JPS5927951A - High tear strength peroxide-hardenable polysiloxane composition - Google Patents

Abstract

(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

[Detailed description of the invention]

BACKGROUND OF THE INVENTION The present invention relates to silicone rubber compositions, particularly silicone elastomer compositions having a tear strength of 100 bods/inch or greater. Heat-cured (canned) Noricone rubber thread 1] Material ('c
In this regard, many new innovations have been made so far. Such a composition is basically a diorganoporin loxane rubber having a viscosity of at least λ at 25°C.
7i1, processing aids and peroxide type free radical initiation 1lilJ
It contains k. For example, DeZuba
See U.S. Pat. No. 3,730,932, No. 11 of
Gusare/koi. In such compositions, it is necessary to modify the diorganoporin loxane polymer. In particular, it is desirable to include vinyl groups in diorganopoly/monocoxane polymers so that they can be more easily polymerized to form elastomeric products with desired properties.
Mareta. Therefore, this technology minute! Development in pj', 1) [Research on vinyl vesicles in polymer mixture
Changing the J portion of included bonds and! Rilj's in the first guard!
The first method was to use a polymer/combination formed from a vinyl group-containing polymer of tv (for example, see US Pat. No. 660.345 J!@). Another development (Jf research is vinyl group-containing borine IN xane,
- Idride Foundation - We succeeded in producing a highly viscous thermosetting silicosaccharide composition containing a borine loxane crosslinking agent and a platinum monomer together with a light filler and other components. Call me. Is the new ingredient in the composition a hydroperoxide type initiation? In some cases, the use of initiators such as VrCu, in some cases, will give a long working life to the composition.
It is possible to package the J,+i+II composition into a 7-acid-41(-) and when the 1-component is heated to a high temperature, i.e. above 100°C, it becomes a silicone elastomer. Hardenable 1, new technology & r
Bobear U.S. Patent M4. o 6 t 60
q Oborogu (Ij4: yc is described. One variation of the above composition is 7゛ in other words Wada)
U.S. Pat. No. 3,671,480/111 of et al.
J, I'm here. As the first polymer, a vinyl group-containing polymer mixture (“vinyl blend”) is
It is one history along with Toshi 11 Linricone and Platinum Lid. This US li ki Xu Ming Wholesale 1iW to ri8
The vinyl blend is a relatively high polymer containing 0.02 to 0.2 moles of vinyl groups (70 kg/unit) 1:
and another vinyl group of somewhat lower molecular weight containing at least about 2 molar units of a vinyl group, i.
It is the same as the table combination body. This United States of America,
1'+1] From the description in 'r'A, the molecule 'L11 of the second polymer has a maximum tJ (at the standard of 100.
It is considered that the OOO sensor can be less than 1 voice. This United States! The object of the claimed invention was to produce a composition of high tensile strength. Jl shown in the examples
, the tear strength achieved by one trial is approximately 50
Point V"l;'f +r should be a value indicating the divine value near pi ('bonds/inch). Another interesting 49 patent invention is POlmarlteer.
It is a thermosetting composition described in Patent No. 6.697.473 Specification 114 of JP et. It consists of wood...itride water-containing borine lokilene and platinum oxide. This US 'I'J'
! ! 'l-ming+! i':II'+4f open/J open The invention is based on the use of a mixed proboscis of a hydride type assembly.
Define one cow as an enemy. In the case of this invention, test, eye tearing is weak:
Sari, 1. In some cases, it reaches a height of about 200p and i-. 5 However, the method for obtaining products with such high tear strength is
It is thought that this was due to the use of a new Hide Two type I complex mixture by Wada et al. Furthermore, Wada et al.
' 52.475-Yumiaki A thermosetting/recone composition which has a viscosity and is mixed with a high viscosity vinyl group-containing boryloxane containing a vinyl group-containing resin having a 5 to 20 molar ratio is currently available. This composition's proboscis contains 5 as the third component.
Another polydiorganone loxane of lower 7A content containing ~90 molar vinyl group-containing units is included. is Δ亥い Temple t い ``明#、:1I-iq
The inside temperature is within the range of 1,000 to 100 at 25°C. OD O-1 = '/The viscosity between the axes of the Tebois can be one having the following 1-highest molecules; 6. This composition is -Ma/ζ71J-)J filler and is converted into (+lJ!) by organic peroxide V. 5゜p, 1.
It is lower. Another related AI M'r in this technical field is U.S. Patent No. 3.696.068. Diornoj novolinroxane rubber, 10-15 at 25℃
A linear vinyl-based liquid polymer having a viscosity of 0.000 centivoids and yet another vinyl group-containing sphere polymer 21
Disclosed is a thermosetting resin composition made of ``-!1''. This composition is cured by a base compound of; '!1 example and in particular in Tables 1, 2 and 6 exceed +00 p, i. in some cases i, but not more than +00 p, i, in some cases . . Table 1152 and Table 6 contain 'r1. +50p,
Trial 1 is shown, which has the gu and ν strengths that increase i and j'a. This 4. L], i*V, the thing is r"J ; lJ' of a vinyl group-containing liquid polymer with a viscosity of 7x1 degrees. However, the US small H' [No. 696.0.58
The inventor of the bow said, ``It is impossible to think that the tear strength was measured on the samples after surface coating. This is because it is recognized that when an a-type polymer is present (1.), after a small curing treatment, the hardness of the polymer will be extremely low.November 4, 1980 Attachment - Head of Bobear Yonee”
lI+l'F application S N 203.849, the most recent H has a vinyl group-containing borinoxane as the basic composition, which may be a mixture of boria, 0, quinano,
)・Hydora・F-do group′ with poly/Lokilean, white finance】
^ and at least one hydroperoquindo group: fill i'l! A composition containing a compound I is shown in [;1]. It is also disclosed that an organic peroxide-type 91H compound can be present in the composition to roughly accelerate the curing of the composition at high temperatures. It should be noted that the vinyl group-containing polyrin loxa/as described in 1-2 can be a mixture of the individual vinyl group-containing boria 0 and 41IJ vinyls. There is no mention of what the group-containing poly/rokinane may be or what benefits different types of vinyl group-containing polyrokinanes may obtain in compositions. 1979 1 of Obear
US patent application 6g/r 1SNi filed on February 26th
No. 06,795 AUI il, which contains organoborinoxane rubber, filler, platinum compound and 4!18
A sentence containing hydrated alumina, titanium dioxide, and rI 1 himagneum! # Field thermosetting & 14
Discloses the product. A more relevant patent is Bobear et al. 1980
U.S. 4F permit 1i”jl S filed on June 6, 2015
No. 156, 137, which describes the composition (S
A high viscosity composition containing an I H-olefin platinum catalyst is described. The patent application of Bobear et al. and Bob
ear U.S. Patent No. 4.061.609 Saimei, 11
11 'iM-described pa J, parabolic C; L hard f hit r
r+r, 1 clause or can be suppressed r'cM I+
, 7, and has a sufficient working life than the composition and stored in a one-piece container.
7' which is desirable in that it can be suppressed so as to
. In addition, the US Special Directory “No. 3.660.345
:, Compounding of vinyl blend according to the ridges'c? By applying 1 [1'] desirable tearing 6H, awns can be obtained. These compositions are vulcanizable by hot air,
In other words, since they are hardened by hot air,
It is highly desirable in that it is highly desirable for use in tubular bodies and other uses, particularly when such compositions are T
The tear strength of such compositions is limited to: ff1J when subjected to a post-curing treatment which is considered to be 1. According to U.S. Pat. No. 3,660,345 to Bobear, experiments were conducted with some success in varying the i'↓ composition of vinyl blends to increase the tear strength of such N2 compositions. Contains. however,
Now, the inventors have constructed a high viscosity polymer with two bows! By using VC with a given type of polysiloxane, the composition has a significantly high tear strength ζ ( is in almost all cases greater than or equal to 100p,i, and in some cases Id:200
p.i. We have discovered the unexpected fact that silicone elastomers can be cured. This is a complex idlide-type polymer mixture, which is difficult to produce because idlide group-containing polylinoxanes are inherently unstable, or without the use of low viscosity vinyl group-containing This was accomplished without the use of a liquid polymer, which was later found to exhibit significantly poorer tear strength after post-curing. Accordingly, one object of the present invention is to provide a noricone rubber composition containing a vinyl group-containing borinoxane rubber mixture 2 and having high tear strength. Another object of the present invention is to form a high viscosity vinyl group-containing boronolokizano mixture, a hydride group-containing borinolokizano mixture and a polypropylene type curing agent, after a post-curing process,
. Yet another object of the present invention is to prepare a vinyl group-containing polyline loxano compound, 5100 p, formed from a vinyl group-containing polysiloxane and a peroxide-type curing agent.
