JPH0451958A - Treating agent for circulation type toilet filth - Google Patents
Treating agent for circulation type toilet filthInfo
- Publication number
- JPH0451958A JPH0451958A JP2157676A JP15767690A JPH0451958A JP H0451958 A JPH0451958 A JP H0451958A JP 2157676 A JP2157676 A JP 2157676A JP 15767690 A JP15767690 A JP 15767690A JP H0451958 A JPH0451958 A JP H0451958A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- parts
- toilet
- filth
- enzyme
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 28
- 108090000790 Enzymes Proteins 0.000 claims abstract description 19
- 102000004190 Enzymes Human genes 0.000 claims abstract description 19
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 claims abstract description 16
- 239000004302 potassium sorbate Substances 0.000 claims abstract description 16
- 229940069338 potassium sorbate Drugs 0.000 claims abstract description 16
- 235000010241 potassium sorbate Nutrition 0.000 claims abstract description 16
- 239000010865 sewage Substances 0.000 claims abstract description 9
- -1 diol compound Chemical class 0.000 claims description 16
- 150000007524 organic acids Chemical class 0.000 claims description 12
- 239000002699 waste material Substances 0.000 claims description 8
- 239000000049 pigment Substances 0.000 claims description 6
- YALHCTUQSQRCSX-UHFFFAOYSA-N sulfane sulfuric acid Chemical compound S.OS(O)(=O)=O YALHCTUQSQRCSX-UHFFFAOYSA-N 0.000 claims description 5
- 230000000694 effects Effects 0.000 abstract description 11
- 239000000975 dye Substances 0.000 abstract description 7
- 229920002472 Starch Polymers 0.000 abstract description 4
- 239000002253 acid Substances 0.000 abstract description 4
- 230000002421 anti-septic effect Effects 0.000 abstract description 4
- 239000010446 mirabilite Substances 0.000 abstract description 4
- RSIJVJUOQBWMIM-UHFFFAOYSA-L sodium sulfate decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-]S([O-])(=O)=O RSIJVJUOQBWMIM-UHFFFAOYSA-L 0.000 abstract description 4
- 235000019698 starch Nutrition 0.000 abstract description 4
- 239000000463 material Substances 0.000 abstract description 3
- 238000004332 deodorization Methods 0.000 abstract description 2
- 150000002009 diols Chemical class 0.000 abstract 3
- 238000013329 compounding Methods 0.000 abstract 1
- 229940088598 enzyme Drugs 0.000 description 14
- 230000001877 deodorizing effect Effects 0.000 description 11
- 235000019645 odor Nutrition 0.000 description 10
- 239000000126 substance Substances 0.000 description 8
- 239000003755 preservative agent Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 108010073178 Glucan 1,4-alpha-Glucosidase Proteins 0.000 description 4
- 102100022624 Glucoamylase Human genes 0.000 description 4
- 235000005985 organic acids Nutrition 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000010802 sludge Substances 0.000 description 4
- SGHZXLIDFTYFHQ-UHFFFAOYSA-L Brilliant Blue Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 SGHZXLIDFTYFHQ-UHFFFAOYSA-L 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 230000002335 preservative effect Effects 0.000 description 3
- 239000008107 starch Substances 0.000 description 3
- PSJBSUHYCGQTHZ-UHFFFAOYSA-N 3-Methoxy-1,2-propanediol Chemical compound COCC(O)CO PSJBSUHYCGQTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000004382 Amylase Substances 0.000 description 2
- LVDKZNITIUWNER-UHFFFAOYSA-N Bronopol Chemical compound OCC(Br)(CO)[N+]([O-])=O LVDKZNITIUWNER-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 102000004139 alpha-Amylases Human genes 0.000 description 2
- 108090000637 alpha-Amylases Proteins 0.000 description 2
- 229940024171 alpha-amylase Drugs 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 239000001055 blue pigment Substances 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- RWLALWYNXFYRGW-UHFFFAOYSA-N 2-Ethyl-1,3-hexanediol Chemical compound CCCC(O)C(CC)CO RWLALWYNXFYRGW-UHFFFAOYSA-N 0.000 description 1
