JPS6426672A - Ultraviolet-curing type resin composition - Google Patents
Ultraviolet-curing type resin compositionInfo
- Publication number
- JPS6426672A JPS6426672A JP62296051A JP29605187A JPS6426672A JP S6426672 A JPS6426672 A JP S6426672A JP 62296051 A JP62296051 A JP 62296051A JP 29605187 A JP29605187 A JP 29605187A JP S6426672 A JPS6426672 A JP S6426672A
- Authority
- JP
- Japan
- Prior art keywords
- formula
- ultraviolet
- resin composition
- alkyl
- type resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011342 resin composition Substances 0.000 title abstract 3
- 125000000217 alkyl group Chemical group 0.000 abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 2
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 239000011347 resin Substances 0.000 abstract 2
- 229920005989 resin Polymers 0.000 abstract 2
- 150000003557 thiazoles Chemical class 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 239000012990 dithiocarbamate Substances 0.000 abstract 1
- 150000004659 dithiocarbamates Chemical class 0.000 abstract 1
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 239000013307 optical fiber Substances 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
- 150000003585 thioureas Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/44—Mechanical structures for providing tensile strength and external protection for fibres, e.g. optical transmission cables
- G02B6/4401—Optical cables
- G02B6/4429—Means specially adapted for strengthening or protecting the cables
- G02B6/44384—Means specially adapted for strengthening or protecting the cables the means comprising water blocking or hydrophobic materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
- C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
- C08F2/50—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
Landscapes
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Optical Fibers, Optical Fiber Cores, And Optical Fiber Bundles (AREA)
Abstract
PURPOSE:To obtain a ultraviolet-curable resin composition with hydrogen gas generation suppressed, suitable for coating material an optical fiber, filler, etc., by incorporating a resin blend with specific sulfur-contg. compound(s). CONSTITUTION:The objective ultraviolet-curable resin composition can be obtained by incorporating (A) 100pts.wt. of a resin blend (e.g. of urethane acrylate base, acrylic base) with (B) 0.01-3pts.wt. of at least one kind of sulfur- contg. compound selected from B1: thiazoles of formula I (X is H, alkyl, cyclohexylamine, etc.), B2: thiazoles carrying substituent on the benzene ring, of formula II (X' is halogen, etc.), B3: thiurams of formula III (R1-R4 are each 1-8C alkyl; X is 1-6), B4: thioureas of formula IV (R5 and R6 are each H, etc.) and B5: dithiocarbamates of formula IV (R7 and R8 are each alkyl, etc.; R9 is the same as R7 or R8 or amino, etc.).
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62296051A JPS6426672A (en) | 1987-04-01 | 1987-11-26 | Ultraviolet-curing type resin composition |
| GB8807184A GB2204050B (en) | 1987-04-01 | 1988-03-25 | Optical fibre coated with an ultraviolet-ray curable resin composition |
| KR1019880003485A KR960007612B1 (en) | 1987-04-01 | 1988-03-30 | Optical fiber coated with an ultraviolet-ray curable resin composition |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7750287 | 1987-04-01 | ||
| JP62296051A JPS6426672A (en) | 1987-04-01 | 1987-11-26 | Ultraviolet-curing type resin composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS6426672A true JPS6426672A (en) | 1989-01-27 |
Family
ID=26418577
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62296051A Pending JPS6426672A (en) | 1987-04-01 | 1987-11-26 | Ultraviolet-curing type resin composition |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JPS6426672A (en) |
| KR (1) | KR960007612B1 (en) |
| GB (1) | GB2204050B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6395393B1 (en) * | 1997-02-28 | 2002-05-28 | The Furukawa Electric Co., Ltd. | Optical fiber core wire binder and optical fiber unit |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0560953A (en) * | 1991-09-03 | 1993-03-12 | Sumitomo Electric Ind Ltd | Glass fiber for optical transmission |
| CA2207226C (en) * | 1996-06-10 | 2005-06-21 | Sumitomo Electric Industries, Ltd. | Optical fiber grating and method of manufacturing the same |
| FR2814168B1 (en) * | 2000-09-18 | 2006-11-17 | Rhodia Chimie Sa | PROCESS FOR THE SYNTHESIS OF BLOCK POLYMERS BY CONTROLLED RADICAL POLYMERIZATION IN THE PRESENCE OF A DISULFIDE COMPOUND |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2460105A (en) * | 1943-08-21 | 1949-01-25 | Du Pont | Photopolymerization of vinylidene compounds with organic disulfides |
| US2423520A (en) * | 1943-10-06 | 1947-07-08 | Du Pont | Photopolymerization of vinylidene compounds in the presence of n-disubstituted dithiocarbamic esters |
| GB771148A (en) * | 1954-07-22 | 1957-03-27 | Du Pont | Photopolymerizable compositions and the polymerization thereof |
| GB1116033A (en) * | 1966-05-23 | 1968-06-06 | Agfa Gevaert Nv | Photopolymerisation of ethylenically unsaturated organic compounds |
| US3860429A (en) * | 1973-03-16 | 1975-01-14 | Ici America Inc | Photopolymerization of ethylenically unsaturated organic compounds |
| US3982942A (en) * | 1973-03-16 | 1976-09-28 | Ici United States Inc. | Photopolymerization of ethylenically-unsaturated organic compounds |
| CA1221795A (en) * | 1982-02-24 | 1987-05-12 | Bolesh J. Skutnik | Optical fiber cladding |
| US4472021A (en) * | 1982-12-10 | 1984-09-18 | Desoto, Inc. | Strippable radiation-cured coatings for optical fiber and method |
| US4472019A (en) * | 1982-12-28 | 1984-09-18 | Desoto, Inc. | Topcoats for buffer-coated optical fiber using urethane acrylate and epoxy acrylate and vinyl monomer |
| JPS59226002A (en) * | 1983-06-06 | 1984-12-19 | Fuji Photo Film Co Ltd | Photo-polymerizable composition |
| AU594336B2 (en) * | 1985-05-13 | 1990-03-08 | Mitsubishi Rayon Company Limited | Photopolymerisable composition |
| DE3786192T2 (en) * | 1986-02-27 | 1993-12-09 | Dainippon Ink & Chemicals | Fluorine-containing resin composition with a low refractive index. |
-
1987
- 1987-11-26 JP JP62296051A patent/JPS6426672A/en active Pending
-
1988
- 1988-03-25 GB GB8807184A patent/GB2204050B/en not_active Expired - Lifetime
- 1988-03-30 KR KR1019880003485A patent/KR960007612B1/en active IP Right Grant
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6395393B1 (en) * | 1997-02-28 | 2002-05-28 | The Furukawa Electric Co., Ltd. | Optical fiber core wire binder and optical fiber unit |
Also Published As
| Publication number | Publication date |
|---|---|
| KR880012688A (en) | 1988-11-28 |
| GB8807184D0 (en) | 1988-04-27 |
| GB2204050B (en) | 1991-04-24 |
| GB2204050A (en) | 1988-11-02 |
| KR960007612B1 (en) | 1996-06-07 |
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