JP3846160B2 - Cosmetic material - Google Patents

Description

【００６６】
上記表１の評価結果より、熱可塑性樹脂と木質系充填剤とを含有する木質樹脂成形体の表面に、前記木質樹脂成形体に含有される熱可塑性樹脂と同系の熱可塑性樹脂を主体とする化粧シートが積層されてなる本発明の化粧材は、木質感があり、切削や釘打ち等の加工性が良く、且つ、優れた意匠性とリサイクル性とを併せ持つ化粧材であることが確認された。
【００６７】
【発明の効果】
以上詳細に説明した様に、本発明の化粧材は、熱可塑性樹脂と木質系充填剤を含有する木質樹脂成形体の表面に、前記木質樹脂成形体に含有される熱可塑性樹脂と同系の熱可塑性樹脂を主体とする化粧シートが積層されてなるので、切削や釘打ち等の加工性にも優れており、化粧シートによる高意匠と木質樹脂成形体による視覚的及び触覚的な木質感とを有し、しかも木質樹脂成形体と化粧シートとの分離の必要なく容易にリサイクル可能であり、また特に熱可塑性樹脂としてポリオレフィン系樹脂を使用したものにあっては、安価で加工性に優れ、しかも用途態様によりリサイクル利用に適さない廃材等は焼却処分も可能である。
【００６８】
この様にして、本発明の化粧材は、化粧シートによる高意匠性を活かして、これまでの意匠性に劣る木質樹脂成形体では用いにくかった建築内装材、建具、家電品の表面材などにも使用しやすくなった。しかも、後加工時や使用後に発生する端材や廃材等の廃棄物は、再度本発明の化粧材の原料としてリサイクル利用できる。また公知の様々な成形法が応用できるため、リブ形状、中空構造などをとることにより化粧材の軽量化にも貢献でき、さらにジョイント形状の工夫により床材などの施工性も大幅に改善できる可能性がある。
【図面の簡単な説明】
【図１】本発明の化粧材の実施の形態を示す模式断面図である。
【図２】本発明の化粧材の実施の形態を示す模式断面図である。
【符号の説明】
１ 木質樹脂成形体
１１ 熱可塑性樹脂
１２ 木質系充填剤
１３ スキン層
２ 化粧シート[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a decorative material used for a building interior material such as a flooring material, a wall material, and a ceiling material, a fitting, and a surface material of home appliances.
[0002]
[Prior art]
Conventionally, as a decorative material for the above-mentioned various uses, a natural veneer, a decorative paper or a decorative sheet that has been designed by printing on a paper or a synthetic resin sheet, and the like are bonded to a woody base material such as plywood or fiberboard. Many things are used. However, these decorative materials have problems such as warpage due to moisture absorption and release of wood base materials, worm-eatenness and corrosion, and are difficult to recycle. However, it is disposed of by landfill or incineration.
[0003]
In addition, as a decorative material using a base material other than wood, a material in which a decorative sheet is bonded to the surface of a synthetic resin base material by profile extrusion or the like is used. The above-mentioned disadvantages due to the use of No. 1 are not found, and the appearance is also like wood by applying a decorative sheet of wood grain design. However, there are problems such that there is no wood texture in terms of specific gravity, rigidity, etc., and various processes such as cutting and nailing are difficult, and it can be used only in limited parts.
[0004]
In recent years, many attempts have been made to provide a wood resin molded article containing a thermoplastic resin and a wood-based filler for applications such as building interior materials, floor materials, joinery, and surface materials for home appliances. . However, these woody resin moldings are excellent in recyclability, workability such as cutting and nailing, and wood texture, but the surface is monotonous colored with a wood-based filler. Therefore, there is a disadvantage that it is inferior in design.
[0005]
Therefore, it is also conceivable to impart desired excellent design properties by bonding a surface material such as a natural veneer, decorative paper, or decorative sheet to the surface of these woody resin moldings. However, it is difficult to separate the surface material from the wood resin molded body, which is a waste resin material and the main body of the waste material, in terms of technology and economy. For this reason, there is a concern that the problem that the recyclability of the bent wood resin molding is not fully utilized can occur.
