JPS636098A - Detergent composition - Google Patents
Detergent compositionInfo
- Publication number
- JPS636098A JPS636098A JP15053686A JP15053686A JPS636098A JP S636098 A JPS636098 A JP S636098A JP 15053686 A JP15053686 A JP 15053686A JP 15053686 A JP15053686 A JP 15053686A JP S636098 A JPS636098 A JP S636098A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- detergent
- group
- cationic surfactant
- humicola
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims description 17
- 239000003599 detergent Substances 0.000 title description 25
- 239000003093 cationic surfactant Substances 0.000 claims description 13
- 108010059892 Cellulase Proteins 0.000 claims description 10
- 229940106157 cellulase Drugs 0.000 claims description 10
- 238000004140 cleaning Methods 0.000 claims description 8
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 230000002538 fungal effect Effects 0.000 claims description 3
- 241000223199 Humicola grisea Species 0.000 claims description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 2
- 229910052736 halogen Inorganic materials 0.000 claims description 2
- 150000002367 halogens Chemical class 0.000 claims description 2
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims 2
- 241000223198 Humicola Species 0.000 claims 1
- 241001480714 Humicola insolens Species 0.000 claims 1
- 238000005406 washing Methods 0.000 description 13
- 239000012459 cleaning agent Substances 0.000 description 10
- 239000003205 fragrance Substances 0.000 description 9
- -1 dihydromircenol Chemical compound 0.000 description 6
- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- QMVPMAAFGQKVCJ-UHFFFAOYSA-N citronellol Chemical compound OCCC(C)CCC=C(C)C QMVPMAAFGQKVCJ-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 206010000496 acne Diseases 0.000 description 3
- 230000006866 deterioration Effects 0.000 description 3
- 239000000428 dust Substances 0.000 description 3
- 229940088598 enzyme Drugs 0.000 description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- OOCCDEMITAIZTP-QPJJXVBHSA-N (E)-cinnamyl alcohol Chemical compound OC\C=C\C1=CC=CC=C1 OOCCDEMITAIZTP-QPJJXVBHSA-N 0.000 description 2
- QMVPMAAFGQKVCJ-SNVBAGLBSA-N (R)-(+)-citronellol Natural products OCC[C@H](C)CCC=C(C)C QMVPMAAFGQKVCJ-SNVBAGLBSA-N 0.000 description 2
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 description 2
- DLHQZZUEERVIGQ-UHFFFAOYSA-N 3,7-dimethyl-3-octanol Chemical compound CCC(C)(O)CCCC(C)C DLHQZZUEERVIGQ-UHFFFAOYSA-N 0.000 description 2
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 2
- 108010084185 Cellulases Proteins 0.000 description 2
- 102000005575 Cellulases Human genes 0.000 description 2
- DZNVIZQPWLDQHI-UHFFFAOYSA-N Citronellyl formate Chemical compound O=COCCC(C)CCC=C(C)C DZNVIZQPWLDQHI-UHFFFAOYSA-N 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 description 2
- HIGQPQRQIQDZMP-DHZHZOJOSA-N Neryl acetate Natural products CC(C)=CCC\C(C)=C\COC(C)=O HIGQPQRQIQDZMP-DHZHZOJOSA-N 0.000 description 2
- KGEKLUUHTZCSIP-HOSYDEDBSA-N [(1s,4s,6r)-1,7,7-trimethyl-6-bicyclo[2.2.1]heptanyl] acetate Chemical compound C1C[C@]2(C)[C@H](OC(=O)C)C[C@H]1C2(C)C KGEKLUUHTZCSIP-HOSYDEDBSA-N 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- QUKGYYKBILRGFE-UHFFFAOYSA-N benzyl acetate Chemical compound CC(=O)OCC1=CC=CC=C1 QUKGYYKBILRGFE-UHFFFAOYSA-N 0.000 description 2
- SESFRYSPDFLNCH-UHFFFAOYSA-N benzyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OCC1=CC=CC=C1 SESFRYSPDFLNCH-UHFFFAOYSA-N 0.000 description 2
- JGQFVRIQXUFPAH-UHFFFAOYSA-N beta-citronellol Natural products OCCC(C)CCCC(C)=C JGQFVRIQXUFPAH-UHFFFAOYSA-N 0.000 description 2
- 235000000484 citronellol Nutrition 0.000 description 2
- JOZKFWLRHCDGJA-UHFFFAOYSA-N citronellol acetate Chemical compound CC(=O)OCCC(C)CCC=C(C)C JOZKFWLRHCDGJA-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- ZYGHJZDHTFUPRJ-UHFFFAOYSA-N coumarin Chemical compound C1=CC=C2OC(=O)C=CC2=C1 ZYGHJZDHTFUPRJ-UHFFFAOYSA-N 0.000 description 2
- 229940019836 cyclamen aldehyde Drugs 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- HIGQPQRQIQDZMP-UHFFFAOYSA-N geranil acetate Natural products CC(C)=CCCC(C)=CCOC(C)=O HIGQPQRQIQDZMP-UHFFFAOYSA-N 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 description 2
- UWKAYLJWKGQEPM-LBPRGKRZSA-N linalyl acetate Chemical compound CC(C)=CCC[C@](C)(C=C)OC(C)=O UWKAYLJWKGQEPM-LBPRGKRZSA-N 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- MDHYEMXUFSJLGV-UHFFFAOYSA-N phenethyl acetate Chemical compound CC(=O)OCCC1=CC=CC=C1 MDHYEMXUFSJLGV-UHFFFAOYSA-N 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- KRIOVPPHQSLHCZ-UHFFFAOYSA-N propiophenone Chemical compound CCC(=O)C1=CC=CC=C1 KRIOVPPHQSLHCZ-UHFFFAOYSA-N 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- 229920003169 water-soluble polymer Polymers 0.000 description 2