The object of the present invention is to provide a method for producing a thermosetting noricone elastomer composition having a tear strength equal to or higher than . Yet another object of the present invention is to provide a high viscosity vinyl-based borine-rokinane mixture, a no-hydride group-containing borine-rokinane crosslinking agent and

[Formed from a chemical hardening agent / 100p
The present invention provides a medical tubular body and a spark plug boot that have a tear strength greater than or equal to . These and other objects of the invention are achieved as detailed below. SUMMARY OF THE INVENTION In accordance with two objectives, the present invention comprises the following components: (A)
Contains 540.005 to 0.540% of vinyl units having at least one vinyl group bonded to silicon and having a viscosity in the range of 1 x 10 to 20 x 10 centiboise at 25°C.
A linear diorganoborinoxane rubber with a vinyl group yield that can range from 1 molar to 60 to 95 moles and a first vinyl end group in which the organo group is a monovalent hydrocarbon group: <B ) a second vinyl group-containing diorganoborin compound having a viscosity in the range of 1×106 to 20×107 centipoise at 25°C, a vinyl group solubility in the range of 05 to 15.0 molar units, and a carbohydric hydrocarbon group; As the concentration of the second vinyl group-containing rubber in the stock composition decreases from 400 parts by weight to 50 parts by weight, The molar vinyl group degree (of the vinyl unit having at least one vinyl group) shall increase from 0.05 molar to 15.0 mol. Filler which is a filler with a weight of 10 to 300%; (D) 0.05 to 50 ni A hydride group having a layer of 0.05 to 50 ni and a viscosity in the range of 10 to 1000 cm at 25°C Contains 0 borinoxane
．． 1 to 25 Jushabu; and (Jl) At least 1 free radical initiation (Suno/self-effect: 1
a curing agent selected from the group consisting of an organic peroxide and an organic hydroperoxide present at a concentration of 1 to 1; Poly/loxane compositions are provided. The method for producing this composition is basically to mix all of the above-mentioned components, and then heat the resulting composition to a temperature of 100°C or higher for a period of 60 seconds to 30 minutes. Consists of things. The vulcanization process is preferably a hot air gallosulfurization process, which is particularly suitable for the production of medical tubular bodies and spark plug boots because of its high tear strength. Of course, to produce a composition with high tear strength, some silica is required in the composition. A filler must be present, preferably in 4f. - It is clear that reinforcing fillers such as mud/liquid and precipitate must be present. Although a platinum catalyst can be included in the composition to accelerate curing, it is not essential; i.e., a platinum catalyst may or may not be used. EMBODIMENTS OF THE INVENTION Before describing the present invention in detail, a method for curing a vinyl-based compound in the presence of a binder and an hydride compound is described by Irving Wender and P.
i e r o P i n o 5ii 6th volume “Or
ganic 5ynthesis ViaMetal
Carbonyls”, Volume 2, Page 676 (1977
) It is necessary to state a known fact, as described in 2. However, using a specific type of diorganopolynoroxane rubber 1''vinyl blend'',
It is not known to produce a compound with high tear strength by reacting this with a hydride hariboline loxane and a peroxide type curing. Now, to explain the present invention, a polyrinloxane composition according to the present invention without stirring: 1 x 106 to 2
It has a viscosity in the range of 0x107 centivoise and 0.00
A linear type having a first vinyl wood end, 1, having a vinyl group, a degree, which can vary in the range of vinyl water content of 5 to 01 moles, and an organo group being a monovalent hydrocarbon group. Contains 60 to 95 overlapping parts of diorganopolysiloxane rubber. This polymer, which is the first feature of the present invention, often has a vinyl group only as a terminal group. However, this polymer may also have vinyl groups on the chain according to the vinyl water content of rubber. This polymer is 1,000,000 = 200.000 at 25℃
．． OOO centiboise viscosity, more preferably 1 to 25℃
It should be noted that the rubber has a viscosity of from 10,000,000 to 100,000,000 centiboise.2 Additionally, in preferred polymers, the mole content of the vinyl groups is from 0.0+ to 0.008 molar range. The vinyl group-containing rubber having the formula: represents an 8-valent hydrocarbon group; The viscosity of the rubber is more preferably in the range of 1×10 7 to 15×10 7 centiboise at 25°C. The group R can be any 01-8-flanked hydrogen group, such as an "alkyl group having 1 to 8 carbon atoms such as methyl, ethyl, propyl group, etc.; tunyl; a monoaryal aryl group such as methylphenyl group; 3.3. Fluoroalkyl groups such as 3.3-trifluoropropyl-1; The group R can be any substituted or unsubstituted flanking hydrogen radical that is inert.
1 may be selected from any of the groups mentioned above for R and further alkenyl-groups such as vinyl, allyl groups, etc. The group R11l'i is most preferably not an alkenyl group. l Coxanogum (I
It has a viscosity of lx106 to 20x107 centepoise at 25°C, has a vinyl group concentration in the 05 to 150 molar range 1:l, and has a vinyl group mole %ilJ LCL.
As - increases from 0.5 molar to 15 molar, the yield 1θ- of the second vinyl group-containing rubber in the composition decreases from 400 parts by weight to 50 parts by weight, and the organo group increases from 5 to 50 parts by weight. Another vinyl group-containing diorganoporin loxane rubber which is a flank water group is incorporated in an amount ranging from 50 to 400 parts total. In the present invention, in the vinyl blend of the second vinyl group-containing diorganoborinoloxane rubber, when the degree of fabrication is true/shi, the molar ratio of the vinyl groups (the The most important thing is the 1F faction.
J'tt, meaning that it increases or that]
One feature of r\ can be preserved. however,
The second vinyl group-containing rubber is vinyl with a mole ratio of 10 to 15/
If it contains Logi/R1 position, d2, it is ++':”
In l acid (・first vinyl group R-containing rubber 80-60jl
j;
j The concentration of the upper part of the body is ヰυ. High vinyl fund! If a rubber having a viscosity of 11% is present in a composition with a viscosity as high as 1; It is preferable that the viscosity of the rubber increases within the dIi range mentioned above and its vinyl content decreases. Therefore, the concentration of the second vinyl-based rubber in the vinyl blend is As VC increases, it is inevitable that the molar concentration of vinyl groups in the rubber decreases within the above-mentioned range 1. 1, the group concentration is between 0.5 and 10 molar or less;
Further (f(,,'ii viscosity of vinyl group-containing rubber)
, 1~2oo at 25℃? It is preferable that the amount of charge is +oa senderboise r. The viscosity of the above two types of rubber is as high as possible within the above-mentioned viscosity limit.
Experimental results show that 11 elastomers have higher tear strength when using higher viscosity vinyl blends.
Indicates that J is done, h, ta 0, and these two 1:
I'Iff+ gono, of, tlt formation's proboscis (・1 mountain and river range Keni 1° first vinyl end "1ln211 negative wired diorganobo") '/IJ
Kizan rubber 70-95 Hand', i; part and second vinyl group a-containing diorganopoly/rokinan rubber 5-30
It is preferable that the second vinyl group-containing rubber (in the chain) contains a vinyl group only in the first position of the second vinyl group-containing rubber (in the chain). However, the broader practicalities of the invention! In the embodiment, the vinyl water-containing path limit 14° is
It may have a vinyl group in the lido chain and a terminal vinyl group within. It is important that both of these vinyl group-containing rubbers do not contain vinyl groups at a high concentration exceeding the above-mentioned limited range. Polymerization 1+ The presence of excessively high m1 degree vinyl groups in the mixture causes the cured elastomer to have optimal tear strength! It will not have any value. Furthermore, all of these vinyl group-containing rubbers have the above-mentioned l1jjj, viscosity of the surrounding area, and vinyl,!
