JP7349295B2 - Liquid type for bread and method for manufacturing bread using the same - Google Patents

Liquid type for bread and method for manufacturing bread using the same Download PDF

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JP7349295B2
JP7349295B2 JP2019157709A JP2019157709A JP7349295B2 JP 7349295 B2 JP7349295 B2 JP 7349295B2 JP 2019157709 A JP2019157709 A JP 2019157709A JP 2019157709 A JP2019157709 A JP 2019157709A JP 7349295 B2 JP7349295 B2 JP 7349295B2
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高司 山田
洋佑 柴田
幹法 金井
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Nisshin Seifun Group Inc
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Description

本発明は、パン類用液種及びそれを用いたパン類の製造方法に関する。 The present invention relates to a liquid type for bread and a method for manufacturing bread using the same.

液種法は、イースト発酵液(液種)に、小麦粉等の原料を加え生地を製造する製パン法であり、小麦粉を含む液種を用いるフラワーブリュー法、粉乳を含む液種を用いるアドミ法などの手法がある。液種法は、機械耐性があり老化が遅いパンを製造することができるという利点を有する。 The liquid dough method is a bread making method in which dough is made by adding raw materials such as flour to yeast fermentation liquid (liquid dough), and includes the flower brew method, which uses a liquid dough containing flour, and the admixture method, which uses a liquid dough containing powdered milk. There are methods such as The yeast method has the advantage of being able to produce breads that are mechanically resistant and slow to age.

特許文献1には、フラワーブリュー製パン法において、蛋白質含量が6.5~10質量%の小麦粉を使用し、且つ液種として、製パンに使用する全小麦粉100質量部中の40~50質量部の小麦粉、0.01~0.07質量部のイースト、0~0.6質量部の食塩及び40~60質量部の水を用いて製造された液種を使用することを特徴とするイースト発酵食品の製造方法が記載されている。特許文献2には、α化穀粉を含む原料粉に、イースト、及び該原料粉100質量部あたり50~200質量部の水を添加して混捏し、発酵させることを含むパン類用発酵種の製造方法、ならびに当該発酵種を用いたパン類の製造方法が記載されている。 Patent Document 1 discloses that in the flour brew bread making method, wheat flour with a protein content of 6.5 to 10% by mass is used, and as a liquid seed, 40 to 50 parts by mass of the total wheat flour used for bread making is used. A yeast characterized by using a liquid type produced using 1 part of wheat flour, 0.01 to 0.07 parts by mass of yeast, 0 to 0.6 parts by mass of salt, and 40 to 60 parts by mass of water. A method for producing fermented foods is described. Patent Document 2 describes a fermented seed for breads, which involves adding yeast and 50 to 200 parts by mass of water per 100 parts by mass of the raw material flour to raw material flour containing pregelatinized flour, kneading and fermenting the mixture. A manufacturing method and a method for manufacturing breads using the fermented bread are described.

モチモチ、且つしっとりした食感のパンを製造する方法として、湯種法、生地を多加水にする方法、原料粉にα化小麦粉を配合する方法などが知られている。しかしながら、これらの方法は、生地の作業性が悪い、製造に時間がかかる、又はパンの品質にばらつきが出るなどの欠点を抱える。これらの欠点を解消する方法として、特許文献3には、α化穀粉100質量部と水200~500質量部とを用いて調製した非発酵のペースト状生地と、非α化穀粉を含む材料を用いて調製した生地とを混合し、発酵させることを含むパン類の製造方法が記載されている。 Known methods for producing bread with a chewy and moist texture include a boiling water method, a method of adding a large amount of water to the dough, and a method of blending pregelatinized wheat flour into raw material flour. However, these methods have drawbacks such as poor dough workability, long production times, and uneven bread quality. As a method to eliminate these drawbacks, Patent Document 3 discloses a non-fermented pasty dough prepared using 100 parts by mass of pregelatinized flour and 200 to 500 parts by mass of water, and a material containing non-gelatinized flour. A method for producing breads is described, which includes mixing and fermenting dough prepared using the same method.

特開2006-109781号公報Japanese Patent Application Publication No. 2006-109781 特開2019-024336号公報JP2019-024336A 特開2017-112989号公報Japanese Patent Application Publication No. 2017-112989

本発明は、老化が遅いパンを製造できるという液種法の利点を保ちつつ、しっとりした食感と、まろやかな酸味と甘みを併せ持った重厚な風味とを有するパン類を製造することを可能にする液種、及びそれを用いたパン類の製造方法を提供する。 The present invention makes it possible to produce bread that has a moist texture and a rich flavor that combines mellow sourness and sweetness, while maintaining the advantage of the liquid dough method that it can produce bread that does not age quickly. The present invention provides a liquid type for producing bread, and a method for producing bread using the liquid type.

本発明者は、鋭意研究を重ねた結果、イーストに、α化穀粉を含む原料粉と、従来の液種と比べて多量の水を加えて発酵させた液種を用いることで、しっとりしたくちどけの良い食感と、まろやかな酸味と甘みを併せ持った重厚な風味とを有し、且つ時間が経過しても老化による食感の低下が起こりにくいパン類が得られることを見出した。 As a result of extensive research, the inventor of the present invention has found that by using raw material flour containing pregelatinized grain flour and a liquid type fermented by adding a large amount of water to yeast compared to conventional liquid types, the inventors have succeeded in creating moist mouths. It has been found that bread can be obtained which has a texture that melts well and a rich flavor that combines mellow sourness and sweetness, and which is less likely to deteriorate in texture due to aging over time.

したがって、本発明は、原料粉、イースト、及び水を混合して発酵させることを含み、該原料粉が、粗蛋白量が8質量%以上の穀粉を原料とするα化穀粉を含み、該水の配合量が、該α化穀粉1質量部あたり2.5質量部~15質量部且つ該原料粉100質量部あたり200質量部超~500質量部である、パン類用液種の製造方法を提供する。 Therefore, the present invention includes mixing and fermenting raw material flour, yeast, and water, and the raw material flour contains gelatinized flour made from grain flour having a crude protein content of 8% by mass or more, and the water A method for producing a liquid bread product, wherein the blending amount of provide.

本発明により提供されるパン類用液種により、しっとりしたくちどけの良い食感と、まろやかな酸味と甘みを併せ持った重厚な風味とを有し、且つ時間が経過しても老化による食感の低下が起こりにくいパン類を製造することができる。 The liquid bread type provided by the present invention has a moist texture that melts in the mouth, a rich flavor that combines mellow sourness and sweetness, and has a texture that does not deteriorate even with the passage of time. It is possible to produce breads that are less likely to suffer from a decrease in temperature.

