JPH07126712A - Deburring method of injection molded goods of metallic powder goods - Google Patents

Deburring method of injection molded goods of metallic powder goods

Info

Publication number
JPH07126712A
JPH07126712A JP30102093A JP30102093A JPH07126712A JP H07126712 A JPH07126712 A JP H07126712A JP 30102093 A JP30102093 A JP 30102093A JP 30102093 A JP30102093 A JP 30102093A JP H07126712 A JPH07126712 A JP H07126712A
Authority
JP
Japan
Prior art keywords
brown body
semi
brown
degreasing
burr
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP30102093A
Other languages
Japanese (ja)
Inventor
Kenji Haga
健二 芳賀
Takuya Kodama
卓弥 児玉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Olympus Corp
Original Assignee
Olympus Optical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Olympus Optical Co Ltd filed Critical Olympus Optical Co Ltd
Priority to JP30102093A priority Critical patent/JPH07126712A/en
Publication of JPH07126712A publication Critical patent/JPH07126712A/en
Withdrawn legal-status Critical Current

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  • Powder Metallurgy (AREA)

Abstract

PURPOSE:To easily execute the removal of burr with the small deformation of molded goods by removing burr from a half-drown body obtd. by degreasing only an organic binder contained in the surface layer part of a green body and thereafter executing degreasing. CONSTITUTION:In a temporary dewaxing stage, e.g. in the green body 2 of metal powder injection molded goods constituted of metal powder and 30wt.% organic binder and in which a bore part 2b is formed, 3 to 5% of the binder is degreased under heating. Thus, a half-brown body 2 in which the contents of the binder in the surface layer part 2d are reduced while the contents of the binder in the product part 2a are maintained is obtd. Next, this brown body 2 is inserted into a rotary barrel together with adrasive stones, the half- brown body 2 is bombarded with the abrasive stones, and the half-brown body burr 2c are removed away from the half-brown body product part 2c.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、金属粉末射出成形法に
よって得られる焼結部品のバリ除去に関する。
FIELD OF THE INVENTION The present invention relates to deburring of sintered parts obtained by metal powder injection molding.

【0002】[0002]

【従来の技術】従来、粉末冶金による焼結部品のバリを
容易に除去する方法として、例えば特公平5−2196
3号公報には金属粉末を圧縮成形して得られる圧粉体に
対し、焼結前にショットブラスト処理を施す発明が開示
されている。一般に、粉末冶金の圧粉体は焼結完了部品
に比べて保形力が小さいため、前記発明によれば焼結完
了部品よりも容易にバリの除去が行える。
2. Description of the Related Art Conventionally, as a method for easily removing burrs from sintered parts by powder metallurgy, for example, Japanese Patent Publication No. 5-2196.
Japanese Patent Publication No. 3 discloses an invention in which a green compact obtained by compression molding of metal powder is subjected to shot blasting before sintering. Generally, the powder metallurgy green compact has a smaller shape-retaining force than that of the completely-sintered part. Therefore, according to the invention, the burr can be removed more easily than the completely-sintered part.

【0003】[0003]

【発明が解決しようとする課題】金属粉末射出成形法
は、金属粉末と有機バインダーとの混練体を金型に射出
成形してグリーンボディを得る射出工程と、前記グリー
ンボディから有機バインダーを除去してブラウンボディ
を得る脱脂工程と、前記ブラウンボディを焼結して焼結
部品を得る焼結工程とからなる。かかる金属粉末射出成
形品のバリの除去を行う場合、バリの保形力が最も小さ
くなるブラウンボディの状態でバリを除去すれば容易に
バリが除去できる。
[MEANS FOR SOLVING THE PROBLEMS] The metal powder injection molding method comprises an injection step of injection molding a kneaded body of metal powder and an organic binder into a mold to obtain a green body, and removing the organic binder from the green body. And a degreasing step of obtaining a brown body, and a sintering step of sintering the brown body to obtain a sintered component. When removing burrs from such a metal powder injection-molded product, burrs can be easily removed by removing the burrs in the state of the brown body where the shape retention force of the burrs is minimized.

