JPS63251287A - Ink ribbon for producing dry transfer material - Google Patents
Ink ribbon for producing dry transfer materialInfo
- Publication number
- JPS63251287A JPS63251287A JP62085350A JP8535087A JPS63251287A JP S63251287 A JPS63251287 A JP S63251287A JP 62085350 A JP62085350 A JP 62085350A JP 8535087 A JP8535087 A JP 8535087A JP S63251287 A JPS63251287 A JP S63251287A
- Authority
- JP
- Japan
- Prior art keywords
- sensitive adhesive
- pressure
- adhesive layer
- thermal transfer
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000463 material Substances 0.000 title claims description 33
- 239000010410 layer Substances 0.000 claims abstract description 76
- 239000004820 Pressure-sensitive adhesive Substances 0.000 claims abstract description 43
- 229920005989 resin Polymers 0.000 claims abstract description 32
- 239000011347 resin Substances 0.000 claims abstract description 32
- 239000003086 colorant Substances 0.000 claims abstract description 9
- 239000004840 adhesive resin Substances 0.000 claims abstract description 3
- 229920006223 adhesive resin Polymers 0.000 claims abstract description 3
- 239000012790 adhesive layer Substances 0.000 claims 1
- 238000007639 printing Methods 0.000 abstract description 12
- 238000003892 spreading Methods 0.000 abstract description 5
- 239000000758 substrate Substances 0.000 abstract description 4
- 238000007790 scraping Methods 0.000 abstract description 3
- 229920006015 heat resistant resin Polymers 0.000 abstract description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
- 230000003449 preventive effect Effects 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- 238000009736 wetting Methods 0.000 abstract 1
- 239000001993 wax Substances 0.000 description 16
- 239000000203 mixture Substances 0.000 description 13
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 12
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 12
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 12
- 230000001070 adhesive effect Effects 0.000 description 11
- 239000000123 paper Substances 0.000 description 11
- 238000009472 formulation Methods 0.000 description 10
- 150000002148 esters Chemical class 0.000 description 8
- 239000000853 adhesive Substances 0.000 description 7
- -1 polyethylene Polymers 0.000 description 7
- 239000011230 binding agent Substances 0.000 description 6
- 239000003921 oil Substances 0.000 description 6
- 235000019198 oils Nutrition 0.000 description 6
- 239000004698 Polyethylene Substances 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 238000002844 melting Methods 0.000 description 5
- 229920000573 polyethylene Polymers 0.000 description 5
- 239000004094 surface-active agent Substances 0.000 description 5
- 239000001856 Ethyl cellulose Substances 0.000 description 4
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229920001249 ethyl cellulose Polymers 0.000 description 4
- 235000019325 ethyl cellulose Nutrition 0.000 description 4
- 239000005038 ethylene vinyl acetate Substances 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000003208 petroleum Substances 0.000 description 4
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 3
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 3
- 239000004952 Polyamide Substances 0.000 description 3
- 206010057040 Temperature intolerance Diseases 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 229920006244 ethylene-ethyl acrylate Polymers 0.000 description 3
- 230000008543 heat sensitivity Effects 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 229920002647 polyamide Polymers 0.000 description 3
- 229920002689 polyvinyl acetate Polymers 0.000 description 3
- 239000011118 polyvinyl acetate Substances 0.000 description 3
- 241000894007 species Species 0.000 description 3
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 2
- 241000951471 Citrus junos Species 0.000 description 2
- NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical compound COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 description 2
- 239000004166 Lanolin Substances 0.000 description 2
- 240000007594 Oryza sativa Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- 239000004734 Polyphenylene sulfide Substances 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 239000012164 animal wax Substances 0.000 description 2
- 235000013871 bee wax Nutrition 0.000 description 2
- 239000012166 beeswax Substances 0.000 description 2
- 229940092738 beeswax Drugs 0.000 description 2
- 239000004204 candelilla wax Substances 0.000 description 2
- 235000013868 candelilla wax Nutrition 0.000 description 2
- 229940073532 candelilla wax Drugs 0.000 description 2
- 239000004203 carnauba wax Substances 0.000 description 2
- 235000013869 carnauba wax Nutrition 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 239000012943 hotmelt Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- 235000019388 lanolin Nutrition 0.000 description 2
- 229940039717 lanolin Drugs 0.000 description 2
- 239000004200 microcrystalline wax Substances 0.000 description 2
- 235000019808 microcrystalline wax Nutrition 0.000 description 2
- 239000012184 mineral wax Substances 0.000 description 2
- 239000012170 montan wax Substances 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 239000012169 petroleum derived wax Substances 0.000 description 2
- 235000019381 petroleum wax Nutrition 0.000 description 2
- 229920001568 phenolic resin Polymers 0.000 description 2
- 239000005011 phenolic resin Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 239000004417 polycarbonate Substances 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920000069 polyphenylene sulfide Polymers 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- 229920002050 silicone resin Polymers 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- 239000012177 spermaceti Substances 0.000 description 2
- 229940084106 spermaceti Drugs 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000012178 vegetable wax Substances 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- QLZJUIZVJLSNDD-UHFFFAOYSA-N 2-(2-methylidenebutanoyloxy)ethyl 2-methylidenebutanoate Chemical compound CCC(=C)C(=O)OCCOC(=O)C(=C)CC QLZJUIZVJLSNDD-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- XTJFFFGAUHQWII-UHFFFAOYSA-N Dibutyl adipate Chemical compound CCCCOC(=O)CCCCC(=O)OCCCC XTJFFFGAUHQWII-UHFFFAOYSA-N 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 235000019483 Peanut oil Nutrition 0.000 description 1
- 239000004695 Polyether sulfone Substances 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 229920002367 Polyisobutene Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 description 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
- 150000001241 acetals Chemical class 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000002313 adhesive film Substances 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 description 1
- 229940063655 aluminum stearate Drugs 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000010495 camellia oil Substances 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 239000002385 cottonseed oil Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 229940100539 dibutyl adipate Drugs 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- FBSAITBEAPNWJG-UHFFFAOYSA-N dimethyl phthalate Natural products CC(=O)OC1=CC=CC=C1OC(C)=O FBSAITBEAPNWJG-UHFFFAOYSA-N 0.000 description 1
- 229960001826 dimethylphthalate Drugs 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 description 1
- 239000005042 ethylene-ethyl acrylate Substances 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000011086 glassine Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000000312 peanut oil Substances 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 150000003021 phthalic acid derivatives Chemical class 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920006393 polyether sulfone Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 229920001289 polyvinyl ether Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000013077 target material Substances 0.000 description 1
- 230000008542 thermal sensitivity Effects 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- 239000002383 tung oil Substances 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- 239000002888 zwitterionic surfactant Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
- B41M5/44—Intermediate, backcoat, or covering layers characterised by the macromolecular compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
- B41M5/44—Intermediate, backcoat, or covering layers characterised by the macromolecular compounds
- B41M5/443—Silicon-containing polymers, e.g. silicones, siloxanes
Landscapes
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
Abstract
Description
【発明の詳細な説明】
え咀少旦旬
[産業上の利用分野]
本発明は乾式転写材の製造に際して用いられる感熱転写
インクリボンに係り、特に感熱転写方式0式%
等を用いて、ぬれ性の悪い、剥離性の強い面へも転写、
印字可能となすと共に、被転写物に感熱転写して得られ
る転写像が、圧力により、目的とする第2の被転写物上
へ効果的に感圧再転写せしめられ得るようにした乾式転
写材製造用インクリボンに関するものである。[Detailed Description of the Invention] [Field of Industrial Application] The present invention relates to a thermal transfer ink ribbon used in the production of dry transfer materials, and in particular, the present invention relates to a thermal transfer ink ribbon used in the production of dry transfer materials. Transfers even to surfaces with poor removability and strong removability.
