JP4709491B2 - Coating method and coating apparatus - Google Patents

Coating method and coating apparatus Download PDF

Info

Publication number
JP4709491B2
JP4709491B2 JP2004008956A JP2004008956A JP4709491B2 JP 4709491 B2 JP4709491 B2 JP 4709491B2 JP 2004008956 A JP2004008956 A JP 2004008956A JP 2004008956 A JP2004008956 A JP 2004008956A JP 4709491 B2 JP4709491 B2 JP 4709491B2
Authority
JP
Japan
Prior art keywords
base material
coating
substrate
applying
liquid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP2004008956A
Other languages
Japanese (ja)
Other versions
JP2005199190A (en
Inventor
克明 小林
勉 橋本
弘 山崎
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Heavy Industries Ltd
Original Assignee
Mitsubishi Heavy Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Heavy Industries Ltd filed Critical Mitsubishi Heavy Industries Ltd
Priority to JP2004008956A priority Critical patent/JP4709491B2/en
Publication of JP2005199190A publication Critical patent/JP2005199190A/en
Application granted granted Critical
Publication of JP4709491B2 publication Critical patent/JP4709491B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Coating Apparatus (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Description

この発明は、基材に塗工液を塗布する塗工方法および塗工装置に関し、特にリチウム電池用電極を製作する際に用いて好適な塗工方法および塗工装置に関する。   The present invention relates to a coating method and a coating apparatus for applying a coating liquid to a substrate, and more particularly to a coating method and a coating apparatus suitable for use in manufacturing a lithium battery electrode.

従来、各種基材の表面に塗工液を塗布する塗工装置としては、基材搬送手段として異なる位置に少なくとも２つ以上の搬送ローラが設けられ、基材の表面に塗工液を塗布する塗工液塗布手段として塗工液供給部が設けられたものが知られている。
この塗工装置においては、搬送された基材が一方の搬送ローラから他方の搬送ローラへ搬送されながら、その表面に塗工液供給部によって塗工液が塗布されることとなる。 Conventionally, as a coating apparatus for applying a coating liquid to the surface of various base materials, at least two or more transport rollers are provided at different positions as the base material transport means, and the coating liquid is applied to the surface of the base material. As a coating liquid application means, one provided with a coating liquid supply unit is known.
In this coating apparatus, the coating liquid is applied to the surface of the transported base material while being transported from one transport roller to the other transport roller.

また、例えば、特許文献１に記載されるように、表面が粗面化され、その表面粗度及び表面粗さを所定の数値に限定して、金属箔と他の材料との接着性を向上させる金属箔も提案されている。
特開２００１−５９１８７号公報（第２−６頁、第１図） Further, for example, as described in Patent Document 1, the surface is roughened, the surface roughness and the surface roughness are limited to predetermined numerical values, and the adhesion between the metal foil and other materials is improved. Metal foils to be made have also been proposed.
JP 2001-59187 A (page 2-6, FIG. 1)

ところで、上記従来の塗工装置においては、基材を搬送する際、平滑な基材の表面に塗工液を塗布するので、基材と塗膜の付着性が悪くなることによって、塗膜耐久性が悪化し、基材から塗膜が剥離するという問題があった。また、基材と塗膜との間に酸化皮膜等の介在物が介在することによって、基材の導電性が低下するという問題があった。
なお、基材が電池用の電極に用いられる場合には、内部抵抗の発生によって放電容量が阻害されるとともに、電池のサイクル性能が悪化するという問題があった。
また、基材の付着性を向上させるために、塗工装置を使用する以前に基材の表面処理を行った場合、この表面処理に要する費用および時間が増大するため、材料コストの増大を招くという問題があった。 By the way, in the said conventional coating apparatus, when conveying a base material, since a coating liquid is apply | coated to the surface of a smooth base material, coating-film durability is deteriorated because the adhesiveness of a base material and a coating film worsens. The properties deteriorated and the coating film peeled off from the substrate. Moreover, there existed a problem that the electroconductivity of a base material fell by inclusions, such as an oxide film, interposing between a base material and a coating film.
In addition, when a base material was used for the electrode for batteries, there existed a problem that while the discharge capacity was inhibited by generation | occurrence | production of internal resistance, the cycle performance of a battery deteriorated.
In addition, if the surface treatment of the base material is performed before using the coating apparatus in order to improve the adhesion of the base material, the cost and time required for this surface treatment increase, which increases the material cost. There was a problem.

この発明は、このような事情を考慮してなされたもので、材料コストをかけずに塗膜の剥離を防止し、かつ基材の導電性の低下を防止する塗工装置を提供することを目的とする。   The present invention has been made in consideration of such circumstances, and provides a coating apparatus that prevents the peeling of the coating film without incurring material costs and prevents the decrease in the conductivity of the substrate. Objective.

