JPS63182203A - Solid agent for generating oxygen - Google Patents
Solid agent for generating oxygenInfo
- Publication number
- JPS63182203A JPS63182203A JP1457587A JP1457587A JPS63182203A JP S63182203 A JPS63182203 A JP S63182203A JP 1457587 A JP1457587 A JP 1457587A JP 1457587 A JP1457587 A JP 1457587A JP S63182203 A JPS63182203 A JP S63182203A
- Authority
- JP
- Japan
- Prior art keywords
- oxygen
- solid agent
- agent
- water
- peroxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 55
- 239000007787 solid Substances 0.000 title claims abstract description 49
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims abstract description 36
- 239000001301 oxygen Substances 0.000 title claims abstract description 36
- 229910052760 oxygen Inorganic materials 0.000 title claims abstract description 36
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 42
- 150000002978 peroxides Chemical class 0.000 claims abstract description 15
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000010439 graphite Substances 0.000 claims abstract description 13
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 13
- 230000003472 neutralizing effect Effects 0.000 claims abstract description 10
- 239000000203 mixture Substances 0.000 claims abstract description 8
- 239000003054 catalyst Substances 0.000 claims abstract description 6
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 claims abstract description 6
- ZJRXSAYFZMGQFP-UHFFFAOYSA-N barium peroxide Chemical compound [Ba+2].[O-][O-] ZJRXSAYFZMGQFP-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000010440 gypsum Substances 0.000 claims abstract description 3
- 229910052602 gypsum Inorganic materials 0.000 claims abstract description 3
- 239000004343 Calcium peroxide Substances 0.000 claims abstract 2
- LHJQIRIGXXHNLA-UHFFFAOYSA-N calcium peroxide Chemical compound [Ca+2].[O-][O-] LHJQIRIGXXHNLA-UHFFFAOYSA-N 0.000 claims abstract 2
- 235000019402 calcium peroxide Nutrition 0.000 claims abstract 2
- 241000894006 Bacteria Species 0.000 claims description 12
- 230000000243 photosynthetic effect Effects 0.000 claims description 12
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 claims description 6
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 claims description 4
- 235000019359 magnesium stearate Nutrition 0.000 claims description 3
- FUFJGUQYACFECW-UHFFFAOYSA-L calcium hydrogenphosphate Chemical group [Ca+2].OP([O-])([O-])=O FUFJGUQYACFECW-UHFFFAOYSA-L 0.000 claims description 2
- 235000010288 sodium nitrite Nutrition 0.000 claims description 2
- 241000251468 Actinopterygii Species 0.000 abstract description 17
- 238000006243 chemical reaction Methods 0.000 abstract description 6
- 239000000126 substance Substances 0.000 abstract description 4
- 238000011084 recovery Methods 0.000 abstract description 2
- 239000007795 chemical reaction product Substances 0.000 abstract 2
- YYRMJZQKEFZXMX-UHFFFAOYSA-L calcium bis(dihydrogenphosphate) Chemical compound [Ca+2].OP(O)([O-])=O.OP(O)([O-])=O YYRMJZQKEFZXMX-UHFFFAOYSA-L 0.000 abstract 1
- 230000001131 transforming effect Effects 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 8
- 238000000465 moulding Methods 0.000 description 7
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 239000011575 calcium Substances 0.000 description 4
- 239000001569 carbon dioxide Substances 0.000 description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 230000005484 gravity Effects 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 241000252233 Cyprinus carpio Species 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- 241000233866 Fungi Species 0.000 description 2
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 241000223218 Fusarium Species 0.000 description 1
- 102000001554 Hemoglobins Human genes 0.000 description 1
- 108010054147 Hemoglobins Proteins 0.000 description 1
- 206010021143 Hypoxia Diseases 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- ONIBWKKTOPOVIA-UHFFFAOYSA-N Proline Natural products OC(=O)C1CCCN1 ONIBWKKTOPOVIA-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 208000006673 asthma Diseases 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 206010006451 bronchitis Diseases 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000000122 growth hormone Substances 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- -1 llows Species 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000002934 lysing effect Effects 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 238000009335 monocropping Methods 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000000384 rearing effect Effects 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 238000002560 therapeutic procedure Methods 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Oxygen, Ozone, And Oxides In General (AREA)
- Farming Of Fish And Shellfish (AREA)
- Fodder In General (AREA)
- Feed For Specific Animals (AREA)
Abstract
Description
【発明の詳細な説明】
産 土の１
本発明は、水との接触によって酸素を発生する酸素発生
固形剤に関するものである。DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to an oxygen-generating solid agent that generates oxygen upon contact with water.
