JP3492237B2 - Display device manufacturing method - Google Patents

Display device manufacturing method

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Publication number
JP3492237B2
JP3492237B2 JP13491899A JP13491899A JP3492237B2 JP 3492237 B2 JP3492237 B2 JP 3492237B2 JP 13491899 A JP13491899 A JP 13491899A JP 13491899 A JP13491899 A JP 13491899A JP 3492237 B2 JP3492237 B2 JP 3492237B2
Authority
JP
Japan
Prior art keywords
electrode
substrate
display device
electrophoretic particles
charged
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP13491899A
Other languages
Japanese (ja)
Other versions
JP2000322004A (en
Inventor
正浩 中西
勉 池田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Canon Inc
Original Assignee
Canon Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Canon Inc filed Critical Canon Inc
Priority to JP13491899A priority Critical patent/JP3492237B2/en
Priority to US09/570,692 priority patent/US6524153B1/en
Publication of JP2000322004A publication Critical patent/JP2000322004A/en
Priority to US10/162,599 priority patent/US6729924B2/en
Application granted granted Critical
Publication of JP3492237B2 publication Critical patent/JP3492237B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Electrochromic Elements, Electrophoresis, Or Variable Reflection Or Absorption Elements (AREA)
  • Devices For Indicating Variable Information By Combining Individual Elements (AREA)

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】本発明は、帯電泳動粒子を移
動させて表示を行う表示装置の製造方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method of manufacturing a display device in which charged electrophoretic particles are moved for displaying.

【0002】[0002]

【従来の技術】近年、情報機器の発達に伴い、低消費電
力で薄型の表示装置のニーズが増しており、これらニー
ズに合わせた表示装置の研究や開発が盛んに行われてい
る。中でも液晶表示装置は、液晶分子の配列を電気的に
制御して液晶の光学的特性を変化させるもので、上記の
ニーズに対応できる表示装置として活発な開発が行われ
商品化されている。
2. Description of the Related Art In recent years, with the development of information equipment, there has been an increasing need for low power consumption and thin display devices, and research and development of display devices meeting these needs have been actively conducted. Among them, the liquid crystal display device, which electrically controls the alignment of liquid crystal molecules to change the optical characteristics of the liquid crystal, has been actively developed and commercialized as a display device that can meet the above needs.

【0003】そのような表示装置の1つとして、Har
old D. Lees等によって提案された電気泳動
表示装置(米国特許、USP3612758号)が知ら
れている。図7は、その電気泳動表示装置の構造及び動
作原理を示す図であるが、該表示装置P3 は、所定間隙
を開けた状態に配置された一対の基板1a,1bを備え
ており、各基板1a,1bには電極36,37がそれぞ
れ形成されている。また、基板間隙には、正極性に帯電
されると共に着色された多数の帯電泳動粒子5と、色素
が溶解されて帯電泳動粒子5とは別の色に着色された泳
動用分散液4とが配置されており、さらに隔壁3が配置
されて、該間隙を基板の面方向に沿った多数の区画2
(図には1つの区画のみ図示)に分割して帯電泳動粒子
5の偏在を防止すると共に基板間隙を規定するように構
成されている。
Har is one of such display devices.
old D.D. An electrophoretic display device proposed by Lees et al. (US Pat. No. 3,612,758) is known. FIG. 7 is a diagram showing the structure and operation principle of the electrophoretic display device. The display device P 3 includes a pair of substrates 1a and 1b arranged with a predetermined gap therebetween. Electrodes 36 and 37 are formed on the substrates 1a and 1b, respectively. Further, in the gap between the substrates, a large number of charged electrophoretic particles 5 that are positively charged and colored, and a migration dispersion liquid 4 in which a dye is dissolved and colored in a color different from that of the charged electrophoretic particles 5 are formed. A plurality of partitions 2 are arranged along the plane direction of the substrate by arranging partition walls 3 further.
(Only one section is shown in the drawing) to prevent uneven distribution of the charged electrophoretic particles 5 and to define the substrate gap.

【0004】このような表示装置P3 において、同図
(a) に示すように、図示下側の電極37に負極性の電圧
を印加すると共に図示上側の電極36に正極性の電圧を
印加すると、正極性に帯電されている帯電泳動粒子5は
下側の電極37を覆うように集まり、図示A方向から表
示装置を眺めると、泳動用分散液4と同じ色の表示が行
われる。反対に、同図(b) に示すように、図示下側の電
極37に正極性の電圧を印加すると共に図示上側の電極
36に負極性の電圧を印加すると、正極性に帯電されて
いる帯電泳動粒子5は上側の電極36を覆うように集ま
り、図示A方向から表示装置を眺めると、帯電泳動粒子
5と同じ色の表示が行われる。このような駆動を区画単
位で行うことにより、多数の区画によって任意の画像が
表示される。
In such a display device P 3 , the same figure is used.
As shown in (a), when a negative voltage is applied to the electrode 37 on the lower side in the drawing and a positive voltage is applied to the electrode 36 on the upper side in the drawing, the charged electrophoretic particles 5 that are positively charged move downward. When the display devices are gathered so as to cover the side electrodes 37 and viewed from the direction A in the drawing, the same color as the electrophoretic dispersion liquid 4 is displayed. On the other hand, as shown in FIG. 2B, when a positive voltage is applied to the lower electrode 37 in the figure and a negative voltage is applied to the upper electrode 36 in the figure, the positively charged The electrophoretic particles 5 gather to cover the upper electrode 36, and when the display device is viewed from the direction A in the figure, the same color as the charged electrophoretic particles 5 is displayed. By performing such driving for each section, an arbitrary image is displayed by a large number of sections.

【0005】ところで、上述した表示装置P3 において
は、各区画2の色濃度がほぼ均一であることが望まし
く、そのためには、帯電泳動粒子5は各区画毎にほぼ等
しい量だけ配置しておく必要がある。そのための製造方
法としては以下のような方法があった。すなわち、 特開昭64−86117号公報に開示されている方
法であって、泳動用分散液4に浸漬されることよって膨
潤する(体積を増す)材料で隔壁3を作成しておき、隔
壁3が膨潤していないときに泳動用分散液4を帯電泳動
粒子5と共に注入し、その後、該分散液によって隔壁3
を膨潤させて区画2を形成する方法や、 特開平1−248183号公報に開示されている方
法であって、基板1a又は1bに各区画毎に貫通孔を穿
設しておき、一対の基板1a,1bを貼り合わせた後
に、これらの貫通孔を介して泳動用分散液4を帯電泳動
粒子5と共に注入する方法や、 特開平2−223935号公報に開示されている方
法であって、一方の基板1a又は1bに隔壁3を形成し
たものを、帯電泳動粒子5を分散させた分散液4の中に
浸し、その状態で可撓性フィルム(他方の基板)を順次
圧着していく方法、 などがある。
By the way, in the above-mentioned display device P 3 , it is desirable that the color density of each section 2 is substantially uniform. For that purpose, the charged electrophoretic particles 5 are arranged in substantially equal amounts in each section. There is a need. As a manufacturing method therefor, there have been the following methods. That is, in the method disclosed in JP-A-64-86117, the partition wall 3 is made of a material that swells (increases the volume) by being immersed in the electrophoretic dispersion liquid 4, and the partition wall 3 is prepared in advance. When the particles are not swollen, the electrophoretic dispersion liquid 4 is injected together with the charged electrophoretic particles 5, and then the partition walls 3 are formed by the electrophoretic dispersion liquid.
And a method for forming compartments 2 by swelling the compartments, or a method disclosed in Japanese Patent Application Laid-Open No. 1-248183, wherein a through-hole is formed in each compartment in the substrate 1a or 1b to form a pair of substrates. A method of injecting the electrophoretic dispersion liquid 4 together with the charged electrophoretic particles 5 through these through holes after laminating 1a and 1b, and a method disclosed in Japanese Patent Laid-Open No. 223935/1990. The substrate 1a or 1b having the partition walls 3 formed thereon is dipped in the dispersion liquid 4 in which the charged electrophoretic particles 5 are dispersed, and the flexible film (the other substrate) is sequentially pressure-bonded in that state. and so on.

【0006】[0006]

【発明が解決しようとする課題】しかしながら、上記
〜の方法を用いても、帯電泳動粒子5を各区画毎にほ
ぼ等しい量だけ配置することには限界があって、各区画
2の色濃度が等しくなく、表示品位が悪くなるという問
題があった。
However, even if the above methods (1) to (4) are used, there is a limit to disposing the charged electrophoretic particles 5 in substantially equal amounts in each section, and the color density of each section 2 is limited. There is a problem that they are not equal and display quality is deteriorated.

