KR20020033397A - How to mix resin for thermal transfer - Google Patents

How to mix resin for thermal transfer Download PDF

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Publication number
KR20020033397A
KR20020033397A KR1020000064465A KR20000064465A KR20020033397A KR 20020033397 A KR20020033397 A KR 20020033397A KR 1020000064465 A KR1020000064465 A KR 1020000064465A KR 20000064465 A KR20000064465 A KR 20000064465A KR 20020033397 A KR20020033397 A KR 20020033397A
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South Korea
Prior art keywords
percent
ink
resin
transfer
thermal transfer
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KR1020000064465A
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Korean (ko)
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이태화
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이태화
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Priority to KR1020000064465A priority Critical patent/KR20020033397A/en
Publication of KR20020033397A publication Critical patent/KR20020033397A/en

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M1/00Inking and printing with a printer's forme
    • B41M1/26Printing on other surfaces than ordinary paper
    • B41M1/38Printing on other surfaces than ordinary paper on wooden surfaces, leather, or linoleum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M3/00Printing processes to produce particular kinds of printed work, e.g. patterns
    • B41M3/12Transfer pictures or the like, e.g. decalcomanias

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Decoration By Transfer Pictures (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

PURPOSE: A method for mixing resin ink for thermal transfer is provided to improve the workability of the ink and to extend the region of use thereof, and to improve the quality of a printed product. CONSTITUTION: The method for mixing resin ink for thermal transfer comprises the steps of mixing ink with turpentine phenol resin 5 percent, acrylated chloroprene 25 percent, normal hexane 5 percent, cyclo hexane 10 percent, methyl ethyl ketone 5 percent, carbon black 5 percent, an adhesive, a thermosetting polyolefin wax 25 percent, rosin phenol synthetic resin 30 percent, polyolefin ethylene propylene base polymer 30 percent, styrene rubber 5 percent; and adding an antioxidant into the mixture, and heating and cooling them to form a transfer ink containing chips.

Description

열 전사용 수지 잉크 배합하는 방법{.}Method of compounding resin ink for thermal transfer {.}

본 발명은 피혁, 비닐 등 원단에 직접 인쇄하지 않고 전사지에 실크 스크린, 옵셋 인쇄 기법을 사용하여 전사지에 인쇄된 무늬나 색상을 피혁, 비닐 등에 열 로라 프레스로 전사가 가능하게 열 경화성 승화 전사 잉크로 인쇄하는 방법이며 이 기법의 종래에 기술은 원단에 직접 나염 착색하여 1도(색상)이상 인쇄 불가, 접착력(원단 위에 인쇄가 뜨있음)이 약하였으나 본 고안은 전사지에 인쇄 후 원단에 접착함으로 선명도(망점), 4도(원색 칼라) 완벽, 열 경화성 수지 사용으로 열 접착 접착력 아주 강함(원단에 침투), 이엉 퍼짐 없는 전사 잉크 배합 방법에 대한 발명이다.The present invention is a heat-curable sublimation transfer ink that can transfer a pattern or color printed on a transfer paper by using a heat roller press to a leather, vinyl, etc. without using a silk screen or offset printing technique. In the conventional technique of this technique, it is impossible to print more than 1 degree (color) by printing directly on the fabric, and the adhesive strength (the printing is on the fabric) is weak, but the present invention is printed on the transfer paper and then adhered to the fabric. (Dotted dot), 4 degree (primary color) perfect, heat-hardening adhesive is used, and it is invention of the transfer ink compounding method which is very strong (penetration into a fabric), and does not spread.

본 발명은 피혁 및 합성 피혁 제품의 다양한 색상과 무늬, 디자인이 칼라화가 되어 신발 , 가방 등의 피혁 제품이 해외 시장에서의 경쟁력 강화에 도움이 되며 자동화 옵셋 인쇄 공정 등의 기술을 개발하여 원색(사진)이 접착된 피혁, 합성 피혁등 원단을 생산할 수 있는 기술을 이루고 전사지를 사용 인쇄함으로 종이 인쇄처럼 옵셋 인쇄 기법으로 기계화 생산하여 원가를 절감 국내외 시장에서 경쟁력을높이고자 하는 발명이다.The present invention is a variety of colors, patterns, designs of leather and synthetic leather products are colorized to help leather products such as shoes, bags, etc. to strengthen the competitiveness in the overseas market, and to develop a technology such as automated offset printing process, such as primary colors (photo ) It is an invention that aims to increase the competitiveness in domestic and overseas markets by accomplishing the technology that can produce fabrics such as bonded leather, synthetic leather, and mechanized production using offset printing technique by printing transfer paper.

