JPH0393189A - Manufacture of thin film el element - Google Patents

Manufacture of thin film el element

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Publication number
JPH0393189A
JPH0393189A JP1228552A JP22855289A JPH0393189A JP H0393189 A JPH0393189 A JP H0393189A JP 1228552 A JP1228552 A JP 1228552A JP 22855289 A JP22855289 A JP 22855289A JP H0393189 A JPH0393189 A JP H0393189A
Authority
JP
Japan
Prior art keywords
thin film
layer
emitter layer
manufacturing
dielectric layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP1228552A
Other languages
Japanese (ja)
Inventor
Shinichiro Hayashi
慎一郎 林
Atsuya Yamamoto
敦也 山本
Koji Senda
耕司 千田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Panasonic Holdings Corp
Original Assignee
Matsushita Electronics Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Matsushita Electronics Corp filed Critical Matsushita Electronics Corp
Priority to JP1228552A priority Critical patent/JPH0393189A/en
Publication of JPH0393189A publication Critical patent/JPH0393189A/en
Pending legal-status Critical Current

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Abstract

PURPOSE:To obtain a high-intensity thin film EL element by forming an EL emitter layer, then heat-treating the EL emitter layer. CONSTITUTION:Stripe-shaped transparent electrodes 12 are formed on a translucent substrate 11, the first dielectric layer 13 made of Ta2O5 is formed on them, then an EL emitter layer 14 made of SrS:Ce and Sm is formed on it. A substrate is continuously heated without breaking vacuum after the EL emitter layer 14 is formed, then the EL emitter layer 14 is heat-treated for two hr or below at the substrate temperature 400-600 deg.C to improve the crystallization of the EL emitter layer 14. The second dielectric layer 15 made of Al2O3 is formed, finally a metal conducting layer made of Al-Si or the like is formed, and stripe-shaped back electrodes 16 are formed so as to intersect with transparent electrodes 12. A high-intensity thin film EL element is obtained.

Description

【発明の詳細な説明】 (3) (2) 産業上の利用分野 本発明は薄膜EL素子の製造方法に関するものである。[Detailed description of the invention] (3) (2) Industrial applications The present invention relates to a method for manufacturing a thin film EL device.

従来の技術 薄膜EL素子は自己発光素子であり、また、薄型の面状
発光素子である等の優れた利点を生かして、モノクロデ
ィスプレイパネルの分野を中心に応用が進んでいる。
2. Description of the Related Art Thin film EL devices are self-luminous devices, and their applications are progressing mainly in the field of monochrome display panels, taking advantage of their excellent advantages such as being thin planar light emitting devices.

ところが実用レベルに達しているのは、EL発光体層に
ZnS:MnやZnS : Tbを用いたような、Zn
SをEL発光母体とするものだけである。
However, Zn materials such as those using ZnS:Mn or ZnS:Tb for the EL light emitting layer have reached a practical level.
It is only one in which S is used as an EL emission matrix.

このため、他のEL発光母体を用いる研究開発が活発に
行なわれ、その結果、CaSやSrSをEL発光母体に
用いたもの、例えば、CaS : Eu.SrS:Ce
等をEL発光体層に用いたもので、比較的高輝度のEL
発光が得られた。
For this reason, research and development using other EL luminescent materials has been actively conducted, and as a result, products using CaS and SrS as EL luminescent materials, such as CaS:Eu. SrS:Ce
etc. are used in the EL light emitting layer, and it is a relatively high-brightness EL
Luminescence was obtained.

以下、図面を参照しながら、上述したようなCaSやS
rSをEL発光母体に用いた従来の薄膜EL素子の製造
方法について説明する。
Hereinafter, with reference to the drawings, the CaS and S
A method for manufacturing a conventional thin film EL device using rS as an EL light emitting matrix will be described.

第4図は従来の製造方法による薄膜EL素子の一部断面
図を示し、第5図は第4図の薄膜EL素子のEL発光体
層のX線回折パターンを示したものである。
FIG. 4 shows a partial cross-sectional view of a thin film EL device produced by a conventional manufacturing method, and FIG. 5 shows an X-ray diffraction pattern of the EL light emitter layer of the thin film EL device of FIG.

第4図において、41は透光性基板、42は透明電極,
43は第一誘電体層、44はEL発光体層、45は第二
誘電体層、46は背面電極である。
In FIG. 4, 41 is a transparent substrate, 42 is a transparent electrode,
43 is a first dielectric layer, 44 is an EL light emitter layer, 45 is a second dielectric layer, and 46 is a back electrode.

