JP2010219057A - Display panel - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a display panel having a thin sheet thickness and not causing warpage of a sheet glass, even if a large-sized sheet glass is used, when a front face sheet glass and a rear face sheet glass are sealed by a low-melting-point sealing glass, and being aimed at realizing enlargement of a display panel, high definition, and lighter weight. <P>SOLUTION: The display panel which is sealed airtight with a front-face sheet glass and a rear-face sheet glass sealed with a low-melting-point sealing glass interposed has a sheet thickness of less than 2.0 mm, in the front face sheet glass and the rear-face sheet glass; the sizes of the front face sheet glass and the rear-face sheet glass are 42 inches or more; and moreover, the thermal expansion coefficient difference between the front face sheet glass and the rear-face sheet glass is 1.0×10<SP>-7</SP>/°C or less. <P>COPYRIGHT: (C)2010,JPO&INPIT

Description

  The present invention relates to a display panel in which a front plate glass and a rear plate glass are hermetically sealed via a low melting point sealing glass, and more particularly, a plasma display in which a front plate glass and a rear plate glass are hermetically sealed via a low melting point sealing glass. Regarding panels.

  A plasma display panel (hereinafter referred to as PDP) has a structure in which a front plate glass and a rear plate glass are bonded together via a low-melting point sealing glass. The front plate glass is formed with a transparent electrode made of an ITO film, a nesa film or the like on its surface, and a dielectric layer is formed after the dielectric glass is applied thereon. Further, the back plate glass is formed with electrodes made of Al, Ag, Ni or the like on the surface thereof, and a partition wall (also referred to as a barrier rib) is formed thereon after a dielectric glass and a partition material are applied thereon. Thereafter, the front plate glass and the back plate glass are made to face each other to align the electrodes and the like, and then the front plate glass and the back plate glass are hermetically sealed using the low melting point sealing glass.

Conventionally, soda lime glass (coefficient of thermal expansion of about 84 × 10 ⁻⁷ / ° C.) widely used for construction or automobiles is used for plate glass for PDP (front plate glass and back plate glass). Other peripheral materials such as dielectric glass have been designed to fit the coefficients. However, since soda lime glass has a strain point as low as about 500 ° C., heat treatment or heat shrinkage occurs when heat treatment is performed at around 600 ° C. For this reason, when the front plate glass and the rear plate glass made of soda lime glass are opposed to each other, it is difficult to accurately align the position of the electrode or the like due to thermal deformation or thermal shrinkage. In particular, it is possible to produce a high-definition PDP with a large screen. It was difficult. Therefore, as a plate glass for PDP, a glass having a thermal expansion coefficient equivalent to that of soda-lime glass and a high strain point has been put into practical use (see Patent Documents 1 and 2).

Moreover, even when high strain point glass is used for the plate glass, if the difference in thermal expansion coefficient between the plate glass and the dielectric layer is large, the plate glass is stressed when heat-treating the plate glass for forming the dielectric layer, There was a problem that the plate glass warped. If the plate glass warps, when the front plate glass and the rear plate glass are hermetically sealed, the respective plate glasses are not parallel to each other, so accurate alignment cannot be performed, and the hermetic seal becomes difficult and the plate glass is cracked. Problems occurred and the yield of the display panel was reduced. According to Patent Document 3, even if warpage is generated in the glass sheet, by using the defined amount of warpage in the range of ^{-1 × 10 -2 m -1 ≦ 1} / R ≦ 1 × 10 -2 m -1 glass sheet, It is described that, during hermetic sealing, breakage of the plate glass can be suppressed and the yield is improved. Here, R is a curvature radius of warpage of the plate glass.

JP-A-8-290938 JP-A-8-290939 JP-A-10-283941

  In recent years, display panels, in particular PDPs, have been increased in screen size and definition. When the screen size of the PDP increases, even if slight thermal deformation or thermal shrinkage occurs in the plate glass in the manufacturing process of the PDP, the entire screen of the PDP appears as a large distortion. Further, when warping occurs in a PDP having a large screen size, a large gap is generated between the partition wall head inside the PDP and the front plate glass, and there is a possibility that erroneous discharge occurs between cells. When viewed from the display surface of the plate glass, the image is curved and the surface quality of the PDP deteriorates. Furthermore, after the front plate glass and the rear plate glass are hermetically sealed with the low melting point sealing glass, if the PDP is warped, the PDP is applied to the vacuum exhaust, rare gas sealing, and exhaust pipe sealing process provided thereafter. When it is added, the PDP is easily displaced in a firing furnace such as a belt furnace, and as a result, the production yield of the PDP is reduced.

  In addition, there is a demand for weight reduction in PDP, and if the plate thickness of the plate glass used for PDP is reduced, it can greatly contribute to weight reduction of PDP. Currently, the plate glass used in the PDP has a plate thickness of approximately 2.8 mm. However, if the plate thickness is set to less than 2.0 mm, for example, it is possible to greatly contribute to the weight reduction of the entire PDP. However, if the plate thickness of the plate glass is reduced, in the PDP manufacturing process, the plate glass is likely to be thermally deformed or contracted, resulting in the same problem as in the case of increasing the screen size.

