JPS61103401A - Spike shoes sole and its production - Google Patents

Spike shoes sole and its production

Info

Publication number
JPS61103401A
JPS61103401A JP22606784A JP22606784A JPS61103401A JP S61103401 A JPS61103401 A JP S61103401A JP 22606784 A JP22606784 A JP 22606784A JP 22606784 A JP22606784 A JP 22606784A JP S61103401 A JPS61103401 A JP S61103401A
Authority
JP
Japan
Prior art keywords
sole
tread
foam
density
heel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP22606784A
Other languages
Japanese (ja)
Other versions
JPH0376121B2 (en
Inventor
孝重 八木
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toyo Tire Corp
Original Assignee
Toyo Tire and Rubber Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toyo Tire and Rubber Co Ltd filed Critical Toyo Tire and Rubber Co Ltd
Priority to JP22606784A priority Critical patent/JPS61103401A/en
Publication of JPS61103401A publication Critical patent/JPS61103401A/en
Publication of JPH0376121B2 publication Critical patent/JPH0376121B2/ja
Granted legal-status Critical Current

Links

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 (産業上の利用分野) この発明は、スポーツシューズ、特にゴルフシューズの
発泡下底の踵部、ふまず部、踏面部の発泡密度を変えて
良好な履用感を形成すると共に踏面部のスパイクの局部
における足裏に対する突き上げを防止し且つスパイクの
安定度等を改良したスパイクシコーズ底とその製法に関
づ′イ)ものである。
[Detailed Description of the Invention] (Industrial Application Field) This invention provides a good wearing feeling by changing the foam density of the heel, foot, and tread of the foamed bottom sole of sports shoes, especially golf shoes. The present invention relates to a spike sole that prevents the spikes of the tread portion from pushing up against the sole of the foot in local areas and improves the stability of the spikes, and a method for manufacturing the same.

〔従来の技術〕[Conventional technology]

従来のゴルフシューズ底は、スパイク部と、その仙の部
分とは、スパイクの嵌合金具の埋設の有無の相違の外は
、同−構造並びに同一物性の底部を構成しているもので
ある。従って、履用感が悪く疲労性も大ぎく、特に、踏
面部のスパイクの突き上げに対する抵抗が弱く、履用感
を著しく阻害しているものであった。
In the conventional golf shoe sole, the spike part and its base part constitute a bottom part having the same structure and the same physical properties, except for the presence or absence of embedded fittings for the spike. Therefore, the wearing feeling is poor and fatigue is high, and in particular, the resistance against pushing up of the spikes on the tread portion is weak, which significantly impairs the wearing feeling.

〔発明が解決しようと1−る問題点〕 上記の従来の欠陥を改良し且つより好適な履用感の得ら
れるスパイクシコーズ底を得るため、特に、外底に内接
する下底(ミツドソール、開底)に、ポリビニルアセタ
ールやポリウレタンエラストマー等のプラスチック系ま
たはゴム系の発泡体111、      を使用し、最
も体重の掛かる踵部に適正なりッション性を与え、下底
踵部から下底ふまず部、下底踏面部に向って、発泡体の
密度を増大するように密度差を構成し、特にスパイクの
突き上げの影響を最も受りやすい踏面部の密度を大きく
する必要があり、さらに、外底のスパイクの位置の上部
の発泡密度を、周囲の下底踏面部の発泡密度より人きく
して、スパイクの突き上げに対する抵抗を大きくする必
要がある。また、発泡体の下底と、ポリウレタンや熱可
塑性プラスチックやゴム系等の硬度の高い外底との組合
せにおいて、スパイクのより安定度を高めるために嵌合
構成が必要であり、さらに、外底には、スパイクによる
嵌合金具の突き上げに対する抵抗を増大するため嵌合金
具の上部に局部的に肉厚を増大J−る必要がある。
[1-Problems to be Solved by the Invention] In order to improve the above-mentioned conventional defects and obtain a spiked sole that provides a more suitable feeling of wearing, the lower sole inscribed in the outer sole (mid sole, A plastic or rubber foam such as polyvinyl acetal or polyurethane elastomer (111) is used in the open sole to provide appropriate cushioning to the heel area, where the most weight is applied, and from the heel of the lower sole to the foot of the lower sole. , it is necessary to configure the density difference so that the density of the foam increases toward the lower sole tread, and in particular to increase the density of the tread, which is most susceptible to the impact of spike thrusting. It is necessary to make the foam density at the top of the spike position higher than the foam density at the surrounding bottom tread portion to increase the resistance to the upward thrust of the spikes. In addition, in the combination of a foam lower sole and a hard outer sole made of polyurethane, thermoplastic plastic, rubber, etc., a mating configuration is required to increase the stability of the spikes. In this case, it is necessary to locally increase the wall thickness at the upper part of the fitting in order to increase the resistance to the pushing up of the fitting by the spikes.

