JPH01241500A - Production of precious metal composit form - Google Patents

Production of precious metal composit form

Info

Publication number
JPH01241500A
JPH01241500A JP7013288A JP7013288A JPH01241500A JP H01241500 A JPH01241500 A JP H01241500A JP 7013288 A JP7013288 A JP 7013288A JP 7013288 A JP7013288 A JP 7013288A JP H01241500 A JPH01241500 A JP H01241500A
Authority
JP
Japan
Prior art keywords
laminate
precious metal
composite plate
resin
plates
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP7013288A
Other languages
Japanese (ja)
Inventor
Masaki Morikawa
正樹 森川
Naoyuki Hosoda
細田 直之
Atsuyuki Fujiie
藤家 敬幸
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Metal Corp
Original Assignee
Mitsubishi Metal Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Metal Corp filed Critical Mitsubishi Metal Corp
Priority to JP7013288A priority Critical patent/JPH01241500A/en
Publication of JPH01241500A publication Critical patent/JPH01241500A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To obtain an inexpensive, highly decorative form with a noble appearance due to a combination of the tone of a precious metal and the texture of a resin, by coating a precious metal plate with a transparent resin to obtain a composite plate, and hot-or cold-forming the composite plate. CONSTITUTION:A plulality of Au plates and Pt plates 2 are prepared as precious metal plate blanks, are then superposed on each other alternately in the order of Au and Pt, and are fed into a diffusion welder, in which degassing, heating and pressurizing are conducted to obtain a laminate 3. The laminate 3 is subjected to repeated hot rolling and cold rolling to obtain a laminate 5. The laminate 5 has a golden color on both sides thereof. One side of the laminate 5 is irradiated with a laser beam from a yttrium-aluminum-garnet laser generator 6, whereby the first layer (Au) is removed in the form of a groove, and the second layer is exposed. With the irradiating position varied, a pattern is marked on the surface of the laminate 5. The laminate 5 is then cut to a desired size, is sandwiched between two transparent acrylic resin plates 7, and the sandwich is heated and worked by a hot press to obtain a composite plate. The composite plate 8 is subjected to thermocompression forming to obtain a pen stand.

Description

【発明の詳細な説明】 「産業上の利用分野」 本発明は、装飾性が高く、しかも安価に製造できて、記
念品や贈答品さらには日用品等に用いても好適な貴金属
複合成形体の製造法に関する。
Detailed Description of the Invention "Field of Industrial Application" The present invention provides a precious metal composite molded article that is highly decorative, can be produced at low cost, and is suitable for use as souvenirs, gifts, and daily necessities. Regarding manufacturing methods.

「従来の技術」 従来、プラスチック製品に絵文字を施す場合は通常、塗
料による着色が行なわれる。また、製品上に金属色を現
出させて付加価値を高める場合には、該プラスチック上
に化学めっきを施すか、または化学めっきをした上に電
気化学めっきを施すようにしている。めっきによって模
様を付す場合には、模様の部分以外を遮蔽膜で覆い、模
様の部分のみめっきを施こす等が行われている。
"Prior Art" Conventionally, when pictograms are applied to plastic products, they are usually colored with paint. In addition, when adding value by making a metallic color appear on the product, chemical plating is applied to the plastic, or electrochemical plating is applied on top of the chemical plating. When a pattern is applied by plating, the area other than the pattern is covered with a shielding film, and only the pattern area is plated.

「発明が解決しようとする課題」 しかしながら、上記のような従来の技術においては、樹
脂面への金属めっきや着色で模様を施こしても樹脂自体
の持つ素材感がなくなってしまい、立体観にとぼしく面
白味のないものとなってしまう。また、塗料やめっきが
表面に付着しているので、長年の使用によりはげる等の
懸念があり、装飾品としての見栄えがせず、近年の高級
志向にそぐわないという難点がある。
"Problem to be Solved by the Invention" However, in the conventional technology described above, even if a pattern is applied to the resin surface by metal plating or coloring, the material feel of the resin itself is lost, and the three-dimensional appearance is not achieved. It becomes dull and uninteresting. In addition, since the paint or plating is attached to the surface, there is a concern that it will peel off after long-term use, and it does not look good as a decorative item and does not suit the recent trend toward luxury.