ｌ米ｌ工
過酸化物をアスベストなどと共に加圧成形した酸素発生
固形剤が、特開昭５５−１３６１０２号公報、特開昭５
５−１２６５０３号公報及び特開昭５４−３５８８７号
公報などにより知られているが、これらは、酸素発生の
ために着火するなど外部よりエネルギーの付与が必要で
ある。更に、これらは、落盤事故、火災等において起こ
る酸欠防止のための救急医療を主目的に発明されたもの
であるため、酸素を短時間に多量発生させるべく構成さ
れており、魚類や植物の生育などに使用できるものでは
なかった。An oxygen-generating solid agent prepared by pressure molding a peroxide with asbestos, etc. is disclosed in Japanese Patent Application Laid-open No. 55-136102 and Japanese Patent Application Laid-open No. 55-136102.
These are known from Japanese Patent Application Laid-open No. 5-126503 and Japanese Patent Application Laid-open No. 54-35887, but these require external energy such as ignition to generate oxygen. Furthermore, since these devices were invented primarily for the purpose of emergency medical care to prevent oxygen deficiency caused by cave-in accidents, fires, etc., they are designed to generate a large amount of oxygen in a short period of time, and are useful for fish and plants. It could not be used for growing purposes.
また、過酸化物を水溶性樹脂で固形化したり、カプセル
化して、水と接触させて使用する酸素発生固形剤も特開
昭５７−１６０９０２号公報や特開昭５４−２０９８７
号公報などにより知られているが、これらも前述のもの
と同様に緊急時の酸素供給を目的とするものであって、
水との接触によって、急激に酸素が発生するが、その持
続性を求めることはできない、更に、これらは水中で崩
壊（樹脂が溶解し、薬剤が水中に分散する）し、水質を
７弓染するため、魚類や植物の生育などに使用できるも
のではなかった。Additionally, oxygen-generating solid agents that are used by solidifying or encapsulating peroxide with a water-soluble resin and bringing it into contact with water are disclosed in JP-A-57-160902 and JP-A-54-20987.
These are known from publications such as the above, but like the ones mentioned above, these are also aimed at supplying oxygen in emergencies.
Oxygen is rapidly generated by contact with water, but its sustainability cannot be determined.Furthermore, oxygen disintegrates in water (resin dissolves and chemicals disperse in water), causing water quality to deteriorate. Therefore, it could not be used for growing fish or plants.
１）立ｌ鯉
本発明では、特別なエネルギーを付与しなくても、水と
接触するだけで、酸素を持続性よく発生し、しかも水質
を汚染することなく、魚類や植物の生育などにも使用で
きる酸素発生固形剤を提供することを目的とする。1) Standing carp In the present invention, the carp can sustainably generate oxygen just by contacting water without applying special energy, and it does not pollute the water quality and is good for the growth of fish and plants. It is an object of the present invention to provide an oxygen-generating solid agent that can be used.
ｌユ立ｌ基
本発明の薬剤は、無機過酸化物を、中和剤及び触媒と共
に、低密度膨張黒鉛に混入し、固形化してなるものであ
る。The chemical agent of the basic invention is obtained by mixing an inorganic peroxide with a neutralizing agent and a catalyst into low-density expanded graphite and solidifying the mixture.