この発明は、上記課題を解決するため、以下の手段を採用する。
請求項１に係る発明は、一対の搬送ローラによって基材を挟んで送り出すことによって該基材を走行させつつ該基材の表面に塗工液を塗布する電池電極用基材の塗工方法において、 前記搬送ローラの表面に凹凸部を形成しておいて、前記搬送ローラによって前記基材を挟んで送り出すことによって、前記凹凸部により前記基材の表面に前記基材と前記塗工液により形成される塗膜との付着性を向上させる粗化加工を施した後、前記表面に前記塗工液を塗布することを特徴とする。 The present invention employs the following means in order to solve the above problems.
The invention according to claim 1, in the coating method of a battery electrode substrate for applying the coating liquid to the surface of the substrate while traveling the base material by sending across the substrate by a pair of conveying rollers An uneven portion is formed on the surface of the conveying roller, and the substrate is sandwiched by the conveying roller and sent out, so that the uneven portion forms the surface of the substrate with the base material and the coating liquid. The coating liquid is applied to the surface after a roughening process for improving adhesion to the coated film.

この発明によれば、基材の表面に粗化加工を施した後、表面に塗工液を塗布することにより、基材の表面と塗工液との塗膜付着性が向上することとなる。   According to this invention, after the roughening process is performed on the surface of the substrate, the coating film adhesion between the surface of the substrate and the coating liquid is improved by applying the coating liquid to the surface. .

請求項２に係る発明は、基材を走行させつつ該基材の表面に塗工液を塗布する電池電極用基材の塗工装置であって、一対の搬送ローラからなり、該一対の搬送ローラによって前記基材を挟んで送りだすことによって、前記基材を走行させる基材搬送手段と、走行する前記基材の表面を前記基材と前記塗工液により形成される塗膜との付着性を向上させる粗面に形成する粗化加工手段と、粗化加工された前記基材の表面に塗工液を塗布する塗工液塗布手段とを備えてなり、前記粗化加工手段が前記搬送ローラの表面に形成された凹凸部であることを特徴とする。 The invention according to claim 2 is a battery electrode base material coating apparatus for applying a coating liquid to the surface of the base material while traveling the base material, and comprises a pair of transport rollers, the pair of transports. Adhesiveness between the base material transporting means for running the base material by feeding the base material between rollers and the coating film formed by the base material and the coating liquid on the surface of the running base material and roughening processing means for forming a rough surface to enhance the roughening processed Ri Na and a coating liquid application means for applying the coating liquid to the surface of the substrate, the roughening processing means the It is the uneven | corrugated | grooved part formed in the surface of a conveyance roller, It is characterized by the above-mentioned.

この発明によれば、粗化加工手段によって基材の表面が粗化されることによって、基材の表面と塗工液塗布手段により塗布された塗工液との塗膜付着性が向上することとなる。   According to this invention, the surface of the base material is roughened by the roughening means, thereby improving the coating film adhesion between the surface of the base material and the coating liquid applied by the coating liquid coating means. It becomes.

また、請求項３に係る発明は、請求項２記載の電池電極用基材の塗工装置において、
前記凹凸部が高さ２０μｍ程度の凹凸で構成されていることを特徴とする。 Also, the invention according to claim 3, in the coating apparatus of a battery electrode substrate according to claim 2,
The concavo-convex portion is formed of concavo-convex portions having a height of about 20 μm.

この発明によれば、搬送ローラの表面に凹凸部が形成されていることにより、基材の表面が粗化加工されることとなる。   According to this invention, the surface of the base material is roughened by forming the irregularities on the surface of the transport roller.

請求項４に係る発明は、請求項２記載の電池電極用基材の塗工装置において、前記搬送ローラのいずれか一方または双方の表面を清掃する清掃手段を備えていることを特徴とする。 According to claim 4 invention, the coating apparatus of a battery electrode substrate according to claim 2, characterized in that it comprises a cleaning means for cleaning the one or both surfaces of the conveying rollers.

この発明によれば、搬送ローラの表面を清掃する清掃手段を備えていることにより、基材の表面に存在する酸化皮膜が除去されることとなる。   According to this invention, by providing the cleaning means for cleaning the surface of the transport roller, the oxide film present on the surface of the substrate is removed.

請求項５に係る発明は、請求項２から４のいずれか一項に記載の電池電極用基材の塗工装置において、前記搬送ローラのいずれか一方または双方に、前記基材と前記塗工液により形成される塗膜との付着性を向上させる付着性向上剤を塗布する液剤塗布手段を備えてなることを特徴とする。
The invention according to claim 5 is the battery electrode substrate coating apparatus according to any one of claims 2 to 4 , wherein the substrate and the coating are provided on one or both of the transport rollers. It is characterized by comprising a liquid application means for applying an adhesion improver that improves the adhesion to a coating film formed from a liquid.