【0004】しかし、焼結時にブラウンボディに含有さ
れる有機バインダーの許容量が極めて小さく(一般的に
ブラウンボディに対して1wt%程度)、またブラウン
ボディに含有されている金属粉末の凝集量が粉末冶金に
おける圧粉体に比べて小さいことから、一般的にブラウ
ンボディは前記圧粉体に比べて保形力が小さい。従っ
て、前記特公平5−21963号公報で開示される方法
を金属粉末射出成形品に用いて脱脂完了後のブラウンボ
ディにショットブラスト処理を行った場合、ブラウンボ
ディが変形する不具合を生じる。
However, the permissible amount of the organic binder contained in the brown body at the time of sintering is extremely small (generally about 1 wt% with respect to the brown body), and the agglomeration amount of the metal powder contained in the brown body is small. Since it is smaller than the green compact in powder metallurgy, the brown body generally has a smaller shape retention force than the green compact. Therefore, when the method disclosed in Japanese Patent Publication No. 5-21963 is used for a metal powder injection-molded article and the brown body after degreasing is shot-blasted, the brown body is deformed.

【0005】因って、本発明は前記従来技術における欠
点に鑑みて開発されたもので、容易で且つ成形品の変形
が少ない金属粉末射出成形品のバリ除去方法を提供する
ことを目的とする。
Therefore, the present invention was developed in view of the above-mentioned drawbacks of the prior art, and an object thereof is to provide a method for removing burrs from a metal powder injection molded product which is easy and has little deformation of the molded product. .

【0006】[0006]

【課題を解決するための手段】本発明は、金属粉末射出
成形品のバリ除去方法において、グリーンボディの表層
部に含有された有機バインダーのみを脱脂して半ブラン
ウンボディを得る仮脱脂工程と、前記半ブラウンボディ
のバリを除去するバリ除去工程と、前記バリが除去され
た半ブラウンボディに含有された有機バインダーを脱脂
して最終ブラウンボディを得る本脱脂工程とからなる方
法である。
Means for Solving the Problems The present invention provides a method for removing burrs of a metal powder injection-molded article, which comprises a temporary degreasing step of degreasing only an organic binder contained in the surface layer of a green body to obtain a semi-blown body. It is a method comprising a deburring step of removing burrs from the semi-brown body, and a degreasing step of degreasing the organic binder contained in the semi-brown body from which the burrs have been removed to obtain a final brown body.

【0007】[0007]

【作用】本発明では、仮脱脂工程にてグリーンボディの
表層部に含有されている有機バインダーのみを脱脂する
ことにより、内部の保形力が維持された状態でバリを含
む表層部の保形力が低下した半ブラウンボディが得られ
る。次に、半ブラウンボディのバリ除去工程において、
内部の保形力によって変形が抑制された状態で保形力の
低下した表層部のバリが容易に除去される。さらに、本
脱脂工程において前記バリが除去された半ブラウンボデ
ィに残留している有機バインダーを所望の含有量まで脱
脂することによって、所望の最終ブラウンボディが得ら
れる。
In the present invention, by degreasing only the organic binder contained in the surface layer of the green body in the temporary degreasing step, the shape retention of the surface layer including burrs is maintained while maintaining the internal shape retention. A semi-brown body with reduced strength is obtained. Next, in the deburring process of the semi-brown body,
The burr on the surface layer portion having a reduced shape retention force is easily removed while the deformation is suppressed by the shape retention force inside. Furthermore, the desired final brown body is obtained by degreasing the organic binder remaining in the semi-brown body from which burrs have been removed in the present degreasing step to a desired content.

【0008】[0008]

【実施例1】図1〜図5は本実施例を示し、図1aおよ
びbはグリーンボディの平面図および縦断面図、図2は
半ブラウンボディの縦断面図、図3は概略説明図、図4
は最終ブラウンボディの縦断面図である。
Embodiment 1 FIGS. 1 to 5 show the present embodiment, FIGS. 1a and 1b are a plan view and a vertical sectional view of a green body, FIG. 2 is a vertical sectional view of a semi-brown body, and FIG. 3 is a schematic explanatory view. Figure 4
FIG. 4 is a vertical sectional view of the final brown body.

