JPH08158201A - Flame retardant fabric excellent in light fastness - Google Patents
Flame retardant fabric excellent in light fastnessInfo
- Publication number
- JPH08158201A JPH08158201A JP6302562A JP30256294A JPH08158201A JP H08158201 A JPH08158201 A JP H08158201A JP 6302562 A JP6302562 A JP 6302562A JP 30256294 A JP30256294 A JP 30256294A JP H08158201 A JPH08158201 A JP H08158201A
- Authority
- JP
- Japan
- Prior art keywords
- fiber
- modacrylic
- spun yarn
- cellulosic
- flame
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/44—Yarns or threads characterised by the purpose for which they are designed
- D02G3/443—Heat-resistant, fireproof or flame-retardant yarns or threads
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/04—Blended or other yarns or threads containing components made from different materials
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D10B2321/10—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of unsaturated nitriles, e.g. polyacrylonitrile, polyvinylidene cyanide
- D10B2321/101—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of unsaturated nitriles, e.g. polyacrylonitrile, polyvinylidene cyanide modacrylic
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Textile Engineering (AREA)
- Artificial Filaments (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Woven Fabrics (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、モダクリル繊維とセル
ロース系繊維から構成される布帛であり、寝装、寝具、
カーテン、作業服、自動車の内装品等の用途に用いて、
好適な難燃性と優れた耐光性を有する新規な布帛に関す
る。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a fabric composed of modacrylic fiber and cellulosic fiber, including bedding, bedding,
Used for curtains, work clothes, automobile interior parts, etc.,
The present invention relates to a novel fabric having suitable flame retardancy and excellent light resistance.
【０００２】[0002]
【従来の技術】近年、インテリア、寝装、寝具用、衣料
用等の繊維製品においては、難燃化が強く要望され、し
かも難燃性以外の視感、風合、吸湿性、耐久性（たとえ
ば耐洗濯性、耐光性）等の性能に対する要望も強まって
いる。従来、天然繊維である綿や再生繊維であるレーヨ
ン等のセルロース系繊維が、風合い、外観、吸湿性など
の優れた特徴から多量に使用されてきたが、これらは易
燃性繊維であるため、難燃性が要求される分野では使用
に耐えられない。そこで、これら綿やレーヨン等のセル
ロース系繊維を難燃化すべく、綿の場合では後加工によ
り、又、レーヨンの場合では難燃剤の添加等によって、
難燃性の向上が図られてきた。2. Description of the Related Art In recent years, in textile products for interior, bedding, bedding, clothing, etc., flame retardancy has been strongly demanded, and in addition to flame retardancy, visual feeling, texture, hygroscopicity, durability ( For example, demands for performance such as washing resistance and light resistance are increasing. Conventionally, cellulosic fibers such as natural fibers such as cotton and regenerated fibers such as rayon have been used in large amounts because of their excellent characteristics such as texture, appearance, and hygroscopicity, but since these are flammable fibers, It cannot be used in the field where flame retardancy is required. Therefore, in order to make these cellulosic fibers such as cotton and rayon flame-retardant, by post-processing in the case of cotton, and by adding a flame retardant in the case of rayon,
Flame retardancy has been improved.
【０００３】例えば、セルロース系繊維が本来有してい
る特徴を維持しつつ、難燃化する方法として、ハロゲン
を１７〜８６重量％含む重合体に、該重合体に対して１
２〜５０重量％のアンチモン化合物を含有させた繊維８
５〜２０重量部と、天然繊維及び化学繊維よりなる群か
ら選ばれた少なくとも１種の繊維１５〜８０重量部とを
１００重量部となるように複合した難燃性複合体（特公
平４−１８０５０）が提案されている。この、アンチモ
ン化合物を含む、ハロゲン含有重合体系繊維と、セルロ
ース系繊維の複合繊維は、難燃性に優れてはいるもの
の、耐光性の点で充分とは言いがたい。即ち、モダクリ
ル繊維などのハロゲン含有重合体系繊維にアンチモン化
合物が添加されると、耐光性が著しく低下するという問
題があった。[0003] For example, as a method of flame retarding while maintaining the inherent characteristics of cellulosic fibers, a polymer containing 17 to 86% by weight of halogen is added, and 1 is added to the polymer.