本明細書において、パン類とは、穀粉を主体とする生地を発酵させたものを加熱(例えば、焼成、蒸し、揚げ等)して得られる食品をいう。パン類としては、例えば、食パン(角型食パン、イギリスパン等)、ロールパン、菓子パン(あんパン、クリームパン等)や総菜パン(カレーパン等)、フランスパン(バゲット、バタール等)、ドイツパン(カイザーゼンメル、ライ麦パン等)、クロワッサン、デニッシュ、イタリアパン(フォカッチャ、パネトーネ等)、ベルギーパン(ワッフル等)、中近東パン(ナン、ピタパン等)などのパン;ピザ;中華まん及び蒸しパン;イーストドーナツ等の発酵菓子、などが挙げられるが、これらに限定されない。 In this specification, breads refer to foods obtained by heating (for example, baking, steaming, frying, etc.) fermented dough mainly composed of grain flour. Examples of bread include white bread (square bread, British bread, etc.), roll bread, sweet bread (red bean paste, cream bread, etc.), deli bread (curry bread, etc.), French bread (baguette, batard, etc.), German bread ( Bread such as Kaiser Semmel, rye bread, etc.), croissant, Danish, Italian bread (focaccia, panettone, etc.), Belgian bread (waffle, etc.), Middle Eastern bread (naan, pita bread, etc.); Pizza; Chinese buns and steamed bread; East donuts Examples include, but are not limited to, fermented confectionery such as, etc.

本発明のパン類用液種(以下、本発明の液種ともいう)は、α化穀粉を用いて製造した多加水の液種である。本発明の液種は、α化穀粉を含む原料粉、イースト及び水を混合して、発酵させることで製造されるが、このとき、原料粉及びそれに含まれるα化穀粉の量と比べてかなり多量の水が使用される。液種におけるα化穀粉及び多量の水の使用によって、本発明の液種により製造されたパンは、しっとりしたくちどけの良い食感と、まろやかな酸味と甘みを併せ持った重厚な風味とを有し、且つ、経時耐性、すなわち時間が経過しても老化による食感の低下が起こりにくいという性質を有する。 The liquid bread type of the present invention (hereinafter also referred to as the liquid type of the present invention) is a highly hydrated liquid type produced using pregelatinized flour. The liquid seed of the present invention is produced by mixing raw material flour containing pregelatinized grain flour, yeast, and water, and fermenting the mixture. Large amounts of water are used. By using pregelatinized flour and a large amount of water in the liquid bread, the bread produced with the liquid bread of the present invention has a moist texture that melts in the mouth and a rich flavor that combines mellow sourness and sweetness. In addition, it has a property of being resistant to aging, that is, the texture is less likely to deteriorate due to aging over time.

本発明の液種の製造に用いられる原料粉は、α化穀粉を含む。本発明の液種を用いて得られたパン類の食感、風味及び経時耐性の向上の観点からは、該原料粉における該α化穀粉の含有量は、好ましくは15質量%以上、より好ましくは20質量%以上、さらに好ましくは25質量%以上、さらに好ましくは30質量%以上、さらに好ましくは40質量%以上である。一方、該原料粉における該α化穀粉の含有量の上限は特に限定されないが、好ましくは95質量%以下である。 The raw material flour used for producing the liquid seed of the present invention includes gelatinized grain flour. From the viewpoint of improving the texture, flavor and aging resistance of breads obtained using the liquid seed of the present invention, the content of the pregelatinized flour in the raw material flour is preferably 15% by mass or more, more preferably is 20% by mass or more, more preferably 25% by mass or more, even more preferably 30% by mass or more, even more preferably 40% by mass or more. On the other hand, the upper limit of the content of the pregelatinized flour in the raw material flour is not particularly limited, but is preferably 95% by mass or less.

当該α化穀粉は、通常の穀粉(α化処理されていない非α化穀粉)をα化処理して得られた穀粉である。該穀粉の種類としては、小麦粉、ライ麦粉、ライ小麦粉、大麦粉、米粉、コーンフラワー等、及びそれらのいずれか2種以上の組合せが挙げられるが、これらに限定されない。本発明の液種を用いて得られたパン類の食感、風味及び経時耐性の向上の観点からは、当該α化穀粉は、粗蛋白量が8質量%以上の穀粉を原料とするとよい。好ましくは、該α化穀粉の原料穀粉の粗蛋白量は、9質量%以上であり、さらに好ましくは10質量%以上、さらに好ましくは11.5質量%以上である。このような粗蛋白量を有する原料穀粉の例としては、強力小麦粉、準強力小麦粉、中力小麦粉、それらのいずれか2種以上の組合せなどの粗蛋白量が8質量%以上の小麦粉、ならびに当該小麦粉を含有し、全体として8質量%以上の粗蛋白量を有する穀粉が挙げられる。より好ましくは、該原料穀粉は、強力小麦粉、準強力小麦粉、又はそれらの組合せであるか、又は当該小麦粉を含有し、全体として9質量%以上、さらに好ましくは10質量%以上、さらに好ましくは11.5質量%以上の粗蛋白量を有する穀粉である。 The gelatinized flour is a flour obtained by gelatinizing normal grain flour (non-gelatinized flour that has not been gelatinized). Types of the flour include, but are not limited to, wheat flour, rye flour, rye flour, barley flour, rice flour, corn flour, etc., and combinations of any two or more thereof. From the viewpoint of improving the texture, flavor, and aging resistance of breads obtained using the liquid seed of the present invention, the gelatinized flour is preferably made from flour having a crude protein content of 8% by mass or more. Preferably, the crude protein content of the raw material flour for the pregelatinized flour is 9% by mass or more, more preferably 10% by mass or more, and even more preferably 11.5% by mass or more. Examples of raw flour having such a crude protein content include wheat flour with a crude protein content of 8% by mass or more, such as strong wheat flour, semi-strong wheat flour, medium wheat flour, and a combination of two or more of them; Examples include flour containing wheat flour and having a total crude protein content of 8% by mass or more. More preferably, the raw material flour is strong wheat flour, semi-strong wheat flour, or a combination thereof, or contains the wheat flour, and has a total of 9% by mass or more, more preferably 10% by mass or more, and even more preferably 11% by mass. It is a flour having a crude protein content of .5% by mass or more.

