JPH0617296B2 - Hair treatment agent - Google Patents
Hair treatment agentInfo
- Publication number
- JPH0617296B2 JPH0617296B2 JP11934387A JP11934387A JPH0617296B2 JP H0617296 B2 JPH0617296 B2 JP H0617296B2 JP 11934387 A JP11934387 A JP 11934387A JP 11934387 A JP11934387 A JP 11934387A JP H0617296 B2 JPH0617296 B2 JP H0617296B2
- Authority
- JP
- Japan
- Prior art keywords
- hair
- weight
- alcohol
- hair treatment
- present
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/416—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Description
【発明の詳細な説明】 （技術分野） 本発明は、ヘアーリンス，ヘアートリートメントなどの
毛髪処理剤に関し、更に詳細には、カチオン性界面活性
剤，ポリペプチド，ステアリルアルコール，ベヘニルア
ルコールによりパール状結晶を生成させ、外観が美麗で
あり、保存安定性に優れると共に髪仕上効果の優れた毛
髪処理剤に関する。TECHNICAL FIELD The present invention relates to a hair treatment agent such as a hair rinse and a hair treatment, and more specifically, it forms a pearl-like crystal with a cationic surfactant, a polypeptide, stearyl alcohol, and behenyl alcohol. The present invention relates to a hair treatment agent which is produced and has a beautiful appearance, excellent storage stability, and excellent hair finishing effect.
（従来技術） シヤンプー，リンス，ローション等の商品価値を高める
目的で、外観をパール状にすることが行なわれている。(Prior Art) For the purpose of increasing the commercial value of shampoo, rinse, lotion, etc., the appearance is made pearly.
いわゆるパール光沢剤としては古くから魚鱗箔，雲母ま
たは高級脂肪酸もしくはその塩、エチレングリコール高
級脂肪酸エステル等の結晶物が用いられている。As a so-called pearl luster agent, fish scale foil, mica, or higher fatty acid or its salt, and crystalline substances such as ethylene glycol higher fatty acid ester have been used for a long time.
これらのうち、近年最も汎用されているパール光沢剤
は、例えば都開昭５７−１５６４０９号等の公報に記載
されているごとく、エチレングリコール等の多価アルコ
ールと高級脂肪酸とのエステル類の結晶物である。しか
し、これらはエチレングリコール高級脂肪酸エステル類
を予めパール剤として調製して、組成物中に配合するな
ど複雑な工程を必要とし、また美麗なパール光沢を付与
するために毛髪用の組成物中に多量に配合すると、後記
の髪仕上効果（髪のしっとり感，髪のなめらかさ，くし
通り性）が悪化するという欠点を有していた。Of these, the most widely used pearlescent agents in recent years are, for example, as disclosed in Tokai Sho 57-156409 and the like, crystalline substances of esters of polyhydric alcohols such as ethylene glycol and higher fatty acids. Is. However, these require complicated steps such as preliminarily preparing ethylene glycol higher fatty acid esters as a pearling agent and compounding into the composition, and in order to impart a beautiful pearly luster to the composition for hair. When it was mixed in a large amount, it had a defect that the hair finishing effects (hair moisturizing feeling, smoothness of hair, combability) described below deteriorated.
（発明の開示） このような状況において、本発明者は外観が美麗で、保
存安定性に優れたパール光沢を付与すると共に、髪仕上
効果の優れたヘアーリンス，ヘアートリートメント等の
毛髪処理剤を得る目的で鋭意研究を重ねた結果、後記特
定のカチオン性界面活性剤とポリペプチドと、ステアリ
ルアルコール及びベヘニルアルコールを必須成分として
含有してなる毛髪処理剤は、上記目的を達成し得ること
を見出し、本発明を完成した。DISCLOSURE OF THE INVENTION In such a situation, the present inventor provides a hair treatment agent such as a hair rinse and a hair treatment which has a beautiful appearance and imparts a pearly luster excellent in storage stability and has an excellent hair finishing effect. As a result of earnest studies for the purpose of obtaining the above, it was found that a hair treatment agent containing the following specific cationic surfactant and polypeptide, and stearyl alcohol and behenyl alcohol as essential components can achieve the above object, The present invention has been completed.
（発明の目的） 即ち、本発明の目的は、パール光沢性，保存安定性，髪
仕上効果に優れた毛髪処理剤を提供することにある。(Object of the Invention) That is, an object of the present invention is to provide a hair treatment agent which is excellent in pearl luster, storage stability and hair finishing effect.
