JP3776350B2 - Agricultural film - Google Patents

Agricultural film Download PDF

Info

Publication number
JP3776350B2
JP3776350B2 JP2001398221A JP2001398221A JP3776350B2 JP 3776350 B2 JP3776350 B2 JP 3776350B2 JP 2001398221 A JP2001398221 A JP 2001398221A JP 2001398221 A JP2001398221 A JP 2001398221A JP 3776350 B2 JP3776350 B2 JP 3776350B2
Authority
JP
Japan
Prior art keywords
film
layer
thickness
white layer
agricultural film
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP2001398221A
Other languages
Japanese (ja)
Other versions
JP2003191392A (en
Inventor
邦彦 角田
正之 江上
和代 稲葉
Original Assignee
みかど化工株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by みかど化工株式会社 filed Critical みかど化工株式会社
Priority to JP2001398221A priority Critical patent/JP3776350B2/en
Publication of JP2003191392A publication Critical patent/JP2003191392A/en
Application granted granted Critical
Publication of JP3776350B2 publication Critical patent/JP3776350B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Description

【0001】
【発明の属する技術分野】
本発明は、作物栽培時に地面を覆い作物の生育に好適な環境を構築するマルチと称される農業用フィルムに関し、詳しくは高温期に畑地を覆い、地温の上昇を抑制し、作物に好適な栽培環境にする農業用フィルムに関する。
【0002】
さらに、高温期以外でも果樹の株元の全面又は部分的に敷設することで、その強力な反射光で果実の着色を増進させたり、根への雨水の浸入を防止し、果実糖度をコントロールしたりする農業フイルムに関する。以下の説明は地温を抑制するマルチフイルムにつき説明するが、用途はこれに限定するものではない。
【0003】
【従来の技術】
一般に多くの農作物(米、麦、トウモロコシを始め、野菜、花卉、果樹等)の栽培に、農業用マルチフィルムが用いられている。
【0004】
かかるマルチフィルムを用いたマルチ栽培によって、土中水分保持、土壌膨軟性の保持、肥料流亡防止、地温の上昇と抑制、初期成育の促進、初期収量の増加、生産の多収安定化等の諸効果が達成される。
【0005】
かかるマルチフィルムとしては、従来、二酸化チタンやアルミ微粒子をフィルムに配合して太陽光線を反射させて地温の上昇を防ぐ反射フィルムが知られている。
【0006】
しかし、かかるマルチフィルムでは、地温の低下がせいぜい裸地程度であり、不十分である。地温の抑制効果が低いと、たとえ1℃程度の上昇でも根の活動に影響し、積算すると植物の生育を大幅に遅らせたりあるいは枯死させるという植物栽培に致命的な問題がある。
【0007】
そこで、本発明者は、地温を裸地温度以下にすることが出来、栽培の難しい高温期の栽培に使用することにより、作物を良い栽培環境で育て、生育促進させ病害も低減することが出来る農業フィルムを先に提案した(特願平11−220513号参照)。この農業フィルムは、ポリオレフィン系樹脂からなる多層フィルムであり、一方の面が黒色層で他方の面が白色層であり、白色層の二酸化チタン濃度(wt%)の数値と厚さ(μm)の数値の積が500以上であり、フィルム面に実質的に均等に孔径1mm以下の孔を設け、かつ該孔の全面積がフィルム1m2当たり1000mm2以上であることを特徴とする。
【0008】
本発明者は、更に研究を進め、上記農業フィルムを用いて地温測定及び栽培テストを実施し、次の知見を得た。