- RBTBFTRPCNLSDE-UHFFFAOYSA-N 3,7-bis(dimethylamino)phenothiazin-5-ium Chemical compound C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 RBTBFTRPCNLSDE-UHFFFAOYSA-N 0.000 description 1
- ZKQDCIXGCQPQNV-UHFFFAOYSA-N Calcium hypochlorite Chemical compound [Ca+2].Cl[O-].Cl[O-] ZKQDCIXGCQPQNV-UHFFFAOYSA-N 0.000 description 1
- 206010037660 Pyrexia Diseases 0.000 description 1
- 239000005708 Sodium hypochlorite Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000005273 aeration Methods 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000001045 blue dye Substances 0.000 description 1
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- ZITKDVFRMRXIJQ-UHFFFAOYSA-N dodecane-1,2-diol Chemical compound CCCCCCCCCCC(O)CO ZITKDVFRMRXIJQ-UHFFFAOYSA-N 0.000 description 1
- 230000003670 easy-to-clean Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 239000003550 marker Substances 0.000 description 1
- 229960000907 methylthioninium chloride Drugs 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 239000010815 organic waste Substances 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 210000001179 synovial fluid Anatomy 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- 210000002700 urine Anatomy 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
Landscapes
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明は、トイレ汚物に消臭性とクリーン感を付与する
ことができる循環式トイレ汚物処理剤に関する。特に、
本発明は、特に、夏場及び冬場の高温と低温の厳しい条
件になる車両のトイレで用いる場合に適するもので、ク
リーン性が高く、悪臭が無く、色相的にも快い汚水処理
剤に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to a circulating toilet filth treatment agent that can impart deodorizing properties and a clean feeling to toilet filth. especially,
The present invention relates to a sewage treatment agent that is particularly suitable for use in vehicle toilets, which are subjected to severe conditions of high and low temperatures in summer and winter, and is highly clean, free of bad odor, and pleasant in color.
１従来の技術及び発明が解決しようとする問題点ｊ従来
、トイレ汚物処理剤としては、（１）酸やアルカリなど
を用いて、化学的に分解処理するもの、（２）酵素や微
生物を含有する溶液に浸し、分解するものが、行なわれ
ている。このうち、トイレ処理剤として、次亜塩素酸ナ
トリウムを使用しているものは、その薬品自体の特有の
臭気のため、与える印象が良くなく、更に、有機物汚物
を分解することができないものである。1. Problems to be solved by conventional techniques and inventions j Conventionally, toilet filth treatment agents include (1) those that are chemically decomposed using acids or alkalis, and (2) those that contain enzymes or microorganisms. A method of decomposing the material by soaking it in a solution is being carried out. Among these, toilet treatment agents that use sodium hypochlorite do not give a good impression due to the unique odor of the chemical itself, and are also unable to decompose organic waste. .
また、それらは、その消臭効果の安定性や即効性につい
ては一部不安な面があった。In addition, there were some concerns about the stability and immediate effectiveness of their deodorizing effects.
また、以上の従来の汚物処理剤では、温度やｐＨ変化に
よる性能低下がさけられなかった。特に、冬場の１０℃
以下や、時として夏場の３５℃以上の気温では、トイレ
悪臭が優位になり、従来の方法では消臭できなかった。Further, in the conventional filth treatment agents described above, performance deterioration due to changes in temperature and pH cannot be avoided. Especially in winter at 10℃
At temperatures below 35 degrees Celsius and sometimes above 35 degrees Celsius in the summer, bad toilet odors become predominant and cannot be eliminated using conventional methods.
また、時として、トイレに投入される強アルカリ物質な
どの添加効果によっても、消臭が妨害されることもあり
、列車トイレのように、乗客が不用意に投入する食品な
どによるｐＨ変化も考慮しておく必要があると考えられ
る。In addition, deodorization can sometimes be hindered by the effects of additives such as strong alkaline substances thrown into the toilet, and pH changes caused by food, etc. that are carelessly thrown in by passengers, such as in train toilets, are also taken into account. It may be necessary to do so.