（発明の構成） 本発明は (A) 一般式 〔式中、Ｒ１，Ｒ２，Ｒ３及びＲ４の１〜２個は炭素数
１２〜２４の長鎖アルキル基を示し、残余は炭素数１〜
３のアルキル基，ベンジル基を示し、Ｘはハロゲン原子
を示す。〕 で表わされる第４級アンモニウム塩の少なくとも一種0.
1〜１０重量％，(B)平均分子量２００〜5,000のポリペ
プチド1.0〜１２重量％(C)ステアリルアルコール0.1〜
１０重量％，(D)ベヘニルアルコール0.15〜１５重量％
を含有してなり、かつステアリルアルコールとベヘニル
アルコールの配合重量比は１：1.5〜１：4.5である毛髪
処理剤である。(Structure of Invention) The present invention includes Wherein 1-2 R 1, R 2, R 3 and R 4 represents a long chain alkyl group having 12 to 24 carbon atoms, the remainder is 1 to carbon atoms
3 represents an alkyl group or a benzyl group, and X represents a halogen atom. ] At least one kind of quaternary ammonium salt represented by 0.
1 to 10% by weight, (B) polypeptide having an average molecular weight of 200 to 5,000 1.0 to 12% by weight (C) stearyl alcohol 0.1 to
10% by weight, (D) behenyl alcohol 0.15 to 15% by weight
And a compounding weight ratio of stearyl alcohol and behenyl alcohol is 1: 1.5 to 1: 4.5.
（構成の具体的な説明） 本発明の(A)成分であるカチオン性界面活性剤は、次の
一般式 〔式中、Ｒ１，Ｒ２，Ｒ３，及びＲ４の１〜２個は炭素
数１２〜２４の長鎖アルキル基を示し、残余は炭素数１
〜３のアルキル基，ベンジル基を示し、Ｘはハロゲン原
子を示す。〕 で表わされる第４級アンモニウム塩の少なくとも一種が
適用され、通常のヘアーリンス剤等に配合され得るすべ
てのものが使用される。例えば、ジステアリルジメチル
アンモニウムクロライド，ステアリルトリメチルアンモ
ニウムクロライド，ステアリルジメチルベンジルアンモ
ニウムクロライド，セチルトリメチルアンモニウムクロ
ライド，ベヘニルトリメチルアンモニウムクロライドな
どが挙げられる。(Specific Description of Structure) The cationic surfactant which is the component (A) of the present invention has the following general formula: [In the formula, 1-2 of R 1 , R 2 , R 3 , and R 4 represent a long-chain alkyl group having 12 to 24 carbon atoms, and the remainder is 1 carbon atom.
To 3 are alkyl groups and benzyl groups, and X is a halogen atom. ] At least one of the quaternary ammonium salts represented by the following is applied, and all that can be mixed with a usual hair rinse agent and the like are used. For example, distearyl dimethyl ammonium chloride, stearyl trimethyl ammonium chloride, stearyl dimethyl benzyl ammonium chloride, cetyl trimethyl ammonium chloride, behenyl trimethyl ammonium chloride, etc. are mentioned.
本発明の毛髪処理剤には、これらの(A)成分の少なくと
も一種を総量を基準として0.1〜１０重量％（以下ｗｔ
％と略記する）好ましくは、0.5〜５ｗｔ％配合され
る。また、配合量が0.1ｗｔ％未満では髪仕上効果に良
好な結果が得られず、１０ｗｔ％を超えると毛髪にべた
つきが生じ好ましくない。The hair treatment agent of the present invention contains at least one of these (A) components in an amount of 0.1 to 10% by weight (hereinafter referred to as wt.
(Abbreviated as%) Preferably, 0.5 to 5 wt% is blended. Further, if the amount is less than 0.1 wt%, good results for the hair finishing effect cannot be obtained, and if it is more than 10 wt%, the hair becomes sticky, which is not preferable.
本発明の(B)成分であるポリペプチドは、公知の物質で
あって、下記一般式で表わされるようにアミノ基とカル
ボキシル基を併せもつ物質で本質的にはその製造の由来
を問うものではないが実用的には、通常のコラーゲン蛋
白質の加水分解物が適用される。The polypeptide which is the component (B) of the present invention is a known substance, which is a substance having both an amino group and a carboxyl group as represented by the following general formula, and essentially does not question the origin of its production. However, in practice, a normal collagen protein hydrolyzate is applied.