この発明によれば、搬送ローラの表面に付着性向上剤を塗布することにより、その付着性向上剤が基材に転写され、基材の塗膜付着性が改善されることとなる。   According to this invention, by applying the adhesion improver to the surface of the transport roller, the adhesion improver is transferred to the substrate, and the coating film adhesion of the substrate is improved.

以上説明したこの発明の塗工装置においては、以下の効果を奏する。
請求項１に係る発明によれば、基材の表面と塗工液との塗膜付着性が向上することとなるので、塗膜耐久性が向上されるという効果が得られる。 In the coating apparatus of this invention demonstrated above, there exist the following effects.
According to the first aspect of the present invention, the coating film adhesion between the surface of the base material and the coating liquid is improved, so that the effect of improving the coating film durability is obtained.

請求項２に係る発明によれば、基材の表面が粗化されることによって、基材の表面と塗工液との塗膜付着性が向上することとなるので、塗膜耐久性が向上されるという効果が得られる。   According to the invention of claim 2, since the surface of the base material is roughened, the coating film adhesion between the surface of the base material and the coating liquid is improved, so that the coating film durability is improved. The effect that it is done is acquired.

請求項３に係る発明によれば、搬送ローラの表面に凹凸部が形成されていることにより、基材の表面が粗化加工されることとなるので、基材の表面と塗工液との塗膜付着性が向上し、塗膜耐久性が向上されるという効果が得られる。   According to the third aspect of the present invention, since the surface of the base material is roughened by forming the uneven portion on the surface of the transport roller, the surface of the base material and the coating liquid The effect that coating film adhesion improves and coating-film durability is improved is acquired.

請求項４に係る発明によれば、搬送ローラの表面を清掃する清掃手段を備えていることにより、基材の表面に存在する酸化皮膜が除去されることとなるので、基材の導電性の低下を防止することができる。   According to the invention which concerns on Claim 4, since the oxide film which exists in the surface of a base material will be removed by providing the cleaning means which cleans the surface of a conveyance roller, the electroconductive property of a base material is removed. A decrease can be prevented.

請求項５に係る発明によれば、搬送ローラの表面に付着性向上剤を塗布することにより、その付着性向上剤が基材に転写され、基材の塗膜付着性が改善されることとなるので、塗膜耐久性が向上されるという効果が得られる。   According to the invention of claim 5, by applying the adhesion improver to the surface of the transport roller, the adhesion improver is transferred to the substrate, and the coating film adhesion of the substrate is improved. Therefore, the effect that the coating film durability is improved is obtained.

以下、この発明の実施の形態について、図面を参照して説明する。
図１は、この発明における第１の実施の形態を示す図であって、この発明を適用した塗工装置を示す図である。
図１において、塗工装置１０は、基材搬送手段である搬送ローラ２１、２２、２３と、粗化加工手段である凹凸部３０と、塗工液塗布手段である塗工液供給部４０とからなる。 Embodiments of the present invention will be described below with reference to the drawings.
FIG. 1 is a diagram showing a first embodiment of the present invention, and is a diagram showing a coating apparatus to which the present invention is applied.
In FIG. 1, a coating apparatus 10 includes transport rollers 21, 22, and 23 that are base material transport units, a concavo-convex portion 30 that is a roughening processing unit, and a coating liquid supply unit 40 that is a coating liquid coating unit. Consists of.

搬送ローラ２１、２２は、基材１を挟んで一対となるように配置され、それぞれ中心に軸部２１ａ、２２ａを有して円柱状に形成されている。また、搬送ローラ２１、２２の表面には、その周方向全体に、基材１を粗面に粗化加工するために凹凸部３０が形成されている。
搬送ローラ２３は、中心に軸部２３ａを有して円柱状に形成されており、搬送ローラ２１、２２と同期して回転するようになっている。 The conveyance rollers 21 and 22 are disposed so as to be paired with the base material 1 interposed therebetween, and each has a shaft portion 21a and 22a at the center and is formed in a cylindrical shape. Further, an uneven portion 30 is formed on the surfaces of the transport rollers 21 and 22 in order to roughen the base material 1 into a rough surface over the entire circumferential direction.
The conveyance roller 23 has a shaft portion 23 a at the center and is formed in a columnar shape, and rotates in synchronization with the conveyance rollers 21 and 22.

凹凸部３０は、図２に示すように、断面形状が例えば半楕円形、矩形、あるいは三角形となる凸部３１、３２、３３を断続的に有した形状とされており、その高さが２０μｍ程度とされている。   As shown in FIG. 2, the concavo-convex portion 30 is a shape having intermittently convex portions 31, 32, 33 whose cross-sectional shape is, for example, semi-elliptical, rectangular, or triangular, and the height thereof is 20 μm. It is said to be about.

