JP3008218B2 - Non-asbestos-based friction material molded product - Google Patents

Non-asbestos-based friction material molded product

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Publication number
JP3008218B2
JP3008218B2 JP3098069A JP9806991A JP3008218B2 JP 3008218 B2 JP3008218 B2 JP 3008218B2 JP 3098069 A JP3098069 A JP 3098069A JP 9806991 A JP9806991 A JP 9806991A JP 3008218 B2 JP3008218 B2 JP 3008218B2
Authority
JP
Japan
Prior art keywords
friction material
asbestos
insulator
material molded
molded product
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP3098069A
Other languages
Japanese (ja)
Other versions
JPH04306289A (en
Inventor
満 小林
正博 難波
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nisshinbo Holdings Inc
Original Assignee
Nisshinbo Holdings Inc
Nisshinbo Industries Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nisshinbo Holdings Inc, Nisshinbo Industries Inc filed Critical Nisshinbo Holdings Inc
Priority to JP3098069A priority Critical patent/JP3008218B2/en
Publication of JPH04306289A publication Critical patent/JPH04306289A/en
Application granted granted Critical
Publication of JP3008218B2 publication Critical patent/JP3008218B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】本発明は、自動車等の車両用ディ
スクパッド、ブレーキランニング、クラッチフェーシン
グ等に使用される非石綿系摩擦材成形品に関するもので
あり、更に詳しくは、特に高負荷の下で使用される中・
大型車用のディスクパッド等に使用して好適な非石綿系
摩擦材成形品に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a non-asbestos-based friction material molded product used for disc pads for vehicles such as automobiles, brake running, clutch facing, and the like. Used in
The present invention relates to a non-asbestos-based friction material molded product suitable for use as a disk pad for a large vehicle and the like.

【0002】[0002]

【従来の技術】自動車等の車両用のブレーキには、周知
のように、ブレーキドラムの内面にブレーキシューを押
しつけて制動するドラムブレーキと、円盤状のローター
の側面にブレーキパッドを押しつけて制動するディスク
ブレーキの2種類がある。
2. Description of the Related Art As is well known, a brake for a vehicle such as an automobile brakes by pressing a brake shoe against an inner surface of a brake drum, and a brake pad by pressing a brake pad against a side surface of a disk-shaped rotor. There are two types of disc brakes.

【0003】而して、上記ディスクブレーキは上記ドラ
ムブレーキに比べて、その構造上、熱が逃げ易く、又、
均一な制動が得られ易いという利点はあるが、耐摩耗性
に関しては、ディスクブレーキに比べて大きなブレーキ
シューを使用するドラムブレーキの方が優れていて、こ
のような理由により、従来から一般に、中・大型車には
ドラムブレーキが、小型車にはディスクブレーキが多く
使用されている。
[0003] In comparison with the above-mentioned drum brake, the above-mentioned disc brake allows heat to escape easily due to its structure.
Although there is an advantage that uniform braking can be easily obtained, a drum brake using a large brake shoe is superior to a disc brake in terms of abrasion resistance.・ Drum brakes are often used for large vehicles and disc brakes are often used for small vehicles.

【0004】そして、ドラムブレーキ用であるとディス
クブレーキ用であるとを問わず、高温時の耐摩耗性に重
点をおいた摩擦材は、金属成分や黒鉛等を多量に含ませ
ることにより摩擦材全体の熱伝導率を上げ、摩擦表面の
温度が高くならないように設計されているものが多い。
[0004] Regardless of whether it is for a drum brake or a disc brake, a friction material focused on abrasion resistance at a high temperature is made by incorporating a large amount of a metal component or graphite. Many are designed to increase the overall thermal conductivity and not increase the temperature of the friction surface.

【0005】しかし、摩擦材の熱伝導率が高くなると、
摩擦により発生する熱がブレーキ装置を伝わってブレー
キオイルを昇温させ、この結果ベーパーロック現象を発
生させるおそれがあるので、通常は摩擦材と裏金の間に
インシュレータを設けるようにしており、従来、このよ
うなインシュレータ材としては、安価で適度な強度を持
つ石綿を基材とするものが多く使用されてきた。
However, as the thermal conductivity of the friction material increases,
Heat generated by friction is transmitted through the brake device to raise the temperature of the brake oil, which may cause a vapor lock phenomenon.Therefore, usually, an insulator is provided between the friction material and the backing metal. As such an insulator material, a material having asbestos as a base material, which is inexpensive and has appropriate strength, has been used in many cases.

