JPS6017197A - Surface treatment of paper - Google Patents
Surface treatment of paperInfo
- Publication number
- JPS6017197A JPS6017197A JP12345483A JP12345483A JPS6017197A JP S6017197 A JPS6017197 A JP S6017197A JP 12345483 A JP12345483 A JP 12345483A JP 12345483 A JP12345483 A JP 12345483A JP S6017197 A JPS6017197 A JP S6017197A
- Authority
- JP
- Japan
- Prior art keywords
- surface treatment
- paper
- resin
- fluorinated hydrocarbon
- treatment agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Paper (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
本発明は紙の表面処理方法に関するもので、特にｃａ
Ｆｌ ７ ＢＯ２Ｆ’から得られる親水基を保有した電
解型弗素化炭化水素を反応性中間樹脂媒質の存在下で使
用することを特徴とする紙の表面処理方法に関するもの
である。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for surface treatment of paper, and in particular to a method for surface treatment of paper.
The present invention relates to a paper surface treatment method characterized in that an electrolytic fluorinated hydrocarbon having a hydrophilic group obtained from Fl 7 BO2F' is used in the presence of a reactive intermediate resin medium.
最近のグラスチック島棄物による公害問題の発生に伴い
紙の特性が再計測されつつあるが、セルロースの有する
本質的利点としての吸水性は高温高湿条件−Ｆにおける
寸法安定性及び強度の劣化という不可瞳的欠点としても
認識されておシ、紙製品の各種分野への用途の拡大に伴
って紙の表面処理のために各種の方法が提案されｌＦ＆
に耐水性については数多くの提案が行われてきているに
も拘らず、これまでに充分満足すべき結果の得られでい
ないことは周知の通シである。The properties of paper are being re-measured due to the recent pollution problem caused by the waste from Glass Island, but the essential advantage of cellulose is its water absorption, which deteriorates in dimensional stability and strength under high-temperature and high-humidity conditions. However, with the expansion of the use of paper products in various fields, various methods have been proposed for surface treatment of paper.
Although many proposals have been made regarding water resistance, it is well known that no fully satisfactory results have been obtained so far.
紙の耐水性を改善するだめの表面処理方法としては一般
に弗素系化合物が使用される場合が多いが耐水性を目的
とした場合には耐油性が劣るの番１これまで当然と考え
られており、耐水性と同時に耐油性を充分に付与するだ
めの試みは殆と知られていない実情である。Generally, fluorine-based compounds are often used as a surface treatment method to improve the water resistance of paper, but it has been taken for granted that oil resistance is inferior when the purpose is water resistance. However, little is known about attempts to sufficiently impart oil resistance as well as water resistance.
従って本発明の目的は新規の紙の処理方法を提供するこ
とであシ、特に紙に耐水性を与えるとともに充分な耐油
性をも同時に付与するための簡便な処理方法とそのため
の処理剤を提供することである０
本発明者は研究の結果、親水基を保有させた電解型弁ツ
メ化炭化水素全反応性中間樹脂媒質の存在下で加熱適用
することによって従来全く異質の処理とさｈていた紙の
耐水、副油処理を単一行程で簡便に行ない得ることを知
った。Therefore, an object of the present invention is to provide a new paper processing method, and in particular, to provide a simple processing method and a processing agent for imparting water resistance and sufficient oil resistance to paper at the same time. As a result of research, the present inventors have discovered that the present inventors have succeeded in applying heat in the presence of an electrolytic valve-sealed hydrocarbon fully reactive intermediate resin medium possessing hydrophilic groups, which is completely different from the conventional treatment. We found that water resistance and secondary oil treatment of paper can be easily done in a single process.