本明細書において、穀粉中の粗蛋白量は、日本食品標準成分表2015年版(七訂)分析マニュアル(www.mext.go.jp/a_menu/syokuhinseibun/1368931.htm参照)に従って、燃焼法を用いて求めることができる。 In this specification, the amount of crude protein in flour is determined using the combustion method in accordance with the Japanese Food Standard Tables 2015 Edition (7th Edition) Analysis Manual (see www.mext.go.jp/a_menu/syokuhinseibun/1368931.htm). can be found.

また好ましくは、該α化穀粉はα化小麦粉である。好ましくは、該α化穀粉の原料粉は、強力小麦粉、準強力小麦粉、中力小麦粉、又はそれらのいずれか2種以上の組合せを含む小麦粉であり、より好ましくは、強力小麦粉、準強力小麦粉、中力小麦粉、又はそれらのいずれか2種以上の組合せであり、さらに好ましくは、強力小麦粉、準強力小麦粉、又はそれらの組合せであり、さらに好ましくは強力小麦粉である。 Also preferably, the pregelatinized flour is pregelatinized wheat flour. Preferably, the raw material flour for the gelatinized grain flour is strong wheat flour, semi-strong wheat flour, medium wheat flour, or wheat flour containing a combination of two or more thereof, more preferably strong wheat flour, semi-strong wheat flour, It is a medium wheat flour or a combination of any two or more thereof, more preferably a strong wheat flour, a semi-strong wheat flour, or a combination thereof, and still more preferably a strong wheat flour.

穀粉のα化処理の方法としては、穀粉中の澱粉をα化させることができる方法であれば特に限定されないが、穀粉を湿熱処理する方法が挙げられる。湿熱処理の方法としては、例えば、穀粉に水を添加し加熱する方法、穀粉を吸水させた後加熱する方法などが挙げられ、より具体的な例としては、穀粉を高速撹拌機で均一加水しながら、蒸気を添加し加熱処理する方法、エクストルーダーを用いて穀粉と水とを加熱混練する方法、穀粉を入れた密閉型容器内に、必要に応じて攪拌しながら、過熱水蒸気又は飽和水蒸気を添加して該穀粉を加熱処理する方法、特開2009-34038号公報に記載の装置等を用いて飽和水蒸気雰囲気下で加熱処理する方法、などが挙げられる。該湿熱処理された穀粉は、棚乾燥、熱風乾燥、流動層乾燥などの方法で乾燥処理することができる。さらに乾燥後、必要に応じて適宜粉砕することができる。乾燥後のα化穀粉の粉砕処理には、ロール粉砕、ピンミル粉砕などの各種粉砕手段を必要に応じて採用することができる。 The method for gelatinizing the flour is not particularly limited as long as it can gelatinize the starch in the flour, but examples include a method of treating the flour with moist heat. Examples of moist heat treatment methods include adding water to flour and heating it, and heating the flour after absorbing water.A more specific example is to uniformly add water to the flour using a high-speed stirrer. However, there is a method in which heat treatment is performed by adding steam, a method in which flour and water are heated and kneaded using an extruder, and a method in which superheated steam or saturated steam is added to a closed container containing flour while stirring as necessary. Examples include a method in which the grain flour is heat-treated by adding it, and a method in which the flour is heat-treated in a saturated steam atmosphere using the apparatus described in JP-A No. 2009-34038. The moist heat-treated flour can be dried by methods such as shelf drying, hot air drying, and fluidized bed drying. Furthermore, after drying, it can be pulverized as appropriate. For the pulverization treatment of the gelatinized flour after drying, various pulverization methods such as roll pulverization and pin mill pulverization can be employed as necessary.

当該α化穀粉は、α化度が好ましくは70%以上、より好ましくは80%以上、さらに好ましくは85%以上である。該α化穀粉のα化度が70%未満であると、本発明の液種を用いて得られたパン類において、食感及び風味が不充分になることがある。 The degree of gelatinization of the gelatinized flour is preferably 70% or more, more preferably 80% or more, and still more preferably 85% or more. If the degree of gelatinization of the gelatinized flour is less than 70%, breads obtained using the liquid seed of the present invention may have insufficient texture and flavor.

α化度が70%以上のα化穀粉は、例えば、穀粉100質量部と、水5~30質量部、好ましくは10~20質量部とを、エクストルーダー等で加圧加熱処理することによって調製することができる(例えば、特開2009-17802号公報参照)が、本発明で用いるα化穀粉の製法はこれに限定されない。 Pregelatinized flour with a degree of gelatinization of 70% or more can be prepared, for example, by subjecting 100 parts by mass of grain flour and 5 to 30 parts by mass, preferably 10 to 20 parts by mass, of water to a pressure and heat treatment using an extruder or the like. However, the method for producing the pregelatinized flour used in the present invention is not limited thereto.