本発明では、以上の問題点を克服すべく、温度やｐＨの
変化による消臭効果の妨害を充分考慮すべく、鋭意研究
を重ねた結果、これらの対策として、（１）強力な防腐
剤としてジオール系化合物を構成要素とすることにより
、多少の温度幅やｐＨ変化に対しても安定な消臭効果を
示すよ゛うにしたこと、（２）ジオール系化合物以外に
もソルビン酸カリウムを添加して防腐性を補強したこと
、（３）酵素としてａ−アミラーゼとグルコアミラーゼ
を併用することにより、汚物中のデンプン質を糖化させ
て、非悪臭物質に変換させること、（４）有機酸を加え
ることにより、ｐＨを低下させ、前記の防腐剤がより効
果を示すｐＨ範囲を作ること。以上の４つの手段をとる
ことにより、従来の処理剤より有効な汚物処理剤を提供
することができた。In the present invention, in order to overcome the above-mentioned problems, as a result of extensive research in order to fully consider the interference with the deodorizing effect due to changes in temperature and pH, we have developed the following countermeasures: (1) as a strong preservative; By using a diol compound as a component, it is able to exhibit a stable deodorizing effect even over a slight temperature range and pH change; (2) Potassium sorbate is added in addition to the diol compound. (3) By using a-amylase and glucoamylase together as enzymes, the starch in the waste is saccharified and converted into a non-malodorous substance; (4) Organic acids are added. thereby lowering the pH and creating a pH range in which the preservatives are more effective. By taking the above four measures, it was possible to provide a filth treatment agent that is more effective than conventional treatment agents.
［問題点を解決するための手段］
本発明の要旨とするものは、酵素、ジオール系化合物、
色素、ソルビン酸カリウム、ぼう硝、有機酸から本質的
になることを特徴とする循環式トイレ汚物処理剤である
。そして、その場合、酵素１重量部に対して、ジオール
系化合物 ３〜２０重量部、色素 ０．２〜４重量部、
ソルビン酸カリウム ３〜９５重量部、ばう硝 ３〜９
５重量部、有機酸 ５〜４０重量部から本質的になる循
環式トイレ汚物処理剤が好適である。[Means for solving the problems] The gist of the present invention is that enzymes, diol compounds,
This is a circulating toilet sewage treatment agent that consists essentially of pigment, potassium sorbate, sulfur sulfate, and organic acids. In that case, for 1 part by weight of enzyme, 3 to 20 parts by weight of diol compound, 0.2 to 4 parts by weight of dye,
Potassium sorbate 3-95 parts by weight, sulfur sulfate 3-9
A circulating toilet filth treatment agent consisting essentially of 5 parts by weight and 5 to 40 parts by weight of an organic acid is preferred.
本発明によると、先ず、トイレ汚物からの悪臭発生を防
止するために、酵素、ジオール系化合物、色素、ソルビ
ン酸カリウム、ぼう硝、有機酸を含有するものである。According to the present invention, first, in order to prevent the generation of bad odor from toilet filth, it contains an enzyme, a diol compound, a pigment, potassium sorbate, sulfur sulfate, and an organic acid.
即ち、酵素１重量部に対して、ジオール系化合物３〜２
０重量部、色素０．２〜４重量部、ソルビン酸カリウム
３〜９５重量部、ぼう硝３〜９５重量部、有機酸５〜４
０重量部の配合割合が好適である。That is, 3 to 2 parts of diol compound per 1 part by weight of enzyme.
0 parts by weight, 0.2 to 4 parts by weight of pigment, 3 to 95 parts by weight of potassium sorbate, 3 to 95 parts by weight of sulfate, 5 to 4 parts by weight of organic acid
A blending ratio of 0 parts by weight is suitable.
酵素としては、α−アミラーゼとグルコアミラーゼを併
用するのが好適であり、トイレ汚物中のデンプン質を糖
化させ、非悪臭物質に変換する。As the enzyme, it is suitable to use α-amylase and glucoamylase in combination, which saccharifies starch in toilet waste and converts it into a non-malodorous substance.
他の物質に対して、１重量部未満では、効果が示されな
いものである。If the amount is less than 1 part by weight with respect to other substances, no effect will be exhibited.
