JPS5954277A - Light emitting diode - Google Patents

Light emitting diode

Info

Publication number
JPS5954277A
JPS5954277A JP57164211A JP16421182A JPS5954277A JP S5954277 A JPS5954277 A JP S5954277A JP 57164211 A JP57164211 A JP 57164211A JP 16421182 A JP16421182 A JP 16421182A JP S5954277 A JPS5954277 A JP S5954277A
Authority
JP
Japan
Prior art keywords
composition
resin
light
cation
agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP57164211A
Other languages
Japanese (ja)
Other versions
JPH0462188B2 (en
Inventor
Teru Okunoyama
奥野山 輝
Tokuo Kurokawa
徳雄 黒川
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toshiba Chemical Products Co Ltd
Kyocera Chemical Corp
Original Assignee
Toshiba Chemical Products Co Ltd
Toshiba Chemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toshiba Chemical Products Co Ltd, Toshiba Chemical Corp filed Critical Toshiba Chemical Products Co Ltd
Priority to JP57164211A priority Critical patent/JPS5954277A/en
Publication of JPS5954277A publication Critical patent/JPS5954277A/en
Publication of JPH0462188B2 publication Critical patent/JPH0462188B2/ja
Granted legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/48Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
    • H01L33/52Encapsulations
    • H01L33/56Materials, e.g. epoxy or silicone resin
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2924/00Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
    • H01L2924/0001Technical content checked by a classifier
    • H01L2924/00014Technical content checked by a classifier the subject-matter covered by the group, the symbol of which is combined with the symbol of this group, being disclosed without further technical details

Abstract

PURPOSE:To seal an LED excellently, by using a low viscosity composition of an ultraviolet ray hardened type, whose main components are an epoxy resin or other cation polymerized organic material and a light polymerization starting agent of aryl onium salt. CONSTITUTION:An aryl onium salt light polymerization starting agent has a composition of (Ar)n-A<+>.B<->, where Ar is aryl group, (n) is 2-3, A is I, S, and Se, and B is BF4, PF6, SbF6, and AsF6. When a small amount of agent is added, cation polymerization reaction is caused by a cation polymerized organic material such as epoxy resin. Hardening contraction does not occur, no discoloration occurs in the product, and uniform hardening is performed. When sealing is performed by this composition, the sealing can be performed without cracks and wire breakdown.

Description

【発明の詳細な説明】 「発明の技術分野1 本ざと明は紫外線硬化ijl能な(11・l lit’
! (’ J’l It ljl、′を省、)Y1タイ
Δ−ドに関りる。。
DETAILED DESCRIPTION OF THE INVENTION Technical Field of the Invention 1.
! ('J'l It ljl, ' is omitted) This relates to the Y1 tie Δ-de. .

1発明の技術向背ビ1とその問題1’、l l従来/)
目ら発光タイA −1−4;L湿気\゛)不純物に:、
 triめ(敏感4「ため液状−1ボ″1−シ(かl 
1lti #ll成物賓(樹脂エルされ(いる。
1 Technical background of the invention 1 and its problems 1', l l Conventional/)
Eye-light-emitting tie A-1-4; L moisture \゛) Impurities:,
Tri-me (sensitive 4 "Liquid-1 Bo" 1-shi (Kal)
1lti #lli synthetic material (resin er).

樹脂月」17′ノ法どしく’ tel、、透明容器内(
J81ノ: IAI脂組成物を注入した後、発光ダイΔ
−ド部品を所望の部分まC゛即設t長、その後(J(]
の樹11ft絹成物を加熱硬化さUで一体化りるいわl
:Jl ;!、rボッlイング法、!IIJ容器を用い
て臼杵に月11ろ11イ1−)1.、: 1や、IIO
型を(1なういわ1.j、lる11・スノrン/)法、
4;;)l脂絹成物中に発光ダイA−ト部品’i凌(C
Ily (’ Lれを一亀引ぎ−1,+J、II盾した
樹脂を加熱1.jlj化さ[」るい4′)ゆるデrツビ
ング法、液状(z)4脂組成物を+ili ffFの部
分に滴1・さlで−でのII: 1: tυ化さく県イ
、)い、1)(つ)り)Iへ1」ツピング?人等があげ
られる。
Resin Month"17' no law" tel,, inside a transparent container (
J81 No.: After injecting the IAI fat composition, the light emitting diode Δ
- Immediately install the code part to the desired part, then (J()
11ft of silk material is heat-cured and integrated with U.
:Jl ;! , rBolling method,! 1. Monthly 11 ro 11 ii 1-) 1. , : 1, IIO
Type (1.j, l11.snorn/) method,
4;;)l Light-emitting die parts 'i Ling (C
Ily ('L-1, +J, II-shielded resin is heated 1.jlj-ized ["rui 4')" Yuru Dertzbing method, liquid (z) 4 fat composition +ili ffF II with 1 drop on the part: 1: tυ conversion prefecture i,)i, 1) (tsu)ri)I to 1'' tsuping? People can be mentioned.