【0009】
上記農業用フィルムは、高反射フィルムで、二酸化チタン粉末(白色顔料)を多量に含むフィルムである(以下、先行高反射フィルムという。)。
【0010】
かかる先行高反射フィルムは白色層表面の汚れがひどいことがわかった。かかるフィルム汚れのため、白色層の反射率が低下し、地温上昇抑制効果が低下していく。即ち、先行高反射フィルムの効果が経時に併ない悪い方向に変化して行ってしまう。
【0011】
先行高反射フィルムは高反射性を付与するために、成形上、また強度や耐候性等の面で、品質上可能なレベルまで、白色顔料の濃度をアップし、またフィルム厚みも厚くしてあり、従来のマルチフィルムに比較すると、はるかにコストアップしている(約2〜3倍)。
【0012】
一方、フィルムの使用期間は夏期高温期が中心であり、一日の使用では償却できないし、またフィルム強度も十分なので、省資源化という面からすると2〜3回使用することが好ましい。
【0013】
この場合、上記のように汚れがひどいと、フィルム性能が低下し、1作目の地温低下効果は十分発揮されたのに、2作目には効果が発揮されないことになる。
【0014】
しかも、このフィルムに付着する汚れは、従来のマルチフィルムに比較して除去するのが難しい。即ち、従来のマルチフィルムなら、降雨や簡単な水洗いで除去できたが、先行高反射フィルムでは、この程度の対処では除去できず、一部の汚れは残ってしまう問題がある。
【0015】
【発明が解決しようとする課題】
そこで、本発明の課題は、フィルム表面の汚れを防止し、地温上昇抑制効果を低下させない農業用フィルムを提供することにある。
【0016】
また本発明の他の課題は、フィルム表面が汚れてもその汚れを簡単に落とせる農業用フィルムを提供することにある。
【0017】
【課題を解決するための手段】
上記課題を解決する請求項1記載の農業用フィルムは、ベース樹脂がポリオレフィン系樹脂である多層フィルムであり、少なくとも黒色層、白色層及び透明層の3層からなり、黒色層/白色層/透明層の順に層構成され、白色層の二酸化チタン濃度(wt%)の数値と厚さ(μm)の数値の積が500以上であることを特徴とする。
【0018】
本発明において、白色層の二酸化チタン濃度(wt%)の数値と厚さ(μm)の数値の積は800以上が好ましく、1000以上がより好ましい。
【0019】
また本発明において、ベース樹脂が直鎖状低密度ポリエチレン(LLDPE)やメタロセンポリエチレンであることが好ましい。
【0020】
白色層と黒色層の2層からなる先行高反射フィルムにおいて、汚れの原因や汚れが落ちにくい原因について検討した結果、本発明者は、高フィラー含有により白層表面の凹凸が増し、また一部フィラーは表面に露出し、またはそれに近い状態となり、汚れが付着し易く、しかも除去し難いことを見出した。
【0021】
またTiO2粉末のような無機フィラーは極性が強く、これをフィルムに練込み添加すると、フィルムが帯電し易くなり、ホコリ微粉体を付着し易く、しかも除去し難い。また、ホコリと同じく、微生物(菌類、藻類、地衣類等)の胞子類も付着し易く、付着表面で繁殖し易い傾向もある。これも汚れを引き起こし、しかも簡単に除去できない種類の原因ともなることがわかった。
【0022】
【発明の実施の形態】
以下、本発明の実施の形態を説明する。
【0023】
多層フィルムの層構成は、黒色層、白色層、透明層の少なくとも3層構成であればよい。この多層フィルムはベース樹脂としてポリオレフィン系樹脂を用いた軟質の多層フィルムである。
【0024】
ポリオレフィン系樹脂としては、低密度ポリエチレン(LDPE)、直鎖状低密度ポリエチレン(LLDPE)、メタロセンポリエチレン、高密度ポリエチレン(HDPE)、エチレン−酢酸ビニル共重合体(EVA)等が挙げられ、その他軟質材料であればよい。軟質材料としては、ポリ塩化ビニル(PVC)ポリプロピレン、エチレン−プロピレン共重合体、エチレン−アクリル酸共重合体、エチレン−メチルメタクリレート共重合体、エチレン−酢酸ビニル−メチルメタクリレート共重合体、アイオノマー共重合体等が挙げられる。
【0025】
この発明において、ポリオレフィン系樹脂として好ましいのは、低密度ポリエチレン(LDPE)、直鎖状低密度ポリエチレン(LLDPE)、メタロセンポリエチレンであり、より好ましいのは、強度、柔軟性、耐候性、光反射性、耐汚染性、あるいはある程度の耐熱性を発揮する観点から、エチレン−ブテン1共重合体、エチレン−4−メチル−1−ペンテン共重合体、エチレン−ヘキセン共重合体、エチレン−オクテン共重合体、エチレン−デセン共重合体等のエチレン−α−オレフィン共重合体からなる直鎖状低密度ポリエチレン(LLDPE)や、これらをシングルサイト触媒を用いて重合したメタロセンポリエチレンで、最も好ましいのはメタロセンポリエチレンである。
