JPH0626686B2 - Content mixing container and content mixing and discharging device using the container - Google Patents

Content mixing container and content mixing and discharging device using the container

Info

Publication number
JPH0626686B2
JPH0626686B2 JP62069799A JP6979987A JPH0626686B2 JP H0626686 B2 JPH0626686 B2 JP H0626686B2 JP 62069799 A JP62069799 A JP 62069799A JP 6979987 A JP6979987 A JP 6979987A JP H0626686 B2 JPH0626686 B2 JP H0626686B2
Authority
JP
Japan
Prior art keywords
container
container body
thin film
content
external force
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP62069799A
Other languages
Japanese (ja)
Other versions
JPS63236556A (en
Inventor
聡 目加多
正次 松浦
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
OOSAKA EYAZOORU KOGYO KK
Original Assignee
OOSAKA EYAZOORU KOGYO KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by OOSAKA EYAZOORU KOGYO KK filed Critical OOSAKA EYAZOORU KOGYO KK
Priority to JP62069799A priority Critical patent/JPH0626686B2/en
Publication of JPS63236556A publication Critical patent/JPS63236556A/en
Publication of JPH0626686B2 publication Critical patent/JPH0626686B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D83/00Containers or packages with special means for dispensing contents
    • B65D83/14Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant
    • B65D83/60Contents and propellant separated
    • B65D83/66Contents and propellant separated first separated, but finally mixed, e.g. in a dispensing head
    • B65D83/666Contents and propellant separated first separated, but finally mixed, e.g. in a dispensing head product and propellant being totally mixed on, or prior to, first use, e.g. by braking an ampoule containing one of those components
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F33/00Other mixers; Mixing plants; Combinations of mixers
    • B01F33/50Movable or transportable mixing devices or plants
    • B01F33/501Movable mixing devices, i.e. readily shifted or displaced from one place to another, e.g. portable during use
    • B01F33/5011Movable mixing devices, i.e. readily shifted or displaced from one place to another, e.g. portable during use portable during use, e.g. hand-held
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F35/00Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
    • B01F35/71Feed mechanisms
    • B01F35/713Feed mechanisms comprising breaking packages or parts thereof, e.g. piercing or opening sealing elements between compartments or cartridges
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F35/00Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
    • B01F35/71Feed mechanisms
    • B01F35/713Feed mechanisms comprising breaking packages or parts thereof, e.g. piercing or opening sealing elements between compartments or cartridges
    • B01F35/7137Piercing, perforating or melting membranes or closures which seal the compartments
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F35/00Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
    • B01F35/71Feed mechanisms
    • B01F35/716Feed mechanisms characterised by the relative arrangement of the containers for feeding or mixing the components
    • B01F35/7162A container being placed inside the other before contacting the contents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D83/00Containers or packages with special means for dispensing contents
    • B65D83/14Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant
    • B65D83/44Valves specially adapted therefor; Regulating devices
    • B65D83/46Tilt valves
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B7/00Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
    • B05B7/24Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas with means, e.g. a container, for supplying liquid or other fluent material to a discharge device
    • B05B7/2402Apparatus to be carried on or by a person, e.g. by hand; Apparatus comprising containers fixed to the discharge device

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Nozzles (AREA)

Description

【発明の詳細な説明】 [産業上の利用分野] 本発明は、内容物混合容器および該容器を用いた内容物
混合吐出装置に関する。さらに詳しくは、本発明は使用
する前においては第一内容物および第二内容物を別個に
収容しておき、使用時に両者を効率的に混合攪拌するこ
とができる容器および該容器中に混合後に内圧を発生す
る第一内容物と第二内容物とを充填した内容物混合吐出
装置に関する。
The present invention relates to a contents mixing container and a contents mixing and discharging device using the container. More specifically, in the present invention, the first content and the second content are separately stored before use, and a container that can efficiently mix and stir both at the time of use and after mixing in the container. The present invention relates to a content mixing and discharging device filled with a first content and a second content that generate internal pressure.

[従来の技術] 従来より2液を混合することにより形成される反応生成
物を利用する商品としては、発泡ポリウレタン、エポキ
シ樹脂系接着剤、塗料、ホットシェービングフォームな
どの化粧品、ヘアダイ、パーマ剤などの医薬部外品など
がある。
[Prior Art] Conventionally, products that use a reaction product formed by mixing two liquids include polyurethane foam, epoxy resin adhesives, paints, cosmetics such as hot shaving foam, hair dies, and permanent agents. Quasi drugs.

これらの商品は2液を別個に保存しておき、使用時に両
者を所定の比率で混合して使用するものである。これら
2液の混合方法としては、特別な方法はなく、たとえば
第一内容物をビーカなどのような容器にとり、これに第
二内容物を加えてガラス棒などで混合するような方法が
とられている。
These products store two liquids separately and mix them at a predetermined ratio before use. There is no special method for mixing these two liquids. For example, the first content is placed in a container such as a beaker and the second content is added to the container and mixed with a glass rod or the like. ing.

また混合することにより生ずる反応生成物を簡単に他の
物の表面に適用することができる混合吐出装置として
は、たとえば本出願人の出願にかかわる特開昭60-28842
号公報に記載されているものがある。
Further, as a mixing and discharging apparatus that can easily apply the reaction product generated by mixing to the surface of another object, for example, Japanese Patent Application Laid-Open No. 60-28842
Some are described in Japanese Patent Publication.

このものは耐圧容器内に噴射剤と共に第一内容物を加圧
状態で封入しておき、さらに耐圧容器中に、第二内容物
を充填したガラス製などのアンプルを入れると共に、ア
ンプルを破砕するためのレバーや重錘を容器本体または
その内部に取りつけたものである。
In this product, the first content is sealed under pressure in a pressure vessel with a propellant, and an ampoule made of glass or the like filled with the second content is placed in the pressure vessel and the ampoule is crushed. A lever and a weight are attached to the container body or the inside thereof.

