JPH02135141A - Adsorptive sheet and air cleaning filter - Google Patents

Adsorptive sheet and air cleaning filter

Info

Publication number
JPH02135141A
JPH02135141A JP63288096A JP28809688A JPH02135141A JP H02135141 A JPH02135141 A JP H02135141A JP 63288096 A JP63288096 A JP 63288096A JP 28809688 A JP28809688 A JP 28809688A JP H02135141 A JPH02135141 A JP H02135141A
Authority
JP
Japan
Prior art keywords
sheet
activated carbon
fibers
adsorptive
fiber
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP63288096A
Other languages
Japanese (ja)
Other versions
JP2679714B2 (en
Inventor
Hiroshi Shimizu
博 清水
Nobuo Ishizaki
石崎 信男
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toyobo Co Ltd
Original Assignee
Toyobo Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toyobo Co Ltd filed Critical Toyobo Co Ltd
Priority to JP63288096A priority Critical patent/JP2679714B2/en
Publication of JPH02135141A publication Critical patent/JPH02135141A/en
Application granted granted Critical
Publication of JP2679714B2 publication Critical patent/JP2679714B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Abstract

PURPOSE:To obtain the title sheet having excellent adsorptivity and good air permeability by making the sheet from a mixture of fine-particle activated carbon having specified mean particle diameter, a supporting fiber having a specified outer surface area, and a water-swollen br thermally fusible fiber in a specified ratio. CONSTITUTION:The adsorptive sheet is made from a mixture contg. 10-80 pts.wt. of the fine-particle activated carbon having 60-150mum mean particle diameter, 5-50 pts.wt. of the supporting fiber having <=1m<2>/g outer surface area, and 1-30 pts.wt. of the water-swollen or thermally fusible fiber. An air-permeable reinforcing sheet is laminated on the adsorptive sheet, and the laminated sheet is used as an air cleaning filter. By this method, the adsorptive sheet having good air permeability, excellent adsorptivity to malodorous gases, and excellent workability in folding, etc., is obtained, and used as the adsorptive material for in air cleaning filter.

Description

【発明の詳細な説明】 [産業上の利用分野] 本発明は、吸着素子としての吸着用シート、および該吸
着シートを構成要素とする空気浄化用フィルターに関す
るものである。
DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to an adsorption sheet as an adsorption element, and an air purification filter having the adsorption sheet as a component.

[従来の技術] 活性炭はエーロゾルや溶液中の溶質に対して強力な吸着
能を示すため、気体や液体の浄化或は脱臭等に利用され
る。活性炭を空気浄化用フィルターに適用する技術の1
つとして、シート状に成形した活性炭に、浄化したい空
気を直交方向に通気させる方法がある。しかしながら活
性炭のうち吸着能力の高い微粒子状活性炭は、それ自体
では濾J1膜として成形することが容易でなく、仮に何
らかの担体を用いて濾過膜を形成することができたとし
ても担体から簡単に剥離して流失してしまうという問題
がある。こうしたことから上記微粒子状活性炭を空気浄
化用フィルターの素材として有効に利用できる技術の開
発が望まれている。
[Prior Art] Activated carbon exhibits strong adsorption ability for solutes in aerosols and solutions, and is therefore used for purification or deodorization of gases and liquids. One of the technologies to apply activated carbon to air purification filters
One method is to allow the air to be purified to pass through the activated carbon sheet in a perpendicular direction. However, among activated carbons, fine particulate activated carbon, which has a high adsorption capacity, is not easy to form into a filtration membrane by itself, and even if it were possible to form a filtration membrane using some kind of carrier, it would easily peel off from the carrier. There is a problem that it gets washed away. For these reasons, it is desired to develop a technology that can effectively utilize the above-mentioned particulate activated carbon as a material for air purifying filters.

[発明が解決しようとする課題] 微粒子状活性炭を空気浄化用フィルターの素材として有
効に利用する技術の一環として、例えば微粒子状活性炭
を接着剤やフィブリル化繊維で固定する技術も提案され
ている(特開昭55−70342号、特公昭56−49
608号等)。
[Problems to be Solved by the Invention] As part of the technology to effectively utilize particulate activated carbon as a material for air purifying filters, for example, a technology has been proposed in which particulate activated carbon is fixed with an adhesive or fibrillated fiber ( Japanese Patent Publication No. 55-70342, Special Publication No. 56-49
608 etc.).