A dry transfer material that is printable and allows a transferred image obtained by heat-sensitive transfer to an object to be transferred to be effectively pressure-sensitively retransferred onto a second target object by pressure. This invention relates to ink ribbons for manufacturing.
[従来の技術]
近年、感熱転写方式によるプリンタ、タイプライタ、ワ
ードプロセッサ等の印字装置が開発されて、小型のパー
ソナルユースからビジネス用途にまで広く使用されるよ
うになってきている。この感熱転写方式による印字は、
サーマルヘッドにより熱転写インクリボンを、所定の印
字用紙に密着させ、そしてそのサーマルヘッドが有する
多数の発熱素子の内、所定の発熱素子を発熱せしめるこ
と;こより、熱転写リボンの支持体を介して発熱素子に
接している熱溶融性インク部分を溶かして、印字用紙に
転写せしめることにより、行われるようになっている。[Prior Art] In recent years, thermal transfer printers, typewriters, word processors, and other printing devices have been developed and are now widely used for everything from small-sized personal use to business use. Printing using this thermal transfer method is
Bringing the thermal transfer ink ribbon into close contact with a predetermined printing paper using a thermal head, and causing a predetermined heating element among a large number of heating elements included in the thermal head to generate heat; This is done by melting the part of the hot-melt ink that is in contact with the paper and transferring it to the printing paper.
ところで、この種の熱転写リボンは、従来から、着色剤
とそのバインダ剤とからなる熱溶融性インりを所定の支
持体上に塗工しただけのものであって、上記バインダ剤
はワックスを主成分とするものであった。しかも、この
種の熱転写リボンは被転写物として通常紙を対象とする
に過ぎない。By the way, this type of thermal transfer ribbon has conventionally been made by simply coating a heat-melting ink consisting of a colorant and a binder agent on a predetermined support, and the binder agent is mainly made of wax. It was supposed to be an ingredient. Moreover, this type of thermal transfer ribbon is only intended for use with ordinary paper as the transfer material.
一方、最近になって、感熱転写方式の普及と共に、ラフ
ペーパー(平滑度の低い紙)への転写性の向上が要求さ
れるようになり、これに関連した種々の特許出願がなさ
れており、また同一インクリボンで何度も転写、印字を
可能とするマルチタイプリボンや、誤字を消去、修正す
ることのできるコレクタプルリボン等の技術も、種々提
案されている。On the other hand, recently, with the spread of thermal transfer methods, there has been a demand for improved transferability to rough paper (paper with low smoothness), and various patent applications related to this have been filed. Various technologies have also been proposed, such as multi-type ribbons that enable multiple transfers and printing with the same ink ribbon, and collector ribbons that can erase and correct typos.
[発明が解決しようとする問題点コ
しかしながら、本発明者らの知る限りにおいて、ぬれ性
が悪くて、離型性、剥離性の良い面への転写、印字を可
能とすることを目的とした感熱転写インクリボンに関し
ては、現在までのところ、何等の報告もなされてはいな
い。しかも、インスタントレタリング用乾式転写材の製
造方法として、感熱転写方式はこれまでのところ全く採
用されていないために、インスタントレタリング用乾式
転写材を製造するのに用いられる感熱転写インクリボン
というものも、これまでに何等の提案もなされてはいな
い。[Problems to be Solved by the Invention] However, to the best of the inventors' knowledge, the present invention aims to enable transfer and printing on surfaces with poor wettability and good releasability and peelability. To date, no reports have been made regarding thermal transfer ink ribbons. Moreover, since the thermal transfer method has not been adopted at all as a method for producing dry transfer materials for instant lettering, the thermal transfer ink ribbon used to produce dry transfer materials for instant lettering is No proposals have been made so far.
ル叫息復成
そこで、本発明は、上記問題点を解決することを目的ど
し、次のような構成を採用した。SUMMARY OF THE INVENTION Therefore, the present invention employs the following configuration in order to solve the above problems.
[問題点を解決するための手段]
flllち、本発明の要旨とするところは、熱転写によ
り被転写物を乾式転写材に変える乾式転写材製造用イン
クリボンであって、フィルム状リボン基材の片面上に設
けられた感圧接着剤層と、該感圧接着剤層上に設けられ
、着色剤、感熱接着性樹脂および粘着付与性樹脂を含ん
で構成された熱転写性インク層と、を備えたことを特徴
とする乾式転写材製造用インクリボンにある。[Means for Solving the Problems] The gist of the present invention is to provide an ink ribbon for producing a dry transfer material, which converts a transferred object into a dry transfer material by thermal transfer, and which uses a film-like ribbon base material. A pressure-sensitive adhesive layer provided on one side, and a heat-transferable ink layer provided on the pressure-sensitive adhesive layer and containing a colorant, a heat-sensitive adhesive resin, and a tackifying resin. An ink ribbon for producing dry transfer materials, which is characterized by:
ここで、第1図に例示するごとく、乾式転写材製造用イ
ンクリボン10は、フィルム状のリボン基材(支持体)
11の一方の表面上に感圧接着剤層12が形成され、更
にその上に熱転写性インク層13が所定厚さで形成され
ているのである。尚、リボン基材11の前記感圧接着剤
層12の塗工面とは反対側の面には、必要に応じてシリ
コン樹脂のような耐熱性樹脂からなるスティッキング防
止層14が設けられる。Here, as illustrated in FIG. 1, the ink ribbon 10 for producing a dry transfer material has a film-like ribbon base (support)
A pressure-sensitive adhesive layer 12 is formed on one surface of the paper 11, and a thermally transferable ink layer 13 is further formed thereon to a predetermined thickness. An anti-sticking layer 14 made of a heat-resistant resin such as silicone resin is provided on the surface of the ribbon base material 11 opposite to the surface coated with the pressure-sensitive adhesive layer 12, if necessary.