It should be noted that it may be a single type of polymer or a mixture of separated polymers. It is important to note that liquid polymers should not be included, ie, for example, vinyl-containing liquid polymers with a viscosity of the order of s o o, o o o centiboise or less should not contain liquid polymers. Initially, an elastomer with good tear strength is used, but after curing with this i:LL compound, the tear strength is significantly reduced. The second vinyl fund fixed-range combination is preferably r(゛(in the formula,
R2 and R4 are C1-8 hydrogen radicals, R3 is a C1-8 hydrogen radical containing no aliphatic unsaturation, and W and 2 are C1-8 hydrogen radicals containing no aliphatic unsaturation; In the range of 1 x 106 to 20 x 107 centimeter voice [month, G ry 1L < 1
2. The number is such that it is within the range of 20 x 106 to 100 x 106 centepoise on c). The vinyl group concentration of the rubber is in the range of 0.5 to 150 mol %, but as the vinyl group concentration approaches 0.5 mol %, the viscosity of the rubber increases. This point constitutes another particular enemy of the present invention94, namely, that rubbers with high viscosity and vinyl undertones within the above-mentioned enclosure will give compositions with poor tear strength when cured. Must be something undesirable. The group R3 can be any group described for the group R in (1) filled in with -. Furthermore, the groups R2 and R4 are of the formula -F (''
) of I,! , +H can be any of the CI to 8-flanked hydrogen atoms, and can also be vinyl, allyl ring alkenyl groups. Vinyl group-containing rubbers are produced by methods well known in the art, such as by reacting vinyl group-containing cyclotetranoxanes at elevated temperatures in the presence of a basic catalyst and in the presence of a low molecular weight linear vinyl chain terminator. It can be produced by a method to obtain a polymer with a molecular weight of λ. 3. After the completion of the reaction, the desired polymer is obtained by neutralizing the reaction mixture and removing excess horizontal compounds. When the amount of chain terminator and reaction temperature are divided, r by k
9 "Detailed information on the method for producing the vinyl group-containing polymer that can control the desired vinyl group-containing polymer final product molecule: 6"
It is described in U.S. Pat. , 10 to 300 parts by weight of a filler, at least a part of which is a reinforcing silica filler, is blended per 1 weight part of a mixture of vinyl water-containing rubber, that is, a vinyl blend at 10°C. It is necessary to incorporate the reinforcing Norica filler into the composition in order to give the composition a high tear strength, especially a tear strength of 100 p, i, or more after post-cure aging treatment (=1-ri). A range of reinforcing silica fillers that can be used are, for example, heated/silica and precipitated silica, with heated/silica being particularly preferred. Heated or precipitated silica helps the uncured composition form a structure. Various treatment agents for residential protection, such as Lucas
As described in U.S. Bamboo Wr. No. 2,938.009 Specification ■
．． The reinforcing filler generally contains 10 to 200 parts by weight and/or (/:l).
I is used in a concentration of 3 to 100 parts by weight and further other extender fillers can be used in the composition. Expanding fillers that can be used include, for example, titanium dioxide, lithopone, zinc oxide, zirconium silicate, silica aerogel, iron oxide, diatomaceous earth, lunorum carbonate, glass fiber, magne oxide/1 cum, 1't/chromium oxide, The material is selected from the group consisting of zirconium oxide, aluminum oxide, alpha quartz, -5 carbon, graphite, cotton and synthetic 4Hi9 fiber. Some of these fillers can be utilized to impart additional properties that are desired in the composition for some reason. Although it is not essential to incorporate fillers, especially hyaluronic acid, in order to produce Noricone elastomers, it is essential to incorporate fillers, especially if it is desired to produce a 7-in-1 material with high tear strength. [i4 no Hi. - It should be noted that it is necessary to incorporate mud/liquid into the composition. Furthermore, a vinyl group-containing diorganopolynoroxane mixture 1
00 weight...Specific hydride group-containing polyoloxane with 01 to 25 weight parts per part, that is, 005 to 5 weight,
(preferably in the range of 0.005 to 2% by weight), having an idlide water content of 10 to 1000 centiboise at 25°C;
A hydride group-containing polyoloxane with a viscosity I (I) in the range of 10 to 100 centipoise at 25°C must be blended. The hydride group-containing polyoloxane preferably has the formula: (wherein R5 is C1-8- containing no aliphatic unsaturation)
It is a group selected from flank hydrogenated groups, and p and q are groups whose viscosity of the hydride group-containing polynoloxane is 10 to 10 at 25°C.
00 centivoise, more preferably 10-10 at 25°C
0 centivoise and a hydride group content ranging from 0.05% to 2.0%. 3. It is desirable that the hydride group-containing polyoloxane does not have an excessively low hydride group content. Otherwise the composition will not fully cure. On the other hand, if the hydride group content of the hydride group-containing polyoloxane is excessively high, an excess of .
Acting as an iJ plasticizer, the composition would not fulfill the intended purpose of having as high a tear strength as possible. The hydride group-containing polynoloxanes of formula (3) can be prepared by various methods known in the prior art, particularly by the suitable hydrolysis method of lorrunran. For more details on the production of hydride water-treated borinoxane +MII, please refer to US Pat. No. 4.041.010. Another type of idlide-type crosslinking agent that can be used in the present invention has the formula: is a hydrocarbon group and R”+H
The ratio of resin to S1 is in the range of 1.0 to 2.7), and the number of idride funds of resin is 005 to 2 & dechi (7
) It is a garden resin containing a hydride group with a radius of 1lili. No matter which number of the hydride group-containing polynoloxane of formula (3) and the above hydride group-containing resin,
It should be noted that the radical R6 can be any of the radicals mentioned for the radical R of formula (1). These groups can be any substituted or unsubstituted hydrocarbon groups that do not participate in the hydrogenation reaction. Idlide group-containing resins are also suitably prepared by hydrolysis of lorrunrane and its purification. Yet another type of no-idlide group-containing resin is one that contains difunctional units. That is, this type of idlide group-containing polynoloxanes which can be used in the present invention has monofunctional units of the formula:
iO difunctional unit (wherein R6 is a group selected from auto- to 8-valent hydrocarbon groups containing no aliphatic unsaturation, and R
It is a -.hydride group-containing resin having a ratio of +H to S1 in the range 111 of 12 to 27. The radical R6 can be of the same monovalent tetracarbide radical caution as indicated for the radical R of formula (1). As previously disclosed and discussed above, basically most of the groups in these polymers are methyl, phenyl and vinyl groups, and these are the most easily produced groups. It should be noted that borynroxane is Some phenyl substituents in the phenylbolysiloxane or polylinoxane may be useful for imparting certain properties to silk fabrics. Otherwise iC
It is preferable that the poly/loxane contains only a methyl group as a substituent for those containing a hydride group, and a methyl group and a vinyl group as a substituent for those containing a shredded vinyl group. These are the most simple and inexpensive borinoxanes to manufacture. Furthermore, the hydride group-containing difunctional 70-unit contains 0.05 to 20% by weight of vinyl groups (it is preferable to have a difunctionality. Does it contain a di-functional 70-unit)? Idride group-containing resins are also well known in the art, as shown in U.S. Pat. can be used as a crosslinking agent in compositions of Furthermore, such a hydride crosslinking agent is
:'J'i' 4. D 4 l can be produced by the well-known method (as described in Appendix 7 of D10). Finally, in the compositions of the present invention, a curing agent, which is generally an organic peroxide and a hydrocarbon initiator, is preferably present in a minimum therapeutic amount. I have to let it happen. Examples of suitable organic peroxides are described in U.S. Pat.・-Okinodo. Cumene hydroperoxide 7, 1, 1, 6. s-tetramethylbutylhydro.zeta.-oquindo and dimethyl2.