しかしながらこれらの技術では通気抵抗が高くなリ、空
気浄化用フィルターの素材としては適用し難いという問
題がある。また微粒子状活性炭を多孔Xなフオーム材に
添着させたシートや、微細繊維よりなるウェッブに分散
、固着させたシート等も提案されている(例えば特公昭
52−4934号)、シかしながらこの様な技術におい
ても、吸着容量、活性炭の脱離し易さ等の点で依然とし
て満足し得るものではなかった。
However, these techniques have a problem in that they have high ventilation resistance and are difficult to use as materials for air purification filters. In addition, sheets in which fine particulate activated carbon is attached to a porous foam material, sheets in which fine fibers are dispersed and fixed in a web, etc. have been proposed (for example, Japanese Patent Publication No. 52-4934). Even with various techniques, the adsorption capacity and ease of desorption of activated carbon remain unsatisfactory.

本発明はこの様な事情に鑑みてなされたものであって、
その目的とするところは、通気性が良好で、悪臭ガスに
対する吸着性能にも優れ、且つ一般的特性として要求さ
れる折り曲げ加工等の加工性においても良好な空気浄化
用フィルター、およびこの様な空気浄化用フィルターの
吸着素材として最適な吸着性シートを提案する点にある
The present invention was made in view of these circumstances, and
The aim is to create an air purifying filter that has good breathability, excellent adsorption performance for foul-smelling gases, and also has good workability such as bending, which is generally required. Our goal is to propose an adsorbent sheet that is optimal as an adsorbent material for purification filters.

[課題を解決する為の手段] 本発明に係る吸着性シートとは、 ■平均粒子径が60〜150μmの微粒子状活性炭:1
0〜80重量部 ■外表面積がll12/g以下である支持繊維:5〜5
0重量部 ■水膨潤性繊維または熱溶融性繊維:1〜30重量部 を含む点に要旨を有するものである。
[Means for Solving the Problems] The adsorbent sheet according to the present invention is: ■ Particulate activated carbon with an average particle diameter of 60 to 150 μm: 1
0 to 80 parts by weight ■ Supporting fibers with an external surface area of 112/g or less: 5 to 5
The gist is that it contains 1 to 30 parts by weight of water-swellable fibers or heat-fusible fibers.

またこの吸着性シートと通気性補強シートを積層するこ
とによって最適な空気浄化用フィルターが得られる。
Furthermore, by laminating this adsorbent sheet and the breathable reinforcing sheet, an optimal air purifying filter can be obtained.

[作用] 本発明は上記の如く構成されるが、要は■所定の平均粒
子径の微粒子状活性炭、■外表面積が所定値以下の支持
繊維、■水膨潤性繊維または熱溶融性繊維を、特定の割
合で混抄して形成される吸着性シートについて検討した
ところ、吸着性能に優れ通気性も良好であることを見出
し、更にこの吸着性シートに通気性補強シートを積層し
たものは、上記吸着性シートの特性を損なうことなく加
工性の点でも良好な空気浄化用フィルターとなり得るこ
とを見出し、本発明を完成したものである。
[Function] The present invention is constructed as described above, but the key points are: (1) fine particulate activated carbon with a predetermined average particle diameter, (2) supporting fibers with an outer surface area of not more than a predetermined value, (2) water-swellable fibers or heat-fusible fibers, When we investigated an adsorbent sheet formed by mixing paper in a specific ratio, we found that it had excellent adsorption performance and good air permeability.Furthermore, this adsorbent sheet laminated with an air permeable reinforcing sheet was found to have the same adsorption properties as described above. The present invention was completed based on the discovery that an air purifying filter with good processability can be obtained without impairing the properties of the adhesive sheet.

微粒子状活性炭は、通気性、活性炭の脱落。Particulate activated carbon is breathable and activated carbon does not fall off.