본 발명은 피혁, 합성 피혁(PU) 제품에는 인쇄용 잉크가 접착이 잘되지 않아 무늬나 다양한 색상을 착색하기가 어려우며 가죽의 뚜게로 인해 일반적인 착색에 어려움을 해결하고자 초종이 전사지에 수지 접착제를 잉크와 혼합하여 인쇄하여 열 로라를 통과하게 하여 열로 전사지에 접착되어 있는 열 경화성 수지를 녹여 원단에 접착시키는 인쇄 방법에 사용하는 전사 인쇄용 잉크에 대한 발명이며 상세히 설명하면 다음과 같다The present invention is difficult to color the pattern or various colors because the printing ink is not well adhered to the leather, synthetic leather (PU) products, and the resin adhesive on the paper transfer paper to solve the difficulty in general coloring due to the thickness of the leather The invention relates to a transfer printing ink used for a printing method in which a mixture is printed and passed through a thermal roller to melt a thermosetting resin adhered to a transfer paper with heat to bond to a fabric.

인쇄용 잉크 색상 안료와 유연성이 풍부하며 배합법에 따라 접착력, 점착 보지 시간, 내열성 등의 특성을 넓은 범위에서 조절이 가능한 CR 중합계 접착제 성분 테레빈 페놀 레진(TURPENTIN PHENOL RESIN) 5%, 카본 불랙 5% 클로로프렌(ACRYLATED, CHLOROPRENE) 25% 메틸, 에틸 케톤(METHYL, ETHYL KETONE) 5% 노말 헥산(NORMAL HEXANE) 45% 사이클로 헥산(CYCLO HEXANE) 10%의 용재로 접착용 잉크를 가교제(DESMOUR)를 5% 혼합하여 액체 상태로 만들어 전사 도포 즉시 냉각되어 접착이 이루어짐으로써 연속 작업이 가능하고 도포 두께를 고르게 조절하는 것이 용이한 열 경화성 폴리 올레핀계 왁스 25% 접착성 내한성, 내열성 향상을 위해 로진계의 점착 성분 페놀 합성 수지 30% 내열 , 내한성 증가용 폴리 올레핀계 에틸렌 프로필렌 공중합체 계열의 베이스 폴리머 30% 스티렌 계열의 공중합체 또는 블록 공중합체 고무 5%를 배합하여 100 ~ 250도 이하로 유지하며 산화 방지제를 투입 가열 용융 후 냉각하여 분쇄 350매쉬 칩(CHIP)으로 만들어 접착제와 인쇄 잉크를 인쇄 용도에 따라 칩10 ~ 15 : 접착제 10~15: 잉크와 혼합 실크 스크린, 옵셋으로 전사지에 인쇄하면 전사지에 도포된 중합계 접착제와 칩(CHIP)이 자연, 강제 건조 상태로 전사지에 피착되어 있다가 로라 프레스의 열에 의해 녹아 피혁과 같이 흡수성이 있는 피착체에 흡수 접착이 되어 피혁등 원단에 원하는 그림이나 색상 무늬를 종이처럼 인쇄 할 수 있는 승화 전사 잉크 배합에 대한 발명이다.5% TURPENTIN PHENOL RESIN CR Polymer Adhesive Ingredients 5% chloroprene (ACRYLATED, CHLOROPRENE) 25% Methyl, ETHYL KETONE 5% NORMAL HEXANE 45% CYCLO HEXANE 10% It is made into a liquid state, and it is cooled and transferred immediately after application of transfer. It is possible to perform continuous operation and easy to control the thickness of coating. 25% of heat curable polyolefin wax. Adhesive phenol of rosin-based adhesive for improving cold resistance and heat resistance. Polyolefin-based ethylene propylene copolymer-based base polymer 30% synthetic resin 30% styrene-based copolymer or block for increasing heat resistance and cold resistance Mixing 5% of copolymer rubber and keeping it at 100 ~ 250 degrees or less, adding antioxidant, heating, melting, and cooling to make a crushed 350 mesh chip (CHIP) to make adhesive and printing ink according to printing purpose. 15: When printing on transfer paper with ink and mixed silk screen and offset, polymer adhesive and chip (CHIP) applied on transfer paper are deposited on transfer paper in natural and forced dry state, and melted by heat of Laura press and absorbs like leather It is an invention for a sublimation transfer ink formulation that can be absorbed and adhered to the adherend with which a desired picture or color pattern can be printed on paper such as leather.