すなわち、本発明はｃＢ Ｆ、７５ｏ２Ｆから得られる
親水基金保有した電解型弗素化炭化水素を反応性中間樹
脂媒質の存在下で使用することをｌ特徴とする紙の表面
処理方法であり℃、電解型弗素化炭化水素と１ノＣ６１
ｃ８ Ｆ１７８０２ Ｑ （Ｃ）１２ ＣＨ２０）ｙＩ
Ｈまたは樹脂媒質としてはメラミン系（１Ｊ１脂、エ
ポキシ系４ＭＪ力旨、アクリル系樹脂等が好適に使用さ
れ、必要な場合には非電解型の弗素系撥水剤及び弗素系
撥油剤との併用が望ましい。特に一般に工、４９キシ系
樹脂とアクリル系樹脂との混合物が好適であシ、処理温
度において反応性を保持することが不可欠の要件である
。工Ｉキシ系樹脂としては例えば三井東圧製エポキシエ
マルジＨンＰ−５２００や日本油脂製アクリルエポキシ
樹脂ブレンマーＧ等の使用が便利である。また本発明で
使用される電解型弗素化炭化水素としては無水弗化水素
に溶ｈｅｒ したカルボン酸型やスルホン酸型の有機化
合物の塩化物を弗素ガスが発生しない程度に低電圧で電
解して陽極に２９−フルオロ化合物と得られる０８Ｆ１
７８０２ Ｆを以下に本発明の処理剤の配合例と処理後
の撥水。That is, the present invention is a paper surface treatment method characterized by using an electrolytic fluorinated hydrocarbon containing hydrophilic acid obtained from cBF, 75o2F in the presence of a reactive intermediate resin medium. type fluorinated hydrocarbon and 1 no C61
c8 F17802 Q (C)12 CH20)yI
As the H or resin medium, melamine type (1J1 resin, epoxy type 4MJ resin, acrylic resin, etc.) is preferably used, and if necessary, it can be used in combination with non-electrolytic fluorine type water repellent and fluorine type oil repellent. In particular, mixtures of 49-based resins and acrylic resins are preferred, and it is essential to maintain reactivity at the processing temperature. It is convenient to use pressure-produced epoxy emulsion H-P-5200 and acrylic epoxy resin Blenmar G manufactured by Nippon Oil & Fats.In addition, as the electrolytic fluorinated hydrocarbon used in the present invention, the electrolytic fluorinated hydrocarbon dissolved in anhydrous hydrogen fluoride can be used. 08F1 is obtained by electrolyzing the chloride of a carboxylic acid type or sulfonic acid type organic compound at a low voltage that does not generate fluorine gas to form a 29-fluoro compound at the anode.
7802 F is shown below as a formulation example of the treatment agent of the present invention and water repellency after treatment.
撥油性を示す。なお各実施例の成分含量は何りも重量％
である。Shows oil repellency. In addition, the component content in each example is weight%.
It is.
実施例１
実施例２
実施例３
実施例４
実施例５
実施例６
実施例７
以上の実施例からも知られるように、本発明の方法によ
れは電解型弗素化炭化水素を反応性中間樹脂とともに紙
の表面処理に適用することによシ、簡便に紙に耐水性、
耐油性を同時に付与することが可能となるばかシでなく
、紙取外の他の例えは織布等のセル目−ス材料にも有効
に適用できることは明白である。Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Example 7 As is known from the above examples, the method of the present invention can convert electrolytic fluorinated hydrocarbons into reactive intermediate resins. It can also be applied to the surface treatment of paper, making it easy to make paper water resistant.
It is obvious that other examples of paper removal can also be effectively applied to cellular materials such as woven fabrics, as well as being able to impart oil resistance at the same time.