塗工液供給部４０は、塗工液貯留部４１と、この塗工液貯留部４１からの塗工液４を基材１に供給するノズル４２を備えたものである。   The coating solution supply unit 40 includes a coating solution storage unit 41 and a nozzle 42 that supplies the coating solution 4 from the coating solution storage unit 41 to the substrate 1.

次に、上記の構成からなる塗工装置の作用について説明する。
塗工装置１０は、基材１の表面に粗化加工を施した後、その表面に塗工液４を塗布して搬送方向に搬送するものである。
図１に示す塗工装置１０において、図示しない駆動源により搬送ローラ２１、２２を起動して回転させた状態で、搬送ローラ２１、２２の間に基材１を供給すると、この基材１は、搬送ローラ２１、２２によって搬送方向に搬送される。この際、基材１と搬送ローラ２１、２２が接触する位置において、搬送ローラ２１、２２の表面に凹凸部３０が設けられているため、基材１の表面が粗化加工される。すなわち、基材１は、搬送ローラ２１、２２に挟み込まれる際に加えられる接触圧によって、その表面が押さえつけられ、凹凸部３０とかみ合うことによって粗化加工される。 Next, the operation of the coating apparatus having the above configuration will be described.
The coating apparatus 10 performs a roughening process on the surface of the base material 1, and then applies the coating liquid 4 to the surface and transports it in the transport direction.
In the coating apparatus 10 shown in FIG. 1, when the base material 1 is supplied between the transport rollers 21 and 22 in a state where the transport rollers 21 and 22 are activated and rotated by a driving source (not shown), the base material 1 is The paper is transported in the transport direction by the transport rollers 21 and 22. At this time, since the concavo-convex portion 30 is provided on the surface of the transport rollers 21 and 22 at a position where the base material 1 and the transport rollers 21 and 22 are in contact with each other, the surface of the base material 1 is roughened. That is, the surface of the base material 1 is pressed by the contact pressure applied when being sandwiched between the transport rollers 21 and 22, and roughened by engaging with the concavo-convex portion 30.

このように粗化加工されて順次送り出される基材１には、基材１が搬送ローラ２１、２２から送り出された位置において塗工液４が供給され、基材１の表面に塗布される。
この場合、基材１の表面が粗化加工されているため、供給された塗工液４との塗膜付着性が向上することとなる。 Thus, the coating liquid 4 is supplied to the base material 1 which is roughened and sequentially sent out, and is applied to the surface of the base material 1 at the position where the base material 1 is sent out from the transport rollers 21 and 22.
In this case, since the surface of the base material 1 is roughened, the coating film adhesion with the supplied coating liquid 4 is improved.

上記の構成によれば、基材１の表面が粗化加工されることによって、基材１と塗工液４との塗膜付着性が向上するので、塗膜の剥離を防止することができる。   According to said structure, since the coating-film adhesiveness of the base material 1 and the coating liquid 4 improves by roughening the surface of the base material 1, peeling of a coating film can be prevented. .

また、塗工装置１０が基材１の表面を粗化加工する機能を有しており、基材１を塗工装置１０によって搬送する前にその表面を処理する工程が不要となるので、材料コストの低減を図ることができる。   In addition, since the coating apparatus 10 has a function of roughening the surface of the base material 1, a process for treating the surface of the base material 1 before the base material 1 is conveyed by the coating apparatus 10 becomes unnecessary. Cost can be reduced.

図３は、この発明における第１の実施の形態に清掃手段を取付けた場合の塗工装置を部分的に示す図である。
図３においては、上記第１の実施の形態における図１と同一構成要素には同一符号を付し、その説明を省略する。 FIG. 3 is a view partially showing the coating apparatus when the cleaning means is attached to the first embodiment of the present invention.
3, the same components as those in FIG. 1 in the first embodiment are denoted by the same reference numerals, and the description thereof is omitted.

搬送ローラ２１、２２が回転して基材１が搬送される際、基材１が搬送ローラ２１、２２に挟み込まれてその表面が押さえつけられるため、基材１と搬送ローラ２１、２２との間に生じる摩擦によって、搬送ローラ２１、２２の表面には、酸化皮膜あるいは汚染物質が付着する場合がある。
この実施の形態は、上記のようにして搬送ローラ２１、２２の表面に付着した酸化皮膜あるいは汚染物質を除去するための清掃手段として清掃具６０を備えたものである。すなわち、搬送ローラ２１、２２の表面には、清掃具６０が設けられており、その清掃具６０は、その軸方向に移動できるようになっている。 When the transport rollers 21 and 22 rotate and the base material 1 is transported, the base material 1 is sandwiched between the transport rollers 21 and 22 and the surface thereof is pressed down, so that the space between the base material 1 and the transport rollers 21 and 22 is reduced. In some cases, oxide films or contaminants may adhere to the surfaces of the transport rollers 21 and 22 due to friction generated in the above.
In this embodiment, a cleaning tool 60 is provided as a cleaning means for removing oxide films or contaminants attached to the surfaces of the transport rollers 21 and 22 as described above. That is, a cleaning tool 60 is provided on the surfaces of the transport rollers 21 and 22, and the cleaning tool 60 can move in the axial direction.