5-sibide roba-oxane/hexane. Preferred peroxides over 4 are organic peroxides, particularly those peroxides that are particularly effective against vinyl groups.
l is an organic peroxide commonly used to harden silicone elastomers. Some of the peroxides that may be used have the following structural formula: where R is all the same alkyl group or - two or more different types of alkyl groups, and a is an alkyl group of 0 or greater. It's a match)
It is a dialkyl peroxide which can have the following properties. . Examples of dialkyl peroxide curing agents that can be used are di-6-butyl-butyl-6-butyl-butyl-6-butyl-butyl-6-butyl
Included are tertiary triphenyl oxide/oxide, tertiary buterperbennoate and di-tertiary alkyl peroxide such as dicumyl oxyoxide. Other peroxyduct catalysts that achieve curing via the Norikono chain-'40;tll and unsaturated hydrocarbon groups include aryl peroxides, including chloraryl peroxides, such as 2.
4- Cyclolbenzoyl peroxide, parachlorbene 7ylperoxide, orthochlorbenethylperoxide. Includes benzoyl chloride and the like. The first dialkyl peroxide is 2,5-dimethyl-2,5-bis(
It was found to be 1-butylperoxy/)hexane. Accordingly, the most preferred peroxides are vinyl group specific peroxides and peroxides which have been found to provide curable compositions with the best tear strength include, for example: do. 2,5-dimethyl-2,5-di(t-buterperoxy)hexane 2,5-dimethyl-2,5-di(t-butylperoxy7)
) Hexyne-6 di-t-buterperoquine 5-bunalcumyl peroquine α, α′-bis(t-buterperoquine) seainozo r
Preferably, the pyrubenzene curing agent is present in an amount of at least 0.11 parts per 10 parts of the remaining components of the composition, more preferably 100 parts of the remaining components of the composition. Hit 0
One to two parts of the curing agent, particularly peroxides, are used. It should be noted that there is no critical limit as to the specific concentration of peroxide used in the composition that provides the best tear strength properties. Finally, 1 to 500% platinum is added to the composition as a curing accelerator.
ppm may be present. Platinum is blended as a platinum compound, particularly as a type of platinum catalyst compound well known in the art. The platinum catalyst that can be used in the compositions of the invention can be platinum supported on a solid support, such as platinum on charcoal or platinum on d gamma alumina, or platinum on d [0] Platinum complexes that have been solubilized are more reactive and are therefore preferably used in the compositions of the present invention.A preferred platinum complex is a platinum complex that can be present in the reaction mixture of the present invention. The platinum compound 1 is a gonadal gland and 7. The platinum compound 1 is a gonad.
1',"l,j!'l'The expression (p
tct, onofine)2 and H(P, tC13onofine). In the above two formulas, 7J (olenoin) can be almost any type of onophine, including alkenine of 2 to 8 carbon atoms, chloroalkene of 5 to 7 carbon atoms, or styrene. It is preferable that
14) Examples of 11'8 constant olefins: ethylene, propylene, styrene. These are isomers of octerene, noclopentene, /clohexene, nclohebutene, etc. Another platinum metal substance used in the compositions of the present invention is A
"Platinum chloride, chloropropa", which is fully described in US 'h M'i No. 3.159.662 specification of shby.
:'i-form (ptcz2・C3H6)2. Furthermore, with a platinum-containing substance, Lam01"eaL
IX America! Permit No. 3,220,972. Formed from chloroplatinic acid as described in the specification and a substance selected from the group consisting of alcohols, ethers, aldehydes and mixtures of alcohols, ethers, aldehydes and the like at a ratio of 2 moles per 12 parts of platinum.
There can be 411 bodies. Not only as a white 6-no-solvent solvent, but also as an additive for flammability.
1. Preferred platinum alloys to be used as 1. 'Kareiiedt's rice 1i14
- Te M no. 5. 7 7 5. 4 5 2 shi)
Generally speaking, platinum complexes of this type contain I□i containing 4 moles of water.
It is formed by reacting lW platinic acid and tetravinyl clotetra/loxane in the presence of sodium bicarbonate in an ethanol solution. The Karstedt or Lamoreaux catalysts are preferred for use in the thread coating of the present invention because they are the most reactive and allow the overall curing rate of the composition to be most easily controlled. Most preferred K a r
The catalyst of s'l; e d t is a complex of general PC alknylboria 0quizano and platinum and is substantially free of oxygen groups. Platinum catalysts may or may not be used conveniently. High tear strength due to composition! I
) to improve the properties or to harden the composition.
However, platinum acts as a curing accelerator. Examples of other components include processing aids. For example, 11 parts (1 to 25 parts) of processing aids per 100 parts of vinyl group-containing diorganopoly/loxane rubber used as a base. It is desirable to use a high viscosity composition.
2 mills and secondary processing equipment - required for processing/rice processing. The second auxiliary agent can also be a dihydrocarbon-substituted borinoloxane oil in which the ratio of negative group to II element -f is from 1.6 to 20, and the hydrocarbon substituent hamethyl,
Consisting of at least one group selected from the group consisting of ethyl, vinyl, allyl, cyclohexenyl, and phenyl groups, the poly/rogylene oil has one or two y-monomers bonded to each terminal silicon atom. It consists of a boria-coyazane molecule containing all of the lower alkokino groups, and the alkokino groups are selected from methoxy, etochyne, propochyne, and butochino groups. Hydrolysis as already detailed for the production of the combs of formula (1) for the production of alkoxino group-containing 1-hydrocarbon f6-hydrated poly/roxane oils which can be used as processing aids in the present invention;
5Q' (one or more types of dihydrocarbon-recursively substituted dichloro-7-ranes and dialkoxy/rans) of one or more types according to the polymerization and fractional distillation process. /roxane, and then mixing the one or more cyclic noroxyherines thus prepared with a predetermined amount of dihydrocarbon-substituted dialcoquine 7, and passing the mixture under side-legged column f. Equilibration treatment to end with desired alkokene groups: , :j, : 1. 'l'l stopped hydrocarbon 1 conversion linear borinrokizanura 1! ). The alcoquine group-containing hydrocarbon-substituted borinlogisan oil suitable for use in the present invention is a relatively low molecular weight poly/logisan oil with a molecular weight of at least 4 to 35 IW and above. 4 These bolineroxane oils have an average of at least one and no more than two alkoxy groups bonded to zero or each of the terminal silicon atoms of the molecule. A more detailed description of the ZI-terminated polyoloxane oils and their method of preparation is given by Fekete, U.S. Pat. No. 2,954,65.
Book No. 7, No. 9, Ill.
I want to be G. Furthermore, as a processing aid, 70 silicon atoms (1/M1
silicon (containing C-bonded hydroxyl groups to 2 silicon-bonded hydroxyl groups per silicon atom and 19 to 21 hydrocarbon groups per silicon atom) Hydroxylated organonolenes may also be used, with the remaining valence of the silicon atom being leaked by an oxygen atom. In addition, hydroquinolated organo7ranes contain both hydroxy/luno, (ionic noroxane and redundantly condensed) It is a mixture of hydroxylated subluganoloxane.There is no specific composition of hydroxylated subluganoloxane, and in the 1.9 organo7 run, there are 70 atomic groups on 5 OH), L :
There is a requirement that two OH groups of one or one silicon group be present. The hydroxylation/roxane can be prepared by any suitable method V (thus, for example, when the noroxane is combined with steam and pcυ1+ I
i, E ``l・, by heating to about 120 °C In', 1 dust, i fL N: formula Rn5iX4-n (,
In the formula, . The former /l:, represents the production of a hydroxylated product in which hydrocarbon J1 (is an alkyl group) /('(0
while the latter force YJi fd is hydroxylated/where the hydrocarbon group is a ring aryl hydrocarbon group
It is the best for the production of Roxane. From now on,
MY'' 7 (11:Q: Explanation! d Konkle et al.'s rice IJ = l special 7iQ 2nd.
