JP4132943B2 - Positive photosensitive film forming method - Google Patents

Positive photosensitive film forming method Download PDF

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JP4132943B2
JP4132943B2 JP2002122142A JP2002122142A JP4132943B2 JP 4132943 B2 JP4132943 B2 JP 4132943B2 JP 2002122142 A JP2002122142 A JP 2002122142A JP 2002122142 A JP2002122142 A JP 2002122142A JP 4132943 B2 JP4132943 B2 JP 4132943B2
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positive photosensitive
plate
coating
roll
photosensitive composition
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JP2003316024A (en
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勉 佐藤
核 重田
龍男 重田
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Think Laboratory Co Ltd
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Think Laboratory Co Ltd
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Description

【0001】
【発明の属する技術分野】
本願発明は、近赤外波長域のレーザーに露光感応して該感応部が現像液に可溶になる近赤外波長域レーザー感応性を有するポジ型感光性組成物をグラビア印刷用の被製版ロールへ塗布して白化を生じずかつ残留溶剤を所要濃度以下としたポジ型感光膜を形成する方法に関する。
【0002】
【従来の技術】
グラビア印刷ロールの製版方法の一つとして、被製版ロールの硫酸銅メッキ面に感光膜を塗布形成しレーザーにより画像を焼き付けてから現像し食刻しレジスト剥離してクロムメッキする、いわゆるエッチング法が行なわれている。
従来のエッチング法では、被製版ロールにネガ型の感光膜を塗布し塗布膜を室温で乾固してネガ型感光膜とし、アルゴンイオンレーザーにより焼付けを行なっており、ポジ型感光膜を形成して近赤外波長域のレーザーにより焼付けすることは行なわれていない。
【0003】
【発明が解決しようとする課題】
アルゴンイオンレーザーと近赤外波長域のレーザーのビーム径が同じ大きさであるならば、レーザーの解像度は、ネガ型よりもポジ型の方が高解像度になる。
又、ポジ型感光性組成物(例えば、特開平10−26826、特開平10−90881、特開平10−161304、特開平11−231515)の感光膜を近赤外波長域のレーザーでポジ画像を焼き付ける方が、ネガ型感光性組成物の感光膜をアルゴンイオンレーザーでネガ画像を焼き付けるよりもパターンの切れが良い。
0004
そこで、グラビア印刷ロールの製版方法の一つとしてのエッチング法について、被製版ロールの硫酸銅メッキ面にポジ型感光性組成物の感光膜を塗布形成し近赤外波長域のレーザーでポジ画像を焼き付けてから現像し食刻しレジスト剥離してクロムメッキする改良をテストしたところ、近赤外波長域のレーザーでポジ画像を焼き付けることができない二つの問題点があることが分かった。
0005
一つは、ポジ型感光性組成物を塗布し塗布膜をドライヤーで乾かしてレーザー露光して現像したところ、現像ができたところとできなかったところとがあった。いろいろな温度で塗布膜を乾燥して現像を繰り返したところ、残留溶剤がおよそ4%であるときは近赤外波長域のレーザーでポジ画像を焼き付けることができず、残留溶剤がおよそ2%〜3%以下になるようにすると、近赤外波長域のレーザーでポジ画像を焼き付けられることが分かった。従って、バーニング処理を行なって残留溶剤がおよそ2%〜3%以下になるようにする必要があることが分かった。
0006
他の一つは、ポジ型感光性組成物を塗布し塗布膜をバーニング処理を十分に行なって残留溶剤がおよそ2%〜3%以下になるようにしても、うまく現像ができる場合と全く現像ができない場合とを生じた。毎日の実験の結果、晴れの日は現像がうまくいき、雨の日は現像が全くできなかった。
現像が全くできない日に形成した感光膜を調べたところ、白化現象を生じていることが判明した。
0007
白化現象は、分子の集まり方が密な部分(結晶部分)と疎の部分(非結晶部分)とからできている高分子の、非結晶部分がガラス転移点Tgよりも温度降下したときに吸湿して白色になりガラス化する現象であり、湿度が多い冷気中で起こりやすい。25℃の恒温室で被製版ロールに塗布したポジ型感光性組成物が白化現象を起こすのは、ポジ型感光性組成物に含まれる溶剤が塗布膜から潜熱を奪って蒸発し、塗布膜の非結晶部分がガラス転移点Tgよりも温度降下するとともに結露吸湿を行なうからと考えられる。
0008
そこで、製版室の湿度を40%以下に抑えることが白化現象を回避するために有効になるが、大形除湿装置の設備コスト・ランニングコストが極めて高くつき、大形除湿装置の設置スペースが必要になり既存の製版室では設置が困難である。
従って、大形除湿装置を設置しない他の解決方法が求められた。
0009
鋭意研究したところ、一つの解決法は、ポジ型感光性組成物を被製版ロールに塗布して蒸発面積を極大にしたときに溶剤の気化に伴う潜熱で塗布膜の温度をガラス転移点以下に温度降下させないようにすることが考えられた。具体的には、IPA等の蒸発速度が速く蒸発潜熱量が大きい溶剤の割合を少なくして蒸発速度が小さく蒸発潜熱量が小さい低沸点溶剤を混合することが考えられた。又、この低沸点溶剤は、水分を寄せない性質が必要であると考えられた。又、低沸点ポリマー又は低沸点可塑剤を所要割合含有させてガラス転移点を下げた改質したポジ型感光性組成物の使用が考えられた。
0010
そこで、低沸点溶剤を混合したポジ型感光性組成物を処方して感光膜の形成を行ない、現像したところ、良好な現像ができた。低沸点ポリマーを所要割合含有させてガラス転移点を下げた改質したポジ型感光性組成物の使用した場合でも良好な現像ができた。さらに、低沸点可塑剤を所要割合含有させてガラス転移点を下げた改質したポジ型感光性組成物の使用した場合でも良好な現像ができた。
0011
低沸点溶剤を混合したポジ型感光性組成物を処方して感光膜の形成を行ない、現像するテストを繰り返したところ、一日の塗布作業の開始の一本目の被製版ロールの感光膜の露光・現像は良好であったが、二本目以降は露光・現像が次第に悪くなり、数本目以降は、悪い状態に落ち着いてしまうことが分かった。