抄紙性等を考慮して、平均粒子径がJ I S$l?[
準ふるい(JIS  Z8801)による値で60〜1
50μmであることが必要であり、より好ましくは10
0〜150μm程度である。即ち平均粒子径が60μ鴨
未満であると通気抵抗が大きくなりすぎ、150μ重を
超えると脱落が生じやすくなるばかりか空気浄化用フィ
ルターとしたときの折り曲げ加工性に劣る。また微粒子
状活性炭と他の繊維(上記■および■)の混抄率は、微
粒子状活性炭が多いほど吸着性は増大するが、一方で吸
着性シートの強度が低下する傾向を示すので好適な範囲
を選定する必要がある。こうした観点からして微粒子状
活性炭の混抄率は90重量部以下にする必要がある。こ
れに対しtoii量部未溝部未満と良好な吸着性が得ら
れない。尚微粒子状活性炭の吸着性能は、悪臭ガスに対
する吸着性を判断する基準として、JIS  K147
4に準拠して測定したときのトルエン吸着量が挙げられ
、この吸着量が2031量%以上のものであるのが好ま
しい。
Considering paper-making properties, etc., the average particle diameter is JIS$1? [
60 to 1 according to semi-sieve (JIS Z8801)
It is necessary that the thickness is 50 μm, more preferably 10 μm.
It is about 0 to 150 μm. That is, if the average particle diameter is less than 60 μm, the ventilation resistance becomes too large, and if it exceeds 150 μm, not only is it easy to fall off, but also the bending processability when used as an air purifying filter is poor. In addition, the mixing ratio of fine particulate activated carbon and other fibers (■ and ■ above) should be set within a suitable range, since the more fine particulate activated carbon there is, the higher the adsorption ability, but on the other hand, the strength of the adsorbent sheet tends to decrease. It is necessary to select. From this point of view, the mixing ratio of particulate activated carbon needs to be 90 parts by weight or less. On the other hand, if the amount is less than the ungrooved portion, good adsorption cannot be obtained. The adsorption performance of fine particulate activated carbon is determined according to JIS K147 as a standard for determining the adsorption ability for malodorous gases.
For example, the amount of toluene adsorbed when measured according to No. 4 is preferably 2031% by weight or more.

支持繊維としては、ポリエステル、ポリアクリロニトリ
ル、ポリアミド、ポリオレフィン等の合成繊維の他、リ
ンター、木綿、麻、木材バイブ。
Supporting fibers include synthetic fibers such as polyester, polyacrylonitrile, polyamide, and polyolefin, as well as linters, cotton, hemp, and wood fibers.

レーヨン、ガラス繊維、セラミック繊維、炭素繊維、活
性炭素繊維等が使用でき、好ましくは木材バルブ、レー
ヨンである。支持繊維はフィブリル化したものであり、
通気性、抄紙性を考慮すればその外表面積は1 m2/
g以下であることが必要である。また支持繊維の混抄割
合は5〜50!を置部とする必要があり、5重量部未満
では抄紙性が悪くなり、50重量部を超えると吸着効果
が不良となる。尚この支持繊維は繊維長が3〜20a+
mの短繊維であることが好ましく、3vn未満では通気
性が悪くなり、20mmを超えると抄紙性が悪くなる。
Rayon, glass fiber, ceramic fiber, carbon fiber, activated carbon fiber, etc. can be used, and wood bulbs and rayon are preferable. The supporting fibers are fibrillated,
Considering air permeability and paper-making properties, its outer surface area is 1 m2/
g or less. Also, the mixing ratio of supporting fibers is 5 to 50! If it is less than 5 parts by weight, paper-making properties will be poor, and if it exceeds 50 parts by weight, the adsorption effect will be poor. In addition, the fiber length of this support fiber is 3 to 20a+
It is preferable that the short fibers are short fibers with a length of 3 vn.If the fiber length is less than 3 vn, air permeability will be poor, and if it exceeds 20 mm, paper-making properties will be poor.

