JPH0631148A - Device and method for diluting reagent - Google Patents

Device and method for diluting reagent

Info

Publication number
JPH0631148A
JPH0631148A JP4188201A JP18820192A JPH0631148A JP H0631148 A JPH0631148 A JP H0631148A JP 4188201 A JP4188201 A JP 4188201A JP 18820192 A JP18820192 A JP 18820192A JP H0631148 A JPH0631148 A JP H0631148A
Authority
JP
Japan
Prior art keywords
reagent
tank
diluting
solvent
suction
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP4188201A
Other languages
Japanese (ja)
Other versions
JP2568791B2 (en
Inventor
Takashi Naka
隆史 中
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nikkiso Co Ltd
Original Assignee
Nikkiso Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nikkiso Co Ltd filed Critical Nikkiso Co Ltd
Priority to JP4188201A priority Critical patent/JP2568791B2/en
Priority to TW82102484A priority patent/TW273009B/zh
Publication of JPH0631148A publication Critical patent/JPH0631148A/en
Application granted granted Critical
Publication of JP2568791B2 publication Critical patent/JP2568791B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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  • Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)

Abstract

PURPOSE:To provide a device for diluting reagent extremely simple in structure, capable of saving space to install in a narrow space and supplying the reagent solution of a prescribed conc. to a desired place while keeping continuously stable state. CONSTITUTION:The device for diluting the reagent 1 is provided with a suction and discharge means sucking and discharging each of the reagent original solution from a reagent tank 2 and a diluting solvent from a solvent tank 3 in a synchronous state and a non-straight mixing pipe 5 for receiving the reagent original solution and the diluting solvent and feeding to the desired place while mixing both and diluting in a prescribed conc.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、試薬の希釈装置および
その希釈方法に関し、例えば、イオンクロマトグラフに
よるイオン検出に好適に適用することのできる試薬の希
釈装置及びその希釈方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a reagent diluting apparatus and a diluting method thereof, for example, a reagent diluting apparatus and a diluting method thereof which can be suitably applied to ion detection by an ion chromatograph.

【0002】[0002]

【従来の技術】例えば、BWR型の原子力発電プラント
や原子炉の炉水中のイオン検出、IC工場の超純水中の
イオン検出等に用いられるイオンクロマトグラフに対し
て溶離液等の試薬を流す場合には、イオンクロマトグラ
フの分離カラムに常に希釈した所定濃度の試薬を流し続
けることが要請される。
2. Description of the Related Art For example, a reagent such as an eluent is flowed to an ion chromatograph used for detecting ions in reactor water of a BWR type nuclear power plant or a nuclear reactor, or detecting ions in ultrapure water of an IC factory. In this case, it is required to constantly keep the diluted reagent having a predetermined concentration flowing in the separation column of the ion chromatograph.

【0003】このような用途に用いられる試薬の希釈装
置として、従来、図6に示すものが知られている。
As a reagent diluter used for such an application, the one shown in FIG. 6 is conventionally known.

【0004】同図に示す試薬の希釈装置20は、予め所
定濃度となるように試薬及び純水を混合希釈した試薬液
を大量に収納した大容量タンク21と、この大容量タン
ク21からイオンクロマトグラフの分離カラムへの配管
22に接続され、大容量タンク21内の試薬液を吸引し
て分離カラムへ送るポンプ23とを具備している。
The reagent diluting device 20 shown in FIG. 1 has a large-capacity tank 21 in which a large amount of a reagent solution prepared by mixing and diluting a reagent and pure water to a predetermined concentration is stored, and an ion chromatograph from the large-capacity tank 21. It is provided with a pump 23 which is connected to the pipe 22 to the separation column in the graph and which sucks the reagent solution in the large capacity tank 21 and sends it to the separation column.