本明細書において、穀粉のα化度とは、BAP法(β-アミラーゼ・プルラナーゼ法)で測定されたα化度をいう。BAP法によるα化度の測定は、既報(家政学雑誌32(9),653-659,1981)に準じて、以下の通りに実施することができる。
〔β-アミラーゼ・プルラナーゼ法によるα化度の測定法〕
(A)試薬
使用する試薬は、以下の通りである。
1)0.8M酢酸-酢酸Na緩衝液
2)10N水酸化ナトリウム溶液
3)2N酢酸溶液
4)酵素溶液:β-アミラーゼ(ナガセケムテックス(株),#1500S)0.017g及びプルラナーゼ(林原生物化学研究所、No.31001)0.17gを上記0.8M酢酸-酢酸Na緩衝液に溶かして100mLとしたもの。
5)失活酵素溶液:上記酵素溶液を10分間煮沸させて調製。
6)ソモギー試薬及びネルソン試薬(還元糖量の測定用試薬)
(B)測定方法
1)サンプル穀粉(α化穀粉)をホモジナイザーで粉砕し、100メッシュ以下とする。この粉砕したサンプル穀粉0.08~0.10gをガラスホモジナイザーに取る。
2)これに脱塩水8.0mLを加え、ガラスホモジナイザーを10~20回上下させて分散を行う。
3)2本の25mL容目盛り付き試験管に上記2)の分散液を2mLずつとり、1本は0.8M酢酸-酢酸Na緩衝液で定容し、試験区とする。
4)他の1本には、10N水酸化ナトリウム溶液0.2mLを添加し、50℃で3~5分間反応させ、完全に糊化させる。その後、2N酢酸溶液1.0mLを添加し、pHを6.0付近に調整した後、0.8M酢酸-酢酸Na緩衝液で定容し、糊化区とする。
5)上記3)及び4)で調製した試験区及び糊化区の試験液をそれぞれ0.4mLとり、それぞれに酵素溶液0.1mLを加えて、40℃で30分間酵素反応させる。同時に、ブランクとして、酵素溶液の代わりに失活酵素溶液0.1mLを加えたものも調製する。酵素反応は途中で反応液を時々攪拌させながら行う。
6)上記反応済液0.5mLにソモギー試薬0.5mLを添加し、沸騰浴中で15分間煮沸する。煮沸後、流水中で5分間冷却した後、ネルソン試薬1.0mLを添加・攪拌し、15分間放置する。
7)その後、脱塩水8.00mLを加えて攪拌し、500nmの吸光度を測定する。
(C)α化度の算出
下式によりα化度を算出する。
α化度(%)=(試験溶液の分解率)/(完全糊化試験溶液の分解率)×100
=(A-a)/(A’-a’)×100
式中、A、A’、a、及びa’は下記の通りである。
A =試験区の吸光度
A’=糊化区の吸光度
a =試験区のブランクの吸光度
a’=糊化区のブランクの吸光度
As used herein, the degree of gelatinization of flour refers to the degree of gelatinization measured by the BAP method (β-amylase pullulanase method). Measurement of the degree of gelatinization by the BAP method can be carried out as follows according to a previous report (Home Economics Magazine 32(9), 653-659, 1981).
[Measurement method of degree of gelatinization using β-amylase/pullulanase method]
(A) Reagents The reagents used are as follows.
1) 0.8M acetic acid-Na acetate buffer 2) 10N sodium hydroxide solution 3) 2N acetic acid solution 4) Enzyme solution: β-amylase (Nagase ChemteX Co., Ltd., #1500S) 0.017g and pullulanase (Hayashibara Bio Chemical Research Institute, No. 31001) 0.17g was dissolved in the above 0.8M acetic acid-Na acetate buffer to make 100mL.
5) Inactivated enzyme solution: Prepared by boiling the above enzyme solution for 10 minutes.
6) Somogyi reagent and Nelson reagent (reagents for measuring reducing sugar content)
(B) Measurement method 1) Grind sample flour (gelatinized flour) with a homogenizer to a size of 100 mesh or less. Take 0.08 to 0.10 g of this ground sample flour into a glass homogenizer.
2) Add 8.0 mL of demineralized water to this and disperse by moving the glass homogenizer up and down 10 to 20 times.
3) Place 2 mL of the above dispersion in 2 25 mL graduated test tubes, make one volume constant with 0.8 M acetic acid-Na acetate buffer, and use it as a test section.
4) Add 0.2 mL of 10N sodium hydroxide solution to the other bottle, and react at 50°C for 3 to 5 minutes to completely gelatinize. Thereafter, 1.0 mL of 2N acetic acid solution was added to adjust the pH to around 6.0, and the volume was then adjusted to a constant volume with 0.8M acetic acid-Na acetate buffer to form a gelatinized area.
5) Take 0.4 mL of each of the test liquids prepared in 3) and 4) above and add 0.1 mL of the enzyme solution to each of the test solutions, and allow the enzyme reaction to occur at 40°C for 30 minutes. At the same time, a blank is also prepared in which 0.1 mL of an inactivated enzyme solution is added instead of the enzyme solution. The enzymatic reaction is performed while stirring the reaction solution from time to time.
6) Add 0.5 mL of Somogyi's reagent to 0.5 mL of the above reaction solution, and boil for 15 minutes in a boiling bath. After boiling and cooling in running water for 5 minutes, 1.0 mL of Nelson's reagent was added, stirred, and left for 15 minutes.
7) Then, add 8.00 mL of demineralized water, stir, and measure the absorbance at 500 nm.
(C) Calculation of degree of gelatinization The degree of gelatinization is calculated by the following formula.
Degree of gelatinization (%) = (decomposition rate of test solution) / (decomposition rate of completely gelatinized test solution) x 100
=(A-a)/(A'-a')×100
In the formula, A, A', a, and a' are as follows.
A = Absorbance of test area A' = Absorbance of gelatinized area a = Absorbance of blank of test area a' = Absorbance of blank of gelatinized area

本発明の液種の製造に用いられる原料粉はさらに、該α化穀粉以外の他の穀粉及び/又は澱粉類を含んでいてもよい。当該他の穀粉としては、通常の穀粉(α化処理されていない非α化穀粉)が挙げられ、該穀粉の例としては、小麦粉、大麦粉、米粉、ライ麦粉、ライ小麦粉、コーンフラワーなどが挙げられる。該小麦粉としては、強力粉、準強力粉、中力粉、薄力粉、全粒粉、デュラム小麦粉、及びこれらの2種以上の組合せが挙げられる。該小麦粉は、熱処理小麦粉を含んでいてもよいが、得られたパン類生地の弾力及び伸展性、ならびに得られたパン類の風味の観点からは、非熱処理小麦粉であることが好ましい。該澱粉類としては、例えば、小麦澱粉、タピオカ澱粉、馬鈴薯澱粉、米澱粉、コーンスターチ、ワキシーコーンスターチ等、及びそれらの加工澱粉(α化澱粉でないことが好ましい)などが挙げられる。該原料粉は、上記に挙げた他の穀粉及び澱粉類のいずれか1種又は2種以上を組み合わせて含有することができる。 The raw material flour used for producing the liquid seed of the present invention may further contain other flours and/or starches other than the pregelatinized flour. Examples of the other flour include normal grain flour (non-gelatinized grain flour that has not been gelatinized), and examples of the flour include wheat flour, barley flour, rice flour, rye flour, rye flour, and corn flour. Can be mentioned. Examples of the wheat flour include strong flour, semi-strong flour, medium-strength flour, weak flour, whole wheat flour, durum wheat flour, and combinations of two or more thereof. Although the wheat flour may contain heat-treated wheat flour, non-heat-treated wheat flour is preferable from the viewpoint of the elasticity and extensibility of the obtained bread dough and the flavor of the obtained bread. Examples of the starches include wheat starch, tapioca starch, potato starch, rice starch, corn starch, waxy corn starch, and modified starches thereof (preferably not pregelatinized starches). The raw material flour may contain any one or a combination of two or more of the other flours and starches listed above.