〔問題点を解決するための手段〕[Means for solving problems]

発泡体の下底と下底踵部から下底ふまず部、下底踏面部
に向かって発泡体の密度を増大する方法として、発泡度
の同一な発泡体のスラブ(31ab)からスキ加工によ
って、踵部、ふまず部、踏面部からなる所要の形状に加
工したモールド成形前の    1発泡下底用の加工底
を圧縮率に対応する肉厚に製作し、他方プラスチック系
外底をモールド成形において、スパイクの取付り位置に
、スパイクの嵌合金臭を埋設し、該嵌合金具に対応する
内側上部に局部的に厚肉状に盛り上げた固定突部を形成
し、該外底と上記発泡下底とを接着剤にて貼り合わせ、
最終形状の成形型に挿入し、加工底の発泡下底の発泡度
に対して下底踵部、下底ふまず部、下底踏面部をそれぞ
れ異なる圧縮率にて加熱圧縮冷却して、発泡密度を踵部
で最低とし、踏面部を最高となるように発泡密度差を形
成づ−ると共に、外底の嵌合金具上の固定突部にて、発
泡下底用の加工底の下部に圧縮嵌合して、外底の嵌合金
具の対応位百の局部の発泡密度を高めて外底と発泡下底
とを固定一体化して所要の形状に成形してスパイクシュ
ーズ底を構成するものであり、発泡密度の範囲は、下底
踵部が○927〜0.35、下底踏面部が0.37〜0
.501下底ふまず部は両名の間の発泡密度とし、下底
踏面部の外底の固定突部に対する固定凹部の発泡密度を
、下底踏面部の密度より0.05〜0.1高い密度範囲
に設定する。
As a method of increasing the density of the foam from the lower sole and heel of the foam toward the foot of the lower sole and the tread of the lower sole, a slab (31ab) of foam with the same degree of foaming is processed by skimming. Before molding, the heel, foot, and tread parts are processed into the required shape.1.The processed sole for the foamed lower sole is made to have a wall thickness that corresponds to the compression ratio, and the plastic outer sole is molded. In this method, a fitting metal odor of the spike is buried at the mounting position of the spike, a fixing protrusion locally thickly raised is formed on the inner upper part corresponding to the fitting metal fitting, and the outer sole and the foamed foam are connected to each other. Attach the bottom bottom with adhesive,
The foamed sole is inserted into the mold of the final shape, and the heel of the lower sole, foot of the lower sole, and tread of the lower sole are heated, compressed, and cooled at different compression rates depending on the degree of foaming of the foamed sole of the processed sole. A foam density difference is created so that the density is lowest at the heel and highest at the tread area, and the fixing protrusion on the fitting metal fitting on the outer sole is used to form a foam density difference in the lower part of the processed sole for the foamed lower sole. The sole of the spiked shoe is constructed by compression fitting and increasing the foam density in the corresponding area of the fitting metal fitting on the outer sole, fixing and integrating the outer sole and the foamed lower sole and molding them into the desired shape. The range of foam density is ○927 to 0.35 for the heel of the lower sole and 0.37 to 0 for the tread of the lower sole.
.. 501 The foam density of the bottom of the bottom is between the two, and the foam density of the fixing recess for the fixing protrusion on the outer sole of the bottom tread is 0.05 to 0.1 higher than the density of the bottom tread. Set to density range.