このJ、うな樹1j11月庄に−ITJいIう’I′+
4+ JMJ脂に(3L次のよう/I′iり能が必要と
きれ(いる。
This J, Unagi 1j November Sho ni-ITJ Iu'I'+
4+ JMJ fat (3L) has the following /I'i ability when necessary.

す41“J’)l) (1)ボッライング、:髪トスノ rン9′;・7のl
j f人の場合、低粘磨樹脂であっ′CJ〜f JJ−
+、二際し、 (、I’17、し易く、(7かb脱泡か
り、f+ 11.1R’J (雪jλる0の(イ「(ノ
れ(,1ならない、。
41 "J')l) (1) Bollaing, :hair tossun 9';・7 no l
j In the case of f people, low viscosity resin 'CJ~f JJ-
+, 2 times, (, I'17, easy to do, (7 or b defoaming, f+ 11.1R'J

(2))llJ!化に際しCa)IIIII化収稲カ小
(\イL)ノ(:’ /、−i(〕れ(」ならないつ硬
硬化線か人。\い場合1.1. J・1止に際しくクラ
ックが’I−1; I::す、じ−トシトン’/ +;
二J、る残留歪みに起因覆るクラックがl:+ 1; 
/、−リ、あるいはボンディングされに一金線か11I
々1lli lる′lqの不都合が/4:?l”る。
(2))llJ! At the time of conversion, Ca) III rice yield is small (\iL)ノ(:' /, -i() is not a hard hardening line or a person. \If 1.1. Cracks occur when J.1 stops. ga'I-1;I::su,ji-toshiton'/+;
2J, cracks covered due to residual strain l: + 1;
/, -ri, or bonded gold wire or 11I
1lli l'lq's inconvenience /4:? l"ru.

(3) t!?られた硬化物の電気絶紅1ノ1か、1く
、熱+V:張係数が小さい(二と、。
(3) t! ? The cured product has a small tensile coefficient (2 and 1).

(4) ’t、’;j ’られ/、二硬化物の耐IB%
 15> jllが良θj”r’; cl L。
(4) 't,';j're/, IB resistance % of double cured product
15> jll is good θj”r'; cl L.

(!□5)熱劣化による変色の少1.[いt)の(ある
こと1゜等ひあり、こ°−トしらの問求性能を植j足さ
1!るものどしζ1lFi!(1酸無水物硬化型I、ポ
1シ樹脂を主成分とづる樹脂組成物が広く使用され(い
る。
(!□5) Less discoloration due to thermal deterioration 1. [It)'s (one thing is 1 degree, etc.), and the required performance of these is added ζ 1 l Fi! (1 acid anhydride curing type I, 1 poly resin) Resin compositions with main components are widely used.

しかし4丁から、この樹脂は加熱硬化!、l!Iて゛あ
るため、硬化に艮口)間を要し牛ρζfI]に劣るとい
う勤S1”、ミがあった。
However, from 4 guns onwards, this resin is cured by heating! ,l! Due to the high temperature, it took a long time to harden and was inferior to that of beef.

rJすわl)、例えl;r 1’ IIス゛フイング2
人を例【1あ0゛れは、11;2八l! iiJ能なま
でに60分稈ltF、必1.ン(゛(1りる。
rJSwal), example l;r 1' II SWIFING 2
For example, a person [1 a 0 is 11; 28 l! iiJ culm ltF for 60 minutes, must be 1. N(゛(1riru.

硬化時間をり、(1紺11]J、・)とじUIゆ止剤を
増j1)シたり、硬化温度を上げるという手段を用いる
こと0検訃1されているか、この、1、う4j手F受に
、1、れば硬化II?の内部光熱が人さくなり、これに
1゛1′つで様々<’L l・ラフルが41−じCいた
Is it possible to increase the curing time, increase the binding UI detergent, or raise the curing temperature? If the F receiver is 1, is it hardening II? The internal light of the body became weak, and in this 1゛1' there were various <'L Rahul 41-C.