そして、この様な乾式転写材製造用インクリボン10に
おいて、その感圧接着剤層12等を支持するフィルム状
のリボン基材11としては、従来から熱転写インクリボ
ンの基材として用いられている各種のものがいずれも使
用可能であるが、特に感熱転写のためにインクリボンに
はサーマルヘッド(印字装置)が接触するところから、
耐熱温度が150℃以上の、ポリエステル、ポリイミド
、ポリカーボネート、ポリサルフォン、ポリエーテルサ
ルフォン、ポリフェニレンサルファイドからなるプラス
チックフィルム、またはコンデンサ紙、グラシン紙等の
紙が好適な材料として用いられ、特に、ポリエステル、
ポリカーボネート、ポリフェニレンサルファイドが耐熱
性等の点から好ましい。またその厚さも、材料の種類に
より適宜に決定されることとなるが、一般に3〜20u
mの範囲の厚さのものを用いることがテープとしての各
種必要性状の点から望ましい。In such an ink ribbon 10 for producing dry transfer materials, the film-like ribbon base material 11 that supports the pressure-sensitive adhesive layer 12, etc. may be any of various types conventionally used as base materials for thermal transfer ink ribbons. Any of these can be used, but in particular, since the ink ribbon comes into contact with the thermal head (printing device) for thermal transfer,
Suitable materials include plastic films made of polyester, polyimide, polycarbonate, polysulfone, polyethersulfone, and polyphenylene sulfide, or papers such as capacitor paper and glassine paper, which have a heat resistance temperature of 150° C. or higher; in particular, polyester,
Polycarbonate and polyphenylene sulfide are preferred from the viewpoint of heat resistance and the like. The thickness will also be determined appropriately depending on the type of material, but generally 3 to 20 μm.
It is desirable to use a tape having a thickness in the range of m from the viewpoint of various necessary properties of the tape.
また、感圧接着剤層12は、バインダ成分およびI、J
圧接着成分を含んで主として構成されている。Further, the pressure sensitive adhesive layer 12 includes a binder component and I, J
It is mainly composed of a pressure bonding component.
感圧接着剤層12を構成するバインダ成分としては、例
えは゛、■キャンデリラワックス、カルナバワックス、
ライスワックス、木ロウ等の植物系ワックス、蜜ろう、
ラノリン、鯨ろう等の動物系ワックス、モンタンワック
ス、セレシン等の鉱物系ワックス、パラフィンワックス
、マイクロクリスタリンワックス等の石油系ワックス、
ポリエチレンワ・ンクス等の合成ワ・ンクス、およびα
−オレフィン−無水マレイン酸共重合体等の樹脂系ワッ
クスの1種または2種以上からなるワックスと、■石油
樹脂、ロジン、水添ロジン、ロジンエステル、ケトン樹
脂、フェノール樹脂等の1種または2種以上からなる粘
着付与剤と、からなるものが用いられる。Examples of the binder component constituting the pressure-sensitive adhesive layer 12 include ゛, ■ Candelilla wax, carnauba wax,
Rice wax, vegetable wax such as wood wax, beeswax,
Animal waxes such as lanolin and spermaceti; mineral waxes such as montan wax and ceresin; petroleum waxes such as paraffin wax and microcrystalline wax;
Synthetic waxes such as polyethylene waxes, and α
- A wax consisting of one or more resin waxes such as an olefin-maleic anhydride copolymer, and one or more petroleum resins, rosins, hydrogenated rosins, rosin esters, ketone resins, phenolic resins, etc. A tackifier consisting of at least one species is used.
この粘着付与剤は感圧接着剤層12の密着性、硬度向上
、凝集力付与、粘着力付与および感圧接着成分の粘着付
与の働きをなすものである。特に、粘着付与剤としては
、石油樹脂、ロジン、水添ロジン、ロジンエステルが粘
着性等の点から、好ましい。また、このバインダ成分を
構成するワックスと粘着付与剤とは、一般に、重量基準
で、15:1〜3:2種度の割合において配合される。This tackifier functions to improve the adhesion and hardness of the pressure-sensitive adhesive layer 12, to impart cohesive force, to impart tackiness, and to impart tackiness to the pressure-sensitive adhesive component. In particular, as the tackifier, petroleum resin, rosin, hydrogenated rosin, and rosin ester are preferred from the viewpoint of tackiness and the like. Further, the wax and tackifier constituting the binder component are generally mixed in a ratio of 15:1 to 3:2 on a weight basis.
更に、感圧接着剤層12を構成する感圧接着成分として
は、ポリ塩化ビニル、ポリアクリル酸エステル、エチレ
ン−酢酸ビニル共重合体、エチレン−エチルアクリレー
ト共重合体、ポリ酢酸ビニル、ポリビニルエーテル、ポ
リビニルアセタール、ポリイソブチレン等のビニル系高
分子、エチルセルロース、ニトロセルロース、酢酸セル
ロース等のPa維系高分子、塩化ゴム、天然ゴム等のゴ
ム系高分子等の1種または2種以上が組み合わされて用
いられる。特に、ポリアクリル酸エステル、エチレン−
酢酸ビニル共重合体、エチレン−エチルアクリレート共
重合体、ポリ酢酸ビニルが、接着性等の点から好ましい
。Furthermore, the pressure-sensitive adhesive components constituting the pressure-sensitive adhesive layer 12 include polyvinyl chloride, polyacrylic ester, ethylene-vinyl acetate copolymer, ethylene-ethyl acrylate copolymer, polyvinyl acetate, polyvinyl ether, A combination of one or more of vinyl polymers such as polyvinyl acetal and polyisobutylene, Pa fiber polymers such as ethyl cellulose, nitrocellulose, and cellulose acetate, and rubber polymers such as chlorinated rubber and natural rubber. used. In particular, polyacrylic acid ester, ethylene-
Vinyl acetate copolymer, ethylene-ethyl acrylate copolymer, and polyvinyl acetate are preferred from the viewpoint of adhesive properties and the like.