丹念に調べたところ、一日の塗布作業の開始の一本目の被製版ロールの感光膜には白化が起きていないが、二本目の被製版ロールでは塗り終わり近くで感光膜に白化が起きており、三本目以降の被製版ロールでは白化が起きている幅が次第に大きくなっていたことが分かった。
0012
いずれの被製版ロールについてもバーニング処理を必要十分に行なっているので、原因は白化現象と考えられた。
ポジ型感光性組成物を貯留するタンクの蓋を閉めて暫く時間を置いて、塗布作業を再開すると、やはり前記と同様に、一本目と二本目と三本目の被製版ロールとで前記と同様に白化現象が生ずる差異があることが分かった。
0013
このことから、ポジ型感光性組成物を貯留するタンクの蓋を開けて塗布作業を行なうと、塗布ロールに付着したポジ型感光性組成物の溶剤が塗布ロールから潜熱を奪って蒸発し、温度低下する塗布ロールとタンク内に貯留されるポジ型感光性組成物との間で熱交換が行なわれ、次第に、タンク内に貯留されるポジ型感光性組成物の温度が下がっていき、該温度降下したポジ型感光性組成物が塗布ロールの表面に付着して被製版ロールに塗布されロール表面で溶剤が蒸発するときには、塗布膜の温度がガラス転移点Tgよりも下がることが原因であると考えられた。
0014
そこで、幾つかの解決法を試みた。ロールを30℃に温めてポジ型感光性組成物を塗布したところ白化現象が生じなかった。又、タンクを保温材で覆いかつタンクをヒータで温めポジ型感光性組成物の温度を25℃に保持したところ白化現象が生じなかった。いずれの場合も、露光・現像が良好に行なわれた。
そして、冬の寒気の時期を考えて、塗布装置で良好に塗布したロールを取出してバーニング処理を行なう前に冷気に触れさせたところ、白化現象が生じたことが分かった。
0015
本願発明は、上述した点に鑑み案出したもので、近赤外波長域のレーザーに露光感応して該感応部が現像液に可溶になる近赤外波長域レーザー感応性を有するポジ型感光性組成物をグラビア印刷用の被製版ロールに塗布して該塗布膜をバーニングするもので、塗布工程、並びに塗布工程とバーニング工程との間で、ポジ型感光性組成物の溶剤の気化に伴う潜熱で塗布膜の温度をガラス転移点以下に温度降下させないようにするので、製版室に大形除湿装置を設備して湿度を大幅に下げることをしなくても白化が生じないとともに、残留溶剤を所要濃度以下になり近赤外波長域のレーザーにより露光感応し得る良好なポジ型感光膜を形成することができる、ポジ型感光膜形成方法を提供することを目的としている。
0016
【課題を解決するための手段】
請求項1に記載の発明は、近赤外波長域のレーザーに露光感応して該感応部が現像液に可溶になる近赤外波長域レーザー感応性を有するポジ型感光性組成物をグラビア印刷用の被製版ロールに対して回転接触する塗布ロール、又は、一定ギャップを保って回転するノンインパクト塗布ロール、又はキスコーター等の塗布手段により塗布して白化が生じないポジ型感光膜を形成する方法であって、(a)タンク内に貯留されるポジ型感光性組成物を所要温度に温めること、(b)塗布ロールを熱線で所要温度に温めること、及び(e)被製版ロールを所要温度に温めることの少なくともいずれか1つを行なうことにより、ポジ型感光性組成物を塗布膜の温度がガラス転移点以下に温度降下しないように被製版ロールに均一に塗布し、引き続いて、塗布膜の温度をガラス転移点以下に温度降下させることなく該塗布膜をバーニングして残留溶剤が近赤外波長域のレーザーがポジ型感光膜を露光感応させ得る濃度以下になるように乾固することを特徴とするポジ型感光膜形成方法を提供するものである。
0017
請求項2に記載の発明は、被製版ロールへのポジ型感光性組成物の塗布は、被製版ロールを出し入れできる開閉自在な扉を有する密閉形でありかつ可燃気体を排気し得るケーシング内に装備された塗布手段により行ない、被製版ロールに塗布した塗布膜のバーニングは、同塗布手段に取着される被製版ロールに対応して近接するように装備されたバーニング用ヒーターによりポジ型感光性組成物の塗布が完了後にかつ防爆条件を整えてから行なうことを特徴とする請求項1に記載のポジ型感光膜形成方法を提供するものである。
0018
請求項3に記載の発明は、被製版ロールへのポジ型感光性組成物の塗布は、ポジ型感光性組成物の溶剤の気化に伴う潜熱で塗布膜がガラス転移点以下に温度降下しないように被製版ロールの雰囲気を所要温度に保つか、及び/又は、被製版ロールの温度を上げた条件下で行なうことを特徴とする請求項1又は請求項2に記載のポジ型感光膜形成方法を提供するものである。
0019
【発明の実施の形態】
本願発明は、近赤外波長域のレーザーに露光感応して該感応部が現像液に可溶になる近赤外波長域レーザー感応性を有するポジ型感光性組成物をグラビア印刷用の被製版ロールへ塗布して白化を生じずかつ残留溶剤を所要濃度以下としたポジ型感光膜を形成する方法である。
0020
本願発明は、ポジ型感光性組成物を被製版ロールに塗布して該塗布膜をバーニングするもので、塗布工程、並びに塗布工程とバーニング工程との間で、ポジ型感光性組成物の溶剤の気化に伴う潜熱で塗布膜の温度をガラス転移点以下に温度降下させないようにするとともに、バーニングして近赤外波長域のレーザーにより露光感応し得るように残留溶剤を所要濃度以下にして乾固したポジ型感光膜を得るものである。
0021
ポジ型感光性組成物を被製版ロールに塗布する方法は、公知の方法を採用できる。
一応説明すると、被製版ロールへのポジ型感光性組成物の塗布は、塗布装置に被製版ロールを水平にして両端チャックして低速回転させると共に、被製版ロールの下側を該被製版ロールの一端に対応して上昇して所要接近してから他端へ移動しうるタンクに付設された塗布ロール(スポンジロール)をタンクに貯留するポジ型感光性組成物に一部浸漬して回転させるとともに被製版ロールに弾力的に極めて軽く接触させて被製版ロールの一端から他端へ移動させてポジ型感光性組成物の塗布を行なう。
又、塗布ロールは電歪アクチュエータ或いはボイスコイル等の駆動により被製版ロールに対して極めて小さいギャップを維持するように浮動的に近接制御して被製版ロールへの塗布を行なうようにしても良い。
0022
ポジ型感光性組成物は、例えば、特開平10−26826、特開平10−90881、特開平10−161304、特開平11−231515に開示され販売されているポジ型感光性組成物の溶剤を水分を寄せない性質を有する低沸点溶剤で置き換えて建浴することが白化防止に大きな効果がある。IPAに替わる低沸点溶剤として、プロピレングリコールモノメチルエーテルやノルマルプロパノール等を用いると、蒸発潜熱量が小さくなり、塗布膜の温度降下が小さく結露吸湿が減少する効果がある。
又、分子量が大きく低沸点である、ポリマー例えばフェノールノボラック変性樹脂又は可塑剤例えばフタル酸エステルを所要割合含有させてガラス転移点を下げた改質したポジ型感光性組成物を使用することが白化防止に大きな効果がある。
0023
塗布と塗布膜を加熱乾固するバーニングは、被製版ロールを出し入れできる開閉自在な扉を有する密閉形であるケーシング内で行なわれ、塗布工程とバーニング工程との間では、被製版ロールを出し入れが行なわれないことが好ましい。
