JPH0743081A - Control method of internal pressure of self-fluxing furnace - Google Patents

Control method of internal pressure of self-fluxing furnace

Info

Publication number
JPH0743081A
JPH0743081A JP20698793A JP20698793A JPH0743081A JP H0743081 A JPH0743081 A JP H0743081A JP 20698793 A JP20698793 A JP 20698793A JP 20698793 A JP20698793 A JP 20698793A JP H0743081 A JPH0743081 A JP H0743081A
Authority
JP
Japan
Prior art keywords
furnace
pressure
heat recovery
self
waste heat
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP20698793A
Other languages
Japanese (ja)
Inventor
Nobumasa Iemori
伸正 家守
Okiyoshi Hondo
起由 本道
Masaru Takebayashi
優 竹林
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Metal Mining Co Ltd
Original Assignee
Sumitomo Metal Mining Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Metal Mining Co Ltd filed Critical Sumitomo Metal Mining Co Ltd
Priority to JP20698793A priority Critical patent/JPH0743081A/en
Publication of JPH0743081A publication Critical patent/JPH0743081A/en
Pending legal-status Critical Current

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  • Manufacture And Refinement Of Metals (AREA)
  • Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)

Abstract

PURPOSE:To provide the control method of internal pressure of a self-fluxing furnace, which is effective for the factor of external disturbance generated suddenly. CONSTITUTION:A self-fluxing furnace is provided with a waste heat recovery boiler, connected to the flue of the automatic balst furnace, and a control valve, provided at the outlet port of the waste heat recovery boiler, while the opening degree of the control valve is regulated based on the value of a difference between the measured value and the specified value of the outlet port pressure of the waste heat recovery boiler and the specified value is regulated based on a difference between the measured value and the set value of the internal pressure of the self-fluxing furnace. According to this method, the response of the outlet port pressure of a boiler with respect to the change of opening degree of the control valve is quickened. As a result, a response speed of internal pressure of the self-fluxing furnace with respect to the opening degree of the control valve is quickened. Further, pressure fractuation in the waste heat recovery boiler, which is generated mainly upon soot blowing, can be detected soon whereby the internal pressure of the self-fluxing furnace can be controlled nicely.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は自熔製錬設備の運転方法
に関し、具体的には自熔炉の炉内圧力の制御方法に関す
る。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for operating a flash smelting equipment, and more particularly to a method for controlling the pressure inside the flash furnace.

【0002】[0002]

【従来の技術】硫化精鉱を原料とする非鉄金属製錬方法
の一つに自熔製錬法がある。この方法は、反応塔と、該
反応塔の下端にその一端が接続されたセトラーと、セト
ラーの他端に設けられた排煙道とから基本的に構成され
る自熔炉を用いるものであり、通常排煙道の下流側に廃
熱回収ボイラーを設け、その下手側に集塵機を設け、製
錬廃ガスを除塵し、次いで廃ガスファンにより硫酸工場
にこの製錬廃ガスを送っている。そして、硫酸工場で
は、例えば空塔、洗浄塔、ミストコットレル等により製
錬廃ガス中のダストやSO3を除去し、乾燥塔を経て製
錬廃ガス中のSO2をSO3に転化すべく転化器に廃ガス
を導入している。
2. Description of the Related Art One of non-ferrous metal smelting methods using sulfide concentrate as a raw material is a flash smelting method. This method uses a flash furnace basically composed of a reaction tower, a settler having one end connected to the lower end of the reaction tower, and a flue gas duct provided at the other end of the settler, Usually, a waste heat recovery boiler is installed on the downstream side of the flue gas, a dust collector is installed on the lower side thereof to remove the smelting waste gas, and then this smelting waste gas is sent to the sulfuric acid factory by a waste gas fan. Then, in the sulfuric acid factory, for example, a tower, a washing tower, a mist cotrel, etc. are used to remove dust and SO 3 from the smelting waste gas, and the SO 2 in the smelting waste gas is converted to SO 3 through the drying tower. Waste gas is being introduced into the converter.