好ましくは、当該原料粉は、該α化穀粉以外の他の穀粉として小麦粉(α化処理されていない非α化小麦粉)を含み、該原料粉における該非α化小麦粉の含有量は、好ましくは5質量%以上であり、より好ましくは10質量%以上である。また、該原料粉における該非α化小麦粉と上記α化穀粉との合計含有量は、好ましくは80質量%以上、より好ましくは90質量%以上であり、さらに好ましくは100質量%である。 Preferably, the raw material flour contains wheat flour (non-gelatinized wheat flour that has not been gelatinized) as a flour other than the pregelatinized flour, and the content of the non-gelatinized wheat flour in the raw material flour is preferably 5. It is at least 10% by mass, more preferably at least 10% by mass. Further, the total content of the non-gelatinized wheat flour and the gelatinized flour in the raw material flour is preferably 80% by mass or more, more preferably 90% by mass or more, and even more preferably 100% by mass.

本発明の液種の製造に使用される水は、水道水、天然水、精製水など、パン類生地の製造に通常使用することができる水であれば、特に限定されない。使用する水の温度は、特に限定されないが、0~40℃程度であればよく、好ましくは5~30℃程度である。当該水は、予め加温する必要はなく、室温又は周囲温度で使用することができる。 The water used for producing the liquid seeds of the present invention is not particularly limited as long as it can be normally used for producing bread dough, such as tap water, natural water, or purified water. The temperature of the water used is not particularly limited, but may be about 0 to 40°C, preferably about 5 to 30°C. The water does not need to be pre-warmed and can be used at room or ambient temperature.

本発明においては、液種の製造に多量の水を使用する。本発明の液種の製造に用いられる水の量は、上記原料粉100質量部あたり200質量部超~500質量部であり、且つ該原料粉に含まれるα化穀粉1質量部あたり2.5質量部~15質量部である。水の量が上述の範囲より少ない場合、本発明の液種を用いて得られたパン類の食感、風味及び経時耐性が充分に向上しない。一方で、水の量が多すぎても、パン生地の製造の際にダマができたり、作業性が低下したりすることによって、やはり得られたパン類の食感、風味及び経時耐性が不充分になることがある。好ましくは、該α化穀粉1質量部あたりの水の量は2.5質量部~12.5質量部であり、より好ましくは4.0~10.5質量部である。一方、該原料粉100質量部あたりの水の量は、好ましくは220~450質量部、より好ましくは250~450質量部である。 In the present invention, a large amount of water is used for producing liquid seeds. The amount of water used in the production of the liquid seed of the present invention is more than 200 parts by mass to 500 parts by mass per 100 parts by mass of the raw material flour, and 2.5 parts by mass per 1 part by mass of pregelatinized flour contained in the raw material flour. Parts by mass to 15 parts by mass. When the amount of water is less than the above-mentioned range, the texture, flavor and aging resistance of breads obtained using the liquid variety of the present invention will not be sufficiently improved. On the other hand, even if the amount of water is too large, lumps may form during bread dough production and workability may decrease, resulting in insufficient texture, flavor, and aging resistance of the resulting bread. It may become. Preferably, the amount of water per 1 part by mass of the pregelatinized flour is 2.5 parts by mass to 12.5 parts by mass, more preferably 4.0 to 10.5 parts by mass. On the other hand, the amount of water per 100 parts by mass of the raw material powder is preferably 220 to 450 parts by mass, more preferably 250 to 450 parts by mass.

本発明の液種の製造に使用されるイーストとしては、パン類の製造に通常用いられるものであれば特に限定されず、例えば生イースト、ドライイースト、インスタントイーストなどが挙げられる。本発明の液種の製造に使用されるイーストの量は、イーストの形態や種類によって調整すればよい。例えば、生イーストの場合、該液種の原料粉100質量部に対して1~10質量部が好ましく、ドライイーストの場合、該液種の原料粉100質量部に対して0.5~5質量部が好ましい。 The yeast used in the production of the liquid seeds of the present invention is not particularly limited as long as it is commonly used in the production of breads, and examples thereof include fresh yeast, dry yeast, instant yeast, and the like. The amount of yeast used for producing the liquid seed of the present invention may be adjusted depending on the form and type of yeast. For example, in the case of fresh yeast, it is preferably 1 to 10 parts by mass per 100 parts by mass of the raw material powder of the liquid type, and in the case of dry yeast, it is preferably 0.5 to 5 parts by mass per 100 parts by mass of the raw material powder of the liquid type. part is preferred.

本発明の液種の製造においては、上記α化穀粉を含む原料粉と、イースト及び水を混合して、混合液を調製する。該混合は、常温下で製パンや調理に使用される通常のミキサーを用いて行うことができ、混合の時間は、好ましくは1~5分程度である。次いで、該混合液を発酵させて液種を得る。該発酵は、温度0~40℃、好ましくは2~30℃、より好ましくは4~25℃で、0.5時間~48時間、好ましくは2~36時間行えばよい。さらに好ましい発酵条件は、4~25℃で8~24時間である。発酵の温度が0℃未満であるか、時間が0.5時間未満である場合、発酵が充分に進まず、製造したパン類の食感と風味が不足することがある。他方、発酵の温度が40℃を超えるか、時間が48時間を超える場合、過発酵となって、やはり製造したパン類の品質が低下しやすい。 In the production of the liquid seed of the present invention, the raw material flour containing the gelatinized flour, yeast, and water are mixed to prepare a liquid mixture. The mixing can be carried out at room temperature using a common mixer used for baking and cooking, and the mixing time is preferably about 1 to 5 minutes. Next, the mixed liquid is fermented to obtain a liquid seed. The fermentation may be carried out at a temperature of 0 to 40°C, preferably 2 to 30°C, more preferably 4 to 25°C, for 0.5 to 48 hours, preferably 2 to 36 hours. More preferred fermentation conditions are 4-25°C for 8-24 hours. If the fermentation temperature is less than 0° C. or the fermentation time is less than 0.5 hours, the fermentation may not proceed sufficiently and the produced bread may lack texture and flavor. On the other hand, if the fermentation temperature exceeds 40° C. or the fermentation time exceeds 48 hours, overfermentation occurs and the quality of the breads produced tends to deteriorate.