このような問題を克服づる方法としく、近日不飽和ポリ
ニスフール系、アクリル系8Lだ(31メタクリル系等
の樹脂組成物に光Φ合間始剤を添加した紫外線硬化性低
粘度Jul IIHに11成物を用いる試・/lか 部
に(1jい(なされ(いイ)、。
As a way to overcome these problems, we are currently developing unsaturated polynisfur-based, acrylic-based 8L (31 methacrylic-based, etc.) resin compositions with ultraviolet curable low viscosity Jul IIH and 11 compositions, which are made by adding a photo-Φ initiator. Test using /l or part (1j (made (ii),.

しかしながら、この紫外線硬化tノI’、 If(Ji
!□1印樹脂組成物を1tii用した場合は、次のJ、
−)イ「欠+、aか/1りるlζめ、J、つIごく実用
化が困f11(あるのが工(+!状(゛あつ lこ 。
However, this ultraviolet curing tnoI', If(Ji
! □When using 1tii resin composition with 1 mark, the following J,
-) I "lack +, a / 1 rir lζme, J, tsu I is extremely difficult to put into practical use f11 (there is a work (+! condition (゛ ATSU l ko).

す41−わ75閉気中の酸系に、]、す) ソ+シ、 
’rjLどK Fl!l! <Iる部分のΦ合阻害が起
こり(いわゆるq)合禁11効宋)、その結ff! l
f+4脂人面がへたつさ、c、−、、’11.を改:’
j iJイ)ために光重合開始剤の含イjWを増大(\
1jる)、変←1が名しくなり、発光タイA−1〜素r
の斤光光線の光透過;おが悲くなって信頼・Illが1
1(1・iJる−いう欠点か((す) 7.Z 。
41-75 In an acid system in a closed atmosphere, ], s) So + Shi,
'rjLdoK Fl! l! Φ combination inhibition occurs in the <I part (so-called q) combination 11 effect Song), and the result is ff! l
f+4 fat face is tired, c, -,,'11. Revised:'
The content of photopolymerization initiator is increased (\
1jru), change ← 1 becomes famous, luminous tie A-1 ~ elementary r
Light transmission of the ray of light; Oga becomes sad and trust/Ill is 1
1 (1・iJru - Is it a drawback? ((su) 7.Z.

また、ラジカルf=I加!11!の樹脂は本v!I的に
硬化収縮が人さく ’+ Jlil什時にタラップが入
(〆)易< f、L−)たり、内部歪みか残存してボン
7” (ンク1)−イーI−か破断されるいわゆるA−
ブン小良が牛してじ51、)等の欠点があった。
Also, the radical f=I addition! 11! The resin is a book v! In general, hardening shrinkage occurs when the ramp is easily inserted (<f, L-), or internal distortion remains and the so-called bond 7'' (Nk 1)-I-I- is broken. A-
There were shortcomings such as 51, ).

「ブを明の目的1 本発明者らはこのようh問題を解消cJるため鋭意?t
ll究を進めた結束、1ボー1シ11 +1it等の力
f Aン重合性右1幾物質どアリルオニウ1112.i
系光jli合間llA剤との反応を弁光ダイA−トの樹
脂月1(3貢凶川りれば、1りれた効果が得られるこ、
′−を見出した。
Purpose 1: The inventors have worked hard to solve this problem.
Unity that has been investigated, 1 Bo 1 C 11 + 1 It, etc. force f A and polymerizable right 1 Geometric substance Do allyl oniu 1112. i
If the reaction with the llA agent in the middle of the system light is carried out with the resin of Benko Dai-A-to (1), an even greater effect can be obtained.
′- was found.

?Iなわl)この反応は、従来のiクリル系紫外わ:;
硬化型の反応系がいわゆる一巾結合にJ:る、11セ化
収縮を伴うラジカルイ;1加手合系であるのに夕・iじ
、本発明に用いられる反応系は力fAン申含反応C゛あ
っ−(硬化収縮がなく、しか=b少吊の光f11含聞殆
剤τ重合Z”′き、また開始剤にJ、る成形品の友Q5
が少4fいうえ、均 に1功化がiil fil (あ
る雪の++p々の利点が得られることを見出した。
? I) This reaction is carried out using the conventional iCrylic ultraviolet method:;
Although the curing type reaction system is a so-called one-width bond, a radical reaction with 11 cationic contraction; C゛ah-(There is no curing shrinkage, but = b little light f11 contains almost all the additives τ polymerization Z''', and the initiator is J, a friend of molded products Q5
It was found that the snow was less than 4f, and the benefits of the snow were evenly reduced to 1.