[0006]
[Problems to be solved by the invention]
The present invention has been made to solve the above-mentioned problems in the prior art, and the problem is that the wood texture, workability such as cutting and nailing is good, and an excellent design. The object is to provide a cosmetic material that combines recyclability.
[0007]
  The decorative material of the present invention isPolyolefin resinAnd a decorative material in which a decorative sheet is laminated on the surface of a wooden resin molded body containing a wooden filler,Mainly made of polyolefin resin and has printed patternDecorative sheetWhen,With polyolefin resinMixing ratio isPolyolefin resin10 to 500 parts by weight per 100 parts by weightLaminated wood-based resin moldings containing wood-based fillersCrush and mold the cosmetics without separating them, Including the printed pattern component of the decorative sheetA decorative material characterized in that a recycled resin woody resin body and a decorative sheet are bonded together.
[0008]
Further, in the decorative material of the present invention, the wood resin molding does not contain a wood filler.Skin layer on the surfaceIt is characterized by havingWith makeup materialis there.
[0009]
In addition, the decorative material of the present invention is the decorative material according to the invention, wherein the wood filler has an average particle diameter of 1 to 200 μm.
[0010]
  In the decorative material of the present invention, the blending ratio of the wood filler in the wood resin molded body molded by the profile extrusion method or the injection molding method is 10 to 200 weights with respect to 100 parts by weight of the polyolefin resin. It is a cosmetic material characterized by being a part.
[0012]
The decorative material of the present invention is a decorative material characterized in that the decorative sheet has a wood grain design.
[0013]
The decorative material of the present invention is a decorative material characterized in that the decorative sheet has transparency.
[0014]
DETAILED DESCRIPTION OF THE INVENTION
The decorative material of the present invention has a thermoplastic resin similar to the thermoplastic resin 11 contained in the wooden resin molded body 1 on the surface of the wooden resin molded body 1 containing the thermoplastic resin 11 and the wooden filler 12. A decorative material comprising a decorative sheet 2 as a main component (FIG. 1).
[0015]
As described above, the decorative material of the present invention is not required for processing / constructing the decorative material because the wooden resin molded body 1 and the decorative sheet 2 laminated on the surface thereof are mainly composed of the same thermoplastic resin. The scraps and waste materials after use can be reused (recycled) as the material of the wooden resin molded body 1 without separating the wooden resin molded body 1 and the decorative sheet 2 at the time of recycling. In molding, no defective molding occurs, and the recycled product does not impair the wood texture or decrease the strength.
[0016]
In addition, if the decorative sheet 2 has a wood grain design, the wood resin molded body 1 contains the wood filler 12, so that there is also a wood texture at the mouth that can be seen by cutting or grooving. In addition to having no sense of incongruity with the wood grain design, the printing ink for giving the wood grain design to the decorative sheet 2 has the same color as the wood material. Even if it is mixed in, there is an advantage that there is no sense of incongruity in color.
[0017]
The material of the wood filler 12 used in the present invention is not particularly limited as long as it is basically a powdery, granular or short fiber filler manufactured using natural wood as a main raw material. It can be arbitrarily selected from conventionally known ones. Generally, wood is broken by a cutter mill or the like, and is pulverized by a ball mill or impeller mill to give a fine powder (wood flour). Can be used.
[0018]
In addition, in the case of a high blending amount such that the blending amount of the wood filler 12 exceeds 100 parts by weight with respect to 100 parts by weight of the thermoplastic resin, dispersibility in the resin is particularly important. It is preferable to use a granular wood filler 12 having relatively little cilia. Specifically, as the woody filler 12 having less cilia, a polishing powder obtained by mainly polishing a particle board or the like is preferably used.
[0019]
Although the average particle diameter of the wood filler 12 is not particularly limited, it is generally 1 to 200 μm, more preferably 5 to 100 μm. When the average particle size is less than 1 μm, it is difficult to handle, and especially when the amount of the wood filler 12 is large, if the dispersion state in the resin is poor, the mechanical strength may be reduced. There is. On the other hand, if it is larger than 200 μm, it tends to cause a decrease in the homogeneity, flatness and mechanical strength of the molded product.