【0007】なお、帯電泳動粒子5を各区画毎にほぼ等
しい量だけ配置することができない理由は以下の通りで
ある。すなわち、上記の方法では、泳動用分散液4の
注入は、基板の一端部から他端部にかけて基板面に沿っ
た方向に行われるが、帯電泳動粒子5が、帯電されてい
るために、注入方向の上流側において基板や隔壁3等の
表面に付着してしまって基板間隙の隅々まで行き渡ら
ず、帯電泳動粒子5の密度は、注入方向上流側が高くて
注入方向下流側が低くなるからである。また、上記の
方法では、帯電されている帯電泳動粒子5が貫通孔部分
に付着し易く、その付着量が多い区画においては帯電泳
動粒子5の各区画への注入が阻害されてしまい、付着量
の少ない区画においては帯電泳動粒子5の注入量が比較
的多くなるからである。なお、表示装置の精細度を高め
る場合には区画面積を小さくせざるを得ず、貫通孔の形
成自体が困難になるという問題もあった。さらに、上記
の方法では、種々の理由(例えば、隔壁3の高さに違
いがある場合や、可撓性フィルムを順次圧着していくと
きの押圧力のバラツキ)によって各区画の分散液4の量
が異なってしまい、それに伴って、帯電泳動粒子5の量
が区画毎に等しくならないからである。
The reason why the charged electrophoretic particles 5 cannot be arranged in substantially equal amounts in each section is as follows. That is, in the above method, the injection of the electrophoretic dispersion liquid 4 is performed in the direction along the substrate surface from one end to the other end of the substrate, but since the charged electrophoretic particles 5 are charged, the injection is performed. This is because the charged electrophoretic particles 5 adhere to the surfaces of the substrate and the partition walls 3 on the upstream side in the direction and do not spread to every corner of the substrate gap, and the density of the charged electrophoretic particles 5 is high in the injection direction upstream side and low in the injection direction downstream side. . Further, in the above method, the charged electrophoretic particles 5 are easily attached to the through-hole portion, and the injection of the electrophoretic particles 5 into each section is hindered in the section where the attached amount is large, so that the attached amount. This is because the injection amount of the charged electrophoretic particles 5 is relatively large in a section having a small number. In addition, when increasing the definition of the display device, there is no choice but to reduce the partition area, which makes it difficult to form the through hole itself. Furthermore, in the above method, the dispersion liquid 4 in each section is dispersed for various reasons (for example, when the height of the partition wall 3 is different or when the flexible film is sequentially pressed). This is because the amounts are different, and accordingly, the amounts of the charged electrophoretic particles 5 are not equal in each section.

【0008】そこで、本発明は、表示品位の悪化を防止
する表示装置の製造方法を提供することを目的とするも
のである。
[0008] Therefore, an object of the present invention is to provide a method of manufacturing a display device which prevents deterioration of display quality.

【0009】[0009]

【課題を解決するための手段】本発明は上記事情を考慮
してなされたものであり、所定間隙を開けた状態に配置
された一対の基板と、該所定間隙を該基板の面に沿った
複数の区画に分割するように配置された隔壁部材と、こ
れら複数の区画にそれぞれ配置された泳動用分散液及び
多数の帯電泳動粒子と、各区画にてこれらの泳動用分散
液及び帯電泳動粒子に対向するように配置された第1電
極及び第2電極と、からなる表示装置を製造する表示装
置の製造方法において、所定間隙を開けた状態に配置さ
れる前の前記一対の基板のうちの一の基板に対して、各
区画毎の量がほぼ等しくなるように前記多数の帯電泳動
粒子を配置し、かつ、前記泳動用分散液の配置は、前記
多数の帯電泳動粒子の配置よりも後に行う、ことを特徴
とする。
The present invention has been made in consideration of the above circumstances, and includes a pair of substrates arranged with a predetermined gap therebetween and the predetermined gap along the surface of the substrate. A partition member arranged so as to be divided into a plurality of compartments, an electrophoretic dispersion liquid and a large number of charged electrophoretic particles respectively arranged in the plurality of compartments, and these electrophoretic dispersion liquids and electrophoretic particles in each compartment A first electrode and a second electrode arranged so as to face each other, and a method of manufacturing a display device for manufacturing a display device, wherein: The large number of charged electrophoretic particles are arranged on one substrate so that the amounts of the respective compartments are substantially equal to each other, and the electrophoretic dispersion liquid is arranged after the arrangement of the large number of charged electrophoretic particles. The feature is to do.

【0010】[0010]

【発明の実施の形態】以下、図1乃至図6を参照して、
本発明の実施の形態について説明する。
DETAILED DESCRIPTION OF THE INVENTION Referring to FIGS.
An embodiment of the present invention will be described.

【0011】まず、本発明によって製造される表示装置
の構造について、図1及び図2を参照して説明する。
First, the structure of a display device manufactured according to the present invention will be described with reference to FIGS.

【0012】本発明によって製造される表示装置は、図
1及び図2に示すように、所定間隙を開けた状態に配置
された一対の基板1a,1bと、該所定間隙を該基板1
a,1bの面に沿った複数の区画2に分割するように配
置された隔壁部材3と、これら複数の区画2にそれぞれ
配置された泳動用分散液4及び多数の帯電泳動粒子5
と、これらの泳動用分散液4及び帯電泳動粒子5に対向
するように各区画2毎にそれぞれ配置された第1電極6
(図2では符号16)及び第2電極7(図2では符号1
7)と、を備えている。なお、前記帯電泳動粒子5は所
定の極性に帯電されている。
As shown in FIGS. 1 and 2, the display device manufactured according to the present invention includes a pair of substrates 1a and 1b arranged with a predetermined gap, and the substrate 1 having the predetermined gap.
A partition member 3 arranged so as to be divided into a plurality of sections 2 along the surfaces a and 1b, a dispersion liquid 4 for migration and a large number of charged electrophoretic particles 5 respectively arranged in the plurality of sections 2.
And a first electrode 6 arranged in each section 2 so as to face the electrophoretic dispersion liquid 4 and the charged electrophoretic particles 5.
(Reference numeral 16 in FIG. 2) and the second electrode 7 (reference numeral 1 in FIG. 2)
7) and are provided. The charged electrophoretic particles 5 are charged to have a predetermined polarity.

【0013】この場合、第1電極及び第2電極は、図1
に符号6,7で示すように同じ基板1bに支持させても
良く、図2に符号16,17で示すように別々の基板1
a,1bに支持させても良い。
In this case, the first electrode and the second electrode are as shown in FIG.
2 may be supported on the same substrate 1b as indicated by reference numerals 6 and 7, and separate substrates 1b may be supported as indicated by reference numerals 16 and 17 in FIG.
It may be supported by a and 1b.