また、インク層13の邑を補ったり、色調調節のために
、必要に応じて、カーボンブラック等の顔料や染Hの1
種又は2種以上を加えてもよい。In addition, in order to supplement the thickness of the ink layer 13 or adjust the color tone, pigments such as carbon black or dye H may be used as needed.
A species or two or more species may be added.
上記感圧接着剤層12を構成する上記バインダ成分と感
圧接着成分とは、一般に40〜93:2〜30程度の割
合において配合され、好ましくは95℃の温度下におい
て、3000センチボイス未満、特に100〜1000
センチボイス程度の粘度を与える組成物とする。また、
その様な組成物は、適当な溶媒に溶解もしくは分散され
て液状とされ、あるいは加熱混合により、溶融状となし
て、目的とするフィルム状のリボン基材11上に、公)
、口の手法に従って塗工あるいはホットメルト塗工され
る。The binder component and the pressure sensitive adhesive component constituting the pressure sensitive adhesive layer 12 are generally blended in a ratio of about 40 to 93:2 to 30, preferably less than 3000 centivoice at a temperature of 95°C. Especially 100-1000
The composition is made to have a viscosity on the order of centivoice. Also,
Such a composition is made into a liquid by dissolving or dispersing it in an appropriate solvent, or is made into a molten state by heating and mixing, and then applied onto the desired film-like ribbon substrate 11.
It is coated or hot-melt coated according to traditional methods.
一方、上記感圧接着剤層12上に形成される、トップコ
ートとしての熱転写性インク層13は、上記感圧接着剤
層12よりも、熱転写条件下において粘度が高くかつ感
熱接着性、硬度および凝集力の大きな層として構成され
ている。この熱転写性インク層13は、被転写物として
の基本シートに対する感熱転写時には、その接着力が強
くされていることによって、ぬれ性の悪い表面への感熱
転写性が向上され、凝集力、粘度、硬度が大きくされて
いるために、漬れ、広がり等の転写不良が効果的に改善
され、また印字装置のヘッドによるインクのかき寄せも
良好に防止する働きを有する。On the other hand, the heat-transferable ink layer 13 as a top coat formed on the pressure-sensitive adhesive layer 12 has a higher viscosity than the pressure-sensitive adhesive layer 12 under thermal transfer conditions, and has higher heat-sensitive adhesive properties, hardness, and It is structured as a layer with high cohesion. When thermally transferring the thermally transferable ink layer 13 to a base sheet as a transfer object, its adhesive force is strengthened, so that thermally transferable to surfaces with poor wettability is improved, and cohesive force, viscosity, Since the hardness is increased, transfer defects such as soaking and spreading can be effectively improved, and the ink can also be effectively prevented from being scraped by the head of a printing device.
また、乾式転写材の基本シートの背後から圧力を加えて
、g6転写により作製したインクの像(転写像)を第2
の被転写物に転写する感圧転写時には、かかる熱転写性
インク層13は、凝集力、硬度が大きくされているため
に、基本シートから、残留インクなく、一体となって、
所定のインク像を転写させることを可能とし、転写した
インクも広がり、もれのない美麗な像を得ることを可能
とし、また同時に自身を保護して強固なものとしている
。In addition, pressure is applied from behind the basic sheet of the dry transfer material to transfer the ink image (transfer image) created by G6 transfer to the second
At the time of pressure-sensitive transfer, the thermal transferable ink layer 13 has high cohesive force and hardness, so that it can be transferred from the basic sheet as one piece without any residual ink.
It makes it possible to transfer a predetermined ink image, and the transferred ink also spreads, making it possible to obtain a beautiful image with no leakage, and at the same time protecting itself and making it strong.
上記熱転写性インク層13は、(1)膜形成性が大きく
、iQ接着性の大きな第1の樹脂、例えば、エチレン酢
酸ビニル共重合体、ポリ酢酸ビニル、アイオノマーアク
リル系重合体、エチレン−エチルアクリレート共重合体
、エチレン−アクリル酸共重合体、塩化ビニル−酢酸ビ
ニル共重合体、ポリビニルブチラール、ポリビニルピロ
リドン、ポリビニルアルコール、ポリアミド、エチルセ
ルロース等の1種または2種以上と、
(2)凝集力が大きく、粘着付与性の第2の樹脂、例え
は、石油樹脂、ロジン、水添ロジン、ロジンエステル、
ケトン樹脂、フェノール樹脂等の1種または2種以上と
、
(3)11剤、例えば、カーボンブラック等の顔料また
は染料の1種または2種以上と、から主として構成され
る。The thermal transferable ink layer 13 is made of (1) a first resin having high film-forming properties and high iQ adhesive properties, such as ethylene-vinyl acetate copolymer, polyvinyl acetate, ionomer acrylic polymer, ethylene-ethyl acrylate; Copolymer, ethylene-acrylic acid copolymer, vinyl chloride-vinyl acetate copolymer, polyvinyl butyral, polyvinylpyrrolidone, polyvinyl alcohol, polyamide, ethyl cellulose, etc., and (2) have a large cohesive force. , a tackifying second resin, such as petroleum resin, rosin, hydrogenated rosin, rosin ester,
It is mainly composed of one or more types of ketone resins, phenolic resins, etc., and (3) one or more types of 11 agents, such as pigments or dyes such as carbon black.
上記第1の樹脂の内でも、エチレン酢酸ビニル共重合体
、ポリアミド、エチルセルロースが造膜性、感熱接着性
等の点から、より好ましく、第2の樹脂の内でも、石油
樹脂、ロジン、水添ロジン、ロジンエステルが凝集力、
粘着付与性等の点から、より好ましい。Among the first resins, ethylene-vinyl acetate copolymer, polyamide, and ethyl cellulose are more preferable from the viewpoint of film-forming properties and heat-sensitive adhesive properties, and among the second resins, petroleum resins, rosin, and hydrogenated resins are more preferable. Rosin and rosin ester have cohesive force,
More preferred from the viewpoint of tackifying properties and the like.
第1の樹脂と第2の樹脂と着色剤とは、重量基準でl:
0.5〜10:0.1〜5が好ましく、特に1:0.8
〜7:0.2〜3が性能のバラン スから好ましい。The first resin, the second resin, and the colorant are l:
0.5-10:0.1-5 is preferable, especially 1:0.8
~7: 0.2 to 3 is preferable from the viewpoint of performance balance.