890. +888” Details: 4: Il? I want to see 1) since I haven't posted it myself. Any item 'f-'i' in the above-mentioned range can be used as a compound. Additionally, other suitable additives are also contemplated for use in the silicone rubber compositions of the invention. As mentioned above, the rubber composition of the present invention has a high viscosity when it comes to processing aids. It is desirable. In general, in the final product of the present invention, U: 3rd vinyl group-containing/loxane, and 4 vinyl group-containing/loxane resins may be blended. Vinyl') 1; The use of resin containing resin has a composition with good enhanced tear strength:
, was recognized as being able to control sexuality. Therefore, A1 of the present invention (V'cO: J:,
) 1 (wooden vinyl group-containing diorganoborine loxanogo)
/11': 1 to 50 parts by weight per 100 parts by weight of the compound;
S i, O(,,5'l' Ij potential unit and H5io
2 Tetrafunctional 'ii position (in the formula, ] (8 is a vinyl group and aliphatic unsaturation) consisting of 5 monovalent hydrocarbon groups (H
) k 'i'1'l'; capability 1i
'l-place vs. 4' 1) Hiroku Hanawa Tsuno 05su of Nohaku unit 1
About 25 to 10 molar ratios of silicon'JL-X atoms are bonded to the silicon so that the ratio is not L1 to 1, and the /c vinyl group is present. It should also be noted that the resin (d) should not contain hydride-type groups. Similar resins having difunctional difunctional 70 Gin units can also be used.Thus, in the compositions of the present invention, the basic vinyl group-containing diorganopoly/roxane rubber 10
0 weight n: 20 to 50 weight h ↑ parts per jf15 of organoborin loxane resinous conjugate, that is, RgSiOo
, 5 Monosensory;! V small unit and S i 02 tetrafunctional) (1 unit and R85iO difunctional lipid unit (in the formula, R8
is a group selected from the group consisting of vinyl groups, aliphatic groups, carbon atoms, arsenic groups, etc.) in which the ratio of monofunctional intermediate to tetrafunctional monophasic units is o5. 1 to 1 to 1 and the divalent functional units are preferably present in a proportion equal to about 1 to 10 mole percent, based on the combined moles of /lo7 units in the copolymer. and the resinous copolymer is about 25
An organoborin loxane resinous co-prepolymer containing ~10 moles of vinyl groups may be further blended. Although it may be heated, it is more preferable to blend the basic vinyl group J-containing diorganoborisiloxane rubber a compound Qf//J100 at a concentration of 5 to 25 parts by weight per nail part.Such a vinyl group-containing resin is It was observed that a well-cured elastomeric composition with good tear strength was formed even after the post-cure aging process.Unlike the low viscosity vinyl-containing liquid intermediate, the vinyl-containing resin The compositions containing the copolymers have good tear properties, i.e., better than +00 p,i, even after post-cure aging treatment7.
Such resinous copolymers are known and can be produced by methods well known to those skilled in the art and can be used with good results as described above. These resins are usually prepared by hydrolyzing W (7 runs), a method well known to those skilled in the art, for more detailed information on these resins. See U.S. Pat. All other ingredients of the Gods type may be incorporated.In addition, other processing aids and other ingredients of the Gods type, such as DeZu, ba et al. US Pat. No. 3.73'0.932) [! Binding additives may also be incorporated into the lubricant compositions of the present invention as described in . 4. However, the following ingredients are (a) essential basic ingredients in the composition of the invention, and optional additions as mentioned above are added as desired, i.e., specific additions as mentioned above. D[I engineering assistant 1111 parent is a platinum catalyst or a resin containing vinyl groups.The addition of these ingredients achieves the desired effect and, as mentioned above, produces a specific effect, for example adhesive +'-t' tongue. -Other ingredients can be added if desired to inhibit f1. It can sink. Specifically, in the case where platinum is present in the poly(oxide), there are also compounds containing platinum in the acid. Furthermore, the composition of the present invention can be prepared in a divine manner without adding 11 ml of platinum to 1/(platinum) with or without platinum. i'i
When combined with 117-11T12
It can be mixed and stored as is without adding chemicals. This ice product is subjected to secondary processing. In the table, the 5.11 composition is milled, 10% peroxide is added, and the composition is then heated to 100°C or higher. ! 60fA per degree
The cured elastomer can be cured by heating for -60 min.
Ten degrees above 00℃? ! u' can be post-cured and aged for 1' to 41R4' in degrees. Means of vulcanization (hardening) and heat 9.13. Ki Ka 114i: Also, 1 shoulder, 7 dust 74 by other means. . In another method for preparing the composition of the present invention, the composition may be formulated with a hydride, especially if platinum is present, a hydride, a water-containing boria, a hydride, and a separate In this case, vinyl group-containing noroxane and platinum i-J: 1rfl-packaged in a package, then the composition is cured i♂'',
Then, mix the two compositions of P and Icage, and apply J stain with 1'I &1'I' and 2'Hydroperoxide' and 7' hardening agent gold 7.
The composition is then heated to a temperature of 100° C. or higher for the time specified above. Packaging method and manufacturing method of the composition used
Regardless of the applicable law, it is preferable that the percarbonate catalyst is not added to the composition until just before the composition is vulcanized, that is, just before it is formed into the desired shape. In some cases, the degassate catalyst may be added in advance, but this is accompanied by the problem that the peroxide tends to settle during storage. Therefore, it is usually impractical to add peroxide to a composition prior to milling the composition, adding it to the desired mass, and vulcanizing it. This method provides high tear strength, i.e. 1
00p. 1, in some cases more than 200 p, i, with a tear strength of more than 100 p, even after post-cure aging treatment. and other kidnappings. Examples are given below for the purpose of illustrating the invention. However, these examples are not intended to limit the invention in any way. In the examples, all parts are as given below. Example 1 80 parts of dinonalborinroxano rubber with vinyl end groups having a viscosity of 5.33 x 10' centipoise at 25°C and 06 molar vinyl having a viscosity of 4.54 x 1'07-hinbupoise at 25°C. A composition was prepared from 20 parts of a dimethylpolysiloxane rubber having all trimethernoroquine groups 'j':lij groups on the chain, and the viscosity of this mixture at 25°C was about 5 x 107 centeboise. To this mixture was added 15 parts of dimethylpoly/loxane with hydroxyl end groups as a processing aid. Furthermore, 42 parts of heaped glue treated with octametheroclotetranoloxane was added to this jJA compound. Then, a Fl
2 parts of a linear borinoloxane having a viscosity of 0.72% to 1.0% by weight were added. This mixture is part 1
0081bO, cured with 5 parts of 2,5-dimethyl 2,5-ditertiary butyl peroxy/hexane, this mixture was further danced for 10 minutes at 650° C. and the properties were d'r-valued. was collected. Additionally, this mixture was post-cured by further heating in an oven under IJ 550 for 2 hours and its physical properties were evaluated. The results are shown in the table below. Physical properties Press hardening Oven heated durometer hardness 45 49
Tensile strength psi 1169 122
2 growth % 720
650 tear strength die B) pi 2
02 215 Fruiting Turtle f row 2 Vinyl powder with viscosity of 2.6Xi07 centivoise at 25°C: 'jfA dimethylpoly/roxane rubber 8
A second composition was prepared consisting of 20 parts of dimethylpolynoroxane rubber with a viscosity of 4.65 x 107 centipoise at 0 parts and 25°C and a vinyl water content in the chain of 0.6 molar. This mixture has a total vinyl water content ranging from 18 to 2.4 F functional units and a ratio of F functional units to tetrafunctional units of 0.
．． 17 parts of a ky/lene solution containing a vinyl group-containing resin containing equal to 6 monofunctional vinylmethanolokine units and tetrafunctional 5i02 units at a solids content of 60% were added. To this mixture were added 3 parts of the same processing aid as in Example 1 and 60 parts of heemdonica treated with the same octamethane clotetranoroxane as in Ri 111. Heated for 1 to 11/! hours and cooled. To 172 parts of this cooled mixture was added Example 1.
Dimethylpolysiloxane oil 63-fold one-leaf Baro with the same hydride group porin-polyxane 6 parts and a viscosity lower than + o o, o o o centiboise at 25°C and with trimethylnoroquine end groups. Varox powder (Varox is R, Go, V
under-bilt Co, product name 5
0 weight ratio 2.5-dimer r-ru 2.5-bis(1-
5 parts of a curing catalyst composition consisting of 50 parts of hexane and 67 parts of hexane and 50 parts of hexane and an inert diluent were added. 350% of the composition without changing the physical properties of this fl' acid.