水膨潤性繊維や熱溶融性繊維は混抄時の接着成分(バイ
ンダー)となるものであり、水膨潤性繊維としてはポリ
ビニルアルコール繊維、熱溶融性繊維としてはポリエチ
レン繊維やポリプロピレン−ポリエチレン複合繊維等が
挙げられる。これらの繊維は、繊維長が20mm以下で
あることが好ましい、この繊維の混抄割合は、1〜30
重量部とする必要がある。即ち1重量部未満では接着成
分としての機能を発揮することができ、30重量部を超
えると接着性が相対的に低下する。尚この繊維の好まし
い割合は5〜20重量部重量部品る。
Water-swellable fibers and heat-meltable fibers serve as adhesive components (binder) during paper mixing. Water-swellable fibers include polyvinyl alcohol fibers, and heat-meltable fibers include polyethylene fibers and polypropylene-polyethylene composite fibers. Can be mentioned. These fibers preferably have a fiber length of 20 mm or less, and the mixing ratio of these fibers is 1 to 30 mm.
Must be expressed in parts by weight. That is, if it is less than 1 part by weight, it can function as an adhesive component, and if it exceeds 30 parts by weight, the adhesive property is relatively reduced. The preferred proportion of this fiber is 5 to 20 parts by weight.

上記各要素を混抄することによって吸着性シートが形成
されるが、その他脱臭、防かび等の付随的機能を有する
成分等を含んでいてもよい。尚この吸着性シートの厚み
は、通気性や加工性を考慮すれば、0.5〜1.2 i
s程度のものが好ましい。また坪量は吸着性の点から1
00 g/ln’以上が好ましい。
An adsorbent sheet is formed by mixing the above-mentioned elements, but it may also contain other components having additional functions such as deodorization and mold prevention. In addition, the thickness of this adsorbent sheet is 0.5 to 1.2 i, considering air permeability and processability.
It is preferable to have a diameter of about s. Also, the basis weight is 1 from the point of view of adsorption.
00 g/ln' or more is preferable.

上記吸着性シートと通気性補強シートを積層することに
よって最適な空気浄化用フィルターが実現できる0通気
性補強シートとしては木材バルブ、レーヨン、アセテー
ト、ポリエステル、ポリアクリロニトリル、ポリアミド
、ポリオレフィン等を素材とした紙や不織布、布等が使
用できるが、前記吸着性シートとの接着性の面から紙や
不織布等の不織シートの形態であることが好ましい。こ
の通気性補強シートは通気抵抗の増大の原因になっては
ならないので、薄く且つ粗な構造であることが必要であ
り、また適度に強靭であることが必要である。こうした
ことから、該補強シートを形成する際における繊維成分
とバインダーの配合は重量割合で60/40〜80/2
0程度が好ましい。また該シートの厚みは0.15〜0
.3ma+ 。
By laminating the above-mentioned adsorbent sheet and breathable reinforcing sheet, an optimal air purifying filter can be realized.The breathable reinforcing sheet is made of wood valve, rayon, acetate, polyester, polyacrylonitrile, polyamide, polyolefin, etc. Although paper, nonwoven fabric, cloth, etc. can be used, it is preferably in the form of a nonwoven sheet such as paper or nonwoven fabric from the viewpoint of adhesiveness with the adsorbent sheet. This breathable reinforcing sheet must not cause an increase in ventilation resistance, so it needs to be thin and have a rough structure, and it needs to be appropriately tough. For this reason, when forming the reinforcing sheet, the weight ratio of the fiber component and binder is 60/40 to 80/2.
About 0 is preferable. In addition, the thickness of the sheet is 0.15 to 0.
.. 3ma+.

坪量は20〜40 g/la2程度が好ましい。The basis weight is preferably about 20 to 40 g/la2.

尚吸着性シートと通気性シートを積層する際には、吸着
性シートが湿潤状態であることが必要であるが、このと
きの含水率は100重量%以上であることが好ましい、
また両シートは積層後、乾燥前に充分にプレスすること
が好ましい。
When laminating the adsorbent sheet and the breathable sheet, it is necessary that the adsorbent sheet is in a wet state, and the moisture content at this time is preferably 100% by weight or more.
Further, it is preferable that both sheets be sufficiently pressed after lamination and before drying.