尚、上記第1の樹脂は、感圧接着剤層12と非相溶性か
、相溶しても混じりがたいものであって、感圧接着剤層
12の上に感熱接着性の大きな膜を形成するものであり
、また他方の第2の樹脂は、上記第1の樹脂と感圧接着
剤層12との接着性を良好にして、凝集力、硬度、粘着
性を増し、感熱転写性を調整するために加えられるもの
である。The first resin is either incompatible with the pressure-sensitive adhesive layer 12 or difficult to mix with the pressure-sensitive adhesive layer 12, and a large heat-sensitive adhesive film is formed on the pressure-sensitive adhesive layer 12. The other second resin improves the adhesion between the first resin and the pressure-sensitive adhesive layer 12, increases cohesive force, hardness, and adhesiveness, and improves heat-sensitive transferability. It is added for adjustment.
更に、これに加えて、融点、溶融粘度、膜強度等の調節
、熱感度の向上、および糸引きを防止して、きれを良く
するため、補助成分として、■キャンデリラワックス、
カルナバワックス、ライスワックス、木ロウ等の植物系
ワックス、蜜ろう、ラノリン、鯨ろう等の動物系ワック
ス、モンタンワックス、セレシン等の鉱物系ワックス、
パラフィンワックス、マイクロクリスタリンワックス等
の石油系ワックス、ポリエチレンワックス等の合成ワッ
クス、およびα−オレフィン−無水マレイン酸共重合体
等の樹脂系ワックス、の1種または2種以上からなるワ
ックス類、■リン酸トリブチル、リン酸トリフェニル等
のリン酸エステル、フタル酸ジメチル、フタル酸ジ−n
−オクチル等のフタル酸エステル、オレイン酸ブナル等
の脂肪族−塩基酸エステル、アジピン酸ジブチル等の脂
肪族二塩基酸エステル、ジエチレングリコールジベンゾ
エ−1・等の二価アルコールエステル等、の1種または
2種以上からなる可塑剤類、■アマニ油、キリ油等の乾
性油、大豆油、綿実油、ナタネ油等の半乾性油、落花生
油、オリーブ油、ツバキ油、ヒマシ油等の不乾性油等の
植物油や動物油、パルミチン酸、ステアリン酸、オレイ
ン酸、ベヘン酸等の脂肪酸、高級アルコール、多価アル
コール等の1種または2種以上からなる油脂および/ま
たは油剤類、■陰イオン活性剤、陽イオン活性剤、非イ
オン活性剤、両性イオン活性剤等の1種または2種以上
からなる界面活性剤類、から選択された1種または2種
以上を加えてもよい。In addition, in order to adjust melting point, melt viscosity, film strength, etc., improve heat sensitivity, prevent stringiness, and improve cleanliness, as an auxiliary ingredient, Candelilla wax,
Vegetable waxes such as carnauba wax, rice wax and wood wax; animal waxes such as beeswax, lanolin and spermaceti; mineral waxes such as montan wax and ceresin;
Waxes consisting of one or more of petroleum waxes such as paraffin wax and microcrystalline wax, synthetic waxes such as polyethylene wax, and resin waxes such as α-olefin-maleic anhydride copolymer; Phosphate esters such as tributyl acid, triphenyl phosphate, dimethyl phthalate, di-n phthalate
- One or more of phthalic acid esters such as octyl, aliphatic basic acid esters such as bunal oleate, aliphatic dibasic acid esters such as dibutyl adipate, dihydric alcohol esters such as diethylene glycol dibenzoate-1, etc. Plasticizers consisting of two or more types, Drying oils such as linseed oil and tung oil, semi-drying oils such as soybean oil, cottonseed oil and rapeseed oil, non-drying oils such as peanut oil, olive oil, camellia oil and castor oil, etc. Fats and/or oils consisting of one or more types of vegetable oils, animal oils, fatty acids such as palmitic acid, stearic acid, oleic acid, behenic acid, higher alcohols, polyhydric alcohols, etc. ■Anion activators, cations One or more surfactants selected from one or more surfactants such as surfactants, nonionic surfactants, and zwitterionic surfactants may be added.
上記■乃至■の内でも、■界面活性剤類は、ぬれ性を向
上させるので、被転写物への転写性が特に良好となる。Among the above items (1) to (2), surfactants (2) improve the wettability, so that the transferability to the transferred material is particularly good.
上記第1の樹脂と第2の樹脂と着色剤との配合量の和と
、■ワックス類、■油脂および/または油剤類、■界面
活性剤類の配合量との比は、重量基準で、100:2〜
40が好ましい。後者が2未満では効果が低くなり、4
0を越えると接着力が低下する。The ratio of the sum of the amounts of the first resin, the second resin, and the colorant to the amounts of waxes, fats and/or oils, and surfactants is based on weight: 100:2~
40 is preferred. If the latter is less than 2, the effect will be low;
If it exceeds 0, the adhesive strength will decrease.
上記第1の樹脂と第2の樹脂と着色剤との配合量の和と
、■可塑剤類の配合量との比は、重量基準で、100:
2〜25が好ましい。後者が2未溝では効果が低くなり
、25を越えると接着力が低下する。The ratio of the sum of the amounts of the first resin, the second resin, and the colorant to the amount of plasticizers is 100:
2 to 25 is preferred. If the latter number of grooves is less than 2, the effect will be low, and if it exceeds 25, the adhesive force will decrease.
この様に上記補助成分は、主に第1の樹脂と第2の樹脂
と着色剤との組成からなる熱転写性インク層13の融点
、溶融粘度を調節し、熱感度を向上させ、熱転写型プリ
ンタによる転写性能を一層向上させる。In this way, the above-mentioned auxiliary components adjust the melting point and melt viscosity of the thermal transfer ink layer 13 mainly composed of the first resin, the second resin, and the colorant, improve the thermal sensitivity, and improve the thermal transfer ink layer 13. further improves transfer performance.
第1の樹脂、第2の樹脂および着色剤、所望により上記
補助成分も含めたものからなる組成物は、水溶液もしく
は水分散液の形態において、あるいは感圧接着剤層12
を侵さないような汎用の有機溶剤の溶液乃至分散液の形
態において、通常の塗工手法に従って、感圧接着剤層1
2の上に所定厚さで塗工される。この様にして形成され
る熱転写性インク層13は、感熱転写条件下において感
圧接着剤層12よりも粘度が高くされ、一般に、95℃
の温度下において3000センチポイズ以上、好ましく
は10000センチボイス以上の粘度を有する層とされ
る。The composition comprising the first resin, the second resin, the colorant, and optionally the above-mentioned auxiliary components can be prepared in the form of an aqueous solution or dispersion, or in the pressure-sensitive adhesive layer 12.