【0009】グリーンボディ1は、平均粒径10μmの
SUS316Lの金属粉末と該金属粉末に対して30w
t%のナイロン樹脂からなる有機バインダーとが混練さ
れたコンパウンドを金型(図示せず)に射出成形するこ
とによって得たものである。また、前記グリーンボディ
1のグリーンボディ製品部1aに設けられた内径部1b
には、前記金型の間隙に前記コンパウンドが流れ込んだ
ことによって発生したグリーンボディバリ1cが形成さ
れている。
The green body 1 is made of SUS316L metal powder having an average particle size of 10 μm and 30 w with respect to the metal powder.
It is obtained by injection-molding a compound (not shown) in which a compound kneaded with an organic binder made of t% nylon resin is kneaded. Also, an inner diameter portion 1b provided in the green body product portion 1a of the green body 1
The green body burr 1c which is generated by the compound flowing into the gap of the mold is formed on the.

【0010】まず、グリーンボディ1を通常の加熱脱脂
炉(図示せず)にて前記ナイロン樹脂の3〜5wt%を
加熱脱脂して、半ブラウンボディ2を得る(仮脱脂工程
−図2参照)。次に、前記半ブラウンボディ2を研磨石
3とともに回転バレル4内に挿入し、研磨石3を半ブラ
ウンボディバリ2cに衝突させることによって、半ブラ
ウンボディバリ2cを半ブラウンボディ製品部2aより
離脱する(バリ除去工程−図3参照)。
First, the green body 1 is heated and degreased with 3 to 5 wt% of the nylon resin in an ordinary heating and degreasing furnace (not shown) to obtain a semi-brown body 2 (temporary degreasing step-see FIG. 2). . Next, the semi-brown body burr 2c is inserted from the semi-brown body burr 2c into the rotary barrel 4, and the semi-brown body burr 2c is separated from the semi-brown body product part 2a. (Deburring step—see FIG. 3).

【0011】この後、半ブラウンボディ2を加熱脱脂炉
(図示せず)に挿入して、ナイロン樹脂を最終ブラウン
ボディ5に対して0.5wt%の含有量になるまで加熱
脱脂することによって最終ブラウンボディ5を得る(本
脱脂工程−図4参照)。さらに、前記最終ブラウンボデ
ィ5を通常の焼結炉(図示せず)によって焼結し、焼結
完了部品(図示せず)を得る。
Thereafter, the semi-brown body 2 is inserted into a heating degreasing furnace (not shown), and the nylon resin is heated and degreased until the content of the nylon resin becomes 0.5 wt% with respect to the final brown body 5. A brown body 5 is obtained (this degreasing step—see FIG. 4). Further, the final brown body 5 is sintered in a normal sintering furnace (not shown) to obtain a completed sintering component (not shown).

【0012】以下、本実施例の作用を説明する。仮脱脂
工程において、加熱がグリーンボディ1のグリーンボデ
ィ表層部1dから内側のグリーンボディ製品部1aの順
に行われること、および加熱分解温度に加熱されたナイ
ロン樹脂がガス化してグリーンボディ表層部1dより飛
散することから、加熱脱脂がグリーンボディ表層部1d
からグリーンボディ製品部1aに向かって順に行われ
る。
The operation of this embodiment will be described below. In the temporary degreasing step, heating is performed in the order from the green body surface layer portion 1d of the green body 1 to the inner green body product portion 1a, and the nylon resin heated to the thermal decomposition temperature is gasified to be heated from the green body surface layer portion 1d. Since it scatters, the heat degreasing causes the green body surface layer 1d.
To the green body product section 1a.

【0013】従って、半ブラウンボディ2では半ブラウ
ンボディ製品部2aのナイロン樹脂の含有量が維持され
たまま半ブラウンボディ表層部2dのナイロン樹脂の含
有率が低下する。すなわち、半ブラウンボディ製品部2
aの保形力が維持された状態で半ブラウンボディバリ2
cを含む半ブラウンボディ表層部2dの保形力のみが低
下している。
Therefore, in the semi-brown body 2, the content of the nylon resin in the semi-brown body surface portion 2d decreases while the content of the nylon resin in the semi-brown body product portion 2a is maintained. That is, the semi-brown body product section 2
Semi-brown body burr 2 with the shape retention of a maintained.
Only the shape retention force of the semi-brown body surface layer portion 2d including c is reduced.