  According to Patent Documents 1 and 2, when a high strain point glass having a strain point of 570 ° C. or higher is used as a plate glass, in the PDP manufacturing process, thermal deformation and heat shrinkage due to the thermal characteristics (strain point etc.) of the plate glass are caused. It becomes possible to suppress. According to Patent Document 3, if the difference in thermal expansion coefficient between the plate glass and the dielectric layer is set to an appropriate value, it is possible to suppress warpage of the plate glass that occurs when the dielectric layer is formed on the plate glass. However, even when a high strain point glass having a strain point of 570 ° C. or higher is used and the thermal expansion coefficient of the dielectric layer formed on the plate glass is set to an appropriate value, the plate glass has a small plate thickness and the size of the plate glass. Is large, when the front plate glass and the rear plate glass are hermetically sealed with the low melting point sealing glass, the plate glass is greatly warped, which is a great obstacle to achieving a large screen, high definition, and light weight of the PDP.

  As described above, the present invention has been made in view of the above circumstances, and even when a plate glass having a small plate thickness and a large size is used, the front plate glass and the back plate glass are made of low melting point sealing glass. It is an object of the present invention to provide a display panel that does not warp a plate glass when hermetically sealing and to contribute to achieving a large screen, high definition, and light weight of the display panel.

As a result of various experiments, the present inventors have determined that the thickness of the front plate glass and the rear plate glass is less than 2.0 mm in the display panel in which the front plate glass and the rear plate glass are hermetically sealed via the low melting point sealing glass. By setting the size of the front plate glass and the back plate glass to 42 inches or more and the difference in thermal expansion coefficient between the front plate glass and the back plate glass to 1.0 × 10 ⁻⁷ / ° C. or less, it is possible to obtain a display panel without warping. In view of the above, it has been found that the display panel can be increased in screen size, definition, and weight, and is proposed as the present invention.

  A display panel in which a front plate glass and a rear plate glass are hermetically sealed via a low melting point sealing glass. For example, in a PDP, the gap (gap) between the front plate glass and the rear plate glass corresponds to the sealing thickness of the low melting point sealing glass. And it is very small value. In such a case, if the thermal expansion coefficients of the front plate glass and the rear plate glass are mismatched, the front plate glass and the rear plate glass are hermetically sealed with a low-melting-point sealing glass, and then a concave warp on the plate glass side having a large thermal expansion coefficient. It was revealed that the display panel warps due to the occurrence of In particular, when the thickness of the front plate glass and the rear plate glass of the PDP is less than 2.0 mm and the size of the front plate glass and the rear plate glass is 42 inches or more, if the thermal expansion coefficients of the front plate glass and the rear plate glass are mismatched, After the plate glass and the back plate glass were hermetically sealed with the low melting point sealing glass, it was revealed that there is a large tendency for the concave warp to occur on the side of the plate glass having a large thermal expansion coefficient.

Therefore, as a result of diligent efforts, the inventors have determined that the difference in thermal expansion coefficient between the front plate glass and the back plate glass is 1 when the plate glass thickness is less than 2.0 mm and the size of the front plate glass and the back plate glass is 42 inches or more. If the temperature is regulated to 0.0 × 10 ⁻⁷ / ° C. or less, after the front plate glass and the rear plate glass are hermetically sealed with a low melting point sealing glass, a situation in which a concave warp occurs on the side of the plate glass having a large thermal expansion coefficient is suppressed. I found out that I can.

As a method for regulating the difference in thermal expansion coefficient between the front plate glass and the back plate glass to 1.0 × 10 ⁻⁷ / ° C. or less, it is highly necessary to use the following methods as appropriate. For example, there is a method in which the front plate glass and the back plate glass to be used are made into glasses having the same production history. In addition, a method of thoroughly controlling the material of the plate glass, measuring the thermal expansion coefficient frequently, and selecting the front plate glass and the rear plate glass having the matched thermal expansion coefficient can be considered. Furthermore, in order to reduce the difference in thermal expansion coefficient between the front plate glass and the back plate glass, the manufacturing conditions of the plate glass (for example, precise temperature control of the glass melt flowing into the tin bath when manufactured by the float method, molten tin It is also effective to thoroughly manage temperature control, precise control of heater output and prevention of output fluctuation, and strict management of batch component fluctuation. In addition, since the curvature of a display tends to arise when the plate | board thickness of plate glass is less than 2.0 mm, the significance which controls the thermal expansion coefficient difference of front plate glass and back plate glass to 0.5x10 < ^-7 > / degrees C or less is large. .