Fiber 8 containing 2 to 50% by weight of antimony compound
5 to 20 parts by weight and 15 to 80 parts by weight of at least one fiber selected from the group consisting of natural fibers and chemical fibers are combined to make 100 parts by weight a flame-retardant composite (Japanese Patent Publication No. 18050) has been proposed. Although the composite fiber of the halogen-containing polymer fiber and the cellulosic fiber containing the antimony compound has excellent flame retardancy, it cannot be said that it is sufficient in light resistance. That is, when an antimony compound is added to a halogen-containing polymer fiber such as modacrylic fiber, there is a problem that the light resistance is significantly reduced.
【０００４】[0004]
【発明が解決しようとする課題】そこで、本発明の目的
は、セルロース系繊維の特徴を維持しつつ、難燃性を有
し、しかも耐光性に優れた布帛を提供することにある。SUMMARY OF THE INVENTION An object of the present invention is to provide a fabric which has flame retardancy and excellent light resistance while maintaining the characteristics of cellulosic fibers.
【０００５】[0005]
【課題を解決するための手段】上述の目的は、モダクリ
ル重合体に対し０．１〜２．０重量％のベンゾトリアゾ
ール化合物及び１〜５０重量％のアンチモン化合物を含
有するモダクリル繊維と、セルロース系繊維とから構成
される布帛であって、布帛総重量に対し３０〜８０重量
％のセルロース系繊維を含有する難燃性布帛によって達
成される。DISCLOSURE OF THE INVENTION The above object is to provide a modacrylic fiber containing 0.1 to 2.0% by weight of a benzotriazole compound and 1 to 50% by weight of an antimony compound based on a modacrylic polymer, and a cellulosic fiber. This is achieved by a flame-retardant fabric composed of fibers and containing 30 to 80% by weight of cellulosic fibers based on the total weight of the fabric.
【０００６】このモダクリル繊維とセルロース系繊維と
からなる難燃性布帛は、（１）前記モダクリル繊維とセ
ルロース系繊維を混紡した複合紡績糸から構成する方
法、（２）前記モダクリル繊維から得られるモダクリル
繊維紡績糸と、セルロース系繊維紡績糸と、から構成す
る方法、（３）前記モダクリル繊維から得られるモダク
リル繊維紡績糸と、前記モダクリル繊維とセルロース系
繊維を混紡した複合紡績糸と、から構成する方法、
（４）前記モダクリル繊維とセルロース系繊維を混紡し
た複合紡績糸と、セルロース系繊維紡績糸と、から構成
する方法、（５）前記モダクリル繊維から得られるモダ
クリル繊維紡績糸と、前記モダクリル繊維とセルロース
系繊維を混紡した複合紡績糸と、セルロース系繊維紡績
糸と、から構成する方法、等により得ることができる。The flame-retardant cloth composed of modacrylic fiber and cellulosic fiber is (1) a method of constructing a composite spun yarn obtained by mixing modacrylic fiber and cellulosic fiber, and (2) modacrylic obtained from the modacrylic fiber. A method comprising a fiber spun yarn and a cellulosic fiber spun yarn, (3) comprising a modacrylic fiber spun yarn obtained from the modacrylic fiber, and a composite spun yarn obtained by mixing the modacrylic fiber and the cellulosic fiber Method,
(4) A method comprising a composite spun yarn in which the modacrylic fiber and the cellulosic fiber are mixed-spun and a cellulosic fiber spun yarn, (5) a modacrylic fiber spun yarn obtained from the modacrylic fiber, and the modacrylic fiber and cellulose It can be obtained by a method comprising a composite spun yarn obtained by mixing spun fibers and a cellulosic fiber spun yarn.