【0005】また、図7に示す試薬の希釈装置30は、
試薬原液を収納した比較的小容量の試薬タンク31と、
純水を収納した比較的小容量の純水タンク32と、試薬
原液と純水との混合希釈を行う希釈タンク33と、試薬
タンク31から希釈タンク33へ試薬原液を送る試薬ポ
ンプ34と、純水タンク32から希釈タンク33へ試薬
を送る純水ポンプ35と、希釈タンク33から分離カラ
ムへ試薬液を送る供給ポンプ36とを具備していてる。
Also, the reagent diluting device 30 shown in FIG.
A reagent tank 31 having a relatively small capacity for storing the reagent stock solution,
A relatively small capacity pure water tank 32 that stores pure water, a dilution tank 33 that mixes and dilutes a reagent stock solution and pure water, a reagent pump 34 that sends the reagent stock solution from the reagent tank 31 to the dilution tank 33, and a pure water tank. A pure water pump 35 for sending a reagent from the water tank 32 to the dilution tank 33 and a supply pump 36 for sending a reagent solution from the dilution tank 33 to the separation column are provided.

【0006】[0006]

【発明が解決しようとする課題】しかしながら、上述し
た試薬の希釈装置20の場合、大容量タンク21の設置
スペースが広大となるため、BWR型の原子力発電所内
等の狭いスペースへの設置が困難になるという問題があ
る。
However, in the case of the above-mentioned reagent diluting device 20, the installation space of the large-capacity tank 21 is so large that it is difficult to install it in a narrow space such as a BWR type nuclear power plant. There is a problem of becoming.

【0007】また、上述した試薬の希釈装置30の場
合、試薬タンク31、純水タンク32の他、希釈タンク
33が必要になること、ポンプ個数が増えること等の要
因でやはり狭いスペースへの設置が困難になるという問
題がある。
Further, in the case of the above-described reagent diluting device 30, the diluting tank 33 is required in addition to the reagent tank 31, the deionized water tank 32, and the number of pumps is increased. There is a problem that it becomes difficult.

【0008】そこで、本発明は、構成が極めて簡略で省
スペース化が図れ狭いスペースへの設置が可能であると
ともに、安定した継続状態を維持しつつ所定濃度の試薬
液を目的箇所へ送ることができる試薬の希釈装置及び希
釈方法を提供することを目的とするものである。
In view of the above, the present invention has a very simple structure, can save space, can be installed in a narrow space, and can send a reagent solution of a predetermined concentration to a target location while maintaining a stable continuous state. It is an object of the present invention to provide a diluting device and a diluting method for a reagent that can be used.

【0009】[0009]

【課題を解決するための手段】本発明の試薬の希釈装置
は、試薬タンクから試薬原液と、溶媒タンクからの希釈
溶媒とを同期した状態で各々吸引吐出する吸引吐出手段
と、この吸引吐出手段から吐出される試薬原液、希釈溶
媒を受け入れて両者を所定濃度に混合希釈しつつ目的箇
所へ送る非直線形状の混合配管とを具備する。
The reagent diluting device of the present invention comprises suction and discharge means for respectively sucking and discharging a reagent stock solution from a reagent tank and a diluted solvent from a solvent tank in a synchronized state, and this suction and discharge means. And a non-linear mixing pipe for receiving the undiluted reagent solution and the diluting solvent discharged from the same and mixing and diluting them to a predetermined location.

【0010】本発明の試薬の希釈方法は、試薬タンクか
らの試薬原液と、純水タンクからの希釈溶媒とを吸引吐
出手段により同期した状態で各々吸引吐出し、この吸引
吐出手段から吐出される試薬原液、希釈溶媒を非直線形
状の混合配管により受け入れ両者を所定濃度に混合希釈
しつつ目的箇所へ送るものである。
In the reagent diluting method of the present invention, the reagent stock solution from the reagent tank and the diluting solvent from the pure water tank are respectively sucked and discharged by the suction and discharge means in synchronization with each other, and discharged from this suction and discharge means. The reagent stock solution and the diluting solvent are received through a non-linear mixing pipe, and both are mixed and diluted to a predetermined concentration and sent to a target location.