【0003】旧来より非鉄金属製錬所排出の廃ガスによ
る公害問題は重大な社会問題となっており、ガス発生場
所である自熔炉等の炉よりガス処理設備出口までの工程
でSO2等を含むガスの漏洩は即座に操業停止に結びつ
くものとなっている。このため、いかに廃ガスの漏洩を
防止するかは非鉄金属製錬所においては死活問題となっ
ていると言っても過言ではない。よって、廃ガス系全体
で装置や煙道内のガス圧を正圧にすることは厳禁とされ
る。とは言え、操業時に種々の要因により各装置内や煙
道内のガス圧に変動が生じるのは避けられず、漏洩した
廃ガスを環境集煙装置により集煙し、無害化することで
対応しているのが実状である。
The pollution problem caused by waste gas discharged from non-ferrous metal smelters has been a serious social problem from the past, and SO 2 and the like are generated in the process from the furnace where the gas is generated, such as a flash smelting furnace, to the outlet of the gas treatment facility. Leakage of gas, including gas, will result in immediate shutdown. Therefore, it is no exaggeration to say that how to prevent the leakage of waste gas is a life and death problem in non-ferrous metal smelters. Therefore, it is strictly prohibited to make the gas pressure in the device and the flue gas positive in the entire waste gas system. However, it is inevitable that the gas pressure in each device and flue will fluctuate due to various factors during operation, and the leaked waste gas is collected by the environmental smoke collector to make it harmless. It is the actual situation.

【0004】ところで、環境集煙に頼ること無く系外へ
の廃ガスの漏洩を防止しようとすれば、各装置や煙道内
のガス圧を常に過剰に負圧としなければ成らず、過剰能
力の硫酸製造設備を設けることが必要となり、あるいは
過剰に負圧とする結果、系内に多量に流入した大気によ
りSO2濃度が極めて低くなったガスを処理できる脱硫
設備を設けることが必要となり、コストの大幅な上昇を
もたらし、場合によっては企業の存続すら危うくなる。
そのため、各装置でのフリーエアーの流入を最小限にし
つつ系内の廃ガスの漏洩を防止する操業方法の開発が常
に求められている。
By the way, in order to prevent the waste gas from leaking out of the system without relying on the environmental smoke collection, it is necessary to constantly make the gas pressure in each device and the flue gas to be an excessive negative pressure. It is necessary to install sulfuric acid production equipment, or as a result of excessive negative pressure, it is necessary to install desulfurization equipment that can process gas whose SO 2 concentration has become extremely low due to the large amount of air that has flowed into the system. And even the survival of the company may be jeopardized.
Therefore, there is always a demand for the development of an operating method for preventing the leakage of waste gas in the system while minimizing the inflow of free air into each device.

【0005】ところで、自熔炉内の圧力を所望の値に制
御する方法としては、自熔炉の下流側に設けられた前記
集塵機入り口にコントロールダンパーを設け、このコン
トロールダンパーの開度を、連続的に測定した自熔炉の
炉内圧力に応じて調節するのが一般的である。
By the way, as a method of controlling the pressure in the flash furnace to a desired value, a control damper is provided at the entrance of the dust collector provided on the downstream side of the flash furnace, and the opening of the control damper is continuously changed. It is generally adjusted according to the measured internal pressure of the flash furnace.

【0006】しかし、この方法によると、炉内圧力の検
出部とコントロールダンパーの間には廃熱回収ボイラー
があり、時定数が大きくコントロールダンパーの開度の
変化に対する炉内圧力の応答に遅れが生じ易い。加え
て、廃熱回収ボイラー内の水管表面に付着する煙灰を除
去するために設けられたスートブロワーの運転時には、
煙灰を水管表面から吹き飛ばすべく多量の空気が一時的
に急激に廃熱回収ボイラー内に吹き込まれる。このた
め、自熔炉内の圧力に非常に急激な圧力変動が起きるこ
とになる。そして、この様な急激な圧力変動は廃ガス処
理系全体では吸収できないため、自熔炉より廃ガスが炉
外部に漏洩する。この自熔炉外に漏洩した廃ガスは環境
集煙装置で回収し、建屋外に絶対に漏洩させないようし
なければならず、どうしても環境集煙装置の能力を過剰
とせざるを得ない。この様な問題は操業度が上がれば上
がるほど顕在化し、重大化してくる。
However, according to this method, there is a waste heat recovery boiler between the detection unit of the furnace pressure and the control damper, and the time constant is large and the response of the furnace pressure to the change of the opening of the control damper is delayed. It is easy to occur. In addition, during operation of the soot blower provided to remove the smoke ash attached to the surface of the water pipe in the waste heat recovery boiler,
A large amount of air is temporarily and rapidly blown into the waste heat recovery boiler to blow off the smoke ash from the surface of the water pipe. For this reason, the pressure in the flash furnace undergoes a very rapid pressure fluctuation. Since such a rapid pressure fluctuation cannot be absorbed by the entire waste gas treatment system, the waste gas leaks from the flash furnace to the outside of the furnace. The waste gas that leaks to the outside of the flash furnace must be collected by an environmental smoke collector to prevent it from leaking outside the building, and the capacity of the environmental smoke collector must be excessive. Such problems become more serious and more serious as the operating rate increases.