【0014】これらの第1電極6及び第2電極7を同じ
基板1bに支持させる場合には、図1に示すように、各
区画2において、第1電極6が前記泳動用分散液4に対
向(露出)している部分の面積S1 (以下、“第1電極
6の露出面積S1 ”とする)の方を第2電極7の露出面
積S2 よりも大きくしておき、第1電極6が前記泳動用
分散液4に対向している部分を第1色(例えば、白色
や、表示装置を反射型にする場合には金属色)に着色す
ると共に、前記帯電泳動粒子5を第2色(例えば、黒
色)に着色すると良い。ここで、第1色の着色は、上述
のように第1電極6が前記泳動用分散液4に対向してい
る部分に施されていれば良く、第1電極6自体を着色し
ても、該第1電極6を被覆する膜(ex. 電極保護膜)を
着色しても良い。かかる場合、図1に示すように、帯電
泳動粒子5が第1電極6を覆うように集まった区画2に
おいては第2色(例えば、黒色)の表示が行われ、第2
電極7を覆うように集まった区画2においては第1色
(例えば、白色)の表示が行われることとなる。ところ
で、この場合の表示コントラストは第1電極6及び第2
電極7の露出面積比(=第2電極7の露出面積/第1電
極6の露出面積)に大きく依存し、該露出面積比が大き
い程コントラストが小さくなり、該露出面積比が小さい
程コントラストが大きくなる。大きいコントラストを実
現するには、この露出面積比を1/2〜1/4程度にす
ると良い。なお、図1においては、第1電極6は、第2
電極7に重なるように配置されると共にそれらの間に絶
縁層8が配置されて絶縁されているが、もちろんこれに
限る必要はなく、両電極6,7を重ならないように配置
しても良い。
When the first electrode 6 and the second electrode 7 are supported on the same substrate 1b, the first electrode 6 faces the electrophoretic dispersion liquid 4 in each section 2 as shown in FIG. The area S 1 of the (exposed) portion (hereinafter referred to as “exposed area S 1 of the first electrode 6”) is made larger than the exposed area S 2 of the second electrode 7, and the first electrode The portion of 6 facing the electrophoretic dispersion liquid 4 is colored with a first color (for example, white, or a metal color when the display device is a reflective type), and the charged electrophoretic particles 5 are colored with a second color. Coloring (for example, black) is preferable. Here, the first color may be colored as long as it is applied to the portion where the first electrode 6 faces the electrophoretic dispersion liquid 4 as described above, and even if the first electrode 6 itself is colored, The film covering the first electrode 6 (ex. Electrode protective film) may be colored. In this case, as shown in FIG. 1, the second color (for example, black) is displayed in the section 2 in which the charged electrophoretic particles 5 are gathered so as to cover the first electrode 6, and the second color is displayed.
In the section 2 gathered so as to cover the electrodes 7, the first color (for example, white) is displayed. By the way, the display contrast in this case is different from that of the first electrode 6 and the second electrode 6.
It largely depends on the exposed area ratio of the electrode 7 (= exposed area of the second electrode 7 / exposed area of the first electrode 6). The larger the exposed area ratio, the smaller the contrast, and the smaller the exposed area ratio, the more the contrast. growing. In order to realize a large contrast, this exposed area ratio may be set to about 1/2 to 1/4. In addition, in FIG. 1, the first electrode 6 is
The electrodes 7 and 7 are arranged so as to overlap with each other, and the insulating layer 8 is arranged between them to be insulated. However, it is not limited to this, and both electrodes 6 and 7 may be arranged so as not to overlap. .

【0015】一方、図2に示すように第1電極16及び
第2電極17を別々の基板1a,1bに支持させる場合
には、少なくともいずれか一方の電極16(観察者側に
配置される電極16)を透明にすると共に区画2のほぼ
全体に(必ずしも基板全体に形成する必要はないが、少
なくとも区画2のほぼ全体に)形成しておき、前記泳動
用分散液4を第1色(例えば、青色)に着色すると共に
帯電泳動粒子5を第2色(例えば、黒色)に着色をして
おく。かかる場合、図2に示すように、帯電泳動粒子5
が電極17を覆うように集まった区画2においては、図
示の矢印Aの方向から表示装置P2 を見ると、泳動用分
散液4のみが視認されて帯電泳動粒子5は視認されず、
泳動用分散液4によって第1色表示が行われることとな
る。また、帯電泳動粒子5が電極16を覆うように集ま
った区画2においては、第2色に着色された帯電泳動粒
子5のみが視認されて泳動用分散液4は視認されず、第
2色表示が行われることとなる。なお、かかる場合、表
示コントラストは第1電極16及び第2電極17の露出
面積比に依存しないので、上述のように少なくともいず
れか一方の電極16が区画2のほぼ全体に形成されてい
れば足り、表示コントラストの観点から両電極16,1
7の露出面積比を調整する必要は無い。すなわち、表示
コントラストの観点からは、他方の電極17の露出面積
を前記一方の電極16の露出面積に比べて小さくする必
要はなく、例えば両方の電極16,17を区画2のほぼ
全体に形成するようにしても良い。
On the other hand, when the first electrode 16 and the second electrode 17 are supported on separate substrates 1a and 1b as shown in FIG. 2, at least one of the electrodes 16 (the electrode arranged on the observer side). 16) is made transparent and is formed on almost the entire section 2 (not necessarily on the entire substrate, but at least on almost the entire section 2), and the electrophoretic dispersion liquid 4 is of the first color (for example, , Blue) and the charged electrophoretic particles 5 are colored in a second color (for example, black). In such a case, as shown in FIG.
When the display device P 2 is viewed from the direction of the arrow A in the section 2 where the particles are collected so as to cover the electrodes 17, only the electrophoretic dispersion liquid 4 is visually recognized and the charged electrophoretic particles 5 are not visually recognized.
The first color display is performed by the electrophoretic dispersion liquid 4. In the section 2 in which the charged electrophoretic particles 5 are collected so as to cover the electrodes 16, only the charged electrophoretic particles 5 colored in the second color are visually recognized and the electrophoretic dispersion liquid 4 is not visually recognized. Will be performed. In this case, since the display contrast does not depend on the exposed area ratio of the first electrode 16 and the second electrode 17, it is sufficient if at least one of the electrodes 16 is formed on almost the entire section 2 as described above. , Both electrodes 16 and 1 from the viewpoint of display contrast
It is not necessary to adjust the exposed area ratio of No. 7. That is, from the viewpoint of display contrast, it is not necessary to make the exposed area of the other electrode 17 smaller than the exposed area of the one electrode 16, and for example, both electrodes 16 and 17 are formed in almost the entire section 2. You may do it.

【0016】ところで、第1電極6,16及び第2電極
7,17が同じ基板1bに支持されている場合、及び別
々の基板1a,1bに支持されている場合を問わず、こ
れらの電極6,7,16,17は、基板1a,1bに接
するように形成されていてもいなくても良い。また、こ
れらの電極6,7,16,17の表面には、必要に応じ
て絶縁層8や電極保護層9やブラックマトリクスパター
ンを形成すると良い。
By the way, regardless of whether the first electrodes 6 and 16 and the second electrodes 7 and 17 are supported by the same substrate 1b, or whether they are supported by different substrates 1a and 1b, these electrodes 6 , 7, 16 and 17 may or may not be formed in contact with the substrates 1a and 1b. Further, on the surfaces of these electrodes 6, 7, 16 and 17, it is preferable to form an insulating layer 8, an electrode protective layer 9 and a black matrix pattern as needed.

【0017】また、上述した第1電極6と第2電極7
(又は第1電極16と第2電極17)との間の電位差の
極性は、それぞれの区画2において別個独立に変更でき
るように構成されている。その方法としては、 * 第1電極6及び第2電極7の双方(又は第1電極1
6と第2電極17の双方)を各区画2にドット状に形成
して、それぞれの電極6,7又は16,17毎に任意の
極性の電圧を印加する方法(不図示)や、 * 図1及び図2に示すように、一方の電極6,16を
基板1a又は1bのほぼ全体に亘って形成して共通電極
にすると共に他方の電極7,17を各区画2毎にドット
状に形成し、共通電極とした一方の電極6,16を例え
ば接地等して基準電位に保持すると共に、他方の電極
7,17には任意の極性の電圧を印加する方法、 を挙げることができる。ここで、印加電圧の大きさは、
帯電泳動粒子5の帯電量や電極間ピッチに応じて調整す
れば良いが、通常は数十V程度が必要である。
Further, the above-mentioned first electrode 6 and second electrode 7
The polarity of the potential difference between (or the first electrode 16 and the second electrode 17) is configured so that it can be changed independently in each section 2. The method is as follows: * Both the first electrode 6 and the second electrode 7 (or the first electrode 1
6 and the second electrode 17) are formed in a dot shape in each section 2 and a voltage of any polarity is applied to each of the electrodes 6, 7 or 16, 17 (not shown), or * As shown in FIG. 1 and FIG. 2, one electrode 6, 16 is formed over almost the entire substrate 1a or 1b to be a common electrode, and the other electrode 7, 17 is formed in a dot shape for each section 2. However, one of the electrodes 6 and 16 serving as the common electrode may be grounded or the like to be held at a reference potential, and a voltage of arbitrary polarity may be applied to the other electrodes 7 and 17. Here, the magnitude of the applied voltage is
It may be adjusted according to the charge amount of the charged electrophoretic particles 5 and the pitch between the electrodes, but normally, several tens of V is required.

【0018】一方、表示装置P1 ,P2 は透過型として
も良く反射型としても良い。なお、図1において図示の
矢印Aの方向から観察するとした場合、図1に示す第1
電極6には、表示装置P1 を透過型とする場合にはIT
O(インジウム・ティン・オキサイド)等の透明電極を
用い、表示装置P1 を反射型とする場合にはAlなどの
金属電極を用いれば良い。また、図2に示す第1電極6
には、表示装置P2 を透過型とするか反射型とするかを
問わずITO(インジウム・ティン・オキサイド)等の
透明電極を用いれば良い。
On the other hand, the display devices P 1 and P 2 may be transmissive or reflective. In addition, when observing from the direction of arrow A shown in FIG.
When the display device P 1 is of a transmissive type, the electrode 6 has an IT
If a transparent electrode such as O (indium tin oxide) is used and the display device P 1 is of a reflective type, a metal electrode such as Al may be used. In addition, the first electrode 6 shown in FIG.
For this, a transparent electrode such as ITO (Indium Tin Oxide) may be used regardless of whether the display device P 2 is a transmissive type or a reflective type.