第1図は、本発明に係る空気浄化用フィルターを長網式
抄紙法によって製造する際の装置構成例を示す概略説明
図であり、1は網状無端ベルト、2は微粒子状活性炭支
持繊維および接着成分を懸垂させた液を入れる容器、3
.4はプレスロール、5はシート運搬用無端ベルト、6
は回転式乾燥ドラム、7は巻取ロール、8は吸着性シー
ト、9は通気性補強シート、10は空気浄化用フィルタ
ーを夫々示す。
FIG. 1 is a schematic explanatory diagram showing an example of an apparatus configuration when producing an air purifying filter according to the present invention by a fourdrinier papermaking method, in which 1 is a reticulated endless belt, 2 is a particulate activated carbon supporting fiber, and an adhesive. A container containing a liquid with suspended ingredients, 3
.. 4 is a press roll, 5 is an endless belt for transporting sheets, 6
1 is a rotary drying drum, 7 is a take-up roll, 8 is an adsorbent sheet, 9 is a breathable reinforcing sheet, and 10 is an air purifying filter.

容器2からカスケード式に網状無端ベルト1上に落下さ
れた懸垂液は、網状無端ベルトl上で濾過されて該ベル
ト1上に吸着性シート8を形成する。この吸着性シート
8は網状無端ベルト1上に載って移動され、プレスロー
ル3でプレスされた後シート運搬用無端ベルト5に載っ
て湿潤状態のままで移動される。一方別途形成された通
気性補強シートは乾燥状態で回転乾燥ドラム6に導かれ
、該回転乾燥ドラム6上で前記吸着性シート8と積層さ
れて空気浄化用フィルター10となる。
The suspended liquid dropped from the container 2 onto the endless mesh belt 1 in a cascade manner is filtered on the endless mesh belt 1 to form an adsorbent sheet 8 on the belt 1. This adsorbent sheet 8 is carried on the reticulated endless belt 1, and after being pressed by the press roll 3, it is carried on the sheet conveying endless belt 5 and is carried in a wet state. On the other hand, the separately formed breathable reinforcing sheet is guided in a dry state to a rotary drying drum 6, and laminated with the adsorbent sheet 8 on the rotary drying drum 6 to form an air purifying filter 10.

このフィルター10は、プレスロール4でプレスされた
後積層されたまま乾燥され、巻取ロール7に巻き取られ
る。
This filter 10 is pressed by a press roll 4, dried while stacked, and wound up by a winding roll 7.

以下本発明を実施例によって更に詳細に説明するが、下
記実施例は本発明を限定する性質のものではなく、前・
後記の趣旨に沿って設計変更することはいずれも本発明
の技術的範囲に含まれるものである。
Hereinafter, the present invention will be explained in more detail with reference to examples, but the following examples are not intended to limit the present invention.
Any design changes in accordance with the spirit described below are included within the technical scope of the present invention.

[実施例] 各種の微粒子状活性炭、支持繊維および接着成分を、下
記第1表の比率となる様に混抄した後、TAPPI式抄
紙機で坪量150 g/m2の各種吸着性シートを作成
した。これらの吸着性シートを湿潤状態で、ポリプロピ
レンからなる通気性補強シート(坪量30 g/m2、
厚み0.2mm )と積層後120〜130℃に加熱し
て乾燥し、空気浄化用フィルターを作成した。
[Example] After mixing various particulate activated carbons, support fibers, and adhesive components in the ratios shown in Table 1 below, various adsorbent sheets with a basis weight of 150 g/m2 were created using a TAPPI paper machine. . These absorbent sheets were wetted with a breathable reinforcing sheet made of polypropylene (basis weight 30 g/m2,
After lamination with a thickness of 0.2 mm), they were heated to 120 to 130°C and dried to produce an air purifying filter.

得られた各空気浄化用フィルターについて、トルエン吸
着性、圧損、引張強度、活性炭脱落性、抄紙性等の各特
性を調査した。この結果を第1表に併記する。
Each of the air purifying filters obtained was investigated for its properties such as toluene adsorption, pressure loss, tensile strength, activated carbon shedding properties, and paper-making properties. The results are also listed in Table 1.