【0007】[0007]

【発明が解決しようとする課題】本発明は係る実状に鑑
みなされたものであり、この様な急激に発生する外乱要
因に対しても有効な炉内圧の制御方法の提供を目的とす
る。
SUMMARY OF THE INVENTION The present invention has been made in view of the above circumstances, and an object of the present invention is to provide a method for controlling the internal pressure of a furnace which is effective against such a sudden disturbance factor.

【0008】[0008]

【課題を解決するための手段】上記課題を解消する本発
明の自熔炉の炉内圧の制御方法は、その頂部に精鉱バー
ナーを有する反応塔と、該反応塔の下端にその一端が接
続されセトラーと、セトラーの他端に設けられた排煙道
から基本的に構成される自熔炉と、該自熔炉の廃煙道と
連結された廃熱回収ボイラーと、廃熱回収ボイラーにコ
ントロール弁を介して連結された集塵機により基本的に
構成される自熔製錬設備の自熔炉の炉内圧の制御方法に
おいて、自熔炉炉内圧を1次とし、廃熱回収ボイラー出
口圧を2次としたカスケード制御によりコントロール弁
の開度を調節するものであり、より具体的には廃熱回収
ボイラー出口圧の計測値と規定値との差の大きさに基づ
きコントロール弁の開度を調節し、該規定値を自熔炉の
炉内圧の計測値と設定値との差に基づき調整するもので
ある。
A method of controlling the internal pressure of a flash furnace of the present invention which solves the above-mentioned problems is a reaction tower having a concentrate burner at the top thereof, and one end of which is connected to the lower end of the reaction tower. A settling furnace, a flash furnace basically composed of a smoke exhaust path provided at the other end of the settler, a waste heat recovery boiler connected to the waste smoke path of the flash furnace, and a control valve for the waste heat recovery boiler. In a method for controlling the internal pressure of a flash furnace of a flash smelting equipment that is basically composed of dust collectors connected via a cascade, the internal pressure of the flash furnace is primary and the outlet pressure of the waste heat recovery boiler is secondary The opening of the control valve is adjusted by control, and more specifically, the opening of the control valve is adjusted based on the size of the difference between the measured value of the waste heat recovery boiler outlet pressure and the specified value. The measured value is the measured value of the internal pressure of the flash furnace. And adjusts on the basis of the difference between the value.

【0009】[0009]