また同種のものとして特開昭60-158073号公報に示され
ているものがある。このものは前記アンプルに代えて容
器本体にとりつけた内部容器を用いると共に、容器本体
の外側から内部容器を穿孔するための針などを備えたも
のである。
Further, as the same kind, there is one disclosed in JP-A-60-158073. This uses an internal container attached to the container body instead of the ampoule, and is provided with a needle or the like for punching the internal container from the outside of the container body.

[発明が解決しようとする問題点] ところで前記ビーカで混合する方法は、第一内容物と第
二内容物とを混合する際に、あらかじめそれぞれの内容
物を逐一計量しておく必要があり、しかもそれぞれの内
容物を均一な組成の反応生成物とするためにはガラス棒
による攪拌などの操作が必要である。
[Problems to be Solved by the Invention] By the way, in the method of mixing with the beaker, it is necessary to measure each content in advance when mixing the first content and the second content, Moreover, operations such as stirring with a glass rod are required in order to make the respective contents into reaction products having a uniform composition.

さらに上記内容物中に人体にとって有害な溶剤が含有さ
れるばあい、かかる内容物を混合する際に有害な溶剤を
吸引してしまうおそれがある。またたとえば発泡ポリウ
レタンのように粘性が高く手指に付着しやすいもの、型
などに流し込まなければならないものなどは、その取り
扱いがきわめて困難である。
Further, when the contents contain a solvent harmful to the human body, there is a possibility that the harmful solvent may be sucked when the contents are mixed. Further, for example, those having a high viscosity such as foamed polyurethane, which easily adhere to fingers, and those which must be poured into a mold are extremely difficult to handle.

また前記二液式エアゾール製品においては、外側容器の
内部には噴射剤を含む内容物がたとえば5〜7kg/cm2
の加圧状態で充填されているため、アンプルや内部容器
自体の耐圧性、ガス不透過性などを高くする必要があ
る。したがって従来の二液式エアゾール製品では比較的
強度の高い内部容器などを容器の外側から苦労して破砕
または穿孔しなければならない。
Further, in the two-pack type aerosol product, the content containing the propellant is, for example, 5 to 7 kg / cm 2 inside the outer container.
Since it is filled in a pressurized state, it is necessary to increase the pressure resistance and gas impermeability of the ampoule and the inner container itself. Therefore, in the conventional two-component aerosol product, an inner container or the like having a relatively high strength must be crushed or perforated from the outside of the container with difficulty.

さらに内部容器の内容量なども制限されるため二液式エ
アゾール製品としての用途も限られている。
Further, since the internal volume of the inner container is also limited, its use as a two-component aerosol product is also limited.

[問題点を解決するための手段] 本発明の内容物混合容器は、容器本体と、該容器本体の
内部を2以上の隔室に区画するとともに開口部を有す
る、実質的に剛体の隔壁と、該隔壁に、前記開口部を閉
塞しかつ外力で破口することができるように設けられた
易破壊性を有する薄膜と、容器本体に設けられた、容器
本体の外部から前記薄膜に外力を加える手段とからな
り、 該外力を加える手段が、容器本体の外部に位置する押圧
操作部と容器本体の内部に位置する薄膜押圧部とから構
成されてなる。
[Means for Solving the Problems] A contents mixing container of the present invention comprises a container body and a substantially rigid partition wall that divides the interior of the container body into two or more compartments and has an opening. An easily destructible thin film provided in the partition wall so as to close the opening and be rupturable by an external force; and an external force applied to the thin film from the outside of the container main body, which is provided in the container main body. And a means for applying the external force. The means for applying the external force is composed of a pressing operation section located outside the container body and a thin film pressing section located inside the container body.

さらに前記内容物混合容器を用いた本発明の内容物混合
吐出装置は、前記容器本体が取り出し手段を備えた耐圧
性のものであり、前記隔室内に、たがいに混合されるべ
き第一内容物と第二内容物とがそれぞれ加圧されておら
ない状態で充填されており、第一内容物および第二内容
物が混合されるときにたがいに反応して圧力を発生する
二種類の薬剤をそれぞれ別個に含有している構成がとら
れている。
Furthermore, the contents mixing and discharging apparatus of the present invention using the contents mixing container is a pressure resistant device in which the container body is provided with a take-out means, and the first contents to be mixed with each other in the compartment. And the second content are respectively filled in a non-pressurized state, and when the first content and the second content are mixed, two types of drugs that react with each other to generate pressure are added. Each of them is contained separately.

なお、特許請求の範囲で、外力を加える手段が容器本体
に設けられている旨の記載があるが、このばあいの容器
本体には、容器本体に設けられたバルブなども包含して
いる。すなわち、前記手段がバルブに設けられたものも
含んでいる。
In the claims, it is stated that the means for applying an external force is provided in the container body, but in this case, the container body also includes a valve provided in the container body. That is, the means includes the means provided in the valve.

[作用] 内容物混合容器は単独の容器内に二種以上の内容物を分
離状態で充填しておくことができる。
[Operation] As a content mixing container, two or more kinds of contents can be separately filled in a single container.

使用時には外力を加える手段を用いて薄膜を破口する
と、隔壁の開口部の内縁に沿ってほぼ全体に開口され
る。すなわち、大きな開口部が隔壁に形成される。
When the thin film is ruptured by using a means for applying an external force during use, it is opened almost entirely along the inner edge of the opening of the partition wall. That is, a large opening is formed in the partition.

したがって容器本体を手に持って浸盪することにより、
内容物同士が素早く均一に混合攪拌されうる。それらの
混合攪拌にはビーカやガラス棒などの他の用具を用いる
ことなくきわめて簡単に行ないうる。
Therefore, by holding the container body in your hand and shaking it,
The contents can be quickly and uniformly mixed and stirred. Such mixing and stirring can be performed very easily without using other tools such as beakers and glass rods.