- ZFNVDHOSLNRHNN-UHFFFAOYSA-N xi-3-(4-Isopropylphenyl)-2-methylpropanal Chemical compound O=CC(C)CC1=CC=C(C(C)C)C=C1 ZFNVDHOSLNRHNN-UHFFFAOYSA-N 0.000 description 2
- DTGKSKDOIYIVQL-WEDXCCLWSA-N (+)-borneol Chemical compound C1C[C@@]2(C)[C@@H](O)C[C@@H]1C2(C)C DTGKSKDOIYIVQL-WEDXCCLWSA-N 0.000 description 1
- REPVLJRCJUVQFA-UHFFFAOYSA-N (-)-isopinocampheol Natural products C1C(O)C(C)C2C(C)(C)C1C2 REPVLJRCJUVQFA-UHFFFAOYSA-N 0.000 description 1
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 description 1
- BCOXBEHFBZOJJZ-ARJAWSKDSA-N (3Z)-hex-3-en-1-yl benzoate Chemical compound CC\C=C/CCOC(=O)C1=CC=CC=C1 BCOXBEHFBZOJJZ-ARJAWSKDSA-N 0.000 description 1
- 229940098795 (3z)- 3-hexenyl acetate Drugs 0.000 description 1
- KRLBLPBPZSSIGH-CSKARUKUSA-N (6e)-3,7-dimethylnona-1,6-dien-3-ol Chemical compound CC\C(C)=C\CCC(C)(O)C=C KRLBLPBPZSSIGH-CSKARUKUSA-N 0.000 description 1
- CDOSHBSSFJOMGT-JTQLQIEISA-N (R)-linalool Natural products CC(C)=CCC[C@@](C)(O)C=C CDOSHBSSFJOMGT-JTQLQIEISA-N 0.000 description 1
- JRJBVWJSTHECJK-LUAWRHEFSA-N (z)-3-methyl-4-(2,6,6-trimethylcyclohex-2-en-1-yl)but-3-en-2-one Chemical compound CC(=O)C(\C)=C/C1C(C)=CCCC1(C)C JRJBVWJSTHECJK-LUAWRHEFSA-N 0.000 description 1
- WAPNOHKVXSQRPX-UHFFFAOYSA-N 1-phenylethanol Chemical compound CC(O)C1=CC=CC=C1 WAPNOHKVXSQRPX-UHFFFAOYSA-N 0.000 description 1
- HGDVHRITTGWMJK-UHFFFAOYSA-N 2,6-dimethylheptan-2-ol Chemical compound CC(C)CCCC(C)(C)O HGDVHRITTGWMJK-UHFFFAOYSA-N 0.000 description 1
- FACFHHMQICTXFZ-UHFFFAOYSA-N 2-(2-phenylimidazo[1,2-a]pyridin-3-yl)ethanamine Chemical compound N1=C2C=CC=CN2C(CCN)=C1C1=CC=CC=C1 FACFHHMQICTXFZ-UHFFFAOYSA-N 0.000 description 1
- VVUMWAHNKOLVSN-UHFFFAOYSA-N 2-(4-ethoxyanilino)-n-propylpropanamide Chemical compound CCCNC(=O)C(C)NC1=CC=C(OCC)C=C1 VVUMWAHNKOLVSN-UHFFFAOYSA-N 0.000 description 1
- DDOYRSPMBLFJTR-UHFFFAOYSA-N 2-(dioctadecylamino)ethane-1,1-diol Chemical class CCCCCCCCCCCCCCCCCCN(CC(O)O)CCCCCCCCCCCCCCCCCC DDOYRSPMBLFJTR-UHFFFAOYSA-N 0.000 description 1
- DNRJTBAOUJJKDY-UHFFFAOYSA-N 2-Acetyl-3,5,5,6,8,8-hexamethyl-5,6,7,8- tetrahydronaphthalene Chemical compound CC(=O)C1=C(C)C=C2C(C)(C)C(C)CC(C)(C)C2=C1 DNRJTBAOUJJKDY-UHFFFAOYSA-N 0.000 description 1
- GUMOJENFFHZAFP-UHFFFAOYSA-N 2-Ethoxynaphthalene Chemical compound C1=CC=CC2=CC(OCC)=CC=C21 GUMOJENFFHZAFP-UHFFFAOYSA-N 0.000 description 1
- LUZDYPLAQQGJEA-UHFFFAOYSA-N 2-Methoxynaphthalene Chemical compound C1=CC=CC2=CC(OC)=CC=C21 LUZDYPLAQQGJEA-UHFFFAOYSA-N 0.000 description 1
- FLUWAIIVLCVEKF-UHFFFAOYSA-N 2-Methyl-1-phenyl-2-propanyl acetate Chemical compound CC(=O)OC(C)(C)CC1=CC=CC=C1 FLUWAIIVLCVEKF-UHFFFAOYSA-N 0.000 description 1
- XSAYZAUNJMRRIR-UHFFFAOYSA-N 2-acetylnaphthalene Chemical compound C1=CC=CC2=CC(C(=O)C)=CC=C21 XSAYZAUNJMRRIR-UHFFFAOYSA-N 0.000 description 1
- GOLORTLGFDVFDW-UHFFFAOYSA-N 3-(1h-benzimidazol-2-yl)-7-(diethylamino)chromen-2-one Chemical compound C1=CC=C2NC(C3=CC4=CC=C(C=C4OC3=O)N(CC)CC)=NC2=C1 GOLORTLGFDVFDW-UHFFFAOYSA-N 0.000 description 1
- VAJVDSVGBWFCLW-UHFFFAOYSA-N 3-Phenyl-1-propanol Chemical compound OCCCC1=CC=CC=C1 VAJVDSVGBWFCLW-UHFFFAOYSA-N 0.000 description 1
- GTNCESCYZPMXCJ-UHFFFAOYSA-N 3-Phenylpropyl propanoate Chemical compound CCC(=O)OCCCC1=CC=CC=C1 GTNCESCYZPMXCJ-UHFFFAOYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 241000282994 Cervidae Species 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- WTEVQBCEXWBHNA-UHFFFAOYSA-N Citral Natural products CC(C)=CCCC(C)=CC=O WTEVQBCEXWBHNA-UHFFFAOYSA-N 0.000 description 1
- JOZKFWLRHCDGJA-LLVKDONJSA-N Citronellyl acetate Natural products CC(=O)OCC[C@H](C)CCC=C(C)C JOZKFWLRHCDGJA-LLVKDONJSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000402754 Erythranthe moschata Species 0.000 description 1
- KBEBGUQPQBELIU-CMDGGOBGSA-N Ethyl cinnamate Chemical compound CCOC(=O)\C=C\C1=CC=CC=C1 KBEBGUQPQBELIU-CMDGGOBGSA-N 0.000 description 1
- GLZPCOQZEFWAFX-YFHOEESVSA-N Geraniol Natural products CC(C)=CCC\C(C)=C/CO GLZPCOQZEFWAFX-YFHOEESVSA-N 0.000 description 1
- 239000005792 Geraniol Substances 0.000 description 1
- 239000006001 Methyl nonyl ketone Substances 0.000 description 1
- 235000007265 Myrrhis odorata Nutrition 0.000 description 1
- 240000009023 Myrrhis odorata Species 0.000 description 1
- GLZPCOQZEFWAFX-JXMROGBWSA-N Nerol Natural products CC(C)=CCC\C(C)=C\CO GLZPCOQZEFWAFX-JXMROGBWSA-N 0.000 description 1
- 241000286209 Phasianidae Species 0.000 description 1
- DYUQAZSOFZSPHD-UHFFFAOYSA-N Phenylpropyl alcohol Natural products CCC(O)C1=CC=CC=C1 DYUQAZSOFZSPHD-UHFFFAOYSA-N 0.000 description 1
- 235000012550 Pimpinella anisum Nutrition 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- KMPQYAYAQWNLME-UHFFFAOYSA-N Undecanal Natural products CCCCCCCCCCC=O KMPQYAYAQWNLME-UHFFFAOYSA-N 0.000 description 1