'F for 10 minutes, then its physicality q7f
f71! If the constant is 17, then the resulting composition is 40
49;'11i-j] and then heat treated/Then its physical properties were evaluated by measuring/ζ0. The obtained physical Fj and quality are as follows.
Bi% 680
400 tear strength (Dai B) pi 297
'248 Example implementation [A composition was prepared consisting of the same rubber containing vinyl end groups as pH 2 and the same rubber compound as Example 2, consisting of a rubber containing vinyl groups in the chain. (14 at 25°C instead of vinyl group-containing (tJ IIM used in +jl 2)
1275 parts of a vinyl group-containing siloxane oil having a viscosity of 10 centivoise was added. This vinyl group-containing oil contains 2 molar units of methylvinylnologin units and has a trimethylnologine powder]:IM group. To this composition were added 6 parts of the same hydride group-containing polyroxane used in Example IK and 3 parts of the same catalyst system as in Example IK. The composition also contained the same processing aids as in Example 1 and a humid/lica treated with octanoterne clotetranoroxane. Example 2
The difference between the composition and the composition of this example is that a vinyl group-containing oil was used instead of a vinyl group-containing resin, and the concentration of the hydride water-containing right column j1h. 35% of this composition
0'F for 10 minutes and evaluate its properties.
did. The composition was then post-cured at 400°F for 4 hours and measured on a durometer of 68 degrees.
72 tensile strength psi 1064
976 growth % 40
0 170 tear strength die E) pi
303 80th V said/Kotori,
Compositions prepared with vinyl group-containing oils had low strength after post-hardening aging, which is undesirable in the compositions of the present invention. Example 4 Dimethylpoly/roxane rubber 80 with vinyl end groups with a discrepancy of 6.25 x 107 centipoise at 25°C
part and has a viscosity of 4.38 x 107 centiboise at 25°C, and V-vinyl-! A composition having a viscosity of 5.7 x 107 centepoise at 25°C was prepared by mixing 20 parts of a dimethylpolynoroxane rubber containing 06 mol% of I5 and having a trimethylnoroquine end. Two parts of the same processing aid as in Example 1 and 40 parts of Heamed/Rica treated with octamenalun clotetranoroxano were added. Furthermore, 1 part of the same hydride group-containing polylinoxane as in Example 1 was added to this mixture, and 0.15 parts of Notel Ether Katon Peroxide solution was also present as an inhibitor. This composition was cured using 0.5 parts per 100 parts of 2,5-menal-2,5-bis(1-butylperoxy)hexane. 350'l of composition? The physical properties were evaluated by pressing once for 10 minutes. The results are shown in the table below. Durometer hardness 5゜Tensile strength p
si +297 elongation L3666
゜Tear strength die B) pi 149 Example 5 Another B, TE 411 product having the same composition as in Example 4 was produced. This a1 composition was dance cured for 10 minutes at 350°C to determine the physical properties. This composition was then post-cured by oven heating at 400 °C for 4 hours to evaluate its physical properties. The results are shown in the table below. Durometer hardness 51 53
Tensile strength psi' +308 135
3rd grade middle school
660 560 tear strength °C die B) pi 23+ 144
Example 6 80 parts of vinyl-terminated dinotyl polyoloxane rubber having a viscosity of 2.19 X 107 centiboise at 25°C and a dinotyl polyoloxane rubber having a viscosity of 4.38Xi07 centiboise at 25°C and having vinyl groups in the chain of 06 molar fraction A vinyl group-containing rubber mixture was prepared consisting of 20 parts of dimethylborinoloxane rubber with 7-terminus. The rubber mixture had a viscosity of 2.5 x 107 centipoise at 25°C. To this mixture were added 4 parts of the same 7-ranol-terminated dimeterporin loxane oil processing aid as in Example 1, 64 parts of octamethylcyclothitra/loxane-treated heated/hydride, and the same -hydride as in Example 1. 1 part of a group-containing crosslinking agent and 0.0 + 5 parts of methyl ethyl ketone peroxide as an inhibitor were added. . This mixture was added as a catalyst to 100 parts of the composition and 0.5 parts of the composition.
．． 5-dimethyl-2,5-bis(t-buterp-oxy)hexano was blended. The resulting composition was press cured at 350 °C for 10 minutes and then heated in an oven at 4 °C.
Post-cure for 4 hours under 0.00°C. The results are shown below. Durometer hardness 70 7
'5 Tensile strength psi 1176 1
184 Extension Section 410
, 330 tear strength die B) pi
177 177 Example 7 Actual hfu <911 Same as...Idride group-containing borinoxano oil was used in place of 2 parts of /ζ and 0.5 part was used as a catalyst, and in place of the catalyst shown in Actual Example 1. Composition 1
A composition identical to Example 1 was prepared except that 0.28 parts per 0.00 parts of dicumyl chloride was used. This composition at 350'F for 10 minutes. After press hardening treatment, the following 9 physical properties are obtained /
3゜durometer hardness 43 tensile strength p
Si 1+03 offshore staff
700 undertow strong die B) pi
EXAMPLE 78 A composition identical to that of Example 7 was prepared, except that the same --hydride group-containing boria 0 chizano oil as in Lm B'll 7 was used, but 2 parts instead of 05 parts. This composition was dance cured at 350 T for 10 minutes and its physical properties were rated J'r. The results are shown in the table below.
Squirrel. Durometer hardness 39 tensile strength ps
i 110+ Elongation % 820 Tear strength die B) pi 120 Example 9 Same as Example 7... except that 4 parts of hydride group-containing borinoloxane oil was used! A composition identical to Example 7 was prepared and its physical properties 7)1 were evaluated after press curing the t[1 composition for 10 minutes at 350'F. The results are shown in the table below: 1 Durometer hardness 39 Tensile strength ps
i 1155 Elongation % 870 Required strength die B) pi 199 As shown in the examples and in the general description (C detailed/hereinafter, in each case the concentration of the particular vinyl group-containing polynoloxane rubber mixture ,
) The idlide group-containing poly/roxane oil concentration and peroxide concentration must be balanced to give a system with optimal tear strength properties. However, it should be noted that even in that case the tear strength will vary depending on the type of peroxide catalyst used. The type of peroxide catalyst used is extremely expensive to obtain a cured composition fI with high tear strength. As shown by the experimental results, in order to obtain a composition with a tear strength of +00 pi or more, an appropriate concentration of vinyl group-containing polyrinloxane rubber mixture, hydrabeto group-containing vorinoloxane, and peroxide should be used. It is necessary to use a suitable peroxide catalyst. Furthermore, a specific vinyl group-containing polynoloxane rubber mixture, a specific Hytry F
The use of water-containing vorinoloxane oils and specific peroxide catalysts will provide tear strength superior to that which can be achieved by using other compounds in the composition. Patent Jawman General I Rectorinok Company Agent (7630) Tokuji Ikunuma

Claims (1)

[Scope of Claims] 1. The following components: (A) having a viscosity in the range of 1×106 to 20×+07 centeboise at 25°C, and having a vinyl group concentration which may range from 0.005 to 0.01 molar vinyl groups; 60-95 parts by weight of a linear diorganopoly/roxano rubber with a first vinyl end group in which the organo group is a monovalent hydrocarbon group: (B) having a viscosity in the range of 1 x 10' to 20 x 107 centeboise at 25°C; The second vinyl group-containing diorganoborinoxane rubber, which is a monovalent hydrocarbon group, has a weight of 5.0 to 400, and as its molar vinyl group conversion increases from 0.5 to 150 molar. (C)
10 to 300 superimposed parts of fillers, at least some of which are reinforcing fillers; (D) having an hydride group content of 0.05 to 5.0 centipoise and 10 to 1000 centipoise at 25°C; Idlide group-containing boria xane 01 with a viscosity in the range of
~25 parts by weight; and (E) a curing agent selected from the group consisting of an organic peroxide and an organic human r'jIA oxide present at least once in the free-radical initiator's availability. Polycone elastomer (curable boronoxane composition) having a tear strength of 100 bonds/inch or more. , R is fat 1177
lb'-It is a 01-B-flanked hydrogen group containing no unsaturation, RI is a C1-8-flanked hydrogen group, and X and t
The viscosity of the rubber is 1X106 to 20X107 at 25℃.