【０００７】本発明に用いる前記モダクリル繊維の重合
体組成は特に限定されるものではないが、好ましくはア
クリロニトリル４０重量％以上と、塩化ビニル及び／又
は塩化ビニルデン３０〜６０重量％と、スルホン酸基含
有モノマー５重量％以下から成る重合体である。そし
て、前記重合体に対し、更に０．１〜２．０重量％のベ
ンゾトリアゾール化合物及び１重量％〜５０重量％のア
ンチモン化合物を混合した後、紡糸することで本発明に
用いるモダクリル繊維が得られる。The polymer composition of the modacrylic fiber used in the present invention is not particularly limited, but preferably 40% by weight or more of acrylonitrile, 30 to 60% by weight of vinyl chloride and / or vinyldene chloride, and a sulfonic acid group. It is a polymer composed of 5% by weight or less of a contained monomer. Then, 0.1 to 2.0% by weight of a benzotriazole compound and 1% to 50% by weight of an antimony compound are further mixed with the polymer and then spun to obtain a modacrylic fiber used in the present invention. To be
【０００８】前記ベンゾトリアゾール化合物としては、
具体的には２−（2'−ヒドロキシ−3'−ターシャリーブ
チル−5'−メチルフニル）−５−クロロベンゾトリアゾ
ール、２−（2'−ヒドロキシ−3'，5'−ジターシャリー
ブチルフエニル）−５−クロロベンゾトリアゾール、２
−（2'−ヒドロキシ−3'−ターシャリーブチル−5'−メ
チルフエニル）ベンゾトリアゾール、２−（2'−ヒドロ
キシ−3'，5'−ジターシャリーアミルフエニル）ベンゾ
トリアゾール、２−（2'−ヒドロキシ−5'−メチルフエ
ニル）ベンゾトリアゾール、２−（2'−ヒドロキシ−4'
−メトキシフエニル）ベンゾトリアゾール、２−（2'，
4'−ジヒドロキシフエニル）ベンゾトリアゾール等が挙
げられる。勿論これら具体例に限定されるものではな
い。又、その使用量は、モダクリル重合体に対し、０．
１〜２．０重量％が好ましい。０．１重量％より少ない
場合は、布帛とした場合の耐光性への効果が少なく、
又、２．０重量％より多く使用しても耐光性への効果が
飽和するので無駄になる。As the benzotriazole compound,
Specifically, 2- (2'-hydroxy-3'-tert-butyl-5'-methylphenyl) -5-chlorobenzotriazole, 2- (2'-hydroxy-3 ', 5'-ditertiarybutylphenyl) ) -5-Chlorobenzotriazole, 2
-(2'-hydroxy-3'-tert-butyl-5'-methylphenyl) benzotriazole, 2- (2'-hydroxy-3 ', 5'-ditertiary amylphenyl) benzotriazole, 2- (2'- Hydroxy-5'-methylphenyl) benzotriazole, 2- (2'-hydroxy-4 '
-Methoxyphenyl) benzotriazole, 2- (2 ',
4′-dihydroxyphenyl) benzotriazole and the like can be mentioned. Of course, it is not limited to these specific examples. Further, the amount used is 0.
1 to 2.0% by weight is preferable. When it is less than 0.1% by weight, the effect on the light resistance of the fabric is small,
Further, even if it is used in an amount of more than 2.0% by weight, the effect on the light resistance is saturated and it is wasted.
【０００９】又、本発明において用いるアンチモン化合
物としては、三酸化アンチモン、五酸化アンチモンなど
の酸化アンチモンが挙げられる。その使用量は、モダク
リル重合体に対し、１．０〜５０重量％が好ましい。
１．０重量％より少ないと布帛とした場合の難燃性の向
上効果が少なく、又、５０重量％より多くなると、モダ
クリル繊維の製造工程での問題が生じ、実質的に製造が
極めて困難となるので好ましくない。Examples of the antimony compound used in the present invention include antimony trioxide and antimony pentoxide. The amount used is preferably 1.0 to 50% by weight based on the modacrylic polymer.
If it is less than 1.0% by weight, the effect of improving the flame retardancy of the fabric is small, and if it is more than 50% by weight, a problem occurs in the modacrylic fiber production process, which makes production extremely difficult. Therefore, it is not preferable.