【0026】
黒色層は、ベース樹脂にカーボンブラックを添加して得られる。かかるカーボンブラックの添加量は、特に限定されないが、1〜10wt%の範囲が好ましい。
【0027】
黒色層は、厚みが2〜28μmの範囲であることが好ましく、より好ましくは、5〜20μmの範囲である。
【0028】
この厚みはフィルム断面の光学顕微鏡観察によって測定することが出来る。
【0029】
白色層の二酸化チタン濃度(wt%)の数値と厚さ(μm)の数値の積は500以上である。かかる要件を満足するには、二酸化チタン濃度の数値を上げるか、あるいは白色層の厚みを増すか、あるいは二酸化チタン濃度の数値を上げると共に白色層の厚みを増す方法がある。
【0030】
白色層の二酸化チタン濃度(wt%)の数値と厚さ(μm)の数値の積が800以上であることが好ましく、その積が1000以上であることがより好ましい。
【0031】
白色層の厚みはフィルム断面の光学顕微鏡観察によって測定することが出来る。
【0032】
透明層は、ベース樹脂だけでもよいが、添加剤を含有してもよい。添加剤としては、酸化防止剤、耐候安定剤、滑剤、アンチブロッキング剤等が挙げられる。
【0033】
また実質的に透明な各種添加剤(例えば保温剤、低含量の二酸化チタンなど)を含有していてもよい。
【0034】
透明層の厚みは 1〜50μmが好ましく、より好ましくは3〜30μmの範囲である。
【0035】
本発明の多層フイルムを製造する方法としては、例えば▲1▼インフレ共押出成形、▲2▼Tダイ共押出成形、▲3▼多層カレンダー、▲4▼多層2軸延伸、などの成形方法により、3層を同時に形成することができるが、黒色層と白色層を上記方法により一体成形し、透明層を貼り合わせてもよい。
【0036】
【実施例】
以下、本発明の実施例について説明するが、かかる実施例によって本発明が限定されるものではない。
【0037】
実施例1
(1)フィルム試料の作成
表1に示すフィルム試料1〜10を作成した。
【0038】
▲1▼ベース樹脂
LLDPE(直鎖状低密度ポリエチレン)とメタロセンPE(メタロセンポリエチレン)の2種類を用いた。
LLDPE: 比重0.920、メルトフロレート 1
メタロセンPE:比重0.915、メルトフロレート 2
【0039】
▲2▼透明層組成物
ベース樹脂に以下の添加物を添加した。
シリカ :ベース樹脂に対して0.1重量%
ヒンダードアミン :ベース樹脂に対して0.1 重量%
【0040】
▲3▼白色層組成物
ベース樹脂に二酸化チタンを混入した。二酸化チタンの濃度は、各試料により二酸化チタン濃度(wt%)と厚み(μm)の積が表1に示す値になるようにして決定した。
【0041】
▲4▼黒色層組成物
ベース樹脂97重量部にカーボンブラックを3重量部混入した。
【0042】
▲5▼製法
上記▲2▼から▲4▼の組成物を、それぞれ別々の押出機で160℃の温度で溶融混練し、1台のインフレーション成形ダイに供給してダイ内で溶融フィルム同士を接着させ、次いでチューブ状に押し出した後ブローアップして冷却し成形して多層フィルム試料1〜10を得た。
各層の厚みは表1に示す。
【0043】
(試験)
上述の多層フィルム試料1〜10を用いて、みかど化工株式会社の試験農場においてマルチ敷設試験を行った。
【0044】
試験農場に畦巾60cm×畦長3mの畦11本の試験列を作成し、該畦面上に各々の農業用フィルムを敷設した。
なお、参考試験としてフィルムを敷設しない畦を1本設けた。
【0045】
フィルム展張は5月23日に行い、7月23日(晴天)外気温 37℃において実施した。
さらに7月21日に同じ試験列を作成して各々の新しい試験フイルムを同様に敷設し、7月23日に測定を実施した。
【0046】
〔日中最高地温〕
日中最高地温は熱電対温度計を使用してフィルム被覆下7cmの位置で測定した。その結果を表1に示した。
【0047】
〔裸地温との差〕
参考試験として設けたフイルムを敷設しない畦にフイルムを敷設した畦と同じ7cmの深さに設置した熱電対温度計を使用して、他の畦と同時に温度を記録してその差を読みとった。その結果を表1に示した。
【0048】
〔表層汚れの評価〕
マルチ敷設後2ヶ月のフイルムを採取して紫外可視分光光度計で420nmの反射率を求め、敷設前のフイルムの反射率と比較して反射率の低下から汚れの程度を評価した。その結果を表1に示した。
【0049】
【表1】