  Moreover, if the front plate glass and the back plate glass to be used are cut out from the same base glass, the difference in thermal expansion coefficient between the front plate glass and the back plate glass can be reduced. However, in actual display panel manufacturing, if a front panel glass and a rear panel glass are cut out from the same mother glass to produce a display panel, unreasonable restrictions are imposed on the combination of the front panel glass and the rear panel glass. Productivity is reduced. Therefore, in the manufacture of a display panel, it is inevitable to combine plate glasses having different production dates, and it is important to strictly manage the plate glass manufacturing process and reduce the difference in thermal expansion coefficient between the front plate glass and the back plate glass.

On the other hand, the difference in thermal expansion coefficient between the front plate glass and the back plate glass is 0.01 × 10 ⁻⁷ / ° C. or more, preferably 0.1 × 10 ⁻⁷ / ° C. or more. If the difference in thermal expansion coefficient between the front plate glass and the back plate glass is regulated to less than 0.01 × 10 ⁻⁷ / ° C., the plate glass manufacturing cost increases, which may lead to an increase in the display panel manufacturing cost.

The display panel of the present invention is a display panel in which a front plate glass and a rear plate glass are hermetically sealed via a low melting point sealing glass, and the thickness of the front plate glass and the rear plate glass is less than 2.0 mm. Since the size is set to 42 inches or more and the difference in thermal expansion coefficient between the front plate glass and the rear plate glass is regulated to 1.0 × 10 ⁻⁷ / ° C. or less, the front plate glass and the rear plate glass have a low melting point in the display panel manufacturing process. When the sealing glass is hermetically sealed, there is no warping of the plate glass, which can greatly contribute to achieving a large screen, high definition, and light weight of the display panel. In particular, according to the display panel of the present invention, the warpage of the plate glass due to the difference in thermal expansion coefficient between the front plate glass and the back plate glass can be remarkably reduced, and in addition, the screen distortion, curvature, blur, etc. of the display panel can be reduced. It can be significantly reduced. In addition, an internal structure in which the inside of the cell is appropriately partitioned can be ensured, and as a result, high-definition image quality free from turbidity (crosstalk) of the emission color can be realized. In the present invention, the “thermal expansion coefficient difference” means an average thermal expansion coefficient difference in a temperature range of 30 to 380 ° C. Moreover, in the display panel of the present invention, the front plate glass and the back plate glass do not exclude an aspect in which the glass composition is different.

  As described above, a plate glass having a plate thickness of 2.8 mm is mainly used for the PDP. However, if the plate thickness of the plate glass is reduced, the mass of the entire PDP can be greatly reduced. However, if the plate thickness of the plate glass is reduced, the warpage of the plate glass due to the difference in thermal expansion coefficient between the front plate glass and the back plate glass increases, and the tendency is larger when the plate thickness is less than 2.0 mm, and less than 1.5 mm. Is even greater. If the plate thickness of the plate glass is halved, the warp of the display panel due to the difference in thermal expansion coefficient between the front plate glass and the back plate glass is approximately doubled. That is, as the plate thickness of the plate glass becomes smaller, the effect brought about by the display panel of the present invention can be enjoyed accurately.

In the display panel of the present invention, the difference in thermal expansion coefficient between the front plate glass and the back plate glass is 1.0 × 10 ⁻⁷ / ° C. or less, preferably 0.5 × 10 ⁻⁷ / ° C. or less, more preferably 0.4 × 10. ^-7 / ℃ is less than or equal to. The higher the definition of the display panel, the greater the influence of display warpage on the display image. In particular, in a high-definition PDP of 42 inches or more, it is desirable that the difference in thermal expansion coefficient between the front plate glass and the rear plate glass is 0.5 × 10 ⁻⁷ / ° C. or less, and in particular, the plate glass has a thickness of less than 2.0 mm. In this case, since warping of the display is likely to occur, it is significant to regulate the difference in thermal expansion coefficient between the front plate glass and the rear plate glass to 0.5 × 10 ⁻⁷ / ° C. or less.

The thickness of the plate glass is t (mm), the thermal expansion coefficient of the front plate glass is α ₁ (× 10 ⁻⁷ / ° C.), the thermal expansion coefficient of the rear plate glass is α ₂ (× 10 ⁻⁷ / ° C.), and the size of the plate glass Is 42 inches or more and 120 inches or less,
When 1.5 ≦ t <2.0, −0.5 ≦ (α ₁ −α ₂ ) ≦ 0.5
When 0.5 <t <1.5, −0.4 ≦ (α ₁ −α ₂ ) ≦ 0.4
If it restrict | limits to, since the curvature of a display panel can be prevented more correctly, it is preferable.

Furthermore, the plate thickness of the plate glass is t (mm), the thermal expansion coefficient of the front plate glass is α ₁ (× 10 ⁻⁷ / ° C.), and the thermal expansion coefficient of the back plate glass is α ₂ (× 10 ⁻⁷ / ° C.). When the size of the glass sheet is 42 inches or more and 120 inches or less,
When 1.5 ≦ t <2.0, −0.25 ≦ (α ₁ −α ₂ ) ≦ 0.25
When 0.5 <t <1.5, −0.2 ≦ (α ₁ −α ₂ ) ≦ 0.2
If it restrict | limits to, since the curvature of a display panel can be prevented more correctly, it is more preferable.