このため、ケーシングを構成する側面パネル又は底面パネルを密閉形のヒータで加熱し温度制御してケーシング内の雰囲気をポジ型感光性組成物中の溶剤に対して爆発の危険がない所要の温度に制御できるケーシングを構成して、ケーシング内にロールチャック回転手段と塗布装置とバーニング用ヒーターを装備し、被製版ロールへのポジ型感光性組成物の塗布に際して、ポジ型感光性組成物の溶剤の気化に伴う潜熱で塗布膜がガラス転移点以下に温度降下しないように被製版ロールの雰囲気を所要温度に保てるようにするのが良い。
なお、被製版ロールについて所要温度になるように予熱して、このましくは30℃位に予熱してケーシング内に収容することが白化現象を回避する上で好ましい。
0024
ロールチャック回転手段は、前記ケーシング内に左右配置に二基備えられ、各一基に二本の被製版ロールを水平に両端チャック自在でありかつ所要低速回転自在であることが好ましい。そして、被製版ロールは、ポジ型感光性組成物の塗布膜がガラス転移点以下に温度降下しないように所要温度、例えば、30℃になるように予熱しておいて、産業ロボットで水平に両端チャックして全面パネル上部の扉を下降し該扉開口を通してケーシング内に収容しロールチャック回転手段にチャックさせるのが好ましい。
0025
塗布装置は、ロールチャック回転手段がケーシング内に左右配置に二基備えられるときはケーシング内の左右配置に取着される二本の被製版ロールに共通の塗布装置となる。
なお、ロールチャック回転手段が一基備えられていても良い。
0026
図1は、本願発明のポジ型感光膜を形成する方法を実施するためのポジ型感光膜形成装置の正面図を示す。
0027
ケーシング1は、全面上部にロール出し入れ用開口1a,1aを有し上昇してロール出し入れ用開口1a,1aを閉じるロール出し入れ用扉2,2を有し、さらに、開扉時に駆動装置(図示しない)により上昇されて戸袋壁1b内に収容され戸袋壁1bの下側を塗布装置の通過を許し、又、閉扉時に下降されて内部空間を左右に仕切る昇降扉3を備えている。ケーシング1は、ケーシング上面の左端及び右端に連通して備える排気ダクト4,4を介してケーシング内の気体を排ガス回収装置(図示しない)に回収されるようになっている。ケーシング上面の中央部に連通するように備えられた給気ダクト5から戸袋壁1b内へ暖気の給送が行なわれるようになっており、戸袋壁1b内の暖気は二重壁構造の昇降扉3の両側の耐熱性メッシュ材3aを通流してケーシング内の左側空間と右側空間に流れ込むようになっていて、左側空間と右側空間との間を引火性ガスが通流しないようにして防爆を行なうようになっている。
0028
ケーシング1内の左側空間と右側空間にはロールチャック回転手段6が各一基備えられ、共通の塗布装置7がレール8上を走行してケーシング1内の左側空間と右側空間を往復動自在に装備されている。
0029
ロールチャック回転手段6は、モータ(図示しない)により回転駆動される駆動側チャック6aと、可動テーブル(図示しない)に設けられロール長さに対応して移動しテイルチャック6bとで100φmm×800mm〜300φmm×2000mmの大きさの被製版ロールRをチャックすることができ所要低速度で回転するようになっている。
0030
塗布装置7は、ロールチャック回転手段6にチャックされた被製版ロールRに沿ってその下側を往復走行する走行台車7aと、走行台車上に装備された昇降テーブル7bと、昇降テーブル上に装備され溢流方式でポジ型感光性組成物の液面レベルが一定になるように管理されるタンク7cと、走行台車上に装備されポジ型感光性組成物を貯留していて前記タンク7cへポンプ補給するとともに溢流液を受け入れる補助タンク7dと、タンク7cの上面の蓋を横へスライドさせると露出するようになっていてタンク7cに貯留されるポジ型感光性組成物に一部浸漬して回転自在である塗布ロール7eとからなる。タンク7cに貯留されるポジ型感光性組成物は、タンク7cが図示しない保温材で覆われかつ内部に挿入されたヒーター7fで時間を間欠して温められ、待機時及び塗布時を通じて一定温度、例えば25℃にほぼ安定するように温度制御される。
0031
塗布ロール7eは、バネで数mm持上げられていて、回転軸心が被製版ロールRの回転軸心に対して平面方向に見て直角方向に相違していて塗布時の走行台車7aの走行方向に向かってアップ回転するように塗布回転するようになっており、ロールチャック回転手段6に取着されて回転される被製版ロールRの一端下面に弾力的に極めて軽く接触されてポジ型感光性組成物の塗布を行なうようになっている。又、塗布ロール7eは、タンク7cの蓋を開けたときに放射を開始する図示しない遠赤外線等の熱線をロール上部に照射されて25℃付近に温められるようになっている。
ロールチャック回転手段6は、塗布装置7が塗布を終了しても回転を停止せずバーニングが終了するまで被製版ロールを回転し続ける。
0032
バーニング用ヒーターは、ケーシング1内に左右配置に取着される二本の被製版ロールR,Rに各別に対応してロールの上面側を筒面状に覆うように装備される。
バーニング用ヒーターは、100φmm×800mm〜300φmm×2000mmの大きさの被製版ロールに対して汎用性を持たせるために、駆動側チャック寄りのバーニング用ヒーター9aと可動側チャック寄りのバーニング用ヒーター9bとで分割構成される。駆動側チャック寄りのバーニング用ヒーター9aはロール径に合わせて接近離隔調整自在であり、可動側チャック寄りのバーニング用ヒーター9bはロール径に合わせて接近離隔調整自在であるとともにロール長さに応じてロール長さ方向に移動調整自在である。
0033
ケーシング1内は、加熱気体が給気ダクト5から昇降扉3の両側の耐熱性メッシュ材3aを通流してケーシング内の左側空間と右側空間に流れ込むとともに、排気ダクト4,4を介して排気されることで、左側空間と右側空間との間の引火性ガスの通流が皆無であり、昇降扉3に関してケーシング内の一方の側では塗布を行ない、他方の側ではバーニングを行なっても、扉が極めて安全なる防爆機能を果たすことができる。
0034
昇降扉3で左右に画されるケーシング1内の左側空間と右側空間に装備されるバーニング用ヒーター9a,9bは、共通の塗布装置7が反対側の空間に移動し、そして、昇降扉3が閉扉しかつ湿気がない加熱気体(例えば30℃)が昇降扉3のメッシュ材3aから両側の空間へ通風された後に、給電されて放熱を開始し、被製版ロールのポジ型感光性組成物の塗布膜を所要温度に加熱し乾固して残留溶剤がおよそ2%以下になるようにして近赤外波長域のレーザーでポジ画像を焼き付けることができるポジ型感光膜を形成できるようになっている。
0035
具体的には好ましいバーニング温度は130℃付近であり、130℃付近でバーニングすると残留溶剤がおよそ2%以下になることが分かり、ポジ型感光膜に830nmmの近赤外波長域のレーザーでポジ画像を焼き付けることができ、現像が良好に行なえることが分かった。
0036
図示しないが、ケーシング内に装備されるロールチャック回転手段にチャックされる被製版ロールにバーニングを完了した後に湿度が例えば20%以下に抑えた冷却風を被製版ロールに吹き付けるようになっている。