ジオール系化合物として、３−メトキシ−１，２−プロ
パンジオール、２−エチル−１，３−ヘキサンジオール
、１．２−ドデカンジオール、２−ブロモ−２−二トロ
ー１．３−プロパンジオール、１．２−ブタンジオール
、１．４−ブタンジオールなどジオール系化合物を用い
ることが好適である。このようなジオール系化合物は、
トイレ汚物から発生する悪臭ガスの生成を長期間にわた
り抑制することができる。これは特に防腐効果によるも
のと考えられ、広い温度幅とｐＨ変化で効果を示すもの
である。このジオール系化合物の含有範囲は、１重量部
の酵素に対して、３〜２０重量部である。As diol compounds, 3-methoxy-1,2-propanediol, 2-ethyl-1,3-hexanediol, 1,2-dodecanediol, 2-bromo-2-nitro-1,3-propanediol, 1 It is preferable to use diol compounds such as .2-butanediol and 1.4-butanediol. Such diol compounds are
The generation of foul-smelling gases generated from toilet waste can be suppressed for a long period of time. This is thought to be particularly due to the antiseptic effect, which is effective over a wide temperature range and pH change. The content range of this diol compound is 3 to 20 parts by weight per 1 part by weight of the enzyme.
めに、一般的に、青色の色素を用いる。For this purpose, blue dyes are generally used.
青色色素は、トイレ汚物に青色を着色し、クリーン感を
与える。色素としては、青色１号、青色２号、メチレン
ブルー、フタロシアニンブルーなどを用いることができ
、粉体でも、何でも良い。The blue pigment colors toilet waste blue, giving it a clean feel. As the dye, Blue No. 1, Blue No. 2, methylene blue, phthalocyanine blue, etc. can be used, and any powder may be used.
酵素１重量部に対して、０．２〜４重量部添加する。即
ち、０，２重量部未満では、色調が弱く、汚物を隠ぺい
できなく、クリーン感が発揮されない。そして、４重量
部を超えると、排水処理するときに青色は、分解されな
く、色調として残り、好ましくない。Add 0.2 to 4 parts by weight per 1 part by weight of enzyme. That is, if it is less than 0.2 parts by weight, the color tone will be weak, dirt will not be hidden, and a clean feeling will not be achieved. If the amount exceeds 4 parts by weight, the blue color will not be decomposed and will remain as a color tone during wastewater treatment, which is not preferable.
ソルビン酸カリウムは、ジオール系化合物の防腐効果を
補強するために含有させる。酵素１重量部に対して、３
〜９５重量部添加する。即ち、３重量部未満では、効果
を表わすために、不足であり、９５重量部を超えて配合
してもコスト高となり、経済的に不利である。Potassium sorbate is contained in order to reinforce the antiseptic effect of the diol compound. For 1 part by weight of enzyme, 3
Add ~95 parts by weight. That is, if it is less than 3 parts by weight, it is insufficient to exhibit the effect, and even if it is blended in excess of 95 parts by weight, the cost will be high and it is economically disadvantageous.
色素は、トイレ汚物にクリーン感を付与するなと硝は、
水溶性に優れるので、色素を水に短時間で、溶解させる
ための助剤として必要である。Pigments do not give toilet filth a clean feel, says Nitsu.
Because it has excellent water solubility, it is needed as an auxiliary agent to dissolve pigments in water in a short time.
酵素１重量部に対して、３〜９５重量部添加する。３重
量部未満では、色素の溶解を助けるのにて
不足するものであり、９５重量部を超え我も色素の溶解
を大きく高めない。Add 3 to 95 parts by weight per 1 part by weight of enzyme. If it is less than 3 parts by weight, it is insufficient to help dissolve the dye, and if it exceeds 95 parts by weight, it does not significantly increase the dissolution of the dye.