清掃具６０が搬送ローラ２１、２２の表面で搬送ローラ２１、２２の軸方向に移動することによって、搬送ローラ２１、２２の表面を適宜自動的に清掃する。
この場合、搬送ローラ２１、２２の表面に付着した酸化皮膜あるいは汚染物質が除去されることとなる。 When the cleaning tool 60 moves in the axial direction of the transport rollers 21 and 22 on the surfaces of the transport rollers 21 and 22, the surfaces of the transport rollers 21 and 22 are automatically and appropriately cleaned.
In this case, oxide films or contaminants attached to the surfaces of the transport rollers 21 and 22 are removed.

上記の構成によれば、搬送ローラ２１、２２の表面に付着した酸化皮膜あるいは汚染物質が除去され、すなわち、基材１の導電性を妨げる介在物が除去されるので、基材の導電性の低下を防止することができる。   According to the above configuration, the oxide films or contaminants attached to the surfaces of the transport rollers 21 and 22 are removed, that is, the inclusions that hinder the conductivity of the substrate 1 are removed. A decrease can be prevented.

また、塗工装置１０が基材の表面に形成された酸化皮膜あるいは汚染物質が除去される機能を有しており、基材１を塗工装置１０によって搬送する前にその表面を処理する工程が不要となるので、材料コストの低減を図ることができる。   The coating device 10 has a function of removing an oxide film or contaminants formed on the surface of the base material, and the surface of the base material 1 is processed before being transported by the coating device 10. Therefore, the material cost can be reduced.

図４は、この発明における第１の実施の形態に液剤塗布手段を取付けた場合の塗工装置を部分的に示す図である。
図４においては、上記第１の実施の形態における図１と同一構成要素には同一符号を付し、その説明を省略する。
搬送ローラ２１、２２の表面には、液剤塗布手段７０が設けられている。液剤塗布手段７０は、刷毛７１と液剤供給ノズル７２を備えている。 FIG. 4 is a view partially showing the coating apparatus when the liquid agent applying means is attached to the first embodiment of the present invention.
In FIG. 4, the same components as those in FIG. 1 in the first embodiment are denoted by the same reference numerals, and the description thereof is omitted.
A liquid application means 70 is provided on the surfaces of the transport rollers 21 and 22. The liquid application means 70 includes a brush 71 and a liquid supply nozzle 72.

液剤塗布手段７０は、液剤供給ノズル７２から付着性向上剤を供給して、刷毛７１が移動することによって、搬送ローラ２１、２２の表面全体に付着性向上剤を塗布できるようにしたものである。搬送ローラ２１、２２が回転すると、搬送ローラ２１、２２の表面に塗布された付着性向上剤は、基材１の表面に転写されて付着する。
この場合、搬送ローラ２１、２２の表面に付着した付着性向上剤が基材１の表面に転写されることにより、基材１と塗膜との付着性が向上することとなる。 The liquid application means 70 supplies an adhesion improver from the liquid supply nozzle 72 and moves the brush 71 so that the adhesion improver can be applied to the entire surface of the transport rollers 21 and 22. . When the transport rollers 21 and 22 rotate, the adhesion improver applied to the surfaces of the transport rollers 21 and 22 is transferred to the surface of the substrate 1 and adheres thereto.
In this case, the adhesion improver adhered to the surfaces of the transport rollers 21 and 22 is transferred to the surface of the substrate 1, thereby improving the adhesion between the substrate 1 and the coating film.

上記の構成によれば、搬送ローラ２１、２２の表面に付着した付着性向上剤が基材１の表面に転写されることにより、基材１と塗膜との付着性が向上するので、塗膜の剥離を防止することができる。   According to the above configuration, the adhesion improver attached to the surfaces of the transport rollers 21 and 22 is transferred to the surface of the substrate 1, thereby improving the adhesion between the substrate 1 and the coating film. Peeling of the film can be prevented.

また、塗工装置１０が基材の表面に界面活性化等による処理が施される機能を有しており、基材１を塗工装置１０によって搬送する前にその表面を処理する工程が不要となるので、材料コストの低減を図ることができる。   In addition, the coating apparatus 10 has a function of performing a surface activation process on the surface of the base material, and a process of treating the surface of the base material 1 before it is transported by the coating apparatus 10 is unnecessary. Thus, the material cost can be reduced.

