JP2008247653A - Method of manufacturing granular fertilizer composition and granular fertilizer composition - Google Patents

Method of manufacturing granular fertilizer composition and granular fertilizer composition Download PDF

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JP2008247653A
JP2008247653A JP2007089476A JP2007089476A JP2008247653A JP 2008247653 A JP2008247653 A JP 2008247653A JP 2007089476 A JP2007089476 A JP 2007089476A JP 2007089476 A JP2007089476 A JP 2007089476A JP 2008247653 A JP2008247653 A JP 2008247653A
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granular fertilizer
coating
coated
raw material
granular
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Sadahiro Takebayashi
禎浩 竹林
Yoshiori Yatsuse
佳織 八瀬
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Sumitomo Chemical Co Ltd
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Sumitomo Chemical Co Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a manufacturing method or the like of a granular fertilizer composition by which the high grade granular fertilizer composition is manufactured with a small number of steps. <P>SOLUTION: The method of manufacturing the granular fertilizer composition containing two or more kinds of coated granular fertilizers is characterized in that a coating film is provided on granular fertilizer raw materials while or after mixing two or more granular fertilizer raw materials. Because it is needless to carry out a coating process for each granular fertilizer raw material and respective granular fertilizer raw materials are coated as a whole by only once coating process, the required number of steps is reduced to be suitable for industrial manufacture. Because the coating process is carried out at the end, the probability of the occurrence of coating defects in the final product is remarkably made low even when the coated granular fertilizer raw materials are rubbed with each other in the mixing process. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

本発明は粒状肥料組成物の製造方法、並びに、粒状肥料組成物に関し、さらに詳細には、高品質の粒状肥料組成物をより少ない工程数で製造することができる粒状肥料組成物の製造方法、並びに、当該方法によって得ることができる粒状肥料組成物に関する。   The present invention relates to a method for producing a granular fertilizer composition, and a granular fertilizer composition, and more specifically, a method for producing a granular fertilizer composition capable of producing a high-quality granular fertilizer composition with fewer steps, In addition, the present invention relates to a granular fertilizer composition obtainable by the method.

近年の農業就労人口の減少と高齢化・大規模化が進む状況の中で、粒状肥料表面を樹脂等で被覆して肥料成分の溶出を制御することにより利用効率を高め、追肥作業の省力化を可能とする被覆粒状肥料の重要性が高まってきている。一般に、被覆粒状肥料は、母核となる粒状肥料の表面に水透過性の被覆が設けられた構造を有している。そして、粒状肥料の種類、被覆の素材、被覆の厚さ等を適宜選択することにより、所望の肥料成分、肥効持続期間、溶出パターン等を有する種々の被覆粒状肥料を得ることができる。被覆の代表的な素材は樹脂である。   Amid the recent decline in the agricultural working population and the aging and increasing scale, the surface of granular fertilizer is covered with resin, etc., and the elution of fertilizer components is controlled to increase utilization efficiency and labor saving in additional fertilization work. The importance of coated granular fertilizers that enable this is increasing. Generally, the coated granular fertilizer has a structure in which a water-permeable coating is provided on the surface of the granular fertilizer serving as a mother nucleus. And various coated granular fertilizers having a desired fertilizer component, fertilization duration, elution pattern, and the like can be obtained by appropriately selecting the type of granular fertilizer, the material of the coating, the thickness of the coating, and the like. A typical material for the coating is a resin.

より多様な肥効持続期間や溶出パターン等を達成するために、2種類以上の粒状肥料を混合して組み合わせた粒状肥料(粒状肥料組成物)も開発されている。特許文献1には、複数肥料銘柄を組み合わせた水稲用肥料が開示されている。この水稲用肥料は、被覆率が異なる複数種の粒状尿素を組み合わせたものであり、被覆はアルキド樹脂からなる。   In order to achieve more diverse duration of fertilization and elution patterns, granular fertilizers (granular fertilizer compositions) in which two or more types of granular fertilizers are mixed and combined have been developed. Patent Document 1 discloses a paddy rice fertilizer in which a plurality of fertilizer brands are combined. This fertilizer for paddy rice is a combination of a plurality of types of granular urea having different coverage, and the coating is made of an alkyd resin.