【0019】さらに、図1に示す第2電極7には、Al
やTi等の金属材料を用いれば良いが、好ましくは色の
黒い材料、例えばTiCなどが好ましく用いられる。
Further, the second electrode 7 shown in FIG.
Although a metal material such as Ti or Ti may be used, a black material, such as TiC, is preferably used.

【0020】またさらに、絶縁層8には、アクリル樹脂
やポリイミド樹脂等の有機材料、或は酸化シリコンや窒
化シリコン等の無機材料を用いれば良い。なお、表示装
置を反射型とする場合には、アルミナ等の白色微粒子を
混入して散乱層としての機能を付与しても良い。
Furthermore, the insulating layer 8 may be made of an organic material such as acrylic resin or polyimide resin, or an inorganic material such as silicon oxide or silicon nitride. When the display device is of a reflection type, white fine particles such as alumina may be mixed to provide a function as a scattering layer.

【0021】一方、上述した基板1a,1bには一般的
なガラスを使用できるが、表示装置をフレキシブルなも
のにするには、ポリエチレンテレフタレート(PET)
やポリエーテルスルフォン(PES)等のプラスチック
フィルムを使用すれば良い。
On the other hand, general glass can be used for the above-mentioned substrates 1a and 1b, but polyethylene terephthalate (PET) is used to make the display device flexible.
Alternatively, a plastic film such as polyether sulfone (PES) may be used.

【0022】また、隔壁部材3には、シリコーンゴム、
フッ素ゴム、アクリルゴム等、或はその他感光性樹脂を
用いれば良い。
The partition member 3 is made of silicone rubber,
Fluorine rubber, acrylic rubber, or other photosensitive resin may be used.

【0023】さらに、帯電泳動粒子5には、ポリスチレ
ンやポリエチレンなどのポリマー樹脂を主成分とし、こ
れにカーボンなどの着色剤を混ぜ合わせたものを好適に
用いることができる。必要に応じて荷電制御剤等を混ぜ
合わせると良く、粒径は0.1〜100μmのものが好
ましく、小径の方が好ましい。
Further, as the electrophoretic particles 5, those having a polymer resin such as polystyrene or polyethylene as a main component and a colorant such as carbon mixed therein can be preferably used. If necessary, a charge control agent or the like may be mixed, and the particle diameter is preferably 0.1 to 100 μm, and the smaller diameter is more preferable.

【0024】またさらに、泳動用分散液4には、帯電泳
動粒子5が良好に帯電しかつ低粘度の液体を使用すると
良く、具体的には、シリコーンオイル、キシレン、トル
エン、アイソパーなどを用いれば良い。さらに、泳動用
分散液4には、必要に応じて比重の大きいものを用い、
泳動用分散液4の比重と帯電泳動粒子5の比重とをほぼ
等しくすると良い。
Furthermore, it is preferable to use, as the electrophoretic dispersion liquid 4, a liquid in which the charged electrophoretic particles 5 are favorably charged and has a low viscosity. Specifically, silicone oil, xylene, toluene, isoper, etc. are used. good. Further, as the electrophoretic dispersion liquid 4, one having a large specific gravity is used if necessary,
It is preferable that the specific gravity of the electrophoretic dispersion liquid 4 and the specific gravity of the charged electrophoretic particles 5 be substantially equal.

【0025】次に、表示装置P1 ,P2 の製造方法につ
いて、図3及び図4を参照して説明する。
Next, a method of manufacturing the display devices P 1 and P 2 will be described with reference to FIGS. 3 and 4.

【0026】表示装置P1 ,P2 を製造するに際して
は、前記一対の基板1a,1bを所定間隙を開けた状態
に配置する前までに、これら一対の基板1a,1bのう
ちの一の基板1a又は1bに対して、前記多数の帯電泳
動粒子5を散布し付着させる(図3(d) 及び図4(d) 参
照)。
When manufacturing the display devices P 1 and P 2 , one of the pair of substrates 1a and 1b is arranged before the pair of substrates 1a and 1b are arranged with a predetermined gap therebetween. The large number of charged electrophoretic particles 5 are scattered and attached to 1a or 1b (see FIGS. 3 (d) and 4 (d)).

【0027】ところで、上述した隔壁部材3の形成はい
ずれか一方の基板1a又は1bに対して行うが、この帯
電泳動粒子5の散布は、 * 隔壁部材3を形成する方の基板(図3(d) 参照)、 * 隔壁部材3を形成しない方の基板(図4(d) 参
照)、 のいずれに対して行っても良い。また、図3(d) では、
該隔壁部材3を形成して区画2を形成した後に帯電泳動
粒子5の散布を行っているが、該隔壁部材3を形成する
前の基板1a又は1bに対して該散布を行うようにして
もよい(不図示)。
By the way, the above-mentioned partition member 3 is formed on either one of the substrates 1a and 1b, but the spraying of the charged electrophoretic particles 5 is performed on the substrate on which the partition member 3 is formed (see FIG. d)), * the substrate on which the partition member 3 is not formed (see FIG. 4 (d)). Also, in FIG. 3 (d),
Although the electrophoretic particles 5 are sprayed after the partition member 3 is formed and the partition 2 is formed, the spraying may be performed on the substrate 1a or 1b before the partition member 3 is formed. Good (not shown).

【0028】かかる帯電泳動粒子5の散布は、図3(d)
に示すように該隔壁部材3を形成して区画2を形成した
基板に対して行う場合、及び区画2が形成されていない
基板(隔壁部材3を形成する前の基板や、図4(d) に示
すように隔壁部材3を形成しない方の基板)に対して行
う場合を問わず、各区画2(既に形成されている区画
2、或は後で形成される区画2)毎の帯電泳動粒子5の
散布量がほぼ等しくなるようにする。
Dispersion of the charged electrophoretic particles 5 is shown in FIG. 3 (d).
As shown in FIG. 4, when the partition member 3 is formed and the partition 2 is formed on the substrate, the substrate on which the partition 2 is not formed (the substrate before the partition member 3 is formed, or FIG. Charged electrophoretic particles for each section 2 (section 2 that has already been formed or section 2 that will be formed later) regardless of the case where the partition member 3 is not formed as shown in FIG. Make the spraying amount of 5 almost equal.

【0029】さらに、前記泳動用分散液4の前記複数の
区画2への配置は、前記多数の帯電泳動粒子5の散布よ
りも後に行う。なお、この泳動用分散液4の配置は、前
記一対の基板1a,1bを所定間隙を開けた状態に配置
する前に行っても良く(図3(e) 参照)、前記一対の基
板1a,1bを所定間隙を開けた状態に配置した後に行
っても良い(図4(e) 及び(f) 参照)。かかる場合、既
に各区画毎にほぼ等しい量ずつ配置されている帯電泳動
粒子5が各区画間で移動し合ってその配置状態が損なわ
れるおそれがあることから、 * 第1電極6及び第2電極7(又は第1電極16及び
第2電極17)の少なくとも一方の電極に電圧を印加し
て帯電泳動粒子5をそれぞれの区画2に静電吸着させた
状態で行なったり、 * 泳動用分散液4の配置を基板貼り合わせ後に行う場
合には、該泳動用分散液4を蒸気にして基板間隙に注入
し、その後冷却して液化させたり、 すると良い。
Further, the placement of the electrophoretic dispersion liquid 4 in the plurality of compartments 2 is performed after the application of the large number of charged electrophoretic particles 5. The electrophoretic dispersion liquid 4 may be placed before the pair of substrates 1a and 1b are placed with a predetermined gap (see FIG. 3 (e)), and the pair of substrates 1a and 1b may be placed. It may be performed after placing 1b in a state where a predetermined gap is opened (see FIGS. 4 (e) and 4 (f)). In such a case, the charged electrophoretic particles 5 that are already arranged in substantially equal amounts in each section may move between the sections and the arrangement state may be impaired. Therefore, the first electrode 6 and the second electrode 7 (or the first electrode 16 and the second electrode 17) by applying a voltage to at least one of the electrodes to electrostatically adsorb the charged electrophoretic particles 5 to the respective compartments 2, or the electrophoretic dispersion liquid 4. When the arrangement is performed after the substrates are bonded together, the electrophoretic dispersion liquid 4 may be vaporized and injected into the gap between the substrates, and then cooled to be liquefied.