[0020]
The blending amount of the wood-based filler 12 with respect to the thermoplastic resin 11 in the wood resin molded article 1 of the decorative material of the present invention is not particularly limited, and is generally based on 100 parts by weight of the thermoplastic resin 11. Although it can be selected as appropriate within the range of about 10 to 500 parts by weight, the optimum blending amount differs depending on the use of the cosmetic material. Therefore, it is desirable to design appropriately according to the use.
[0021]
Specifically, for example, when an olefin-based resin is used as the thermoplastic resin 11, for a purpose of performing a cutting process or a V-cut process after being formed into a flat plate by a compression molding method or the like, a post-processing such as a cutting property is performed. In order to obtain an excellent material, the amount of the wood filler 12 is preferably 50 to 500 parts by weight, more preferably 100 to 500 parts by weight with respect to 100 parts by weight of the thermoplastic resin 11. . On the other hand, for applications molded by, for example, a profile extrusion method or an injection molding method, the amount of the wood filler 12 is set to 100 parts by weight of the thermoplastic resin 11 in order to improve moldability and homogeneity. On the other hand, it is desirable to set it as 10-200 weight part, More preferably, it is 15-150 weight part.
[0022]
Examples of the thermoplastic resin 11 used in the wood resin molded body 1 in the present invention include polyolefin resin, polystyrene resin, polycarbonate resin, polyester resin, polyamide resin, polyvinyl alcohol resin, acrylic resin, polyvinyl chloride. It is possible to select from various conventionally known thermoplastic resins such as resins and fibrin derivatives, but problems such as generation of harmful substances such as hydrogen chloride gas and dioxin during incineration and outflow of environmental hormones during landfill, etc. In view of the above, it is desirable to use a non-halogen resin, and among them, it is most desirable to use a polyolefin resin in order to satisfy performance such as weather resistance and heat resistance as a member and resistance to chemicals and solvents.
[0023]
The polyolefin resin used here is polyethylene, polypropylene, polybutene, polyisoprene, ethylene-propylene copolymer, ethylene-vinyl acetate copolymer, ethylene-α olefin copolymer, propylene-α olefin copolymer, ethylene. -Ethyl acrylate copolymers, those obtained by acid modification for the purpose of improving adhesion, ionomers and the like can be selected as appropriate, and they may be single or mixed.
[0024]
However, in order to obtain a wood resin molded article 1 having sufficient physical properties as a base material for a decorative material, when using a mixture of a plurality of types of polyolefin resins, select those that are compatible with each other as much as possible. It is desirable to combine them. Alternatively, in the case of mixing resins having poor compatibility, it is also effective to add a compatibilizing agent. For example, when incompatible resins are mixed, such as mixing or lamination of polyethylene and polypropylene, these are compatible, for example. It is more desirable to blend ethylene-propylene copolymer.
[0025]
In addition to the wood filler 12, the thermoplastic resin 11 constituting the wood resin molded body 1 may be colored as necessary, for example, a heat stabilizer, an acid neutralizer, an ultraviolet absorber, a light stabilizer, a pigment or a dye. Agents, non-wood based organic or inorganic fillers, antistatic agents, lubricants, nucleating agents, foaming agents, flame retardants, antiblocking agents, light scattering agents for translucency, gloss adjusting agents, etc. One or more additives may be added.