第4図に示すように、まず、ガラスあるいは石英等から
なる透光性基板41上に酸化インジウム錫( Indi
um Tin Oxide :以下、ITOと記す。)
等の透明導電層を形成した後に、フォトリソグラフィー
によりストライプ状等のバターニングされた透明電極4
2を形戒する。
As shown in FIG. 4, first, indium tin oxide (Indi
um Tin Oxide: Hereinafter referred to as ITO. )
After forming a transparent conductive layer such as, a transparent electrode 4 patterned into a stripe shape or the like by photolithography.
2 is a form of precept.

次に、透光性基板41上に、Si02等からなる第一誘
電体層43を高周波マグネトロンスパッタ装置(以下、
RFスパッタ装置と記す。)で形成し、そして、CaS
 : EuあるいはS rS : Ce等からなるEL
発光体層44を電子線蒸着装置〈以下、EB蒸着装置と
記す。)で基板温度500℃程度で形成し、さらに、A
t tos等からなる第二誘電体層45をRFスパッタ
装置で形成する。
Next, a first dielectric layer 43 made of Si02 or the like is deposited on the transparent substrate 41 using a high frequency magnetron sputtering device (hereinafter referred to as
It will be referred to as an RF sputtering device. ), and CaS
: Eu or S rS : EL consisting of Ce, etc.
The light emitting layer 44 is formed using an electron beam evaporation device (hereinafter referred to as an EB evaporation device). ) at a substrate temperature of about 500°C, and then
A second dielectric layer 45 made of t tos or the like is formed using an RF sputtering device.

最後に、透光性基板41上に、At等の金属導電層を形
成し、フォトリソグラフィーにより、透明電極42と互
いに交差するようにストライブ状等のパターニングされ
た背面電極46を形戒する。
Finally, a metal conductive layer such as At is formed on the transparent substrate 41, and a back electrode 46 patterned in a stripe shape or the like so as to intersect with the transparent electrode 42 is formed by photolithography.

以上のようにして、CaSやSrSをEL発光母体に用
いた薄膜EL素子が製造される。
In the manner described above, a thin film EL element using CaS or SrS as an EL light emitting matrix is manufactured.

発明が解決しようとする課題 しかしながら上記のような製造方法では、EL発光体層
の結晶性が悪かった。すなわち、EL発光体層が十分に
柱状結晶化しておらず、第5図に示すX線回折パターン
から明らかなように、高輝度を示す(200)あるいは
(220)への配向が十分でなかった。
Problems to be Solved by the Invention However, in the above manufacturing method, the crystallinity of the EL light emitting layer was poor. That is, the EL emitter layer was not sufficiently columnar crystallized, and as is clear from the X-ray diffraction pattern shown in FIG. 5, the orientation toward (200) or (220), which exhibits high brightness, was not sufficient. .

その結果として、製造された薄膜EL素子が低輝度にな
るという欠点を有していた。
As a result, the produced thin film EL device had the disadvantage of low brightness.

本発明は上記欠点に鑑み、EL発光母体がCaSあるい
はSrSのうち少なくとも1種類を含むEL発光体層の
結晶性を向上させ、輝度の高い、信頼性の高い薄膜EL
素子の製造方法を提供するものである。
In view of the above drawbacks, the present invention improves the crystallinity of an EL light emitting layer whose EL light emitting matrix contains at least one type of CaS or SrS, thereby producing a thin film EL with high brightness and high reliability.
A method for manufacturing an element is provided.

課題を解決するための手段 上記課題を解決するために、本発明の薄膜EL素子の製
造方法は、透光性基板上に透明電極,第一誘電体層.E
L発光母体がCaSあるいはSrSのうち少なくとも1
種類を含むEL発光体層,第二誘電体層,背面電極が順
次積層され形成される薄膜EL素子の製造方法において
、前記EL発光体層の形成に引き続いて真空をやぶらず
に基板力u熱を行なうことにり、前記EL発光体層の熱
処理を400℃〜600℃で2時間以下で行なう工程を
含むことから構成されている。
Means for Solving the Problems In order to solve the above problems, the method for manufacturing a thin film EL device of the present invention includes a transparent electrode, a first dielectric layer, and the like on a light-transmitting substrate. E
L-emitting host is at least one of CaS or SrS
In a method for manufacturing a thin film EL device in which an EL light emitting layer, a second dielectric layer, and a back electrode are sequentially laminated, the substrate is heated by applying heat to the substrate without breaking the vacuum, following the formation of the EL light emitting layer. The method includes a step of heat-treating the EL light emitting layer at 400° C. to 600° C. for 2 hours or less.