これによって、感光膜が形成された被製版ロールを直ぐに現像処理に回すことができるとともに、ロール冷却装置及びその設置スペースを別途に設けることを省略できるメリットがある。
0037
上記の実施の形態は、同一のケーシング内に被製版ロールRを左右配置にチャックして共通の塗布装置7により塗布を行ない、昇降扉3を閉扉し加熱気体が昇降扉3の耐熱性メッシュ材3aから両側の空間へ通風して防爆を図ってからバーニングを行なうもので、この場合には、塗布装置7の可動率を100%近くまで高められることになる。又、上記の実施の形態は、別途にバーニングを行なうスペースを省略できるメリットがある。
0038
これに対して、ケーシング内に一本の被製版ロールをチャックして塗布装置により塗布を行ない、バーニングを別途の装置で行なわない場合では、塗布工程とバーニング工程との間に、塗布装置の位置で室温での乾固工程を行なって塗布膜のダレを回避しなければならないから、塗布後の室温での乾固時間が塗布時間よりも多くかかり、塗布装置の可動率を50%未満となる。又、この場合には、塗布工程からバーニング工程へ移行するための搬送工程で白化が起こりうる惧れがある。
0039
本願発明は、昇降テーブル7bをフローティング制御して塗布ロール7eと被製版ロールRとの間を極めて小さい一定ギャップ、例えば60μmmとなるように近接させて被製版ロールの一端から他端へ移動させてポジ型感光性組成物の塗布を行なうようにしても良い。
0040
なお、ロールチャック回転手段6がケーシング1内に一基のみ装備されている場合には、ケーシング内の一側の待機位置に塗布装置7が移動してタンク7cの蓋が閉じて扉が閉じて塗布装置を待機位置に密閉して防爆が図れるようにする。
0041
【発明の効果】
請求項1に記載のポジ型感光膜形成方法によれば、近赤外波長域のレーザーに露光感応して該感応部が現像液に可溶になる近赤外波長域レーザー感応性を有するポジ型感光性組成物をグラビア印刷用の被製版ロールに塗布して該塗布膜をバーニングするもので、塗布工程、並びに塗布工程とバーニング工程との間で、ポジ型感光性組成物の溶剤の気化に伴う潜熱で塗布膜の温度をガラス転移点以下に温度降下させないようにするので、製版室に大形除湿装置を設備して湿度を大幅に下げることをしなくても白化が生じないとともに、残留溶剤を所要濃度以下になり近赤外波長域のレーザーにより露光感応し得る良好なポジ型感光膜を形成することができる。
0042
請求項2に記載のポジ型感光膜形成方法によれば、請求項1に記載の発明の効果に加えて、塗布と加熱乾固を単一のケーシング内で行なうことで塗布工程とバーニング工程との間で白化現象が起こる要因が皆無であり、防爆の危険がなくポジ型感光膜を良好に形成することができる、という効果を有する。
0043
請求項3に記載のポジ型感光膜形成方法によれば、請求項1又は請求項2に記載の発明の効果に加えて、塗布工程において白化現象が起こる要因が皆無になり、ポジ型感光膜を良好に形成する確率が一層高まる、という効果を有する。
0044
さらに、請求項1ないし請求項3に記載のポジ型感光膜形成方法によれば、白化現象が生じていないポジ型感光膜を形成できるから、ポジ型感光性組成物用現像剤で現像したときに良好な現像が実現できる。
【図面の簡単な説明】
【図1】本願発明のポジ型感光膜を形成する方法を実施するためのポジ型感光膜形成装置の正面図を示す。
【符号の説明】
R・・・被製版ロール、1・・・ケーシング、1a・・・ロール出し入れ用開口、1b・・・戸袋壁、2・・・ロール出し入れ用扉、3・・・昇降扉、3a・・・耐熱性メッシュ材、4,5・・・排気ダクト、6・・・給気ダクト、6・・・塗布装置、6a・・・駆動側チャック、6b・・・テイルチャック、7・・・塗布装置、7a・・・走行台車、7b・・・昇降テーブル、7c・・・タンク、7d・・・補助タンク、7e・・・塗布ロール、7f・・・ヒーター、8・・・レール、9a,9b・・・バーニング用ヒーター
[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a plate for gravure printing of a positive photosensitive composition having a near-infrared wavelength region laser sensitivity that is sensitive to exposure to a near-infrared wavelength region laser and the sensitive part becomes soluble in a developer. The present invention relates to a method for forming a positive photosensitive film which is applied to a roll without causing whitening and having a residual solvent at a required concentration or less.
[0002]
[Prior art]
As one of the plate making methods for gravure printing rolls, there is a so-called etching method in which a photosensitive film is applied and formed on the copper sulfate plating surface of a plate making roll, an image is printed with a laser, developed, etched, resist stripped and chromium plated. It is done.
In the conventional etching method, a negative photosensitive film is applied to a plate-making roll, and the coating film is dried at room temperature to form a negative photosensitive film, which is baked with an argon ion laser to form a positive photosensitive film. Therefore, no baking is performed with a laser in the near-infrared wavelength region.
[0003]
[Problems to be solved by the invention]
If the beam diameters of the argon ion laser and the laser in the near-infrared wavelength region are the same, the resolution of the laser is higher in the positive type than in the negative type.