（ただしＲはアルキル基を示す） また、ポリペプチドの平均分子量（ゲルロ過測定）は、
２００〜５０００であり好ましくは、４００〜３０００
である。平均分子量が２００未満あるいは５０００を超
えては良好なパール光沢及び髪仕上効果が得られない。
また、ポリペプチドの含有量は1.0〜１２ｗｔ％，好ま
しくは2.0〜１０ｗｔ％である。また配合量が１ｗｔ％
未満あるいは１２ｗｔ％を超えては良好なパール光沢が
得られず、後記の保存安定性が劣る。 (However, R represents an alkyl group.) The average molecular weight of the polypeptide (measured by gel filtration) is
200 to 5000, preferably 400 to 3000
Is. If the average molecular weight is less than 200 or more than 5000, good pearly luster and hair finishing effect cannot be obtained.
The content of the polypeptide is 1.0 to 12 wt%, preferably 2.0 to 10 wt%. Moreover, the compounding amount is 1 wt%
If the amount is less than 12% or more than 12% by weight, good pearly luster cannot be obtained and the storage stability described below is poor.
また、(C)成分であるステアリルアルコール，(D)成分で
あるベヘニルアルコールの配合量は0.1〜１０ｗｔ％，
好ましくは0.5〜６ｗｔ％であり、ステアリルアルコー
ルとベヘニルアルコールの配合重量比は１：1.5〜１：
4.5特に好ましくは、１：２〜１：４の範囲である。Further, the compounding amount of stearyl alcohol which is the component (C) and behenyl alcohol which is the component (D) is 0.1 to 10 wt%,
It is preferably 0.5 to 6 wt% and the blending weight ratio of stearyl alcohol and behenyl alcohol is 1: 1.5 to 1:
4.5 Particularly preferably, the range is 1: 2 to 1: 4.
ステアリルアルコールとベヘニルアルコールの配合重量
比が上記範囲以外では優れたパール光沢性及び保存安定
性は得られない。If the blending weight ratio of stearyl alcohol and behenyl alcohol is outside the above range, excellent pearly luster and storage stability cannot be obtained.
本発明の毛髪処理剤は、上述した４成分を必須の構成成
分とするが、当該組成物には、本発明の目的を達成する
範囲で他の成分を配合することができる。The hair treatment agent of the present invention contains the above-mentioned four components as essential constituent components, but other components can be added to the composition within a range that achieves the object of the present invention.
即ち、流動パラフィン、ワセリン，スクワラン，等の炭
化水素，イソプロピルミリステート，イソプロピルパル
ミテート，等のエステル油，ツバキ油，オリーブ油，ア
ボカド油等の植物油，ポリグリセリン脂肪酸エステル，
ポリオキシエチレン脂肪酸エステル，ポリオキシエチレ
ンソルビタンモノラウレート等の非イオン界面活性剤，
メチルセルロース，ヒドロキシエチルセルロース，カチ
オン化セルロース等のセルロース誘導体，エチレングリ
コール，プロピレングリコール，グリセリン等の保湿
剤，その他殺菌剤，キレート剤，紫外線吸収剤，着色
剤，香料などが挙げられ、これらの一種または二種以上
を配合することができる。That is, hydrocarbons such as liquid paraffin, petrolatum and squalane, ester oils such as isopropyl myristate and isopropyl palmitate, vegetable oils such as camellia oil, olive oil and avocado oil, polyglycerin fatty acid esters,
Nonionic surfactants such as polyoxyethylene fatty acid ester, polyoxyethylene sorbitan monolaurate,
Examples include cellulose derivatives such as methyl cellulose, hydroxyethyl cellulose and cationized cellulose, moisturizers such as ethylene glycol, propylene glycol and glycerin, and other bactericides, chelating agents, UV absorbers, coloring agents, and fragrances. More than one species can be blended.
本発明の毛髪処理剤にパール状光沢が付与される理由は
明確ではないが、本発明に用いるカチオン性界面活性剤
と特定の配合比率のステアリルアルコール及びベヘニル
アルコールとポリペプチドの複合塩が析出するためであ
ると推考される。The reason why the hair treatment composition of the present invention is imparted with pearly luster is not clear, but the cationic surfactant used in the present invention and stearyl alcohol or behenyl alcohol in a specific mixing ratio and a complex salt of a polypeptide are precipitated. Is supposed to be.
