JPS565435A - Trans-2,2-dimethyl-3- p-substituted phenyl -cyclopropane- carboxylic acid and its preparation - Google Patents

Trans-2,2-dimethyl-3- p-substituted phenyl -cyclopropane- carboxylic acid and its preparation

Info

Publication number
JPS565435A
JPS565435A JP8059779A JP8059779A JPS565435A JP S565435 A JPS565435 A JP S565435A JP 8059779 A JP8059779 A JP 8059779A JP 8059779 A JP8059779 A JP 8059779A JP S565435 A JPS565435 A JP S565435A
Authority
JP
Japan
Prior art keywords
formula
trans
dimethyl
substituted phenyl
cyclopropane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP8059779A
Other languages
Japanese (ja)
Other versions
JPH0112741B2 (en
Inventor
Shimizu Ozawa
Shigeru Ishii
Masataka Hatanaka
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nissan Chemical Corp
Original Assignee
Nissan Chemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nissan Chemical Corp filed Critical Nissan Chemical Corp
Priority to JP8059779A priority Critical patent/JPS565435A/en
Publication of JPS565435A publication Critical patent/JPS565435A/en
Publication of JPH0112741B2 publication Critical patent/JPH0112741B2/ja
Granted legal-status Critical Current

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  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

NEW MATERIAL:trans-2, 2-Dimethyl-3-( p-substituted phenyl )cyclopropanecarboxylic acid of formula I (X is Br, alkyl except CH3, cycloalkyl, CF3, trialkylsilyl, dialkylamino, CN, or SCH3). EXAMPLE:trans-2,2-Dimethyl-3-(p-t-butylphenyl)cyclopropanecarboxylic acid. USE:Intermediate of a substituted phenylcyclopropanecarboxylic ester which is an insecticidal and miticidal agent effective to control house vermin and agricultural and horticultural vermin. PROCESS:Carboxylic ester of formula IV is obtained by the reaction of p-substituted cinnamic ester of formula II (R is lower alkyl) with isopropyltriphenylphosphonium iodide of formula III in the pesence of a base, e.g. n-butyl lithium. The compound of formula IV thus obtained is then hydrolyzed to give the objective compound of formula I.
JP8059779A 1979-06-26 1979-06-26 Trans-2,2-dimethyl-3- p-substituted phenyl -cyclopropane- carboxylic acid and its preparation Granted JPS565435A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP8059779A JPS565435A (en) 1979-06-26 1979-06-26 Trans-2,2-dimethyl-3- p-substituted phenyl -cyclopropane- carboxylic acid and its preparation

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP8059779A JPS565435A (en) 1979-06-26 1979-06-26 Trans-2,2-dimethyl-3- p-substituted phenyl -cyclopropane- carboxylic acid and its preparation

Publications (2)

Publication Number Publication Date
JPS565435A true JPS565435A (en) 1981-01-20
JPH0112741B2 JPH0112741B2 (en) 1989-03-02

Family

ID=13722731

Family Applications (1)

Application Number Title Priority Date Filing Date
JP8059779A Granted JPS565435A (en) 1979-06-26 1979-06-26 Trans-2,2-dimethyl-3- p-substituted phenyl -cyclopropane- carboxylic acid and its preparation

Country Status (1)

Country Link
JP (1) JPS565435A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57150635A (en) * 1981-02-20 1982-09-17 Chinoin Gyogyszer Es Vegyeszet Manufacture of dihalovinylcyclopropane carboxylic acid
WO2006097817A1 (en) * 2005-03-17 2006-09-21 Pfizer Japan Inc. N- (n-sulfonylaminomethyl) cyclopropanecarboxamide derivatives useful for the treatment of pain

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
CHEMICAL ABSTRACTS *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57150635A (en) * 1981-02-20 1982-09-17 Chinoin Gyogyszer Es Vegyeszet Manufacture of dihalovinylcyclopropane carboxylic acid
JPH0521904B2 (en) * 1981-02-20 1993-03-25 Kinoin Giogisuzeru Esu Begiesuzechi Terumekeku Giara Ruto
WO2006097817A1 (en) * 2005-03-17 2006-09-21 Pfizer Japan Inc. N- (n-sulfonylaminomethyl) cyclopropanecarboxamide derivatives useful for the treatment of pain
JP2008535801A (en) * 2005-03-17 2008-09-04 ファイザー株式会社 N- (N-sulfonylaminomethyl) cyclopropanecarboxamide derivatives useful for the treatment of pain
US7622589B2 (en) 2005-03-17 2009-11-24 Pfizer Inc. Substituted sulfonylaminoarylmethyl cyclopropanecarboxamide as VR1 receptor antagonists
US7915448B2 (en) * 2005-03-17 2011-03-29 Pfizer Inc. Substituted sulfonylaminoarylmethyl cyclopropanecarboxamide as VR1 receptor antagonists

Also Published As

Publication number Publication date
JPH0112741B2 (en) 1989-03-02

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