「課題を解決するための手段」 上記のような課題を解決するために、本発明は、貴金属
板を透明な樹脂により被覆して複合板を形成し、この複
合板を熱間あるいは冷間で成形加工を施すようにしたも
のである。模様を付す場合には、貴金属板自体に適宜の
方法で模様を付してらよく、また樹脂に模様を付してお
いてもよい。成形加工法は、樹脂の性状に応じて適宜の
ものが採用されてよい。例えば、熱硬化性樹脂の場合に
は、貴金属を覆うときには硬化反応を途中で止めるよう
にし7、複合板とした後に金型中で加熱し、あるいは金
型成形した後に加熱して最終的に硬化させる。熱可塑性
樹脂の場合には、−たん)夏合板とした後に、加熱しつ
つ成形すればよい。
"Means for Solving the Problems" In order to solve the above problems, the present invention covers a noble metal plate with a transparent resin to form a composite plate, and then heats or cold coats the composite plate. It is designed to be molded. When a pattern is to be applied, the pattern may be applied to the noble metal plate itself by an appropriate method, or the pattern may be applied to the resin. An appropriate molding method may be adopted depending on the properties of the resin. For example, in the case of thermosetting resin, when covering precious metals, the curing reaction is stopped midway,7 and the composite plate is heated in a mold or molded into a mold and then heated to finally harden. let In the case of thermoplastic resin, it may be formed into summer plywood and then molded while heating.

貴金属板に模様を付す方法としては、貴金属板を複数種
の色調の異なる素材から積層して構成し、その表面にレ
ーザビームを照射して内層を4出させて模様をマーキン
グするなどの方法が好適である。
One way to add a pattern to a precious metal plate is to construct the precious metal plate by laminating multiple materials with different colors, and then irradiate the surface with a laser beam to make the four inner layers come out and mark the pattern. suitable.

「作用J このような貴金属複合成形体の製造法においては、貴金
属板の外部を樹脂が覆った状態で複合板が構成され、こ
の樹脂を熱間あるいは冷間で成形加工すると、内部の貴
金属は樹脂の変形に伴って一体に塑性変形する。貴金属
自体は金型などの加工具と直接接触しておらず、移動を
拘束されていないので、歪み速度が大きくなることがな
く、成形中に破断したりすることが防がれる。このよう
に加工された成形体においては、透明樹脂層を通して貴
金属板が見えるので、貴金属の色調と樹脂の質感が相ま
って気品の高い外観をもたらす。貴金属板を可能な限り
薄くし、樹脂層を厚くすることにより安価でかつ装飾性
の高い成形体を得ることができる。
``Function J'' In this method of manufacturing a precious metal composite molded body, the composite plate is constructed by covering the outside of the precious metal plate with resin, and when this resin is molded hot or cold, the precious metal inside is removed. It deforms plastically as the resin deforms.The precious metal itself is not in direct contact with processing tools such as molds, and its movement is not restricted, so the strain rate does not increase and it does not break during molding. In a molded object processed in this way, the precious metal plate can be seen through the transparent resin layer, so the color tone of the precious metal and the texture of the resin combine to create an elegant appearance. By making the resin layer as thin as possible and making the resin layer thick, it is possible to obtain a molded article that is inexpensive and highly decorative.

「実施例」 以下、図面を参照して、この発明の詳細な説明する。"Example" Hereinafter, the present invention will be described in detail with reference to the drawings.

第1図は、この製造法により製造した筆立てを示すもの
である。以下、製造法を説明する。
FIG. 1 shows a brush holder manufactured by this manufacturing method. The manufacturing method will be explained below.

まず、第2図に示すように、貴金属板素材として、いず
れら幅:50m+++X長さ=6011IIi×厚さ0
゜52m…の寸法を有する色調が黄金色のAu板1(A
u:99.99vt%)10枚と、同白色系素材として
pt板2(Pt:99.99wt%)を9枚用意し、脱
脂処理した後、Au、Ptの順に交互に重ね合わせ、拡
散溶接機に装入し、脱気、昇温、加圧を行い、厚さ8.
6mmの積層体3とする(第3図参照)。引き続いてロ
ール4により熱間圧延および冷間圧延をくり返して厚さ
25μmの積層板(貴金属板)5とする(第4図参照)
First, as shown in Figure 2, as a precious metal plate material, width: 50m+++X length = 6011IIi x thickness 0
Au plate 1 (A
After preparing 10 sheets of PT plate 2 (Pt: 99.99 wt%) and 9 sheets of PT board 2 (Pt: 99.99 wt%) as the same white material, degreasing them, stacking them alternately in the order of Au and Pt, and diffusion welding. It is charged into a machine, deaerated, heated, and pressurized until it reaches a thickness of 8.
The laminated body 3 has a thickness of 6 mm (see FIG. 3). Subsequently, hot rolling and cold rolling are repeated using rolls 4 to obtain a 25 μm thick laminate (precious metal plate) 5 (see Fig. 4).
.