（実施例） 次に実施例を挙げ本発明を説明するが、本発明はこれら
実施例に限定されるものではない。(Examples) Next, the present invention will be described with reference to examples, but the present invention is not limited to these examples.
なお、本実施例中で用いた試験方法は、下記の通りであ
る。The test method used in this example is as follows.
(1) パール光沢性 試料を１００ｍｌの透明ガラス容器に入れ、肉眼判定に
より下記基準で評価を行なった。(1) Pearl luster The sample was placed in a 100 ml transparent glass container and evaluated by the naked eye for the following criteria.
○：美麗なパール光沢が認められる。 ◯: A beautiful pearl luster is recognized.
△：わずかにパール光沢が認められる。 Δ: A slight pearly luster is recognized.
×：パール光沢が認められない。 X: No pearl luster is observed.
(2) 保存安定性 (イ) 高温安定性 試料を１００ｍｌの透明ガラス容器に入れ、密閉し、４
５℃の恒温室中に１ケ月保存した後、肉眼判定により、
下記基準で評価を行なった。(2) Storage stability (b) High temperature stability Put the sample in a 100 ml transparent glass container, seal it, and
After storing it in a thermostatic chamber at 5 ° C for 1 month,
The evaluation was performed according to the following criteria.
○：相分離、パール光沢の凝集，消失等を認めない。 ◯: No phase separation, aggregation or disappearance of pearly luster is observed.
×：相分離、パール光沢の凝集，消失等を認める。 X: Phase separation, aggregation and disappearance of pearly luster are recognized.
(ロ) 低温安定性 試料を１００ｍｌの透明ガラス容器に入れ、密閉し、０
℃の恒温室中に１ケ月保存した後、肉眼判定により下記
基準で評価を行なった。(B) Low temperature stability Put the sample in a 100 ml transparent glass container, seal it, and
After being stored in a thermostatic chamber at a temperature of 1 ° C. for 1 month, the following criteria were evaluated by the naked eye.
○：相分離、固結等が認められない。 ◯: Phase separation and solidification are not observed.
×：相分離、固結等が認められる。 X: Phase separation, solidification, etc. are recognized.
(3) 髪仕上げ効果 各例における「髪のしっとり感」，「髪のなめらか
さ」，「くし通り性」を市販のヘアーリンス剤と比べ、
女性２０名のパネラーにより官能的に比較し、下記基準
で評価を行なった。(3) Hair finishing effect Compared to commercially available hair rinse agents, "moist feeling of hair", "smoothness of hair", and "combability" in each example.
Sensory comparisons were carried out by 20 female panelists, and evaluation was performed according to the following criteria.
◎：良いと答えた人が１８人以上の場合 ○： 〃 が１４〜１７人の場合 △： 〃 が８〜１３人の場合 ×： 〃 が７人以下の場合 実施例１〜２、比較例１〜３ 第１表に示す配合組成のヘアーリンス組成物を通常の方
法で調製し、各必須成分の効果を調べ第１表にその結果
を示す。◎: When the number of people who answered good was 18 or more ○: When 〃 was 14 to 17 △: When 〃 was 8 to 13 ×: When 〃 was 7 or less Examples 1-2, Comparative Example 1 to 3 A hair rinse composition having the composition shown in Table 1 was prepared by a usual method, and the effect of each essential component was investigated. Table 1 shows the results.
実施例３〜４、比較例４〜７ 第２表に示す配合組成のヘアートリートメント組成物を
通常の方法で調製し、各必須成分の効果を調べ第２表に
その結果を示す。 Examples 3 to 4 and Comparative Examples 4 to 7 Hair treatment compositions having the composition shown in Table 2 were prepared by a usual method, and the effect of each essential component was investigated. Table 2 shows the results.
実施例５〜６、比較例８〜１０ 第３表に示す配合組成のヘアーリンス組成物を通常の方
法で調製し、各必須成分の効果を調べ第３表にその結果
を示す。 Examples 5 to 6 and Comparative Examples 8 to 10 Hair rinse compositions having the composition shown in Table 3 were prepared by a usual method, and the effect of each essential component was investigated, and Table 3 shows the results.