[0026]
Among these additives, hindered phenols, sulfurs, phosphoruss, etc. as heat stabilizers, stearic acid metal salts, hydrotalcite, etc. as acid neutralizers, benzotriazoles, benzoates as ultraviolet absorbers, etc. -Based, benzophenone-based, triazine-based, light stabilizer as hindered amine-based, flame retardant as halogen-based flame retardant, phosphorus-based flame retardant, chlorine-based flame retardant, etc., filler as calcium carbonate, silica, titanium oxide, Barium sulfate, zinc oxide, alumina, talc, mica, magnesium silicate, potassium titanate, magnesium sulfate, aluminum hydroxide, magnesium hydroxide, iron oxide, carbon black, metal powder, etc., lubricants include hydrocarbon lubricants, fatty acids, Nucleating agents such as higher alcohols, fatty acid amides, metal soaps, esters, etc. Carboxylic acid metal salt type, sorbitol type, phosphoric acid ester metal salt type, etc., pigments are condensed azo, insoluble azo, quinacridone, isoindolinone, anthraquinone, imidazolone, phthalocyanine, carbon black, cobalt blue, titanium oxide, There are pearl pigments such as zinc oxide, iron oxide, and titanium oxide-coated mica, and these additives can be used in any combination.
[0027]
In the present invention, the wood resin molded body 1 may contain the wood filler 12 as a whole, and if it does not impair the recyclability, wood texture, workability such as cutting and nailing, which are the objects of the present invention. For example, there is a portion not containing the wood filler 12 such as a skin layer (thin layer on the surface) 13 made of the same thermoplastic resin as the thermoplastic resin 11 contained in the portion containing the wood filler 12. It does not matter (Fig. 2).
[0028]
The presence of the skin layer 13 that does not include the wood filler 12 as described above prevents the wood filler 12 from being exposed on the surface of the wood resin molded body 1, smoothes the surface, and particularly a decorative sheet. In the case where the stain resistance and water resistance are improved at the place where 2 is not bonded, or when the wooden resin molded body 1 and the decorative sheet 2 are laminated by thermal lamination or simultaneous lamination, the role of both of them as an adhesive There are advantages such as improving adhesiveness by fulfilling.
[0029]
The aspect of the presence of the portion not including the wood filler 12 is not limited to the skin layer 13, and an arbitrary structure such as a sea island shape, a streak shape, a mesh shape, a layer shape, or the like inside the wood resin molded body 1. Can be taken. Further, even in the portion including the wood filler 12, it is not always necessary that the wood filler 12 is uniformly blended in the whole, and plural kinds of portions having different blending ratios of the wood filler 12 are, for example, sea islands. It may be configured in a shape, stripe shape, mesh shape, layer shape, or the like.
[0030]
The wooden resin molded body 1 can be obtained by molding a wooden resin composition obtained by adding and kneading a wooden filler 12 to a thermoplastic resin 11 into an appropriate shape by an appropriate molding method. The wood filler 12 and the thermoplastic resin 11 may be kneaded by any method, but generally kneaded with a Banbury mixer and pelletized with a pelletizer, or mixed and pelletized with a twin screw extruder kneader. Is. Further, the wood filler and the resin may be kneaded simultaneously with the molding of the thermoplastic resin. In addition, since the wood type filler 11 causes foaming due to evaporation of moisture at the time of molding when the moisture content is large, it is previously dried by a dryer or a hopper dryer before kneading to keep the moisture content to 8% or less. It is desirable.
[0031]
The molding method of the woody resin molded body 1 is not particularly limited, for example, from various known molding methods such as compression molding method, extrusion molding method, profile extrusion molding method, injection molding method, injection compression molding method, transfer molding method, etc. What is necessary is just to select suitably according to the shape and dimension of a molding. The shape of the woody resin molded body 1 can be freely selected from a flat plate shape, a three-dimensional shape, a hollow shape, a rib shape, and the like.
[0032]
The decorative material of the present invention is configured by laminating a decorative sheet 1 for imparting a desired appropriate design on the surface of the above-described wood resin molded body 1. The decorative sheet 1 is mainly composed of a thermoplastic resin similar to the thermoplastic resin 11 contained in the woody resin molded body 1, thereby ensuring the recyclability of the decorative material of the present invention. .
[0033]
In the present invention, it is important that the thermoplastic resin of the same type is recyclable without significant change in physical properties even when mixed with each other, and as long as the thermoplastic resin is composed mainly of the decorative sheet 2. As the resin, a similar resin can be selected from various thermoplastic resins similar to those listed as examples of the thermoplastic resin 11 contained in the wood resin molded body 1 described above.