Figure 0003776350
【0050】
以上の表1にも明らかなように、本発明のフイルムは高い光反射率を維持しており、実際の農業用途に使用して長期間地温を低下させることが出来る。
【0051】
【発明の効果】
以上の如く、本発明によれば、フィルム表面の汚れを防止し、地温上昇抑制効果を低下させない農業用フィルム、フィルム表面が汚れてもその汚れを簡単に落とせる農業用フィルムを提供することができる。[0001]
BACKGROUND OF THE INVENTION
The present invention relates to an agricultural film called a mulch that covers the ground during crop cultivation and builds a suitable environment for growing the crop. More specifically, the present invention covers a field in the high temperature period, suppresses the rise in the ground temperature, and is suitable for crops. It is related with the film for agriculture made into cultivation environment.
[0002]
In addition, by laying the entire or part of the fruit tree stock even during periods other than the high temperature period, it is possible to increase the coloration of the fruit with its strong reflected light, prevent rainwater from entering the roots, and control the sugar content of the fruit. It is related to the agricultural film. Although the following description demonstrates the multifilm which suppresses ground temperature, a use is not limited to this.
[0003]
[Prior art]
Agricultural multi-films are generally used for the cultivation of many agricultural crops (rice, wheat, corn, vegetables, flowers, fruit trees, etc.).
[0004]
Multi-cultivation using such multi-films, such as retention of soil moisture, retention of soil softness, prevention of fertilizer loss, rise and suppression of soil temperature, promotion of initial growth, increase of initial yield, stabilization of high yield of production, etc. The effect is achieved.
[0005]
As such a multi-film, conventionally, a reflective film is known in which titanium dioxide or aluminum fine particles are blended into a film to reflect sunlight to prevent an increase in ground temperature.
[0006]
However, in such a multi-film, the decrease in ground temperature is at most about bare ground, and is insufficient. If the suppression effect of the soil temperature is low, even if it rises by about 1 ° C, it will affect the root activity, and if accumulated, there will be a fatal problem in plant cultivation where the growth of the plant will be greatly delayed or killed.
[0007]
Therefore, the inventor can reduce the soil temperature to a bare ground temperature or less, and by using it for cultivation in the high temperature season where cultivation is difficult, the crop can be grown in a good cultivation environment and promoted to grow and reduce disease. An agricultural film was previously proposed (see Japanese Patent Application No. 11-220513). This agricultural film is a multilayer film made of a polyolefin-based resin. One side is a black layer and the other side is a white layer. The white layer has a titanium dioxide concentration (wt%) value and thickness (μm). The product of numerical values is 500 or more, and the film surface is provided with holes having a hole diameter of 1 mm or less substantially uniformly, and the total area of the holes is 1000 mm 2 or more per 1 m 2 of film.
[0008]
The present inventor further advanced research, conducted soil temperature measurement and cultivation test using the agricultural film, and obtained the following knowledge.
[0009]
The agricultural film is a highly reflective film and is a film containing a large amount of titanium dioxide powder (white pigment) (hereinafter referred to as a preceding highly reflective film).
[0010]
It has been found that such a highly reflective film is very dirty on the surface of the white layer. Due to such film contamination, the reflectance of the white layer is lowered, and the effect of suppressing the rise in ground temperature is lowered. That is, the effect of the preceding highly reflective film is changed in a bad direction over time.
[0011]
In order to give high reflectivity to the preceding highly reflective film, the concentration of the white pigment has been increased to a level that allows quality in terms of molding and strength and weather resistance, and the film thickness has also been increased. Compared to conventional multi-film, the cost is much higher (about 2 to 3 times).
[0012]
On the other hand, the film is mainly used in the summer high temperature period and cannot be depreciated by using it for one day, and the film strength is sufficient. Therefore, it is preferable to use the film 2-3 times from the viewpoint of saving resources.
[0013]
In this case, if the dirt is severe as described above, the film performance is lowered, and the effect of lowering the ground temperature in the first work is sufficiently exhibited, but the effect is not exhibited in the second work.
[0014]