The composition according to claim 1, wherein the number is within the range of 7. 6. The fourth compound described in Section 2 of Patent A11, Section 1111, in which the group R1 does not contain aliphatic unsaturation. 4 The first vinyl end group-bearing borinoloxano rubber is 0
．． 5. The composition according to item 3, wherein the second vinyl group-containing poly/roxano rubber has the formula: In the middle, R2 and R4 are CI~8-flank hydrogenation,
R3 is a C, ~8-valent hydrocarbon group containing no aliphatic unsaturation, and W and 2 are viscosity of the rubber of 1 x 10 at 25°C.
6 to 20 x 107 centivoids) and the vinyl group concentration of the rubber is 0.5
~150 molar ratio, but as the viscosity of the shaving rubber increases, the vinyl group concentration increases by 75 molar ratios! ]' Paraboloid of thread 1 described in section ii+iJ of claim 4. 6. The composition according to claim 5, wherein the group R2 is a C, to 8-valent hydrocarbon group containing no aliphatic unsaturation. 7. The composition according to claim 6, which contains a portion of a filler (10 to 200 weights of U-strength filler) selected from the group consisting of heem-donry strength and sedimentation/liquid. 8. Composition according to claim 7, in which, in addition to the reinforcing fillers, additional fillers are used selected from the thickening fillers. 9. A-I acid c110 according to claim 8, in which the reinforcing filler is treated with a treatment agent selected from the group consisting of cyclic porin coxano and nrazan. A composition according to claim 9. 11 Vinyl-specific peryl'-narrowing products include 2,5-dimethyl-2,5-di(t-butylperoxy/)hexane, di-t-butylperoxy and 5-bunalcumylperoxy/do. Patent selected from Sf'j Water's 4.1C; l'
I'll composition, with part 1 it+, . Paraboloid 1-5001)]: The composition according to item 11, containing a platinum catalyst of 1-5001). 13 Hydride group-containing poly/loxano has the formula: (wherein R5 is a 01-8-lateral hydrogenated group containing no aliphatic unsaturation, and p and q are) hydride group-containing poly/loxano A linear type having a viscosity in the range of 10 to 1000 centiboise at 25°C and an idride base part in the range of 0.05 to 20 (the number in this range) The composition according to claim 12, which is a poly/loxane. 14 Hydride group-containing poly/loxane has 6 〇-8iOO, 5 units and 5102i1M6 (wherein R6 is aliphatic unsaturation,
~ 8-valent carbon side hydrogen group and the ratio of R6+H to S1 is in the range of 10 to 2.7) and 1ζ1 fat hydride foundation rat is 0.05 to 20 weight and 41 weight. No.-1 Fiij, which is a dryide group-containing resin, patented in Patent 1
Listed in Section 12, Section 12 of Box j. 15 Hydride group-containing poly/loxane contains 6 H-8iO (35 units and 5102 units and (R)
iO6 unit (wherein R6 is an aliphatic unsaturation containing C, ~8-
is a valent hydrocarbon group and the ratio of R6+H to S1 is 12 to
13. The A11 composition according to claim 12, which is a no-hydride group-containing resin having a polyhydric acid group of 27%. 16. The +fJ1 composition of claim 1, wherein the curing agent is present at a concentration of at least 0.11 parts per 100 tons of the remainder of the composition. 17, R1-8iOo, 5 units and 5102 monoM (
In the formula, R8 is a group selected from the group consisting of a vinyl group and an aliphatic nitrogen group and a hydrogenated group consisting of a hydrogenated group consisting of njj -Sj, OO, 5 units and 7JSi02 units. and about 25 to 10 moles of silicon atoms are bonded to silicon such that the ratio is about 0.5 to 1 to +741.
13. The composition according to claim 12, further comprising a 20 to 50 Φ sector of an organopolymer-sun resin copolymer containing a ζ vinyl group. 18, R: S i O6,5 units and 8102 units and present 5iO-? The first position (wherein R8 is a group selected from the group consisting of a vinyl group and a monovalent hydrocarbon group containing no aliphatic unsaturation) is R1510o, 5 unit pairs 8102
The ratio of units is 05:1 to 1:1 and the river Si
The resinous copolymer contains about 25 to 100 moles of vinyl groups such that the O units are present in an amount equal to about 1 to 10 moles based on the number of moles of gold side units of Nroquine units in the copolymer. Containing organopolynoroxane resin copolymers 1 to 5
The composition according to item 12 of the 'Samurai 5 No 1 Poetry', which contains 0 parts by weight. 19. The composition according to claim 12, further comprising 1 to 25 parts by weight of a processing aid. 20 The processing aid has a ratio of hydrocarbon substituents to silicon atoms ranging from 1.0 to 20, and the hydrocarbon substituents are methyl,
A polysiloxane consisting of at least some groups from the group consisting of vinyl, ethyl, allyl, /chlorohegycenyl and fenyl groups and containing an average of 1 to 2 lower alkoxy 7 groups bonded to each terminal silicon atom. The 1fJ1 product according to claim 19, which is a dihydrocarbon group-substituted polysiloxane oil consisting of molecules. 21 Vinyl-specific peroxide is 2,5-dumenal-2
, 5-di(t-butylperoquine)hexene-3. 22. The processing aid contains from 1 to 2 silicon-bonded hydroquine groups per 70 silicon atoms and from 19 to 2.1 hydrocarbon groups per silicon atom, The remaining valence of silicon atoms is filled by oxygen atoms! The composition according to claim 19, which is a hydroxylated organone loxane prepared by ':1'). 23 The curing agent is present in the remainder of the composition 100 j, lj f
01 to 2 F per part II, present at a concentration of 3 parts
F. The composition according to claim 16. 24. Electrification 1) Component of tsuki'. (A) Hji'1. with a viscosity in the range of 1.times.106 to 20.times.107 centeboise at 25.degree. '- Linear diorganopoly/logisan rubber with vinyl end groups 60-9
(B) A second vinyl group-containing diorganopolynoroxane rubber having a viscosity in the range of 1X10' to 2DXi07 centiboise at 25°C and in which the organo group is a monovalent hydrocarbon group 5.0 to 40 .0 mass + f1s, and the mole multi-vinyl group 7 parts by weight from 50 parts by weight; <C) 10 to 300 parts by weight of filler, at least in part being reinforcing phosphor filler; (1 part by weight from 0.05 to 5.0 parts by weight) ) to 11-25 parts of 11-helical poly/loxane having an idlide group content and a viscosity in the range of 10 to 1000 mm at 25°C; and (11) a hardening agent selected from the group consisting of organic peroxides and organic hydroperoxides present in an effective amount of Schiff's starting compound; and (11) obtained. A method for manufacturing a silicone elastomer having a tear strength of at least 100 lbs. 25 Next ingredient. (A) having a viscosity in the range of 1.times.10' to 20.times.10@7 centepoise at 25 DEG C., a vinyl group concentration which may range from 1.0.005 to 0.01 molar vinyl groups, and an organo group being a monovalent hydrocarbon group; Linear diorganoborin loxane rubber with first vinyl end group 60-95'fX
Amount N'Jr; (B) 1X10' to 20 at 25°C
A second vinyl group-containing diorganopoly/loxane rubber having a viscosity in the range of U, 5 moles to 150
The concentration of the second vinyl group-containing rubber in the composition shall decrease from 40.0 molar parts to 50 molar parts (CO) at least in part. Filling with reinforcing glue force filling ft1l? ilJ 10
~600 weight ratio 1?1 d; (D) 0.05~50 weight ratio -.Idlide basis 111 and at 25℃ 10.~
from 701 to 25 parts by weight of an hydride group-containing poly/loxazole having a viscosity in the range of 1000 cm; A hardening agent selected from the group consisting of:
One tubular piece of high temperature cured noricorn elastomer with a tear strength of over 100 bonds/inch. 26% have 1-1j characteristics for medical use:'
26. The tubular body according to item 25. 27 Borine with a first vinyl end group [Koyazan rubber has the formula: C1
~8- flank hydrogenated group, X and t are 1 x 106 to 2'0 x 407 when the viscosity of the polynoloxane rubber is 25°C
Claim 81!1 Claim 21. The tubular body according to claim 25. Patent 1.28, gJIk: R1 contains no aliphatic unsaturation. N desired range A+'; the tubular shape described in item 27 (4=,,.