The pressure-sensitive adhesive layer 1 is applied in the form of a solution or dispersion of a general-purpose organic solvent that does not attack the
2 to a predetermined thickness. The thermal transferable ink layer 13 formed in this manner has a higher viscosity than the pressure-sensitive adhesive layer 12 under thermal transfer conditions, and generally has a viscosity of 95° C.
The layer has a viscosity of 3,000 centipoise or more, preferably 10,000 centipoise or more at a temperature of .
またこの様にして形成される熱転写性インク層1;3に
は、史にその膜強度を調節し、切れの良いシャープな印
字像を得るために、また汚れやブロッキング防止等のた
めに、カオリン、タルク、ベントナイト、酸化チタン等
の充填剤や、ステアリン酸亜鉛、ステアリン酸アルミニ
ウム等の金属石鹸のごとき有機もしくは無機の粉末を、
15重量%を越えない割合において配合することも可能
である。In addition, kaolin was used in the thermal transfer ink layers 1 and 3 formed in this way to adjust the film strength and obtain a sharp printed image, as well as to prevent stains and blocking. , fillers such as talc, bentonite, titanium oxide, and organic or inorganic powders such as metal soaps such as zinc stearate and aluminum stearate.
It is also possible to incorporate them in proportions not exceeding 15% by weight.
更に、必要に応じて感圧接着剤層12とリボン碁打11
との間に、感圧接着剤層12の接着力を調節するために
、リボン基材11に固定された、離型剤からなろ離型層
を設けてもよい。Furthermore, a pressure sensitive adhesive layer 12 and a ribbon board 11 are added as necessary.
In order to adjust the adhesive force of the pressure-sensitive adhesive layer 12, a release layer made of a release agent may be provided fixed to the ribbon base material 11 between the ribbon base material 11 and the pressure-sensitive adhesive layer 12.
このようにして得られたインクリボン10を用いて、ヘ
ッド発熱体形状、ヘッド発熱体位置、ヘッド取付角度、
ヘッド押え圧力、巻取りトルク、ヘッド印加エネルギー
、印字スピード等を調節した熱転写型プリンタにて、ぬ
れ性の悪い表面を有するフィルム上へ、所望の文字や図
形等の転写像を感熱印字すると、広がり、漬れ、濃淡、
ヘッドによるかき寄せ、糸引き、柚子肌、転写不足等の
問題を惹起することなく、良好な印字像を実現すること
ができる。Using the ink ribbon 10 obtained in this way, the shape of the head heating element, the position of the head heating element, the head mounting angle,
When a transfer image such as a desired character or figure is thermally printed on a film with a surface with poor wettability using a thermal transfer printer that adjusts the head pressure, winding torque, head application energy, printing speed, etc., it spreads. , Pickled, Thickness,
A good printed image can be realized without causing problems such as scraping by the head, stringiness, yuzu skin, and insufficient transfer.
また、このようにして印字された像を、フィルムシート
の裏側から圧力を加えて目的とする紙、プラスチックス
、金属等の被転写物上に感圧転写しても、上記フィルム
上には残留インクはなく、更に転写した像も、潰れ、広
がり、脆さのない、強固に接着した良好な像となすこと
ができる。In addition, even if the image printed in this way is pressure sensitively transferred onto the target material such as paper, plastic, metal, etc. by applying pressure from the back side of the film sheet, it will not remain on the film. There is no ink, and furthermore, the transferred image can be a good, firmly adhered image without crushing, spreading, or brittleness.
[実施例コ
以下に本発明の実施例を示すが本発明はこれに限られる
ものではなく、要旨を逸脱しない限り種々の態様を採り
得る。[Example] Examples of the present invention are shown below, but the present invention is not limited thereto, and various embodiments can be adopted without departing from the gist.
次のような感圧接着剤層用配合物と熱転写性インク層用
配合物とを調製した。The following formulations for pressure-sensitive adhesive layer and thermal transferable ink layer were prepared.
感圧接着剤層用配合−1l1皿
* ! 、/ T’ U 9−′ス
3[京油11旨Hのキャシテーリラロウ2698コ邪鈍
晶酩)陥陀花P10
ロジン上4チル
[荒用化 工業!4勾製のスーパーエステIIA−10
0]メチルイソブチルケトン 100感圧
接着剤層用配合−21童皿
3−″″′!’:1ツクス 5[京
ン由 柱噂 のhシテーリラロウ269B]ロジン
エステル 2[荒用化学工業
曲製のλ−;1°−エステJIA−100コ岑づゝブ9
4′) 2三菱化成工 ■製の
MA−7]
メチルイソブチルケトン 100熱転写性
インク層用配合−111部
石ン巾樹脂
5[東邦石油樹脂曲調のIIイ
L’l/”)tt90]カーボンブラック
1[三菱化成工業利由製のMA−7]
メチルイソブチルケトン 53熱転写性
インク層用配合−2i!!