本発明では、水と反応して酸素を発生する無機過酸化物
、例えば過酸化バリウム及び過酸化力ルシェウムなどを
、低密度膨張黒鉛（一般に比重０゜１以下、好ましくは
比重０．０１に発泡膨張させたグラファイト）を固形化
媒体として使用し、加圧成形することによって、水に投
入しても原形を安定して保持する固形物の薬剤として提
供可能としたものである。低密度膨張黒鉛は適度の空隙
をもって固形化されるため、無機過酸化物と水は徐々に
連続して反応し、しかも完全に効率よく反応する。過酸
化力ルシュウム及び過酸化バリュウムを使用した場合の
反応は次式の通りである。In the present invention, an inorganic peroxide that reacts with water to generate oxygen, such as barium peroxide and lucium peroxide, is mixed with low-density expanded graphite (generally foamed to a specific gravity of 0°1 or less, preferably 0.01). By using expanded graphite as a solidification medium and press-molding it, it is possible to provide a solid drug that stably retains its original shape even when placed in water. Since low-density expanded graphite is solidified with appropriate voids, the inorganic peroxide and water react gradually and continuously, and moreover, completely and efficiently. The reaction when lucium peroxide and barium peroxide are used is as shown in the following equation.
Ｃａ０ｚ十ＨｚＯ−すＣａ（ＯＨ）ｔ ＋ ＡＯｚ
ｆｌ）Ｂａｉｔ ＋ ＨｚＯ−一→Ｂａ（Ｏ
Ｈ）ｔ ８Ｈ２Ｏ＋ ＡＯｚ （２１このような反
応では、酸素発生と同時に強アルカリ性物質を生ずるの
で、その中和剤を無機過酸化物と共に固形物に含有させ
るが、中和剤は一触に無機過酸化物に対して等モル以上
使用されるのが好ましい、中和剤としては第一燐酸カル
シュウムＣａ（ＨｔＰＯｔ）ｔＨｚｏ 、焼石膏Ｃａ５
Ｏ＃ｚＨｚＯを使用する場合、これらは、次式に示す通
り作用し、反応系の中和、解毒、ｐＨＪ整をする。Ca0z 1HzO-suCa(OH)t + AOz
fl) Bait + HzO−1→Ba(O
H) t 8H2O+ AOz (21 In such a reaction, a strong alkaline substance is generated at the same time as oxygen is generated, so the neutralizing agent is contained in the solid material together with the inorganic peroxide, but the neutralizing agent is immediately mixed with the inorganic peroxide. Neutralizing agents that are preferably used in an amount equal to or more than the same mole relative to the oxide include calcium monophosphate Ca (HtPOt)tHzo, calcined gypsum Ca5
When O#zHzO is used, these act as shown in the following formula to neutralize, detoxify, and adjust pHJ of the reaction system.
２Ｃａ（ＯＨ） ！ ＋ Ｃａ（ＨｚＰＯａ） ｚＨｔ
ｏ−→Ｃａｓ （ＰＯ４） ｔ ” ５８ｚＯ（３１２
Ｂａ（ＯＨ）ｔ８ＨｚＯ＋ Ｃａ（ＨｚＰＯａ）ｚＨｚ
ｏ ＋ ２ＣａＳＯａＶＳＨｚＯ２ＢａＳＯｔ２Ｈ１０
＋ Ｃａｘ （ＰＯ４）！ ＋１８１）ｚＯ（４１反応
生成するＢａ５Ｏａ２ＨｔＯ、Ｃａ３ＣＰＯａ＞ｚは共
に水に難溶性物質である。2Ca(OH)! + Ca(HzPOa) zHt
o-→Cas (PO4) t” 58zO(312
Ba(OH)t8HzO+ Ca(HzPOa)zHz
o + 2CaSOaVSHzO2BaSOt2H10
+ Cax (PO4)! +181) zO (41 Both Ba5Oa2HtO and Ca3CPOa>z produced by the reaction are poorly soluble substances in water.