内容物混合吐出装置内にはそれぞれ内容物が加圧されて
おらない状態、すなわち大気圧で充填されている。した
がって充填作業などの製造作業が簡単である。さらに内
容物同士を隔離する手段に高い耐圧性やガス不透過性、
強度を与える必要がない。それゆえ比較的薄く、面積の
大きい隔壁、たとえば容器内部を上下に二分する隔壁を
採用することができる。さらに隔壁に大きい開口部を形
成するための薄膜を形成しても、隔室同士の内圧差で破
断されることがない。
The contents mixing and discharging device is filled with the contents in a non-pressurized state, that is, at atmospheric pressure. Therefore, manufacturing work such as filling work is easy. In addition, high pressure resistance and gas impermeability as a means to isolate contents from each other,
No need to give strength. Therefore, it is possible to employ a partition that is relatively thin and has a large area, for example, a partition that divides the interior of the container into upper and lower parts. Further, even if a thin film for forming a large opening is formed in the partition wall, it is not broken by the internal pressure difference between the compartments.

このものを使用するには、前述の混合容器のばあいと同
じ操作を加えることにより内容物同士を混合攪拌して反
応生成物を生じさせると共に、それによって生じた内圧
により反応生成物を吐出させる。吐出させる形態は噴
霧、発泡状体、あるいは液体や気体のままなど、種々の
態様を採用しうる。
To use this product, the same operation as in the case of the above-mentioned mixing container is performed to mix and stir the contents to generate a reaction product, and the reaction product is discharged by the internal pressure generated thereby. . Various forms such as spray, foam, or liquid or gas can be adopted as the form for discharging.

[実施例] つぎに本発明の実施例を説明する。[Examples] Next, examples of the present invention will be described.

第1図は本発明の一実施例にかかわる容器の断面図、第
2図は同容器において薄膜を破口した状態の断面図、第
3図は同容器の噴射操作中の状態を示す断面図、第4〜
5図は本発明にかかわる容器において採用しうる底部構
造を示す断面図、第6図は本発明の他の実施例にかかわ
る容器の要部断面図である。
FIG. 1 is a cross-sectional view of a container according to an embodiment of the present invention, FIG. 2 is a cross-sectional view of the same container with a thin film ruptured, and FIG. 3 is a cross-sectional view of the same container during a jetting operation. , 4th ~
FIG. 5 is a cross-sectional view showing a bottom structure that can be adopted in the container according to the present invention, and FIG. 6 is a main-part cross-sectional view of the container according to another embodiment of the present invention.

第1図に示された内容物混合容器は、容器本体(1)、隔
壁(2)を備えている。
The content mixing container shown in FIG. 1 includes a container body (1) and a partition (2).

容器本体(1)は、筒状の外周壁(1a)の上下の端縁に蓋部
材(1b)と底部材(1c)とを一体にかしめることにより構成
されている。なお底部材(1c)の中心部には密封栓(1d)が
挿入されている。
The container body (1) is configured by integrally caulking a lid member (1b) and a bottom member (1c) on the upper and lower edges of a cylindrical outer peripheral wall (1a). A sealing plug (1d) is inserted in the center of the bottom member (1c).

隔壁(2)は容器本体(1)内を上下に区隔する部材であり、
有底筒状の部材で構成されている。そしてこの隔壁(2)
の底部(2a)は大きい開口部(2b)が形成されている。隔壁
(2)の開口端(2c)は容器本体(1)の外周壁(1a)に蓋部材(1
b)とともにかしめによって固定されている。
The partition wall (2) is a member that vertically separates the interior of the container body (1),
It is composed of a bottomed tubular member. And this partition (2)
A large opening (2b) is formed in the bottom (2a) of the. Partition
The open end (2c) of (2) is attached to the outer wall (1a) of the container body (1) by the lid member (1
It is fixed by caulking together with b).

前記容器本体(1)や隔壁(2)は金属製のもののほか、混合
後も内圧がかからないばあいは合成樹脂シート、紙また
はそれらのラミネート、またはそれらと金属箔とのラミ
ネートなど、種々のものを採用しうる。
The container body (1) and the partition wall (2) are made of metal, and if the internal pressure is not applied even after mixing, a synthetic resin sheet, paper or a laminate thereof, or a laminate of them and a metal foil is used. Can be adopted.

隔壁(2)の底部(2a)には開口部(2b)を塞ぐようにして、
薄膜(3)が貼着されている。この薄膜(3)は後述するロッ
ド(5)で破口しやすくなるため、アルミ箔やパラフィン
紙、プラスチックフィルムなどが用いられる。薄膜(3)
の上面には、板(11)が接着などの手段により取りつけら
れる。この板(11)は薄膜(3)が開口部(2b)に沿って全周
が完全に破れるようにするため設けられている。なおこ
の板(11)はさらに破口しやすくするため、その周縁部に
鋸歯状の刃や星型などの鋭角部を形成しておいてもよ
い。
At the bottom (2a) of the partition wall (2) so as to close the opening (2b),
A thin film (3) is attached. Since the thin film (3) is easily broken by the rod (5) described later, aluminum foil, paraffin paper, plastic film or the like is used. Thin film (3)
A plate (11) is attached to the upper surface of the plate by means such as adhesion. This plate (11) is provided so that the thin film (3) is completely broken along the opening (2b) along the entire circumference. In addition, in order to make the plate (11) easier to break, a serrated blade or an acute-angled portion such as a star shape may be formed on the peripheral edge thereof.

容器本体(1)の蓋部材(1b)にはまたマウンティングキャ
ップ(12)がかしめつけられており、このマウンティング
キャップ(12)にはバルブ(4)が取りつけられている。
The lid member (1b) of the container body (1) is also caulked with a mounting cap (12), and the valve (4) is attached to the mounting cap (12).