【発明が解決しようとする課題】[Problems to be solved by the invention]

【0006】しかしながら、石綿は環境的な問題が指摘
された結果、その使用が規制されつつあり、従って、摩
擦材料ばかりでなく、インシュレータ材についても非石
綿系材への転換が要求されている。
However, the use of asbestos has been regulated as a result of environmental problems. Therefore, it has been required to convert not only friction materials but also insulator materials to non-asbestos materials.

【0007】又、中・大型車にディスクブレーキを用い
た場合、ドラムブレーキを用いた場合に比較して、摩擦
材の摩擦面に平行な断面積が小さくなるので、このよう
な条件下で使用される摩擦材には、インシュレータ材料
としてより高強度のものが要求されている。
Further, when a disk brake is used for a medium or large vehicle, the cross-sectional area of the friction material parallel to the friction surface becomes smaller than when a drum brake is used. The friction material to be used is required to have a higher strength as an insulator material.

【0008】本発明は、上述した従来技術を背景とし
て、断熱性を有し、且つ、例えば中・大型車の制動中の
ブレーキ力に耐えられるような強度を有するインシュレ
ータを備えた非石綿系摩擦材を提供することを主な目的
としてなされた。
[0008] The present invention is based on the background of the prior art described above, and is a non-asbestos-based friction provided with an insulator having heat insulating properties and strength enough to withstand braking force during braking of a medium or large vehicle. The main purpose was to provide wood.

【0009】[0009]

【課題を解決するための手段】上記目的を達成するため
に本発明が採用した非石綿系摩擦材の構成は、石綿以外
の補強繊維と、フェノール樹脂等の熱硬化性樹脂による
結合剤及び硫酸バリウム等の充填材とからなる非石綿系
摩擦材において、摩擦材と裏金の間に、石綿以外の補強
繊維とフェノール樹脂等の熱硬化性樹脂による結合剤及
び硫酸バリウム等の充填材とからなると共に、少なくと
もその成分の一部として金属繊維を含み、且つ、その熱
伝導率が約1.0〜約2.5kcal/mh℃であるイ
ンシュレータを介在させたことを特徴とするものであ
る。
In order to achieve the above object, the present invention employs a non-asbestos-based friction material comprising a reinforcing fiber other than asbestos, a binder made of a thermosetting resin such as a phenol resin, and a sulfuric acid. In a non-asbestos-based friction material comprising a filler such as barium, a reinforcing fiber other than asbestos and a binder made of a thermosetting resin such as a phenol resin and a filler such as barium sulfate are provided between the friction material and the backing metal. In addition, an insulator containing metal fibers as at least a part of the component and having a thermal conductivity of about 1.0 to about 2.5 kcal / mh ° C is interposed.

【0010】上記本発明で使用する非石綿系インシュレ
ータにおいて、成分中の金属繊維は、その平均繊維径が
約30〜約150μm、平均繊維長が約0.5〜約6.
0mmのものを使用することができ、又、金属繊維の含
有量としては、インシュレータ全量に対して約0.5〜
約20体積%という範囲をそれぞれ例示することができ
る。
In the non-asbestos-based insulator used in the present invention, the metal fibers in the components have an average fiber diameter of about 30 to about 150 μm and an average fiber length of about 0.5 to about 6.
0 mm can be used, and the content of the metal fiber is about 0.5 to about the total amount of the insulator.
A range of about 20% by volume can be exemplified.

【0011】又、上記インシュレータとしては、その厚
みが、摩擦材成形品全体の厚みの約1/5〜約1/3で
あるものを例示することができる。
The insulator may have a thickness of about 1/5 to about 1/3 of the thickness of the entire friction material molded product.

【0012】以下に本発明を詳細に説明する。Hereinafter, the present invention will be described in detail.

【0013】本発明の非石綿系摩擦材成形品において使
用する石綿以外の補強繊維としては、例えば、アラミド
繊維、アクリル繊維、フェノ−ル繊維、PVA繊維、セ
ルロース繊維等の有機繊維、又は、ガラス繊維、セラミ
ック繊維、炭素繊維等の無機繊維、更に、スチ−ル繊
維、銅繊維、青銅繊維等の金属繊維のうちの1種又は2
種以上の繊維を含んだ混合物が用いられ、これらは従来
の非石綿系摩擦材成形品に用いられていたものと同じで
ある。
The reinforcing fibers other than asbestos used in the non-asbestos-based friction material molded article of the present invention include, for example, organic fibers such as aramid fiber, acrylic fiber, phenol fiber, PVA fiber, cellulose fiber, and glass. One or two of inorganic fibers such as fibers, ceramic fibers, and carbon fibers; and metal fibers such as steel fibers, copper fibers, and bronze fibers.
Mixtures containing more than one type of fiber are used, which are the same as those used in conventional non-asbestos-based friction material moldings.