【００１０】本発明で用いるモダクリル繊維は、上記の
ようなモダクリル重合体、ベンゾトリアゾール化合物、
及びアンチモン化合物を混合し、これを湿式紡糸等の公
知の方法で紡糸することで得られる。このモダクリル繊
維の繊度は、特に限定されるものではないが、通常１〜
１５デニールのものが使用される。そしてこのモダクリ
ル繊維は、公知の方法でカットした後、紡績用原綿とし
て供される。The modacrylic fiber used in the present invention is a modacrylic polymer, a benzotriazole compound,
And an antimony compound are mixed and spun by a known method such as wet spinning. The fineness of this modacrylic fiber is not particularly limited, but is usually 1 to
A 15 denier one is used. The modacrylic fiber is cut by a known method and then used as raw cotton for spinning.
【００１１】紡績は公知の方法で、本発明で使用される
モダクリル繊維を単独で、又は綿やレーヨン等のセルロ
ース系繊維と混紡して、紡績糸となす。続いて、この紡
績糸を、セルロース繊維を含む紡績糸の場合には複合単
独で、又はセルローズ系繊維紡績糸と併用し、又、セル
ロース系繊維を含まないモダクリル繊維のみからなる紡
績糸の場合には、セルロース系繊維を含む複合紡績糸若
しくはセルロース系繊維のみからなる紡績糸と併用し
て、公知の方法で織成して布帛とする。布帛の組織は、
平織、朱子織、綾織等いずれでも良く、特に限定される
ものではないが、布帛中に占めるセルロース系繊維の割
合が重量％で３０〜８０％、あるいは前記モダクリル繊
維の割合が重量％で７０％〜２０％であることが好まし
い。セルロース系繊維の割合が３０％より少なくなる
と、セルロース系繊維が本来有している特徴が失われ、
又、８０％より多くなると難燃性が不十分となる。Spinning is a known method, and the modacrylic fiber used in the present invention is spun alone or mixed with a cellulosic fiber such as cotton or rayon to give a spun yarn. Subsequently, in the case of a spun yarn containing cellulose fibers, this spun yarn is used alone or in combination with a cellulosic fiber spun yarn, and in the case of a spun yarn consisting only of modacrylic fiber containing no cellulose fiber. Is used in combination with a composite spun yarn containing cellulosic fibers or a spun yarn composed of only cellulosic fibers, and is woven by a known method to give a cloth. The fabric structure is
Any of plain weave, satin weave, twill weave, etc. is not particularly limited, but the proportion of the cellulosic fibers in the cloth is 30 to 80% by weight, or the proportion of the modacrylic fiber is 70% by weight. It is preferably ˜20%. When the proportion of cellulosic fibers is less than 30%, the characteristics inherent to cellulosic fibers are lost,
Further, if it exceeds 80%, the flame retardancy becomes insufficient.
【００１２】本発明の布帛の例としては、経糸にセルロ
ース系繊維紡績糸を、緯糸に前記モダクリル繊維紡績糸
を用いた布帛、経糸、緯糸共に前記モダクリル繊維とセ
ルロース系繊維を複合して紡績した紡績糸を用いた布
帛、更に、前述の布帛例の経糸と緯糸の構成を変えた布
帛等が挙げられる。As an example of the fabric of the present invention, a cellulosic fiber spun yarn is used as a warp, and a fabric using the modacrylic fiber spun yarn as a weft, a warp, and a weft are both spun by combining the modacrylic fiber and the cellulosic fiber. Examples include cloths using spun yarns, cloths in which the configurations of the warp threads and the weft threads in the above-described cloth examples are changed, and the like.
【００１３】いずれの布帛の場合でも布帛中に占めるセ
ルロース系繊維の割合が重量％で３０〜８０％の範囲に
あり、かつ本発明で使用されるモダクリル繊維の割合が
重量％で７０〜２０％の範囲の範囲であればモダクリル
およびセルロース系繊維以外の繊維が少量含まれていて
も良い。In the case of any of the cloths, the proportion of the cellulosic fibers in the cloth is in the range of 30 to 80% by weight, and the proportion of the modacrylic fiber used in the present invention is 70 to 20% in the weight%. A fiber other than modacrylic and cellulosic fibers may be contained in a small amount within the range of the above range.