この積層板5の外観色は両面黄金色を呈している。その
片面にYAG(イツトリウム−アルミニウムーガーネッ
ト)レーザ発生装置6からレーザビームを照射すると、
表面の第1層(Au)が溝状に除去され、第2層が露出
し、照射位置を変えると表面に模様がマーキングされる
(第5図、第6図参照)。例えば発生装置6を適当な制
御装置と組み合わせることにより、図形を入力しただけ
でそのままそれか模様や文字となってマーキングがなさ
れるようにできる。照射の強度を変えることにより、模
様を形成する凹凸の深さを適宜に調整することができ、
この例では2種の貴金属を重ねて構成1.たが、3種類
以上の金囮層を何層にも設けて曵雑な色調を出すことも
できる。
The exterior color of this laminate 5 is golden yellow on both sides. When one side is irradiated with a laser beam from a YAG (yttrium-aluminum-garnet) laser generator 6,
The first layer (Au) on the surface is removed in a groove shape, the second layer is exposed, and when the irradiation position is changed, a pattern is marked on the surface (see FIGS. 5 and 6). For example, by combining the generator 6 with a suitable control device, it is possible to input a figure and then mark it as a pattern or character. By changing the intensity of the irradiation, the depth of the unevenness that forms the pattern can be adjusted as appropriate.
In this example, two types of precious metals are stacked to form the structure 1. However, it is also possible to create a rough color tone by providing many layers of three or more types of gold decoys.

この模様をマーキングした積層板5を直径170mmに
切断し、さらに同寸大の厚み3mmの2枚の透明アクリ
ル板(!を脂)7に挾んで180℃に加熱し、十ノドブ
レスで;夏合板8とした(第7図参照)。
The laminated board 5 marked with this pattern was cut to a diameter of 170 mm, and then sandwiched between two transparent acrylic boards (!) 7 of the same size and 3 mm thick, heated to 180°C, and pressed with ten-node pressure; summer plywood 8 (see Figure 7).

この複合板8を筆立てに成形するため電熱型加熱炉にて
140℃に加熱し、加圧成形を行い直径6(1+m、高
さ100III11の筆立てを成形した。成形した筆立
ては表面の肌荒れをなくすため、パフ研磨を行った。こ
の筆立ては表面が黄金色で、その表面に白色の模様が立
体的に現出され、大部分が樹脂7でありながら装飾的に
も優美であり、商品価値が高い。また、筆立てとして使
用しても樹脂7か内部の積層板5をを機械的にあるいは
化学的に保護するので耐用性があり、価値が長く保、す
れる。
In order to form this composite plate 8 into a brush holder, it was heated to 140°C in an electric heating furnace and pressure-molded to form a brush holder with a diameter of 6 (1+ m) and a height of 100 III 11. Puff polishing was performed to eliminate rough skin.The surface of this brush holder is golden yellow, and a three-dimensional white pattern appears on the surface.Although most of the brush holder is made of resin 7, it is also decoratively elegant. , has high commercial value.Furthermore, even when used as a brush holder, the resin 7 and the internal laminate 5 are protected mechanically or chemically, so it is durable and retains its value for a long time.

なお、上記の実施例は、貴金属板にレーザビームを用い
て模様を付した例であるが、他の方法、例えばめっきや
着色でもよい。また、アクリル仮の方に模様を付しても
よく、全く模様がなくてもよい。さらに、上記例では貴
金属板を積層して構成したが、単板の場合でもよく、板
厚もこれより厚くてらあるいは薄くてもよい。
Note that although the above embodiment is an example in which a pattern is applied to a noble metal plate using a laser beam, other methods such as plating or coloring may be used. Further, a pattern may be attached to the temporary acrylic material, or there may be no pattern at all. Further, in the above example, the noble metal plates are laminated, but a single plate may be used, and the plate thickness may be thicker or thinner.