【0011】[0011]

【作用】上述した構成の試薬の希釈装置によれば、吸引
吐出手段により、試薬タンクから試薬原液と、溶媒タン
クからの希釈溶媒とを同期した状態で各々吸引吐出し、
非直線形状の混合配管により吸引吐出手段から吐出され
る試薬原液、希釈溶媒を混合希釈しつつ目的箇所へ送る
ようにしたので、大容量のタンクや所要数のポンプが不
用となり、省スペース化が図れ狭いスペースへの設置が
可能となる。
According to the reagent diluting device having the above-described structure, the reagent discharging solution from the reagent tank and the diluting solvent from the solvent tank are respectively sucked and discharged by the suction and discharging means in synchronization with each other.
Since the reagent stock solution and the diluting solvent discharged from the suction and discharge means are mixed and diluted by the non-linear mixing pipe and sent to the target location, a large-capacity tank and a required number of pumps are unnecessary, saving space. It can be installed in a tight space.

【0012】上述した試薬の希釈方法によれば、上述し
た構成の試薬の希釈装置を用いて、試薬原液、希釈溶媒
を所定濃度に混合希釈し、安定した継続状態を維持しつ
つ目的箇所へ送ることができる。
According to the above-described reagent diluting method, the reagent diluting device having the above-mentioned configuration is used to mix and dilute the reagent stock solution and the diluting solvent to a predetermined concentration, and the mixture is sent to the target site while maintaining a stable continuous state. be able to.

【0013】[0013]

【実施例】以下に本発明の実施例を詳細に説明する。EXAMPLES Examples of the present invention will be described in detail below.

【0014】図1に示す試薬の希釈装置1は、NaCO
3 溶液、HCl溶液等の試薬原液を収納した比較的小容
量の試薬タンク2と、希釈溶媒としての純水(又は有機
溶媒)を収納した比較的小容量の溶媒タンク3と、試薬
タンク2からの試薬原液と、溶媒タンク3からの純水と
を図2に示すように完全に同期した状態で各々吸引吐出
する吸引吐出手段としてのダブルプランジャポンプ4
と、このダブルプランジャポンプ4から吐出される試薬
原液、純水を受け入れて両者を所定濃度に混合希釈しつ
つ目的箇所、例えばイオンクロマトグラフの分離カラム
へ送る非直線形状の混合配管5と、試薬タンク2の排出
口とダブルプランジャポンプ4の一方の吸引口とを連通
する試薬チューブ6と、純水タンク3の排出口とダブル
プランジャポンプ4の他方の吸引口とを連通する溶媒チ
ューブ7とを具備している。
The reagent diluting device 1 shown in FIG.
From the reagent tank 2, a relatively small capacity reagent tank 2 containing a stock solution of a solution such as 3 solutions and an HCl solution, a relatively small capacity solvent tank 3 containing pure water (or an organic solvent) as a diluting solvent. Double plunger pump 4 as suction and discharge means for respectively sucking and discharging the undiluted reagent solution and pure water from the solvent tank 3 in a completely synchronized state as shown in FIG.
And a non-linear mixing pipe 5 which receives the undiluted reagent solution and pure water discharged from the double plunger pump 4, mixes and dilutes them to a predetermined concentration, and sends them to a target site, for example, a separation column of an ion chromatograph, and a reagent. A reagent tube 6 that connects the discharge port of the tank 2 and one suction port of the double plunger pump 4, and a solvent tube 7 that connects the discharge port of the pure water tank 3 and the other suction port of the double plunger pump 4. It has.

【0015】混合配管5、試薬チューブ6、溶媒チュー
ブ7は、いずれもテフロンチューブを用いている。
Teflon tubes are used as the mixing pipe 5, the reagent tube 6 and the solvent tube 7.

【0016】前記ダブルプランジャポンプ4としては、
2個のプランジャをモータ、カムを用いた駆動機構によ
り同期して駆動する構成、2個のプランジャを流体圧に
より同期して駆動する構成又は2個のプランジャを電磁
力により同期して駆動する構成を採用することができ
る。
As the double plunger pump 4,
Configuration in which two plungers are synchronously driven by a drive mechanism using a motor and cam, configuration in which two plungers are synchronously driven by fluid pressure, or configuration in which two plungers are synchronously driven by electromagnetic force Can be adopted.