このバルブ(4)は筒状の本体(13)とその周囲に配置され
る取付部(14)とから構成されている。本体(13)は、ポリ
エチレン、ポリプロピレン、ポリアセタール、ポリアミ
ドなどの合成樹脂で形成された部材であり、上下に貫通
孔(15)が形成されている。本体(13)の上端部には後述す
るスパウト(20)を取りつけるための雄ネジ部(17)と取付
部(14)を固定するための嵌合部(18)が形成されており、
下端部には内容物を通すための通孔(19)と弁座部(21)が
形成されている。弁座部(21)の内周面には環状に内方に
突出した環状突起(22)が形成されている。
The valve (4) is composed of a tubular body (13) and a mounting portion (14) arranged around the body. The main body (13) is a member made of synthetic resin such as polyethylene, polypropylene, polyacetal, polyamide, etc., and has through holes (15) formed at the top and bottom. A male screw portion (17) for attaching a spout (20) described later and a fitting portion (18) for fixing the mounting portion (14) are formed at the upper end of the main body (13),
A through hole (19) for passing contents and a valve seat (21) are formed at the lower end. An annular protrusion (22) is formed on the inner peripheral surface of the valve seat portion (21) so as to protrude inward in an annular shape.

取付部(14)はゴムなどの弾性体で作製された部材であ
り、中心部は本体(13)を通すように貫通されている。該
取付部(14)の上端部には、本体(13)の嵌合部(18)に密着
して嵌合する嵌合部(23)が形成され、中央部外周にはマ
ウンティングキャップ(12)の内周縁が嵌められる嵌合部
(24)が形成されている。バルブ(4)はこの嵌合部(24)と
マウンティングキャップ(12)により、容器本体(1)に取
りつけられている。また取付部(14)の下端部は舌片状に
形成された弁体(25)となっており、弁体(25)の下面と弁
座部(21)の上面とが密着状態に接するようになってい
る。そのため常態では内容物は貫通孔(15)内に入ること
がない。
The attachment portion (14) is a member made of an elastic body such as rubber, and the center portion is penetrated so as to pass through the main body (13). A fitting portion (23) is formed at an upper end portion of the mounting portion (14) so as to be closely fitted to the fitting portion (18) of the main body (13), and a mounting cap (12) is provided on an outer periphery of a central portion. Fitting part where the inner peripheral edge of
(24) is formed. The valve (4) is attached to the container body (1) by the fitting portion (24) and the mounting cap (12). Further, the lower end of the mounting portion (14) is a tongue-shaped valve body (25) so that the lower surface of the valve body (25) and the upper surface of the valve seat portion (21) are in close contact with each other. It has become. Therefore, normally, the contents do not enter the through hole (15).

バルブ(4)の貫通孔(15)内には薄膜押圧部としてのロッ
ド(5)が挿入されている。ロッド(5)は前記薄膜(3)を突
き破るための手段であり、比較的長尺の棒状部材であ
る。ロッド(5)の直径はバルブ(4)の環状突起(22)の内周
に密着する寸法であり、ロッド(5)が貫通孔(15)内にあ
るときは、貫通孔(15)内に内容物が入らないようになっ
ている。ロッド(5)の下端には板(26)が取りつけられて
おり、薄膜(3)上の板(11)全体に均等に力が作用するよ
うになっている。このロッド(5)は、使用前の状態では
板(26)が薄膜(3)のやや上方に位置し、ロッド(5)の上端
が貫通孔(15)のなかほどに位置するように挿入しておか
れる。そして外力を加えない状態では、環状突起(22)と
の摩擦力によりその位置が保持される。
A rod (5) as a thin film pressing portion is inserted into the through hole (15) of the valve (4). The rod (5) is a means for breaking through the thin film (3) and is a relatively long rod-shaped member. The diameter of the rod (5) is such that it fits closely to the inner circumference of the annular protrusion (22) of the valve (4), and when the rod (5) is inside the through hole (15), it is inside the through hole (15). The contents do not enter. A plate (26) is attached to the lower end of the rod (5) so that the force is evenly applied to the entire plate (11) on the thin film (3). Insert the rod (5) so that the plate (26) is located slightly above the thin film (3) before use and the upper end of the rod (5) is located in the middle of the through hole (15). Be saved. Then, in the state where no external force is applied, the position is held by the frictional force with the annular protrusion (22).

バルブ(4)の貫通孔(15)の上方には、ロッド(5)を下方へ
押し込むための押圧操作部としての操作ロッド(6)が挿
入される。操作ロッド(6)は上端につまみ(27)が設けら
れ、下端にピストン(28)が形成されている。ピストン(2
8)はゴムなどの弾性体で作られ、貫通孔(15)の内径とほ
ぼ等しい外径を有している。なおこの操作ロッド(6)
(すなわち押圧操作部)と前記ロッド(5)(すなわち薄
膜押圧部)とで、「外力を加える手段」が構成されてい
る。
Above the through hole (15) of the valve (4), an operation rod (6) as a pushing operation portion for pushing the rod (5) downward is inserted. The operation rod (6) has a knob (27) at the upper end and a piston (28) at the lower end. Piston (2
8) is made of an elastic material such as rubber and has an outer diameter substantially equal to the inner diameter of the through hole (15). This operating rod (6)
(In other words, the pressing operation section) and the rod (5) (that is, the thin film pressing section) constitute "means for applying an external force".

本実施例の容器では、第2図に示されるように、操作ロ
ッド(6)を手で押し込むとロッド(5)が押し下げられ、ロ
ッド(5)の押し下げ力で薄膜(3)が破られ、隔壁(2)に大
きな開口が形成される。
In the container of this embodiment, as shown in FIG. 2, when the operating rod (6) is pushed by hand, the rod (5) is pushed down, and the thin film (3) is broken by the pushing force of the rod (5). A large opening is formed in the partition wall (2).