A positive image is formed on a photosensitive film of a positive photosensitive composition (for example, JP-A-10-26826, JP-A-10-90881, JP-A-10-161304, JP-A-11-231515) with a laser in the near infrared wavelength region. The pattern is cut better when the negative photosensitive image is printed on the photosensitive film of the negative photosensitive composition with an argon ion laser.
[ 0004 ]
Therefore, with regard to the etching method as one of the plate making methods of the gravure printing roll, a positive type photosensitive composition photosensitive film is applied and formed on the copper sulfate plating surface of the plate making roll, and a positive image is formed with a laser in the near infrared wavelength region. After testing for improvement after baking, developing, etching, stripping resist, and chromium plating, it was found that there were two problems that could not print positive images with a laser in the near infrared wavelength region.
[ 0005 ]
One was that the positive photosensitive composition was applied, the coating film was dried with a drier, developed by laser exposure, and where development was possible or not. When the coating film was dried at various temperatures and developed repeatedly, when the residual solvent was about 4%, a positive image could not be printed with a laser in the near infrared wavelength region, and the residual solvent was about 2% to It was found that a positive image could be printed with a laser in the near-infrared wavelength region when the amount was 3% or less. Therefore, it has been found that it is necessary to perform a burning treatment so that the residual solvent is about 2% to 3% or less.
[ 0006 ]
The other is that when the positive photosensitive composition is applied and the coating film is sufficiently burned so that the residual solvent is about 2% to 3% or less, the development can be done well and the development is quite complete. When it was not possible. As a result of daily experiments, development was successful on sunny days, and development was not possible at all on rainy days.
Examination of the photosensitive film formed on a day when development could not be performed at all revealed that whitening occurred.
[ 0007 ]
The whitening phenomenon is the absorption of moisture when the temperature of the non-crystalline part of the polymer, which is composed of a dense part (crystalline part) and a sparse part (non-crystalline part), falls below the glass transition point Tg. It is a phenomenon that turns white and vitrifies, and is likely to occur in cold air with a high humidity. The positive photosensitive composition applied to the plate-making roll in a constant temperature room at 25 ° C. causes a whitening phenomenon because the solvent contained in the positive photosensitive composition evaporates by removing latent heat from the coating film. This is presumably because the amorphous portion lowers the temperature below the glass transition point Tg and absorbs moisture from condensation.
[ 0008 ]
Therefore, keeping the humidity in the platemaking room below 40% is effective to avoid the whitening phenomenon, but the equipment and running costs of the large dehumidifier are extremely high, and a large dehumidifier installation space is required. Therefore, it is difficult to install in the existing plate making room.
Therefore, another solution that does not install a large-sized dehumidifier is required.
[ 0009 ]
As a result of intensive research, one solution is that when the positive photosensitive composition is applied to a plate-making roll and the evaporation area is maximized, the temperature of the coating film is lowered below the glass transition point due to the latent heat accompanying the evaporation of the solvent. It was considered to prevent the temperature from dropping. Specifically, it has been considered to mix a low boiling point solvent having a low evaporation rate and a small amount of latent heat of vaporization by reducing the proportion of a solvent having a high evaporation rate and a large amount of latent heat of vaporization such as IPA. Further, it was considered that this low boiling point solvent needs to have a property of preventing moisture. Further, it has been considered to use a positive-type photosensitive composition modified by containing a low-boiling point polymer or a low-boiling point plasticizer and reducing the glass transition point.
[ 0010 ]
Therefore, when a positive photosensitive composition mixed with a low boiling point solvent was formulated to form a photosensitive film and developed, good development was achieved. Good development could be achieved even when a modified positive photosensitive composition containing a low-boiling point polymer and containing a low glass transition point was used. Furthermore, even when a modified positive photosensitive composition in which a low-boiling plasticizer was contained in a required proportion to lower the glass transition point was used, good development could be achieved.
[ 0011 ]
A positive photosensitive composition mixed with a low-boiling solvent was formulated, a photosensitive film was formed, and the development test was repeated. The exposure of the photosensitive film on the first plate-making roll was started after one day of coating operation.・ Development was good, but exposure / development gradually worsened after the second one, and it became clear that the second and later ones settled down.
After careful examination, whitening of the photosensitive film on the first plate-making roll at the start of the day's coating operation has not occurred, but whitening has occurred near the end of the coating on the second plate-making roll. In addition, it was found that the width of whitening gradually increased gradually in the third and subsequent plate-making rolls.
[ 0012 ]
The reason for this was considered to be the whitening phenomenon because the burning treatment was necessary and sufficient for all the plate-making rolls.
When the coating operation is restarted after a while after closing the lid of the tank for storing the positive photosensitive composition, the same as the above with the first, second and third plate-making rolls as above. It was found that there was a difference in which whitening phenomenon occurred.
[ 0013 ]
Therefore, when the coating operation is performed by opening the lid of the tank for storing the positive photosensitive composition, the solvent of the positive photosensitive composition adhering to the coating roll takes away latent heat from the coating roll and evaporates. Heat exchange is performed between the lowering application roll and the positive photosensitive composition stored in the tank, and the temperature of the positive photosensitive composition stored in the tank gradually decreases. When the lowered positive photosensitive composition adheres to the surface of the coating roll and is applied to the plate-making roll and the solvent evaporates on the surface of the roll, the temperature of the coating film is lower than the glass transition point Tg. it was thought.
[ 0014 ]
So we tried several solutions. When the positive photosensitive composition was applied with the roll heated to 30 ° C., no whitening phenomenon occurred. Further, when the tank was covered with a heat insulating material and the tank was heated with a heater to keep the temperature of the positive photosensitive composition at 25 ° C., no whitening phenomenon occurred. In both cases, exposure and development were performed satisfactorily.
In consideration of the cold season in winter, it was found that when a roll that was satisfactorily applied with a coating apparatus was taken out and exposed to the cold before performing the burning treatment, a whitening phenomenon occurred.
[ 0015 ]
The present invention has been devised in view of the above points, and is a positive type having a near-infrared wavelength region laser sensitivity that is sensitive to exposure to a near-infrared wavelength region laser and the sensitive part becomes soluble in a developer. The photosensitive composition is applied to a plate-making roll for gravure printing and the coating film is burned. Between the coating process and the coating process and the burning process, the solvent of the positive photosensitive composition is vaporized. Since the temperature of the coating film is not lowered below the glass transition point due to the accompanying latent heat, whitening does not occur even if the large-scale dehumidifier is installed in the plate making room and the humidity is not significantly reduced, and it remains. It is an object of the present invention to provide a positive photosensitive film forming method capable of forming a good positive photosensitive film that can be exposed to light by a laser in the near infrared wavelength region when the solvent is at a required concentration or less.