- 235000010724 Wisteria floribunda Nutrition 0.000 description 1
- BCOXBEHFBZOJJZ-UHFFFAOYSA-N Z-hex-3-en-1-yl benzoate Natural products CCC=CCCOC(=O)C1=CC=CC=C1 BCOXBEHFBZOJJZ-UHFFFAOYSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- OOCCDEMITAIZTP-UHFFFAOYSA-N allylic benzylic alcohol Natural products OCC=CC1=CC=CC=C1 OOCCDEMITAIZTP-UHFFFAOYSA-N 0.000 description 1
- JKRWZLOCPLZZEI-UHFFFAOYSA-N alpha-Trichloromethylbenzyl acetate Chemical compound CC(=O)OC(C(Cl)(Cl)Cl)C1=CC=CC=C1 JKRWZLOCPLZZEI-UHFFFAOYSA-N 0.000 description 1
- QUMXDOLUJCHOAY-UHFFFAOYSA-N alpha-methylbenzyl acetate Natural products CC(=O)OC(C)C1=CC=CC=C1 QUMXDOLUJCHOAY-UHFFFAOYSA-N 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 235000015278 beef Nutrition 0.000 description 1
- 229940007550 benzyl acetate Drugs 0.000 description 1
- 229960002903 benzyl benzoate Drugs 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 229940116229 borneol Drugs 0.000 description 1
- CKDOCTFBFTVPSN-UHFFFAOYSA-N borneol Natural products C1CC2(C)C(C)CC1C2(C)C CKDOCTFBFTVPSN-UHFFFAOYSA-N 0.000 description 1
- 229940115397 bornyl acetate Drugs 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- KBEBGUQPQBELIU-UHFFFAOYSA-N cinnamic acid ethyl ester Natural products CCOC(=O)C=CC1=CC=CC=C1 KBEBGUQPQBELIU-UHFFFAOYSA-N 0.000 description 1
- CCRCUPLGCSFEDV-UHFFFAOYSA-N cinnamic acid methyl ester Natural products COC(=O)C=CC1=CC=CC=C1 CCRCUPLGCSFEDV-UHFFFAOYSA-N 0.000 description 1
- NPFVOOAXDOBMCE-PLNGDYQASA-N cis-3-Hexenyl acetate Natural products CC\C=C/CCOC(C)=O NPFVOOAXDOBMCE-PLNGDYQASA-N 0.000 description 1
- RRGOKSYVAZDNKR-ARJAWSKDSA-M cis-3-hexenylacetate Chemical compound CC\C=C/CCCC([O-])=O RRGOKSYVAZDNKR-ARJAWSKDSA-M 0.000 description 1
- 229940043350 citral Drugs 0.000 description 1
- 229960000956 coumarin Drugs 0.000 description 1
- 235000001671 coumarin Nutrition 0.000 description 1
- 229940095104 dimethyl benzyl carbinyl acetate Drugs 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- OGQYPPBGSLZBEG-UHFFFAOYSA-N dimethyl(dioctadecyl)azanium Chemical class CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC OGQYPPBGSLZBEG-UHFFFAOYSA-N 0.000 description 1
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 1
- DTGKSKDOIYIVQL-UHFFFAOYSA-N dl-isoborneol Natural products C1CC2(C)C(O)CC1C2(C)C DTGKSKDOIYIVQL-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- WTEVQBCEXWBHNA-JXMROGBWSA-N geranial Chemical compound CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 description 1
- 229940113087 geraniol Drugs 0.000 description 1
- FQMZVFJYMPNUCT-UHFFFAOYSA-N geraniol formate Natural products CC(C)=CCCC(C)=CCOC=O FQMZVFJYMPNUCT-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- PZOUSPYUWWUPPK-UHFFFAOYSA-N indole Natural products CC1=CC=CC2=C1C=CN2 PZOUSPYUWWUPPK-UHFFFAOYSA-N 0.000 description 1
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine Natural products C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- YJSUCBQWLKRPDL-UHFFFAOYSA-N isocyclocitral Chemical compound CC1CC(C)=CC(C)C1C=O YJSUCBQWLKRPDL-UHFFFAOYSA-N 0.000 description 1
- 229930007744 linalool Natural products 0.000 description 1
- UWKAYLJWKGQEPM-UHFFFAOYSA-N linalool acetate Natural products CC(C)=CCCC(C)(C=C)OC(C)=O UWKAYLJWKGQEPM-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- CCRCUPLGCSFEDV-BQYQJAHWSA-N methyl trans-cinnamate Chemical compound COC(=O)\C=C\C1=CC=CC=C1 CCRCUPLGCSFEDV-BQYQJAHWSA-N 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000010446 mirabilite Substances 0.000 description 1
- 229940067137 musk ketone Drugs 0.000 description 1
- HIGQPQRQIQDZMP-FLIBITNWSA-N neryl acetate Chemical compound CC(C)=CCC\C(C)=C/COC(C)=O HIGQPQRQIQDZMP-FLIBITNWSA-N 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical class OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 229940067107 phenylethyl alcohol Drugs 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 235000010259 potassium hydrogen sulphite Nutrition 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- RSIJVJUOQBWMIM-UHFFFAOYSA-L sodium sulfate decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-]S([O-])(=O)=O RSIJVJUOQBWMIM-UHFFFAOYSA-L 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- NPFVOOAXDOBMCE-UHFFFAOYSA-N trans-3-hexenyl acetate Natural products CCC=CCCOC(C)=O NPFVOOAXDOBMCE-UHFFFAOYSA-N 0.000 description 1
- KYWIYKKSMDLRDC-UHFFFAOYSA-N undecan-2-one Chemical compound CCCCCCCCCC(C)=O KYWIYKKSMDLRDC-UHFFFAOYSA-N 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
１擢光更
本発明は、衣類の黒ずみや香気の劣化を防止して、短時
間で濯ぎ作業が終了できる洗浄剤組成物に関する。DETAILED DESCRIPTION OF THE INVENTION 1. The present invention relates to a detergent composition that prevents darkening of clothes and deterioration of fragrance, and allows rinsing work to be completed in a short time.