また、本発明では、＋１） （２１の反応を速やかにす
るために、触媒、例えば二酸化マンガンを酸素発生固形
剤に含をさせるが、更に該酸素発生固形剤を反応させる
水が水道水である場合など、水中の塩素を除去するため
に亜硝酸ソーダを併合させてもよい。In addition, in the present invention, +1) (In order to speed up the reaction of 21, a catalyst such as manganese dioxide is added to the oxygen-generating solid agent, and the water in which the oxygen-generating solid agent is reacted is tap water. In some cases, sodium nitrite may be incorporated to remove chlorine from the water.
無機過酸化物と低密度膨張黒鉛の使用割合は、加圧成形
によって固形化可能な範囲であればよく、後者の膨張の
程度によって異なる。The ratio of the inorganic peroxide to the low-density expanded graphite may be within a range that can be solidified by pressure molding, and varies depending on the degree of expansion of the latter.
なお、本発明の固形剤は、固形剤の成形性を高めるため
に、離型剤であるステアリン酸マグネシウムを含有して
もよ（、また、固形剤への水の浸透性を高め、更に、そ
の使用時の水中での溶存酸素の安定性を高める目的で、
光合成細菌（日本土壌肥料科学雑誌第４６巻第３号第１
０１〜１５６頁参照）を含有してもよい。In addition, the solid agent of the present invention may contain magnesium stearate as a mold release agent in order to improve the moldability of the solid agent (also, to increase the permeability of water into the solid agent, For the purpose of increasing the stability of dissolved oxygen in water during its use,
Photosynthetic bacteria (Japanese Journal of Soil and Fertilizer Science, Vol. 46, No. 3, No. 1)
(see pages 01 to 156).
低密度膨張黒鉛は、このような添加物を併合しても、加
圧成形によって、水中でも安定な固形剤の形成を可能と
する。Low-density expanded graphite allows the formation of a stable solid agent even in water by pressure molding, even with the incorporation of such additives.
従って、本発明では、使用後（酸素発生後）、固形剤を
原形の状態で、水中より容易に取り出すことが可能であ
り、水質を汚染することはない。Therefore, in the present invention, after use (after oxygen generation), the solid agent can be easily taken out of the water in its original form without contaminating the water quality.
次に、本発明における光合成細菌添加の効果について簡
単に述べる。Next, the effects of adding photosynthetic bacteria in the present invention will be briefly described.
本発明による酸素発生固形剤は魚類、植物の生存に必要
なる酸素供給用として特に宵月であるが、魚類及び植物
は水に溶存する酸素を採り、その生命を維持している。The oxygen-generating solid agent according to the present invention is particularly useful for supplying oxygen necessary for the survival of fish and plants, and fish and plants maintain their lives by absorbing oxygen dissolved in water.
弐ｆｌｌ ＋２１に示した如く本発明による酸素発生固
形剤は水と接触してはじめて反応が起こり酸素を発生す
るものであるから、酸素発生固形剤と水との接触面積、
固形剤に水の進入が容易にするための固形剤の空隙量が
最も重要なる要素である。空隙量は、加圧成形時の荷重
、原料粉体の粒度も重要な因子であるが、固形剤中に水
は容易に溶け、固形剤の空隙量を増大することにより水
の進入を容易とするため、光合成細菌を配合するのが好
ましい。As shown in 2fl +21, since the oxygen-generating solid agent according to the present invention reacts and generates oxygen only when it comes into contact with water, the contact area between the oxygen-generating solid agent and water,
The most important factor is the amount of pores in the solid agent so that water can easily enter the solid agent. The load during pressure molding and the particle size of the raw material powder are important factors for the amount of voids, but water easily dissolves in the solid agent, and increasing the amount of voids in the solid agent makes it easier for water to enter. Therefore, it is preferable to incorporate photosynthetic bacteria.