なお本発明の容器の底部構造は、第1図に示されたもの
に限られず、第4図に示されるような板材だけの底部材
(1e)でもよく、第5図に示されるような盲状のマウンテ
ィングキャップ(1f)を用いてもよい。
The bottom structure of the container of the present invention is not limited to that shown in FIG. 1, and is a bottom member made of only plate material as shown in FIG.
(1e) may be used, or a blind mounting cap (1f) as shown in FIG. 5 may be used.

つぎに前記混合容器を用いた内容物混合吐出装置を説明
する 第1図において内容物混合吐出装置(以下、装置とい
う)に用いられる容器本体(1)は通常のエアゾール容器
として用いられる耐圧性の金属缶などを用いることがで
きる。
Next, a content mixing and discharging device using the mixing container will be described. In FIG. 1, a container body (1) used in the content mixing and discharging device (hereinafter, referred to as a device) has a pressure resistant property which is used as an ordinary aerosol container. A metal can or the like can be used.

隔壁(2)によって区画された上方の第一隔室(A)には、混
合しようとしている二種の原液のうち一方(以下、第一
原液という)と、混合されることにより圧力を発生する
2種の液剤のうちの一方(以下、第一液剤という)とを
含有する第一内容物が充填されている。
In the upper first compartment (A) divided by the partition wall (2), one of the two types of undiluted solutions to be mixed (hereinafter referred to as the first undiluted solution) generates pressure when mixed. The first content containing one of the two liquid agents (hereinafter, referred to as the first liquid agent) is filled.

前記容器本体(1)内の第二隔室(B)には混合しようとして
いる他方の原液(第二原液)と混合によって圧力を発生
する他方の液剤(第二液剤)とを含有する第二内容物が
充填されている。
The second compartment (B) in the container body (1) contains a second undiluted solution (second undiluted solution) to be mixed and another liquid agent (second liquid agent) that generates pressure by mixing. The contents are filled.

なお混合しようとしている原液自体が前記液剤として機
能するばあい、すなわち第一原液と第一液剤または第二
原液と第二液剤のいずれかの組み合わせあるいは両方が
それぞれ同一の液体からなるものであってもよい。
If the undiluted solution itself to be mixed functions as the liquid agent, that is, one of the first undiluted solution and the first undiluted solution or the second undiluted solution and the second undiluted solution or both of them are composed of the same liquid. Good.

前記二種の原液と二種の液剤の組み合わせは任意である
が、一方の原液と一方の液剤との組み合わせがたがいに
反応して不都合を生ずるものであるばあいには、それら
を第一内容物と第二内容物とに分離して含有させるのが
好ましい。
The combination of the two kinds of stock solutions and the two kinds of solutions is optional, but if the combination of one stock solution and one solution causes a reaction and causes inconvenience, the first content It is preferable to separately contain the product and the second content.

第一原液および第二原液としては混合されることにより
発泡ポリウレタン、エポキシ樹脂系接着剤、塗料、ホッ
トシェービングフォームなどの化粧品、ヘアダイ、パー
マ剤などの医薬部外品などの目的生成物を生成するもの
など、従来公知の二液混合タイプの原液があげられる。
When mixed as the first and second undiluted solutions, the desired product such as foamed polyurethane, epoxy resin adhesives, paints, cosmetics such as hot shaving foam, and quasi-drugs such as hair dyes and perms are produced. For example, a conventionally known two-liquid mixed type stock solution can be used.

前記第一液剤および第二液剤の組合せとしては、第一内
容物と第二内容物とが混じり合うときに反応して圧力を
生じるものでなければならない。
The combination of the first liquid and the second liquid should be one that reacts when the first content and the second content are mixed to generate pressure.

圧力を発生させるしくみとしては、反応によりガスを発
生させ、それにより内圧を高めるもの、および反応によ
り熱を発生し、その熱で低沸点化合物を気化させて圧力
をうるものなどが考えられる。
Mechanisms for generating pressure include those that generate gas by the reaction and thereby increase the internal pressure, and those that generate heat by the reaction and vaporize the low boiling point compound to obtain pressure.

前者の例としては、たとえば重炭酸塩と酸とを組み合わ
せておき、反応により炭酸ガスを発生させるものなどが
あげられる。
Examples of the former include a combination of a bicarbonate and an acid, which produces carbon dioxide gas by a reaction.

また後者の例としては、過酸化水素水とチオ硫酸塩とを
反応させて反応熱を生じさせ、後述するような低沸点化
合物を気化させる組み合わせがあげられる。
Further, as an example of the latter, there is a combination of reacting a hydrogen peroxide solution with a thiosulfate to generate heat of reaction and vaporizing a low boiling point compound as described later.

発熱を伴なう反応には前記以外に過酸化水素水とチオグ
リコール類、水と活性酸化鉄などの微粉末状の金属、水
と酸または塩基、イソシアネートとポリオール、エポキ
シ化合物と酸無水物などがあげられるが、本発明の装置
においては、これらのみに限定されず、他のものをも好
適に使用しうる。
In addition to the above, hydrogen peroxide water and thioglycols, water and fine powder metal such as active iron oxide, water and acid or base, isocyanate and polyol, epoxy compound and acid anhydride, etc. However, the device of the present invention is not limited to these, and other devices can be suitably used.