【0014】次に、バリ除去工程において前記保形力が
低下している半ブラウンボディバリ2cに研磨石3が衝
突し、その時の衝撃力によって半ブラウンボディバリ2
cが半ブラウンボディ製品部2aより離脱する。この
後、本脱脂工程にて半ブラウンボディ2の半ブラウンボ
ディ製品部2aのナイロン樹脂が所望の含有量になるま
で加熱脱脂され、最終ブラウンボディ5が得られる。
Next, in the deburring step, the polishing stone 3 collides with the semi-brown body burr 2c whose shape-retaining force is lowered, and the impact force at that time causes the semi-brown body burr 2 to have a shape.
c separates from the semi-brown body product part 2a. After this, in the degreasing step, the nylon resin in the semi-brown body product portion 2a of the semi-brown body 2 is heated and degreased until the desired content is obtained, and the final brown body 5 is obtained.

【0015】本実施例によれば、半ブラウンボディ2の
半ブラウンボディ製品部2aの保形力が維持された状態
で保形力が低下した半ブラウンボディバリ2cの除去を
行うため、半ブラウンボディ製品部2aが変形すること
なく半ブラウンボディバリ2cを半ブラウンボディ製品
部2aより除去できる。
According to this embodiment, the semi-brown body burr 2c whose shape-retaining force is lowered is removed while the shape-retaining force of the semi-brown body product part 2a of the semi-brown body 2 is maintained. The semi-brown body burr 2c can be removed from the semi-brown body product 2a without deforming the body product 2a.

【0016】[0016]

【実施例2】図5は本実施例を示す概略説明図である。
本実施例は、前記実施例1におけるバリ除去工程が異な
るもので、他の構成は同一な構成部分から成り、同一構
成部分には同一番号を付してその説明を省略する。
Second Embodiment FIG. 5 is a schematic explanatory view showing the present embodiment.
The present embodiment is different in the burr removal process in the first embodiment, and the other construction is composed of the same constituent parts, and the same constituent parts are designated by the same reference numerals and the description thereof will be omitted.

【0017】半ブラウンボディ2をショットブラスト装
置(図示せず)のノズル6上下間に挿入した状態で、ノ
ズル6上下より半ブラウンボディ表層部2dおよび半ブ
ラウンボディバリ2cに研磨粉7を吹きつける。この
際、半ブラウンボディ表層部2d全体へ均等に研磨粉7
が衝突する様に、ノズル6上下間で半ブラウンボディ2
の移動,反転および持ち替えを繰り返し行う。また、前
記半ブラウンボディ2の移動および反転はロボット(図
示せず)や回転バレル(図示せず)等の自動機で行って
も良い。
With the semi-brown body 2 inserted between the upper and lower sides of the nozzle 6 of the shot blasting device (not shown), the abrasive powder 7 is sprayed from the upper and lower sides of the nozzle 6 onto the semi-brown body surface layer portion 2d and the semi-brown body burr 2c. . At this time, the polishing powder 7 is evenly distributed over the entire surface layer 2d of the semi-brown body.
So that they collide with each other, a half brown body 2 is placed between the upper and lower parts of the nozzle 6.
Repeatedly move, invert, and change patterns. The movement and reversal of the semi-brown body 2 may be performed by an automatic machine such as a robot (not shown) or a rotating barrel (not shown).

【0018】以下、本実施例の作用を説明する。半ブラ
ウンボディ表層部2dおよび半ブラウンボディバリ2c
に研磨粉7が衝突した時の衝撃力で、半ブラウンボディ
バリ2cが半ブラウンボディ製品部1aから離脱する。
他は前記実施例1と同様な作用であり、作用の説明を省
略する。
The operation of this embodiment will be described below. Half brown body surface layer 2d and half brown body burr 2c
The semi-brown body burr 2c is detached from the semi-brown body product portion 1a by the impact force when the polishing powder 7 collides with.
The other operations are the same as those in the first embodiment, and the description of the operation is omitted.

【0019】本実施例によれば、前記実施例1の効果に
加えて以下の効果がある。前記実施例1における研磨石
3の衝撃力よりもノズル6より噴出する研磨粉7の衝撃
力の調整が容易であるため、半ブラウンボディ製品部2
aを損傷させる危険が前記実施例1よりも小さい。
According to this embodiment, the following effects are obtained in addition to the effects of the first embodiment. Since it is easier to adjust the impact force of the polishing powder 7 ejected from the nozzle 6 than the impact force of the polishing stone 3 in the first embodiment, the semi-brown body product portion 2
The risk of damaging a is smaller than that in the first embodiment.