[0034]
Specifically, for example, for polyolefin resins, polyethylene, polypropylene, polybutene, polyisoprene, ethylene-propylene copolymer, ethylene-vinyl acetate copolymer, ethylene-α olefin copolymer, propylene-α olefin copolymer. Polymers, ethylene-ethyl acrylate copolymers and their acid-modified products (copolymerized with unsaturated carboxylic acids or anhydrides for the purpose of improving adhesion), ionomers (olefin-unsaturated carboxylic acid copolymers) The same or different resins selected from these can be used for the woody resin molded body 1 and the decorative sheet 2.
[0035]
When different types of resins are combined, it is desirable that they are a combination of resins that are compatible with each other or that adhere well to each other. If the physical properties after mixing can be maintained by the addition of a solubilizer and / or an adhesive, it can be used. However, in that case, the compatibilizing agent and / or the adhesive is used as one or both of the wood resin molded article 1 and the decorative sheet 2 so that it is not necessary to add a compatibilizing agent and / or an adhesive separately at the time of recycling. It is desirable to add in advance to the constituent resin.
[0036]
If necessary, one or more of the same various additives as those of the thermoplastic resin 11 constituting the woody resin molded body 1 described above can be added to the thermoplastic resin constituting the decorative sheet 2.
[0037]
The specific configuration of the decorative sheet 2 is not particularly limited. For example, a single-layer decorative sheet in which a pattern is printed on the surface of a transparent or colored sheet, the pattern is printed on the surface of the colored sheet, and the printed surface is printed. Depending on the application, for example, a multi-layer decorative sheet in which a clear sheet is bonded by, for example, a dry laminate method, an extrusion laminate method, a thermal laminate method, a back-printed single-layer decorative sheet with a printed pattern on the back side of a transparent sheet, etc. Appropriate selection is possible. In the case of a multi-layer decorative sheet, the same type or the same type of thermoplastic resin is used as the thermoplastic resin constituting each layer.
[0038]
The type of design of the printed pattern applied to the decorative sheet 2 is not particularly limited, and can be arbitrarily selected from, for example, wood grain, stone grain, cloth grain, abstract pattern, etc. Then, since there is no sense of incongruity with the wooden resin molded body 1 of the lip that is exposed by cutting and cutting of the decorative material, and the printing ink has the same color as the wooden material, there is a problem of color change of the wooden resin molded body 1 during recycling. This is the most desirable for the purposes of the present invention.
[0039]
At this time, when the decorative sheet 2 has a sufficient hiding property by adopting a colored sheet and / or forming a hiding solid printing layer, there is an advantage that a stable design reproduction is achieved, but conversely When the decorative sheet 2 has transparency, the surface of the wooden resin molded body 1 including the wooden filler 12 can be seen through the decorative sheet 2, so that the wood texture of the wooden resin molded body 1 is utilized. There is an advantage that design expression is possible.
[0040]
Examples of the binder of printing ink used for printing the design pattern on the decorative sheet 2 include, for example, nitrified cotton, cellulose, vinyl chloride-vinyl acetate copolymer, polyvinyl butyral, polyurethane, acrylic, polyester, etc. What is necessary is just to select from the inside suitably. These may be any of aqueous, solvent-based and emulsion types, and can be arbitrarily selected from a one-component type or a two-component type using a curing agent. Further, it is possible to cure the ink by irradiation with ultraviolet rays or electron beams. Among them, the most common is a two-component curable urethane resin-based printing ink that is cured with a curing agent composed of an isocyanate compound, and is particularly excellent in adhesiveness to a polyolefin-based resin.
[0041]
In addition to these binders, colorants such as pigments and dyes, extender pigments, solvents, and various additives contained in ordinary inks are added. Particularly frequently used pigments include condensed azo, insoluble azo, quinacridone, isoindolinone, anthraquinone, imidazolone, phthalocyanine, carbon black, cobalt blue, titanium oxide, iron oxide, titanium oxide-coated pearl pigments, and the like.
