JP2016088889A - Hair dye - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a non-oxidative hair dye which has an excellent hair dyeing effect and a white hair concealing effect, and gives a good color tone in which particularly the bluish color tone in the hair after being dyed is suppressed.SOLUTION: The invention provides a hair dye comprising at least a first agent and a second agent. The first agent contains urea and at least one kind of benzophenone compounds having three or more hydroxyl groups, and the second agent contains at least one kind of iron salt.SELECTED DRAWING: None

Description

  The present invention relates to a non-oxidative hair dye that has an excellent hair dyeing effect and a gray hair combing effect and gives a good color tone to the hair after dyeing.

  The permanent hair dye is a hair dye that gives a permanent dyeing result to the hair. As a permanent hair dye, conventionally, a first agent containing an oxidative dye such as paraphenylenediamine and an alkali agent and a second agent containing an oxidant such as hydrogen peroxide are used in combination. Mold hair dyes are generally widely used. However, the oxidized hair dye may damage the hair due to the action of the alkaline agent and the hydrogen peroxide solution. Some oxidative dyes can also cause strong allergic reactions.

  On the other hand, non-oxidative hair dyes are known as hair dyes that cause little damage to hair and are less likely to cause allergic reactions. As non-oxidative hair dyes, for example, hair dyes that dye hair using a reaction between polyhydric phenols and metal salts are known (see Patent Documents 1 to 7).

  Further, a non-oxidative hair dye having a photobleaching preventing effect, comprising a combination of a first agent containing a substance that develops color by reacting with iron, an ultraviolet absorber, and a second agent containing an iron salt. Has been proposed (Patent Document 8).

  However, conventional non-oxidative hair dyes do not have sufficient hair dyeing effect and white hair combing effect.

Japanese Patent Publication No. 48-31902 JP-A-53-52633 JP-A-55-154912 JP-A-62-33113 JP-A 64-90117 Japanese Patent Laid-Open No. 4-164017 JP-A-5-170629 JP 2011-126845 A

Conventional hair dyes that use a plant extract or an organic compound that develops color by reacting with an iron salt require a long hair dyeing time. Moreover, the hair dyeing property and color tone of the hair after hair dyeing were not satisfactory. Furthermore, if tannic acid, gallic acid and / or derivatives thereof and iron are only added to the hair dye, the color tone of the bluish color of the hair after dyeing becomes stronger if the color is darkened in order to sufficiently dye white hair. No hair dyeing result giving good color tone to the hair was obtained.
The present invention solves the above-mentioned problems of the prior art, and has a non-oxidative hair dye that has an excellent hair dyeing effect and a gray hair combing effect, and gives a good color tone to the hair after hair dyeing. The issue is to provide.

  In order to solve the above-mentioned problems, the present inventors have made detailed studies on non-oxidative hair dyes and have completed the present invention.

That is, the present invention includes the following preferred embodiments.
[1] A hair dye comprising at least a first agent and a second agent, wherein the first agent contains urea and at least one benzophenone compound having three or more hydroxyl groups, The second agent is a hair dye containing at least one iron salt.
[2] The dye according to [1], wherein the first agent further contains at least one organic compound that develops color by reacting with iron and / or at least one plant extract containing the organic compound. Hair agent.

  The hair dye of the present invention has an excellent hair dyeing effect and a gray hair combing effect, and gives a good color tone to the hair after dyeing.

  The hair dye of the present invention comprises at least a first agent and a second agent. The first agent in the hair dye of the present invention contains urea in order to enhance the hair dyeing effect and the gray hair combing effect.

  The content of urea in the first agent is preferably 1% by mass or more, more preferably 3% by mass or more based on the total amount of the first agent, from the viewpoint of the hair dyeing effect and the gray hair combing effect. Further, from the viewpoint of the stability of the preparation, it is preferably 20% by mass or less, more preferably 10% by mass or less.