  The size of the glass sheet according to the display panel of the present invention is 42 inches (for example, 550 mm long × 1000 mm wide) or more, 50 inches (for example, 700 mm long × 1200 mm wide), and 58 inches (for example, 800 mm long × 1350 mm wide). As described above, 65 inches (for example, length 850 mm × width 1500 mm) or more is more preferable. As the size of the plate glass increases, the warpage of the display panel due to the difference in thermal expansion coefficient between the front plate glass and the back plate glass increases. That is, as the size of the plate glass increases, the effect brought about by the display panel of the present invention can be enjoyed more accurately. Further, when the size of the plate glass is less than 42 inches, even when there is a difference in thermal expansion coefficient between the front plate glass and the rear plate glass, when the front plate glass and the rear plate glass are hermetically sealed with the low melting point sealing glass, There exists a tendency for curvature to become difficult to generate | occur | produce and the effect which the display panel of this invention brings is scarce.

  The sealing thickness of the low melting point sealing glass according to the display panel of the present invention is preferably less than 500 μm, more preferably less than 400 μm, still more preferably less than 300 μm, and most preferably less than 250 μm. If the sealing thickness of the low melting point sealing glass is reduced, the degree of adhesion between the front plate glass and the rear plate glass is increased, and the warpage of the display panel is increased. That is, as the sealing thickness of the low melting point sealing glass becomes smaller, the effect brought about by the display panel of the present invention can be properly enjoyed. When the sealing thickness of the low melting point sealing glass is 500 μm or more, even when the front plate glass and the rear plate glass have a difference in thermal expansion coefficient, the front plate glass and the rear plate glass are hermetically sealed with the low melting point sealing glass. The display panel tends to be less likely to warp, and the effect of the display panel of the present invention is poor. In the present invention, “low melting point” refers to a case where the softening point measured with a differential thermal analysis (DTA) apparatus is 600 ° C. or lower.

  The strain point of the plate glass according to the display panel of the present invention is preferably 570 ° C. or higher, more preferably 580 ° C. or higher, still more preferably 590 ° C. or higher, and most preferably 600 ° C. or higher. If the strain point of the glass is lower than 570 ° C., the plate glass is likely to be cracked or warped due to the thermal characteristics of the plate glass in the heat treatment process when manufacturing the display panel, and heat shrinkage or thermal deformation is caused. It becomes easy.

Plate glass according to the display panel of the present invention, soda-lime glass, borosilicate glass, aluminosilicate glass, can be used various glass such as barium strontium glass, SiO ₂ 50-70 mass% display a glass composition %, Al ₂ O ₃ 0-10%, MgO 0-10%, CaO 0-10%, SrO 0-15%, BaO 0-15%, ZrO ₂ 0-10%, B ₂ O ₃ 0-5% , Na ₂ O 0 to 10%, K ₂ O 0 to 10%, and glass having a thermal expansion coefficient of 60 to 90 × 10 ⁻⁷ / ° C. are preferably used. In addition, the following% display points out the mass% except the case where there is especially limitation.

SiO ₂ is a glass network former. The preferred content is 50 to 70%, in particular 54 to 70%. When the amount of SiO ₂ increases, the meltability deteriorates. When the amount of SiO ₂ decreases, the strain point of the glass tends to decrease and thermal deformation and thermal shrinkage tend to increase.

Al ₂ O ₃ is a component that increases the strain point of glass. The preferred content is 0-10%, especially 0-8%. When the amount of Al ₂ O ₃ increases, the high-temperature viscosity tends to increase and glass molding tends to be difficult.

  MgO is a component that lowers the high-temperature viscosity of the glass to increase the moldability and meltability of the glass and increase the strain point of the glass. The preferred content is 0-10%, especially 1-9%. When the amount of MgO increases, the devitrification temperature of the glass tends to increase.

  CaO, like MgO, is a component that lowers the high-temperature viscosity of the glass to increase the moldability and meltability of the glass and increase the strain point of the glass. The preferred content is 0-10%, especially 0-6%. When the amount of CaO increases, the devitrification temperature of the glass tends to increase.

  SrO is a component that lowers the high temperature viscosity of the glass to increase the moldability and meltability of the glass and increase the strain point of the glass. The preferred content is 0-15%, especially 2-13%. When SrO increases, the density of the glass increases and the devitrification temperature of the glass tends to increase.

  BaO, like SrO, is a component that lowers the high-temperature viscosity of the glass and increases the moldability and meltability of the glass. The preferred content is 0-15%, in particular 0-8%. When BaO increases, the density of the glass increases and the devitrification temperature of the glass tends to increase. Since BaO is an environmentally hazardous substance, it is desirable to reduce it as much as possible without damaging the characteristics.