[ 0016 ]
[Means for Solving the Problems]
According to the first aspect of the present invention, there is provided a gravure positive photosensitive composition having a near-infrared wavelength region laser sensitivity that is sensitive to exposure to a near-infrared wavelength region laser and the sensitive part becomes soluble in a developer. A positive photosensitive film that does not cause whitening is formed by coating with a coating roll that rotates in contact with a printing plate making roll, a non-impact coating roll that rotates while maintaining a certain gap, or a coating means such as a kiss coater. A method comprising: (a) warming a positive photosensitive composition stored in a tank to a required temperature; (b) heating a coating roll to a required temperature with a hot wire; and (e) requiring a plate-making roll. By performing at least one of heating to a temperature, the positive photosensitive composition is uniformly applied to the plate-making roll so that the temperature of the coating film does not drop below the glass transition point. The coating film is burned without lowering the temperature of the coating film below the glass transition point, and the residual solvent is dried to a concentration below the concentration at which the laser in the near-infrared wavelength region can sensitize the positive photosensitive film to exposure. The present invention provides a method for forming a positive type photosensitive film.
[ 0017 ]
In the invention described in claim 2, the positive photosensitive composition is applied to the plate-making roll in a sealed form having an openable / closable door through which the plate-making roll can be taken in and out, and in a casing capable of exhausting combustible gas. Burning of the coating film applied to the plate-making roll is carried out by the equipped coating means, and positive type photosensitivity is provided by a burning heater equipped so as to be close to the plate-making roll attached to the coating means. 2. The positive photosensitive film forming method according to claim 1, which is carried out after the application of the composition is completed and after the explosion-proof conditions are adjusted.
[0018]
According to the third aspect of the present invention, the application of the positive photosensitive composition to the plate-making roll is such that the coating film does not drop below the glass transition point due to the latent heat accompanying the vaporization of the solvent of the positive photosensitive composition. 3. The positive photosensitive film forming method according to claim 1, wherein the process is performed under the condition that the atmosphere of the plate-making roll is maintained at a required temperature and / or the temperature of the plate-making roll is increased. Is to provide.
[ 0019 ]
DETAILED DESCRIPTION OF THE INVENTION
The present invention relates to a plate for gravure printing of a positive photosensitive composition having a near-infrared wavelength region laser sensitivity that is sensitive to exposure to a near-infrared wavelength region laser and the sensitive part becomes soluble in a developer. This is a method for forming a positive photosensitive film which is applied to a roll without causing whitening and having a residual solvent at a required concentration or less.
[ 0020 ]
The present invention is a method in which a positive photosensitive composition is applied to a plate-making roll to burn the coating film. Between the coating process and the coating process and the burning process, the solvent of the positive photosensitive composition is used. In order to prevent the temperature of the coating film from dropping below the glass transition point due to the latent heat accompanying vaporization, the residual solvent is reduced to a required concentration or less so that it can be exposed to light by a laser in the near infrared wavelength region after burning. Thus, a positive type photosensitive film is obtained.
[ 0021 ]
As a method for applying the positive photosensitive composition to the plate-making roll, a known method can be adopted.
Explaining once, the application of the positive photosensitive composition to the plate-making roll is performed by horizontally rotating the plate-making roll on the coating device and chucking the both ends at a low speed, and the lower side of the plate-making roll is placed under the plate-making roll. A coating roll (sponge roll) attached to a tank that rises corresponding to one end and moves to the other end after the required approach is immersed in a positive photosensitive composition stored in the tank and rotated. The positive photosensitive composition is coated by moving the plate-making roll from one end to the other end in an extremely light contact with the plate-making roll.
The coating roll may be applied to the plate making roll by floating proximity control so as to maintain an extremely small gap with respect to the plate making roll by driving an electrostrictive actuator or a voice coil.
[ 0022 ]
The positive photosensitive composition may be prepared by, for example, treating the solvent of the positive photosensitive composition disclosed and sold in JP-A-10-26826, JP-A-10-90881, JP-A-10-161304, and JP-A-11-231515 with moisture. Replacing with a low-boiling solvent having the property of preventing the occurrence of whitening has a great effect on whitening prevention. When propylene glycol monomethyl ether, normal propanol, or the like is used as a low boiling point solvent that replaces IPA, there is an effect that the latent heat of vaporization is reduced, the temperature drop of the coating film is small, and the dew condensation moisture absorption is reduced.
In addition, it is possible to use a positive type photosensitive composition having a high molecular weight and a low boiling point, which is modified with a polymer such as a phenol novolac-modified resin or a plasticizer such as a phthalic acid ester to lower the glass transition point. It has a great effect on prevention.
[ 0023 ]
Burning to heat and dry the coating and coating film is performed in a sealed casing having an openable / closable door that allows the plate-making roll to be taken in and out, and the plate-making roll can be taken in and out between the coating step and the burning step. Preferably it is not done.
For this reason, the side panel or the bottom panel constituting the casing is heated with a hermetic heater to control the temperature, and the atmosphere in the casing is set to a required temperature at which there is no risk of explosion with respect to the solvent in the positive photosensitive composition. A casing that can be controlled is provided, and a roll chuck rotating means, a coating device, and a heating heater are provided in the casing, and when the positive photosensitive composition is applied to the plate-making roll, the solvent of the positive photosensitive composition is removed. It is preferable to maintain the atmosphere of the plate making roll at a required temperature so that the coating film does not drop below the glass transition point due to latent heat accompanying vaporization.
In order to avoid the whitening phenomenon, it is preferable that the plate making roll is preheated to a required temperature, preferably preheated to about 30 ° C. and accommodated in the casing.
[ 0024 ]
It is preferable that two roll chuck rotating means are provided in the casing on the left and right side, and two plate-making rolls can be horizontally chucked at each end and can be rotated at a required low speed. The plate making roll is preheated to a required temperature, for example, 30 ° C., so that the coating film of the positive photosensitive composition does not drop below the glass transition point, and both ends are horizontally moved by an industrial robot. It is preferable that chucking is performed to lower the door at the upper part of the entire panel and accommodate it in the casing through the door opening and chuck it by the roll chuck rotating means.
[ 0025 ]
When two roll chuck rotating means are provided in the left and right arrangement in the casing, the coating apparatus is a common application apparatus for the two plate-making rolls attached in the left and right arrangement in the casing.
One roll chuck rotating means may be provided.
[ 0026 ]
FIG. 1 is a front view of a positive photosensitive film forming apparatus for carrying out the method for forming a positive photosensitive film of the present invention.