本発明は2二のよ−)な知、Q (Jji4 =’、j
’ イ(t’E 2311 /Jt)ので、硬化が75
17時間(−行なえ、変C1,や内部4゛・7)、クラ
ックパりのイ」′い光)にり(−A−ドを1rj)供り
る(−どを目的とりる。
The present invention is based on 22-) knowledge, Q (Jji4 =', j
'E (t'E 2311 /Jt), so the curing is 75
17 hours (-do, change C1, internal 4゛・7), bright light of the crack par) (-A-do 1rj) offer (-do).

[発明の(頑犬1 すl、r、1つlうA発明の発光タイΔ−Fは、1ボ1
シ樹脂:I:1:=は他のカブΔン申合1/1イ1(代
物7′(どj7リルA−ラム塩系光市台聞始剤どを一1
成分どりる紫タト線硬化1ノ1低粘度樹脂組成物でブし
光り(A−1−察J′a3よびリード部を樹脂J’l止
しく4I?る(−とを特1敗とりる1゜ 本VN明に使用りる紫外線硬化1ノ1但粘度樹脂絹成物
は、1−ボ1−シ(か1脂等の力LΔンr−1’i i
’−t’lIll幾物vりどノ′リルA−ウlX’、1
晶系光11)含聞殆ハ!ト1−を1成分どし、この他に
必要に応じて酸化菌11剤や着色剤か添加されたもので
ある。
[The invention's light-emitting tie Δ-F is 1 bo 1
Resin: I:1:= is the other turnip ∆ combination 1/1 1 (substitute 7')
Ingredients are purple Tato line curing 1 no 1 low viscosity resin composition and shining (A-1 - detection J'a 3 and lead part are resin J'l 4I? (- and special 1 loss) The ultraviolet curing resin silk composition used in 1° VN light has a viscosity of 1 to 1.
'-t'lIll geometry v ridono'ril A-UlX', 1
Crystal light 11) Implications are almost ha! In addition to this, 11 oxidizing bacteria and a coloring agent are added as necessary.

このj′リルオニウム塩系光十合開始剤(、L、一般式
(Δr)n−△→ ・13− (但し代中Δ1゛;アリールJij、、llニア−・J
)、△:1、S、So 、F3:B「n 、PI+:、
 S11 I−d; 。
This j′ lyluonium salt photoinitiator (,L, general formula (Δr)n−△→ ・13− (where Δ1゛; aryl Jij, llniar−・J
), △:1, S, So , F3:B'n, PI+:,
S11 I-d; .

△Sにら)で示される。ΔS leek).

このアリルオニウム塩系光千合開始剤は11L来のシj
′ゾーウムIn形重合間!tri 剤(1) J、l>
 +L IIII!fls 物M lf?i泡が起こつ
lこり、jQU3したりりに)t−、I (!、−,/
J\イjく、また配合(か1脂のボッ1−ラぞ〕も良θ
r(゛あ0、さらにカーIAン重合CあるからWal+
気中の1蔑素1.L、よる小合用害作用もないという刊
員を有しくいる、。
This allyl onium salt-based photochemical initiator has been used since 11L.
'Zoum In-type polymerization! tri agent (1) J, l>
+LIII! fls thing M lf? i bubbles occur, jQU3, etc.) t-, I (!,-,/
J\Good, and the combination (1 fat 1-razo) is also good θ
r(゛A0, there is also car IA polymerization C, so Wal+
1 derogatory element in the atmosphere 1. L, I have a publisher who says that there is no harmful effect when using a small combination.

な631〜11ツビング法\ゝ)j゛イツピング法適用
?Jる場合は、無1幾7°iヂ15填剤やブ)ソ剤る添
加りる。J、゛)にしくT f)J、い1゜ 1Σ〉、明の実施例1 次に本発明の実施例についt IJ+!明りる1、実施
例 図面はA発明の一実施例を示り1す1面図Cil’+る
。。
631-11 Tsubing method\ゝ)j゛Applying the Itsuping method? When using, add no filler or solvent. J, ゛) Nishishi T f) J, I1゜1Σ〉, Example 1 of the present invention Next, regarding the example of the present invention, t IJ+! Figure 1. Embodiment The drawings show an embodiment of the invention A and are a top view. .