【作用】本発明の方法において、自熔炉の炉内圧を負側
の所定値に維持することは前提条件となっている。廃ガ
ス系統におけるスートブロワー等の圧変動の発生にもか
かわらず、この条件を満たすためにはコントロール弁の
開度を変更する基準信号をどの位置で検出された圧力に
するかが極めて重要になる。本発明ではこの位置を廃熱
回収ボイラー出口とした。これは炉内圧と廃熱回収ボイ
ラー出口圧との変動が一定のタイムラグを前提とし、最
も強い相関を示したからである。すなわち、廃熱回収ボ
イラー出口圧に変動が生じると一定時間後に必ず自熔炉
炉内圧に同じ変動を生じ、かつ廃熱回収ボイラー出口圧
の変動の大きさと自熔炉炉内圧の変動の大きさとに相関
係数0.911という極めて強い相関関係があるからであ
る。加えて、廃熱回収ボイラーにスートブロワーが設け
られている場合には、該スートブロワーの運転により生
ずる圧変動を最も早く検知できる位置でもあるからであ
る。
In the method of the present invention, maintaining the internal pressure of the flash furnace at a predetermined value on the negative side is a prerequisite. Despite the occurrence of pressure fluctuations such as soot blower in the waste gas system, in order to satisfy this condition, it is extremely important to determine at which position the detected pressure is the reference signal that changes the opening of the control valve. . In the present invention, this position is the outlet of the waste heat recovery boiler. This is because the fluctuations between the internal pressure of the furnace and the outlet pressure of the waste heat recovery boiler showed the strongest correlation, assuming a constant time lag. That is, if the outlet pressure of the waste heat recovery boiler fluctuates, the same fluctuation in the internal pressure of the flash furnace will always occur after a certain period of time, and the fluctuation of the outlet pressure of the waste heat recovery boiler and the fluctuation of the internal pressure of the flash furnace will be proportional to each other. This is because there is an extremely strong correlation of 0.911. In addition, when the waste heat recovery boiler is provided with a soot blower, this is also the position where the pressure fluctuation caused by the operation of the soot blower can be detected earliest.

【0010】よって、本発明の方法では、自熔炉炉内圧
が所定の負圧となるように前記相関関係より得られる廃
熱回収ボイラー出口圧を選定し、これを規定値とし、廃
熱回収ボイラー出口圧の測定値と規定値との差を基にコ
ントロール弁の開度を増減する。このための制御動作と
してP動作、PI動作、PD動作、PID動作など種々
の動作方式の採用が可能であり、適用する系に最も対応
したものを採用すれば良いが、通常PID動作による制
御が最適である。
Therefore, in the method of the present invention, the outlet pressure of the waste heat recovery boiler obtained from the above correlation is selected so that the internal pressure of the flash heating furnace becomes a predetermined negative pressure, and this is set as the specified value, and the waste heat recovery boiler is set. Increase or decrease the control valve opening based on the difference between the measured outlet pressure and the specified value. As a control operation for this purpose, various operation methods such as P operation, PI operation, PD operation, and PID operation can be adopted, and the one that most corresponds to the system to be applied may be adopted. Optimal.

【0011】自熔炉の操業状態が一定である限り、コン
トロール弁の開度の調整は廃熱回収ボイラー出口圧のみ
に依存する調整方法で支障はない。しかし、操業条件は
用いる鉱種の変更や炉況の変動に応じてして変更される
ため、長期にわたり一定となることはない。この場合、
特に反応塔に吹き込む反応用気体の量の増減によりボイ
ラー出口圧と自熔炉炉内圧との相関関係を示す関係式の
係数は異なるものとなってくる。この係数の差に対する
修正が自熔炉炉内圧の測定値と設定値との差に基づく前
記廃熱回収ボイラー出口圧の規定値の修正である。
As long as the operating state of the flash furnace is constant, the adjustment of the opening of the control valve can be done by an adjusting method that depends only on the outlet pressure of the waste heat recovery boiler. However, the operating conditions do not remain constant over a long period of time because they change according to changes in the mineral species used and fluctuations in the furnace conditions. in this case,
In particular, the coefficient of the relational expression showing the correlation between the boiler outlet pressure and the internal pressure of the flash furnace becomes different as the amount of the reaction gas blown into the reaction tower increases or decreases. The correction for the difference in the coefficient is the correction for the specified value of the outlet pressure of the waste heat recovery boiler based on the difference between the measured value and the set value of the internal pressure of the flash furnace.