丈末肢亙
近年の渇水状況に対応して、短時間で濯ぎ作業の終了で
きる洗剤を開発する試みがなされており、その多くはシ
リコーン、石鹸またはカチオン界面活性剤を添加するも
のである。しかしながら、このような洗剤で衣類を洗浄
した場合は、洗浄力の低下や洗濯時の著しい泡立ちの低
下を招いたり、被洗布への粒子状物の付着が生じたりし
て、消費者に対して好ましい結果をもたらさなかった。In response to the recent drought situation, attempts have been made to develop detergents that can complete the rinsing process in a short time, and many of these detergents contain silicone, soap, or cationic surfactants. However, when washing clothes with such detergents, it causes a decrease in detergency, a significant drop in foaming during washing, and adhesion of particulate matter to the washed fabric, which is harmful to consumers. did not give favorable results.
特に、カチオン界面活性剤を添加した洗剤で衣類を洗浄
すると、濯ぎ時間は短くなるものの、洗浄を繰り返して
いくうちに衣類が黒ずむようになる。これはカチオン界
面活性剤と洗剤の主活性成分であるアニオン界面活性剤
とが複合体を形成し、これに汚れ成分が吸着して繊維に
蓄積するためである。In particular, when washing clothes with a detergent containing a cationic surfactant, the rinsing time is shortened, but the clothes tend to darken as the washing process is repeated. This is because the cationic surfactant and the anionic surfactant, which is the main active ingredient of the detergent, form a complex, and dirt components are adsorbed to this complex and accumulated on the fibers.
従来、カチオン界面活性剤を洗浄と同時に添加する洗剤
における再汚染の防止方法としては、水溶性高分子を添
加することが提案されている（特開昭５９−６２９９号
）、シかしこの方法は、カチオン界面活性剤と水溶性高
分子とをできるだけ均一に混合する必要があり、製造工
程の増加の問題などから、実用上より一層の改善がまた
れていた。Conventionally, as a method for preventing recontamination in detergents in which a cationic surfactant is added at the same time as washing, it has been proposed to add a water-soluble polymer (Japanese Patent Application Laid-open No. 59-6299). However, it is necessary to mix the cationic surfactant and the water-soluble polymer as uniformly as possible, and further improvements have not been made in practical terms due to problems such as an increase in the number of manufacturing steps.
また、近年、本発明と同じセルラーゼを洗浄剤組成物に
用いて柔軟性を付与することも提案されているが（特開
昭５７−２３６９９号公報）、これは単にアニオン界面
活性剤を主成分とするもので。In addition, in recent years, it has been proposed to use the same cellulase as the present invention in detergent compositions to impart flexibility (Japanese Unexamined Patent Publication No. 57-23699); That's what I mean.
濯ぎ時間を短縮化すべくカチオン界面活性剤を配合した
本発明の洗浄剤組成物とは本質的に異なる。This is essentially different from the cleaning composition of the present invention, which contains a cationic surfactant to shorten the rinsing time.
また、亜硫酸塩を含む洗剤組成は、特開昭４９−１０９
０７号公報に提案され、公知である。しがしこれは、亜
硫酸塩を１０〜８４重量％含有せしめて低リンないし烈
リン洗剤とすることを開示するに止まっている。その他
にもゼオライト−酵素含有洗剤の提案もなされているが
、洗浄力の向上を主目的とするものである。In addition, detergent compositions containing sulfites are
This method was proposed in Japanese Patent No. 07 and is well known. However, this document only discloses that the detergent contains 10 to 84% by weight of sulfite to produce a low-phosphorus to high-phosphorus detergent. In addition, zeolite-enzyme-containing detergents have been proposed, but their main purpose is to improve detergency.
このように、濯ぎ時間を短縮すべくカチオン界面活性剤
を添加した洗剤系に、セルラーゼや亜硫酸塩を配合する
ことについては何ら示唆されていない。Thus, there is no suggestion of incorporating cellulases or sulfites into detergent systems to which cationic surfactants have been added in order to shorten the rinsing time.
月１Ｒ口り蝮
本発明の目的は、衣類の黒ずみゃ香気の劣化を招くこと
なく、短時間で濯ぎ作業が終了する洗浄剤組成物を提供
することにある。An object of the present invention is to provide a detergent composition that can complete the rinsing work in a short time without causing darkening of clothes or deterioration of fragrance.