Claims (1)
基金保有した電Ｎ型弗素化炭化水素を反応性中間樹脂媒
質の存在下で使用することをη′ケ徴とする紙の表面処
理方法。 （２）非電解型の弗素系撥水剤及び／又は弗素系撥油剤
′ｆｔ該電解弗素化炭化水素及び反応性中間樹脂線１４
とともに使用する仁とを特徴とする前記第（０項記載の
方法。 （３）該電解弗素化炭化水素が Ｃ８Ｆ’ｉ ７ ｓｏ２ ｈ （ｃＨ２ＣＨ２０） ｎ
Ｈ及び／′又は項記載の方法。 （４）該反応性中間樹脂媒質がメラミン系樹脂、エポキ
シ系樹脂及び／又はアクリル系樹脂である前記第（１）
項記載の方法。 （５）紙製品のＪＪｌｌ、型抜に噴霧及び加熱処理する
ことを特徴とする前記第（ＩＪ〜（４）項記載の方法。 （（ｉＪ Ｃ’ｇ Ｆｌ７８０２ Ｆから得られる親水
基を有する電解弗素化炭化水素と反応性１−間樹脂媒質
とを含有することを特徴とする紙の表面処理剤。 （７］弗素系撥水剤及び／又は弗素系撥油剤を含有する
ことを特徴とする前記第（６）項記載の表面処理剤。 （８）該電解弗素化炭化水素が ｃ６ Ｆｌ ７ ｓｏ２ Ｎ （ＣＨ２Ｃ１１２０）ｎ
Ｈ及び／又は（９）該反応性中間樹脂媒質がメラミン系
樹脂、エポキシ系樹脂及び／又はアクリル系樹脂である
前記第（６）項記載の表面処理剤。 （１，０）前記第（６）〜（７）項の表面処理剤で処理
さｉｔでいることを％徴とする弗素樹脂コート紙。[Scope of Claims] (1) A paper with the characteristic η' that an N-type fluorinated hydrocarbon obtained from as Fl 7 so2 F is used in the presence of a reactive intermediate resin medium. Surface treatment method. (2) Non-electrolytic fluorine-based water repellent and/or fluorine-based oil repellent'ft the electrolytic fluorinated hydrocarbon and reactive intermediate resin wire 14
The method according to item (0), characterized in that the electrolytic fluorinated hydrocarbon is C8F'i 7 so2 h (cH2CH20) n
H and/' or the method described in section. (4) The above-mentioned (1), wherein the reactive intermediate resin medium is a melamine resin, an epoxy resin and/or an acrylic resin.
The method described in section. (5) The method described in paragraphs (IJ to (4)) above, characterized in that JJll of paper products is subjected to spraying and heat treatment on die cutting. A paper surface treatment agent characterized by containing a fluorinated hydrocarbon and a reactive monomer resin medium. (7) A paper surface treatment agent characterized by containing a fluorine-based water repellent and/or a fluorine-based oil repellent. The surface treatment agent according to item (6) above. (8) The electrolytically fluorinated hydrocarbon is c6 Fl 7 so2 N (CH2C1120)n
H and/or (9) the surface treatment agent according to item (6) above, wherein the reactive intermediate resin medium is a melamine resin, an epoxy resin and/or an acrylic resin. (1,0) Fluororesin-coated paper characterized by being treated with the surface treatment agent of items (6) to (7) above.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12345483A JPS6017197A (en) | 1983-07-08 | 1983-07-08 | Surface treatment of paper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12345483A JPS6017197A (en) | 1983-07-08 | 1983-07-08 | Surface treatment of paper |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS6017197A true JPS6017197A (en) | 1985-01-29 |
Family
ID=14861010
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP12345483A Pending JPS6017197A (en) | 1983-07-08 | 1983-07-08 | Surface treatment of paper |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6017197A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS646196A (en) * | 1987-02-12 | 1989-01-10 | Daikin Ind Ltd | Oil resistant oil for paper |
| EP0693476A1 (en) * | 1994-05-26 | 1996-01-24 | Bayer Ag | Resins containing perfluoroalkyl groups and their use |
| EP0694551A1 (en) * | 1994-05-26 | 1996-01-31 | Bayer Ag | Self-crosslinking aqueous compositions of resins containing perfluoroalkyl groups |
| TWI731558B (en) * | 2019-03-25 | 2021-06-21 | 日商阿爾卑斯阿爾派股份有限公司 | Variable resistor |
-
1983
- 1983-07-08 JP JP12345483A patent/JPS6017197A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS646196A (en) * | 1987-02-12 | 1989-01-10 | Daikin Ind Ltd | Oil resistant oil for paper |
| EP0693476A1 (en) * | 1994-05-26 | 1996-01-24 | Bayer Ag | Resins containing perfluoroalkyl groups and their use |
| EP0694551A1 (en) * | 1994-05-26 | 1996-01-31 | Bayer Ag | Self-crosslinking aqueous compositions of resins containing perfluoroalkyl groups |
| US5539024A (en) * | 1994-05-26 | 1996-07-23 | Bayer Aktiengesellschaft | Resins containing perfluoroalkyl groups and their use |
| TWI731558B (en) * | 2019-03-25 | 2021-06-21 | 日商阿爾卑斯阿爾派股份有限公司 | Variable resistor |
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