作用 この構成によって、EL発光体層を熱処理効果により十
分に柱状結晶化し、(200)あるいは(220)への
配向を相対的に強くすることができる。
Effect: With this configuration, the EL light emitter layer can be sufficiently columnar crystallized by the heat treatment effect, and the (200) or (220) orientation can be relatively strengthened.

その結果、高輝度、かつ信頼性の高い薄膜EL素子が製
造できる。
As a result, a thin film EL element with high brightness and high reliability can be manufactured.

実施例 本発明の一実施例について、図面を用いて簡単に説明す
る。第2図は本発明の薄膜EL素子の製造方法により製
作した薄1!IIEL素子の平面図を示し、第1図は第
2図のA−Bにおける断面の製造工程を示す図である。
Embodiment An embodiment of the present invention will be briefly described with reference to the drawings. FIG. 2 shows a thin film EL device manufactured by the method of manufacturing a thin film EL device of the present invention. A plan view of the IIEL element is shown, and FIG. 1 is a cross-sectional view taken along line AB in FIG. 2, showing the manufacturing process.

第3図は本発明の薄膜EL素子の製造方法により製作し
た薄膜EL素子のEL発光体層のX線回折スペクトルで
ある。
FIG. 3 is an X-ray diffraction spectrum of the EL emitter layer of a thin film EL device manufactured by the method for manufacturing a thin film EL device of the present invention.

第1図,第2図において、11は透光性基板、12は透
明電極、13は第一誘電体層、14はEL発光体層、1
5は第二誘電体層、16は背面電極である。
1 and 2, 11 is a transparent substrate, 12 is a transparent electrode, 13 is a first dielectric layer, 14 is an EL light emitting layer, 1
5 is a second dielectric layer, and 16 is a back electrode.

第1図に示すように、まず、ガラスあるいは石英等から
なる透光性基板ll上に、直流バイアススパッタ装置(
以下、DCスパッタ装置と記す。)により厚さ0.1μ
m程度のITO等の透明導電層を形成した後、フォトレ
ジストをマスクとしてウェットエッチング装置により、
ストライブ状に透明電極12を形威する(第1図(a)
)。
As shown in FIG. 1, first, a DC bias sputtering device (
Hereinafter, this will be referred to as a DC sputtering device. ), the thickness is 0.1μ
After forming a transparent conductive layer such as ITO with a thickness of about 100 yen, it is etched using a wet etching device using a photoresist as a mask.
The transparent electrode 12 is shaped like a stripe (Fig. 1(a)).
).

次に、透光性基板11上にRFスパッタ装置より厚さ0
.2μm程度のTa205からなる第一誘電体層13を
形成した〈第1図(b)〉上に、EB蒸着装置により基
板温度500℃で厚さlμm程度のS rS : Ce
+ SmからなるEL発光体層14を形成する(第1図
(C))。このときイオウの再蒸発を補うためにイオウ
の蒸発を同時に別のるつぼ等から行なう方が望ましい。
Next, a film with a thickness of 0 is deposited on the transparent substrate 11 using an RF sputtering device.
.. On the first dielectric layer 13 made of Ta205 with a thickness of about 2 μm (FIG. 1(b)), SrS:Ce with a thickness of about 1 μm is deposited using an EB evaporation apparatus at a substrate temperature of 500°C.
An EL light emitting layer 14 made of +Sm is formed (FIG. 1(C)). At this time, it is preferable to simultaneously evaporate sulfur from another crucible or the like in order to compensate for the re-evaporation of sulfur.

ここで、EL発光体層14の結晶性を向上させるために
熱処理をする。すなわち、EL発光体層l4の形成後、
真空をやぶらずに基板加熱を継続し、基板温度500℃
で1時間EL発光体層14を熱処理する。
Here, heat treatment is performed to improve the crystallinity of the EL light emitting layer 14. That is, after forming the EL light emitter layer l4,
Continue heating the substrate without breaking the vacuum, and the substrate temperature reaches 500℃.
The EL light emitter layer 14 is heat-treated for one hour.