有機酸は、前記ジオール系化合物やソルビン酸カリウム
の防臭効果を発揮させやすいｐＨ範囲を調整するために
用いるが、トイレ汚物のアンモニア悪臭を抑制するため
にも用いられるリンゴ酸、シュウ酸、クエン酸などが好
適である。酵素１重量部に対して、５〜４０重量部添加
する。即ち、５重量部未満では、悪臭抑制の効果に不足
であり、４０重量部を超えると、酸性が強くなり、鋼材
などの腐食など悪影響を及ぼす。 以上のような配合に
することにより、アンモニア悪臭の抑制効果が得られ、
ジオール系化合物や、ソルビン酸カリウムなどの防腐剤
が、その効果を充分に発揮できるように、トイレ汚水の
ｐＨを低減させることができる。Organic acids are used to adjust the pH range in which the diol compounds and potassium sorbate exhibit their deodorizing effects, but malic acid, oxalic acid, and citric acid are also used to suppress the ammonia odor of toilet filth. etc. are suitable. Add 5 to 40 parts by weight per 1 part by weight of enzyme. That is, if it is less than 5 parts by weight, the effect of suppressing bad odor is insufficient, and if it exceeds 40 parts by weight, the acidity becomes strong and adverse effects such as corrosion of steel materials etc. occur. By making the above combination, the effect of suppressing ammonia odor can be obtained,
The pH of toilet wastewater can be reduced so that diol compounds and preservatives such as potassium sorbate can fully exhibit their effects.
以上の組成配合物を混合し、水溶液として、トイレ汚物
と混合する。先ず、ジオール系化合物やソルビン酸カリ
ウムが防腐効果を示して、悪臭の生成を抑制し、青色色
素がクリーン感を付与する。The above composition formulation is mixed and mixed with toilet waste as an aqueous solution. First, diol compounds and potassium sorbate have a preservative effect, suppressing the formation of bad odors, and the blue pigment gives a clean feel.
同時に、酵素がトイレ汚物中のデンプン質に作用して、
糖化し、非悪臭物質にするとともに、有機酸がトイレ汚
水のｐＨを低下させ、防腐剤の作用を円滑にする。At the same time, enzymes act on starch in toilet waste,
It is saccharified and becomes a non-malodorous substance, and the organic acid lowers the pH of toilet sewage, facilitating the action of preservatives.
このように、本発明の構成物質は、互いに補助し、総合
的に見て、バランスのとれた消臭作用を成す。As described above, the constituent substances of the present invention mutually assist each other and, taken as a whole, provide a well-balanced deodorizing effect.
このような配合により、また、上記のような構成の本発
明の循環式トイレ汚物処理剤が得られ、トイレ汚物に対
して、混入することにより使用する。By such a combination, the circulating toilet filth treatment agent of the present invention having the above-mentioned structure can be obtained, and is used by mixing it into toilet filth.
次に、本発明の循環式トイレ汚物処理剤について具体例
により説明するが、本発明は、次の実施例に限定される
ものではない。Next, the circulating toilet filth treatment agent of the present invention will be explained using specific examples, but the present invention is not limited to the following examples.
［実施例］
［１１Ｍｆ）＊＊＊
例１．α−アミラーゼ０．５重量部、グルコアミラーゼ
０．５重量部、２−ブロモ−２−二トロー１，３−プロ
パンジオール５重量部、青色１号０．４重量部、ソルビ
ン酸カリウム９０重量部、芒硝１０重量部、有機酸２０
重量部を粉砕混合した。[Example] [11Mf)*** Example 1. α-amylase 0.5 parts by weight, glucoamylase 0.5 parts by weight, 2-bromo-2-nitro-1,3-propanediol 5 parts by weight, Blue No. 1 0.4 parts by weight, potassium sorbate 90 parts by weight , 10 parts by weight of Glauber's salt, 20 parts by weight of organic acid
Parts by weight were ground and mixed.
例２．ａ−アミラーゼ０．５重量部、グルコアミラーゼ
０．５重量部、３−メトキシ−１，２−プロパンジオー
ル１０重量部、青色１号０．４重量部、ソルビン酸カリ
ウム９０重量部、芒硝１０重量部、有機酸２０重量部を
粉砕混合した。Example 2. 0.5 parts by weight of a-amylase, 0.5 parts by weight of glucoamylase, 10 parts by weight of 3-methoxy-1,2-propanediol, 0.4 parts by weight of Blue No. 1, 90 parts by weight of potassium sorbate, 10 parts by weight of Glauber's salt 1 part and 20 parts by weight of an organic acid were pulverized and mixed.