以上の手順で本発明の液種を製造することができる。得られた液種は、パン類の製造に使用される。本発明の液種を用いてパン類を製造する場合、該液種をパン類生地に配合すればよい。 The liquid species of the present invention can be produced by the above procedure. The obtained liquid seed is used for manufacturing breads. When producing bread using the liquid seed of the present invention, the liquid seed may be blended into bread dough.

例えば、本発明においては、パン類生地の原料粉(例えば穀粉及びその他の副原料)に本発明の液種及び水を添加し、混捏してパン類生地を製造してもよい。あるいは、予め該パン類生地の原料粉と水とを混捏して粗生地を調製してから、該粗生地に本発明の液種を添加し、さらに混捏してパン類生地を製造してもよい。パン類生地が中種法で製造される場合は、本発明の液種を本捏工程で生地に添加するのが好ましい。 For example, in the present invention, the liquid seed of the present invention and water may be added to raw material flour (for example, grain flour and other auxiliary raw materials) for bread dough, and the mixture is kneaded to produce bread dough. Alternatively, the raw material flour for the bread dough and water may be mixed and kneaded in advance to prepare a rough dough, and then the liquid seed of the present invention may be added to the rough dough and further kneaded to produce bread dough. good. When bread dough is produced by the dough method, it is preferable to add the liquid dough of the present invention to the dough in the main kneading step.

当該パン類生地の原料粉に含まれる穀粉の例としては、小麦粉、ライ麦粉、ライ小麦粉、大麦粉、コーンフラワー、米粉等、及びそれらのいずれか2種以上の組合せが挙げられる。これらの穀粉は、好ましくは非α化穀粉(α化処理されていない穀粉)であり、より好ましくは、非α化小麦粉を主体とする非α化穀粉である。該小麦粉としては、パン類の製造に通常用いる小麦粉、例えば、強力粉、準強力粉、中力粉、薄力粉、全粒粉、デュラム小麦粉、及びそれらのいずれか2種以上の組合せが挙げられるが、中でも、強力粉、準強力粉、中力粉、全粒粉、デュラム小麦粉、及びそれらのいずれか2種以上の組合せが好ましい。該小麦粉は、熱処理小麦粉を含んでいてもよいが、得られたパン類生地の弾力及び伸展性、ならびに得られたパン類の風味の観点からは、非熱処理小麦粉であることが好ましい。 Examples of the grain flour contained in the raw material flour for the bread dough include wheat flour, rye flour, rye flour, barley flour, corn flour, rice flour, and a combination of two or more thereof. These flours are preferably non-gelatinized flours (flours that have not been subjected to gelatinization treatment), and more preferably non-gelatinized flours mainly composed of non-gelatinized wheat flour. Examples of the flour include wheat flour commonly used in the production of breads, such as strong flour, semi-strong flour, medium-strength flour, weak flour, whole wheat flour, durum flour, and combinations of two or more of these.Among them, strong flour , semi-strong flour, medium-strength flour, whole wheat flour, durum wheat flour, and combinations of any two or more thereof are preferred. Although the wheat flour may contain heat-treated wheat flour, non-heat-treated wheat flour is preferable from the viewpoint of the elasticity and extensibility of the obtained bread dough and the flavor of the obtained bread.

当該パン類生地の原料粉に含まれる副原料としては、パン類の製造に通常用いられる副原料、例えばイースト(生イースト、ドライイースト等);イーストフード;ベーキングパウダー;砂糖、ブドウ糖、果糖、転化糖、水あめ、麦芽糖、乳糖等の糖類;卵又は卵粉;加工もしくは未加工の澱粉類(α化澱粉でないことが好ましい);脱脂粉乳、全脂粉乳、チーズ粉末、ヨーグルト粉末、ホエー粉末などの乳製品;ショートニングやバター、マーガリンやその他の動植物油等の油脂類;乳化剤、膨張剤、増粘剤、甘味料、香料、着色料、アスコルビン酸等の添加剤;食塩等の無機塩類;グルコシダーゼ、グルコースオキシダーゼ、アミラーゼ、リパーゼ、ヘミセルラーゼ等の酵素類;食物繊維、などを適宜使用することができる。本発明のパン類生地の製造に使用される水は、水道水、天然水、精製水など、パン類生地の製造に通常使用することができる水であれば、特に限定されない。又は水の代わりに牛乳、豆乳等のミルクを使用することもできる。 The auxiliary materials contained in the raw material flour of the bread dough include auxiliary materials normally used in bread production, such as yeast (fresh yeast, dry yeast, etc.); yeast food; baking powder; sugar, glucose, fructose, invert Sugars such as sugar, starch syrup, maltose, and lactose; eggs or egg powder; processed or unprocessed starches (preferably not pregelatinized starches); skim milk powder, whole milk powder, cheese powder, yogurt powder, whey powder, etc. Dairy products; fats and oils such as shortening, butter, margarine, and other animal and vegetable oils; additives such as emulsifiers, swelling agents, thickeners, sweeteners, flavors, colorants, and ascorbic acid; inorganic salts such as table salt; glucosidase, Enzymes such as glucose oxidase, amylase, lipase, hemicellulase; dietary fiber, etc. can be used as appropriate. The water used in the production of bread dough of the present invention is not particularly limited as long as it can be normally used in the production of bread dough, such as tap water, natural water, or purified water. Alternatively, milk such as cow's milk or soy milk may be used instead of water.

当該パン類生地における本発明の液種の配合量は、最終的に得られるパン類生地に含まれる全ての穀粉(上記パン類生地の原料粉に含まれる全穀粉及び本発明の液種の原料粉に含まれる全穀粉を含む)の全量中における本発明の液種の原料粉中の全穀粉量が、好ましくは1~30質量%、より好ましくは2~25質量%、さらに好ましくは3~20質量%となる量である。該液種の配合量が少ないと、得られたパン類の食感及び風味が不足することがある。他方、該液種の配合量が多すぎると、パン類生地の弾力が弱くなることで製パン性が低下し、かつ得られたパン類が、ボリュームが小さく、食感が低下しかつ酸味が強すぎるものになる。 The blending amount of the liquid seed of the present invention in the bread dough includes all the flour contained in the final bread dough (all the flour contained in the raw material flour of the bread dough and the raw material of the liquid seed of the present invention). The amount of total flour in the raw material flour of the liquid seed of the present invention is preferably 1 to 30% by mass, more preferably 2 to 25% by mass, and even more preferably 3 to The amount is 20% by mass. If the amount of the liquid type is small, the texture and flavor of the resulting breads may be insufficient. On the other hand, if the amount of the liquid type is too large, the elasticity of the bread dough will become weak, resulting in poor bread-making properties, and the resulting bread will have a small volume, poor texture, and a sour taste. It becomes too strong.