エチルセルロース−1
[関東化学曲調の試薬10cpsl
駅呑ロジン 5荒用化学
工業曲製のハイへ’ −11]]在−ボ′ブに′)1
三菱化成工 ■製のMA−7コ
イソプロピルアルコール 53熱転写性
インク層用配合−31王郡
ポリアミド
[三不ロ化学工業件勾製のリンマイト”615Aコ″′
&′″”W畢 4[川 工業
9−$I製のケトシレシーンに一90コ福鈍晶6r11
侃ふ41デ21
キーボゝブ1晶 1三菱化成工
製のMA−7コ
イソブロピルアルコーノし 90上記
2例の感圧接着剤層用配合と上記3例の熱転写性インク
層用配合との6通りの組み合わせを用いて、3.5um
のポリエチレンテレフタレートのフィルム上に、まず感
圧接着剤層を乾燥膜厚で2〜?umとなるよう塗工形成
し、ついで熱転写性インク層を乾燥膜厚で1〜4 J4
rrtとなるよう塗工形成して、インクリボンを得た
。このインクリボンを用いて調節した感熱転与型のタイ
プライタ(ブラザーエ業■製EP43)で、シリコン樹
脂を表面に塗工した被転写物としてのポリエチレンフィ
ルム1100uの表面に印字した。Formula for pressure sensitive adhesive layer - 1l 1 dish*! , / T'U 9-'s
3 [Kyoto oil 11 effect H Cassitey Rarrow 2698 Ko evil crystal alcohol] Fallen flower P10 Rosin top 4 chill [Abusive industrial! 4-grade super esthetics IIA-10
0] Methyl isobutyl ketone 100 Pressure-sensitive adhesive layer formulation-21 Children's dish 3-'''''! ': 1 tux 5 [Kyoin Yu Hashira Rumor's H Shiteri Rarrow 269B] Rosin Ester 2 [Arayo Kagaku Kogyo Kusei's λ-; 1°-Esthetic JIA-100 Kozub 9
4') 2 MA-7 manufactured by Mitsubishi Kasei Kogyo ■ Methyl isobutyl ketone 100 Formula for thermal transferable ink layer - 111 parts Stone cloth resin
5 [Toho Sekiyu resin tune II L'l/'')tt90] Carbon black
1 [MA-7 manufactured by Mitsubishi Chemical Industries, Ltd.] Methyl isobutyl ketone 53 Formulation for thermal transferable ink layer-2i! ! Ethyl cellulose - 1 [Kanto Kagaku Kyoroku reagent 10cpsl Ekinomi rosin 5 Arayo Kagaku Kogyo Kyusei's Haihe'-11]] Zai-Bo'bu') 1 Mitsubishi Kagaku Kogyo's MA-7 coisopropyl alcohol 53 Formulation for thermal transferable ink layer - 31 Ogun polyamide [Linmite "615A" manufactured by Sanfuro Chemical Industries Co., Ltd.]
&'''”W 4
41 DE 21 Key Bob 1 Crystal 1 MA-7 coisopropyl alcohol manufactured by Mitsubishi Kasei 90 The combination of the above two examples for the pressure-sensitive adhesive layer formulation and the above three examples for the thermal transfer ink layer formulation. 3.5um using 6 combinations
First, a pressure-sensitive adhesive layer is applied to a polyethylene terephthalate film with a dry film thickness of 2 to 30%. um, and then a thermal transferable ink layer with a dry film thickness of 1 to 4 J4
An ink ribbon was obtained by coating and forming the ink ribbon. Using this ink ribbon, printing was carried out on the surface of a polyethylene film 1100u coated with silicone resin as a transfer material using a heat transfer type typewriter (EP43, manufactured by Brother Industries, Ltd.).
すべての矧合せについて、印字像は十分にきれいで良好
な品質の印字像であった。また、このポリエチレンフィ
ルムの裏から圧力を加えながら擦ることにより、ポリエ
チレンフィルム上の印字像は、第2の被転写物としての
紙、プラスチック、金属へ感圧転写し、十分良好な品質
の像が形成できた。The printed images were sufficiently clean and of good quality for all the grain alignments. In addition, by rubbing the polyethylene film while applying pressure from the back side, the printed image on the polyethylene film is pressure-sensitively transferred to the second transfer material such as paper, plastic, or metal, resulting in an image of sufficiently good quality. I was able to form it.
本発明の他の絹合せも同様な良好な結果であった。Similar good results were obtained with other silk combinations of the present invention.
尚、各感圧接着剤層用配合および各熱転写性インク層用
配合の乾燥後95℃における粘度は、感圧接着剤層用配
合では100〜1000センチボイス、熱転写性インク
層用配合では50000〜80000センチボイスであ
った。The viscosity at 95° C. after drying of each pressure-sensitive adhesive layer formulation and each thermal transferable ink layer formulation is 100 to 1000 centibois for the pressure-sensitive adhesive layer formulation, and 50000 to 50000 centibois for the thermal transfer ink layer formulation. It was an 80,000 centimeter voice.
ル較揖
熱転写性インク層用配合1,2のいずれかにてり1%転
写牲インク層を形成し、感圧接着剤層12は形成しなか
ったインクリボンおよび市販のワックスタイプの熱転写
インクリボンを用いて、実施例と同様の転写試験を行っ
たところ、感熱転写性も感圧転写性も不十分であった。An ink ribbon in which a 1% transferable ink layer was formed using either Formulation 1 or 2 for the thermal transferable ink layer, but no pressure-sensitive adhesive layer 12 was formed, and a commercially available wax-type thermal transfer ink ribbon. When a transfer test similar to that in the Examples was conducted using the same, both heat-sensitive transferability and pressure-sensitive transferability were insufficient.
具体的には、前二者は、Hat転写性に関しては、リボ
ン基材11への過剰接着力による転写性不足、印字の濃
淡、柚子肌等の問題が発生した。市販品は、接着力不足
による転写性不足、凝集力、粘度、硬度不足による転写
印字の広がり、漬れや、ヘッドによる印字のかき寄せ、
印字の濃)臥柚子肌等の問題が発生した。Specifically, with regard to the Hat transferability, the former two had problems such as insufficient transferability due to excessive adhesive force to the ribbon base material 11, print shading, and yuzu skin. Commercially available products have problems such as insufficient transferability due to insufficient adhesive strength, spreading of transferred prints due to insufficient cohesive force, viscosity, and hardness, soaking, and scraping of prints by the head.
Problems such as dark printing (darkness) occurred.
また、感圧転写性に関しては、前二者は、感圧接着力不
足による転写不足、固着力不足による最終転写印字像の
強度不足、一体転写不良で、フィルム基本シート上への
残留インクが認められる等の問題が発生した。市販品は
、感圧接着力不足による転写不足、固着力不足、凝集力
や粘度、更には硬度不足による最終転写印字像の漬れ、
広がり、強度不足、一体転写不良で、フィルム基本シー
ト上への残留インクが認められる等の問題が発生した。Regarding pressure-sensitive transferability, the former two are found to have insufficient transfer due to insufficient pressure-sensitive adhesive strength, insufficient strength of the final transferred printed image due to insufficient adhesion, and poor integral transfer, resulting in residual ink remaining on the film base sheet. Problems such as this occurred. Commercially available products suffer from insufficient transfer due to insufficient pressure-sensitive adhesive strength, insufficient adhesion, and smearing of the final transferred printed image due to insufficient cohesive force, viscosity, and even hardness.
Problems such as spreading, insufficient strength, poor integral transfer, and residual ink on the film base sheet occurred.