〔作用〕[Effect]

従来のように、下底(ミツドソール、開底)をモールド
成形による同時発泡によって、同様な発泡度の下底を形
成する方法と異なり、発泡度の同一なスラブ発泡体から
スキ加工によって形成したモールド成形前の下底用加工
底の発泡下底を、それぞれ異なる圧縮率にて加熱して、
下底踵部、下底ふまず部、下底踏面部にそれぞれ異なる
所要の発泡密度に形成したため、最も重量の掛かる下底
踵部には、他部より大なるクッション性が与えられ、下
底ふまず部に中間的な支持性とクッション性が形成され
、下底踏面部と外底の嵌合金具上の発泡密度を最大とし
て安定的な支持性を増大したことによって、スパイクの
突き上げが防止される良好な履用感が形成される。
Unlike the conventional method, in which the bottom sole (mid sole, open sole) is simultaneously foamed by molding to form the bottom sole with the same degree of foaming, the mold is formed from slab foam with the same degree of foaming by skimming. The foamed soles of the processed soles before molding are heated at different compression ratios,
The heel of the lower sole, the foot of the lower sole, and the tread of the lower sole are each formed with different required foam densities, so the heel of the lower sole, where the heel carries the most weight, is given greater cushioning than other parts. Intermediate support and cushioning properties are formed at the base, and the foam density on the bottom tread and outer sole fittings is maximized to increase stable support, preventing spikes from pushing up. A good feeling of wearing is created.

さらに、硬い外底のスパイク嵌合金具の埋設上部に、局
部的に外底材料による厚肉の固定突部を局部的に形成し
て、該突部を加工底の下部に圧縮固定したことによって
、固定突部の周囲の発泡体にて緩衝性が与えられ、スパ
イクが必要以上に剛高化されることなく、安定した好適
なスパイク作用が得られると共にスパイクの突き上げに
対する抵抗を著しく増大力る等のスパイクシ、]−ズ底
としての好適な特性作用を右するものである。
Furthermore, by locally forming a thick fixing protrusion made of the outer sole material on the embedded upper part of the spike fitting metal tool of the hard outer sole, and compressing and fixing the protrusion to the lower part of the processed bottom. The foam around the fixed protrusion provides cushioning properties, and the spike does not become more rigid than necessary, providing a stable and suitable spike action and significantly increasing the resistance to spike thrusting. Spikes, etc., have suitable characteristics as a bottom.

〔実施例〕〔Example〕

例示の図面に基づいて、この発明の詳細な説明する。 The invention will be explained in detail on the basis of exemplary drawings.

第1図は、発泡度の同一な発泡体のスラブ(Slab)
からスキ加工によって踵部、ふまず部、踏面部を形成し
た発泡体の下底用の加工底PSの側面を示したもので、
1が下底踵部、2が下底ふまず部、3が下底踏面部であ
る。
Figure 1 shows slabs of foam with the same foaming degree.
This figure shows the side view of a processed sole PS for the lower sole made of foam with a heel, foot, and tread formed by karaski processing.
1 is a lower sole heel portion, 2 is a lower sole foot portion, and 3 is a lower sole tread portion.

この加工底PSは、実施の一例として、ポリビニルアセ
タールを使用、発泡密度として0.25の発泡度のもの
を使用した。この加工底PSは、最終形状の成形型にて
、外底と組み合わけて圧縮成型してスパイクシューズ底
とするものである。
As an example of implementation, this processed sole PS was made of polyvinyl acetal and had a foaming density of 0.25. This processed sole PS is compressed and combined with the outer sole in a final shape mold to form a spiked shoe sole.

従って、加工底PSは、下底踵部1の圧縮率を最低とし
、下底踏面部3を最高とし、下底ふまず部を両者の間程
度のそれぞれの圧縮率に対応した肉厚に加工される。
Therefore, in the processed sole PS, the compression ratio of the heel part 1 of the lower sole is the lowest, the tread part 3 of the lower sole is the highest, and the foot part of the lower sole is processed to a thickness corresponding to the respective compression ratios between the two. be done.

第2図は、外底O8の片方の裏面(接地面側)を平面図
にて示したもので、第3図は、第2図の■−■線断面を
示したものである。
FIG. 2 shows a plan view of one back surface (ground plane side) of the outer sole O8, and FIG. 3 shows a cross section taken along the line ■--■ in FIG.