［１止メ１］
上記で得られた循環式トイレ汚物処理剤について、次の
試験を行なった。[1 Stop 1] The following tests were conducted on the circulating toilet filth treatment agent obtained above.
即ち、電車のトイレを想定し、最初の張り込み水１００
１量部に対して、本発明の循環式トイレ汚物処理剤の例
１を、０．００１２６４重量部、又は、例２の処理剤を
、０．００１３１４重量部添加して使用した。In other words, assuming a train toilet, the initial water supply is 100 ml.
To 1 part by weight, 0.001264 parts by weight of Example 1 of the circulating toilet filth treatment agent of the present invention or 0.001314 parts by weight of the treatment agent of Example 2 were used.
電車トイレを４日間使用することを想定して、ヒトの尿
と大便を１９＝１の重量割合で混合した汚水を５０重量
部づつ１回／日、合計２００重量部添加し、その間に、
夏場（４０℃、３ ｏｔ）と冬場（５℃）の温度を想定
して、その温度で振盪し、試験した。更に、開始時の張
り込み水に、ＮａＯＨを加えてｐＨを９．０に高めた場
合を設定して試験をした。Assuming that the train toilet will be used for 4 days, 50 parts by weight of sewage mixed with human urine and feces at a weight ratio of 19 = 1 is added once a day for a total of 200 parts by weight, and during that time,
The samples were shaken and tested at temperatures assumed to be summer (40° C., 3 ot) and winter (5° C.). Furthermore, a test was conducted in which NaOH was added to the initial charging water to raise the pH to 9.0.
１日毎に色相（官能試験）と臭気（検知管法）について
、観察した。結果を第１表及び第２表に示す。The hue (sensory test) and odor (detection tube method) were observed every day. The results are shown in Tables 1 and 2.
第１表、第２表には、本発明のトイレ処理剤の効果を市
販品Ａ及び従来使用の次亜塩素酸カルシウムの例と比較
して、示しである。Tables 1 and 2 show the effectiveness of the toilet treatment agent of the present invention in comparison with commercially available product A and conventionally used calcium hypochlorite.
１ 試験結果 注：の：ｅｌｍである。■：色相が買色昧である。1 Test results Note: of: elm. ■: The hue is bright.
第１表、第２表から、本発明のトイレ処理剤は、クリー
ン感も有り、色相、臭気に於て、従来技術に比較して、
大幅にすぐれていることが分かる。From Tables 1 and 2, it can be seen that the toilet treatment agent of the present invention has a clean feeling, and has a higher hue and odor compared to the conventional technology.
It can be seen that it is significantly superior.
また、第１表、第２表で得られた４種の汚水を、東京部
下水道局から入手した活性汚泥を用いて、該汚水１００
重量部、水１００重量部、該活性汚泥１００重量部を加
え、エアレーションを３０分間行なった後に、底にマジ
ックインキでＸ印を付けた１１のメスシリンダーに試験
液の上清液を入れ、各上滑液の透明度を比較したところ
、本発明のトイレ処理剤を使用したものが、最も透明度
が高く、他の２例は、それより透明度が悪がった。In addition, the four types of sewage obtained in Tables 1 and 2 were treated using activated sludge obtained from the Tokyo Department of Sewerage Bureau.
After adding parts by weight, 100 parts by weight of water, and 100 parts by weight of the activated sludge, and performing aeration for 30 minutes, the supernatant liquid of the test solution was poured into 11 graduated cylinders marked with an X on the bottom with marker ink, and each When the transparency of the synovial fluid was compared, the one using the toilet treatment agent of the present invention had the highest transparency, and the other two cases had worse transparency.
従って、本発明の循環式汚物処理剤は、活性汚泥の浄化
縫方をも向上させたものと推定される。Therefore, it is presumed that the circulating filth treatment agent of the present invention also improves the method of purifying activated sludge.
この結果から分かるように、本発明の循環式トイレ汚物
処理剤では、従来品に比較して、ｐＨ変化でも、また、
温度の高低の変化が激しくても、消臭効果が有効で同時
に、クリーンな汚物処理を可能にするものである。As can be seen from these results, the circulating toilet filth treatment agent of the present invention is more effective against pH changes than conventional products.