【0030】また、上述した帯電泳動粒子5の散布は、
図5に示すように、前記帯電泳動粒子5を一の極性に帯
電させた状態で前記一の基板1a又は1bに対向する位
置に配置する共に(符号B参照)、前記一の基板1a又
は1bの近傍に配置した吸着電極21に電圧を印加して
該一の基板1a又は1bを他の極性(前記帯電泳動粒子
5の帯電極性とは異なる極性)に帯電させることにより
静電吸引力を発生させ電界による飛翔吸着を利用して行
うと良い。このような前記帯電泳動粒子5の散布は、前
記一の基板1a又は1bをその面方向に移動させながら
行うと良い。さらに、前記吸着電極21に印加する電圧
を可変可能に構成しておき(例えば、−1kV〜−2k
V)、該電圧を調整することによって前記帯電泳動粒子
5の散布量を変化させると良い。またさらに、前記吸着
電極21に印加する電圧の調整を前記一の基板1a又は
1bの移動(移動位置)に応じて行うことにより、前記
帯電泳動粒子5を散布する量を前記基板1a又は1bの
位置に応じて異ならせても良い。かかる場合、吸着電極
21に印加する電圧の極性は、前記帯電泳動粒子5の帯
電極性とは異なる極性とすれば良い。
The above-mentioned spraying of the charged electrophoretic particles 5 is
As shown in FIG. 5, the charged electrophoretic particles 5 are arranged in a position facing the one substrate 1a or 1b in a state of being charged to one polarity (see reference numeral B), and the one substrate 1a or 1b is also provided. An electrostatic attraction force is generated by applying a voltage to the adsorption electrode 21 arranged in the vicinity of to charge the one substrate 1a or 1b to another polarity (a polarity different from the charging polarity of the charged electrophoretic particles 5). Then, it is preferable to use the flying adsorption by the electric field. Such distribution of the charged electrophoretic particles 5 may be performed while moving the one substrate 1a or 1b in the surface direction. Further, the voltage applied to the adsorption electrode 21 is made variable (for example, -1 kV to -2 kV).
V), it is advisable to change the spray amount of the charged electrophoretic particles 5 by adjusting the voltage. Furthermore, by adjusting the voltage applied to the adsorption electrode 21 in accordance with the movement (movement position) of the one substrate 1a or 1b, the amount of the charged electrophoretic particles 5 to be dispersed can be adjusted by the amount of the substrate 1a or 1b. It may be different depending on the position. In this case, the polarity of the voltage applied to the adsorption electrode 21 may be different from the charging polarity of the charged electrophoretic particles 5.

【0031】なお、図5に示す吸着電極21は、前記一
の基板1a又は1bとは分離可能であって、前記帯電泳
動粒子5の散布に際して前記一の基板1a又は1bの裏
側(該基板1a又は1bを基準として帯電泳動粒子5が
散布される側とは反対の側)に配置されるものである
が、もちろんこれに限る必要はない。例えば、図6に示
すように、前記帯電泳動粒子5を散布する前までに前記
第1電極6を前記一の基板1a又は1bに形成してお
き、この第1電極6を、前記帯電泳動粒子5の散布に際
して前記吸着電極として用いると良い。すなわち、前記
帯電泳動粒子5を散布する際には、この第1電極6に電
圧を印加して、前記帯電泳動粒子5が付着される部分を
他の極性(前記帯電泳動粒子5の帯電極性とは異なる極
性)に帯電させると良い。
The adsorption electrode 21 shown in FIG. 5 is separable from the one substrate 1a or 1b, and when the charged electrophoretic particles 5 are sprayed, the back side (the substrate 1a) of the one substrate 1a or 1b is dispersed. Alternatively, it is arranged on the side opposite to the side on which the charged electrophoretic particles 5 are scattered based on 1b), but the arrangement is not limited to this. For example, as shown in FIG. 6, the first electrode 6 is formed on the one substrate 1a or 1b before the charged electrophoretic particles 5 are dispersed, and the first electrode 6 is formed on the substrate 1a or 1b. When spraying No. 5, it may be used as the adsorption electrode. That is, when the charged electrophoretic particles 5 are sprayed, a voltage is applied to the first electrode 6 so that the portion to which the charged electrophoretic particles 5 are attached has another polarity (the charge polarity of the charged electrophoretic particles 5 is different from that of the charged electrophoretic particles 5). Are charged with different polarities).

【0032】ところで、散布するに際して帯電泳動粒子
5を前記一の基板1a又は1bに対向する位置に配置す
る方法としては、該基板1a又は1bに対向配置された
部材22に帯電泳動粒子5を一時的に付着させておけば
良いが、その付着方法としては、 * 帯電泳動粒子5の帯電を利用する方法や、 * 帯電泳動粒子5に磁性体粉を混入しておき、その磁
性を利用する方法、 がある。但し、部材22への帯電泳動粒子5の付着力
(吸着力)は、吸着電極21(又は第1電極6)の電圧
印加によって帯電泳動粒子5が部材22から容易に離脱
できる程度にしておく必要がある。
By the way, as a method for disposing the charged electrophoretic particles 5 at a position facing the one substrate 1a or 1b when spraying, the charged electrophoretic particles 5 are temporarily placed on the member 22 placed so as to face the substrate 1a or 1b. It may be possible to attach the particles electrically, but as the attachment method, a method of using the charging of the charged electrophoretic particles 5 or a method of mixing magnetic powder in the charged electrophoretic particles 5 and utilizing the magnetism thereof , There is. However, the adhesion force (adsorption force) of the charged electrophoretic particles 5 to the member 22 needs to be set so that the charged electrophoretic particles 5 can be easily separated from the member 22 by applying a voltage to the adsorption electrode 21 (or the first electrode 6). There is.

【0033】なお、帯電泳動粒子5を一時的に付着させ
ておく部材22としては、不図示の駆動手段によって回
転駆動されるドラム状部材(以下“吸着ドラム”とす
る)を挙げることができる。また、この部材22の近傍
には、帯電泳動粒子5を一の極性に帯電させた状態で収
納するための帯電泳動粒子供給機構23を配置すると良
い。さらに、一の基板1a又は1bは、部材22の下方
を通って移動するようにすると良い。図中の符号24
は、吸着電極21に接続されて電圧を印加する電源を示
す。
As the member 22 to which the charged electrophoretic particles 5 are temporarily attached, a drum-shaped member (hereinafter referred to as "adsorption drum") which is rotationally driven by a driving means (not shown) can be mentioned. In addition, a charged electrophoretic particle supply mechanism 23 for accommodating the charged electrophoretic particles 5 in a state of being charged to one polarity may be arranged near the member 22. Further, one substrate 1a or 1b may be moved below the member 22. Reference numeral 24 in the figure
Indicates a power source that is connected to the adsorption electrode 21 and applies a voltage.

【0034】図5に示す装置において吸着ドラム22を
回転させると、帯電泳動粒子5は、帯電泳動粒子供給機
構23から吸着ドラム22の表面に静電吸着され、該ド
ラムと共に回転する。この状態で吸着電極21に電圧を
印加すると、該電圧印加によって基板1a又は1bに発
生する静電力が、吸着ドラム22への帯電泳動粒子5の
吸着力を上回り、帯電泳動粒子5は、基板1a又は1b
に向かって飛翔し基板1a又は1bに付着される。
When the adsorption drum 22 is rotated in the apparatus shown in FIG. 5, the charged electrophoretic particles 5 are electrostatically adsorbed on the surface of the adsorption drum 22 from the charged electrophoretic particle supply mechanism 23 and rotate together with the drum. When a voltage is applied to the adsorption electrode 21 in this state, the electrostatic force generated on the substrate 1a or 1b by the voltage application exceeds the adsorption force of the charged electrophoretic particles 5 on the adsorption drum 22, and the charged electrophoretic particles 5 are transferred to the substrate 1a. Or 1b
It flies toward and is attached to the substrate 1a or 1b.

【0035】次に、本実施の形態の効果について説明す
る。
Next, the effect of this embodiment will be described.

【0036】本実施の形態によれば、帯電泳動粒子5
は、各区画毎にほぼ等しい量ずつ配置されるため、該粒
子により表示される色の濃度も区画毎にほぼ等しくな
り、作成された表示装置の表示品位が良好となる。
According to the present embodiment, the charged electrophoretic particles 5 are
Are arranged in substantially equal amounts in each section, so that the densities of the colors displayed by the particles are also substantially equal in each section, and the display quality of the produced display device is good.

