer
30: Insulation outer layer
Claims (29)
Conductor; And
And an insulation layer surrounding the conductor and formed by crosslinking of an insulating composition containing a non-halogen resin as a base resin,
Wherein the insulating composition comprises an antioxidant and a flame retardant,
The antioxidant has a melting point of 90 DEG C or lower,
Wherein the insulating layer comprises an insulating inner layer and an insulating outer layer,
A non-halogen flame retardant crosslinked insulated wire, wherein the insulating outer layer further comprises a pigment for color rendering and an external activator for enhancing the durability.
Wherein the content of the flame retardant is 100 to 180 parts by weight based on 100 parts by weight of the base resin.
Wherein the insulating outer layer has a thickness of 50 to 500 占 퐉.
Wherein the flame retardant is magnesium hydroxide (Mg (OH) 2 ) or aluminum hydroxide (Al (OH) 3 ).
Wherein the flame retardant is surface-treated with at least one surface modifier selected from the group consisting of vinyl silane, titanate-based coupling agent, stearic acid, oleic acid, and aminopolysiloxane.
Wherein the crosslinking is a number crossing.
Wherein the base resin comprises a polyolefin-based resin and a polyolefin elastomer.
Wherein the polyolefin-based resin comprises low-density polyethylene (LDPE).
Wherein the content of the polyolefin resin is 25 to 70 parts by weight based on 100 parts by weight of the base resin.
Wherein the antioxidant comprises a phenolic, amine, quinone antioxidant, or a combination thereof.
Wherein the content of the antioxidant is 0.05 to 5 parts by weight based on 100 parts by weight of the base resin.
Wherein said insulating composition comprises at least one internal lubricant selected from the group consisting of paraffin wax and olefin wax.
Wherein the content of the internal lubricant is 0.3 to 7 parts by weight based on 100 parts by weight of the base resin.
Wherein said external lubricant comprises at least one external lubricant selected from the group consisting of fatty acid series, fatty acid salts, fatty acid amides, silicone lubricants and special grade waxes.
Wherein the content of the external lubricant is 0.3 to 5 parts by weight based on 100 parts by weight of the base resin.
Wherein said insulating composition further comprises 0.5 to 5 parts by weight of pigment based on 100 parts by weight of said base resin.
Wherein said insulating composition comprises 0.5 to 5 parts by weight of a crosslinking agent based on 100 parts by weight of said base resin.
The cross-linking agent may be an organosilane such as vinyltrimethoxysilane, vinyltriethoxysilane or vinyltrimethoxyethoxysilane; And dicumyl peroxide, benzoyl peroxide, lauryl peroxide, t-butyl cumyl peroxide, di (t-butylperoxyisopropyl) benzene, 2,5-dimethyl- ) Hexane or an organic peroxide-based cross-linking agent of di-t-butyl peroxide.
Wherein the insulating composition is a metal carboxylate of dibutyltin dilaurate, tin octoate, tin acetate, lead naphthenate or zinc octoate; Organometallic compounds of titanium esters and chelates or tetrabutyl titanate; Organic bases of ethylamine, hexylamine or piperidine; Or at least one condensation catalyst selected from the group consisting of acids of inorganic or fatty acids.
Wherein the total content of the internal lubricant and the external lubricant is greater in the insulating outer layer than in the insulating inner layer.
Conductor; And
And an insulation layer surrounding the conductor and formed by bridging the number of the insulating composition including a halogen-free resin as a base resin,
Wherein the insulating composition further comprises an antioxidant, a flame retardant, a pigment, and an external lubricant,
Wherein the melting point of the antioxidant is not higher than the crosslinking temperature of the insulating layer + 5 DEG C,
Wherein the external lubricant and the pigment are included in a region having a thickness of 50 to 500 mu m from the surface of the insulating layer,
The flame retardant may be magnesium hydroxide (Mg (OH) 2 ) or aluminum hydroxide (Al (OH) 3 ) surface treated with at least one surface modifying agent selected from the group consisting of vinylsilane, titanate coupling agent, stearic acid, oleic acid and aminopolysiloxane ),
Wherein the content of the flame retardant is 100 to 180 parts by weight based on 100 parts by weight of the base resin.
Conductor; And
And an insulation layer surrounding the conductor and formed by crosslinking of an insulating composition containing a non-halogen resin as a base resin,
Wherein the insulating composition further comprises an antioxidant, a flame retardant, a pigment, and an external lubricant,
The antioxidant has a melting point of 90 DEG C or lower,
Wherein the external lubricant and the pigment are contained in a region radially inwardly from the surface of the insulating layer in a range of 50 to 500 占 퐉.