本例では、該外底O8は、硬いプラスチックの−例とし
て、熱可塑性ポリウレタン+J 料を使用し、スパイク
の取付は位置にスパイクの嵌合金具を埋設し、該嵌合金
具の内側上部に固定突部を形成するように外底成形型に
て加熱成形して形成される。
In this example, the outer sole O8 is made of hard plastic, such as thermoplastic polyurethane + J material, and the spikes are attached by embedding a spike fitting in the position and fixing it to the inner upper part of the fitting. It is formed by heating and molding using an outer sole mold to form a protrusion.

図において、4は外底内に埋設されるスパイクの+m合
金具、5は嵌合金具の埋設部、6は嵌合金具4の内側上
部に外底U斜にて局部的に厚肉状に盛り上げた固定突部
である。
In the figure, 4 is the +m alloy tool of the spike buried in the outer sole, 5 is the embedded part of the fitting alloy tool, and 6 is a locally thick-walled part on the inner upper part of the fitting alloy tool 4 at the outer bottom U diagonal. It is a raised fixed protrusion.

なお、第2図に示ず外底の接地面側には適宜に所要の滑
り止め意匠が設けられる。また、この外底O8のポリウ
レタンわ1底は、JISスプリング式硬度計Aタイプで
95°±2°稈度のものである。
Note that, although not shown in FIG. 2, a required anti-slip design is appropriately provided on the contact surface side of the outer sole. Further, the polyurethane sole of the outer sole O8 has a culmness of 95°±2° as measured by JIS spring type hardness tester A type.

嗜 次に、前記の発泡下底用の加工底PSと上記の外底O8
との両省の接合部にウレタン系接着剤を塗布して接着し
、R柊形状の成形型に挿入し、下底踵部1、下底ふまず
部2、下底踏面部3のそれぞれに対応する所要の圧縮率
に圧縮づ゛る上蓋にて加熱圧縮して所定の圧縮率とし冷
却して、踵部から踏面部に向かって発泡密度を増大し、
各部にそれぞれ異なる適正な発泡密度を形成した下底M
Sと外底oSと一体化したスパイクシューズ底を構成す
るものである。
Next, the above-mentioned processed sole PS for the foamed bottom sole and the above-mentioned outer sole O8
Apply urethane adhesive to the joints of the two sides and adhere them, and insert into an R-shaped mold to correspond to the lower heel part 1, the lower foot part 2, and the lower tread part 3, respectively. The foam is heated and compressed in the upper lid to a desired compression ratio, and then cooled to a predetermined compression ratio to increase the foam density from the heel to the tread surface.
Lower sole M with different appropriate foam densities in each part
This constitutes the sole of a spiked shoe that is integrated with the outer sole oS.

第4図は、一体化されたスパイクシ]−ズ底の下底MS
の形状を取り出して、第3図の外底O8の断面図に対応
する下底MSの断面を示したもので、7は外底の固定突
部6との加熱圧縮一体化時に形成された下底M Sの固
定凹部である。すなわち、外底O8の固定突部6と下底
MSの固定凹部7とによって投錨的に強力な一体固定が
得られるものである。
Figure 4 shows the lower MS of the integrated spike series bottom.
This figure shows a cross section of the lower sole MS corresponding to the cross-sectional view of the outer sole O8 in FIG. This is a fixed recess on the bottom MS. That is, the fixing protrusion 6 of the outer sole O8 and the fixing recess 7 of the lower sole MS provide strong integral fixation in terms of anchorage.

第5図は、下底MSと外底O8と一体化したスパイクシ
ューズ底SO8の側面図を示したものである。
FIG. 5 shows a side view of the spiked shoe sole SO8 integrated with the lower sole MS and the outer sole O8.

なお、下底および外底に、他のゴム系、プラスチック系
相別を使用する場合は、それぞれの材質に適合した接着
剤を使用する。
In addition, when using other rubber-based or plastic-based materials for the bottom sole and outer sole, use an adhesive that is compatible with each material.