ZrO ₂ is a component that increases the strain point of glass. The preferred range is 0-10%, especially 0-6%. When the amount of ZrO ₂ increases, the density of the glass tends to increase.

B ₂ O ₃ is a component that lowers the viscosity of the glass and improves the meltability and moldability. However, since the strain point of the glass is also remarkably lowered, the content is preferably limited to 5% or less. . When the content of B ₂ O ₃ is more than 5%, the plate glass is likely to be cracked or warped in the thermal process for producing the PDP, and the plate glass is likely to be thermally deformed or thermally contracted.

Na ₂ O is a component that controls the thermal expansion coefficient of the glass or increases the meltability of the glass. The preferred content is 0 to 10%, in particular 1 to 7%. When Na ₂ O increases, the strain point of the glass tends to decrease.

K ₂ O, like Na ₂ O, is a component that controls the thermal expansion coefficient of glass and increases the meltability of glass. The preferred content is 0 to 10%, in particular 2 to 10%. When K ₂ O increases, the glass strain point tends to decrease.

In addition to the above components, various components can be added to the plate glass used in the present invention. For example, in order to prevent coloring by ultraviolet rays, TiO ₂ and CeO ₂ are reduced to 5%, and Y ₂ O ₃ , La ₂ O ₃ and Nb ₂ O ₅ are each 3% for the purpose of improving the moldability by lowering the liquidus temperature. Up to 5% ZnO can be added to improve water resistance and up to 4% P ₂ O ₅ to improve crack resistance. Further, a clarifier component such as As ₂ O ₃ , Sb ₂ O ₃ , SO ₃ , SnO ₂ , and Cl is added to a total amount of 1%, and a colorant component such as Fe ₂ O ₃ , CoO, NiO, and Cr ₂ O _{3 is} added. It is possible to add up to 1% each.

The thermal expansion coefficient of the plate glass according to the display panel of the present invention is preferably 60 to 90 × 10 ⁻⁷ / ° C., more preferably 65 to 85 × 10 ⁻⁷ / ° C. in the temperature range of 30 to 380 ° C. When the thermal expansion coefficient is larger than 90 × 10 ⁻⁷ / ° C., thermal cracking of the plate glass due to the thermal expansion coefficient of the glass tends to occur in the display panel manufacturing process. If the coefficient of thermal expansion is less than 60 × 10 ⁻⁷ / ° C., the thermal expansion coefficient of the dielectric glass, the low-melting-point sealing glass, etc. and the sheet glass is inconsistent. Problems are likely to occur.

  The glass sheet according to the display panel of the present invention is prepared by charging a glass raw material prepared so as to have a desired glass composition into a continuous melting furnace, heating and melting the glass raw material, defoaming, and then supplying it to a molding apparatus. It can be produced by forming glass into a plate shape and slowly cooling it. As a method for forming the plate glass according to the display panel of the present invention, various forming methods such as a float method, a slot down draw method, an overflow down draw method, and a redraw method can be adopted, but the plate method is formed by the float method. It is preferable to do. The reason is that in the case of the float process, it is easy to obtain a large plate glass at a relatively low cost.

  When a glass substrate is formed by the float process, the glass may be colored by a reducing atmosphere such as molten tin, hydrogen, or nitrogen. When the colored glass substrate is used as the front plate glass, there arises a problem that the image quality of the display panel is deteriorated. However, it can be used as the back plate glass.

  The display panel of the present invention can have a structure corresponding to the type of display applied. For example, in the case of PDP, a dielectric layer is formed on the surface of the front plate glass and the back plate glass. The formed dielectric layer controls the warpage of the display panel due to the difference in thermal expansion coefficient between the glass sheet and the dielectric layer by regulating the thermal expansion coefficient of the dielectric layer to the value described in Patent Document 3. can do. In addition, when using lead-free dielectric glass for the dielectric layer, the residual stress remaining on the plate glass should be as small as possible to suppress warpage and cracking of the plate glass due to the difference in thermal expansion coefficient between the plate glass and the dielectric layer. However, if the residual stress remaining on the plate glass is regulated within a range of −800 to 1500 (psi) (preferably −700 to 1300 (psi), more preferably 0 to 1300 (psi)), the above problem is hardly caused. The “residual stress remaining in the plate glass” means the residual stress existing in the plate glass observed when the interface between the plate glass and the dielectric layer is observed with a strain gauge in the fired plate glass. When the residual stress is a compressive stress, it is indicated by a “negative” value, and when it is a tensile stress, it is indicated by a “positive” value.