【0020】[0020]

【実施例3】図6は本実施例を示す概略説明図である。
本実施例は、前記実施例1における仮脱脂工程が異なる
もので、他の構成は同一な構成部分から成り、同一構成
部分には同一番号を付してその説明を省略する。
Third Embodiment FIG. 6 is a schematic explanatory view showing the present embodiment.
The present embodiment is different from the first embodiment in the temporary degreasing step, and the other components are the same, and the same components are designated by the same reference numerals and the description thereof is omitted.

【0021】仮脱脂工程においてグリーンボディ1をN
aOH水溶液8が注入されたパレット9内に挿入し、グ
リーンボディ1をNaOH水溶液8に液浸させることに
よってグリーンボディ1に含有されたナイロン樹脂を溶
解する。前記ナイロン樹脂の3〜5wt%を溶解脱脂し
た後、グリーンボディ1をパレット9より取り出して、
半ブラウンボディ2を得る。
In the temporary degreasing process, the green body 1 is
The nylon resin contained in the green body 1 is dissolved by inserting it into the pallet 9 into which the aOH aqueous solution 8 has been injected and immersing the green body 1 in the NaOH aqueous solution 8. After dissolving and degreasing 3 to 5 wt% of the nylon resin, the green body 1 is taken out from the pallet 9,
Get a half brown body 2.

【0022】以下、本実施例の作用を説明する。グリー
ンボディ1をNaOH水溶液8内に液浸させることによ
ってNaOHがナイロン樹脂を溶解しながらグリーンボ
ディ1内に浸透していくことにより、ナイロン樹脂の溶
解脱脂がグリーンボディ表層部1dよりグリーンボディ
製品部1aに向かって順に行われる。
The operation of this embodiment will be described below. By immersing the green body 1 in the aqueous NaOH solution 8 and allowing the NaOH to permeate into the green body 1 while dissolving the nylon resin, the nylon resin is dissolved and degreased from the green body surface layer portion 1d to the green body product portion. The steps are sequentially performed toward 1a.

【0023】従って、半ブラウンボディ2では半ブラウ
ンボディ製品部2aのナイロン樹脂の含有量が維持され
たま半ブラウンボディ表層部2dのナイロン樹脂の含有
率が低下する。すなわち、半ブラウンボディ製品部2a
の保形力が維持された状態で半ブラウンボディバリ2c
を含む半ブラウンボディ表層部2dの保形力のみが低下
する。他は前記実施例1と同様な作用であり、作用の説
明を省略する。
Therefore, in the semi-brown body 2, the content of nylon resin in the semi-brown body product portion 2a is maintained, and the content rate of nylon resin in the semi-brown body surface portion 2d decreases. That is, the semi-brown body product part 2a
Half brown body burr 2c with the shape retention of
Only the shape-retaining power of the semi-brown body surface layer portion 2d including is reduced. The other operations are the same as those in the first embodiment, and the description of the operation is omitted.

【0024】本実施例によれば、前記実施例1の効果に
加えて以下の効果がある。前記実施例1における加熱脱
脂よりもNaOH水溶液8による溶解脱脂の方が、グリ
ーンボディ表層部1dのナイロン樹脂を早く脱脂するた
め、前記実施例1よりも加工時間を短くできる。
According to this embodiment, the following effects are obtained in addition to the effects of the first embodiment. The dissolution degreasing with the NaOH aqueous solution 8 degreases the nylon resin of the green body surface layer portion 1d earlier than the heating degreasing in Example 1, and thus the processing time can be shorter than that in Example 1.

【0025】[0025]

【発明の効果】以上説明した様に、本発明に係る金属粉
末射出成形品のバリ除去方法によれば、半ブラウンボデ
ィのバリ除去工程において、内部の保形力によって変形
が抑制された状態で保形力の低下した表層部のバリが容
易に除去されるため、金属粉末射出成形品のバリを容易
に且つ成形品を変形させることなく除去できる。
As described above, according to the method for removing burrs of metal powder injection-molded articles according to the present invention, in the step of removing burrs of a semi-brown body, the deformation is suppressed by the internal shape retention force. Since the burrs on the surface layer portion having the reduced shape retention are easily removed, the burrs of the metal powder injection-molded product can be easily removed without deforming the molded product.