[0042]
Examples of design pattern printing methods include gravure printing, offset printing, gravure offset printing, dry offset printing, screen printing, flexographic printing, letterpress printing, inkjet printing, electrostatic printing, transfer printing A conventionally known appropriate printing method such as the above can be used. When using a solid layer such as a concealed solid printing layer, for example, gravure coating method, micro gravure coating method, roll coating method, knife coating method, air knife coating method, kiss coating method, rod coating method, die coating method A coating method such as a lip coating method, a comma coating method, a flow coating method, or a dip coating method can also be used.
[0043]
In addition, if necessary, the surface to be printed such as corona discharge treatment, plasma treatment, ozone treatment, flame treatment, acid treatment, alkali treatment, primer or anchor treatment may be applied to the printing surface of the printing sheet as necessary before printing the design pattern. It is also possible to improve the adhesiveness with the printing ink.
[0044]
In any decorative sheet 2, a primer coat for bonding to the wood resin molded body 1 is applied to the back surface, a top coat for surface protection and gloss adjustment, an embossing method, a wiping method, The surface may be provided with a conduit expression by the gloss mat method or the like.
[0045]
In the decorative material of the present invention, the method for laminating the wooden resin molded body 1 and the decorative sheet 2 is not particularly limited, and an appropriate laminating method can be selected depending on the shape of the molded body. For example, in the case of a flat plate shape, the same shape is used in the longitudinal direction of profile extrusion molding, such as a roll laminating method in which an adhesive is applied to the front surface of the flat wooden resin molded body 1 and / or the back surface of the decorative sheet and bonded with a roll. For example, a wrapping method can be used for a molded body having a shape, and a vacuum press laminating method can be used for a molded body having a complicated three-dimensional surface.
[0046]
In addition, simultaneous painting can be performed in which a decorative sheet is pasted simultaneously with molding by a profile extrusion molding simultaneous laminating method, an injection molding simultaneous laminating method, or the like. Moreover, when using the wood resin molding 1 or the decorative sheet 2 made of a thermoplastic resin that is difficult to adhere, such as a polyolefin resin, corona discharge treatment, ozone treatment, plasma discharge treatment, flame treatment, etc., as necessary. It is desirable to improve adhesion by performing surface treatment or primer coating.
[0047]
When the decorative material of the present invention is recycled, it is not necessary to separate and separate the wooden resin molded body 1 and the decorative sheet 2, and the whole is crushed as it is and pelletized again, or heated and melt-kneaded as it is. By doing so, the recycled woody resin molding 1 can be obtained. Here, the pelletization or molding method is exactly the same as the method described above as the method for the original wood resin molded body 1. In addition, in the case of recycling, you may add suitably the wood type filler 12, the thermoplastic resin 11, various additives, etc. to the crushed material of the decorative material of this invention, or its heating melt as needed.
[0048]
In addition to the above, the recycling method includes a method in which the thermoplastic resin 11 and the wooden filler 12 are separated and recovered, but in that case, the decorative sheet 2 does not need to be separated from the wooden resin molded body 1. It can be recovered together with the thermoplastic resin 11 contained in the woody resin molded body 1.
[0049]
Depending on the mode of use of the decorative material of the present invention, it may not be suitable for recycling due to, for example, compositing with other resin parts. In such a case, in the decorative material of the present invention, the thermoplastic resin mainly composed of the thermoplastic resin 11 and the decorative sheet 2 contained in the wood resin molded body 1 is a non-halogen-based material such as a polyolefin resin. If the resin is used, it can be incinerated without worrying about the generation of harmful substances such as hydrogen chloride gas and dioxin during combustion. Needless to say, if the waste heat is subjected to thermal recycling in which the waste heat is reused for power generation, hot water supply, heating, or the like at the time of the incineration, the use form is more friendly to the global environment.
[0050]
【Example】
Hereinafter, the present invention will be described in more detail with reference to specific examples and comparative examples of the present invention.