  The 1st agent in the hair dye of this invention contains the at least 1 sort (s) of benzophenone compound which has a 3 or more hydroxyl group, in order to improve the hair dyeing effect and the white hair combing effect.

Examples of the benzophenone compound having three or more hydroxyl groups include 2,3,4-trihydroxybenzophenone, 2,2 ′, 4,4′-tetrahydroxybenzophenone, and 2,3,4,4′-tetrahydroxy. Examples include benzophenone, 2,3,3 ′, 4,4 ′, 5-hexahydroxybenzophenone, and the like. A benzophenone compound having four or more hydroxyl groups is preferable from the viewpoint of easily enhancing the hair dyeing effect and the hair combing effect, and 2,2 ′, 4,4′-tetrahydroxybenzophenone and 2,3,4,4′-tetra. More preferred are benzophenone compounds selected from the group consisting of hydroxybenzophenone and 2,3,3 ′, 4,4 ′, 5-hexahydroxybenzophenone.
The first agent in the hair dye of the present invention may contain one kind of compound as a benzophenone compound having three or more hydroxyl groups, or may contain two or more kinds of compounds in combination.

  The content of the benzophenone compound having three or more hydroxyl groups in the first agent is preferably 0.1% by mass or more based on the total amount of the first agent from the viewpoint of the hair dyeing effect and the gray hair combing effect. Preferably it is 0.3 mass% or more. Further, from the viewpoint of the stability of the preparation, it is preferably 5% by mass or less, more preferably 3% by mass or less.

The first agent in the hair dye of the present invention contains an oil agent from the viewpoint of stably blending a benzophenone compound having three or more hydroxyl groups into the first agent and enhancing the hair dyeing effect and the hair removal effect. Is preferred. Examples of the oil agent include ester oils, hydrocarbon oils, silicone oils, animal and vegetable oils, higher alcohols that are liquid at room temperature, and higher fatty acids that are liquid at room temperature. From the viewpoint of the stability of the first agent, the first agent may contain at least one oil agent selected from the group consisting of hydrocarbon oils, ester oils, higher alcohols that are liquid at room temperature, and silicone oils as oil agents. More preferably, it contains at least one oil agent selected from the group consisting of hydrocarbon oils and ester oils. The first agent in the hair dye of the present invention more preferably contains a hydrocarbon oil from the viewpoint of stably blending a benzophenone compound having three or more hydroxyl groups into the first agent. Examples of the hydrocarbon oil include liquid paraffin, dioctylcyclohexane, α-olefin oligomer, light isoparaffin, light liquid isoparaffin, squalane, polybutene, and liquid isoparaffin.
The content of the oil agent is preferably 1% by mass or more, more preferably 3% by mass or more based on the total amount of the first agent from the viewpoint of the stability of the preparation. Moreover, from a viewpoint of usability, Preferably it is 30 mass% or less, More preferably, it is 15 mass% or less.

  The first agent in the hair dye of the present invention may further contain at least one organic compound that develops color by reacting with iron and / or at least one plant extract containing the organic compound. Examples of organic compounds that develop color by reacting with iron or plant extracts containing the organic compounds include, for example, tannic acid, gallic acid and derivatives thereof, pentaploid, pyrogallol, logwood, hematein, catechol, salicylic acid or derivatives thereof, phthalates Acid, eugenol, isoeugenol, nicotinamide, dehydroacetic acid, pyridoxine, ellagic acid, kojic acid, maltol, ferulic acid, hinokitiol, turmeric extract, curcumin, ougon extract, onion extract, quercetin, rutin, hesperetin, hesperidin, fresh coffee Bean extract, caffeic acid, chlorogenic acid, tea extract, catechin, epicatechin, shikon extract, perilla extract, shisonin, grape leaf extract, butto extract, enocyanin, laccaic acid, lac, cochineal, carminic acid, Rudaberi, red cabbage, purple sweet potato, tamarind, sorghum, Apigeninijin, there may be mentioned a Ruteorinijin, but is not limited thereto. The first agent in the hair dye of the present invention preferably contains tannic acid, gallic acid and derivatives thereof, salicylic acid and derivatives thereof from the viewpoint of the hair dyeing effect.