【0037】また、前記複数の区画2への泳動用分散液
4の配置を、第1電極6及び第2電極7の少なくとも一
方の電極に電圧を印加して帯電泳動粒子5をそれぞれの
区画2に静電吸着させた状態で行なった場合には、帯電
泳動粒子5の配置状態(各区画毎にほぼ等しい量ずつ配
置されている配置状態)が損なわれることを防止でき
る。
Further, the electrophoretic dispersion liquid 4 is arranged in the plurality of compartments 2 by applying a voltage to at least one of the first electrode 6 and the second electrode 7 so that the electrophoretic particles 5 are charged into the respective compartments 2. When the electrostatic adsorption is performed in the above state, it is possible to prevent the arrangement state of the charged electrophoretic particles 5 (the arrangement state in which substantially equal amounts are arranged in each section) from being impaired.

【0038】[0038]

【実施例】以下、実施例に沿って本発明を更に詳細に説
明する。
The present invention will be described in more detail below with reference to examples.

【0039】(実施例1)本実施例においては、図1に
示す表示装置P1 を、図3に示す方法によって製造し
た。
Example 1 In this example, the display device P 1 shown in FIG. 1 was manufactured by the method shown in FIG.

【0040】すなわち、図1に示すように、第1電極6
は一方の基板1bの表面全面に形成し、その第1電極6
の表面には絶縁層8や第2電極7や電極保護層9を順に
形成した。
That is, as shown in FIG. 1, the first electrode 6
Is formed on the entire surface of one substrate 1b, and its first electrode 6
An insulating layer 8, a second electrode 7, and an electrode protective layer 9 were sequentially formed on the surface of the.

【0041】なお、基板1a,1bにはポリエチレンテ
レフタレート(PET)を使用し、第1電極6には、反
射層としての機能を兼用させるためにAlを用いた。ま
た、絶縁層8には、アルミナ微粒子を混入して散乱層と
しての機能を付与したアクリル樹脂を用い、第2電極7
には、暗黒色を呈するTiCを用いた。さらに、隔壁
(隔壁部材)3にはシリコーンゴムを用い、帯電泳動粒
子5には、ポリスチレンを主成分とし、これにカーボン
及び荷電制御剤を混ぜ合わせたもの(粒径2μm)であ
って負極性に帯電されたものを用いた。また、泳動用分
散液4には透明のシリコーンオイルを使用した。
Polyethylene terephthalate (PET) was used for the substrates 1a and 1b, and Al was used for the first electrode 6 so that it also functions as a reflection layer. The insulating layer 8 is made of acrylic resin mixed with alumina fine particles to have a function as a scattering layer.
For this, TiC that exhibits a dark black color was used. Further, the partition wall (partition wall member) 3 is made of silicone rubber, and the electrophoretic particles 5 are mainly composed of polystyrene, which is mixed with carbon and a charge control agent (particle size 2 μm) and has a negative polarity. The one charged to was used. A transparent silicone oil was used as the electrophoretic dispersion liquid 4.

【0042】次に、表示装置P1 の製造方法について、
図3を参照して説明する。
Next, regarding the manufacturing method of the display device P 1 ,
This will be described with reference to FIG.

【0043】表示装置P1 を製造するに際しては、一方
の基板1bの表面全体に第1電極6を形成し、該電極6
の表面には絶縁層8を形成した(同図(a) 参照)。さら
に、絶縁層8の表面にはTiC被膜を形成し、各区画2
の70%ずつの部分をパターニングによって除去して第
2電極7をドット状に形成した(同図(b) 参照)。そし
て、第2電極7の表面には電極保護層9を形成し、その
表面には隔壁3をパターン形成した(同図(c) 参照)。
When manufacturing the display device P 1 , the first electrode 6 is formed on the entire surface of the one substrate 1b, and the electrode 6 is formed.
An insulating layer 8 was formed on the surface of the (see FIG. 3 (a)). Further, a TiC film is formed on the surface of the insulating layer 8 to form each partition 2
70% of each of the above was removed by patterning to form the second electrode 7 in a dot shape (see FIG. 2B). Then, the electrode protective layer 9 was formed on the surface of the second electrode 7, and the partition walls 3 were pattern-formed on the surface thereof (see FIG. 3C).

【0044】次に、図6に示す散布装置を用いて、帯電
泳動粒子5を各区画2に等量ずつ散布した(同図(d) 参
照)。
Next, using the spraying device shown in FIG. 6, the charged electrophoretic particles 5 were sprayed in equal amounts in each of the compartments 2 (see FIG. 6 (d)).

【0045】その後、第1電極6と第2電極7との間に
70Vの電圧を印加して帯電泳動粒子5をそれぞれの区
画2に静電吸着させた状態で、泳動用分散液4を各区画
2に注入し(同図(e) 参照)、同じく該電圧を印加した
状態で基板1a,1bの貼り合わせを行った(同図(f)
参照)。
Then, a voltage of 70 V is applied between the first electrode 6 and the second electrode 7 to electrostatically adsorb the charged electrophoretic particles 5 to the respective compartments 2, and the electrophoretic dispersion liquid 4 is applied to each of them. It was injected into the compartment 2 (see FIG. 2 (e)), and the substrates 1a and 1b were bonded together with the voltage applied (FIG. 2 (f)).
reference).

【0046】以上のようにして作成した表示装置P1
を、40Vの電圧を電極6,7に印加して駆動したとこ
ろ、コントラストが5であって応答速度が20msec
の良好な表示が得られた。なお、帯電泳動粒子5は負極
性に帯電されているため、図1に示すように第2電極7
に負極性の電圧を印加すると共に第1電極6に正極性の
電圧を印加した場合には、帯電泳動粒子5は、第1電極
6が露出された部分に集まる。本実施例においては、第
2電極7及び帯電泳動粒子5が共に黒色であるため、黒
表示を行うこととなる。
Display device P 1 created as described above
Was driven by applying a voltage of 40 V to the electrodes 6 and 7, the contrast was 5 and the response speed was 20 msec.
A good display of was obtained. Since the charged electrophoretic particles 5 are negatively charged, as shown in FIG.
When a negative voltage is applied to the first electrode 6 and a positive voltage is applied to the first electrode 6, the charged electrophoretic particles 5 gather in the portion where the first electrode 6 is exposed. In this embodiment, since the second electrode 7 and the charged electrophoretic particles 5 are both black, black display is performed.

【0047】また、各区画間の濃度ばらつきは観察され
ず、表示品位は良好であった。
Further, no density variation was observed between the sections, and the display quality was good.

【0048】(実施例2)本実施例においては、図2に
示す表示装置P2 を、図4に示す方法によって製造し
た。
Example 2 In this example, the display device P 2 shown in FIG. 2 was manufactured by the method shown in FIG.

【0049】すなわち、図2に示すように、第1電極1
6は一方の基板1aの表面全体に形成すると共に第2電
極17は他方の基板1bに各区画毎にドット状に形成
し、各電極16,17の表面には絶縁層8をそれぞれ形
成した。また、隔壁(隔壁部材)3には、第1電極16
の近傍であって第2電極17から離れた位置に貫通孔3
aを形成し、各区画2が連通されるようにした。この貫
通孔3aは、泳動用分散液4のみが区画2から他の区画
2へ移動でき、帯電泳動粒子5は移動できないような大
きさとした。
That is, as shown in FIG. 2, the first electrode 1
6 is formed on the entire surface of one substrate 1a, the second electrode 17 is formed in a dot shape for each section on the other substrate 1b, and the insulating layer 8 is formed on the surfaces of the electrodes 16 and 17, respectively. Further, the first electrode 16 is provided on the partition wall (partition member) 3.
At a position near the second electrode 17 and away from the through hole 3
a was formed so that each section 2 was communicated. The size of the through hole 3a was such that only the electrophoretic dispersion liquid 4 could move from the compartment 2 to the other compartment 2 and the charged electrophoretic particles 5 could not move.