光合成細菌は水圏微生物の一種で２０億年以上も昔、ま
だ地球上に酸素が存在しない頃から活動してきた微生物
で自然水界において嫌気層、アンモニア、硫化水素等の
有害物質が存在し、生物が棲めない世界の上部に浮遊し
、硫化水素、二酸化炭素、アンモニアを他の化合物に変
換しながら栄養源を摂取して生きている微生物で、光の
殆どない時でも、わずかな光を利用して炭酸ガスと有機
物から炭酸固定を行いｐＨをアルカリ性に維持する働き
をする他、水中のアンモニヤ態窒素の除去、亜硝酸、硝
酸の脱窒素による除去という窒素固定、脱窒素効果の両
機能をもっているので、魚類の排泄物、老廃物、残餌に
よるアンモニヤ、亜硝酸などによる水質の悪化を防止す
る働きをする。更に、光合成細菌はタンパク源と活性ビ
タミンが豊富なので魚類の成長促進に驚くべき効果を発
揮し、添加した水中では、魚類の体力や水質の向上によ
り魚類の病気にかかる比率が下がるばかりでなく、水中
の糸状菌をはじめとする病原性細菌を抑制する働きがあ
る。また、植物に対しては作物の成長促進成長ホルモン
（ウラシルシトシン、プロリン）を含有する。病原性糸
状菌の増殖抑制（フザリュウム菌を溶菌）、長期保存性
及び鮮度持続効力増大、連作障害の防除等の効果がある
。光合成細菌を含有する酸素発生固形剤を水に投入する
と、他のエネルギーを与えることなく、水と反応し、酸
素を長時間発生し続ける。固形剤中の光合成細菌が水中
に溶出し、固形剤中の空隙量が増大し、水の固形剤への
浸入が容易となり、酸素発生の効果も倍増し、溶出光合
成細菌による魚類植物に対する前述の如き効果が得られ
る。Photosynthetic bacteria are a type of aquatic microorganisms that have been active for more than 2 billion years, when there was no oxygen on Earth. It is a microorganism that floats above the world where it cannot live, and lives by ingesting nutrients while converting hydrogen sulfide, carbon dioxide, and ammonia into other compounds, and makes use of small amounts of light even when there is almost no light. In addition to fixing carbon dioxide from carbon dioxide gas and organic matter and maintaining the pH at an alkaline level, it also has the functions of both nitrogen fixation and denitrification, such as removing ammonia nitrogen from water and removing nitrite and nitric acid by denitrification. It works to prevent water quality from deteriorating due to fish excrement, waste products, ammonia and nitrite caused by leftover feed. In addition, photosynthetic bacteria are rich in protein sources and active vitamins, so they have an amazing effect on promoting the growth of fish, and when added to the water, they not only improve the physical strength and water quality of fish, but also reduce the proportion of fish that get sick. It has the ability to suppress pathogenic bacteria such as filamentous fungi in water. Also, for plants, it contains growth hormones (uracilcytosine, proline) that promote crop growth. It has effects such as inhibiting the growth of pathogenic filamentous fungi (lysing Fusarium fungi), increasing long-term storage and freshness-sustaining effects, and controlling continuous cropping disorders. When an oxygen-generating solid agent containing photosynthetic bacteria is added to water, it reacts with the water and continues to generate oxygen for a long time without providing any other energy. Photosynthetic bacteria in the solid agent elute into water, increasing the amount of voids in the solid agent, making it easier for water to penetrate into the solid agent, and doubling the effect of oxygen generation. A similar effect can be obtained.
従って、光合成細菌を併合する本発明の酸素発生固形剤
は、水中への添加によって、魚類植物の棲息に必要なる
酸素を効率よく供給すると同時に、水質を保全し、魚類
植物に栄養を与え、成長促進を図るなどという数多（の
効果を発揮する。Therefore, when added to water, the oxygen-generating solid agent of the present invention that incorporates photosynthetic bacteria efficiently supplies the oxygen necessary for fish plants to live, preserves water quality, nourishes fish plants, and allows them to grow. It has many (effects) such as promoting.