図にJ5い4反射板11−゛には銀系ベースト′/)が
ノスベンリーにより目出2)れ−(おり、さIら(5ニ
この1艮系ベースl” 2 ’7)十ににLガリウムー
砒素系fツブ3がマウン1〜され(加熱ににり接着され
(いる3、接?゛1後ブッノ°3ど小ンデrング側電極
4の間は金線1〕によって接続され(いる。
In the figure, the J5-4 reflector plate 11-゛ has a silver-based base '/) made by Nosvenry2). L gallium-arsenic type f-tubes 3 are mounted (heated and bonded) (3, after bonding, gold wire 1 is connected between the lower electrodes 4). (There is.

次にCX221 (チッソ株式会社製−1−ボ1シ樹脂
の商品名) 100Jfit部、1〜リシウリル1−リ
JAスフj・イI・1.0甲虫部、シフ1ニルニl−l
’ fffつ1XjIヘノノルA11ボ1ノー1〜3.
0Φω部’t:、−’+’l; fA+!で30分間攪
拌混合した樹脂にI tl相成物を成形用金型にL1人
し、前述し/j素子をこの樹脂組成物中に浸漬さけた後
、80 W / cmの昌j1水銀月3大I C40秒
間紫外線を照射し硬化さし!た。光ill;!との距1
1はi b (:+ll (あ・2人=3.【のi稔1
1()す(11,さ1↓る(−:、 (J j、り樹脂
月11(3,\れIご光尤/7でA する111冒、二
、1このJ、うにしく製ノ1−1また弁光りrΔ−1・
(・111成彫物の1゛1性(,1次表の通り(あり、
1分(、−jご月1(こ1ii4ンるb (1) ”C
(Ij)つI、5゜第1に 外    観         ’llt Ll’、透
明耐    湿    (’l’、   40”CX 
9!i% RHX 10(HallC輝度劣化イ「シフ 耐    熱    1〕I    12!i”(:x
  !1o01+C’ fI′ll; Ij:1.劣化
4トシ耐  半  [11雇   260°CO) ’
I’ Ill浴、20.1’し間含格通71 Wl; 
111劣化111   ン、2v  −2!im A 
X  +7(li7、帥jυ、劣化30% [発明の効!、P!] 以)説明し/;: J、・)にA\什、明の樹11i7
 II・l II弁、 )11.タイA−トは、短時間
テ硬化がl1Jfit; (あるのζ11. ili”
 f’1が高く、しから成形品の内部歪カー1リクンツ
タ、弯色がなく、;k 7;二師度の劣化も極め(少泡
い。し/)1も肉19月Jt: ’t’>可能Cあると
いう利貞がある。
Next, CX221 (trade name of -1-BO1 resin made by Chisso Corporation) 100Jfit part, 1~lisiuril 1-li JA Sufj・iI・1.0 beetle part, Schiff 1nilni l-l
' ffftsu1XjIhenonorA11bo1no1~3.
0Φω part't:, -'+'l; fA+! After stirring and mixing the resin for 30 minutes, the I tl phase composition was poured into a mold, and the above-mentioned /j element was immersed in this resin composition. Irradiate UV rays for 40 seconds to harden! Ta. Light ill;! distance 1
1 is i b (:+ll (A・2 people = 3. [i Minoru 1
1 ()su (11, 1↓ru (-:, 1-1 Also Bengikari rΔ-1・
(・111 completed carvings 1゛1 characteristics (, as per the first table (yes,
1 minute (, -j month 1 (ko1ii4nrub (1) ”C
(Ij) Tsu I, 5゜Firstly, the appearance 'llt Ll', transparent moisture resistant ('l', 40"CX
9! i% RHX 10 (Hall C brightness deterioration "Schiff heat resistance 1] I 12!i" (:x
! 1o01+C'fI'll; Ij:1. Degradation resistance 4 and a half [11 hours 260°CO)'
I' Ill bath, 20.1' between 71 Wl;
111 Deterioration 111 N, 2v -2! im A
X +7 (li7, 帥jυ, deterioration 30% [Efficacy of invention!, P!] Hereafter) Explain /;: J, ·) to A\you, Tree of Ming 11i7
II・l II valve, )11. The tie A-t can be hardened for a short time.
f'1 is high, there is no internal distortion of the molded product, there is no curved color; Toshisada says that there is a possibility C.