本発明によるパン類の製造方法においては、パン類生地に本発明の液種を配合すること以外は、パン類生地の製造の手法は特に限定されず、例えば、ストレート法、中種法、速成法、液種法、冷凍生地法などの各種常法に従って行うことができる。例えば中種法の場合、本発明の液種は、中種、本捏のどちらの段階で添加してもよいが、本捏の段階で添加することが好ましい。次いで、該液種を配合したパン類生地を、常法に従って、発酵させ、さらに成形、ホイロして、その後加熱することで、パン類を製造することができる。加熱の方法としては、焼成、蒸し、揚げ(油ちょう)などが挙げられる。あるいは、本発明で得られたパン類生地を、そのまま、又は発酵もしくは成形した状態、又は半焼成した状態で冷蔵又は冷凍保存し、必要に応じて解凍及び加熱してパン類を製造してもよい。 In the method for producing bread according to the present invention, the method for producing bread dough is not particularly limited, except that the liquid type of the present invention is blended into bread dough, and examples include the straight method, the dough method, and the quick-dough method. It can be carried out according to various conventional methods such as the method, the liquid seed method, and the frozen dough method. For example, in the case of the medium dough method, the liquid seed of the present invention may be added at either stage of the medium dough or main kneading, but it is preferably added at the stage of main kneading. Next, the bread dough blended with the liquid seed is fermented in accordance with a conventional method, further molded, proofed, and then heated to produce bread. Examples of heating methods include baking, steaming, and frying. Alternatively, the bread dough obtained according to the present invention may be stored as is, in a fermented or molded state, or in a semi-baked state, refrigerated or frozen, and thawed and heated as necessary to produce bread. good.

以下、実施例を挙げて、本発明をさらに詳細に説明するが、本発明はこれらの実施例にのみ限定されるものではない。 EXAMPLES Hereinafter, the present invention will be explained in more detail with reference to Examples, but the present invention is not limited only to these Examples.

試験例1 パンの製造-1
(1)α化小麦粉の製造
表1記載の粗蛋白量を有する小麦粉100質量部に10~20質量部の水を添加し、エクストルーダーにて加圧加熱処理してα化小麦粉1~6(いずれもα化度85%)を調製した。
Test example 1 Bread production-1
(1) Production of pregelatinized flour 100 to 20 parts by mass of water is added to 100 parts by mass of wheat flour having the amount of crude protein listed in Table 1, and subjected to pressure heat treatment using an extruder to pregelatinized flour 1 to 6 ( Both were prepared with a degree of gelatinization of 85%).

(2)液種の製造
表2の配合で、小麦粉(強力粉、粗蛋白量11.8質量%)と(1)で製造したα化小麦粉1~6のいずれかを混合し、これに水(約25℃)、及び生イースト(オリエンタル酵母工業(株)製、「レギュラー」)を添加してパン用ミキサーにて低速で混合した(低速2分高速1分、温度24℃)。得られた混合液を発酵させて[室温条件(温度20℃湿度75%)で45分間発酵→冷蔵保管(4℃で18時間)]、液種1~6を製造した。対照としてα化小麦粉を用いずに液種を製造した。
(2) Production of liquid seeds Mix wheat flour (strong flour, crude protein content 11.8% by mass) with any of the pregelatinized flours 1 to 6 produced in (1) according to the formulation shown in Table 2, and add water ( (approximately 25°C) and fresh yeast (manufactured by Oriental Yeast Industry Co., Ltd., "Regular") were added and mixed at low speed with a bread mixer (low speed 2 minutes, high speed 1 minute, temperature 24°C). The resulting mixture was fermented [fermentation at room temperature (temperature 20°C, humidity 75%) for 45 minutes → refrigerated storage (4°C for 18 hours)] to produce liquid types 1 to 6. As a control, liquid seeds were produced without using gelatinized wheat flour.

(3)パンの製造
(2)で製造した液種を用いて表3の製法に従ってコッペパンを製造した。
(3) Manufacture of bread Coppe bread was manufactured according to the manufacturing method shown in Table 3 using the liquid seed manufactured in (2).

(4)パンの評価
(3)で製造したパンの食感、風味、及び経時耐性を評価した。食感(しっとり感、くちどけ)、及び風味については焼成後2時間後のサンプルで評価した。経時耐性については、焼成後20℃で26時間保管したサンプルと、焼成2時間後のサンプル(保管前)とを比較した。評価は、訓練した10人のパネラーにより下記評価基準に従って行い、その平均値を求めた。結果を表2に示す。
<評価基準>
食感
(しっとり感)
5点:非常にしっとりとした食感である
4点:しっとりとした食感である
3点:ややしっとりとした食感である
2点:ややパサついた食感である(対照の液種を用いた場合と同等)
1点:パサついた食感である
(くちどけ)
5点:非常にくちどけが良好である
4点:くちどけが良好である
3点:問題のないくちどけである
2点:ややくちどけに劣る(対照の液種を用いた場合と同等)
1点:くちどけに劣る
風味
5点:まろやかな酸味と甘みを充分に有し、かつ酸味と甘みのバランスが非常に良く、非常に優れた風味である
4点:まろやかな酸味と甘みを有し、酸味と甘みのバランスが良く、優れた風味である
3点:酸味と甘みのバランスは悪くなく、やや優れた風味である
2点:酸味と甘みのバランスがやや悪く、やや劣った風味である(対照の液種を用いた場合と同等)
1点:、酸味と甘みのバランスが悪く、劣った風味である。
経時耐性(食感)
5点:保管前とほとんど変わらない
4点:保管前と比較してわずかに劣る
3点:保管前と比較してやや劣る
2点:保管前と比較してかなり劣る
1点:保管前と比較して非常に劣る
(4) Evaluation of bread The bread produced in (3) was evaluated for texture, flavor, and resistance over time. The texture (moistness, melt in the mouth) and flavor were evaluated using samples taken 2 hours after baking. Regarding durability over time, a sample stored at 20° C. for 26 hours after firing was compared with a sample 2 hours after firing (before storage). The evaluation was performed by 10 trained panelists according to the following evaluation criteria, and the average value was calculated. The results are shown in Table 2.
<Evaluation criteria>
Texture (moist feeling)
5 points: Very moist texture 4 points: Moist texture 3 points: Slightly moist texture 2 points: Slightly dry texture (compared to the control liquid type) (equivalent to when using)
1 point: It has a dry texture (melt in your mouth)
5 points: Very good melting in the mouth 4 points: Good melting in the mouth 3 points: Melting in the mouth without any problems 2 points: Slightly poor melting in the mouth (same as when using the control liquid type)
1 point: Flavor that is inferior to melting in the mouth 5 points: Has a mellow sourness and sweetness, and has a very good balance between sourness and sweetness, and has an excellent flavor 4 points: Has a mellow sourness and sweetness 3 points: The balance between sourness and sweetness is not bad, and the flavor is slightly good. 2 points: The balance between sourness and sweetness is not bad, and the flavor is slightly inferior. Yes (same as when using the control liquid type)
1 point: The balance between sourness and sweetness is poor, and the flavor is inferior.
Resistance over time (texture)
5 points: Almost the same as before storage 4 points: Slightly inferior to before storage 3 points: Slightly inferior to before storage 2 points: Significantly inferior to before storage 1 point: Compared to before storage very poor