ｌ尻立皇處
本発明の洗浄剤組成物は、以下の（Ａ）、（Ｂ）および
（Ｃ）成分を含有することを特徴とする。The cleaning composition of the present invention is characterized by containing the following components (A), (B), and (C).
（Ａ） 一般式（１）で示されるカチオン界面活性剤
：０．５〜７重量％。(A) Cationic surfactant represented by general formula (1): 0.5 to 7% by weight.
式中、各記号は次のものを示す。In the formula, each symbol represents the following.
Ｒ１、Ｒｚ ： ＣＬｚ〜Ｃ０のアルキル基、Ｒ３，Ｒ
，：Ｃ工〜Ｃ９のアルキル基、ベンジル基、Ｃ２〜Ｃ４
のヒドロキシア
ルキル基またはポリオキシアル
キレン基、
Ｘ：ハロゲン、ＣＨ３Ｓ○い
Ｃ２Ｈ５５０４、ＳＯ２または
（Ｂ） ＤＳＭ１８００の番号の下に寄託された菌株
であるヒュミコーラ・インソレン
ス（Ｈｕｍｉｃｏｌａ １ｎｓｏｌｅｎｓ）［ヒュミコ
ーラ・グリセア変異株サーモディア
（Ｈｕｍｉｃｏｌａ ｇｒｉｓｅａ ｖａｒ、ｔｈ
ｅｒｍｏｉｄｅａ）コから生産される菌類セルラーゼ：
Ｏ，ＯＳ〜５重量％。R1, Rz: CLz to C0 alkyl group, R3, R
, : C-C9 alkyl group, benzyl group, C2-C4
hydroxyalkyl group or polyoxyalkylene group, Deer (Humicola grisea var, th
Fungal cellulases produced from ermoidea):
O,OS~5% by weight.
（Ｃ） 亜硫酸塩：０．２〜２重量％。(C) Sulfite: 0.2 to 2% by weight.
以下１本発明についてさらに詳細に説明する。The present invention will be explained in more detail below.
（Ａ）成分のカチオン界面活性剤の具体例としては、ジ
ステアリルジメチルアンモニウム塩、ジ水添牛脂アルキ
ルジメチルアンモニウム塩、ジステアリルメチルヒドロ
キシプビルアンモニウム塩、ジステアリルジヒドロキシ
エチルアンモニウム塩などが挙げられる。また、対イオ
ンのハロゲンの具体例としてはクロリド、プロミドなど
が挙げられる。Specific examples of the cationic surfactant as component (A) include distearyldimethylammonium salt, dihydrogenated beef tallow alkyldimethylammonium salt, distearylmethylhydroxypupylammonium salt, and distearyldihydroxyethylammonium salt. Further, specific examples of halogen as a counter ion include chloride and bromide.
（Ａ）成分のカチオン界面活性剤は、洗剤組成物中に０
．５〜７重量％、好ましくは１〜５重量％配合される。(A) Component cationic surfactant is present in the detergent composition.
．． It is blended in an amount of 5 to 7% by weight, preferably 1 to 5% by weight.
この配合量が０．５重量％未満では、濯ぎ性が改善され
ず、−方、７重量％を超えると洗濯時の泡立ちが著しく
低下し好ましくない。If the amount is less than 0.5% by weight, the rinseability will not be improved, and if it exceeds 7% by weight, foaming during washing will be significantly reduced, which is not preferable.
（Ａ）カチオン界面活性剤は、破砕造粒や噴霧などによ
り粒径が５０〜１０００μｍ程度の造粒物として粒状洗
浄剤組成物に配合することが望ましい。(A) The cationic surfactant is desirably blended into the granular detergent composition in the form of granules having a particle size of about 50 to 1000 μm by crushing, granulation, spraying, or the like.
（Ｂ）成分のセルラーゼはＰＨ７〜１０の範囲で、かつ
、温度が７０℃以下、好ましくは６０℃以下の範囲で活
性を有する酵素である。既に説明したように、この酵素
の手粗さ軽減剤（柔軟仕上げ剤）としての使用は、特開
昭５７−２３６９９号公報に詳記されている。この菌類
セルラーゼは、ノボ・インダストリー社から５Ｐ−２２
７の名称で入手できる
（Ｃ）成分のセルラーゼは、洗剤組成物中に０．０５〜
５．０重量％、好ましくは０．５〜３．０重量％配合さ
れる。この配合量が０．０５重量％未満では、黒ずみを
十分に防止できず、−方、５．０重量％を超えても効果
が飽和してしまい、経済的に不利である。The cellulase component (B) is an enzyme that is active at a pH of 7 to 10 and at a temperature of 70°C or lower, preferably 60°C or lower. As already explained, the use of this enzyme as a roughness reducing agent (softening agent) is described in detail in JP-A-57-23699. This fungal cellulase is 5P-22 from Novo Industries.
Component (C) cellulase, which is available under the name No. 7, can be used in detergent compositions containing
It is blended in an amount of 5.0% by weight, preferably 0.5 to 3.0% by weight. If the amount is less than 0.05% by weight, darkening cannot be sufficiently prevented, and if it exceeds 5.0% by weight, the effect will be saturated, which is economically disadvantageous.
セルラーゼにダストが多いと、セルラーゼと洗剤成分と
を混合する工程や、セルラーゼ含有洗剤の使用時におい
て種々の問題が生じるので、ダストが少ないことが望ま
しい、そこで、ゼオライトはベルギー特許第７６０１３
５号公報に記載されているようなカプセル化した粒状物
としたり。If there is a lot of dust in cellulase, various problems will occur during the process of mixing cellulase and detergent components and when using cellulase-containing detergents, so it is desirable to have less dust.
It may be made into encapsulated granules as described in Publication No. 5.