【００１４】[0014]
【実施例】先ず、実施例の記載に先立ち、本明細書にお
ける特性値の測定法を記述する。EXAMPLES First, prior to the description of examples, a method of measuring characteristic values in the present specification will be described.
【００１５】（Ａ）耐光性 紫外線強度の強力な、スーパーＵＶテスター（型式ＳＵ
Ｖ−Ｆ１：大日本プラスチック（株）社製）を使用し、
５０℃条件下での促進テストを実施した。サンプル（繊
維、又は紡績糸、又は布帛）をスーパーＵＶテスターで
照射後、サンプルの色相を色差計（型式ＮＤ−３００
Ａ：日本電色工業（株）社製）で測色した。又、未照射
のサンプルについても色相を測色し、その色相の差（Δ
Ｅ）から耐光性を判定した。 ΔＥ＝√〔（ΔＬ）2 ＋（Δａ）2 ＋（Δｂ）2 〕 但し、 ΔＬ： 照射前後のＬ値の差 Δａ： 照射前後のａ値の差 Δｂ： 照射前後のｂ値の差 ΔＥは小さい程、変化が少ないと判断出来る。(A) Light resistance Super UV tester (model SU
V-F1: manufactured by Dainippon Plastics Co., Ltd.,
An accelerated test was carried out under 50 ° C conditions. After irradiating the sample (fiber, spun yarn, or cloth) with a super UV tester, the hue of the sample is measured by a color difference meter (Model ND-300).
A: Color was measured by Nippon Denshoku Industries Co., Ltd.). In addition, the hue of the unirradiated sample was measured, and the difference in hue (Δ
The light resistance was evaluated from E). ΔE = √ [(ΔL) 2 + (Δa) 2 + (Δb) 2 ] where ΔL: difference in L value before and after irradiation Δa: difference in a value before and after irradiation Δb: difference in b value before and after irradiation ΔE is The smaller the value, the smaller the change.
【００１６】（Ｂ）風合 風合については官能試験を行ない、主として吸湿性を有
するか否かで判定した。○は良好、△はやや不良、×は
不良との基準で判断した。(B) Feeling Regarding the feeling, a sensory test was conducted, and it was judged mainly by whether or not it had hygroscopicity. It was judged based on the criteria that ◯ is good, Δ is slightly bad, and x is bad.
【００１７】（Ｃ）難燃性 ＪＩＳ−Ｋ７２０１−１９７２に基づき限界酸素指数
（ＬＯＩ）を測定した。即ち、長さ１５ｃｍ、幅６ｃｍ
に布帛を切り取り、Ｕ字形保持具に取り付けて、酸素指
数試験器の試験片支持具にＵ字形保持具を固定し、前記
布帛が５ｃｍ燃え続けるのに必要な最小酸素濃度を測定
し、この酸素濃度をＬＯＩ値とした。(C) Flame retardance The limiting oxygen index (LOI) was measured according to JIS-K7201-1972. That is, length 15 cm, width 6 cm
The cloth is cut out and attached to a U-shaped holder, the U-shaped holder is fixed to the test piece support of the oxygen index tester, and the minimum oxygen concentration required for the cloth to continue burning for 5 cm is measured. The concentration was defined as the LOI value.
【００１８】以下、本発明を実施例により更に詳細に説
明するが、本発明はこれらに限定されるものではない。Hereinafter, the present invention will be described in more detail with reference to Examples, but the present invention is not limited thereto.