このように、塗工装置１０によって、基材１の塗膜耐久性の向上および導電性向上の効果を得ることができるが、特に、基材１が電池用の電極として用いられる場合、これらの効果によって、内部抵抗が低減され、放電容量が向上されるとともに、電池のサイクル性能が向上するという効果を得ることができる。   As described above, the coating apparatus 10 can obtain the effect of improving the coating film durability and the conductivity of the base material 1, and in particular, when the base material 1 is used as an electrode for a battery, these The effect can reduce the internal resistance, improve the discharge capacity, and improve the cycle performance of the battery.

なお、搬送ローラ２１、２２は、塗工される前の基材１の表面形状を任意に調整するため、その材質、表面粗さ、表面形状、またはそれぞれを押付ける際の接触圧を任意に変化させてよい。
また、搬送ローラ２１、２２の表面に設けられた清掃具６０は、搬送ローラ２１、２２のどちらか一方のみに設けられてもよい。
また、搬送ローラ２１、２２の表面に設けられた液剤塗布手段７０は、搬送ローラ２１、２２のどちらか一方のみに設けられてもよい。 In addition, since the conveyance rollers 21 and 22 adjust the surface shape of the base material 1 before coating arbitrarily, the material, surface roughness, surface shape, or the contact pressure at the time of pressing each is arbitrarily set You can change it.
Further, the cleaning tool 60 provided on the surface of the transport rollers 21 and 22 may be provided only on one of the transport rollers 21 and 22.
Further, the liquid agent applying means 70 provided on the surfaces of the transport rollers 21 and 22 may be provided only on one of the transport rollers 21 and 22.

この発明における第１の実施の形態に係る塗工装置の概略を示す断面図である。It is sectional drawing which shows the outline of the coating apparatus which concerns on 1st Embodiment in this invention. この発明における第１の実施の形態に係る塗工装置に備えられた搬送ローラを示す図であって、（ａ）はその断面図、（ｂ）はその部分拡大図である。It is a figure which shows the conveyance roller with which the coating apparatus which concerns on 1st Embodiment in this invention was equipped, Comprising: (a) is the sectional drawing, (b) is the elements on larger scale. この発明において、第１の実施の形態に係り清掃手段が備えられた塗工装置の概略を示す部分斜視図である。In this invention, it is a fragmentary perspective view which shows the outline of the coating device provided with the cleaning means concerning 1st Embodiment. この発明において、第１の実施の形態に係り液剤塗布手段が備えられた塗工装置の概略を示す部分斜視図である。In this invention, it is a fragmentary perspective view which shows the outline of the coating device provided with the liquid agent application means according to the first embodiment.

符号の説明Explanation of symbols

１ 基材
１０ 塗工装置
２１、２２、２３ 搬送ローラ
３０ 凹凸部
４０ 塗工液供給部
６０ 清掃具
７１ 刷毛
７２ 液剤供給ノズル DESCRIPTION OF SYMBOLS 1 Base material 10 Coating apparatus 21, 22, 23 Conveyance roller 30 Uneven part 40 Coating liquid supply part 60 Cleaning tool 71 Brush 72 Liquid supply nozzle

Claims (5)