また前記発熱反応により気化されるべき低沸点化合物と
しては、内容物の種類によって異なるが、通常溶剤とし
て使用されている化合物、すなわち、ジクロロテトラフ
ルオロエタン、トリクロロモノフルオロメタン、塩化メ
チレン、ブタン、ペンタン、ヘキサン、ヘプタン、メタ
ノール、エタノールなどの低沸点溶剤などを使用するこ
とができる。さらに低沸点化合物は第一内容物と第二内
容物とが反応することによってはじめて生成されるもの
であってよい。
The low boiling point compound to be vaporized by the exothermic reaction varies depending on the kind of the content, but is a compound that is usually used as a solvent, that is, dichlorotetrafluoroethane, trichloromonofluoromethane, methylene chloride, butane, pentane. A low boiling point solvent such as hexane, heptane, methanol or ethanol can be used. Further, the low boiling point compound may be produced only by the reaction between the first content and the second content.

さて、以上のごとく内容物が充填された装置を使用する
ばあい、第2図に示されるように操作される。
Now, when using the device filled with the contents as described above, it is operated as shown in FIG.

操作ロッド(6)を貫通孔(15)内に押し込むと、ロッド(5)
が押し下げられて、薄膜(3)上の板(11)も押し下げられ
る。その結果、薄膜(3)が隔壁(2)の開口部(2b)の内縁に
沿って破られ、大きく破口される。なお、操作ロッド
(6)は押し込まれた時点で、その下端のピストン(28)が
バルブ本体(13)の環状突起(22)に密着して、外界と容器
本体(1)内部とを遮断する。
Push the operating rod (6) into the through hole (15) and the rod (5)
Is pushed down, and the plate (11) on the thin film (3) is also pushed down. As a result, the thin film (3) is ruptured along the inner edge of the opening (2b) of the partition wall (2) and largely ruptured. The operating rod
When the piston (6) is pushed in, the piston (28) at the lower end thereof comes into close contact with the annular protrusion (22) of the valve body (13) to shut off the outside world from the inside of the container body (1).

以上のごとく薄膜(3)が破口されると、容器本体(1)内で
前記第一液剤と第二液剤とが反応して、容器本体(1)内
の圧力が高くなり、いつでも内容物を噴射しうる状態と
なる。
When the thin film (3) is breached as described above, the first liquid agent and the second liquid agent react in the container body (1), the pressure in the container body (1) increases, and the contents are always contained. Is ready to be ejected.

内容物を噴射するには、第3図に示されるようにスパウ
ト(7)を取りつけて行なう。スパウト(7)の下端部には雌
ネジ部(29)が形成されており、それをバルブ本体(13)の
雄ネジ部(17)に螺合すると図示のごとくバルブ(3)に取
りつけうる。スパウト(7)を手指で押して傾けると、弁
体(25)と弁座部(21)との間に隙間ができるので、内容物
が通孔(19)から貫通孔(15)内に入り、外部に吐出され
る。
To spray the contents, attach the spout (7) as shown in FIG. A female screw portion (29) is formed at the lower end portion of the spout (7), and when the female screw portion (29) is screwed into the male screw portion (17) of the valve body (13), it can be attached to the valve (3) as shown. When the spout (7) is pushed by hand and tilted, a gap is created between the valve body (25) and the valve seat portion (21), so that the contents enter from the through hole (19) into the through hole (15), It is discharged to the outside.

つぎに第6図を参照しながら本発明の他の実施例を説明
する。
Next, another embodiment of the present invention will be described with reference to FIG.

容器本体(1)と隔壁(2)の上端部にはバルブ(30)がマウン
ティングキャップ(31)によってかしめられている。隔壁
(2)は有底筒状の容器で、底部(2a)には開口部(2b)が形
成されている。そして開口部(2b)を塞ぐようにして薄膜
(3)が貼着されている。
A valve (30) is caulked by a mounting cap (31) at the upper ends of the container body (1) and the partition wall (2). Partition
(2) is a bottomed cylindrical container having an opening (2b) formed in the bottom (2a). Then, the thin film is formed so as to close the opening (2b).
(3) is attached.

バルブ(30)はバルブハウジング(32)を備え、その中にス
テム(33)がスプリング(34)を介して入れられている。バ
ルブハウジング(32)の上端とマウンティングキャップ(3
1)との間にはステムラバー(35)が固定されている。前記
ステム(33)には軸方向に貫通孔(36)が形成されており、
その中にロッド(37)が通されている。このロッド(37)は
長尺の棒状部材であり、下端部は薄膜(3)を破りやすく
かつできるだけ大きな破口がえられるよう、円錐形や角
錐形、その他任意の形状に形成されている。またロッド
(37)の上端部分には軸方向に縦孔(38)が形成され、その
下端部では半径方向に通孔(39)が形成されている。一
方、ステム(33)の上端部には半径方向に通孔(41)が形成
され、ロッド(37)をステム(33)中に押し込んだ状態で、
通孔(41)と前記通孔(39)とが連通するようになってい
る。なおロッド(37)には鍔(42)が形成されており、通孔
(39)、(41)が連通する位置が規制されるとともに、ロッ
ド(37)の押し込み操作でステム(33)も押し込まれるよう
なっている。
The valve (30) comprises a valve housing (32) in which a stem (33) is inserted via a spring (34). Top of valve housing (32) and mounting cap (3
A stem rubber (35) is fixed between 1). A through hole (36) is formed in the stem (33) in the axial direction,
A rod (37) is passed through it. The rod (37) is a long rod-shaped member, and the lower end portion thereof is formed in a conical shape, a pyramid shape, or any other shape so that the thin film (3) can be easily broken and the largest possible break can be obtained. Also rod
A vertical hole (38) is formed in the upper end portion of (37) in the axial direction, and a through hole (39) is formed in the lower end portion in the radial direction. On the other hand, a through hole (41) is formed in the upper end of the stem (33) in the radial direction, and the rod (37) is pushed into the stem (33).
The through hole (41) and the through hole (39) communicate with each other. A flange (42) is formed on the rod (37), and the through hole
The position where the (39) and (41) communicate with each other is regulated, and the stem (33) is also pushed in by pushing the rod (37).