【００１９】（モダクリル繊維の製造）アクリロニトリ
ル（ＡＮ）、塩化ビニル（ＶＣ）、塩化ビニリデン（Ｖ
Ｄ）、スチレンスルホン酸ソーダ（ＳＳＳ）を用い重合
を行ない、表１に示す樹脂組成物を得た。この樹脂組成
物を、アセトン（Ａｃ）、又はジメチルホルムアミド
（ＤＭＦ）に溶解し、三酸化アンチモン（Ｓｂ）及び２
−（2'−ヒドロキシ−3'，5'−ジターシャリーブチルフ
エニル）−５−クロロベンゾトリアゾール（ＢＴ）を表
１に示す量で添加したものを原液とし、孔数１５０００
Ｈ、孔径０．０９ｍｍφの口金から常法により湿式紡糸
して、単繊維繊度２．０ｄの繊維束を得た。続いて、こ
の繊維束を３８ｍｍにカットした。(Production of modacrylic fiber) Acrylonitrile (AN), vinyl chloride (VC), vinylidene chloride (V)
Polymerization was performed using D) and sodium styrene sulfonate (SSS) to obtain resin compositions shown in Table 1. This resin composition is dissolved in acetone (Ac) or dimethylformamide (DMF) to obtain antimony trioxide (Sb) and 2
-(2'-Hydroxy-3 ', 5'-ditertiarybutylphenyl) -5-chlorobenzotriazole (BT) was added in an amount shown in Table 1 to prepare a stock solution with a pore number of 15,000.
Wet spinning was performed by a conventional method from a spinneret having H and a pore diameter of 0.09 mmφ to obtain a fiber bundle having a single fiber fineness of 2.0 d. Then, this fiber bundle was cut into 38 mm.
【００２０】[0020]
【表１】 [Table 1]
【００２１】（実施例１〜４及び比較例１）表１に示す
（１−１）〜（１−５）のモダクリル繊維を、公知の方
法で紡績し、２０番手（綿番手）の紡績糸を紡出した。
そして、これらのモダクリル繊維紡績糸を緯糸とし、天
然繊維の綿紡績糸３０番手を経糸として、目付３００ｇ
／ｍ 2 の朱子織物を織成した。これら織物のＬＯＩ値は
いずれも３１〜３２と極めて高度の難燃性を示した。し
かし表２に示すように、ＢＴを含むモダクリル繊維紡績
糸を用いた実施例１〜４に比較して、ＢＴを含まないモ
ダクリル紡績糸を用いた比較例１は、ΔＥの数値が大き
く、耐光性が劣ることがわかる。(Examples 1 to 4 and Comparative Example 1)
The modacrylic fibers of (1-1) to (1-5) are known
The yarn was spun according to the method, and a 20th (cotton count) spun yarn was spun.
Then, these modacrylic fiber spun yarns are used as weft yarns and
Natural cotton spun yarn, number 30 is used as warp, and weight is 300g.
/ M 2Weaved the satin fabric. The LOI value of these fabrics is
All showed extremely high flame retardance of 31 to 32. Shi
As shown in Table 2, as shown in Table 2, modacrylic fiber spinning containing BT
Compared to Examples 1 to 4 using the yarn, the model containing no BT
In Comparative Example 1 using the Dacryl spun yarn, the value of ΔE is large.
The light resistance is inferior.
【００２２】[0022]
【表２】 [Table 2]
【００２３】（実施例５〜８及び比較例２、３）（１−
４）のモダクリル繊維と、綿繊維を表３に示す各種割合
で混綿した後、公知の方法で紡績し、２０番手の紡績糸
を紡出した。次に、得られた紡績糸から目付３００ｇ／
ｍ2 の平織物を織成した。結果を表３に示す。(Examples 5 to 8 and Comparative Examples 2 and 3) (1-
The modacrylic fiber of 4) and the cotton fiber were mixed at various ratios shown in Table 3, and spun by a known method to spun a 20th spun yarn. Next, from the obtained spun yarn, a basis weight of 300 g /
A plain weave of m 2 was woven. The results are shown in Table 3.
【００２４】[0024]
【表３】 [Table 3]
【００２５】表３から、セルロース系繊維である綿の布
帛中に占める割合が、難燃性と風合いの点から重要であ
ることがわかる。It can be seen from Table 3 that the ratio of the cotton, which is a cellulosic fiber, in the fabric is important in terms of flame retardancy and texture.
【００２６】（実施例９〜１１及び比較例４−６）（２
−１）〜（２−６）のモダクリル繊維を、実施例１〜４
と同様に紡績し、織成して朱子織物を得た。得られた織
物の結果を表４に示す。(Examples 9 to 11 and Comparative Example 4-6) (2
-1) to (2-6) modacrylic fiber, Examples 1 to 4
Spinning and weaving were carried out in the same manner as described above to obtain a satin woven fabric. The results of the resulting fabric are shown in Table 4.