【0014】又、結合剤としては、例えば、フェノ−ル
樹脂等の熱硬化性樹脂が、又、充填材としては、例え
ば、硫酸バリウム、カシュ−ダスト、炭酸カルシウム等
が用いられ、これらの成分も、通常の非石綿系摩擦材成
形品において汎用されているものである。
As the binder, for example, a thermosetting resin such as phenol resin is used. As the filler, for example, barium sulfate, cash dust, calcium carbonate, etc. are used. These are also commonly used in ordinary non-asbestos-based friction material molded products.

【0015】而して、本発明の非石綿系摩擦材成形品
は、摩擦材と裏金の間に、少なくともその成分の一部と
して、金属繊維を含むインシュレータを介在させたこと
を特徴とする。
The non-asbestos-based friction material molded article of the present invention is characterized in that an insulator containing metal fibers is interposed at least as a part of the component between the friction material and the backing metal.

【0016】上記インシュレータは、組成的には石綿以
外の補強繊維と、フェノール樹脂等の熱硬化性樹脂によ
る結合剤、及び、硫酸バリウム等の充填材とからなる
が、これらについては、上記本発明の非石綿系摩擦材成
形品に使用されるものを、特に制限なく使用することが
できる。
The insulator is composed of a reinforcing fiber other than asbestos, a binder made of a thermosetting resin such as a phenol resin, and a filler such as barium sulfate. The non-asbestos-based friction material molded product can be used without any particular limitation.

【0017】上記インシュレータにおいて使用する金属
繊維は、その平均繊維径が約30〜約150μmのもの
であることが好ましく、約30μm以下では強度が低下
し、約150μm以上では繊維どうしの絡みが悪くな
り、やはり強度が低下する。
The metal fibers used in the insulator preferably have an average fiber diameter of about 30 to about 150 μm. When the average fiber diameter is about 30 μm or less, the strength is reduced. When the average fiber diameter is about 150 μm or more, the entanglement of the fibers becomes poor. , Again, the strength is reduced.

【0018】又、上記金属繊維は、その平均繊維長が約
0.5〜約6.0mmであることが好ましく、約0.5
mm以下及び約6.0mm以上では絡みが悪くなり強度
が低下する。
Preferably, the metal fiber has an average fiber length of about 0.5 to about 6.0 mm, and about 0.5 to about 6.0 mm.
mm or less and about 6.0 mm or more, the entanglement worsens and the strength is reduced.

【0019】更に、金属繊維の含有量は、インシュレー
タ全量の約0.5〜約20体積%が好ましく、約0.5
%以下では強度が不足し、約20%以上では熱伝導率が
高くなるためインシュレータとしての本来の役割を果た
さなくなるので好ましくない。
Further, the content of the metal fiber is preferably about 0.5 to about 20% by volume of the total amount of the insulator, and is preferably about 0.5 to about 20% by volume.
% Or less is not preferable because the strength is insufficient, and if it is about 20% or more, the thermal conductivity becomes high, so that it does not play its original role as an insulator.

【0020】上記インシュレータは、例えば、摩擦材成
形品全体の厚みの1/5〜1/3となるように使用する
ことが好ましい。
It is preferable that the insulator is used, for example, so that the thickness of the insulator is 1/5 to 1/3 of the thickness of the entire friction material molded product.

【0021】又、上記インシュレータは、その熱伝導率
が約1.0〜約2.5kcal/mh℃のものであり、
摩擦材とインシュレータとの温度差を少なくし、熱応力
の発生を抑制することができるので、特に高負荷の下で
使用する摩擦材成形品として好ましいものである。
Further, the insulator has a thermal conductivity of about 1.0 to about 2.5 kcal / mh ° C.,
Since the temperature difference between the friction material and the insulator can be reduced and the generation of thermal stress can be suppressed, it is particularly preferable as a friction material molded product used under a high load.