〔発明の効果〕〔Effect of the invention〕

この発明の構成は、上記説明のとおり、下底踵部、下底
ふまず部は、下底踏面部の発泡密度に変化を与えたため
に、好適な履用感が得られるものであり、また、スパイ
クの影響を最も受りやすい下底踏面部の発泡密度をより
高く構成し目つより高い発泡密度の固定凹部が形成され
、さらに、外底のスパイクの嵌合金具の内側上部を、局
部的に外底材料の厚肉の固定突部を形成して、該固定突
部と、発泡体からなる下底の固定凹部との固定一体化し
たことによって、スパイクの突き上げに対する影響が防
1トされるばかりでなく、必要以上にスパイクを剛直化
するすることなく適度の緩衝性と安定した好適なスパイ
ク作用が得られる等のスパイクシューズ底としての好ま
しい特性の得られる効果を右するものである。
As explained above, the structure of the present invention is that the foam density of the lower heel and foot of the lower sole is changed in the tread portion of the lower sole, so that a suitable feeling of wearing can be obtained. The foaming density of the lower sole tread, which is most susceptible to the effects of spikes, is made higher, and a fixing recess with a higher foaming density is formed. By forming a thick fixing protrusion in the outer sole material and integrating the fixing protrusion with the fixing recess in the lower sole made of foam, the influence of the spikes from pushing up can be prevented. Not only is it effective, but it also determines the effect of obtaining desirable characteristics as a spiked shoe sole, such as obtaining appropriate cushioning properties and stable and suitable spike action without making the spikes more rigid than necessary. .

【図面の簡単な説明】[Brief explanation of drawings]

第1図は、この発明のスパイクシコーズ底の発泡体の下
底用の加工底の側面図、 第2図は、外底の裏面の平面図、 第3図は、第2図のI[r−111線断面図、第4図は
、スパイクシコーズ底の外底と一体化時の下底の断面図
、 第5図は、スパイクシコーズ底の側面図である。 PS・・・加工底    O8・・・外底M S・・・
下底 SO8・・・スパイクシューズ底 1・・・下底踵部     2・・・下底ふまず部3・
・・下底踏面部    4・・・嵌合金具5・・・嵌合
金具の埋設部 6・・・固定文部7・・・固定四部
Fig. 1 is a side view of a processed sole for the foam lower sole of the Spike Shikoz sole of the present invention, Fig. 2 is a plan view of the back side of the outer sole, and Fig. 3 is the I [ FIG. 4 is a cross-sectional view of the lower sole when integrated with the outer sole of the spiked Shicose sole, and FIG. 5 is a side view of the spiked Shicose sole. PS... Processed sole O8... Outer sole M S...
Lower sole SO8... Spike shoe sole 1... Lower sole heel portion 2... Lower sole foot portion 3.
... Lower bottom tread part 4 ... Fitting metal fitting 5 ... Burying part of fitting metal fitting 6 ... Fixing part 7... Four fixing parts

Claims (2)