【0050】なお、基板1a,1bには、ガスバリヤー
層が形成されたポリエーテルスルフォン(PES)を用
い、第1電極16にはITOを、第2電極17にはTi
を用いた。また、絶縁層8にはアクリル樹脂を用い、隔
壁3にはポリイミド樹脂を用いた。さらに、帯電泳動粒
子5には、酸化チタン粒子を荷電制御剤入りポリマーで
被覆した白色のもの(粒径3μm)であって正極性に帯
電させたものを使用し、泳動用分散液4には、青色顔料
によって青色に着色したシリコーンオイルを使用した。
For the substrates 1a and 1b, polyether sulfone (PES) having a gas barrier layer is used, ITO is used for the first electrode 16 and Ti is used for the second electrode 17.
Was used. Acrylic resin was used for the insulating layer 8 and polyimide resin was used for the partition walls 3. Further, as the charged electrophoretic particles 5, white particles (particle diameter 3 μm) in which titanium oxide particles are coated with a polymer containing a charge control agent and which are positively charged are used. A silicone oil colored blue with a blue pigment was used.

【0051】次に、表示装置P2 の製造方法について、
図4を参照して説明する。
Next, regarding the manufacturing method of the display device P 2 ,
This will be described with reference to FIG.

【0052】表示装置P2 を製造するに際しては、一方
の基板1aの表面全体に第1電極16を形成し(同図
(a) 参照)、該電極16の表面には絶縁層8を形成し
た。また、その表面には、貫通孔形成用レジストパター
ン18を基板端部から基板端部までライン状に形成し、
さらにレジストパターン18を覆うように隔壁3をパタ
ーン形成した。その後、貫通孔形成用レジストパターン
18を溶解除去し、隔壁3に貫通孔3aを形成した(同
図(b) 参照)。
When manufacturing the display device P 2 , the first electrode 16 is formed on the entire surface of the one substrate 1a (see FIG.
(See (a)), and the insulating layer 8 was formed on the surface of the electrode 16. Further, on the surface thereof, a through hole forming resist pattern 18 is formed in a line shape from the substrate end portion to the substrate end portion,
Further, the partition wall 3 was patterned so as to cover the resist pattern 18. After that, the through hole forming resist pattern 18 was dissolved and removed, and the through holes 3a were formed in the partition walls 3 (see FIG. 2B).

【0053】次に、他方の基板1bの表面に第2電極1
7をパターン形成し、その表面には絶縁層8を形成した
(同図(c) 参照)。
Next, the second electrode 1 is formed on the surface of the other substrate 1b.
7 was patterned, and an insulating layer 8 was formed on the surface (see FIG. 7C).

【0054】次に、図6に示す散布装置を用いて、帯電
泳動粒子5を(後で形成される区画2毎の散布量がほぼ
等しくなるように)基板1bに対して散布した(同図
(d) 参照)。
Next, using the spraying device shown in FIG. 6, the charged electrophoretic particles 5 were sprayed on the substrate 1b (so that the sprayed amount in each of the sections 2 formed later would be substantially equal) (see FIG. 6).
(See (d)).

【0055】その後、これらの基板1a,1bの貼り合
わせを行い(同図(e) 参照)、基板間隙を封止剤19で
封止して、泳動用分散液4の漏洩や蒸発を防止するよう
にした(同図(f) 参照)。
Thereafter, the substrates 1a and 1b are bonded to each other (see (e) in the same figure), and the gap between the substrates is sealed with a sealant 19 to prevent leakage and evaporation of the electrophoretic dispersion liquid 4. (See (f) in the figure).

【0056】なお、封止剤19には離れた2か所の位置
にそれぞれ開口部を設けておき(不図示)、一方の開口
部から基板間隙に残存している空気を吸引して減圧し、
他方の開口部から泳動用分散液4を注入した。これによ
って、泳動用分散液4は貫通孔3aを通って各区画2に
充填される。このとき、第2電極17に電圧を印加し、
貫通孔3aから離れた位置に帯電泳動粒子5を引き寄せ
ておき、帯電泳動粒子5が貫通孔3aを塞いで泳動用分
散液4の注入を阻害しないようにした。
It should be noted that the sealant 19 is provided with openings at two separate positions (not shown), and the air remaining in the substrate gap is sucked from one opening to reduce the pressure. ,
The electrophoretic dispersion liquid 4 was injected from the other opening. As a result, the electrophoretic dispersion liquid 4 is filled in the respective compartments 2 through the through holes 3a. At this time, a voltage is applied to the second electrode 17,
The charged electrophoretic particles 5 were attracted to a position away from the through holes 3a so that the charged electrophoretic particles 5 did not block the through holes 3a and hinder the injection of the electrophoretic dispersion liquid 4.

【0057】このように作成した表示装置P2 におい
て、第1電極16を接地して基準電位とし、第2電極1
7には正極性又は負極性の電圧を選択的に印加した。第
2電極17に負極性の電圧を印加した場合には、正極性
に帯電されている帯電泳動粒子5は、図2に示すように
第2電極17を覆うように集まる。この場合、図示の矢
印Aの方向から表示装置P2 を見ると、青色に着色され
た泳動用分散液4のみが視認されて帯電泳動粒子5は視
認されず、青色表示が行われることとなる。また、第2
電極17に正極性の電圧を印加した場合には、正極性に
帯電されている帯電泳動粒子5は、第2電極17から離
れて第1電極16の側に集まる。この場合、図示の矢印
Aの方向から表示装置P2 を見ると、白色に着色された
帯電泳動粒子5のみが視認されて泳動用分散液4は視認
されず、白色表示が行われることとなる。
In the display device P 2 thus produced, the first electrode 16 is grounded to the reference potential, and the second electrode 1
A positive or negative voltage was selectively applied to No. 7. When a negative voltage is applied to the second electrode 17, the positively charged charged electrophoretic particles 5 gather to cover the second electrode 17 as shown in FIG. In this case, when the display device P 2 is viewed from the direction of the arrow A in the figure, only the electrophoretic dispersion liquid 4 colored in blue is visually recognized, the charged electrophoretic particles 5 are not visually recognized, and blue display is performed. . Also, the second
When a positive voltage is applied to the electrode 17, the positively charged charged electrophoretic particles 5 are separated from the second electrode 17 and gather on the side of the first electrode 16. In this case, when viewing the display device P 2 from the direction of the arrow A shown in the figure, only the charged electrophoretic particles 5 colored in white are visually recognized, and the electrophoretic dispersion liquid 4 is not visually recognized, and white display is performed. .

【0058】本発明者が実際に70Vの電圧を印加して
表示装置P2 を駆動したところ、コントラストが4であ
って応答速度が200msecの良好な表示が得られ
た。また、各区画間の濃度ばらつきは観察されず、表示
品位は良好であった。
When the present inventor actually applied a voltage of 70 V to drive the display device P 2 , a good display with a contrast of 4 and a response speed of 200 msec was obtained. Further, no variation in density was observed between the sections, and the display quality was good.

【0059】[0059]

【発明の効果】以上説明したように、本発明によると、
帯電泳動粒子は、各区画毎にほぼ等しい量ずつ配置され
るため、該粒子により表示される色の濃度も区画毎にほ
ぼ等しくなり、作成された表示装置の表示品位が良好と
なる。
As described above, according to the present invention,
Since the charged electrophoretic particles are arranged in substantially equal amounts in each section, the density of the color displayed by the particles is also substantially equal in each section, and the display quality of the produced display device is good.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明にて製造される表示装置の構成の一例を
示す断面図。
FIG. 1 is a cross-sectional view showing an example of the configuration of a display device manufactured by the present invention.

【図2】本発明にて製造される表示装置の構成の他の例
を示す断面図。
FIG. 2 is a cross-sectional view showing another example of the configuration of the display device manufactured by the present invention.

【図3】本発明に係る表示装置の製造方法の一例を示す
模式図。
FIG. 3 is a schematic view showing an example of a method of manufacturing a display device according to the present invention.

【図4】本発明に係る表示装置の製造方法の他の例を示
す模式図。
FIG. 4 is a schematic view showing another example of the method for manufacturing the display device according to the present invention.

【図5】帯電泳動粒子を散布する工程及び装置を説明す
るための図。
FIG. 5 is a diagram for explaining a process and an apparatus for spraying charged electrophoretic particles.

【図6】帯電泳動粒子を散布する工程及び装置を説明す
るための図。
FIG. 6 is a diagram for explaining a process and a device for spraying charged electrophoretic particles.

【図7】電気泳動表示装置の構造及び動作原理を示す
図。
FIG. 7 is a diagram showing a structure and an operating principle of an electrophoretic display device.