The flame retardant may be magnesium hydroxide (Mg (OH) 2 ) or aluminum hydroxide (Al (OH) 3 ) surface treated with at least one surface modifying agent selected from the group consisting of vinylsilane, titanate coupling agent, stearic acid, oleic acid and aminopolysiloxane ), And the content of the flame retardant is 100 to 180 parts by weight based on 100 parts by weight of the base resin.
Wherein the antioxidant is a phenol-based, amine-based, quinone-based antioxidant, or a combination thereof, and is contained in an amount of 0.05 to 5 parts by weight based on 100 parts by weight of the base resin. .
The external lubricant may include at least one selected from the group consisting of a fatty acid series, a fatty acid salt, a fatty acid amide, a silicone lubricant and a special grade wax, and the content of the external lubricant is 0.3 to 10 parts by weight based on 100 parts by weight of the base resin Wherein the halogen-free flame-retardant bridged insulated wire is characterized in that it is a halogen-free flame retardant insulated wire.
Wherein the content of the pigment is 0.5 to 5 parts by weight based on 100 parts by weight of the base resin.
Wherein the insulating composition comprises at least one internal lubricant selected from the group consisting of paraffin wax and olefin ga wax and the content of the internal lubricant is 0.3 to 7 parts by weight based on 100 parts by weight of the base resin. Halogen based flame retardant insulated wire.
Wherein the insulating composition comprises 0.5 to 5 parts by weight of a crosslinking agent based on 100 parts by weight of the base resin, wherein the crosslinking agent is selected from the group consisting of vinyltrimethoxysilane, vinyltriethoxysilane or vinyltrimethoxyethoxysilane organosilane; And dicumyl peroxide, benzoyl peroxide, lauryl peroxide, t-butyl cumyl peroxide, di (t-butylperoxyisopropyl) benzene, 2,5-dimethyl- ) Hexane or an organic peroxide-based cross-linking agent of di-t-butyl peroxide.
Wherein the base resin comprises a polyolefin resin and a polyolefin elastomer, the polyolefin resin includes low density polyethylene (LDPE), and the content of the polyolefin resin is 25 to 70 parts by weight based on 100 parts by weight of the base resin Non-halogen flame-retardant bridged insulated wire.
Priority Applications (5)
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KR1020160033874A KR20170011988A (en) | 2015-07-24 | 2016-03-22 | Halogen free flame-retardant crosslinked polyolefin insulation wire |
KR1020160039993A KR20170011995A (en) | 2015-07-24 | 2016-04-01 | Halogen free flame-retardant crosslinked polyolefin insulation wire |
KR1020160040044A KR101848991B1 (en) | 2015-07-24 | 2016-04-01 | Halogen free flame-retardant crosslinked polyolefin insulation wire |
KR1020160040046A KR101894135B1 (en) | 2015-07-24 | 2016-04-01 | Halogen free flame-retardant crosslinked polyolefin insulation wire |
KR1020160043411A KR102580923B1 (en) | 2015-07-24 | 2016-04-08 | Bundle of cable and method for packaging the same |
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KR1020150190947A KR20170012859A (en) | 2015-07-24 | 2015-12-31 | Halogen free flame-retardant crosslinked polyolefin insulation wire |
KR1020150190947 | 2015-12-31 | ||
KR1020160019662A KR20170012862A (en) | 2015-07-24 | 2016-02-19 | Halogen free flame-retardant crosslinked polyolefin insulation wire |
KR1020160019662 | 2016-02-19 |
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WO2018151420A1 (en) * | 2017-02-20 | 2018-08-23 | 엘에스전선 주식회사 | Insulation composition for high-voltage cable, and cable comprising insulation layer formed therefrom |
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---|---|---|---|---|
KR102604898B1 (en) * | 2018-11-15 | 2023-11-21 | 엘에스전선 주식회사 | High voltage DC power cable system |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009026666A (en) * | 2007-07-20 | 2009-02-05 | Furukawa Electric Co Ltd:The | Multilayer insulation electric wire |
JP2013045529A (en) * | 2011-08-22 | 2013-03-04 | Auto Network Gijutsu Kenkyusho:Kk | Wire and wire harness for automobile |
KR101314010B1 (en) * | 2013-07-25 | 2013-10-01 | 김웅 | Fire-retardant polyolefine composition |
-
2016
- 2016-03-18 KR KR1020160033023A patent/KR20170011987A/en unknown
- 2016-04-01 KR KR1020160040044A patent/KR101848991B1/en active IP Right Grant
- 2016-04-01 KR KR1020160039993A patent/KR20170011995A/en not_active Application Discontinuation
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2018151420A1 (en) * | 2017-02-20 | 2018-08-23 | 엘에스전선 주식회사 | Insulation composition for high-voltage cable, and cable comprising insulation layer formed therefrom |
Also Published As
Publication number | Publication date |
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KR101848991B1 (en) | 2018-04-16 |
KR20170011996A (en) | 2017-02-02 |
KR20170011995A (en) | 2017-02-02 |
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