発夏団パ伽果
本発明は、上述のごとく、トップコート層として、感熱
接着性で、硬度、粘度、凝集力の大きい熱転写性インク
層を設け、更に、該インク層の下層として、インク層よ
り溶融粘度の低い感圧接着剤層をリボン基材との間に設
けて、2層構造とすることによ′す、ぬれ性の悪い面へ
の感熱転写性が著しく良好となるとともに、感熱転写に
より設けた印字像の、圧力による第2の被転写物への感
圧転写性も良好となる利点がある。As described above, the present invention provides a heat-sensitive adhesive, heat-transferable ink layer with high hardness, viscosity, and cohesive force as a top coat layer, and furthermore, as a lower layer of the ink layer, an ink layer. By providing a pressure-sensitive adhesive layer with a lower melt viscosity between the ribbon base material and creating a two-layer structure, thermal transfer properties to surfaces with poor wettability are significantly improved, and sensitivity is improved. There is an advantage that the pressure-sensitive transferability of the printed image provided by thermal transfer to the second transfer object by pressure is also improved.
更に熱転写性インク層にワックス等の熱感度向上成分を
加えれば、熱感度が向上し、低エネルギーでの熱転写を
可能とする。更に、エネルギーに応じた融点、溶融粘度
、膜強度等の調節を可能にし、糸引きを防止して、切れ
をよくする効果もある。Furthermore, if a heat sensitivity improving component such as wax is added to the heat transferable ink layer, the heat sensitivity will be improved and thermal transfer can be performed with low energy. Furthermore, it is possible to adjust the melting point, melt viscosity, film strength, etc. according to the energy, and it also has the effect of preventing stringiness and improving cutting.
第1図は、本発明の一実施例の乾式転写材製造用インク
リボンの一例を示す断面説明図である。
10・・・乾式転写材製造用インクリボン11・・・リ
ボン基材
12−・・感圧接着剤層
13・・・熱転写性インク層FIG. 1 is an explanatory cross-sectional view showing an example of an ink ribbon for producing a dry transfer material according to an embodiment of the present invention. 10... Ink ribbon for dry transfer material production 11... Ribbon base material 12... Pressure sensitive adhesive layer 13... Thermal transferable ink layer
Claims (1)
写材製造用インクリボンであって、フィルム状リボン基
材の片面上に設けられた感圧接着剤層と、 該感圧接着剤層上に設けられ、着色剤、感熱接着性樹脂
および粘着付与性樹脂を含んで構成された熱転写性イン
ク層と、 を備えたことを特徴とする乾式転写材製造用インクリボ
ン。[Scope of Claims] 1. An ink ribbon for producing a dry transfer material that converts a transferred object into a dry transfer material by thermal transfer, comprising a pressure-sensitive adhesive layer provided on one side of a film-like ribbon base material; An ink ribbon for producing a dry transfer material, comprising: a heat transferable ink layer provided on a pressure adhesive layer and configured to include a colorant, a heat-sensitive adhesive resin, and a tackifying resin.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP62085350A JP2605711B2 (en) | 1987-04-07 | 1987-04-07 | Ink ribbon for dry transfer material production |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP62085350A JP2605711B2 (en) | 1987-04-07 | 1987-04-07 | Ink ribbon for dry transfer material production |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS63251287A true JPS63251287A (en) | 1988-10-18 |
JP2605711B2 JP2605711B2 (en) | 1997-04-30 |
Family
ID=13856232
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP62085350A Expired - Fee Related JP2605711B2 (en) | 1987-04-07 | 1987-04-07 | Ink ribbon for dry transfer material production |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2605711B2 (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH02151486A (en) * | 1988-12-02 | 1990-06-11 | Konica Corp | Transfer recording method and thermal transfer recording medium |
US5153059A (en) * | 1990-08-20 | 1992-10-06 | Brother Kogyo Kabushiki Kaisha | Ink ribbon to be used for producing a dry transfer material |
US5154972A (en) * | 1990-10-25 | 1992-10-13 | Brother Kogyo Kabushiki Kaisha | Ink ribbon to be used for producing a dry transfer material |
US5154971A (en) * | 1990-08-07 | 1992-10-13 | Brother Kogyo Kabushiki Kaisha | Ink ribbon to be used for producing a dry transfer material |
US5326622A (en) * | 1989-10-27 | 1994-07-05 | Brother Kogyo Kabushiki Kaisha | Heat transferable inked ribbon |
WO2006009198A1 (en) | 2004-07-23 | 2006-01-26 | Asahi Kasei Life & Living Corporation | Propylene-based multilayered wrapping film |
CN114771123A (en) * | 2022-04-13 | 2022-07-22 | 广州倾松数码科技有限公司 | Preparation method and application of environment-friendly preset scraping cold transfer printing film |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60127191A (en) * | 1983-12-14 | 1985-07-06 | Konishiroku Photo Ind Co Ltd | Thermal transfer recording medium |
-
1987
- 1987-04-07 JP JP62085350A patent/JP2605711B2/en not_active Expired - Fee Related
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60127191A (en) * | 1983-12-14 | 1985-07-06 | Konishiroku Photo Ind Co Ltd | Thermal transfer recording medium |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH02151486A (en) * | 1988-12-02 | 1990-06-11 | Konica Corp | Transfer recording method and thermal transfer recording medium |
US5326622A (en) * | 1989-10-27 | 1994-07-05 | Brother Kogyo Kabushiki Kaisha | Heat transferable inked ribbon |
US5154971A (en) * | 1990-08-07 | 1992-10-13 | Brother Kogyo Kabushiki Kaisha | Ink ribbon to be used for producing a dry transfer material |
US5153059A (en) * | 1990-08-20 | 1992-10-06 | Brother Kogyo Kabushiki Kaisha | Ink ribbon to be used for producing a dry transfer material |
US5154972A (en) * | 1990-10-25 | 1992-10-13 | Brother Kogyo Kabushiki Kaisha | Ink ribbon to be used for producing a dry transfer material |
WO2006009198A1 (en) | 2004-07-23 | 2006-01-26 | Asahi Kasei Life & Living Corporation | Propylene-based multilayered wrapping film |
JP4832301B2 (en) * | 2004-07-23 | 2011-12-07 | 旭化成ケミカルズ株式会社 | Propylene-based multilayer wrap film |
CN114771123A (en) * | 2022-04-13 | 2022-07-22 | 广州倾松数码科技有限公司 | Preparation method and application of environment-friendly preset scraping cold transfer printing film |
CN114771123B (en) * | 2022-04-13 | 2023-10-27 | 广州倾松数码科技有限公司 | Preparation method of environment-friendly preset scratch-off cold transfer film |
Also Published As
Publication number | Publication date |
---|---|
JP2605711B2 (en) | 1997-04-30 |
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