【符号の説明】[Explanation of symbols]

1a,1b 基板 2 区画 3 隔壁(隔壁部材) 4 泳動用分散液 5 帯電泳動粒子 6 第1電極 7 第2電極 16 第1電極 17 第2電極 21 吸着電極 P1 表示装置 P2 表示装置1a, 1b Substrate 2 Partition 3 Partition (partition member) 4 Dispersion liquid 5 Electrophoretic particles 6 First electrode 7 Second electrode 16 First electrode 17 Second electrode 21 Adsorption electrode P 1 Display device P 2 Display device

───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 昭53−108508(JP,A) 特開 昭49−24695(JP,A) 特開 平10−260589(JP,A) 特開 平2−223935(JP,A) 特開 平1−248183(JP,A) 特公 昭47−35842(JP,B1) 特表 平8−502599(JP,A) (58)調査した分野(Int.Cl.7,DB名) G09F 9/37 311 ─────────────────────────────────────────────────── ─── Continuation of the front page (56) Reference JP-A-53-108508 (JP, A) JP-A-49-24695 (JP, A) JP-A-10-260589 (JP, A) JP-A-2- 223935 (JP, A) JP-A-1-248183 (JP, A) JP-B 47-35842 (JP, B1) JP-A 8-502599 (JP, A) (58) Fields investigated (Int.Cl. 7 , DB name) G09F 9/37 311

Claims (10)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 所定間隙を開けた状態に配置された一対
の基板と、該所定間隙を該基板の面に沿った複数の区画
に分割するように配置された隔壁部材と、これら複数の
区画にそれぞれ配置された泳動用分散液及び多数の帯電
泳動粒子と、各区画にてこれらの泳動用分散液及び帯電
泳動粒子に対向するように配置された第1電極及び第2
電極と、からなる表示装置を製造する表示装置の製造方
法において、 所定間隙を開けた状態に配置される前の前記一対の基板
のうちの一の基板に対して、各区画毎の量がほぼ等しく
なるように前記多数の帯電泳動粒子を配置し、かつ、 前記泳動用分散液の配置は、前記多数の帯電泳動粒子の
配置よりも後に行う、 ことを特徴とする表示装置の製造方法。
1. A pair of substrates arranged with a predetermined gap therebetween, a partition member arranged so as to divide the predetermined gap into a plurality of partitions along the surface of the substrate, and a plurality of these partitions. Dispersion liquid and a large number of charged electrophoretic particles, which are respectively disposed on the first and second electrodes, and a second electrode and a second electrode that are arranged so as to face the electrophoretic dispersion liquid and the electrophoretic migration particles in each section.
In a display device manufacturing method for manufacturing a display device including electrodes, an amount of each section is substantially equal to one of the pair of substrates before being placed with a predetermined gap. The plurality of charged electrophoretic particles are arranged so as to be equal to each other , and the electrophoretic dispersion liquid is arranged such that
A method for manufacturing a display device, which is performed after the arrangement .
【請求項2】 前記帯電泳動粒子の配置は、前記帯電泳
動粒子を一の極性に帯電させた状態で前記一の基板に対
向する位置に配置する共に該一の基板を他の極性に帯
電させることにより静電吸引力を発生させ電界による飛
翔吸着を利用して行う、 ことを特徴とする請求項1に記載の表示装置の製造方
法。
2. The arrangement of the charged electrophoretic particles is such that the charged electrophoretic particles are charged to one polarity and face the one substrate , and the one substrate is charged to another polarity. fly by an electric field to generate an electrostatic attraction force by
The method for manufacturing a display device according to claim 1, wherein the method is carried out by utilizing the adsorption of light .
【請求項3】 前記一の基板の帯電は、該一の基板の近
傍に配置した吸着電極に電圧を印加して行う、 ことを特徴とする請求項2に記載の表示装置の製造方
法。
3. The charging of the one substrate is performed in the vicinity of the one substrate.
The method of manufacturing a display device according to claim 2, wherein a voltage is applied to a suction electrode arranged nearby.
Law.
【請求項4】 前記帯電泳動粒子を各区画に配置する量
は、前記吸着電極に印加する電圧を調整することによっ
て変化させる、 ことを特徴とする請求項に記載の表示装置の製造方
法。
4. The method for manufacturing a display device according to claim 3 , wherein the amount of the charged electrophoretic particles arranged in each section is changed by adjusting the voltage applied to the adsorption electrode.
【請求項5】 前記吸着電極に印加する電圧の調整を前
記一の基板の移動に応じて行うことにより、前記帯電泳
動粒子を各区画に配置する量を前記基板の位置に応じて
異ならせる、 ことを特徴とする請求項4に記載の表示装置の製造方
法。
5. The voltage applied to the adsorption electrode is adjusted according to the movement of the one substrate , so that the amount of the charged electrophoretic particles to be arranged in each section is changed according to the position of the substrate. The method for manufacturing a display device according to claim 4, wherein.
【請求項6】 前記吸着電極は、前記一の基板とは分離
可能であって、前記帯電泳動粒子の配置に際して前記一
の基板の裏側に配置する、 ことを特徴とする請求項3乃至5のいずれか1項に記載
の表示装置の製造方法。
6. The adsorption electrode is separable from the one substrate and is arranged on the back side of the one substrate when the charged electrophoretic particles are arranged . A method for manufacturing the display device according to any one of items .
【請求項7】 前記第1電極は、前記帯電泳動粒子を
区画に配置する前までに前記一の基板に形成し、前記一
の基板の帯電は、前記第1電極に電圧を印加して行う、 ことを特徴とする請求項2に記載の表示装置の製造方
法。
7. The first electrode comprises each of the charged electrophoretic particles.
Wherein formed on one substrate and before placing the partition, the one
The method for manufacturing a display device according to claim 2 , wherein the substrate is charged by applying a voltage to the first electrode .
【請求項8】 前記帯電泳動粒子の配置は、前記一の基
板をその面方向に移動させながら行う、 ことを特徴とする請求項1乃至7のいずれか1項に記載
の表示装置の製造方法。
Arrangement according to claim 8, wherein the electrophoretic particles, a method of manufacturing a display device according to any one of claims 1 to 7, characterized in said performed while moving one of the substrate in a planar direction thereof, it .
【請求項9】 前記泳動用分散液の前記複数の区画への
配置は、前記一対の基板を所定間隙を開けた状態に配置
する前に行う、 ことを特徴とする請求項1乃至のいずれか1項に記載
の表示装置の製造方法。
Arranged to 9. wherein the plurality of compartments of the dispersion liquid is more of claims 1 to 8 wherein the pair of the substrates performed before placing with a predetermined spacing, characterized in that 2. A method of manufacturing a display device according to item 1.
【請求項10】 前記泳動用分散液の前記複数の区画へ
の配置は、前記第1電極及び前記第2電極の少なくとも
一方の電極に電圧を印加して前記帯電泳動粒子をそれぞ
れの区画に静電吸着させた状態で行う、 ことを特徴とする請求項に記載の表示装置の製造方
法。
10. The arrangement of the electrophoretic dispersion liquid in the plurality of compartments is performed by applying a voltage to at least one electrode of the first electrode and the second electrode to statically charge the electrophoretic particles in each compartment. The method for manufacturing a display device according to claim 9 , wherein the method is performed in a state of being electro-adsorbed.
JP13491899A 1999-05-14 1999-05-14 Display device manufacturing method Expired - Fee Related JP3492237B2 (en)

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JP13491899A JP3492237B2 (en) 1999-05-14 1999-05-14 Display device manufacturing method
US09/570,692 US6524153B1 (en) 1999-05-14 2000-05-12 Process for producing display device
US10/162,599 US6729924B2 (en) 1999-05-14 2002-06-06 Process for producing display device

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US8139050B2 (en) 1995-07-20 2012-03-20 E Ink Corporation Addressing schemes for electronic displays
JP4868560B2 (en) * 2000-11-29 2012-02-01 スタンレー電気株式会社 Display device and manufacturing method thereof
JP2005070714A (en) * 2003-08-25 2005-03-17 Majima Kenkyusho:Kk Rewritable thin image display sheet
JP4614711B2 (en) * 2004-08-11 2011-01-19 株式会社ブリヂストン Manufacturing method of image display panel
JP4820576B2 (en) * 2005-05-11 2011-11-24 株式会社ブリヂストン Manufacturing method of information display panel
JP4815888B2 (en) 2005-06-17 2011-11-16 富士ゼロックス株式会社 Display medium, display element, and display method
JP2007086729A (en) 2005-06-20 2007-04-05 Fuji Xerox Co Ltd Display medium, and display device, and display method using the same
JP5194355B2 (en) 2005-11-25 2013-05-08 富士ゼロックス株式会社 Display medium and display method
JP5050343B2 (en) 2005-12-06 2012-10-17 富士ゼロックス株式会社 Display medium, display element, and display method

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