In addition, the dirt adhering to the film is difficult to remove as compared with the conventional multi-film. That is, the conventional multi-film can be removed by rain or simple water washing, but the preceding highly reflective film cannot be removed by this measure, and there is a problem that some dirt remains.
[0015]
[Problems to be solved by the invention]
Then, the subject of this invention is providing the film for agriculture which prevents the stain | pollution | contamination of a film surface and does not reduce the increase effect of ground temperature.
[0016]
Another object of the present invention is to provide an agricultural film that can easily remove dirt even if the film surface is dirty.
[0017]
[Means for Solving the Problems]
The agricultural film according to claim 1, wherein solving the above problems is a multilayer film base resin is a polyolefin resin, at least a black layer, a three-layered structure including the white layer and the transparent layer, the black layer / white layer / transparent The layers are formed in the order of layers, and the product of the numerical value of the titanium dioxide concentration (wt%) and the thickness (μm) of the white layer is 500 or more.
[0018]
In the present invention, the product of the numerical value of the titanium dioxide concentration (wt%) and the thickness (μm) of the white layer is preferably 800 or more, and more preferably 1000 or more.
[0019]
In the present invention, the base resin is preferably linear low density polyethylene (LLDPE) or metallocene polyethylene.
[0020]
As a result of investigating the cause of dirt and the reason why dirt is difficult to remove in the preceding highly reflective film composed of two layers of a white layer and a black layer, the present inventors have found that the unevenness of the surface of the white layer increases due to the high filler content, and partly It has been found that the filler is exposed on the surface or close to the surface, so that the dirt is easily attached and is difficult to remove.
[0021]
Inorganic fillers such as TiO 2 powder have a strong polarity, and when this is kneaded and added to a film, the film is easily charged, dust fine powder is easily adhered, and is difficult to remove. In addition, as with dust, spores of microorganisms (fungi, algae, lichens, etc.) are likely to adhere and tend to propagate on the adherent surface. This has also been found to cause contamination and a type that cannot be easily removed.
[0022]
DETAILED DESCRIPTION OF THE INVENTION
Embodiments of the present invention will be described below.
[0023]
The layer configuration of the multilayer film may be at least three layers including a black layer, a white layer, and a transparent layer. This multilayer film is a soft multilayer film using a polyolefin resin as a base resin.
[0024]
Examples of polyolefin resins include low density polyethylene (LDPE), linear low density polyethylene (LLDPE), metallocene polyethylene, high density polyethylene (HDPE), and ethylene-vinyl acetate copolymer (EVA). Any material can be used. Soft materials include polyvinyl chloride (PVC) polypropylene, ethylene-propylene copolymer, ethylene-acrylic acid copolymer, ethylene-methyl methacrylate copolymer, ethylene-vinyl acetate-methyl methacrylate copolymer, ionomer copolymer Examples include coalescence.
[0025]
In the present invention, preferred as the polyolefin-based resin are low density polyethylene (LDPE), linear low density polyethylene (LLDPE), and metallocene polyethylene, and more preferred are strength, flexibility, weather resistance, light reflectivity. From the viewpoint of exhibiting stain resistance or a certain degree of heat resistance, ethylene-butene 1 copolymer, ethylene-4-methyl-1-pentene copolymer, ethylene-hexene copolymer, ethylene-octene copolymer , Linear low density polyethylene (LLDPE) made of an ethylene-α-olefin copolymer such as ethylene-decene copolymer, and metallocene polyethylene obtained by polymerizing these using a single site catalyst, most preferably metallocene polyethylene It is.
[0026]
The black layer is obtained by adding carbon black to the base resin. The amount of carbon black added is not particularly limited, but is preferably in the range of 1 to 10 wt%.
[0027]
The black layer preferably has a thickness in the range of 2 to 28 μm, more preferably in the range of 5 to 20 μm.
[0028]
This thickness can be measured by optical microscope observation of the film cross section.
[0029]
The product of the numerical value of the titanium dioxide concentration (wt%) and the thickness (μm) of the white layer is 500 or more. In order to satisfy such requirements, there are methods of increasing the titanium dioxide concentration, increasing the thickness of the white layer, or increasing the titanium dioxide concentration and increasing the thickness of the white layer.