50 Second vinyl group-containing boronoxane rubber is the formula: (wherein, R2 and R4 are C, ~8-valent carbon side groups, R3 is a 01-B-side hydrogen group that does not include the aliphatic unsaturation, W and 2 is a number in the range such that the viscosity of the polyethylene loxane rubber is in the range of 1X106 to 20Xi07 centepoise at 25°C), and the vinyl group concentration of the rubber is in the range of 05 to 150 molar ratio, but the rubber The tubular body according to claim 29, wherein the viscosity increases (as C increases, the vinyl group concentration approaches 0.5 molar ratio). 3i ail;
61. The f1-shaped body according to claim 60, which is a ~8-flank hydrogen group. 32 The tubular body 1.66 of claim 31, containing 10 to 200 parts by weight of a reinforcing filler selected from the group consisting of 5-hydrocarbons and precipitated minerals; 33. The tubular body according to claim 32, which additionally uses an additional filler selected from fillers 7i1. 34 Reinforcing filler with cyclic boria 1m1 xane and 7
64. A tubular body according to claim 63, which is treated with a treatment agent selected from the group consisting of lazan. 35. A tubular body according to claim 34, wherein the curing agent is selected from vinyl-specific peroxides. 36 Vinyl-specific peroxide is 2,5-dimethyl-2
,5-di(t-butylperoxy)hexane 5-di-t-
Special i'F selected from the group consisting of butyl peroquinide and 5-bunalcumyl peroquinide? :'4 The tubular body according to item 35. 67 When containing platinum catalyst 1 to 500 ppm k,
i'l The tubular body according to claim 36. 38 The hydride group-containing borine 1 coxane has the formula ゛ (in the formula, R5 is a C1-8-
It is a side-attached hydrogen group, and the viscosity of p- and q-, idride-based, 1-borin logisan is in the range of 10 to 1000 centivoids at 25°C, and the hydride group content is 0.05 to 20 centibodies. 68. The tubular piece according to claim 67, which is a linear polysiloxane having a number in the range of ). 39 Hydride group-containing polysiloxane is 6] (Si0,5 unit and Eli02 unit 6 (wherein, R6 is a C1-8-flanked water group not included in the aliphatic unsaturation, and R6-1-H The ratio of S1 to S1 is 10~
Patent No. 1.1 to '43 which is a no-idlide group-containing resin having a no-idlide group content of 2.7) and a no-idlide group content of 005 to 2.0 weight (1 tLl).
The tubular body according to item 7. 40 Hydride group-containing polysiloxane is H-S
i Oo , s units and S i 02 units and (RIl
i12SiO unit - 6 (in the formula, R6 is a C1-8-side hydrogen group which does not contain aliphatic unsaturation, and the ratio of R6+H to soil 1 is 12 to
38. The tubular body according to claim 37, wherein the tubular body is a hydride group-containing resin having a molecular weight of 2.7. 41. The tubular body of claim 25, wherein the curing agent is present at a concentration of at least 0.1 parts per 100 parts by weight of the composition. 42, R: Sio6.5 units and Si○2 units (in the formula, R8 is a group selected from the group consisting of a vinyl group and a monovalent hydrocarbon group containing no aliphatic unsaturation) as R
: -S i Ol, containing such that the ratio of 5 units to 5i02 units is about 0.5:1 to 1:1 and about 25 to 10 molar percentages of the silicon atoms contain vinyl groups bonded to silicon; Novolin loxane resin copolymer 1-50
A composition further comprising:
! ``The tubular body according to claim 37. The ratio of R:5iO0,5 units to 5102 units is from 05:1 to 1:1, and the R85iO position is a group selected from the group consisting of siloxane units in the copolymer. Approximately 1~ based on number
organoborinoxane resin copolymers containing about 2.5 to 100 moles of vinyl groups such that m'' is present in molar proportions equal to 10 to 50 moles)
38. A tubular body according to claim 37, formed from a composition further comprising a meter. 44 Poems further containing 1 to 25 parts by weight of processing aids
The tubular body according to item 67, the range of Fi'F'M4. is selected from the group consisting of notel, vinyl, ether, allyl, chlorohexenyl and phenyl group.
Patent No. 614, which is a polysiloxane oil with one dihydrocarbon group, consisting of a polysiloxane molecule containing 1 to 2 alkoxy groups bonded to each terminal silicon atom; The tubular body according to item 11544, in which the vinyl specific peroxide is 2,5-dimethyl-
66. The tubular body according to claim 65, which is 2,5-di(t-buterperoquine)hexene-3. 4Z the processing aid contains from 1 to 2 silicon-bonded hydroquine groups per 70 silicon atoms and from 19 to 2.1 hydrocarbon groups per silicon atom; The remaining one atom of the atom is filled/ζ by an oxygen atom ('fVF tj' [Mfi, which is the hydroquinylated organosiloxane of Tarazo, the fourth range of interest).
The tubular body according to item 4. 48 The curing agent is present in a concentration of 01 to 2 parts by weight per 11 parts by weight of the remainder of the composition.
The tubular body according to item P3, 44. 49 Ingredients with: CA) Has a viscosity IJ1 in the range of 1x+o6 to 20x+07 centapoise at 25°C, o,oos to 01 mol%
In the middle of the vinyl group, h re#! vinyl 71
It has α degree and the organo group is a monovalent hydrocarbon group.
:Linear diorganopolymer with vinyl end groups of I'r-/
60 to 95 parts by weight of Roxano Rubber; (3) Diorganopoly/Loxane Rubber having a viscosity in the range of 1 x 106 to 20 x 107 centeboise at 25°C, and in which the orka group is a monovalent hydrocarbon group / η2 vinyl group-containing diorganopoly/roxane rubber 400 weight units, but the molar vinyl group concentration is from 0.5 molar! (C) The concentration of the second vinyl group-containing rubber in the composition shall decrease from 400% to 50% as the mole ratio increases to 150%; Filler which is a filler 10 to 600 layers; 01 to 25 parts by weight of an idlide group-containing boria having a viscosity of 0.1 to 25 parts by weight;
A polysiloxane composition containing an organic peroxycarboxylic compound present at a temperature of JJ and a curing agent selected from the group consisting of: A boot for a spark plug having a tear strength of 100 bonds/inch or more.so, (i) The following ingredients: (A) 0.005 to 0.1 mole having a viscosity in the range of 1X106 to 20X407 centiboise at 2'5°C. A linear diorganopoly/roxano rubber 6 having a first vinyl end group in which the organo group is a monovalent hydrocarbon group;
(13) A second vinyl having a viscosity in the range of lx106 to 20x107 centeboise at 25°C and whose organo group is a monovalent hydrocarbon group, (containing organobori/loxane rubber 50 to 400 weight M) However, as the molar vinyl group concentration increases from 0.5 molar to 150 molar, the concentration of the vinyl group-containing rubber in the composition increases by 4.
It shall be reduced from 00 folds to 50 folds; <O) At least part of the reinforcing glue force filling 111
filler 10 to 300 layers; g+)o, os to 50 layers containing hydride and water; 701 to 25 parts by weight of a hydride group-containing borinoxa having a viscosity of ~1000 centiboise; and ('B) an organic, 'li+1 oxide and an organic a curing agent selected from the group consisting of hydroperoxides; and (11
) The resulting 7 compositions A at a temperature of 100°C or higher,
1) heating for a sufficient period of time to cure the acid to a ``Noricorn Elas''mer;
Oh. Treatment 1. Tubular body 48 ignition bulb 7,') II n-
Wow. Manufacturing method 13