【0017】また、ダブルプランジャポンプ4は、2個
のプランジャによる試薬原液、純水の吐出量を別々に調
整可能となっている。
Further, the double plunger pump 4 can separately adjust the discharge amounts of the reagent stock solution and the pure water by the two plungers.

【0018】前記混合配管5は、ダブルプランジャポン
プ4の2個の吐出口に接続した接続チューブ8a、8b
と、非直線形状を有し接続チューブ8a、8bから送ら
れてくる試薬原液、純水を混合希釈して所定濃度の試薬
液として送り出す混合チューブ9とを具備している。
The mixing pipe 5 has connecting tubes 8a, 8b connected to the two discharge ports of the double plunger pump 4.
And a mixing tube 9 having a non-linear shape and mixing and diluting the reagent stock solution and pure water sent from the connection tubes 8a and 8b and sending out as a reagent solution having a predetermined concentration.

【0019】混合チューブ9の形状としては、図3に示
すコイル状、図4に示す蛇行状、図5に示す渦巻状のも
のを挙げることができる。
Examples of the shape of the mixing tube 9 include the coil shape shown in FIG. 3, the meandering shape shown in FIG. 4, and the spiral shape shown in FIG.

【0020】次に、前記希釈装置1の作用を説明する。Next, the operation of the diluting device 1 will be described.

【0021】試薬タンク2に試薬原液を収納し、溶媒タ
ンク3に純水を収納した状態で、ダブルプランジャポン
プ4を始動する。ダブルプランジャポンプ4は、完全に
同期した状態で試薬タンクから試薬チューブ6を介して
試薬原液を吸引するとともに溶媒タンク3からの純水を
吸引し、これらを各々完全に同期した状態で接続チュー
ブ8a、8bに送り出す。接続チューブ8a、8bを経
た試薬原液、純水は混合チューブ9に至り、この混合チ
ューブ9が形成する長い非直線状の流路を通過する間に
混合希釈されて所定濃度の試薬液となって図示しない分
離カラムに送られる。これにより、大容量のタンクや所
要数のポンプを用いること無く、継続的にかつ安定した
状態で所定濃度の試薬液を分離カラムに供給することが
可能となる。
With the reagent stock solution stored in the reagent tank 2 and the pure water stored in the solvent tank 3, the double plunger pump 4 is started. The double plunger pump 4 sucks the reagent stock solution from the reagent tank via the reagent tube 6 in a completely synchronized state and sucks pure water from the solvent tank 3 into the connection tube 8a in a completely synchronized state. , 8b. The reagent stock solution and pure water that have passed through the connection tubes 8a and 8b reach the mixing tube 9 and are mixed and diluted while passing through a long non-linear flow path formed by the mixing tube 9 to become a reagent solution having a predetermined concentration. It is sent to a separation column (not shown). As a result, it becomes possible to continuously and stably supply the reagent solution of a predetermined concentration to the separation column without using a large capacity tank or a required number of pumps.

【0022】本発明は、上述した実施例に限定されるも
のではなく、その要旨の範囲内で種々の変形が可能であ
る。
The present invention is not limited to the above-described embodiments, but various modifications can be made within the scope of the gist thereof.

【0023】[0023]

【発明の効果】以上詳述した本発明によれば、以下の効
果を奏する。
According to the present invention described in detail above, the following effects can be obtained.

【0024】本発明の試薬の希釈装置によれば、吸引吐
出手段により、試薬タンクから試薬原液と、溶媒タンク
からの希釈溶媒とを同期した状態で各々吸引吐出し、非
直線形状の混合配管により吸引吐出手段から吐出される
試薬原液、希釈溶媒を混合希釈しつつ目的箇所へ送るよ
うにしたので、大容量のタンクや所要数のポンプが不用
となり、省スペース化が図れ狭いスペースへの設置が可
能となる。
According to the reagent diluting device of the present invention, the suction and discharge means sucks and discharges the reagent stock solution from the reagent tank and the diluted solvent from the solvent tank, respectively, in synchronization with each other, and uses the non-linear mixing pipe. Since the reagent stock solution and the diluting solvent discharged from the suction / discharging means are mixed and diluted and sent to the target location, a large-capacity tank and the required number of pumps are not required, and space saving can be achieved and installation in a narrow space is possible. It will be possible.