  Examples of tannic acid include hydrolyzed tannin and condensed tannin. Examples of the hydrolyzable tannin include tannin obtained from pentaploid, gallic, smack, cod, chestnut, milobaran, oak, dividi, algarovia, and ganoderma. Examples of the condensed tannin include tannin obtained from Gambia, Gebracho, Mimosa, Mangrove, Hemlock, Spruce, Burma Katsch, Oak Bark, and Astringency.

  Examples of gallic acid derivatives include alkyl esters of gallic acid. Examples of alkyl esters of gallic acid include esters of gallic acid and linear or branched alkyl having 1 to 10 carbon atoms, preferably 2 to 5 carbon atoms. Examples of such alkyl esters include ethyl gallate, propyl gallate, and isoamyl gallate. Gallic acid or a derivative thereof may be chemically synthesized by a known method or may be isolated from a plant. What further added chemical synthesis to what was isolated from the plant may be used. Moreover, you may use the extract obtained from the plant containing a gallic acid or its derivative (s) as it is. For example, gallic acid derived from leguminous plant cod, gallic acid derived from pentaploid which occurs in urchinaceae, or extracts containing them can be used. In addition, derivatives obtained by chemically esterifying those gallic acids can also be used.

  Salicylic acid derivatives include salicylic acid esters and salts. Examples of the salicylic acid salt include alkali metal salts of salicylic acid. Specific examples include sodium salicylate. Examples of the ester of salicylic acid include linear or branched alkyl esters and phenyl esters having 1 to 10 carbon atoms, and specific examples include octyl salicylate, phenyl salicylate, and methyl salicylate.

  The first agent in the hair dye of the present invention may contain one kind of compound or extract as an organic compound that reacts with iron and develops color, or a plant extract containing the organic compound, or two or more kinds. These compounds or extracts may be contained in combination. You may contain combining the organic compound which reacts with iron, and develops color, and the plant extract containing this organic compound.

  In the first agent, the content of the organic compound that develops color by reacting with iron is not particularly limited as long as the effect of the present invention is obtained, but from the viewpoint of enhancing the hair dyeing effect and the gray hair combing effect, Preferably it is 0-10 mass% based on the total amount, More preferably, it is 0.5-6 mass%.

  The pH of the first agent in the hair dye of the present invention is preferably 6 to 10, more preferably 7 to 9, from the viewpoint of the hair dyeing effect and the stability of the agent.

  The 2nd agent in the hair dye of this invention contains an at least 1 sort (s) of iron salt in order to improve the hair dyeing effect and the white hair combing effect. The iron salt develops color by reaction with a benzophenone compound having three or more hydroxyl groups and an organic compound that develops color by reacting with iron contained in some cases, thereby fixing the pigment on the hair.

Examples of iron salts include ferrous sulfate, ferrous chloride, ferrous acetate, ferrous phosphate, ferrous oxalate, ferric sulfate, ferric chloride, and ferric acetate. It is done. From the viewpoint of the hair dyeing effect, it is preferable to use at least one iron salt selected from the group consisting of ferrous sulfate, ferrous chloride, ferrous acetate, ferric sulfate and ferric chloride, More preferably, at least one iron salt selected from the group consisting of ferrous sulfate, ferrous chloride and ferrous acetate is used.
The second agent in the hair dye of the present invention may contain one type of iron salt alone, or may contain two or more types of iron salts in combination.

  The content of the iron salt in the second agent may be appropriately set within the range where the effects of the present invention are exhibited, but from the viewpoint of the stability of the preparation and the hair dyeing effect, It is 0.5-10 mass%, More preferably, it is 1-6 mass%.