The low melting point sealing glass used for the display panel of the present invention includes PbO—B ₂ O ₃ glass, Bi ₂ O ₃ —B ₂ O ₃ glass, SnO—P ₂ O ₅ glass, V ₂ O. Various glasses such as _5- P ₂ O ₅ glass can be used. In _{particular, Bi 2 O 3 -B 2 O} 3 based glass, _SnO-P 2 _{O 5} based _{glass, V 2 O 5 -P 2 O} 5 -based glass may be substantially glass composition containing no PbO Therefore, it can meet recent environmental demands. Here, “substantially does not contain PbO” refers to a case where the content of PbO in the glass composition is 1000 ppm or less.

Bi ₂ O ₃ -B ₂ O ₃ based glass, a glass composition, in _{mol%, Bi 2 O 3 30~50%,} B 2 O 3 20~35%, 1~25% ZnO ( preferably 10 to 25%), BaO 0-15% (preferably 1-15%), BaO + SrO + MgO + CaO 0-20% (preferably 3-15%). If the glass composition range is regulated as described above, a glass having a low melting point and good thermal stability can be obtained.

_SnO-P 2 _{O 5} based glass, a glass composition, in _{mol%, SnO 40~70%, P 2 O} 5 20~40%, SiO 2 0~10%, 0~25% ZnO ( preferably 1 _20%), preferably contains B 2 O 3 0 to 25% of (preferably 1 to 20%). If the glass composition range is regulated as described above, a glass having a low melting point and good water resistance and thermal stability can be obtained.

V ₂ O ₅ -P ₂ O ₅ based glass, a glass composition, in _{mol%, V 2 O 5 10~60%,} P 2 O 5 5~40%, Bi 2 O 3 0~30% ( preferably 1 to 10%), ZnO 0 to 40%, TeO ₂ 0 to 40%, RO (R is one or more selected from Mg, Ca, Ba, and Sr) 0 to 35% (preferably 3 to 25%) It is preferable to contain. If the glass composition range is regulated as described above, a glass having a low melting point and good water resistance and thermal stability can be obtained.

The low melting point sealing glass is appropriately added a refractory filler for the purpose of matching the thermal expansion coefficient with the plate glass and improving the mechanical strength of the low melting point sealing glass (for example, the refractory filler 5 with respect to 100 parts by mass of the glass). The coefficient of thermal expansion is adjusted so that a slight stress of tension is applied to the glass sheet. Moreover, as a refractory filler, cordierite, willemite and tin oxide are Bi ₂ O ₃ —B ₂ O ₃ based glass, SnO—P ₂ O ₅ based glass and V ₂ O ₅ —P ₂ O ₅ based glass. It has good compatibility and is suitable.

  The softening point of the low melting point sealing glass is preferably 450 ° C. or lower. When the softening point of the low melting point sealing glass is higher than 450 ° C., the sealing temperature must be higher than 530 ° C. Therefore, when the front plate glass and the rear plate glass are hermetically sealed with the low melting point sealing glass, the heat of the plate glass There is a risk of thermal deformation and thermal shrinkage due to characteristics (such as strain point).

  The display panel of the present invention is preferably applied to a PDP. This is because PDPs are strongly required to have a large screen, high definition, and light weight, and there is a great need to reduce the thickness of the plate glass and increase the size of the plate glass. In addition, the PDP performs airtight sealing between the front plate glass and the rear plate glass in a heat process of about 450 to 520 ° C., and warpage of the plate glass due to the difference in thermal expansion coefficient between the front plate glass and the rear plate glass occurs in the sealing step. This is because there is a great concern.

  The display panel of the present invention is preferably applied to a field emission display (hereinafter referred to as FED). According to the present invention, since the warpage of the plate glass can be reduced, the distance between the front plate glass and the rear plate glass can be made uniform, and the acceleration voltage applied between the front plate glass and the rear plate glass within the FED apparatus varies. It is difficult to cause a situation in which the luminance characteristics of the FED are adversely affected due to the occurrence or change of the velocity of electrons colliding with the phosphor. In addition, the FED, like the PDP, has a strong demand for larger screen, higher definition, and lighter weight, and there is a great need for reducing the thickness of the plate glass and increasing the size of the plate glass. Needless to say, the FED referred to in the present invention includes all types of FEDs having various electron-emitting devices.

The structure of the present invention is a structure in which a front plate glass and a rear plate glass are hermetically sealed via a low melting point sealing glass, and the thickness of the front plate glass and the rear plate glass is less than 2.0 mm. size is equal to or greater than 42 inches, and the thermal expansion coefficient difference of the back plate glass front plate glass is characterized by at 1.0 × 10 -7 ^/ ℃ or less. Since the structure of the present invention can have the same structure and effects as the display panel of the present invention described above, the description thereof is omitted here for convenience. Needless to say, the structure of the present invention can have the same characteristics as the display panel of the present invention.

The plate glass set for producing a display panel of the present invention is a plate glass set for producing a display panel having a front plate glass and a back plate glass, and the thickness of the front plate glass and the back plate glass is less than 2.0 mm. When the thermal expansion coefficient of the front plate glass is α ₁ and the thermal expansion coefficient of the rear plate glass is α ₂ , −1.0 × 10 ⁻⁷ / ° C. ≦ (α ₁ −α ₂ ) It is characterized by satisfying the relationship of ≦ 1.0 × 10 ⁻⁷ / ° C. If a display panel is produced using the flat glass set for producing a display panel of the present invention, the resulting display panel can have the same functions and effects as the display panel of the present invention. The description thereof is omitted here for convenience.