あるいは、マルメライザー（Ｍａｒｕｍｅｒｉｚｅｒ、
商標名、不二パウダルー製）や、アウフベライトウング
ス・テクニーク
（Ａｕｆｂｅｒｅｉｔｕｎｇｓ−Ｔｅｃｈｎｉｋ） Ｎ
ｏ ３ ／ １９７０． ｐ １４７−１５３等に記載
された造粒機によって調製したものがよい。さらに、セ
ルラーゼは白色化剤、好ましくはＴｉＯ，をダスト結合
剤と組合せて被覆したものを、粒状洗浄剤と混合するの
がよい。Or Marumerizer (Marumerizer,
Trade name, manufactured by Fuji Powderoo) and Aufbereitungs-Technik N
o 3/1970. It is preferable to use the granulator described in p. 147-153. Additionally, the cellulase may be coated with a whitening agent, preferably TiO, in combination with a dust binder and mixed with the granular cleaning agent.
（Ｃ）成分の亜硫酸塩の具体例としては、Ｎａ、ＳＯ，
、Ｋ、 Ｓ Ｏ３、ＫＨＳＯ３，Ｍｇ５Ｏ。Specific examples of the sulfite of component (C) include Na, SO,
, K, SO3, KHSO3, Mg5O.
などが挙げられ、この中でもＮ ａ ｘ Ｓ Ｏｚ （
亜硫酸ナトリウムが好適である。Among them, N a x S Oz (
Sodium sulfite is preferred.
（Ｃ）成分は、洗浄剤組成物中に０．２〜２重量％配合
される。この量が０．２重量％未満では黒ずみを十分に
防止できず、−方、２重量％を超えると臭気が劣化して
しまう。Component (C) is blended in the cleaning composition in an amount of 0.2 to 2% by weight. If the amount is less than 0.2% by weight, darkening cannot be sufficiently prevented, and if it exceeds 2% by weight, the odor will deteriorate.
本発明の洗浄剤組成物中には香料を添加して芳香を付与
することができ、また、上記３成分を併用することによ
り、この臭気の劣化も有効に防止されている。A perfume can be added to the cleaning composition of the present invention to impart a fragrance, and deterioration of this odor can also be effectively prevented by using the above three components in combination.
特に限定されないが、香料としては、アリルイソアミル
オキシアセテート、シクラメンアルデヒド、トナリッド
、ｐ−ｔａｒｔ−ブチル−ジヒドロシンナムアルデヒド
、テトラヒドロリナロール、６−アセチル−１−イソプ
ロピル−１，２，３，５−テトラヒドロインダン、メチ
ル−β−ナフチルケトン、アセトフェノン、ネロール、
β−ナフトールメチルエーテルおよびβ−ナフトールエ
チルエーテルの中から選ばれた少なくとも１種の香料を
主成分として、必要に応じシトロネロール、フェニルエ
チルアルコール、２−６−１０−トリメチル−９−ウン
デシレニツクアルデヒト、アンブレトン、ボルニルアセ
テート、デイフェニルオキサイド、エチルリナロール、
ゲラニルフォーメート、ｐ−ターシャワー−ブチル−α
−メチル−ヒドロシンナムアルデヒド、ムスクケトン、
メチルアセトフェノン、メチルアンスブレニート、・ベ
ンジルベンゾエート、ボルネオール、シス−３−ヘキセ
ニルベンゾエート、シトロネリルホーメート、ジメチル
オクタツール、エチルシンナメート、メチルニーシノー
ル、メチルノニルケトン、ネリルアセテート、スチラリ
ルアルコール、シンナミルアルコール、テトラヒドロリ
ナロール、アニスインクアルコール、シトロネリルアセ
テート、ジメトール、インドール、ムスクキジロール、
クマリン、ゲラニルアセテート、ジメチルベンジルカル
ビニルアセテート、リナリルアセテート、ジヒドロミル
セノール、ゲラニオール、リナロール、フェニルプロピ
ルアルコール、シトラール、ヴイゴローズ、シス−３−
ヘキセニルサリシレート、トビカル、メチルイソニーシ
ノール、γ−メチルイオノン、イソニーシノール、イソ
シクロシトラール、シス−３−へキセニルアセテート、
メチルシンナメート、ローズフェノン、フェニルエチル
アセテート、ベンジルアセテートなどを併用して用いる
ことができる。Although not particularly limited, examples of fragrances include allylisoamyloxyacetate, cyclamenaldehyde, tonalid, p-tart-butyl-dihydrocinnamaldehyde, tetrahydrolinalool, 6-acetyl-1-isopropyl-1,2,3,5-tetrahydroindan , methyl-β-naphthyl ketone, acetophenone, nerol,
The main ingredient is at least one fragrance selected from β-naphthol methyl ether and β-naphthol ethyl ether, and optionally citronellol, phenylethyl alcohol, and 2-6-10-trimethyl-9-undecylenic aldehyde. , ambretone, bornyl acetate, diphenyl oxide, ethyl linalool,
Geranyl formate, p-tershower-butyl-α
-Methyl-hydrocinnamaldehyde, musk ketone,
Methyl acetophenone, methyl ansubrenite, benzyl benzoate, borneol, cis-3-hexenyl benzoate, citronellyl formate, dimethyl octatool, ethyl cinnamate, methyl nisinol, methyl nonyl ketone, neryl acetate, styralyl alcohol, Cinnamyl alcohol, tetrahydrolinalool, anise ink alcohol, citronellyl acetate, dimetol, indole, musk pheasant,
Coumarin, geranyl acetate, dimethylbenzyl carbinyl acetate, linalyl acetate, dihydromircenol, geraniol, linalool, phenylpropyl alcohol, citral, vigorose, cis-3-
hexenyl salicylate, tobical, methylisonisinol, γ-methylionone, isisonisinol, isocyclocitral, cis-3-hexenyl acetate,
Methyl cinnamate, rosephenone, phenylethyl acetate, benzyl acetate, etc. can be used in combination.
本発明の洗浄剤組成物中には、他の界面活性剤やビルダ
ー等の任意成分を添加することができる。これらの具体
例としては以下のものが例示できる。Optional components such as other surfactants and builders can be added to the cleaning composition of the present invention. Specific examples of these include the following.
（１） 直鎖アルキルベンゼンスルホン酸塩、α−オレ
フィンスルホン酸塩、アルキル硫酸塩などのアニオン界
面活性剤、アルキルベタインなどの両性界面活性剤、ア
ルコールエトキシレートなどのノニオン界面活性剤。(1) Anionic surfactants such as linear alkylbenzene sulfonates, α-olefin sulfonates, and alkyl sulfates, amphoteric surfactants such as alkyl betaines, and nonionic surfactants such as alcohol ethoxylates.