一対の搬送ローラによって基材を挟んで送り出すことによって該基材を走行させつつ該基材の表面に塗工液を塗布する電池電極用基材の塗工方法において、
前記搬送ローラの表面に凹凸部を形成しておいて、前記搬送ローラによって前記基材を挟んで送り出すことによって、前記凹凸部により前記基材の表面に前記基材と前記塗工液により形成される塗膜との付着性を向上させる粗化加工を施した後、前記表面に前記塗工液を塗布することを特徴とする電池電極用基材の塗工方法。 In the coating method of a battery electrode substrate for applying the coating liquid to the surface of the substrate while traveling the base material by sending across the substrate by a pair of conveying rollers,
An uneven portion is formed on the surface of the conveying roller, and the substrate is sandwiched by the conveying roller and sent out, so that the uneven portion is formed on the surface of the substrate by the base material and the coating liquid. A coating method for a battery electrode substrate, comprising: applying a roughening process to improve adhesion to a coating film to be coated, and then applying the coating liquid to the surface. 基材を走行させつつ該基材の表面に塗工液を塗布する電池電極用基材の塗工装置であって、
一対の搬送ローラからなり、該一対の搬送ローラによって前記基材を挟んで送りだすことによって、前記基材を走行させる基材搬送手段と、走行する前記基材の表面を前記基材と前記塗工液により形成される塗膜との付着性を向上させる粗面に形成する粗化加工手段と、粗化加工された前記基材の表面に塗工液を塗布する塗工液塗布手段とを備えてなり、
前記粗化加工手段が前記搬送ローラの表面に形成された凹凸部であることを特徴とする電池電極用基材の塗工装置。 A battery electrode base material coating apparatus for applying a coating liquid to the surface of the base material while running the base material,
A pair of transport rollers, and a base material transport means for running the base material by feeding the base material between the pair of transport rollers; A roughening means for forming a rough surface for improving adhesion to a coating film formed by the liquid, and a coating liquid application means for applying a coating liquid to the surface of the roughened base material. Do Te Ri,
The battery electrode substrate coating apparatus, wherein the roughening means is a concavo-convex portion formed on a surface of the transport roller . 請求項２記載の電池電極用基材の塗工装置において、
前記凹凸部が高さ２０μｍ程度の凹凸で構成されていることを特徴とする電池電極用基材の塗工装置。 In the coating apparatus of the base material for battery electrodes of Claim 2 ,
The coating device for a battery electrode substrate, wherein the uneven portion is formed of unevenness having a height of about 20 μm. 請求項２記載の電池電極用基材の塗工装置において、
前記搬送ローラのいずれか一方または双方の表面を清掃する清掃手段を備えていることを特徴とする電池電極用基材の塗工装置。 In the coating apparatus of the base material for battery electrodes of Claim 2 ,
A coating apparatus for a battery electrode substrate, comprising a cleaning means for cleaning one or both surfaces of the transport roller. 請求項２から４のいずれか一項に記載の電池電極用基材の塗工装置において、
前記搬送ローラのいずれか一方または双方に、前記基材と前記塗工液により形成される塗膜との付着性を向上させる付着性向上剤を塗布する液剤塗布手段を備えてなることを特徴とする電池電極用基材の塗工装置。 In the coating apparatus of the base material for battery electrodes as described in any one of Claim 2 to 4 ,
One or both of the transport rollers are provided with a liquid application means for applying an adhesion improver that improves the adhesion between the substrate and the coating film formed by the coating liquid. Battery electrode base material coating device.
JP2004008956A 2004-01-16 2004-01-16 Coating method and coating apparatus Expired - Lifetime JP4709491B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2004008956A JP4709491B2 (en) 2004-01-16 2004-01-16 Coating method and coating apparatus

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2004008956A JP4709491B2 (en) 2004-01-16 2004-01-16 Coating method and coating apparatus

Publications (2)

Publication Number Publication Date
JP2005199190A JP2005199190A (en) 2005-07-28
JP4709491B2 true JP4709491B2 (en) 2011-06-22

Family

ID=34822129

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2004008956A Expired - Lifetime JP4709491B2 (en) 2004-01-16 2004-01-16 Coating method and coating apparatus

Country Status (1)

Country Link
JP (1) JP4709491B2 (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10629947B2 (en) 2008-08-05 2020-04-21 Sion Power Corporation Electrochemical cell
JP4957167B2 (en) * 2006-10-13 2012-06-20 パナソニック株式会社 Current collector, electrode plate for non-aqueous electrolyte secondary battery, and method for producing non-aqueous electrolyte secondary battery using the same
DE102007001806A1 (en) * 2007-01-12 2008-07-17 Airbus Deutschland Gmbh Coating of a mounting rail
CA2678616C (en) * 2007-04-18 2015-12-22 Industrie De Nora S.P.A. Electrodes with mechanically roughened surface for electrochemical applications
CN102576855B (en) 2009-08-24 2015-11-25 赛昂能源有限公司 For the stripping system of electrochemical cell
EP2721665B1 (en) 2011-06-17 2021-10-27 Sion Power Corporation Plating technique for electrode
CN103947027B (en) 2011-10-13 2016-12-21 赛昂能源有限公司 Electrode structure and manufacture method thereof
US10862105B2 (en) 2013-03-15 2020-12-08 Sion Power Corporation Protected electrode structures
CN105051944B (en) 2013-03-15 2019-04-02 锡安能量公司 Protected electrode structure and method
CN110465442B (en) * 2019-09-12 2020-06-09 淮北市作科新能源有限公司 Coating operation system for lithium battery production

Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6046240A (en) * 1984-04-28 1985-03-13 株式会社アイジ−技術研究所 Production unit for colored zinc iron plate on which embossed pattern is formed
JPH0864201A (en) * 1994-08-23 1996-03-08 Sumitomo Electric Ind Ltd Negative electrode for lithium battery and manufacture thereof
JPH10162816A (en) * 1996-12-03 1998-06-19 Toshiba Battery Co Ltd Electrode for secondary battery and manufacture thereof
JP2000048823A (en) * 1998-05-29 2000-02-18 Matsushita Electric Ind Co Ltd Non-sintering type electrode and manufacture thereof
JP2000200610A (en) * 1999-01-08 2000-07-18 Hitachi Ltd Copper foil for lithium battery, lithium secondary battery, its manufacture, and manufacturing device for negative electrode material for lithium battery
JP2001059187A (en) * 1999-08-20 2001-03-06 Dainippon Printing Co Ltd Surface-roughened metallic foil
JP2001273901A (en) * 2000-03-27 2001-10-05 Yuasa Corp Electrode material
JP2002079466A (en) * 2000-09-07 2002-03-19 Hitachi Cable Ltd Surface roughening method for rolled copper foil
JP2002211159A (en) * 2001-01-18 2002-07-31 Fuji Photo Film Co Ltd Method for manufacturing support for lithographic printing plate, support for lithographic printing plate and lithographic printing original plate
JP2003157839A (en) * 2001-11-20 2003-05-30 Fukuda Metal Foil & Powder Co Ltd Negative electrode material for lithium battery and its manufacturing method
JP2003297364A (en) * 2002-03-29 2003-10-17 Yuasa Corp Electrode material for electrochemical cell and electrochemical cell using it
JP2003340356A (en) * 2002-05-28 2003-12-02 Toppan Printing Co Ltd Coating method