なお、本発明の固形剤の使用による単位時間当たりの酸
素発生量は、温度の上昇に従い増加する。Note that the amount of oxygen generated per unit time by using the solid agent of the present invention increases as the temperature rises.
実施例１
Ｂａｆｔ ３４．６６χＣａ（ｌ
ｌｔＰＯ，）ｚＨＪ ２５．６３χＣａ５Ｏａ
’Ａ ＨＪ ２９．７３χＭｎＯ！
５．１９χ低密度膨張黒鉛
（比重０．０３） ４．７６χ
ＮａＮ０ｚ Ｏ，０３χ
上記成分からなる配合物に対して５％以下の光合成細菌
を均一に混合し、金型に移し、４００〜６００にｇ／ｃ
１）２にて加圧成形した。Example 1 Baft 34.66χCa(l
ltPO,)zHJ 25.63χCa5Oa
'A HJ 29.73χMnO!
5.19χ Low-density expanded graphite (specific gravity 0.03) 4.76χ NaN0z O,03χ 5% or less of photosynthetic bacteria is uniformly mixed with the formulation consisting of the above components, transferred to a mold, and heated to 400 to 600 g/c
1) Pressure molding was performed in step 2.
実施例２
Ｃａｒｔ ３２．９９χ
Ｃａ（ＨｚＰＯ，ａ）ｚｔｌｔｏ ５７．２９χＭｎ
０１ ４．９４χ
低密度膨張黒鉛
（比重０．０３） ４．７６χ
ＮａＮ０ｚ Ｏ，０２χ
上記成分からなる配合物に対して５％以下の光合成細菌
を均一に混合し、金型に移し、４００〜６００ Ｋｇ／
ａｍ”にて加圧成形した。Example 2 Cart 32.99χ Ca(HzPO,a)ztlto 57.29χMn
01 4.94χ Low-density expanded graphite (specific gravity 0.03) 4.76χ NaN0z O,02χ Mix 5% or less of photosynthetic bacteria uniformly with the formulation consisting of the above ingredients, transfer it to a mold, Kg/
Pressure molding was carried out at "am".
実施例３
実施例１の成分と実施例２の成分を同量混合し、その配
合物に対して５％以下の光合成細菌を均一に混合し、金
型に移し、４００〜６００Ｋｇ／ｃｍ”にて加圧成形し
た。Example 3 The components of Example 1 and the components of Example 2 were mixed in equal amounts, and 5% or less of photosynthetic bacteria was evenly mixed with the mixture, transferred to a mold, and molded to 400 to 600 kg/cm. It was then pressure molded.
実施例１〜３で得られた固形剤（５０ｇ ）をそれぞれ
、熱帯魚の飼育槽（２０βの水槽）に投入したところ、
約４８時間連続して酸素の発生が認められた。１日おき
に、固形剤を新しいものに取り替えて、熱帯魚の飼育を
′１ａｙＥシたところ、いずれの固形剤を使用した場合
にも、常法に従ってポンプにより空気導入する水槽に比
較して、同等以上の熱帯魚の成長が認められた。When the solid preparations (50 g) obtained in Examples 1 to 3 were respectively put into a tropical fish breeding tank (20β aquarium),
Oxygen generation was observed continuously for about 48 hours. When we reared tropical fish for 1 day by replacing the solid agent with a new one every other day, no matter which solid agent was used, the results were the same as in an aquarium in which air was introduced using a pump according to the conventional method. Growth of tropical fish was observed.
なお、実施例１〜３の成分に更にステアリン酸マグネシ
ュウムを少量添加使用した場合、離型性よく安定した形
状の固形剤を得ることができた。In addition, when a small amount of magnesium stearate was added to the components of Examples 1 to 3, a solid agent having a stable shape with good mold releasability could be obtained.