【００２７】[0027]
【表４】 [Table 4]
【００２８】表４から、難燃性、耐光性の両方を同時に
満足するためには、モダクリル繊維に、三酸化アンチモ
ンとベンゾトリアゾールを含む事が必須であることがわ
かる。From Table 4, it is found that it is essential that the modacrylic fiber contains antimony trioxide and benzotriazole in order to satisfy both flame retardancy and light resistance at the same time.
【００２９】[0029]
【発明の効果】以上のように、本発明に係る布帛は、セ
ルロース系繊維の風合を維持しつつ、難燃性と耐光性に
優れており、インテリア及び寝具用及び作業服等の衣料
用などの繊維製品に好適なものである。INDUSTRIAL APPLICABILITY As described above, the fabric according to the present invention is excellent in flame retardancy and light resistance while maintaining the texture of cellulosic fibers, and is suitable for interiors, bedding, and clothing such as work clothes. It is suitable for textile products such as.
Claims (6)
重量％のベンゾトリアゾール化合物及び１〜５０重量％
のアンチモン化合物を含有するモダクリル繊維と、セル
ロース系繊維とから構成される布帛であって、布帛総重
量に対し３０〜８０重量％のセルロース系繊維を含有す
る難燃性布帛。1. 0.1 to 2.0 relative to modacrylic polymer
Wt% benzotriazole compound and 1 to 50 wt%
A flame-retardant fabric comprising a modacrylic fiber containing the antimony compound and a cellulosic fiber, the cellulosic fiber being 30 to 80% by weight based on the total weight of the fabric.
を混紡した複合紡績糸から構成される請求項１記載の難
燃性布帛。2. The flame-retardant fabric according to claim 1, which is composed of a composite spun yarn in which the modacrylic fiber and the cellulosic fiber are mixed-spun.
リル繊維紡績糸と、セルロース系繊維紡績糸と、から構
成される請求項１記載の難燃性布帛。3. The flame-retardant fabric according to claim 1, which is composed of a modacrylic fiber spun yarn obtained from the modacrylic fiber and a cellulosic fiber spun yarn.
リル繊維紡績糸と、前記モダクリル繊維とセルロース系
繊維を混紡した複合紡績糸と、から構成される請求項１
記載の難燃性布帛。4. A composite spun yarn obtained by mixing the modacrylic fiber and the cellulosic fiber, and comprising a modacrylic fiber spun yarn obtained from the modacrylic fiber.
The flame-retardant fabric described.
を混紡した複合紡績糸と、セルロース系繊維紡績糸と、
から構成される請求項１記載の難燃性布帛。5. A composite spun yarn in which the modacrylic fiber and a cellulosic fiber are mixed-spun, a cellulosic fiber spun yarn,
The flame-retardant fabric according to claim 1, which is composed of
リル繊維紡績糸と、前記モダクリル繊維とセルロース系
繊維を混紡した複合紡績糸と、セルロース系繊維紡績糸
と、から構成される請求項１記載の難燃性布帛。6. The flame retardant according to claim 1, which is composed of a modacrylic fiber spun yarn obtained from the modacrylic fiber, a composite spun yarn obtained by mixing the modacrylic fiber and a cellulosic fiber, and a cellulosic fiber spun yarn. Sex fabric.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6302562A JPH08158201A (en) | 1994-12-07 | 1994-12-07 | Flame retardant fabric excellent in light fastness |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6302562A JPH08158201A (en) | 1994-12-07 | 1994-12-07 | Flame retardant fabric excellent in light fastness |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH08158201A true JPH08158201A (en) | 1996-06-18 |
Family
ID=17910474
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6302562A Pending JPH08158201A (en) | 1994-12-07 | 1994-12-07 | Flame retardant fabric excellent in light fastness |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH08158201A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008027454A1 (en) * | 2006-08-31 | 2008-03-06 | Southern Mills, Inc. | Flame resistant fabrics and garments made from same |
| JP2008208509A (en) * | 2007-01-29 | 2008-09-11 | Japan Wool Textile Co Ltd | Heat-resistant flame retardant workwear and woven fabric to be used for the same |
| JP2010537074A (en) * | 2007-08-22 | 2010-12-02 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | Flame retardant spun staple yarns made from blends of fibers derived from diaminodiphenyl sulfone and modacrylic fibers, fabrics and garments made therefrom, and methods for their production |