[0030]
The product of the numerical value of the titanium dioxide concentration (wt%) and the thickness (μm) of the white layer is preferably 800 or more, and more preferably 1000 or more.
[0031]
The thickness of the white layer can be measured by optical microscope observation of the film cross section.
[0032]
The transparent layer may be only the base resin, but may contain an additive. Examples of the additive include an antioxidant, a weather resistance stabilizer, a lubricant, and an antiblocking agent.
[0033]
Further, various transparent additives (for example, a heat retaining agent, a low content of titanium dioxide, etc.) may be contained.
[0034]
The thickness of the transparent layer is preferably 1 to 50 μm, more preferably 3 to 30 μm.
[0035]
As a method for producing the multilayer film of the present invention, for example, (1) inflation coextrusion molding, (2) T-die coextrusion molding, (3) multilayer calendaring, (4) multilayer biaxial stretching, etc. Although three layers can be formed simultaneously, the black layer and the white layer may be integrally formed by the above method, and the transparent layer may be bonded.
[0036]
【Example】
Examples of the present invention will be described below, but the present invention is not limited to these examples.
[0037]
Example 1
(1) Preparation of film sample Film samples 1 to 10 shown in Table 1 were prepared.
[0038]
(1) Base resin
Two types of LLDPE (linear low density polyethylene) and metallocene PE (metallocene polyethylene) were used.
LLDPE: specific gravity 0.920, melt flow rate 1
Metallocene PE: specific gravity 0.915, melt flow rate 2
[0039]
(2) The following additives were added to the transparent layer composition base resin.
Silica: 0.1% by weight based on the base resin
Hindered amine: 0.1% by weight based on the base resin
[0040]
(3) Titanium dioxide was mixed into the white layer composition base resin. The concentration of titanium dioxide was determined so that the product of the titanium dioxide concentration (wt%) and the thickness (μm) became a value shown in Table 1 for each sample.
[0041]
(4) 3 parts by weight of carbon black was mixed with 97 parts by weight of the black layer composition base resin.
[0042]
(5) Manufacturing method The compositions of (2) to (4) above are melt-kneaded at a temperature of 160 ° C. in separate extruders, and supplied to one inflation molding die to bond the molten films together in the die. Then, after extruding into a tube, it was blown up, cooled and molded to obtain multilayer film samples 1-10.
The thickness of each layer is shown in Table 1.
[0043]
(test)
Using the multilayer film samples 1 to 10 described above, a multi-laying test was conducted at a test farm of Mikado Chemical Co., Ltd.
[0044]
On the test farm, 11 test rows of 60 cm wide and 3 m long were prepared, and each agricultural film was laid on the surface.
In addition, as a reference test, one ridge that does not lay a film was provided.
[0045]
The film was stretched on May 23, and was carried out at an outside temperature of 37 ° C. on July 23 (sunny day).
Further, the same test row was created on July 21 and each new test film was laid in the same manner, and measurement was performed on July 23.
[0046]
[Highest daytime temperature during the day]
The daytime maximum ground temperature was measured using a thermocouple thermometer at a position 7 cm below the film cover. The results are shown in Table 1.
[0047]
[Difference from bare ground temperature]
Using a thermocouple thermometer installed at the same depth of 7 cm as the cocoon where the film was installed as a reference test, the temperature was recorded simultaneously with the other cocoons and the difference was read. The results are shown in Table 1.
[0048]
[Evaluation of surface dirt]
Films were collected two months after the multi-laying, and the reflectance at 420 nm was determined with an ultraviolet-visible spectrophotometer, and the degree of contamination was evaluated from the decrease in reflectance compared to the reflectance of the film before laying. The results are shown in Table 1.
[0049]
[Table 1]
Figure 0003776350
[0050]
As apparent from Table 1 above, the film of the present invention maintains a high light reflectance, and can be used for actual agricultural applications to lower the ground temperature for a long period of time.
[0051]
【The invention's effect】
As described above, according to the present invention, it is possible to provide an agricultural film that prevents soiling on the film surface and does not reduce the effect of suppressing increase in ground temperature, and an agricultural film that can easily remove the soiling even if the film surface is soiled. .