【0012】[0012]

【実施例】次に本発明の実施例について述べる。 (実施例1)PID動作による制御を用いた本発明の自
熔炉の炉内圧の制御方法で廃熱回収ボイラー出口に設け
られたコントロール弁の開度調整をする自熔炉を用いて
操業試験を行った。反応塔への製錬原料の装入を開始す
る(操業開始)と共に手動で自熔炉炉内圧を−3mmAqと
なるように、廃ガスファンの回転数とコントロール弁の
開度を調整した。操業が安定した時点で自熔炉炉内圧の
制御を自動制御に切り替えた。この時点での自熔炉炉内
圧は−3mmAqであり、廃熱回収ボイラー出口圧の値はほ
ぼ−7mmAqであり、コントロール弁の開度は約70%であ
った。
EXAMPLES Next, examples of the present invention will be described. (Example 1) An operation test was conducted using a flash furnace in which the opening of a control valve provided at the outlet of a waste heat recovery boiler was adjusted by the method for controlling the internal pressure of the flash furnace of the present invention using the control by PID operation. It was When the charging of the smelting raw material into the reaction tower was started (start of operation), the rotation speed of the exhaust gas fan and the opening of the control valve were manually adjusted so that the internal pressure of the flash furnace was -3 mmAq. When the operation became stable, the control of the internal pressure of the flash furnace was switched to automatic control. At this time, the internal pressure of the flash furnace was -3 mmAq, the value of the outlet pressure of the waste heat recovery boiler was approximately -7 mmAq, and the opening of the control valve was approximately 70%.

【0013】また、このときの操業条件は銅精鉱装入量
92t/H、補助燃料としての重油の吹き込み量155l/
H、反応用空気の吹き込み量33000Nm3/Hであった。ま
た、操業途中に廃熱回収ボイラーに設けられた1本の吹
き込み管より3000Nm3/Hの吹き込み量で1分15秒のス
ートブロワーの運転を行った。このスートブロワーの運
転時間をほぼ中心に含む全9分間の炉内圧の変動を示し
たチャートを5秒刻みで読みとり、自熔炉炉内圧の変動
を調べた。その結果、炉内圧の設定値−3mmAqに対し計
測値の平均値は−2.91mmAq、σN-1は0.83mmAqであっ
た。
The operating condition at this time is the amount of copper concentrate charged.
92t / H, blowing amount of heavy oil as auxiliary fuel 155l /
H, the blowing amount of reaction air was 33000 Nm 3 / H. During the operation, the soot blower was operated for 1 minute and 15 seconds with a blowing amount of 3000 Nm 3 / H from one blowing pipe provided in the waste heat recovery boiler. A chart showing fluctuations in the furnace pressure for a total of 9 minutes including the operation time of the soot blower at the center was read at 5-second intervals, and fluctuations in the furnace pressure in the flash furnace were examined. As a result, the average value of the measured values was -2.91 mmAq and σ N-1 was 0.83 mmAq with respect to the set value of the furnace pressure of -3 mmAq.

【0014】(従来例)従来通り、コントロール弁を自
熔炉炉内圧のみでPID動作による制御し、廃熱回収ボ
イラー出口圧を成りゆきとした以外は実施例と同様にし
て自熔炉炉内圧の変動を調べた。その結果、炉内圧の設
定値−3mmAqに対し計測値の平均値は−3.54mmAq、σ
N-1は1.62mmAqであった。また、スートブロワー運転時
に2回自熔炉の炉内圧が正圧になり、自熔炉の点検孔よ
りのガスの吹き出しが起きた。以上の結果より本発明の
自熔炉の炉内圧の制御方法を用いれば自熔炉炉内圧を安
定化できることは明かである。
(Conventional example) As in the conventional case, the fluctuation of the internal pressure of the flash furnace is controlled in the same manner as in the example except that the control valve is controlled by the PID operation only by the internal pressure of the flash furnace and the outlet pressure of the waste heat recovery boiler is controlled. Examined. As a result, the average value of the measured values was -3.54 mmAq, σ for the set value of the furnace pressure -3 mmAq.
N-1 was 1.62 mmAq. Further, during soot blower operation, the internal pressure of the flash furnace became positive twice and gas was blown out from the inspection hole of the flash furnace. From the above results, it is clear that the internal pressure of the flash furnace can be stabilized by using the method for controlling the internal pressure of the flash furnace of the present invention.