[ 0027 ]
The casing 1 has roll entry / exit openings 1a, 1a at the upper part of the entire surface, and has roll entry / exit doors 2 and 2 that close up and close the roll entry / exit openings 1a, 1a. ) And is accommodated in the door pocket wall 1b, allowing the lower side of the door pocket wall 1b to pass through the coating device, and is provided with a lifting door 3 that is lowered when the door is closed and partitions the internal space left and right. The casing 1 is configured such that the gas in the casing is recovered by an exhaust gas recovery device (not shown) through exhaust ducts 4 and 4 provided in communication with the left end and the right end of the upper surface of the casing. Warm air is fed into the door pocket wall 1b from the air supply duct 5 provided so as to communicate with the central portion of the upper surface of the casing, and the warm air in the door pocket wall 1b is a double-wall structure elevator door The heat-resistant mesh material 3a on both sides of 3 is passed through and flows into the left space and right space in the casing, and the flammable gas does not flow between the left space and the right space. To do.
[ 0028 ]
A roll chuck rotating means 6 is provided in each of the left space and right space in the casing 1, and a common coating device 7 runs on the rail 8 so as to reciprocate between the left space and right space in the casing 1. Equipped.
[ 0029 ]
The roll chuck rotating means 6 is driven by a motor (not shown) and rotated by a drive side chuck 6a and a movable table (not shown) according to the roll length. A plate-making roll R having a size of 300 φmm × 2000 mm can be chucked and rotated at a required low speed.
[ 0030 ]
The coating device 7 is equipped with a traveling carriage 7a that reciprocates below the plate-making roll R chucked by the roll chuck rotating means 6, a lifting table 7b equipped on the traveling carriage, and a lifting table. In addition, a tank 7c that is managed so that the liquid level of the positive photosensitive composition becomes constant by an overflow method, and a positive photosensitive composition that is mounted on a traveling carriage is stored and pumped to the tank 7c. Auxiliary tank 7d for replenishing and receiving overflow liquid, and a lid on the upper surface of tank 7c are exposed to slide sideways, and are partially immersed in a positive photosensitive composition stored in tank 7c. The coating roll 7e is rotatable. The positive photosensitive composition stored in the tank 7c is warmed intermittently with a heater 7f that is covered with a heat insulating material (not shown) and inserted inside, and is kept at a constant temperature during standby and application. For example, the temperature is controlled so as to be almost stable at 25 ° C.
[ 0031 ]
The coating roll 7e is lifted by several mm by a spring, and the rotation axis is different in the direction perpendicular to the rotation axis of the plate making roll R in the plane direction. The coating is rotated so as to rotate upward toward the surface, and is positively photosensitive by being brought into contact with the bottom surface of one end of the plate-making roll R which is attached and rotated by the roll chuck rotating means 6 and extremely elastically lightly. Application of the composition is performed. The application roll 7e is heated to about 25 ° C. by irradiating the upper part of the roll with heat rays such as far-infrared rays (not shown) that start radiation when the lid of the tank 7c is opened.
The roll chuck rotating means 6 does not stop the rotation even after the coating device 7 finishes coating, and continues to rotate the plate making roll until the burning is completed.
[ 0032 ]
The heater for burning is equipped so as to cover the upper surface side of the roll in a cylindrical shape corresponding to each of the two plate-making rolls R, R mounted in the casing 1 in the left-right arrangement.
In order to give versatility to the plate-making roll having a size of 100 φmm × 800 mm to 300 φmm × 2000 mm, the burning heater includes a burning heater 9a near the driving side chuck and a burning heater 9b near the movable side chuck, It is divided by. The burning heater 9a near the drive side chuck can be adjusted to approach and separate according to the roll diameter, and the burning heater 9b near the movable side chuck can be adjusted to approach and separate according to the roll diameter and according to the roll length. The movement can be adjusted in the roll length direction.
[ 0033 ]
In the casing 1, the heated gas flows from the air supply duct 5 through the heat-resistant mesh material 3 a on both sides of the elevator door 3 and flows into the left space and the right space in the casing, and is exhausted through the exhaust ducts 4 and 4. Thus, there is no flow of flammable gas between the left side space and the right side space, and the door is applied even if the application is performed on one side of the casing with respect to the lifting door 3 and the burning is performed on the other side. Can fulfill the extremely safe explosion-proof function.
[ 0034 ]
Burning heaters 9a and 9b provided in the left space and right space in the casing 1 defined by the elevator door 3 on the left and right sides move the common applicator 7 to the opposite space, and the elevator door 3 A heated gas (eg, 30 ° C.) that is closed and free of moisture is ventilated from the mesh material 3a of the elevating door 3 to the spaces on both sides, then supplied with electricity to start heat dissipation, and the positive photosensitive composition of the plate-making roll The coating film is heated to the required temperature and dried to form a positive photosensitive film that can be printed with a laser in the near-infrared wavelength region so that the residual solvent is about 2% or less. Yes.
[ 0035 ]
Specifically, the preferable burning temperature is around 130 ° C., and it is found that the residual solvent is about 2% or less when burning at around 130 ° C., and the positive image is formed on the positive photosensitive film with a laser in the near infrared wavelength region of 830 nm. It was found that development could be performed satisfactorily.
[ 0036 ]
Although not shown, after the burning is completed on the plate making roll chucked by the roll chuck rotating means provided in the casing, a cooling air whose humidity is suppressed to, for example, 20% or less is blown onto the plate making roll.
Accordingly, there is an advantage that the plate-making roll on which the photosensitive film is formed can be immediately sent to the development process, and it is possible to omit providing the roll cooling device and its installation space separately.
[ 0037 ]
In the above-described embodiment, the plate-making roll R is chucked in the left and right positions in the same casing, the coating is performed by the common coating device 7, the lifting door 3 is closed, and the heated gas is the heat resistant mesh material of the lifting door 3. Burning is performed after ventilating the space from 3a to both sides to prevent explosion, and in this case, the mobility of the coating device 7 can be increased to nearly 100%. Further, the above-described embodiment has an advantage that a space for performing burning separately can be omitted.
[ 0038 ]
On the other hand, in the case where one plate-making roll is chucked in the casing and coating is performed by the coating apparatus, and burning is not performed by a separate apparatus, the position of the coating apparatus is between the coating process and the burning process. In order to avoid dripping of the coating film by performing a drying step at room temperature, the drying time at room temperature after coating takes longer than the coating time, and the mobility of the coating apparatus is less than 50%. . Further, in this case, there is a possibility that whitening may occur in the transport process for shifting from the coating process to the burning process.
[ 0039 ]
In the present invention, the elevating table 7b is controlled in a floating manner so that the gap between the coating roll 7e and the plate-making roll R is close to a very small constant gap, for example, 60 μm, and moved from one end of the plate-making roll to the other end. You may make it apply | coat a positive photosensitive composition.