【特許請求の範囲】[Claims] (1)発泡体の下底と硬度の高い外底とからなるスパイ
クシューズ底において、下底踵部と下底ふまず部並びに
下底踏面部にそれぞれ圧縮率の変化によって下底踵部の
発泡密度を0.27〜0.35、下底踏面部を0.37
〜0.50、下底ふまず部は両者の間の発泡密度とし、
下底踏面部の固定凹部の発泡密度を、下底踏面部の密度
より0.05〜0.1高い密度の範囲に設定し、スパイ
クの嵌合金具を埋設した内側上部に固定突部を形成した
外底の固定突部と、上記発泡体の下底の固定凹部とが接
着一体化したスパイクシューズ底。
(1) In spike shoe soles consisting of a foam lower sole and a highly hard outer sole, the heel of the lower sole is foamed by changing the compression ratio of the heel of the lower sole, foot of the lower sole, and tread of the lower sole. Density: 0.27 to 0.35, bottom tread: 0.37
~0.50, the foaming density of the lower bottom part is between the two,
The foaming density of the fixing recess on the bottom tread is set in a range of 0.05 to 0.1 higher than the density of the bottom tread, and a fixing protrusion is formed at the upper part of the inside where the spike fittings are buried. A spiked shoe sole in which a fixing protrusion on the outer sole and a fixing recess on the lower sole of the foam are integrated by adhesive.
(2)発泡度の同一な発泡体のスラブからスキ加工によ
つて、所要の圧縮率を加算した寸法の踵部、ふまず部、
踏面部を形成した下底用の加工底を製作し、他方硬度の
高い外底材料のモールド成形において、スパイクの取付
け位置にスパイクの嵌合金具を埋設し、該嵌合金具の埋
設部の内側上部に外底材料の固定突部を形成するように
モールドにて加熱成型し、該外底と上記下底用加工底と
を接着剤にて貼り合わせ、最終形状の成形型に挿入し、
下底踵部、下底ふまず部、下底踏面部をそれぞれ異なる
圧縮率にて加熱圧縮冷却して、発泡密度を踵部で最低と
し、踏面部を最高となるように発泡密度差を形成すると
共に、外底の嵌合金具上の固定突部にて、加工底の発泡
体の下部に加熱圧縮固定して、外底の嵌合金具の対応位
置の局部の発泡密度を高めて外底と発泡下底とを接着一
体化して所要形状に形成することを特徴とするスパイク
シューズの製法。
(2) Heel and foot parts of dimensions obtained by adding the required compression ratio by skimming from slabs of foam with the same degree of foaming.
A machined sole for the lower sole with a tread formed thereon is manufactured, and on the other hand, during molding of a hard outer sole material, a fitting metal fitting for the spike is buried in the spike attachment position, and the inner side of the embedded part of the fitting metal fitting is buried in the spike attachment position. The outer sole is heated and molded to form a fixing protrusion of the outer sole material on the upper part, and the outer sole and the processed sole for the lower sole are bonded together with an adhesive, and inserted into a mold for the final shape.
The heel of the lower sole, foot of the lower sole, and tread of the lower sole are heated, compressed, and cooled at different compression rates to create a foam density difference such that the foam density is lowest at the heel and highest at the tread. At the same time, the fixing protrusion on the fitting tool on the outer sole is heated and compressed to the lower part of the foam on the processed sole to increase the local foam density at the corresponding position of the fitting tool on the outer sole. A method for manufacturing spiked shoes characterized by integrally bonding and forming a foamed bottom sole into a desired shape.
JP22606784A 1984-10-26 1984-10-26 Spike shoes sole and its production Granted JPS61103401A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP22606784A JPS61103401A (en) 1984-10-26 1984-10-26 Spike shoes sole and its production

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP22606784A JPS61103401A (en) 1984-10-26 1984-10-26 Spike shoes sole and its production

Publications (2)

Publication Number Publication Date
JPS61103401A true JPS61103401A (en) 1986-05-21
JPH0376121B2 JPH0376121B2 (en) 1991-12-04

Family

ID=16839286

Family Applications (1)

Application Number Title Priority Date Filing Date
JP22606784A Granted JPS61103401A (en) 1984-10-26 1984-10-26 Spike shoes sole and its production

Country Status (1)

Country Link
JP (1) JPS61103401A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4906464A (en) * 1987-12-26 1990-03-06 Shinagawa Fuel Co., Ltd. Method for preparing dispersions containing antibiotic power
US4938958A (en) * 1986-12-05 1990-07-03 Shinagawa Fuel Co., Ltd. Antibiotic zeolite
US4938955A (en) * 1987-04-22 1990-07-03 Shingawa Fuel Co., Ltd Antibiotic resin composition
US5556699A (en) * 1987-06-30 1996-09-17 Shingawa Fuel Co. Ltd. Antibiotic zeolite-containing film
US6929705B2 (en) 2001-04-30 2005-08-16 Ak Steel Corporation Antimicrobial coated metal sheet

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4938958A (en) * 1986-12-05 1990-07-03 Shinagawa Fuel Co., Ltd. Antibiotic zeolite
US4938955A (en) * 1987-04-22 1990-07-03 Shingawa Fuel Co., Ltd Antibiotic resin composition
US5556699A (en) * 1987-06-30 1996-09-17 Shingawa Fuel Co. Ltd. Antibiotic zeolite-containing film
US4906464A (en) * 1987-12-26 1990-03-06 Shinagawa Fuel Co., Ltd. Method for preparing dispersions containing antibiotic power
US6929705B2 (en) 2001-04-30 2005-08-16 Ak Steel Corporation Antimicrobial coated metal sheet

Also Published As

Publication number Publication date
JPH0376121B2 (en) 1991-12-04

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