본 발명은 단색의 피혁이나 합성 피혁 비닐 원단 등에 칼라 무늬 등 다양한 디자인을 전사, 피혁 원단이 일반 천이나 종이처럼 다양한 무늬나 그림이 인쇄 나염되며 원단 상태가 아닌 일정한 형태로 형성된 제품에도 부분적인 도안이나 색상을 착색할 수 있는 잉크 혼합용으로 건조가 빠르고 접착력이 강하고 내열 내수성 우수하며 고형분이 높아 흡수성 소재에 1회 도포 사용함으로 작업 범위가 넓고 작업성이 좋으며 합성 소재에 접착력이 좋아 인쇄 적용 제품의 고급화와 디자인 우위로 국내 신발, 가방 산업의 수출 경쟁력을 신장할 수 있는 열 전사용 잉크의 발명이다.The present invention is transferred to a variety of designs, such as color patterns, such as monochromatic leather or synthetic leather vinyl fabric, leather fabric is printed or printed in a variety of patterns or pictures, such as general cloth or paper, and partially formed even in the product formed in a certain form, not the state of the fabric It is used for mixing ink which can color color, and it has fast drying, strong adhesiveness, excellent heat resistance and high solid content, so that it can be applied to absorbent materials once. It has a wide working range, good workability and good adhesion to synthetic materials. It is the invention of heat transfer ink that can enhance the export competitiveness of domestic shoe and bag industry with its design advantage.

Claims (1)

인쇄용 잉크에 TURPENTIN PHENOL RESIN 5%, ACRYLATED CHLOROPRENE 25% NORMAL HEXANE 50% CYCLO HEXANE 10% METHYL ETHYL KETONE 5% 카본 불랙 5%의 접착제와 열 경화성 폴리올레핀계 왁스 25% 로진 페놀 합성 수지 30% 폴리올레핀계 에틸렌 프로필렌 베이스 폴리머 30% 스티렌 계열의 고무 5%를 배합 산화 방지제를 투입 가열 용융후 냉각하여 만든 칩(CHIP)을 혼합한 전사 잉크로 전사지에 인쇄한 후 피혁이나 합성 피혁, 비닐 원단 에 열 로라 프레스를 사용 전사지에 인쇄된 잉크에 첨가된 수지 칩을 열로 녹여 원단 등에 무늬, 색상을 접착시켜는 열 전사용 수지 잉크 배합하는 방법TURPENTIN PHENOL RESIN 5%, ACRYLATED CHLOROPRENE 25% NORMAL HEXANE 50% CYCLO HEXANE 10% METHYL ETHYL KETONE 5% Carbon Black Adhesive 5% Base polymer 30% Styrene-based rubber 5% mixed with antioxidant Addition of heat-melted and cooled chips (CHIP) Transfer ink is printed on transfer paper and heat roller press is used on leather, synthetic leather and vinyl fabric. A method of blending resin ink for thermal transfer which melts the resin chips added to the ink printed on the transfer paper with heat to bond patterns and colors to fabrics and the like.
KR1020000064465A 2000-10-31 2000-10-31 How to mix resin for thermal transfer KR20020033397A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100478954B1 (en) * 2002-09-17 2005-03-28 주식회사 에이팩드롬 Method for transfering various color images on a surface of leather and the leather prepared by the same

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63239087A (en) * 1987-03-27 1988-10-05 Toyo Ink Mfg Co Ltd Thermal transfer material
JPH10138643A (en) * 1996-11-06 1998-05-26 Sony Chem Corp Heat transfer ink ribbon
JPH10329431A (en) * 1997-06-03 1998-12-15 Hokuetsu Paper Mills Ltd High gloss type hot-melt thermal transfer recording sheet
KR19990033135A (en) * 1997-10-23 1999-05-15 장용균 Thermal transfer recording media
KR20000058683A (en) * 2000-06-24 2000-10-05 정하승 Polyolefin-based hot melt adhesive for deflection yoke

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63239087A (en) * 1987-03-27 1988-10-05 Toyo Ink Mfg Co Ltd Thermal transfer material
JPH10138643A (en) * 1996-11-06 1998-05-26 Sony Chem Corp Heat transfer ink ribbon
JPH10329431A (en) * 1997-06-03 1998-12-15 Hokuetsu Paper Mills Ltd High gloss type hot-melt thermal transfer recording sheet
KR19990033135A (en) * 1997-10-23 1999-05-15 장용균 Thermal transfer recording media
KR20000058683A (en) * 2000-06-24 2000-10-05 정하승 Polyolefin-based hot melt adhesive for deflection yoke

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100478954B1 (en) * 2002-09-17 2005-03-28 주식회사 에이팩드롬 Method for transfering various color images on a surface of leather and the leather prepared by the same

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