  The display panel according to the present invention will be described in detail based on examples. Tables 1 and 2 show examples of the present invention, and Table 3 shows comparative examples of the present invention.

  First, front plate glass and back plate glass having thermal expansion coefficients, strain points, and plate thicknesses as shown in Tables 1 to 3 were prepared. The front plate glass and the back plate glass shown in Tables 1 to 3 are formed with uniform electrodes and dielectric layers, and there are cracks, warpage, etc. in the plate glass before air-sealing with the low melting point sealing glass. I used something that was not. The thermal expansion coefficient of the low melting point sealing glass and the dielectric layer is set to a value that does not cause mismatch with the thermal expansion coefficient of the plate glass. As a result, the low melting point sealing glass / dielectric layer Thermal deformation and thermal shrinkage due to mismatch of thermal expansion coefficients of plate glass were set to a negligible value. In addition, about members other than the above, PDP was produced using the manufacturing method of a normal PDP using the manufacturing method of the normal PDP.

  The plate glass used in Tables 1 and 3 was 42 inches diagonally with length: width = 16: 9. The plate glass used in Table 2 was a 50-inch diagonal size of length: width = 16: 9.

  The thermal expansion coefficient of the plate glass was calculated by measuring the average thermal expansion coefficient in a temperature range of 30 to 380 ° C. with a dilatometer using the plate glass described in the examples as a sample.

  The strain point of the plate glass was measured by a method based on ASTM C336-71. In addition, it becomes possible to suppress the thermal deformation and thermal shrinkage of the plate glass due to the thermal process when manufacturing the display as the temperature of the strain point is higher. In the embodiment of the present invention, the strain point of the front plate glass and the back plate glass is considerably higher than the sealing temperature of the low-melting glass (for example, 50 ° C. or higher), so the deformation of the glass due to the thermal characteristics of the glass is It is so slight that it can be ignored.

Bi ₂ O ₃ —B ₂ O ₃ -based low melting point lead-free sealing glass is used for hermetic sealing of the front plate glass and the rear plate glass, and the thermal expansion coefficient at 30 to 250 ° C. is 69 × 10 ⁻⁷ / ° C. The one having a softening point of 425 ° C. measured by a macro type differential thermal analyzer (DTA) was used. Moreover, the airtight sealing of the front plate glass and the back plate glass was performed by applying the paste of the low melting point sealing glass on the outer periphery of the back plate glass with a dispenser, and then baking it in a belt-type baking furnace. The sealing conditions were performed by raising and lowering the temperature at 2 ° C./min and maintaining the sealing temperature in the table for 30 minutes.

  The substrate damage of the display panel was observed visually. The plate glass with no cracks was marked with “◯”, and the plate glass with cracks was marked with “x”.

  The amount of warpage of the display panel was calculated by irradiating the plate glass with a laser beam in parallel along the plate width direction and measuring the amount of change in shading of the laser beam due to the size of the warp of the plate glass. The warp width of the display panel was measured for each of the four sides of the front plate glass, and the value with the largest warp width was defined as the “warp amount”. A display having a warp amount of less than 3.5 mm is less affected by distortion, curvature, blurring, etc. of the screen, meaning that the definition of image quality is not lowered.

In Examples 1 and 2 of Tables 1 and 2. In the display panels shown in 1 to 10, since the difference in thermal expansion coefficient between the front plate glass and the back plate glass is regulated to 0.5 × 10 ⁻⁷ / ° C. or less, the substrate is not damaged, and the display panel The amount of warpage was 0.1 to 2.2 mm. As a result, Example Nos. The display panels shown in 1 to 10 are judged to have little influence of distortion, curvature, blurring, etc. of the screen, and the sharpness of the image is not impaired.

Comparative Example No. The display panel shown in No. 1 had a large thermal expansion coefficient difference between the front plate glass and the back plate glass of 6.0 × 10 ⁻⁷ / ° C., and thus the substrate was damaged. Comparative Example No. Display panel shown in 2-4, the thermal expansion coefficient difference of the back plate glass front plate glass is large as 2.1~4.0 × ^{10 -7} / ℃, warpage of the display panel is from 3.9 to 6. It was a large value of 7 mm. As a result, Comparative Example No. The display panels shown in 2 to 4 are greatly influenced by distortion, curvature, blurring, etc. of the screen, and it is determined that the sharpness of the image is impaired. Comparative Example No. 5, the plate thickness of the plate glass is as large as 3.5 mm, but the thermal expansion coefficient difference between the front plate glass and the back plate glass is as large as 3.0 × 10 ⁻⁷ / ° C., so the amount of warpage of the display panel is 3.9 mm there were.