ステム(33)の下端には、内方へ向って少し突出した係止
部(42)が形成されている。ロッド(37)は押し込まれる以
前は、その先端部(37a)が前記係止部(42)で係止される
ようになっている。
At the lower end of the stem (33), a locking portion (42) slightly protruding inward is formed. Before the rod (37) is pushed in, the tip portion (37a) thereof is locked by the locking portion (42).

使用に際しては、ロッド(37)を手で強く押し込み、その
先端部(37a)で薄膜(3)を突き破り、隔壁(2)に開口を形
成する。このようにして、薄膜(3)が破口されると、容
器本体(1)内で前記第一液剤と第二液剤とが反応して、
容器本体(1)内の圧力が高くなり、いつでも内容物を噴
射しうる状態となる。
In use, the rod (37) is strongly pushed by hand, the thin film (3) is pierced by the tip portion (37a) thereof, and an opening is formed in the partition wall (2). In this way, when the thin film (3) is breached, the first liquid agent and the second liquid agent react in the container body (1),
The pressure in the container body (1) becomes high and the contents can be sprayed at any time.

そして内容物を噴射するには、ロッド(37)を少し押し込
むと同時にステム(33)も少し押し込まれ、通孔(41)がス
テムラバー(35)から外れるので、通孔(41)、(39)を通し
て、内容物がロッド(37)の縦孔(38)に流れ込み、外部に
噴射される。
Then, in order to spray the contents, the rod (37) is pushed a little and the stem (33) is also pushed a little at the same time, and the through hole (41) is disengaged from the stem rubber (35) .Thus, the through holes (41), (39 ), The contents flow into the vertical hole (38) of the rod (37) and are ejected to the outside.

以上に本発明の二実施例を説明したが、本発明はその要
旨を逸脱しない範囲で種々の変更例を採用することがで
きる。
Although the two embodiments of the present invention have been described above, the present invention can employ various modifications without departing from the scope of the invention.

[発明の効果] 本発明の内容物混合容器は、剛体の隔壁および隔壁の開
口部を閉塞する破壊しやすい薄膜によって容器本体が区
画されているので、二種以上の内容物を別々に充填して
おくことができると共に、使用時には簡単に隔壁に大き
い開口部を形成しうるので1つの容器内で簡単に、素早
く、かつ均一に混合攪拌することができる。また混合の
ときに溶剤の蒸気を使用者が扱うことがなく、液をこぼ
すこともない。
[Effects of the Invention] In the content mixing container of the present invention, the container body is partitioned by the rigid partition wall and the easily breakable thin film that closes the opening of the partition wall, so that two or more types of content are separately filled. In addition, since a large opening can be easily formed in the partition wall during use, it is possible to easily, quickly and uniformly mix and stir in one container. In addition, the user does not handle the vapor of the solvent during mixing, and the liquid is not spilled.

さらに本発明の内容物混合吐出装置は、加圧されておら
ない状態で二種以上の内容物を分離充填しておくことが
できる。さらに使用時には二種の内容物を簡単に混合攪
拌することができ、発生した内圧で反応生成物を吐出す
ることができる。そのため反応生成物が手についたりす
ることがなく、また型に流しこむばあいでも特別な容器
や機器を用いることなく直接容器本体から流出させるこ
とができる。
Furthermore, the content mixing and discharging apparatus of the present invention can separately fill two or more kinds of content without being pressurized. Further, when used, the two kinds of contents can be easily mixed and stirred, and the reaction product can be discharged by the generated internal pressure. Therefore, the reaction product does not stick to the hands, and when it is poured into the mold, it can be directly discharged from the container body without using a special container or equipment.

さらにはえられた反応生成物の粘度が低いばあいには、
適当な構造を有する噴射口を使用することにより霧状に
噴出させることもできる。
Furthermore, when the viscosity of the obtained reaction product is low,
It is also possible to eject in the form of mist by using an injection port having an appropriate structure.

【図面の簡単な説明】[Brief description of drawings]

第1図は本発明の一実施例にかかわる容器の断面図、第
2図は同容器において薄膜を破口した状態の断面図、第
3図は同容器の噴射操作中の状態を示す断面図、第4〜
5図は本発明にかかわる容器において採用しうる底部構
造を示す断面図、第6図は本発明の他の実施例にかかわ
る容器の要部断面図である。 (図面の主要符号) (1):容器本体 (2):隔壁 (3):薄膜 (4):バルブ (5):ロッド (6):操作ロッド (7):スパウト (30):バルブ (37):ロッド
FIG. 1 is a cross-sectional view of a container according to an embodiment of the present invention, FIG. 2 is a cross-sectional view of the same container with a thin film ruptured, and FIG. 3 is a cross-sectional view of the same container during a jetting operation. , 4th ~
FIG. 5 is a cross-sectional view showing a bottom structure that can be adopted in the container according to the present invention, and FIG. 6 is a main-part cross-sectional view of the container according to another embodiment of the present invention. (Main symbols in the drawing) (1): Container body (2): Partition wall (3): Thin film (4): Valve (5): Rod (6): Operation rod (7): Spout (30): Valve (37) ):rod

Claims (6)