「発明の効果」 以上上述したように、この発明は、貴金属板を透明な樹
脂により被覆して複合板を形成し、この複合板を熱間あ
るいは冷間で成形加工を施すようにしたものであるので
、貴金属板を芯として樹脂を成形して種々の成形体を構
成することができる。
"Effects of the Invention" As described above, the present invention covers a noble metal plate with a transparent resin to form a composite plate, and then performs hot or cold molding on this composite plate. Therefore, various molded bodies can be constructed by molding resin using a noble metal plate as a core.

透明樹脂層を通して貴金属板が見えるので、貴金属の色
調と樹脂の質感が相まって気品の高い外観をもたらす。
Since the precious metal plate is visible through the transparent resin layer, the color tone of the precious metal and the texture of the resin combine to create an elegant appearance.

貴金属板を可能な限り薄くし、樹脂層を厚くすることに
より安価でかつ装飾性の高い成形体を得ることができる
など浸れた効果を奏するものである。
By making the noble metal plate as thin as possible and making the resin layer as thick as possible, it is possible to obtain a molded article that is both inexpensive and highly decorative.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図ないし第7図はこの発明の一実施例を示すもので
、第1図は製造された筆立ての図、第2図は素材板を重
ねる工程を示す図、第3図は重ねた板を拡散接合した図
、第4図はこれを圧延する図、第5図はレーザビームを
照射する図、第6図はその一部を破断して拡大した図、
第7図は複合板の断面図である。 ■、2・・・・・素材板、5・・・・積層板(貴金属板
)、7・・・・・・樹III、8・・・・・・複合板。
Figures 1 to 7 show an embodiment of the present invention. Figure 1 is a diagram of a manufactured brush holder, Figure 2 is a diagram showing the process of stacking the material plates, and Figure 3 is a diagram showing the stacking process. Figure 4 is a diagram of the plates being diffusion bonded, Figure 4 is a diagram of rolling them, Figure 5 is a diagram of irradiation with a laser beam, Figure 6 is a partially broken and enlarged diagram,
FIG. 7 is a sectional view of the composite plate. ■, 2... Material board, 5... Laminated board (precious metal plate), 7... Tree III, 8... Composite board.

Claims (1)

【特許請求の範囲】[Claims] 貴金属板を透明な樹脂により被覆して複合板を形成し、
この複合板を熱間あるいは冷間で成形加工を施すことを
特徴とする貴金属複合成形体の製造法。
A composite plate is formed by coating a precious metal plate with a transparent resin,
A method for producing a precious metal composite molded body, which is characterized by subjecting this composite plate to hot or cold molding.
JP7013288A 1988-03-24 1988-03-24 Production of precious metal composit form Pending JPH01241500A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP7013288A JPH01241500A (en) 1988-03-24 1988-03-24 Production of precious metal composit form

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP7013288A JPH01241500A (en) 1988-03-24 1988-03-24 Production of precious metal composit form

Publications (1)

Publication Number Publication Date
JPH01241500A true JPH01241500A (en) 1989-09-26

Family

ID=13422732

Family Applications (1)

Application Number Title Priority Date Filing Date
JP7013288A Pending JPH01241500A (en) 1988-03-24 1988-03-24 Production of precious metal composit form

Country Status (1)

Country Link
JP (1) JPH01241500A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2744066A1 (en) * 1996-01-30 1997-08-01 Otis Elevator Co Method of laser printing on e.g. metal, wood etc.
WO2009133757A1 (en) * 2008-05-01 2009-11-05 株式会社浜野メッキ Article-surface decorative structure and method of processing for the same
JP2010058499A (en) * 2009-07-28 2010-03-18 Hamano Mekki:Kk Surface-decorating structure for goods and processing method therefor

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2744066A1 (en) * 1996-01-30 1997-08-01 Otis Elevator Co Method of laser printing on e.g. metal, wood etc.
US5919853A (en) * 1996-01-30 1999-07-06 Otis Elevator Company Method and compositions for laser imprinting and articles imprinted using such methods and composition
WO2009133757A1 (en) * 2008-05-01 2009-11-05 株式会社浜野メッキ Article-surface decorative structure and method of processing for the same
US8067083B2 (en) 2008-05-01 2011-11-29 Hamano Plating Co., Ltd. Surface ornamental structure of an article and a method for ornamentally working the surface structure of the article
JP2010058499A (en) * 2009-07-28 2010-03-18 Hamano Mekki:Kk Surface-decorating structure for goods and processing method therefor
JP4465408B2 (en) * 2009-07-28 2010-05-19 株式会社浜野メッキ Surface decoration structure of article and processing method thereof

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