【0015】[0015]

【発明の効果】本発明の自熔炉の炉内圧の制御方法で
は、コントロール弁の開度の変化に対するボイラー出口
圧の応答が早くなる結果、自熔炉炉内圧のコントロール
弁の開度変化に対する応答速度が早くなる。さらに主と
してスートブロワー時に引き起こされる廃熱回収ボイラ
ー内の圧変動もいち早く検知できるため自熔炉炉内圧を
良好に制御できる。
In the method for controlling the internal pressure of the flash furnace of the present invention, the response of the boiler outlet pressure to the change in the opening of the control valve becomes faster, resulting in the response speed of the internal pressure of the flash furnace to the change in the opening of the control valve. Will be faster. Furthermore, pressure fluctuations in the waste heat recovery boiler, which are mainly caused by soot blowers, can be detected quickly, so that the internal pressure of the flash furnace can be well controlled.

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 その頂部に精鉱バーナーを有する反応
塔と、該反応塔の下端にその一端が接続されたセトラー
と、セトラーの他端に設けられた排煙道から基本的に構
成される自熔炉と、該自熔炉の廃煙道と連結された廃熱
回収ボイラーと、廃熱回収ボイラーにコントロール弁を
介して連結された集塵機により基本的に構成される自熔
製錬設備の自熔炉の炉内圧の制御方法において、自熔炉
炉内圧を1次とし、廃熱回収ボイラー出口圧を2次とし
たカスケード制御によりコントロール弁の開度を調節す
ることを特徴とする自熔炉の炉内圧の制御方法。
1. A reaction column having a concentrate burner at its top, a settler having one end connected to the lower end of the reaction column, and a flue gas duct provided at the other end of the settler. A self-smelting furnace of a self-smelting and smelting facility basically composed of a self-smelting furnace, a waste heat recovery boiler connected to a waste flue of the self-smelting furnace, and a dust collector connected to the waste heat recovery boiler via a control valve. In the method for controlling the internal pressure of the flash furnace, the internal pressure of the flash furnace is set as the primary and the outlet pressure of the waste heat recovery boiler is set as the secondary to adjust the opening of the control valve by the cascade control. Control method.
【請求項2】 廃熱回収ボイラー出口圧の計測値と規
定値との差の大きさに基づきコントロール弁の開度を調
節し、該規定値が自熔炉の炉内圧の計測値と設定値との
差に基づき調整されることを特徴とする請求項1記載の
自熔炉の炉内圧の制御方法。
2. The opening of the control valve is adjusted based on the difference between the measured value of the outlet pressure of the waste heat recovery boiler and the specified value, and the specified value is the measured value and the set value of the furnace pressure of the flash furnace. The method for controlling the furnace pressure of the flash furnace according to claim 1, wherein the method is adjusted on the basis of the difference.
JP20698793A 1993-07-30 1993-07-30 Control method of internal pressure of self-fluxing furnace Pending JPH0743081A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP20698793A JPH0743081A (en) 1993-07-30 1993-07-30 Control method of internal pressure of self-fluxing furnace

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP20698793A JPH0743081A (en) 1993-07-30 1993-07-30 Control method of internal pressure of self-fluxing furnace

Publications (1)

Publication Number Publication Date
JPH0743081A true JPH0743081A (en) 1995-02-10

Family

ID=16532309

Family Applications (1)

Application Number Title Priority Date Filing Date
JP20698793A Pending JPH0743081A (en) 1993-07-30 1993-07-30 Control method of internal pressure of self-fluxing furnace

Country Status (1)

Country Link
JP (1) JPH0743081A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007121536A1 (en) * 2006-04-24 2007-11-01 Technological Resources Pty. Limited Pressure control in direct smelting process
WO2007121531A1 (en) * 2006-04-24 2007-11-01 Technological Resources Pty. Limited Pressure control in direct smelting process
WO2007121530A1 (en) * 2006-04-24 2007-11-01 Technological Resources Pty. Limited Direct smelting plant with waste heat recovery unit

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007121536A1 (en) * 2006-04-24 2007-11-01 Technological Resources Pty. Limited Pressure control in direct smelting process
WO2007121531A1 (en) * 2006-04-24 2007-11-01 Technological Resources Pty. Limited Pressure control in direct smelting process
WO2007121530A1 (en) * 2006-04-24 2007-11-01 Technological Resources Pty. Limited Direct smelting plant with waste heat recovery unit

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