【特許請求の範囲】[Claims] 【請求項1】容器本体と、該容器本体の内部を2以上の
隔室に区画するとともに開口部を有する、実質的に剛体
の隔壁と、該隔壁に、前記開口部を閉塞しかつ外力で破
口することができるように設けられた易破壊性を有する
薄膜と、容器本体に設けられた、容器本体の外部から前
記薄膜に外力を加える手段とからなり、 該外力を加える手段が、容器本体の外部に位置する押圧
操作部と容器本体の内部に位置する薄膜押圧部とから構
成されてなる内容物混合容器。
1. A container body, a substantially rigid partition wall that divides the interior of the container body into two or more compartments and has an opening, and the partition wall that closes the opening and is provided with an external force. A thin film having an easily destructible property provided so as to be capable of breaking, and a means for applying an external force to the thin film from the outside of the container body, which is provided in the container body, and the means for applying the external force is a container. A contents mixing container comprising a pressing operation unit located outside the main body and a thin film pressing unit located inside the container main body.
【請求項2】前記隔壁が、容器本体の筒状の外周壁の一
方の端縁と共締めされた有底筒状部材によって構成され
てなる特許請求の範囲第1項記載の容器。
2. The container according to claim 1, wherein the partition wall is constituted by a bottomed tubular member that is fastened together with one edge of a tubular outer peripheral wall of the container body.
【請求項3】前記外力を加える手段が、容器本体のバル
ブの中心部を気密状態で貫通するロッドである特許請求
の範囲第1項記載の容器。
3. The container according to claim 1, wherein the means for applying the external force is a rod that penetrates the central portion of the valve of the container body in an airtight state.
【請求項4】取り出し手段を備えた耐圧性の容器本体
と、該容器本体の内部を2以上の隔室に区画するととも
に開口部を有する、実質的に剛体の隔壁と、該隔壁に、
前記開口部を閉塞しかつ外力で破口することができるよ
うに設けられた易破壊性を有する薄膜と、容器本体に設
けられた、容器本体の外部から前記薄膜に外力を加える
手段とからなり、 該外力を加える手段が、容器本体の外部に位置する押圧
操作部と容器本体の内部に位置する薄膜押圧部とから構
成されてなる混合容器を有し、 前記隔室内にたがいに混合されるべき第一内容物と第二
内容物とがそれぞれ加圧されておらない状態で充填され
ており、第一内容物および第二内容物が、混合されると
きにたがいに反応して圧力を発生する二種類の薬剤を含
有してなる内容物混合吐出装置。
4. A pressure-resistant container body provided with a take-out means, a substantially rigid partition wall that divides the interior of the container body into two or more compartments and has an opening, and the partition wall.
It comprises a thin film having an easily destructible property that is provided so as to close the opening and can be breached by an external force, and a means that is provided in the container body and applies an external force to the thin film from the outside of the container body. The means for applying the external force has a mixing container including a pressing operation part located outside the container body and a thin film pressing part located inside the container body, and the mixing container is mixed with each other in the compartment. The first content and the second content to be filled are respectively filled in a non-pressurized state, and the first content and the second content react with each other to generate pressure when mixed. A content mixing and discharging device containing two kinds of chemicals.
【請求項5】前記二種類の薬剤が、混合されることによ
り圧力ガスを発生するものである特許請求の範囲第4項
記載の装置。
5. The device according to claim 4, wherein the two kinds of chemicals generate a pressure gas when mixed.
【請求項6】前記二種類の薬剤が混合されるときにたが
いに反応して発熱するものであり、かつ少なくとも一方
の内容物が、発生した熱によって圧力を発生する低沸点
の液体を含有する特許請求の範囲第4項記載の装置。
6. When the two kinds of drugs are mixed together, they react with each other to generate heat, and at least one of the contents contains a low boiling point liquid which generates pressure by the generated heat. The device according to claim 4.
JP62069799A 1987-03-24 1987-03-24 Content mixing container and content mixing and discharging device using the container Expired - Fee Related JPH0626686B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP62069799A JPH0626686B2 (en) 1987-03-24 1987-03-24 Content mixing container and content mixing and discharging device using the container

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP62069799A JPH0626686B2 (en) 1987-03-24 1987-03-24 Content mixing container and content mixing and discharging device using the container

Publications (2)

Publication Number Publication Date
JPS63236556A JPS63236556A (en) 1988-10-03
JPH0626686B2 true JPH0626686B2 (en) 1994-04-13

Family

ID=13413150

Family Applications (1)

Application Number Title Priority Date Filing Date
JP62069799A Expired - Fee Related JPH0626686B2 (en) 1987-03-24 1987-03-24 Content mixing container and content mixing and discharging device using the container

Country Status (1)

Country Link
JP (1) JPH0626686B2 (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19709036A1 (en) * 1997-03-06 1998-09-17 Draenert Klaus Container, device and method for mixing, filling and decanting a mixture of substances
DE10144133A1 (en) 2001-09-07 2003-03-27 Peter Kwasny Gmbh Two-component paint-spray can, especially e.g. for repairing cars, contains a curable epoxy resin stock component, solvent and propellant gas, with a hardener in a separate, externally-activated tube inside the can
DE10260117A1 (en) * 2002-12-19 2004-07-01 Peter Kwasny Gmbh Pressure can for mixing and dispensing two-component materials
EP2819557B1 (en) * 2012-02-28 2020-07-29 Gudpod Corp. A nutraceutical compounding system and method therefore
MY185337A (en) * 2014-12-10 2021-05-06 Orientus Ind Sdn Bhd A single hole single action aerosol can
EP3454817A4 (en) * 2016-05-12 2020-02-19 Nextteq LLC Device for fit testing of gas masks
CN107310857A (en) * 2017-08-05 2017-11-03 中山市美捷时包装制品有限公司 A kind of two-component packaging aerosol valves tank arrangement
EP3560582A1 (en) * 2018-04-23 2019-10-30 Covestro Deutschland AG Container with multiple chambers for storing and mixing a multicomponent liquid coating or gluing system
CN111867715B (en) * 2018-02-22 2023-05-19 科思创知识产权两合公司 Multi-chamber container for a liquid coating or bonding system for storing and mixing multiple components
CN110117143B (en) * 2019-05-10 2021-09-17 大成科创基础建设股份有限公司 Method for curing slurry by using magnesium-based composite material

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4938576U (en) * 1972-07-06 1974-04-05
JPS5147609U (en) * 1974-10-07 1976-04-08

Also Published As

Publication number Publication date
JPS63236556A (en) 1988-10-03

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