（特性） 実施例１〜６より明らかなように、本発明の毛髪処理剤
は、いずれも優れた性能を示している。 (Characteristics) As is clear from Examples 1 to 6, the hair treatment agents of the present invention all show excellent performance.
これに対し、必須成分である高級アルコールが、セチル
アルコール，ステアリルアルコール及びベヘニルアルコ
ールの単独、またはセチルアルコールとステアリルアル
コールあるいはセチルアルコールとベヘニルアルコール
のごとく二種の併用の場合（比較例１〜５）、ステアリ
ルアルコールとベヘニルアルコールの配合重量比が本発
明の範囲外の場合（比較例６〜７）、また必須成分であ
るポリペプチドの配合量が本発明の範囲外の場合（比較
例８〜１０）等々は、いずれも劣った性能を示し、本発
明の目的を達成できない。On the other hand, when the higher alcohol which is an essential component is cetyl alcohol, stearyl alcohol and behenyl alcohol alone or in combination of two kinds such as cetyl alcohol and stearyl alcohol or cetyl alcohol and behenyl alcohol (Comparative Examples 1 to 5), stearyl is used. When the blending weight ratio of alcohol and behenyl alcohol is outside the range of the present invention (Comparative Examples 6 to 7), and when the blending amount of the polypeptide which is an essential component is outside the range of the present invention (Comparative Examples 8 to 10), etc. However, all of them show inferior performance, and the object of the present invention cannot be achieved.
（発明の効果） 以上記載のごとく、本発明は、パール光沢性，保存安定
性，髪仕上効果に優れた有用なる毛髪処理剤を提供する
ことは明らかである。(Effects of the Invention) As described above, it is apparent that the present invention provides a useful hair treatment agent which is excellent in pearly luster, storage stability and hair finishing effect.
Claims (1)
１２〜２４の長鎖アルキル基を示し、残余は炭素数１〜
３のアルキル基，ベンジル基を示し、Ｘはハロゲン原子
を示す。〕 で表わされる第４級アンモニウム塩の少なくとも一種0.
1〜１０重量％，(B)平均分子量２００〜5,000のポリペ
プチド1.0〜１２重量％(C)ステアリルアルコール0.1〜
１０重量％，(D)ベヘニルアルコール0.15〜１５重量％
を含有してなり、かつステアリルアルコールとベヘニル
アルコールの配合重量比は１：1.5〜１：4.5である毛髪
処理剤。1. A general formula (A) Wherein 1-2 R 1, R 2, R 3 and R 4 represents a long chain alkyl group having 12 to 24 carbon atoms, the remainder is 1 to carbon atoms
3 represents an alkyl group or a benzyl group, and X represents a halogen atom. ] At least one kind of quaternary ammonium salt represented by 0.
1 to 10% by weight, (B) polypeptide having an average molecular weight of 200 to 5,000 1.0 to 12% by weight (C) stearyl alcohol 0.1 to
10% by weight, (D) behenyl alcohol 0.15 to 15% by weight
And a blending weight ratio of stearyl alcohol and behenyl alcohol of 1: 1.5 to 1: 4.5.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11934387A JPH0617296B2 (en) | 1987-05-15 | 1987-05-15 | Hair treatment agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11934387A JPH0617296B2 (en) | 1987-05-15 | 1987-05-15 | Hair treatment agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63284113A JPS63284113A (en) | 1988-11-21 |
| JPH0617296B2 true JPH0617296B2 (en) | 1994-03-09 |
Family
ID=14759136
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP11934387A Expired - Lifetime JPH0617296B2 (en) | 1987-05-15 | 1987-05-15 | Hair treatment agent |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0617296B2 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19622967C1 (en) * | 1996-06-07 | 1998-01-29 | Henkel Kgaa | Aqueous pearlescent concentrates |
| DE19622968C2 (en) * | 1996-06-07 | 2000-08-17 | Cognis Deutschland Gmbh | Aqueous pearlescent concentrates |
| FR2781368B1 (en) * | 1998-07-27 | 2000-09-01 | Oreal | COMPOSITION CONTAINING AN OPACIFYING OR NACRANT AGENT AND AT LEAST ONE FATTY ALCOHOL |
-
1987
- 1987-05-15 JP JP11934387A patent/JPH0617296B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPS63284113A (en) | 1988-11-21 |
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