Even if there are drastic changes in temperature, the deodorizing effect is effective and at the same time, clean waste disposal is possible.
［発明の効果］
本発明の循環式トイレ汚物処理剤は、次のような消臭効
果を奏することにより、トイレ汚物処理剤として、著し
く有効なものである。[Effects of the Invention] The circulating toilet filth treatment agent of the present invention exhibits the following deodorizing effect, making it extremely effective as a toilet filth treatment agent.
即ち、
第１に、好適な防腐剤を用いるために、有機酸や酵素の
効果を有効に、利用できるため、温度変化、即ち夏場の
高温（４０℃等）、冬場の低温（５℃等）などの車両ト
イレで予想される悪条件でも、消臭効果が充分に発揮さ
れ、従来品に比べて、有用な汚物処理剤が提供された。Firstly, by using a suitable preservative, the effects of organic acids and enzymes can be effectively utilized, so temperature changes, i.e. high temperatures in summer (40 degrees Celsius etc.) and low temperatures in winter (5 degrees Celsius etc.) The deodorizing effect was fully demonstrated even under the adverse conditions expected in vehicle toilets, and the product provided a more useful filth treatment agent than conventional products.
第２に、万が−に、トイレ中に高アルカリ性物質が投入
されても、消臭効果に変化が起きず、良好な消臭効果を
維持することのできる汚物処理剤が提供された。Second, a filth treatment agent has been provided which can maintain a good deodorizing effect without causing any change in deodorizing effect even if a highly alkaline substance is injected into the toilet.
第３に、従って、温度変化、ｐＨ変化が起こり得る車両
トイレなどに極めて実用的であり、その後の汚物の活性
汚泥添加処理時の浄化作用に大きく貢献でき、更に、加
えて、排水処理工程後の排水もクリーンなので、本発明
のトイレ汚物処理剤は、清浄化が容易であり、従って、
産業上極めて有意義である。Thirdly, it is extremely practical for vehicle toilets where temperature and pH changes can occur, and can greatly contribute to the purification effect during the subsequent treatment of sewage with the addition of activated sludge. The toilet filth treatment agent of the present invention is easy to clean, and the wastewater of the toilet is also clean.
It is extremely significant industrially.
特許出願人 三菱鉱業セメント株式会社代理人 弁
理士 倉 持 裕Patent applicant: Mitsubishi Mining and Cement Co., Ltd. Representative: Hiroshi Kuramochi, patent attorney
Claims (1)
ム、ぼう硝、有機酸から本質的になることを特徴とする
循環式トイレ汚物処理剤。 ２、酵素１重量部に対して、 ジオール系化合物３〜２０重量部、 色素０．２〜４重量部、 ソルビン酸カリウム３〜９５重量部、 ぼう硝３〜９５重量部、 有機酸５〜４０重量部 から本質的になることを特徴とする請求項１に記載の循
環式トイレ汚物処理剤。[Scope of Claims] 1. A circulating toilet sewage treatment agent characterized by essentially consisting of an enzyme, a diol compound, a pigment, potassium sorbate, sulfur sulfate, and an organic acid. 2. For 1 part by weight of enzyme: 3 to 20 parts by weight of diol compound, 0.2 to 4 parts by weight of dye, 3 to 95 parts by weight of potassium sorbate, 3 to 95 parts by weight of sulfur sulfate, 5 to 40 parts by weight of organic acid. The circulating toilet waste treatment agent according to claim 1, characterized in that it consists essentially of parts by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2157676A JPH0451958A (en) | 1990-06-18 | 1990-06-18 | Treating agent for circulation type toilet filth |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2157676A JPH0451958A (en) | 1990-06-18 | 1990-06-18 | Treating agent for circulation type toilet filth |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0451958A true JPH0451958A (en) | 1992-02-20 |
Family
ID=15654949
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2157676A Pending JPH0451958A (en) | 1990-06-18 | 1990-06-18 | Treating agent for circulation type toilet filth |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0451958A (en) |
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