| EP4053318A4 (en) * | 2019-11-01 | 2023-01-04 | Asahi Kasei Advance Corporation | Flame retardant stretch fiber structure, flame retardant stretch woven/knitted fabric, flame retardant stretch core spun yarn, and protective clothing using same |
| US11873587B2 (en) | 2019-03-28 | 2024-01-16 | Southern Mills, Inc. | Flame resistant fabrics |
| US11891731B2 (en) | 2021-08-10 | 2024-02-06 | Southern Mills, Inc. | Flame resistant fabrics |
-
1994
- 1994-12-07 JP JP6302562A patent/JPH08158201A/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008027454A1 (en) * | 2006-08-31 | 2008-03-06 | Southern Mills, Inc. | Flame resistant fabrics and garments made from same |
| US9765454B2 (en) | 2006-08-31 | 2017-09-19 | Southern Mills, Inc. | Flame resistant fabrics and garments made from same |
| JP2008208509A (en) * | 2007-01-29 | 2008-09-11 | Japan Wool Textile Co Ltd | Heat-resistant flame retardant workwear and woven fabric to be used for the same |
| JP2010537074A (en) * | 2007-08-22 | 2010-12-02 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | Flame retardant spun staple yarns made from blends of fibers derived from diaminodiphenyl sulfone and modacrylic fibers, fabrics and garments made therefrom, and methods for their production |
| US11873587B2 (en) | 2019-03-28 | 2024-01-16 | Southern Mills, Inc. | Flame resistant fabrics |
| EP4053318A4 (en) * | 2019-11-01 | 2023-01-04 | Asahi Kasei Advance Corporation | Flame retardant stretch fiber structure, flame retardant stretch woven/knitted fabric, flame retardant stretch core spun yarn, and protective clothing using same |
| US11891731B2 (en) | 2021-08-10 | 2024-02-06 | Southern Mills, Inc. | Flame resistant fabrics |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US5503916A (en) | Flame-retarded clothing | |
| US5208105A (en) | Flame-retarded composite fiber | |
| JP4958359B2 (en) | Flame retardant interwoven fabric | |
| JP2593986B2 (en) | Manufacturing method of flame retardant fiber composite | |
| JP4118238B2 (en) | Interwoven fabric with flame retardancy | |
| WO2012176859A1 (en) | Suede-tone flame-retardant union cloth | |
| WO1997043475A1 (en) | Thermal resistance-improved flame retardant cloth | |
| JPH08158201A (en) | Flame retardant fabric excellent in light fastness | |
| JPWO2003080909A1 (en) | Highly flame retardant interwoven fabric | |
| JP3453901B2 (en) | Composite fiber yarn and fabric excellent in flame retardancy, strength and abrasion resistance | |
| JPH10280250A (en) | Flame retardant woven fabric excellent in color development property | |
| JP2898563B2 (en) | Flame retardant method for combustible fibers | |
| JPH08158202A (en) | Flame retardant fabric | |
| JP2593989B2 (en) | Interior textile products | |
| JP2593988B2 (en) | Textile products for clothing | |
| JP3004107B2 (en) | Flame retardant fiber composite | |
| JPH08209490A (en) | Heat and flame resistant cloth | |
| JP2812672B2 (en) | Manufacturing method of flame retardant fiber composite | |
| JPH09324330A (en) | Flame retardant blended yarn and flame retardant fabric excellent in strength using the same | |
| JP2505377B2 (en) | Composite flame retardant fiber | |
| JP2550266B2 (en) | Manufacturing method of composite flame-retardant fiber | |
| JPH101821A (en) | Halogen-containing fiber and flame-retardant fiber composite material using the same | |
| JPH0611930B2 (en) | Composite flame retardant fiber | |
| JPS59204918A (en) | Flame-retardant acrylic synthetic yarn | |
| JPH04194053A (en) | Flame-retardant cloth |