（２）炭酸塩、珪酸塩、ホウ酸塩などのアルカリビルダ
ー。(2) Alkali builders such as carbonates, silicates, and borates.
（３） アルミノ珪酸塩、ニトリロトリ酢酸塩、ポリア
クリル酸塩などのキレートビルダー・
（４）過炭酸塩、過ホウ酸塩などの酸素系漂白剤。(3) Chelate builders such as aluminosilicates, nitrilotriacetates, and polyacrylates; (4) Oxygen bleaches such as percarbonates and perborates.
（５）ポリエチルグリコール、カルボキシメチルセルロ
ース、メチルセルロースなどの再汚染防止剤。(5) Anti-recontamination agents such as polyethyl glycol, carboxymethyl cellulose, and methyl cellulose.
（６） 石鹸などの泡コントロール剤。(6) Foam control agents such as soap.
（７）蛍光増白剤、色素、芒硝等の増量剤。(7) Extending agents such as optical brighteners, dyes, and Glauber's salt.
ｌ更立羞米
本発明によれば、カチオン界面活性剤、特定のセルラー
ゼ、亜硫酸塩の３成分を併用することにより、これらが
相剰的に作用して、繰返し洗浄によっても衣類の黒ずみ
を防止し、また。According to the present invention, by using the three components of a cationic surfactant, a specific cellulase, and a sulfite salt, they work together to prevent darkening of clothes even after repeated washing. And again.
経時においても洗浄剤の香気を損なうことなく、しかも
、短時間で濯ぎ作業を完結する洗浄剤組成物を実現でき
る。It is possible to realize a cleaning composition that does not lose its fragrance over time and can complete rinsing work in a short time.
以下、実施例により１本発明の効果を具体的に説明する
。実施例における性能の評価方法は次の通りである。Hereinafter, the effects of the present invention will be specifically explained using examples. The performance evaluation method in Examples is as follows.
（１）濯ぎ性
二槽式電気洗濯機に２５℃、４°ＤＨの水３００を入れ
、そこに４０ｇの洗浄剤を加えて１分間攪拌する０次い
で、有機質汚垢を付けた肌シャツを浴比３０倍に合わせ
て加え、１０分間洗濯したのち１分間脱水する。この被
洗布を４”ＤＨの水３０ｆｉで３分間濯ぐ操作を２回繰
返し、最終回の操作で得た濯ぎ液について泡残り状態を
次に示す基準で評価した。(1) Rinseability Pour 300ml of water at 25°C and 4°DH into a two-tank electric washing machine, add 40g of detergent, and stir for 1 minute.Next, wash the skin shirt with organic dirt in it. Add 30 times the ratio, wash for 10 minutes, then dehydrate for 1 minute. The operation of rinsing the cloth to be washed with 30 fi of 4"DH water for 3 minutes was repeated twice, and the rinsing liquid obtained in the final operation was evaluated for the remaining foam according to the following criteria.
−泡が認められない。- No bubbles observed.
＋１ 泡が極くわずかに存在する。+1 Very few bubbles are present.
＋２ 泡がわずかに存在する。+2 Slight presence of bubbles.
＋３ 泡がやや多く存在する。+3: Slightly more bubbles are present.
＋４ 泡が多く存在する。+4 There are many bubbles.
＋５ 泡が非常に多く存在する。+5 There are a lot of bubbles.
（２）黒ずみ防止性
２日間着用した綿メリヤス肌シャツを左右対称に分割し
、−方を基準洗剤（比較例１）で、他方を本発明洗浄剤
および他の比較洗浄剤で洗濯した。(2) Darkening prevention A cotton knitted skin shirt worn for two days was divided symmetrically, and the - side was washed with the standard detergent (Comparative Example 1) and the other side was washed with the present invention detergent and other comparative detergents.
洗濯条件は洗浄剤濃度： ０．１３３％、使用水＝４’
ＤＨ１温度＝２５℃、浴比：３０倍、洗濯時間＝１０分
、洗濯機：二槽式電気洗濯機とした。そして、洗濯後に
肌シャツをぬい合わせて、また、２日間着用した。Washing conditions: detergent concentration: 0.133%, water used = 4'
DH1 temperature = 25°C, bath ratio: 30 times, washing time = 10 minutes, washing machine: two-tank electric washing machine. After washing, I sewed the skin shirt together and wore it again for two days.
この操作を３０回繰返した後、黒ずみを下記の基準で５
名の判定者により目視判定し、その合計点で評価した。After repeating this operation 30 times, remove the blackheads by 5% according to the following criteria.
Visual judgment was made by a qualified judge, and the total score was used for evaluation.
＋２ 基準洗浄剤より明らかに黒ずみが少ない。+2 Obviously less darkening than the standard cleaning agent.
＋１ 基準洗浄剤より黒ずみが少ない。+1 Less darkening than the standard cleaning agent.
０ 基準洗浄剤と同等である。0 Equivalent to the standard cleaning agent.
−１基準洗浄剤より黒ずみが多い。-1 More blackheads than the standard cleaning agent.
−２基準洗浄剤より明らかに黒ずみが多ａ
（３）香気
洗浄剤にシクラメンアルデヒド、シトロネロール、クマ
リンを１：１：１の割合で配合した香料を０．１重量％
噴霧し、ガラスビンに密封して４５℃に１ケ月間保存し
たのち、管能検査により香気を下記の基準で評価した。-2 Noticeably more blackheads than the standard cleaning agent (3) 0.1% by weight of a scented cleaning agent containing cyclamen aldehyde, citronellol, and coumarin in a ratio of 1:1:1.
The mixture was sprayed, sealed in a glass bottle, and stored at 45°C for one month, and the aroma was evaluated using the following criteria using a tube function test.
○： 洗浄剤に配合した香気が残っている。○: The fragrance blended into the cleaning agent remains.