【0025】本発明の試薬の希釈方法によれば、上述し
た構成の試薬の希釈装置を用いて、試薬原液、希釈溶媒
を所定濃度に混合希釈し、安定した継続状態を維持しつ
つ目的箇所へ送ることができる。
According to the reagent diluting method of the present invention, the reagent diluting device having the above-mentioned configuration is used to mix and dilute the reagent stock solution and the diluting solvent to a predetermined concentration to reach a desired location while maintaining a stable continuous state. Can be sent.

【図面の簡単な説明】[Brief description of drawings]

【図1】図1は本発明の実施例装置を示す配置図であ
る。
FIG. 1 is a layout view showing an apparatus according to an embodiment of the present invention.

【図2】図2は本実施例装置のダブルプランジャポンプ
による試薬及び純水の吸引及び吐出の状態を示す説明図
である。
FIG. 2 is an explanatory view showing a state of suction and discharge of a reagent and pure water by a double plunger pump of the apparatus of this embodiment.

【図3】図3は本実施例装置の混合配管の一例を示す平
面図である。
FIG. 3 is a plan view showing an example of a mixing pipe of the apparatus of this embodiment.

【図4】図4は本実施例装置の混合配管の一例を示す平
面図である。
FIG. 4 is a plan view showing an example of a mixing pipe of the apparatus of this embodiment.

【図5】図5は本実施例装置の混合配管のさらに別の例
を示す平面図である。
FIG. 5 is a plan view showing still another example of the mixing pipe of the device of this embodiment.

【図6】図6は従来の試薬の希釈装置を示す配置図であ
る。
FIG. 6 is a layout showing a conventional reagent diluter.

【図7】図7は従来の試薬の希釈装置の他例を示す配置
図である。
FIG. 7 is a layout view showing another example of a conventional reagent diluting device.

【符号の説明】[Explanation of symbols]

1 試薬の希釈装置 2 試薬タンク 3 溶媒タンク 4 ダブルプランジャポンプ 5 混合配管 1 Reagent dilutor 2 Reagent tank 3 Solvent tank 4 Double plunger pump 5 Mixing pipe

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.5 識別記号 庁内整理番号 FI 技術表示箇所 G01N 30/34 A 8310−2J ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 5 Identification code Office reference number FI technical display location G01N 30/34 A 8310-2J

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 試薬タンクから試薬原液と、溶媒タンク
からの希釈溶媒とを同期した状態で各々吸引吐出する吸
引吐出手段と、この吸引吐出手段から吐出される試薬原
液、希釈溶媒を受け入れて両者を所定濃度に混合希釈し
つつ目的箇所へ送る非直線形状の混合配管とを具備する
ことを特徴とする試薬の希釈装置。
1. A suction / discharge means for respectively sucking and discharging a reagent stock solution from a reagent tank and a diluent solvent from a solvent tank in a synchronized state, and a reagent stock solution and a diluent solvent discharged from the suction / discharge means, both of which are received. And a mixing pipe having a non-linear shape, which mixes and dilutes the mixture to a predetermined concentration and sends the diluted mixture to a target location.
【請求項2】 試薬タンクからの試薬原液と、溶媒タン
クからの希釈溶媒とを吸引吐出手段により同期した状態
で各々吸引吐出し、この吸引吐出手段から吐出される試
薬原液、希釈溶媒を非直線形状の混合配管により受け入
れ両者を所定濃度に混合希釈しつつ目的箇所へ送ること
を特徴とする試薬の希釈方法。
2. The reagent stock solution from the reagent tank and the diluent solvent from the solvent tank are sucked and discharged by the suction and discharge means in synchronization with each other, and the reagent stock solution and the diluted solvent discharged from the suction and discharge means are nonlinear. A method for diluting a reagent, characterized in that the reagent is received by a shaped mixing pipe and mixed and diluted to a predetermined concentration and sent to a target location.
JP4188201A 1992-07-15 1992-07-15 Reagent dilution apparatus and dilution method Expired - Lifetime JP2568791B2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP4188201A JP2568791B2 (en) 1992-07-15 1992-07-15 Reagent dilution apparatus and dilution method
TW82102484A TW273009B (en) 1992-07-15 1993-04-02