Figure 0007349295000001
Figure 0007349295000001

Figure 0007349295000002
Figure 0007349295000002

Figure 0007349295000003
Figure 0007349295000003

試験例2 パンの製造-2
(1)液種の製造
試験例1(2)と同様の手順で液種を製造した。α化小麦粉としては試験例1(1)で製造したα化小麦粉5を用い、液種の材料における小麦粉、α化小麦粉、及び水の配合は表4~5のとおり変更した。得られた液種を用いて、試験例1(3)及び(4)と同様の手順でコッペパンを製造し、評価した。結果を表4~5に示す。
Test example 2 Bread production-2
(1) Manufacture of liquid seeds A liquid seed was manufactured in the same manner as in Test Example 1 (2). As the pregelatinized wheat flour, pregelatinized wheat flour 5 produced in Test Example 1 (1) was used, and the composition of the flour, pregelatinized wheat flour, and water in the liquid material was changed as shown in Tables 4 and 5. Using the obtained liquid species, Coppépan was produced and evaluated in the same manner as in Test Examples 1 (3) and (4). The results are shown in Tables 4 and 5.

Figure 0007349295000004
Figure 0007349295000004

Figure 0007349295000005
Figure 0007349295000005

Claims (10)

パン類用液種の製造方法であって、
原料粉、イースト、及び水を混合して発酵させることを含み、
該原料粉が、粗蛋白量が8質量%以上の穀粉を原料とするα化穀粉を30質量%以上含み、
該水の配合量が、該α化穀粉1質量部あたり2.5質量部~15質量部且つ該原料粉100質量部あたり200質量部超~500質量部である、
方法。
A method for producing a liquid type for bread, comprising:
Including mixing and fermenting raw flour, yeast, and water,
The raw material flour contains 30% by mass or more of gelatinized flour made from grain flour having a crude protein content of 8% by mass or more,
The amount of water is 2.5 parts by mass to 15 parts by mass per 1 part by mass of the pregelatinized flour, and more than 200 parts by mass to 500 parts by mass per 100 parts by mass of the raw material flour.
Method.
前記イーストが生イーストであり、その配合量が前記原料粉100質量部あたり1質量部~10質量部である、請求項1記載の方法。 The method according to claim 1, wherein the yeast is fresh yeast, and the amount thereof is 1 part by mass to 10 parts by mass per 100 parts by mass of the raw material flour. 前記α化穀粉がα化小麦粉である、請求項1又は2記載の方法。 The method according to claim 1 or 2, wherein the pregelatinized flour is pregelatinized wheat flour. 前記原料粉が非α化小麦粉を含む、請求項1~3のいずれか1項記載の方法。 The method according to any one of claims 1 to 3, wherein the raw material flour includes non-gelatinized wheat flour. 前記原料粉における前記非α化小麦粉と前記α化穀粉との合計含有量が80質量%以上である、請求項記載の方法。 The method according to claim 4 , wherein the total content of the non-gelatinized wheat flour and the gelatinized flour in the raw material flour is 80% by mass or more. 前記発酵が温度0~40℃で0.5~48時間の発酵である、請求項1~5のいずれか1項記載の方法。 The method according to any one of claims 1 to 5, wherein the fermentation is a fermentation at a temperature of 0 to 40°C for 0.5 to 48 hours. 前記α化穀粉のα化度が70%以上である、請求項1~6のいずれか1項記載の方法。 The method according to any one of claims 1 to 6, wherein the degree of gelatinization of the gelatinized flour is 70% or more. 前記α化穀粉が、粗蛋白量が8質量%以上の穀粉100質量部と水5~30質量部をエクストルーダーにて加圧加熱処理して得られたα化穀粉である、請求項1~7のいずれか1項記載の方法。 The pregelatinized flour is a pregelatinized flour obtained by pressurizing and heating 100 parts by mass of flour having a crude protein content of 8% by mass or more and 5 to 30 parts by mass of water using an extruder. 7. The method according to any one of 7. 請求項1~8のいずれか1項記載のパン類用液種を用いることを特徴とする、パン類生地の製造方法。 A method for producing bread dough, comprising using the liquid bread dough according to any one of claims 1 to 8. 前記パン類生地に含まれる穀粉全量中における前記パン類用液種に含まれる原料粉の量が1~30質量%である、請求項9記載の方法。 The method according to claim 9, wherein the amount of raw material flour contained in the liquid bread dough is 1 to 30% by mass in the total amount of flour contained in the bread dough.
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JP2021019556A (en) 2019-07-30 2021-02-18 昭和産業株式会社 Method for manufacturing fermentation leaven, method for manufacturing bakery product dough, and method for manufacturing bakery product

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JP2004321097A (en) 2003-04-25 2004-11-18 Kanegafuchi Chem Ind Co Ltd Hop yeast species
JP2017112989A (en) 2015-12-21 2017-06-29 日清製粉株式会社 Manufacturing method of breads
JP2019024336A (en) 2017-07-26 2019-02-21 日清製粉株式会社 Production method of bread
JP2021019555A (en) 2019-07-30 2021-02-18 昭和産業株式会社 Fermentation dough, bakery product dough using the same, and method for manufacturing bakery product
JP2021019556A (en) 2019-07-30 2021-02-18 昭和産業株式会社 Method for manufacturing fermentation leaven, method for manufacturing bakery product dough, and method for manufacturing bakery product

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