【0022】[0022]

【発明の作用】本発明の摩擦材成形品は、摩擦材と裏金
の間に、石綿以外の補強繊維とフェノール樹脂等の熱硬
化性樹脂による結合剤及び硫酸バリウム等の充填材とか
らなると共に、少なくともその成分の一部として金属繊
維を含み、且つ、その熱伝導率が約1.0〜約2.5k
cal/mh℃であるインシュレータを介在させること
により、断熱性を損なうことなくブレーキ力に対する強
度を常温から高温にいたるまで向上させたものである。
The molded article of the friction material of the present invention comprises a reinforcing fiber other than asbestos, a binder made of a thermosetting resin such as a phenol resin, and a filler such as barium sulfate between the friction material and the backing metal. Including metal fibers at least as part of the component, and having a thermal conductivity of about 1.0 to about 2.5 k.
By interposing an insulator of cal / mh ° C., the strength against braking force is improved from normal temperature to high temperature without impairing the heat insulation.

【0023】次に本発明を実施例により更に詳細に説明
する。
Now, the present invention will be described in further detail with reference to Examples.

【0024】[0024]

【実施例1〜5】金属繊維としてスチール繊維、銅繊
維、黄銅繊維を表1に示す割合で、他の成分と均一に混
合し、インシュレータ材料とした。ただし、金属繊維は
すべて平均繊維径50μmで平均繊維長3mmのものを
使用した。次に、以下の組成を有する摩擦材原料を、圧
力400kg/cm2、室温で1分間予備成型を行な
い、続いて圧力600kg/cm2、温度150℃で1
5分間圧縮成型を行なった後、200℃で5時間熱処理
して実施例1〜5のディスクパッド用の摩擦材を得た。 スチール繊維 30体積% フェノール樹脂 21体積% 硫酸バリウム 15体積% 銅粉 4体積% 黒鉛 10体積% 石油コークス 20体積%
Examples 1 to 5 Steel fibers, copper fibers and brass fibers were uniformly mixed with other components in the proportions shown in Table 1 as metal fibers to obtain insulator materials. However, all the metal fibers used had an average fiber diameter of 50 μm and an average fiber length of 3 mm. Next, a friction material material having the following composition is preformed at a pressure of 400 kg / cm 2 at room temperature for 1 minute, and then at a pressure of 600 kg / cm 2 and a temperature of 150 ° C. for 1 minute.
After performing compression molding for 5 minutes, heat treatment was performed at 200 ° C. for 5 hours to obtain friction materials for disk pads of Examples 1 to 5. Steel fiber 30% by volume Phenol resin 21% by volume Barium sulfate 15% by volume Copper powder 4% by volume Graphite 10% by volume Petroleum coke 20% by volume

【0025】[0025]

【比較例1〜3】金属繊維を使用しないこと以外は上記
実施例と同様にして、比較例1〜3の摩擦材を得た。
Comparative Examples 1 to 3 The friction materials of Comparative Examples 1 to 3 were obtained in the same manner as in the above Example except that no metal fiber was used.

【0026】[0026]

【摩擦試験】上記実施例1〜4の摩擦材及び上記比較例
1〜4の摩擦材に関し、フルサイズダイナモ試験機によ
る温度別摩耗試験(JASO C427−83、イナー
シャ40kgms2)を行ない、摩擦材とインシュレー
タ境界面の亀裂発生状態を調べると共に、摩擦材とイン
シュレータ境界面の剪断強度試験(JASO C444
ー78)を行った。その結果を以下の表1に示す。尚、
イナーシャ40kgms2は、4トン〜5トン車定積荷
重状態に相当する。
[Friction test] With respect to the friction material of Examples 1 to 4 and the friction materials of Comparative Examples 1 to 4, a wear test at different temperatures (JASO C427-83, inertia 40 kgms 2 ) was performed using a full-size dynamo testing machine. In addition to examining the state of crack initiation at the interface between the friction material and the insulator, a shear strength test between the friction material and the insulator interface (JASO C444)
-78). The results are shown in Table 1 below. still,
Inertia of 40 kgms 2 corresponds to a 4 to 5 ton vehicle constant load state.

【表1】 [Table 1]

【0027】[0027]

【発明の効果】上記表1に明らかなように、摩擦材と裏
金の間に、少なくとも成分の一部として金属繊維を含む
インシュレータを介在させた本発明摩擦材は、断熱性を
損なうことなく、ブレーキ力に対する強度が向上してい
ることがわかる。
As is clear from Table 1, the friction material of the present invention in which an insulator containing a metal fiber as at least a part of the component is interposed between the friction material and the backing metal does not impair the heat insulating property. It can be seen that the strength against the braking force has been improved.