Claims (5)

ベース樹脂がポリオレフィン系樹脂である多層フィルムであり、少なくとも黒色層、白色層及び透明層の3層からなり、黒色層/白色層/透明層の順に層構成され、白色層の二酸化チタン濃度(wt%)の数値と厚さ(μm)の数値の積が500以上であることを特徴とする農業用フィルム。The base resin is a multilayer film made of a polyolefin-based resin, consisting of at least three layers of a black layer, a white layer, and a transparent layer, and is composed of a black layer / a white layer / a transparent layer in this order. %) And the product of thickness (μm) are 500 or more. 白色層の二酸化チタン濃度(wt%)の数値と厚さ(μm)の数値の積が800以上である請求項1記載の農業用フィルム。The agricultural film according to claim 1, wherein the product of the numerical value of the titanium dioxide concentration (wt%) and the thickness (µm) of the white layer is 800 or more. 白色層の二酸化チタン濃度(wt%)の数値と厚さ(μm)の数値の積が1000以上である請求項1記載の農業用フィルム。The agricultural film according to claim 1, wherein the product of the titanium dioxide concentration (wt%) and the thickness (µm) of the white layer is 1000 or more. ベース樹脂が直鎖状低密度ポリエチレン(LLDPE)であることを特徴とする請求項1、2又は3記載の農業用フィルム。The agricultural film according to claim 1, 2 or 3, wherein the base resin is linear low density polyethylene (LLDPE). ベース樹脂がメタロセンポリエチレンであることを特徴とする請求項1、2又は3記載の農業用フィルム。The agricultural film according to claim 1, 2 or 3, wherein the base resin is metallocene polyethylene.
JP2001398221A 2001-12-27 2001-12-27 Agricultural film Expired - Fee Related JP3776350B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2001398221A JP3776350B2 (en) 2001-12-27 2001-12-27 Agricultural film