  As a reference, Table 4 shows glass composition examples of plate glass applicable to the display panel of the present invention.

The display panel of the present invention is a display panel in which a front plate glass and a rear plate glass are hermetically sealed via a low melting point sealing glass, and the thickness of the front plate glass and the rear plate glass is less than 2.0 mm. Since the size is set to 42 inches or more and the difference in thermal expansion coefficient between the front plate glass and the rear plate glass is regulated to 1.0 × 10 ⁻⁷ / ° C. or less, the front plate glass and the rear plate glass have a low melting point in the display panel manufacturing process. When the sealing glass is hermetically sealed, there is no warping of the plate glass, which can greatly contribute to achieving a large screen, high definition, and light weight of the display panel. In particular, according to the display panel of the present invention, the warpage of the plate glass due to the difference in thermal expansion coefficient between the front plate glass and the back plate glass can be remarkably reduced, and in addition, the screen distortion, curvature, blur, etc. of the display panel can be reduced. It can be significantly reduced. In addition, an internal structure in which the inside of the cell is appropriately partitioned can be ensured, and as a result, high-definition image quality free from turbidity (crosstalk) of the emission color can be realized.

  Therefore, the display panel of the present invention is suitable not only for PDP but also for other displays. The display panel of the present invention is also suitable for, for example, an FED and a plasma addressed liquid crystal panel (PALC).

Claims (15)

In the display panel in which the front plate glass and the rear plate glass are hermetically sealed via the low melting point sealing glass, the thickness of the front plate glass and the rear plate glass is less than 2.0 mm, and the size of the front plate glass and the rear plate glass is 42 inches or more. And a difference in thermal expansion coefficient between the front plate glass and the back plate glass is 1.0 × 10 ⁻⁷ / ° C. or less. The front plate glass and the back plate glass are expressed by mass% as a glass composition, SiO ₂ 50 to 70%, Al ₂ O ₃ 0 to 10%, MgO 0 to 10%, CaO 0 to 10%, SrO 2 to 15%, BaO. _{0~15%, ZrO 2 0~10%,} B 2 O 3 0~5%, Na 2 O 0~10%, containing K 2 O 0~10%, and heat at a temperature range of 30 to 380 ° C. The display panel according to claim 1, wherein an expansion coefficient is 60 × 10 ⁻⁷ / ° C. to 90 × 10 ⁻⁷ / ° C.   The display panel according to claim 1 or 2, wherein the front plate glass and the back plate glass have a strain point of 580 ° C or higher.   The display panel according to any one of claims 1 to 3, wherein a strain point of the front plate glass and the back plate glass is higher by 50 ° C or more than the sealing temperature.   The display panel according to claim 1, wherein the front plate glass and the back plate glass contain 0 to 6 mass% of CaO as a glass composition.   6. The display panel according to claim 1, wherein the front plate glass and the rear plate glass are produced by a float process.   The display panel according to claim 1, wherein a warpage amount is 2.2 mm or less.   The display panel according to claim 1, wherein the low melting point sealing glass has a sealing thickness of less than 500 μm. The low melting point sealing glass has a glass composition in terms of mol%, Bi ₂ O ₃ 30-50%, B ₂ O ₃ 20-35%, ZnO 1-25%, BaO 0-15%, BaO + SrO + MgO + CaO 0-20. %. The display panel according to claim 1, comprising:%.   The refractory filler is added in an amount of 5 to 80 parts by mass with respect to 100 parts by mass of the low melting point sealing glass, and tension stress is applied to the front plate glass and the back plate glass. Display panel.   The dielectric layer is formed on the surface of the front plate glass and the back plate glass, and the residual stress of the front plate glass and the back plate glass by the dielectric layer is in the range of 0 to 1500 psi. 10. The display panel according to 10.   The display panel according to claim 1, wherein the display panel is a plasma display panel.   The display panel according to claim 1, wherein the display panel is a field emission display panel. In the structure in which the front plate glass and the rear plate glass are hermetically sealed through the low melting point sealing glass, the thickness of the front plate glass and the rear plate glass is less than 2.0 mm, and the size of the front plate glass and the rear plate glass is 42 inches or more. And a difference in coefficient of thermal expansion between the front plate glass and the back plate glass is 1.0 × 10 ⁻⁷ / ° C. or less. A plate glass set for producing a display panel having a front plate glass and a back plate glass, wherein the thickness of the front plate glass and the back plate glass is less than 2.0 mm, the size of the front plate glass and the back plate glass is 42 inches or more, and When the thermal expansion coefficient of the plate glass is α ₁ and the thermal expansion coefficient of the back plate glass is α ₂ , −1.0 × 10 ⁻⁷ / ° C. ≦ (α ₁ −α ₂ ) ≦ 1.0 × 10 ⁻⁷ / A flat glass set for producing a display panel, characterized by satisfying the relationship of ° C.