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP4188201A JP2568791B2 (en) 1992-07-15 1992-07-15 Reagent dilution apparatus and dilution method

Publications (2)

Publication Number Publication Date
JPH0631148A true JPH0631148A (en) 1994-02-08
JP2568791B2 JP2568791B2 (en) 1997-01-08

Family

ID=16219548

Family Applications (1)

Application Number Title Priority Date Filing Date
JP4188201A Expired - Lifetime JP2568791B2 (en) 1992-07-15 1992-07-15 Reagent dilution apparatus and dilution method

Country Status (2)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09274048A (en) * 1996-04-04 1997-10-21 Tosoh Corp Pretreatment apparatus
US5679575A (en) * 1994-12-21 1997-10-21 Toa Medical Electronics, Co., Ltd. Particle measuring apparatus and method
JP2008031115A (en) * 2006-07-31 2008-02-14 Sunstar Inc Method and apparatus for producing liquid composition
JP2008175810A (en) * 2006-12-19 2008-07-31 Ngk Insulators Ltd Cartridge for analysis, and absorbance measuring device
JP2011226914A (en) * 2010-04-20 2011-11-10 Tosoh Corp Liquid feeding device for liquid chromatography
WO2021140796A1 (en) * 2020-01-06 2021-07-15 株式会社日立ハイテク Electrolyte analysis apparatus

Families Citing this family (2)

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Publication number Priority date Publication date Assignee Title
TWM369876U (en) 2009-07-15 2009-12-01 Radar Electronics Co Ltd Universal type monitor holder structure for vehicle use
TWI549745B (en) 2014-05-16 2016-09-21 財團法人工業技術研究院 Apparatus and method for mixing solution and monitoring particles in solution

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JPS5139382A (en) * 1974-09-30 1976-04-01 Oki Electric Ind Co Ltd DOSAJUNJOSEIGYO HOSHIKI
JPS5337669A (en) * 1976-09-16 1978-04-06 Bayer Ag Production and use of 1*44dihydropyridine derivatives
JPS5622564A (en) * 1979-07-27 1981-03-03 Od Polt Institut Threeephase twoolayer pole change type winding for twoospeed motor
JPS60176235U (en) * 1984-05-04 1985-11-21 日本電気株式会社 adhesive mixing equipment

Patent Citations (4)

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Publication number Priority date Publication date Assignee Title
JPS5139382A (en) * 1974-09-30 1976-04-01 Oki Electric Ind Co Ltd DOSAJUNJOSEIGYO HOSHIKI
JPS5337669A (en) * 1976-09-16 1978-04-06 Bayer Ag Production and use of 1*44dihydropyridine derivatives
JPS5622564A (en) * 1979-07-27 1981-03-03 Od Polt Institut Threeephase twoolayer pole change type winding for twoospeed motor
JPS60176235U (en) * 1984-05-04 1985-11-21 日本電気株式会社 adhesive mixing equipment

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5679575A (en) * 1994-12-21 1997-10-21 Toa Medical Electronics, Co., Ltd. Particle measuring apparatus and method
JPH09274048A (en) * 1996-04-04 1997-10-21 Tosoh Corp Pretreatment apparatus
JP2008031115A (en) * 2006-07-31 2008-02-14 Sunstar Inc Method and apparatus for producing liquid composition
JP2008175810A (en) * 2006-12-19 2008-07-31 Ngk Insulators Ltd Cartridge for analysis, and absorbance measuring device
JP2011226914A (en) * 2010-04-20 2011-11-10 Tosoh Corp Liquid feeding device for liquid chromatography
WO2021140796A1 (en) * 2020-01-06 2021-07-15 株式会社日立ハイテク Electrolyte analysis apparatus

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