【図面の簡単な説明】[Brief description of drawings]

【図1】実施例1を示し、aは平面図、bは縦断面図で
ある。
1A and 1B show a first embodiment, in which a is a plan view and b is a longitudinal sectional view.

【図2】実施例1を示す縦断面図である。FIG. 2 is a vertical sectional view showing the first embodiment.

【図3】実施例1を示す概略説明図である。FIG. 3 is a schematic explanatory diagram illustrating a first embodiment.

【図4】実施例1を示す縦断面図である。FIG. 4 is a vertical sectional view showing the first embodiment.

【図5】実施例2を示す概略説明図である。FIG. 5 is a schematic explanatory view showing a second embodiment.

【図6】実施例3を示す概略説明図である。FIG. 6 is a schematic explanatory view showing a third embodiment.

【符号の説明】[Explanation of symbols]

1 グリーンボディ 2 半ブラウンボディ 3 研磨石 4 回転バレル 5 最終ブラウンボディ 1 Green body 2 Half brown body 3 Polishing stone 4 Rotating barrel 5 Final brown body

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 金属粉末射出成形品のバリ除去方法にお
いて、グリーンボディの表層部に含有された有機バイン
ダーのみを脱脂して半ブラウンボディを得る仮脱脂工程
と、前記半ブラウンボディのバリを除去するバリ除去工
程と、前記バリが除去された半ブラウンボディに含有さ
れた有機バインダーを脱脂して最終ブラウンボディを得
る本脱脂工程とからなることを特徴とする金属粉末射出
成形品のバリ除去方法。
1. A method for removing burrs from a metal powder injection-molded article, comprising a temporary degreasing step of degreasing only an organic binder contained in the surface layer of a green body to obtain a semi-brown body, and removing the burrs from the semi-brown body. And a degreasing step of degreasing the organic binder contained in the semi-brown body from which the burr has been removed to obtain a final brown body. .
JP30102093A 1993-11-05 1993-11-05 Deburring method of injection molded goods of metallic powder goods Withdrawn JPH07126712A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP30102093A JPH07126712A (en) 1993-11-05 1993-11-05 Deburring method of injection molded goods of metallic powder goods

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP30102093A JPH07126712A (en) 1993-11-05 1993-11-05 Deburring method of injection molded goods of metallic powder goods

Publications (1)

Publication Number Publication Date
JPH07126712A true JPH07126712A (en) 1995-05-16

Family

ID=17891882

Family Applications (1)

Application Number Title Priority Date Filing Date
JP30102093A Withdrawn JPH07126712A (en) 1993-11-05 1993-11-05 Deburring method of injection molded goods of metallic powder goods

Country Status (1)

Country Link
JP (1) JPH07126712A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008531841A (en) * 2005-01-25 2008-08-14 アベルズ ノルベルト Method for forming green body and product produced by the method
US8931171B2 (en) 2005-01-25 2015-01-13 Ormco Corporation Method of manufacturing an orthodontic bracket having a laser shaped green body
US9539064B2 (en) 2005-01-25 2017-01-10 Ormco Corporation Methods for shaping green bodies and articles made by such methods

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008531841A (en) * 2005-01-25 2008-08-14 アベルズ ノルベルト Method for forming green body and product produced by the method
KR101362575B1 (en) * 2005-01-25 2014-02-13 오름코 코포레이션 Methods for shaping green bodies and articles made by such methods
US8931171B2 (en) 2005-01-25 2015-01-13 Ormco Corporation Method of manufacturing an orthodontic bracket having a laser shaped green body
US9107725B2 (en) 2005-01-25 2015-08-18 Ormco Corporation Method of manufacturing an orthodontic bracket having a laser shaped green body
US9539064B2 (en) 2005-01-25 2017-01-10 Ormco Corporation Methods for shaping green bodies and articles made by such methods
US10058400B2 (en) 2005-01-25 2018-08-28 Ormco Corporation Method of manufacturing an orthodontic bracket having a laser shaped green body

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