  The pH of the second agent in the hair dye of the present invention is preferably 2 to 6, more preferably 3 to 5, from the viewpoint of the stability of the preparation and the hair dyeing effect.

  The 1st agent and / or 2nd agent in the hair dye of this invention may contain the other component normally used in a hair dye in addition to the component described above. Such components include bases, surfactants, fats and oils, solvents, thickeners, organic acids, preservatives, antioxidants, pH adjusters, wetting agents, fragrances, metal odor masking agents, colorants. Contains UV absorbers, hair restoration agents, anti-dandruff agents, antibacterial agents, softeners, moisturizers, active oxygen scavengers, antioxidants, antimicrobial agents, silicones, minerals, hydrolyzed proteins, peptides, amino acids, etc. It's okay. The content of these components can be appropriately set within the range where the effects of the present invention are exhibited.

Examples of the base include higher alcohols, hydrocarbons, fatty acid esters, vegetable oils, fatty acids and the like.
In particular, the first agent in the hair dye of the present invention preferably contains a higher alcohol from the viewpoint of the stability of the preparation, and is at least selected from the group consisting of cetostearyl alcohol, cetyl alcohol, stearyl alcohol, and behenyl alcohol. More preferably, it contains one higher alcohol. From the viewpoint of the stability of the preparation, the content of the higher alcohol is preferably 1% by mass or more, more preferably 3% by mass or more, based on the total amount of the first agent. Moreover, from a viewpoint of usability, Preferably it is 20 mass% or less, More preferably, it is 10 mass% or less.

Examples of the surfactant include an anionic surfactant, a nonionic surfactant, an amphoteric surfactant, and a cationic surfactant. Examples of the nonionic surfactant include polyoxyethylene alkyl ether, polyoxyethylene polyoxypropylene alkyl ether, glycerin fatty acid ester, polyglycerin fatty acid ester, polyethylene glycol fatty acid ester, and alkyl glucoside. Examples of the anionic surfactant include polyoxyethylene alkyl ether phosphoric acid and its salt, N-acyl amino acid salt, alkyl ether carboxylate, alkyl sulfate, polyoxyethylene alkyl ether sulfate, sulfonate and the like. It is done. Examples of the cationic surfactant include alkyl ammonium salts. Examples of amphoteric surfactants include alkylamidopropylbetaine.
In particular, the first agent in the hair dye of the present invention preferably contains at least one nonionic surfactant and more preferably contains a polyoxyethylene alkyl ether from the viewpoint of the stability of the preparation. . From the same viewpoint, the content of the nonionic surfactant is preferably 0.1 to 10% by mass, more preferably 1 to 7% by mass, based on the total amount of the first agent.

  Examples of the antioxidant include ascorbic acid and derivatives thereof, sodium sulfite and the like.

  Examples of pH adjusters include citric acid, phosphoric acid, ammonia, ammonium hydrogen carbonate, ammonium carbonate, potassium hydroxide, sodium hydroxide, monoethanolamine, isopropanolamine, ammonium phosphate, diammonium monohydrogen phosphate, citric acid. Sodium, ammonium citrate, potassium phosphate, sodium phosphate and the like can be used.

  Examples of the wetting agent include 1,3-butylene glycol, propylene glycol, glycerin, sorbitol, sodium pyrrolidonecarboxylate, amino acid, vegetable oil, and the like.

  Examples of the thickener include xanthan gum, polyethylene glycol, hydroxyethyl cellulose and the like.

  Examples of the solvent include water, ethanol, isopropyl alcohol, 1,3-butylene glycol, 1,2-pentanediol, 2-methyl-2,4-pentanediol, glycerin, diglycerin, propylene glycol, dipropylene glycol, and benzyl. Alcohol etc. can be mentioned.

  The hair dye of the present invention is a hair dye comprising at least a first agent and a second agent, and may be a two-component hair dye composed of the first agent and the second agent. It may be a three-component hair dye that further comprises a third agent in addition to the first agent and the second agent, or may be a multi-component hair dye that further comprises more agents.