Patent Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6046240A (en) * 1984-04-28 1985-03-13 株式会社アイジ−技術研究所 Production unit for colored zinc iron plate on which embossed pattern is formed
JPH0864201A (en) * 1994-08-23 1996-03-08 Sumitomo Electric Ind Ltd Negative electrode for lithium battery and manufacture thereof
JPH10162816A (en) * 1996-12-03 1998-06-19 Toshiba Battery Co Ltd Electrode for secondary battery and manufacture thereof
JP2000048823A (en) * 1998-05-29 2000-02-18 Matsushita Electric Ind Co Ltd Non-sintering type electrode and manufacture thereof
JP2000200610A (en) * 1999-01-08 2000-07-18 Hitachi Ltd Copper foil for lithium battery, lithium secondary battery, its manufacture, and manufacturing device for negative electrode material for lithium battery
JP2001059187A (en) * 1999-08-20 2001-03-06 Dainippon Printing Co Ltd Surface-roughened metallic foil
JP2001273901A (en) * 2000-03-27 2001-10-05 Yuasa Corp Electrode material
JP2002079466A (en) * 2000-09-07 2002-03-19 Hitachi Cable Ltd Surface roughening method for rolled copper foil
JP2002211159A (en) * 2001-01-18 2002-07-31 Fuji Photo Film Co Ltd Method for manufacturing support for lithographic printing plate, support for lithographic printing plate and lithographic printing original plate
JP2003157839A (en) * 2001-11-20 2003-05-30 Fukuda Metal Foil & Powder Co Ltd Negative electrode material for lithium battery and its manufacturing method
JP2003297364A (en) * 2002-03-29 2003-10-17 Yuasa Corp Electrode material for electrochemical cell and electrochemical cell using it
JP2003340356A (en) * 2002-05-28 2003-12-02 Toppan Printing Co Ltd Coating method

Also Published As

Publication number Publication date
JP2005199190A (en) 2005-07-28

Similar Documents

Publication Publication Date Title
JP4709491B2 (en) Coating method and coating apparatus
US10960442B2 (en) Coating line cleaning apparatus
TW201532689A (en) Cleaning device
JP4644726B2 (en) Coating device
JP4719903B2 (en) Coating method and coating apparatus for coating agent
JP4186611B2 (en) Electronic component holding jig and electronic component handling method
JP2014147855A (en) Tape winding device
JP2002045775A (en) Coating apparatus
JP2013257987A (en) Peeling device of coating film, manufacturing apparatus of separator for secondary battery, peeling method of coating film, and manufacturing method of separator for secondary battery
JP2015218008A (en) Coating system
JP3070565B2 (en) Application method
JP6629662B2 (en) Intermittent coating apparatus and method
CN212856762U (en) Glued copper foil dust removal device and copper foil gluing equipment
JP2006282285A (en) Dust disposal device in roller conveyor
JP6175875B2 (en) Electrode manufacturing method
JP2006080187A (en) Roll brush, substrate washing device
JP2001246610A (en) Method and apparatus for manufacturing ceramic green sheet
JP2006021092A (en) Cleaning system
JPH08236415A (en) Roll coater
JP2000133934A (en) Device for filling conductor into ceramic board
JPH075895Y2 (en) Roll coater
JP2018149492A (en) Gravure coating device
JP2015217320A (en) Coating system
JP4497037B2 (en) Corona discharge treatment method
JP2003284981A (en) Coating apparatus

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20061225

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20090512

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20090526

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20090723

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A821

Effective date: 20090724

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20100525

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20100726

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A821

Effective date: 20100727

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20110222

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20110318

R151 Written notification of patent or utility model registration

Ref document number: 4709491

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R151

S111 Request for change of ownership or part of ownership

Free format text: JAPANESE INTERMEDIATE CODE: R313113

R350 Written notification of registration of transfer

Free format text: JAPANESE INTERMEDIATE CODE: R350

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

EXPY Cancellation because of completion of term