[ 0040 ]
When only one roll chuck rotating means 6 is provided in the casing 1, the coating device 7 moves to a standby position on one side in the casing, the lid of the tank 7c is closed, and the door is closed. Seal the applicator at the standby position so that explosion protection can be achieved.
[ 0041 ]
【The invention's effect】
According to the positive photosensitive film forming method of claim 1, a positive having a near-infrared wavelength region laser sensitivity in which the sensitive part becomes soluble in a developer upon exposure to a near-infrared wavelength region laser. Is applied to a plate roll for gravure printing and the coating film is burned, and the solvent of the positive photosensitive composition is vaporized between the coating process and between the coating process and the burning process. The temperature of the coating film is prevented from dropping below the glass transition point due to the latent heat that accompanies, so whitening does not occur even if a large dehumidifier is installed in the platemaking room and the humidity is not significantly reduced. It is possible to form a good positive photosensitive film that can be exposed to light by a laser in the near-infrared wavelength region with the residual solvent being less than the required concentration.
[ 0042 ]
According to the positive photosensitive film forming method of the second aspect, in addition to the effect of the invention of the first aspect, the coating process and the burning process are performed by performing coating and heating to dryness in a single casing. There is no factor that causes a whitening phenomenon in between, and there is no risk of explosion prevention, and a positive photosensitive film can be formed satisfactorily.
[ 0043 ]
According to the positive photosensitive film forming method of the third aspect, in addition to the effect of the invention of the first or second aspect, there is no cause of whitening in the coating process, and the positive photosensitive film is formed. This has the effect of further increasing the probability of forming the film.
[ 0044 ]
Furthermore, according to the positive photosensitive film forming method according to any one of claims 1 to 3, a positive photosensitive film in which no whitening phenomenon occurs can be formed. Therefore, when developing with a developer for a positive photosensitive composition. Excellent development can be realized.
[Brief description of the drawings]
FIG. 1 is a front view of a positive photosensitive film forming apparatus for carrying out a method of forming a positive photosensitive film according to the present invention.
[Explanation of symbols]
R: Plate making roll, 1 ... Casing, 1a ... Opening / unloading for rolls, 1b ... Door pocket wall, 2 ... Door for rolling out / loading, 3 ... Lift door, 3a ... Heat-resistant mesh material, 4, 5 ... Exhaust duct, 6 ... Air supply duct, 6 ... Application device, 6a ... Drive side chuck, 6b ... Tail chuck, 7 ... Application device , 7a ... traveling cart, 7b ... lifting table, 7c ... tank, 7d ... auxiliary tank, 7e ... coating roll, 7f ... heater, 8 ... rail, 9a, 9b ... Heater for burning .

Claims (3)

近赤外波長域のレーザーに露光感応して該感応部が現像液に可溶になる近赤外波長域レーザー感応性を有するポジ型感光性組成物をグラビア印刷用の被製版ロールに対して回転接触する塗布ロール、又は、一定ギャップを保って回転するノンインパクト塗布ロール、又はキスコーター等の塗布手段により塗布して白化が生じないポジ型感光膜を形成する方法であって、
(a)タンク内に貯留されるポジ型感光性組成物を所要温度に温めること、
(b)塗布ロールを熱線で所要温度に温めること、及び
(e)被製版ロールを所要温度に温めること
の少なくともいずれか1つを行なうことにより、ポジ型感光性組成物を塗布膜の温度がガラス転移点以下に温度降下しないように被製版ロールに均一に塗布し、引き続いて、塗布膜の温度をガラス転移点以下に温度降下させることなく該塗布膜をバーニングして残留溶剤が近赤外波長域のレーザーがポジ型感光膜を露光感応させ得る濃度以下になるように乾固することを特徴とするポジ型感光膜形成方法。
A positive-type photosensitive composition having a near-infrared wavelength region laser sensitivity, in which the sensitive part becomes soluble in a developer upon exposure to a near-infrared wavelength region laser, for a plate-making roll for gravure printing A method of forming a positive photosensitive film that does not cause whitening by coating by a coating roll that rotates, a non-impact coating roll that rotates while maintaining a certain gap, or a coating means such as a kiss coater,
(A) warming the positive photosensitive composition stored in the tank to a required temperature;
By performing at least one of (b) heating the coating roll to the required temperature with a hot wire and (e) heating the plate-making roll to the required temperature, the temperature of the coating film of the positive photosensitive composition is increased. Apply uniformly to the plate making roll so that the temperature does not drop below the glass transition point, and then the coating film is burned without lowering the temperature of the coating film below the glass transition point so that the residual solvent is near infrared. A method for forming a positive photosensitive film, characterized by drying so that a laser in a wavelength region has a concentration lower than that at which the positive photosensitive film can be exposed to light.
被製版ロールへのポジ型感光性組成物の塗布は、被製版ロールを出し入れできる開閉自在な扉を有する密閉形でありかつ可燃気体を排気し得るケーシング内に装備された塗布手段により行ない、被製版ロールに塗布した塗布膜のバーニングは、同塗布手段に取着される被製版ロールに対応して近接するように装備されたバーニング用ヒーターによりポジ型感光性組成物の塗布が完了後にかつ防爆条件を整えてから行なうことを特徴とする請求項1に記載のポジ型感光膜形成方法。  Application of the positive photosensitive composition to the plate-making roll is performed by a coating means provided in a casing that has a door that can be opened and closed and that can open and close the plate-making roll and that can exhaust combustible gas. Burning of the coating film applied to the plate-making roll is performed after the positive photosensitive composition has been applied by the burning heater equipped so as to be close to the plate-making roll attached to the coating means and explosion-proof. 2. The positive photosensitive film forming method according to claim 1, which is carried out after adjusting the conditions. 被製版ロールへのポジ型感光性組成物の塗布は、ポジ型感光性組成物の溶剤の気化に伴う潜熱で塗布膜がガラス転移点以下に温度降下しないように被製版ロールの雰囲気を所要温度に保つか、及び/又は、被製版ロールの温度を上げた条件下で行なうことを特徴とする請求項1又は請求項2に記載のポジ型感光膜形成方法。  The positive photosensitive composition is applied to the plate-making roll by setting the atmosphere of the plate-making roll to the required temperature so that the coating film does not drop below the glass transition point due to the latent heat accompanying the vaporization of the solvent of the positive photosensitive composition. The positive photosensitive film forming method according to claim 1, wherein the method is carried out under a condition that the temperature is maintained and / or the temperature of the plate-making roll is increased.
JP2002122142A 2002-04-24 2002-04-24 Positive photosensitive film forming method Expired - Fee Related JP4132943B2 (en)

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