  The hair dye of the present invention can perform hair dyeing by mixing at least the first agent and the second agent. Here, as described later, the mixing may be performed by applying the second agent after applying the first agent on the hair, or by previously mixing the first agent and the second agent. May be. From the viewpoint of usability, the mixing ratio of the first agent and the second agent is preferably the first agent: second agent = 1: 0.5 to 1: 2, more preferably the first agent, in terms of mass ratio. : Second agent = 1: 0.8 to 1: 1.2, more preferably 1: 1.

  As a dosage form of the first agent and the second agent contained in the hair dye of the present invention, for example, a cream, liquid, gel, emulsion, foam, spray, aerosol type or the like can be used. The first agent and the second agent may be the same dosage form, or may be different dosage forms. From the viewpoint of usability and stability, the first agent is preferably a cream or a gel. From the viewpoint of usability, the second agent is preferably a cream or gel.

  The preparation method of the 1st agent and the 2nd agent contained in the hair dye of this invention is not specifically limited, It can manufacture by a normal method. Here, the first agent contains a benzophenone compound having 3 or more hydroxyl groups, but a benzophenone compound having 3 or more hydroxyl groups generally has low solubility in water. Therefore, it is preferable to obtain a cream by heating and dissolving an oil phase component such as a benzophenone compound having three or more hydroxyl groups and an oil agent, and adding and emulsifying the water phase component to the oil phase component. Thus, the storage stability of a 1st agent can be improved by manufacturing a 1st agent.

  Hair dyeing can be performed by applying the first agent and the second agent contained in the hair dye of the present invention to the hair. Examples of hair dyeing methods include: (i) Firstly applying the first agent to the hair, leaving it for a certain period of time, then applying the second agent without washing away the first agent, and then leaving it for a certain period of time, (Ii) A method in which the first agent and the second agent are applied to the hair at the same time and left standing for a certain period of time, and then the hair is washed out to dye the hair, and (iii) the first agent And a composition obtained by mixing the second agent is applied to the hair, left standing for a certain period of time, and then the hair is washed to dye the hair. From the viewpoint of the hair dyeing effect, it is preferable to carry out hair dyeing by the above method (i).

  The hair dyeing time after application to the hair is appropriately adjusted according to the type and amount of the benzophenone compound, the amount applied to the hair, and the desired dyeing degree. The hair dyeing time after application to the hair is usually 1 to 60 minutes, preferably 5 to 40 minutes with the first agent applied when hair is dyed by the method (i) or (ii), Furthermore, in the state which apply | coated the 2nd agent, it is 1 to 60 minutes normally, Preferably it is 5 to 40 minutes.

  The coating amount of the first agent and the second agent contained in the hair dye of the present invention is such that the first agent is about 30 to 70 g and the second agent is about 20 cm in length from the viewpoint of usability. Is preferably about 30 to 70 g, more preferably about 40 to 60 g for the first agent and about 40 to 60 g for the second agent. In one aspect of the present invention, 50 g of the first agent and 50 g of the second agent may be applied to hair having a length of about 20 cm. The temperature at the time of applying to hair is preferably 15 to 45 ° C. from the viewpoint of burden on hair and human body.

  The following examples further illustrate the present invention, but the present invention is not limited to the examples.

(Preparation of the first agent)
The first agent was prepared as follows.
Weigh out oil phase components such as surfactants, higher alcohols, hydrocarbon oils, and benzophenone compounds, and water phase components such as gallic acid, tannic acid or sodium salicylate, and purified water, and dissolve them sufficiently with heating. After that, the water phase component is added and emulsified while stirring well in the oil phase component. Thereafter, the mixture was cooled, and a pH adjusting agent in an amount to adjust the pH of the first agent to 8 and urea dissolved in water were added to obtain the first agent.