第1表から明らかである様に、本発明で規定する要件を
満足する実施例は、空気浄化用フィルターとして最適な
特性を備えている。尚実施例のものは加工性の点につい
てもいずれも良好であった。
As is clear from Table 1, the examples that satisfy the requirements stipulated by the present invention have optimal characteristics as air purifying filters. In addition, all of the examples were good in terms of workability.

9・・・通気性補強シート 1G・・・空気浄化用フィルター9...Breathable reinforcement sheet 1G...Air purification filter

Claims (2)

【特許請求の範囲】[Claims] (1)[a]平均粒子径が60〜150μmの微粒子状
活性炭:10〜80重量部 [b]外表面積が1m^2/g以下である支持繊維:5
〜50重量部 [c]水膨潤性繊維または熱溶融性繊維:1〜30重量
部 を含むことを特徴とする吸着性シート。
(1) [a] Particulate activated carbon with an average particle diameter of 60 to 150 μm: 10 to 80 parts by weight [b] Support fiber with an outer surface area of 1 m^2/g or less: 5
~50 parts by weight [c] Water-swellable fibers or heat-meltable fibers: 1 to 30 parts by weight. An absorbent sheet.
(2)請求項(1)に記載の吸着性シートと通気性補強
シートを積層して構成されることを特徴とする空気浄化
用フィルター。
(2) An air purifying filter characterized by being constructed by laminating the adsorbent sheet according to claim (1) and the breathable reinforcing sheet.
JP63288096A 1988-11-14 1988-11-14 Adsorbent sheet and air purification filter Expired - Fee Related JP2679714B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP63288096A JP2679714B2 (en) 1988-11-14 1988-11-14 Adsorbent sheet and air purification filter

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP63288096A JP2679714B2 (en) 1988-11-14 1988-11-14 Adsorbent sheet and air purification filter

Related Child Applications (1)

Application Number Title Priority Date Filing Date
JP9121272A Division JPH10128109A (en) 1997-05-12 1997-05-12 Adsorptive sheet and filter for purification of air

Publications (2)

Publication Number Publication Date
JPH02135141A true JPH02135141A (en) 1990-05-24
JP2679714B2 JP2679714B2 (en) 1997-11-19

Family

ID=17725743

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04323007A (en) * 1991-04-22 1992-11-12 Japan Gore Tex Inc Adsorbent
EP0955087A1 (en) * 1998-05-08 1999-11-10 Toyobo Co., Ltd. Gas adsorption sheet and air-purifying filter
US5997829A (en) * 1995-05-26 1999-12-07 Hitachi Chemical Company, Ltd. Environment purifying material
US6956882B2 (en) * 1997-03-07 2005-10-18 Sharp Kabushiki Kaisha Gallium nitride semiconductor light emitting device having multi-quantum-well structure active layer, and semiconductor laser light source device

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS534789A (en) * 1976-05-12 1978-01-17 Honshu Paper Co Ltd Adsorptive nonnwoven fabrics and its manufacture

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS534789A (en) * 1976-05-12 1978-01-17 Honshu Paper Co Ltd Adsorptive nonnwoven fabrics and its manufacture

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04323007A (en) * 1991-04-22 1992-11-12 Japan Gore Tex Inc Adsorbent
US5997829A (en) * 1995-05-26 1999-12-07 Hitachi Chemical Company, Ltd. Environment purifying material
US6956882B2 (en) * 1997-03-07 2005-10-18 Sharp Kabushiki Kaisha Gallium nitride semiconductor light emitting device having multi-quantum-well structure active layer, and semiconductor laser light source device
US7183569B2 (en) 1997-03-07 2007-02-27 Sharp Kabushiki Kaisha Gallium nitride semiconductor light emitting device having multi-quantum-well structure active layer, and semiconductor laser light source device
EP0955087A1 (en) * 1998-05-08 1999-11-10 Toyobo Co., Ltd. Gas adsorption sheet and air-purifying filter
US6746760B2 (en) 1998-05-08 2004-06-08 Toyobo Co., Ltd Gas adsorption sheet and air-purifying filter

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