発明の効果
本発明の酸素発生固形剤は、特別なエネルギーを必要と
することなく、水との接触で持続性よく安定して酸素を
発生するので、所望時にＰＪ ＪＩＬに使用できる。携
帯が容易である。Effects of the Invention The oxygen-generating solid agent of the present invention does not require special energy and can stably generate oxygen in a sustained manner upon contact with water, so it can be used for PJ JIL whenever desired. Easy to carry.
更に、本発明の酸素発生固形剤は、使用後すなわち酸素
発生後も、水中で安定して原形を保つため、水を汚染す
ることなく除去し易い。Furthermore, the oxygen-generating solid agent of the present invention stably maintains its original shape in water even after use, that is, after oxygen generation, and therefore can be easily removed without contaminating the water.
従って、本発明の酸素発生固形剤は、例えば、魚類の輸
送、魚類の水槽での飼育、釣餌の寿命の延長、植物の発
芽育成、切花の寿命延長、激しいスポーツ、受験勉強、
会議などの後の疲労回復（疲労により血液中のヘモグロ
ビンが減少し、乳酸が増加するが、この回復には酸素供
給が必要である）、ぜんそくや気管支炎患者の在宅療法
などに非常に有用なものである。なお、本発明の酸素発
生固形剤を使用して内燃機関等の燃焼効率を上昇させ、
ノックを少なくすることもできる。Therefore, the oxygen-generating solid agent of the present invention can be used, for example, for transporting fish, rearing fish in aquariums, extending the lifespan of fishing bait, germinating and growing plants, extending the lifespan of cut flowers, strenuous sports, studying for entrance exams, etc.
It is very useful for recovering from fatigue after meetings (fatigue reduces hemoglobin in the blood and increases lactic acid, but oxygen supply is necessary for this recovery), and for home therapy for patients with asthma and bronchitis. It is something. In addition, the oxygen generating solid agent of the present invention can be used to increase the combustion efficiency of internal combustion engines, etc.
You can also reduce knocking.
Claims (8)
膨張黒鉛に混入し、固形化してなることを特徴とする水
との接触によって酸素を発生する酸素発生固形剤。(1) An oxygen-generating solid agent that generates oxygen upon contact with water, which is made by mixing an inorganic peroxide with a neutralizing agent and a catalyst into low-density expanded graphite and solidifying the mixture.
ルシュウムの少なくとも一種を使用する特許請求の範囲
第１項記載の酸素発生固形剤。(2) The oxygen generating solid agent according to claim 1, wherein at least one of barium peroxide and calcium peroxide is used as the inorganic peroxide.
する特許請求の範囲第１項記載の酸素発生固形物。(3) The oxygen-generating solid according to claim 1, wherein a neutralizing agent is used in an amount equal to or more than the mole of the inorganic peroxide.
特許請求の範囲第３項記載の酸素発生固形剤。(4) The oxygen generating solid agent according to claim 3, wherein the neutralizing agent is calcium monophosphate or calcined gypsum.
項〜第４項いずれか１項記載の酸素発生固形剤。(5) Claim 1 in which the catalyst is manganese dioxide
The oxygen-generating solid agent according to any one of Items 1 to 4.
第５項いずれか１項記載の酸素発生固形剤。(6) Claims 1-- containing sodium nitrite
The oxygen generating solid agent according to any one of Item 5.
範囲第１項〜第６項いずれか１項記載の酸素発生固形剤
。(7) The oxygen-generating solid agent according to any one of claims 1 to 6, which contains magnesium stearate.