【図面の簡単な説明】[Brief explanation of drawings]

図面は本発明の発光タイA−1・の−実Ml1例4゛小
す断面図である。 1・・・・・・・・・・・・反射板 2・・・・・・・・・・・・銀系ベースI−1′3・・
・・・・・・・・・・Jツゾト・・・・・・・・・・・
ボンディング側’lt&[う・・・・・・・・・・・・
金 線 6・・・・・・・・・・・・封止樹脂 代理人弁理−1須 111  仏
The drawing is a 4'' smaller sectional view of the light-emitting tie A-1 and M11 of the present invention. 1...Reflector plate 2...Silver base I-1'3...
・・・・・・・・・・・・J Tsuzoto・・・・・・・・・・・・
Bonding side'lt & [U......
Gold wire 6・・・・・・・・・Sealing resin agent patent attorney-1 111 France

Claims (1)

【特許請求の範囲】[Claims] エポキシ樹脂J、たは他のカブAンΦ合性右態物貿とフ
7リルΔ−ウム塩系光ip合聞始剤とを主成分と覆る紫
外線硬化性低粘度樹脂組成物て介)Y;クイA−ド索子
(13J、びリード部を樹脂l’J +1シ1:なるこ
とを特徴とりる発光グイΔ−ド1゜
(Ultraviolet curable low viscosity resin composition containing epoxy resin J or other turnip A Φ compound as main components and furyl Δ-um salt-based optical IP initiator) Y: A light-emitting guide Δ-1° characterized by the fact that the lead part is made of resin l'J +1.
JP57164211A 1982-09-21 1982-09-21 Light emitting diode Granted JPS5954277A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP57164211A JPS5954277A (en) 1982-09-21 1982-09-21 Light emitting diode

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP57164211A JPS5954277A (en) 1982-09-21 1982-09-21 Light emitting diode

Publications (2)

Publication Number Publication Date
JPS5954277A true JPS5954277A (en) 1984-03-29
JPH0462188B2 JPH0462188B2 (en) 1992-10-05

Family

ID=15788773

Family Applications (1)

Application Number Title Priority Date Filing Date
JP57164211A Granted JPS5954277A (en) 1982-09-21 1982-09-21 Light emitting diode

Country Status (1)

Country Link
JP (1) JPS5954277A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61203644A (en) * 1985-03-06 1986-09-09 Suriibondo:Kk Manufacture of electronic component parts
US6617787B2 (en) 2000-01-11 2003-09-09 Toyoda Gosei Co., Ltd. Light-emitting system with alicyclic epoxy sealing member
US6960878B2 (en) 2001-01-24 2005-11-01 Nichia Corporation Light emitting diode, optical semiconductor element and epoxy resin composition suitable for optical semiconductor element and production methods therefor

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS56135520A (en) * 1980-02-29 1981-10-23 Ciba Geigy Ag Photopolymerizable mixture containing cation polymerizable compound and photopolymerization thereof
JPS58219781A (en) * 1982-06-15 1983-12-21 Showa Denko Kk Sealing method for light emitting diode element
JPS5919381A (en) * 1982-07-23 1984-01-31 Hitachi Chem Co Ltd Manufacture of resin-sealed light emitting diode

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS56135520A (en) * 1980-02-29 1981-10-23 Ciba Geigy Ag Photopolymerizable mixture containing cation polymerizable compound and photopolymerization thereof
JPS58219781A (en) * 1982-06-15 1983-12-21 Showa Denko Kk Sealing method for light emitting diode element
JPS5919381A (en) * 1982-07-23 1984-01-31 Hitachi Chem Co Ltd Manufacture of resin-sealed light emitting diode

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61203644A (en) * 1985-03-06 1986-09-09 Suriibondo:Kk Manufacture of electronic component parts
JPH0446449B2 (en) * 1985-03-06 1992-07-30 Three Bond Co Ltd
US6617787B2 (en) 2000-01-11 2003-09-09 Toyoda Gosei Co., Ltd. Light-emitting system with alicyclic epoxy sealing member
US6960878B2 (en) 2001-01-24 2005-11-01 Nichia Corporation Light emitting diode, optical semiconductor element and epoxy resin composition suitable for optical semiconductor element and production methods therefor
US7342357B2 (en) 2001-01-24 2008-03-11 Nichia Corporation Light emitting diode, optical semiconductor device, epoxy resin composition suited for optical semiconductor device, and method for manufacturing the same
US7550096B2 (en) 2001-01-24 2009-06-23 Nichia Corporation Light emitting diode, optical semiconductor device, epoxy resin composition and phosphor suited for optical semiconductor device, and method for manufacturing the same

Also Published As

Publication number Publication date
JPH0462188B2 (en) 1992-10-05

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