(Preparation of the second agent)
About 2nd agent of Examples 1-7 and Comparative Examples 1-7, it prepared as follows.
Ferrous sulfate or ferrous chloride was added to purified water at room temperature, and ascorbic acid was further added. The obtained solution was dissolved by stirring to obtain a second agent. The pH of the obtained solution was about 3.
About the 2nd agent of Examples 8-13, it adjusted as follows.
Separately weigh the oil phase components of cetostearyl alcohol and polyoxyethylene cetostearyl ether and the aqueous phase components of ferrous sulfate, L-ascorbic acid, and purified water, and dissolve them with sufficient heat. Add water phase component and emulsify while mixing well. Then, it cooled and finished with stirring.

(Hair dyeing effect and hair color)
After the shampooing and rinsing treatment, 2 g of the first agent having each composition shown in Table 1 is applied to 1 g of a fully dried hair bundle (100% white hair ratio), and 15 minutes at 30 ° C. and 65% relative humidity. I left it alone. Next, 2 g of the second agent having each composition shown in Table 1 was applied and left again at 30 ° C. and 65% relative humidity for 15 minutes. Thereafter, the hair bundle was shampooed and rinsed and dried with a dryer.

  Using the dried hair bundle, the hair dyeing effect and the color of the hair were evaluated as follows.

Five professional panelists evaluated the hair dyeing effect with the naked eye according to the following criteria. If the evaluation of 5 panelists is divided into two, the more evaluation is adopted, and if the evaluation is divided into 3 or more, the test and evaluation are repeated until the evaluation of 5 persons agrees or is divided into two. went.
Evaluation criteria for hair dyeing effect A: Deep and deep hair dyed.
○: Hair was clearly dyed.
Δ: Slightly dyed.
X: Hair was not dyed.

Five professional panelists evaluated the color of hair (particularly the strength of bluishness) with the naked eye according to the following criteria. In addition, when evaluation of five panelists was divided into two or three or more, it evaluated in the same manner as described above.
Evaluation criteria for hair color ◎: Blueness is very weak 〇: Blueness is weak △: Blueness is slightly strong ×: Blueness is very strong

(White hair combing effect)
After the shampooing and rinsing treatment, 4 g of the first agent having each composition shown in Table 1 is applied to 2 g of a fully dried hair bundle (white hair ratio 20%), and 15 minutes at 30 ° C. and 65% relative humidity. I left it alone. Next, 4 g of the second agent having each composition shown in Table 1 was applied and left again at 30 ° C. and 65% relative humidity for 15 minutes. Thereafter, the hair bundle was shampooed and rinsed and dried with a dryer.

  Using the dried hair bundle, the gray hair combing effect was evaluated as follows.

Five professional panelists evaluated the gray hair combing effect with the naked eye according to the following criteria. In addition, when evaluation of five panelists was divided into two or three or more, it evaluated in the same manner as described above.
Evaluation criteria for white hair combing effect ◎: Gray hair is inconspicuous ○: White hair is slightly conspicuous △: White hair is conspicuous ×: White hair is not dyed

  The hair dye of the present invention containing urea and at least one benzophenone compound having three or more hydroxyl groups in the first agent and containing an iron salt in the second agent has the hair dyeing effect, white hair Good results were obtained in the effect and color tone. In contrast, Comparative Examples 1 to 4 and 7, which do not contain at least one benzophenone compound having 3 or more hydroxyl groups, do not contain at least one benzophenone compound having 3 or more hydroxyl groups, and urea The hair dyes described in Comparative Examples 5 and 6 that do not contain did not show sufficient effects in the hair dyeing effect, the gray hair combing effect, and / or the color tone.

Claims (2)

  A hair dye comprising at least a first agent and a second agent, wherein the first agent contains urea and at least one benzophenone compound having three or more hydroxyl groups, and the second agent Is a hair dye containing at least one iron salt.   The hair dye according to claim 1, wherein the first agent further contains at least one organic compound that develops color by reacting with iron and / or at least one plant extract containing the organic compound.