[0051]
<Example 1>
90 parts by weight of homopolypropylene resin, 10 parts by weight of maleic acid-modified homopolypropylene resin, wood-based filler (wood powder having an average particle diameter of 20 μm, which is obtained by breaking a wood with a cutter mill and pulverizing it with a ball mill) Weight parts were mixed and pelletized by a twin-screw extrusion kneader to prepare a woody resin composition. This wood resin composition was extruded into a rectangular parallelepiped shape having a cross section of 10 mm × 100 mm by a profile extrusion molding method, and further subjected to corona discharge treatment to produce a virgin polyolefin-based wood resin molding. .
[0052]
On the other hand, the design pattern of wood grain by gravure printing method using a two-component curable urethane resin printing ink on a 100μm thick colored polypropylene sheet formed by blending pigments such as iron oxide and titanium oxide with random polypropylene A transparent homopolypropylene resin is laminated to a thickness of 100 μm by the extrusion laminating method on the printed surface, and at the same time embossed in a wood grain conduit shape, and a top coat is applied to the surface and a primer coat is applied to the back surface. A decorative sheet mainly composed of polyolefin resin was prepared.
[0053]
Thereafter, the decorative sheet of the present invention as a virgin product was prepared by laminating the decorative sheet on the surface of the wooden resin molded body by a lapping method.
[0054]
Further, the wood resin molded body of the virgin decorative material and the decorative sheet were crushed as they were without being separated, and then re-pelletized by a single-screw extruder, and the cross-section was again 10 mm by the profile extrusion molding method. The product was extruded into a rectangular parallelepiped shape having a rectangular shape of 100 mm, and the surface was further subjected to corona discharge treatment to produce a recycled polyolefin-based wood resin molded body.
[0055]
Thereafter, the same decorative sheet as that used for the virgin product was bonded to the surface of the recycled resinous wood molded product by a lapping process to produce a recycled product of the present invention.
[0056]
<Example 2>
90 parts by weight of homopolypropylene resin, 10 parts by weight of maleic acid-modified homopolypropylene resin, and 300 parts by weight of a wood-based filler (the same as those used in Example 1 above) were mixed and pelletized by a twin-screw extrusion kneader. A woody resin composition was prepared. This wood resin composition was molded into a flat plate having a thickness of 4 mm by a compression molding method, and the surface was further subjected to corona discharge treatment to produce a virgin polyolefin wood resin molding.
[0057]
Thereafter, the same decorative sheet as used in Example 1 was bonded to the surface of the wooden resin molded body by the roll laminating method to produce a virgin cosmetic material of the present invention.
[0058]
Further, the wood resin molded product of the virgin decorative material and the decorative sheet were crushed as they were without being separated, and then re-pelletized by a single screw extruder, and this was again compressed by a compression molding method to a thickness of 4 mm. The product was molded into a flat plate shape, and the surface was further subjected to corona discharge treatment to produce a recycled polyolefin-based wood resin molding.
[0059]
Thereafter, the same decorative sheet as that used for the virgin product was bonded to the surface of the recycled resinous wood molded product by a lapping process to produce a recycled product of the present invention.
[0060]
<Comparative Example 1>
In Example 1 above, pigments such as iron oxide and titanium oxide were blended in place of the wood-based filler, and the rest was exactly the same as in Example 1 to produce virgin and recycled cosmetics. .
[0061]
<Comparative example 2>
In Example 1, instead of a decorative sheet mainly composed of polyolefin resin, on the surface of a semi-rigid colored polyvinyl chloride resin sheet having a thickness of 100 μm formed by blending pigments such as iron oxide and titanium oxide, Using urethane resin printing ink, print design of wood grain by gravure printing method, and laminate 100μm thick semi-rigid transparent polyvinyl chloride resin sheet on the printing surface by thermal laminating method and at the same time, wood grain conduit shape Using a decorative sheet mainly made of polyvinyl chloride resin, which was prepared by applying a top coat on the front surface and a primer coat on the back surface, and the rest was exactly the same as in Example 1 except that the virgin And recycled cosmetics.