７項いずれか１項記載の酸素発生固形剤。(8) The oxygen-generating solid agent according to any one of claims 1 to 7, which contains photosynthetic bacteria.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1457587A JPS63182203A (en) | 1987-01-23 | 1987-01-23 | Solid agent for generating oxygen |
| CN 88100398 CN88100398A (en) | 1987-01-23 | 1988-01-23 | Oxygenous solid agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1457587A JPS63182203A (en) | 1987-01-23 | 1987-01-23 | Solid agent for generating oxygen |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63182203A true JPS63182203A (en) | 1988-07-27 |
| JPH0432001B2 JPH0432001B2 (en) | 1992-05-28 |
Family
ID=11864960
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1457587A Granted JPS63182203A (en) | 1987-01-23 | 1987-01-23 | Solid agent for generating oxygen |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JPS63182203A (en) |
| CN (1) | CN88100398A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6465001A (en) * | 1987-09-05 | 1989-03-10 | Nippon Sanken Kk | Oxygen feeding agent composition |
| JPH01138104A (en) * | 1987-11-25 | 1989-05-31 | Meiwa Kouyu Kk | Oxygen generation agent |
| JPH02296702A (en) * | 1989-05-10 | 1990-12-07 | Hoshiko Riyouka Kenkyusho:Kk | Generation of oxygen |
| JPH05319805A (en) * | 1992-05-20 | 1993-12-03 | Miton House:Kk | Oxygen generation type plant nutrient |
| EP0905086A3 (en) * | 1997-09-26 | 2003-12-03 | Mitsubishi Gas Chemical Company, Inc. | Oxygen generating materials, carbon dioxide absorbing materials, and transport method of live fishery products |
| JP2010071090A (en) * | 2008-09-16 | 2010-04-02 | Kubota Corp | Valve gear for engine |
| CN112674001A (en) * | 2020-12-21 | 2021-04-20 | 中国药科大学 | Composite tablet with function of slowly releasing oxygen, preparation method and application |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102144379B1 (en) * | 2013-03-25 | 2020-08-13 | 다테호 가가쿠 고교 가부시키가이샤 | Solid oxygen-generating composition |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60176904A (en) * | 1984-02-20 | 1985-09-11 | Nishi Akizo | Solid agent for generating oxygen, and its preparation |
| JPS6177605A (en) * | 1984-09-21 | 1986-04-21 | Daiichi Sangyo Kk | Oxygen generating pellet |
-
1987
- 1987-01-23 JP JP1457587A patent/JPS63182203A/en active Granted
-
1988
- 1988-01-23 CN CN 88100398 patent/CN88100398A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60176904A (en) * | 1984-02-20 | 1985-09-11 | Nishi Akizo | Solid agent for generating oxygen, and its preparation |
| JPS6177605A (en) * | 1984-09-21 | 1986-04-21 | Daiichi Sangyo Kk | Oxygen generating pellet |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6465001A (en) * | 1987-09-05 | 1989-03-10 | Nippon Sanken Kk | Oxygen feeding agent composition |
| JPH0446881B2 (en) * | 1987-09-05 | 1992-07-31 | Nippon Sanken Kk | |
| JPH01138104A (en) * | 1987-11-25 | 1989-05-31 | Meiwa Kouyu Kk | Oxygen generation agent |
| JPH02296702A (en) * | 1989-05-10 | 1990-12-07 | Hoshiko Riyouka Kenkyusho:Kk | Generation of oxygen |
| JPH05319805A (en) * | 1992-05-20 | 1993-12-03 | Miton House:Kk | Oxygen generation type plant nutrient |
| EP0905086A3 (en) * | 1997-09-26 | 2003-12-03 | Mitsubishi Gas Chemical Company, Inc. | Oxygen generating materials, carbon dioxide absorbing materials, and transport method of live fishery products |
| JP2010071090A (en) * | 2008-09-16 | 2010-04-02 | Kubota Corp | Valve gear for engine |
| CN112674001A (en) * | 2020-12-21 | 2021-04-20 | 中国药科大学 | Composite tablet with function of slowly releasing oxygen, preparation method and application |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0432001B2 (en) | 1992-05-28 |
| CN88100398A (en) | 1988-08-03 |
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