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2001398221A JP3776350B2 (en) 2001-12-27 2001-12-27 Agricultural film

Publications (2)

Publication Number Publication Date
JP2003191392A JP2003191392A (en) 2003-07-08
JP3776350B2 true JP3776350B2 (en) 2006-05-17

Family

ID=27603743

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2001398221A Expired - Fee Related JP3776350B2 (en) 2001-12-27 2001-12-27 Agricultural film

Country Status (1)

Country Link
JP (1) JP3776350B2 (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4825011B2 (en) * 2006-01-20 2011-11-30 みかど化工株式会社 Agricultural multi-film
US7864163B2 (en) 2006-09-06 2011-01-04 Apple Inc. Portable electronic device, method, and graphical user interface for displaying structured electronic documents
US7956849B2 (en) 2006-09-06 2011-06-07 Apple Inc. Video manager for portable multifunction device
ES2399135B1 (en) * 2013-02-18 2014-01-28 Sphere Group Spain S.L. Biodegradable padding for agricultural applications
JP2014198043A (en) * 2013-03-14 2014-10-23 積水フィルム株式会社 Agricultural mulch film

Also Published As

Publication number Publication date
JP2003191392A (en) 2003-07-08

Similar Documents

Publication Publication Date Title
JP5263298B2 (en) Agricultural light scattering fluororesin film and method for producing the same
JP2002513273A (en) Improved agricultural multi-film and method of using same
CN1777359B (en) Plant protection covering
JP3776350B2 (en) Agricultural film
OA10437A (en) Cover for growing bananas
JP4825011B2 (en) Agricultural multi-film
CN106541662A (en) A kind of silver-colored unregistered land film and its preparation technology
US7866088B1 (en) Barrier mulch films
NZ310386A (en) Greenhouse comprising cover support and thermoplastic film having variable light diffuse surface
JP2001045880A (en) Film for farming
JP5859997B2 (en) Agricultural multilayer multi-film
JP4694041B2 (en) Agricultural coating film
JPH0465646B2 (en)
KR100624606B1 (en) Envelopment for growing non-environmental pollution apples/pears and Method for growing apples/pears using the same
JP6060249B2 (en) Agricultural multilayer multi-film
JP2002335775A (en) Method for cultivating farm crop
JPS5876031A (en) Agricultural cover material and culturing of cut lily flower using same
JP2771637B2 (en) Crop cultivation coated film and cultivation method using the same
JPS62122545A (en) Harmful insect evading film or sheet
Cascone et al. Agronomic Evaluation of an Innovative Covering Thermal PE/PA Film: Two Years of Research on Tomato (Lycopersicon esculentum Mill.)
JPS6037792B2 (en) agricultural film
JP2017086042A (en) Agricultural sheet
JP2022153220A (en) Sole plate for fruit/vegetable culture medium
JPH0229294B2 (en)
JPS5890960A (en) Agricultural laminated film

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20040416

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20050713

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20051101

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20051221

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20060124

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20060222

R150 Certificate of patent or registration of utility model

Ref document number: 3776350

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

Free format text: JAPANESE INTERMEDIATE CODE: R150

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20100303

Year of fee payment: 4

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20100303

Year of fee payment: 4

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20110303

Year of fee payment: 5

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20120303

Year of fee payment: 6

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20130303

Year of fee payment: 7

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

LAPS Cancellation because of no payment of annual fees