そして、RFスパッタ装置により厚さ0.2μm程度の
Ae 20.からなる第二誘電体層15を形成する(第
1図(イ))。
Then, Ae 20. A second dielectric layer 15 is formed (FIG. 1(a)).

最後に、DCスパッタ装置により厚さ0.1μm程度の
Ae−Si等からなる金属導電層を形威し、フォトリソ
グラフィーにより、透明電極12と互いに交差するよう
にドライエッチング装置により、ストライブ状に背面電
極16を形成する(第1図(e))。
Finally, a metal conductive layer made of Ae-Si or the like is formed with a thickness of about 0.1 μm using a DC sputtering device, and is formed into strips by photolithography using a dry etching device so as to cross each other with the transparent electrode 12. A back electrode 16 is formed (FIG. 1(e)).

以上のようにして、第2図に示すような、薄膜EL素子
が製造される。
In the manner described above, a thin film EL element as shown in FIG. 2 is manufactured.

以上のように本実施例によれば、EL発光体層形威後、
基板加熱を継続することにより、製作方法も簡単にEL
発光体層の結晶形を向上させることができる。
As described above, according to this embodiment, after the EL luminescent layer shape,
By continuing to heat the substrate, the manufacturing method is simple.
The crystal shape of the light emitter layer can be improved.

なお、本実施例においては基板偏度制御の簡便性を考慮
して、EL発光体層の形成時基板温度と熱処理温度とを
同程度の500℃程度にしたが、特別に限定されたもの
ではない。熱処理温度は400℃〜600℃が良い。す
なわち、熱処理温度が低すぎるとEL発光体層の結晶性
を向上させる効果がなくなり、また、熱処理温度が高す
ぎると堆積層が剥離する。さらに、熱処理時間について
も同様に、熱処理時間が短かいと、結晶性向上の効果が
少なくなり、一方、熱処理時間を長くしても結晶性向上
効果が飽和したり、堆積層が剥離したりする。熱処理時
間は2時間以下が良い。
Note that in this example, the substrate temperature and the heat treatment temperature during the formation of the EL light emitting layer were set at about the same level, about 500°C, in consideration of the ease of controlling the substrate bias, but there is no particular limitation. do not have. The heat treatment temperature is preferably 400°C to 600°C. That is, if the heat treatment temperature is too low, the effect of improving the crystallinity of the EL luminescent layer is lost, and if the heat treatment temperature is too high, the deposited layer will peel off. Furthermore, regarding the heat treatment time, if the heat treatment time is short, the effect of improving crystallinity will be reduced, while if the heat treatment time is increased, the effect of improving crystallinity will be saturated or the deposited layer will peel off. . The heat treatment time is preferably 2 hours or less.

また、本実施例ではEL発光体層としてSrS:Ce,
Smを用いたが、EL発光体層のEL発光母体がCaS
あるいはSrSのうち少なくともlIMを含むものであ
れば何でもよい。すなわち、付活材料にも限定されるも
のでもなく、CaS :EuでもSrS:SmでもCa
,(S r+−.S : P r(0<xx<1)でも
よい。
In addition, in this example, SrS:Ce,
Although Sm was used, the EL luminescent matrix of the EL luminescent layer was CaS.
Alternatively, any SrS containing at least lIM may be used. In other words, it is not limited to the activation material, and may be CaS:Eu, SrS:Sm or Ca.
, (S r+-.S : P r (0<xx<1).

さらに、本実施例では誘電体層としてTa205とAe
 203とを用いたが、特別に限定されるものではなく
、S i02,S i3N4,S iON,Ae N.
PZTなどでもよいことは言うまでもない。
Furthermore, in this example, Ta205 and Ae are used as the dielectric layer.
203 was used, but the invention is not particularly limited to S i02, S i3N4, S iON, Ae N.203.
Needless to say, PZT or the like may also be used.