[0062]
<Comparative Example 3>
In Example 2, pigments such as iron oxide and titanium oxide were blended in place of the wood-based filler, and the rest was made in exactly the same manner as in Example 2 to produce virgin and recycled cosmetics. .
[0063]
<Comparative example 4>
In Example 2, a decorative sheet mainly composed of the same polyvinyl chloride resin as that used in Comparative Example 2 was used in place of the decorative sheet mainly composed of a polyolefin-based resin. Virgin and recycled cosmetics were made in exactly the same manner as in the above.
[0064]
<Performance evaluation>
For the decorative materials of virgin products and recycled products of Examples 1 to 2 and Comparative Examples 1 to 4, respectively, formability, saw cutting property, nailing property, V groove cutting property (however, Example 2 suitable for V cut processing) And Comparative Examples 3 to 4 only), and the design and wood texture (by visual and tactile sensation) were evaluated. The results are shown in Table 1.
[0065]
[Table 1]

[0066]
From the evaluation results in Table 1 above, the surface of the wood resin molding containing the thermoplastic resin and the wood filler is mainly composed of the same thermoplastic resin as the thermoplastic resin contained in the wood resin molding. The decorative material of the present invention in which a decorative sheet is laminated is confirmed to be a decorative material having wood texture, good workability such as cutting and nailing, and having both excellent design and recyclability. It was.
[0067]
【The invention's effect】
As described above in detail, the decorative material of the present invention has the same heat as the thermoplastic resin contained in the wood resin molded body on the surface of the wood resin molded body containing the thermoplastic resin and the wood filler. Since the decorative sheet mainly composed of plastic resin is laminated, it has excellent workability such as cutting and nailing, and has a high design by the decorative sheet and a visual and tactile wooden texture by the wooden resin molding. And is easily recyclable without the need to separate the woody resin molded article and the decorative sheet, and especially those using polyolefin resins as the thermoplastic resin are inexpensive and excellent in processability. Waste materials that are not suitable for recycling can be incinerated, depending on the application.
[0068]
In this way, the decorative material of the present invention makes use of the high designability of the decorative sheet, and is used as a surface material for building interior materials, fittings, home appliances, etc. Also easier to use. In addition, wastes such as scraps and waste materials generated during post-processing and after use can be recycled again as raw materials for the decorative material of the present invention. In addition, since various known molding methods can be applied, the rib shape, hollow structure, etc. can contribute to weight reduction of the decorative material, and the workability of the flooring can be greatly improved by devising the joint shape. There is sex.
[Brief description of the drawings]
FIG. 1 is a schematic cross-sectional view showing an embodiment of a decorative material of the present invention.
FIG. 2 is a schematic cross-sectional view showing an embodiment of a decorative material of the present invention.
[Explanation of symbols]
1 Wood resin molding
11 Thermoplastic resin
12 Wood filler
13 Skin layer
2 Makeup sheet

Claims (6)

In a decorative material in which a decorative sheet is laminated on the surface of a wooden resin molded article containing a polyolefin resin and a wooden filler,
A decorative sheet having a print pattern mainly composed of a polyolefin resin, and a wood resin molded article containing a polyolefin filler and a wood filler having a blending ratio of 10 to 500 parts by weight with respect to 100 parts by weight of the polyolefin resin. Crushing and molding the laminated cosmetics without separating them,
A decorative material comprising a decorative resin sheet and a recycled resinous wood resin product containing a printed pattern component of the decorative sheet. The decorative material according to claim 1, wherein the wood resin molded body has a skin layer not containing a wood filler on the surface. The cosmetic material according to claim 1 or 2, wherein the wood-based filler has an average particle diameter of 1 to 200 µm. The blending ratio of the wood filler in the wood resin molded body molded by a profile extrusion method or an injection molding method is 10 to 200 parts by weight with respect to 100 parts by weight of the polyolefin resin. Item 4. A cosmetic material according to any one of Items 1 to 3. The decorative material according to any one of claims 1 to 4 , wherein the decorative sheet has a wood grain design. The decorative material according to any one of claims 1 to 5 , wherein the decorative sheet has transparency.

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