フロントページの続き (51)Int.Cl.7 識別記号 FI F16D 69/02 F16D 69/02 G (58)調査した分野(Int.Cl.7,DB名) C09K 3/14 520 C09K 3/14 530 C08J 5/14 F16D 69/00 - 69/02 Continuation of the front page (51) Int.Cl. 7 identification code FI F16D 69/02 F16D 69/02 G (58) Investigated field (Int. Cl. 7 , DB name) C09K 3/14 520 C09K 3/14 530 C08J 5/14 F16D 69/00-69/02

Claims (5)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 石綿以外の補強繊維と、フェノール樹脂
等の熱硬化性樹脂による結合剤及び硫酸バリウム等の充
填材とからなる非石綿系摩擦材において、摩擦材と裏金
の間に、石綿以外の補強繊維とフェノール樹脂等の熱硬
化性樹脂による結合剤及び硫酸バリウム等の充填材とか
らなると共に、少なくともその成分の一部として金属繊
維を含み、且つ、その熱伝導率が約1.0〜約2.5k
cal/mh℃であるインシュレータを介在させたこと
を特徴とする非石綿系摩擦材成形品。
1. A non-asbestos-based friction material comprising a reinforcing fiber other than asbestos, a binder made of a thermosetting resin such as a phenol resin, and a filler such as barium sulfate. A reinforcing fiber, a binder made of a thermosetting resin such as a phenol resin, and a filler such as barium sulfate, and at least a metal fiber as a part of the components, and having a thermal conductivity of about 1.0. ~ About 2.5k
A non-asbestos-based friction material molded product characterized by interposing an insulator at cal / mh ° C.
【請求項2】 インシュレータの成分中の金属繊維は、
その平均繊維径が約30〜約150μmのものである請
求項1に記載の非石綿系摩擦材成形品。
2. The metal fiber in the component of the insulator,
The non-asbestos-based friction material molded article according to claim 1, wherein the average fiber diameter is about 30 to about 150 µm.
【請求項3】 インシュレータの成分中の金属繊維は、
その平均繊維長が約0.5〜約6.0mmのものである
請求項1に記載の非石綿系摩擦材成形品。
3. The metal fiber in the component of the insulator,
The non-asbestos-based friction material molded article according to claim 1, wherein the average fiber length is about 0.5 to about 6.0 mm.
【請求項4】 インシュレータの成分中の金属繊維の含
有量が、インシュレータ材全量に対して約0.5〜約2
0体積%である請求項1に記載の非石綿系摩擦材成形
品。
4. The content of the metal fiber in the component of the insulator is about 0.5 to about 2 with respect to the total amount of the insulator material.
The non-asbestos-based friction material molded product according to claim 1, which is 0% by volume.
【請求項5】 インシュレータの厚みが、摩擦材成形品
全体の厚みの約1/5〜約1/3である請求項1に記載
の非石綿系摩擦材成形品。
5. The non-asbestos-based friction material molded product according to claim 1, wherein the thickness of the insulator is about 1/5 to about 1/3 of the total thickness of the friction material molded product.
JP3098069A 1991-04-03 1991-04-03 Non-asbestos-based friction material molded product Expired - Fee Related JP3008218B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP3098069A JP3008218B2 (en) 1991-04-03 1991-04-03 Non-asbestos-based friction material molded product

Applications Claiming Priority (1)

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JP3098069A JP3008218B2 (en) 1991-04-03 1991-04-03 Non-asbestos-based friction material molded product

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JPH04306289A JPH04306289A (en) 1992-10-29
JP3008218B2 true JP3008218B2 (en) 2000-02-14

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AT412766B (en) * 2003-01-22 2005-07-25 Miba Frictec Gmbh FRICTION BODY HAVING A POROUS INTERIOR LAYER BETWEEN A STEEL CARRIER AND A CARBURETING BASE OF CARBON FIBER
JP5331428B2 (en) * 2008-09-29 2013-10-30 日立オートモティブシステムズ株式会社 Brake friction material
CN103821852B (en) * 2013-11-30 2017-06-13 摩擦一号汽车科技(仙桃)有限公司 It is a kind of to use the environmentally friendly brake block without copper crystallite friction material
JP6425333B2 (en) * 2014-08-22 2018-11-21 日立オートモティブシステムズ株式会社 Brake friction material

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Publication number Priority date Publication date Assignee Title
KR101680652B1 (en) * 2016-04-07 2016-11-29 유한회사 지구환경공사 Collecting apparatus for hamful material

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