発明の効果 以上のように本発明は、透光性基板上に、透明電極、第
一誘電体層、EL発光母体がCaSあるいはSrSのう
ち少なくとも1種類を含むEL発光体層、第二誘電体層
、背面電極が順次積層され形成される薄膜EL素子の製
造方法において、前記EL発光体層の形成に引き続いて
、前記発光体層の熱処理を行なう工程を含むことからな
る構成により、前紀EL発光体層を十分に柱状結晶化し
、(200)あるいは(220)への配向を相対的に強
くすることができる。
Effects of the Invention As described above, the present invention provides a transparent electrode, a first dielectric layer, an EL luminescent layer containing at least one of CaS or SrS as an EL luminescent matrix, and a second dielectric material on a transparent substrate. In the method for manufacturing a thin film EL device in which a layer and a back electrode are sequentially laminated, the method includes a step of heat-treating the light emitting layer subsequent to the formation of the EL light emitting layer. The light emitting layer can be sufficiently columnar crystallized to make the (200) or (220) orientation relatively strong.

その結果、高輝度の薄膜EL素子が製造でき、なおかつ
、製作方法も簡単であり、その実用的効果は大なるもの
である。
As a result, a thin film EL element with high brightness can be manufactured, and the manufacturing method is simple, and its practical effects are great.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本発明の一実施例における薄膜EL素子の製造
方法の製造工程を示す図、第2図は本発明の一実施例に
より製作された薄膜EL素子の平面図、第3図は本発明
の一実施例により製作された薄膜EL素子のEL発光体
層のX線回折スペクトル図、第4図は従来の製造方法に
よる薄膜EL素子の一部断面図、第5図は従来の製造方
法による薄膜EL素子のEL発光体層のX線回折スペク
ト図である。 11・・・・・・透光性基板、12・・・・・・透明電
極、13・・・・・・第一誘電体層、14・・・・・・
EL発光体層、15・・・・・・第二誘電体層、16・
・・・・・背面電極。
FIG. 1 is a diagram showing the manufacturing process of a method for manufacturing a thin film EL device according to an embodiment of the present invention, FIG. 2 is a plan view of a thin film EL device manufactured according to an embodiment of the present invention, and FIG. An X-ray diffraction spectrum diagram of the EL emitter layer of a thin film EL device manufactured according to an embodiment of the invention, FIG. 4 is a partial cross-sectional view of a thin film EL device manufactured by a conventional manufacturing method, and FIG. 5 is a diagram of a conventional manufacturing method. FIG. 2 is an X-ray diffraction spectrum diagram of an EL emitter layer of a thin film EL device according to the present invention. 11... Transparent substrate, 12... Transparent electrode, 13... First dielectric layer, 14...
EL light emitter layer, 15... second dielectric layer, 16.
...Back electrode.

Claims (3)

【特許請求の範囲】[Claims] (1)透光性基板上に、透明電極,第一誘電体層,EL
発光体層,第二誘電体層,背面電極が順次積層され形成
される薄膜EL素子の製造方法において、前記EL発光
体層の形成に引き続いて、前記EL発光体層の熱処理を
行なう工程を含むことを特徴とする薄膜EL素子の製造
方法。
(1) Transparent electrode, first dielectric layer, EL on a transparent substrate
A method for manufacturing a thin film EL device in which a light emitter layer, a second dielectric layer, and a back electrode are sequentially laminated, including the step of heat-treating the EL light emitter layer subsequent to the formation of the EL light emitter layer. A method for manufacturing a thin film EL device, characterized in that:
(2)EL発光体層のEL発光母体がCaSあるいはS
rSのうち少なくとも1種類を含むことを特徴とする特
許請求の範囲第1項記載の薄膜EL素子の製造方法。
(2) The EL luminescent matrix of the EL luminescent layer is CaS or S
2. The method for manufacturing a thin film EL device according to claim 1, wherein the method includes at least one type of rS.
(3)EL発光体層の熱処理の温度が400℃〜600
℃で、前記熱処理の時間が2時間以下であることを特徴
とする特許請求の範囲第1項記載の薄膜EL素子の製造
方法。
(3) The temperature of heat treatment of the EL light emitter layer is 400°C to 600°C
2. The method of manufacturing a thin film EL device according to claim 1, wherein the heat treatment time is 2 hours or less at .degree.
JP1228552A 1989-09-04 1989-09-04 Manufacture of thin film el element Pending JPH0393189A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1228552A JPH0393189A (en) 1989-09-04 1989-09-04 Manufacture of thin film el element

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1228552A JPH0393189A (en) 1989-09-04 1989-09-04 Manufacture of thin film el element

Publications (1)

Publication Number Publication Date
JPH0393189A true JPH0393189A (en) 1991-04-18

Family

ID=16878162

Family Applications (1)

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Country Status (1)

Country Link
JP (1) JPH0393189A (en)

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