Δ： 洗浄剤に配合した香気がやや残っている。Δ: Slight scent of the cleaning agent remains.
×： 洗浄剤に配合した香気が残っていない。×: The fragrance blended into the cleaning agent does not remain.
実施例
表−１に示した各洗浄剤組成物を調製し、濯ぎ性、黒ず
み防止性、および香気を評価し、その結果を表−１に示
した。Examples Each of the cleaning compositions shown in Table 1 was prepared and evaluated for rinsability, anti-blackening properties, and fragrance, and the results are shown in Table 1.
（以下余白）Ｉ(Left below) I
Claims (1)
剤：０．５〜７重量％、 ▲数式、化学式、表等があります▼（ I ） （式中、各記号は次のものを示す。 Ｒ＿１、Ｒ＿２：Ｃ＿１＿２〜Ｃ＿２＿６のアルキル基
、Ｒ＿３、Ｒ＿４：Ｃ＿１〜Ｃ＿４のアルキル基、ベン
ジル基、Ｃ＿２〜Ｃ＿４のヒドロキシアルキル基または
ポリオキシアルキレン基、Ｘ：ハロゲン、ＣＨ＿３ＳＯ
＿４、Ｃ＿２Ｈ＿５ＳＯ＿４、ＳＯ＿４または▲数式、
化学式、表等があります▼） （Ｂ）ＤＳＭ１８００の番号の下に寄託された菌株であ
るヒュミコーラ・インソレンス （Ｈｕｍｉｃｏｌａ ｉｎｓｏｌｅｎｓ）［ヒュミコー
ラ・グリセア変異株サーモディア（Ｈｕｍｉｃｏｌａｇ
ｒｉｓｅａ ｖａｒ．ｔｈｅｒｍｏｉｄｅａ）］から生
産される菌類セルラーゼ：０．０５〜５重量％、および （Ｃ）亜硫酸塩：０．２〜２重量％ を含有することを特徴とする洗浄剤組成物。[Claims] 1. (A) Cationic surfactant represented by the general formula (I): 0.5 to 7% by weight, ▲There are numerical formulas, chemical formulas, tables, etc.▼(I) (In the formula, each The symbols represent the following: R_1, R_2: alkyl group of C_1_2 to C_2_6, R_3, R_4: alkyl group of C_1 to C_4, benzyl group, hydroxyalkyl group or polyoxyalkylene group of C_2 to C_4, X: halogen, CH_3SO
_4, C_2H_5SO_4, SO_4 or ▲ formula,
There are chemical formulas, tables, etc. ▼) (B) Humicola insolens, a strain deposited under the number DSM 1800 [Humicola grisea mutant strain Thermodia (Humicola
risea var. 1. A cleaning composition comprising: 0.05 to 5% by weight of a fungal cellulase produced from A. thermoidea); and 0.2 to 2% by weight of (C) sulfite.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15053686A JPS636098A (en) | 1986-06-26 | 1986-06-26 | Detergent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15053686A JPS636098A (en) | 1986-06-26 | 1986-06-26 | Detergent composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS636098A true JPS636098A (en) | 1988-01-12 |
Family
ID=15499013
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP15053686A Pending JPS636098A (en) | 1986-06-26 | 1986-06-26 | Detergent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS636098A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6317996A (en) * | 1986-07-09 | 1988-01-25 | 花王株式会社 | Oxygen-containing powdery detergent composition |
| US5445747A (en) * | 1994-08-05 | 1995-08-29 | The Procter & Gamble Company | Cellulase fabric-conditioning compositions |
| US5599786A (en) * | 1993-08-12 | 1997-02-04 | The Procter & Gamble Company | Cellulase fabric-conditioning compositions |
| US5616553A (en) * | 1993-08-12 | 1997-04-01 | The Procter & Gamble Company | Fabric conditioning compositions |
| WO1997043386A1 (en) * | 1996-05-15 | 1997-11-20 | The Procter & Gamble Company | Detergent compositions comprising improved amylases, cellulase and cationic surfactant |
| US5721205A (en) * | 1994-04-29 | 1998-02-24 | The Procter & Gamble Company | Cellulase fabric-conditioning compositions |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5070684A (en) * | 1973-11-01 | 1975-06-12 | ||
| JPS58138797A (en) * | 1982-02-12 | 1983-08-17 | 三洋化成工業株式会社 | Cationic activator post-treatment |
| JPS596299A (en) * | 1982-07-05 | 1984-01-13 | ライオン株式会社 | Additive for granular detergent |
| JPS6164797A (en) * | 1984-08-29 | 1986-04-03 | ユニリーバー・ナームローゼ・ベンノートシヤープ | Detergent composition |
-
1986
- 1986-06-26 JP JP15053686A patent/JPS636098A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5070684A (en) * | 1973-11-01 | 1975-06-12 | ||
| JPS58138797A (en) * | 1982-02-12 | 1983-08-17 | 三洋化成工業株式会社 | Cationic activator post-treatment |
| JPS596299A (en) * | 1982-07-05 | 1984-01-13 | ライオン株式会社 | Additive for granular detergent |
| JPS6164797A (en) * | 1984-08-29 | 1986-04-03 | ユニリーバー・ナームローゼ・ベンノートシヤープ | Detergent composition |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6317996A (en) * | 1986-07-09 | 1988-01-25 | 花王株式会社 | Oxygen-containing powdery detergent composition |
| US5599786A (en) * | 1993-08-12 | 1997-02-04 | The Procter & Gamble Company | Cellulase fabric-conditioning compositions |
| US5616553A (en) * | 1993-08-12 | 1997-04-01 | The Procter & Gamble Company | Fabric conditioning compositions |
| US5721205A (en) * | 1994-04-29 | 1998-02-24 | The Procter & Gamble Company | Cellulase fabric-conditioning compositions |
| US5445747A (en) * | 1994-08-05 | 1995-08-29 | The Procter & Gamble Company | Cellulase fabric-conditioning compositions |
| WO1997043386A1 (en) * | 1996-05-15 | 1997-11-20 | The Procter & Gamble Company | Detergent compositions comprising improved amylases, cellulase and cationic surfactant |
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