また、所望の特性を付与するために、被覆あるいは粒状肥料に他の成分を添加することも行われている。特許文献2には、緩効性(遅効性ともいう)の付与を目的として、粒状肥料あるいは熱硬化性樹脂の被覆にワックス等の疎水性化合物を含有させた被覆粒状肥料が開示されている。   Moreover, in order to provide a desired characteristic, adding another component to a coating or granular fertilizer is also performed. Patent Document 2 discloses a coated granular fertilizer in which a hydrophobic compound such as wax is contained in a granular fertilizer or a thermosetting resin coating for the purpose of imparting slow action (also referred to as delayed action).

被覆粒状肥料の製造方法および製造装置については、肥料粒子を噴流として流動させながら被覆材を付着乾燥させる噴流方式によるもの(例えば、特許文献3)や、コンクリートミキサ型の転動装置によるもの(例えば、特許文献4)が代表的である。
特開平5−105569号公報 特開2000−44377号公報 特開2002−362991号公報 特開2005−89258号公報
About the manufacturing method and manufacturing apparatus of a covering granular fertilizer, it is based on the jet method (for example, patent documents 3) which makes a covering material adhere and dry, making a fertilizer particle flow as a jet, and the thing by a concrete mixer type rolling device (for example, Patent Document 4) is a typical example.
Japanese Patent Laid-Open No. 5-105569 JP 2000-44377 A Japanese Patent Laid-Open No. 2002-362991 JP 2005-89258 A

2種類以上の粒状肥料を混合して組み合わせた粒状肥料組成物を製造する方法としては、組み合わせるべき各々の粒状肥料を予め調製しておき、最後にこれらの粒状肥料を混合する方法が採用されている。これは、粒状肥料が樹脂等からなる被覆が設けられた被覆粒状肥料である場合も同様である。しかし、この方法によって2種類以上の被覆粒状肥料を含有する粒状肥料組成物を製造する場合には、種々の課題が存在する。例えば、予め各々の被覆粒状肥料を調製しておく必要があるため、各々の被覆粒状肥料を調製する工程は独立したものとなり工程を共通化することが難しい。そのため、混合すべき被覆粒状肥料の種類が増えるほど、在庫すべき被覆粒状肥料の種類と量が増えてしまい、工業生産の面で不利となる。また、最後の混合工程で被覆粒状肥料同士が擦れ、最終製品において被覆欠陥が生じる確率が高まるという問題点もある。   As a method of producing a granular fertilizer composition in which two or more kinds of granular fertilizers are mixed and combined, a method of preparing each granular fertilizer to be combined in advance and finally mixing these granular fertilizers is adopted. Yes. The same applies to the case where the granular fertilizer is a coated granular fertilizer provided with a coating made of resin or the like. However, when producing a granular fertilizer composition containing two or more kinds of coated granular fertilizers by this method, there are various problems. For example, since it is necessary to prepare each coated granular fertilizer in advance, the process of preparing each coated granular fertilizer becomes independent and it is difficult to make the process common. Therefore, the more types of coated granular fertilizer to be mixed, the more types and amounts of coated granular fertilizer to be stocked, which is disadvantageous in terms of industrial production. In addition, there is a problem that the coated granular fertilizer rubs in the final mixing step and the probability that a coating defect occurs in the final product is increased.

本発明の目的は、工業生産に好適で、且つより高品質の粒状肥料組成物を製造することができる粒状肥料組成物の製造方法等を提供することにある。   An object of the present invention is to provide a method for producing a granular fertilizer composition that is suitable for industrial production and that can produce a higher quality granular fertilizer composition.

上記した課題を解決するための請求項1に記載の発明は、2種類以上の被覆粒状肥料を含有する粒状肥料組成物の製造方法であって、2種類以上の粒状肥料原料を混合しながら又は混合した後に、前記粒状肥料原料に対して被覆を設けることを特徴とする粒状肥料組成物の製造方法である。   Invention of Claim 1 for solving an above-mentioned subject is a manufacturing method of the granular fertilizer composition containing two or more types of coated granular fertilizers, or mixing two or more types of granular fertilizer materials, or After mixing, it is a manufacturing method of the granular fertilizer composition characterized by providing a covering to the granular fertilizer raw material.

本発明は2種類以上の被覆粒状肥料を含有する粒状肥料組成物の製造方法にかかるものであり、2種類以上の粒状肥料原料を混合しながら又は混合した後に、前記粒状肥料原料に対して被覆を設けることを特徴とする。すなわち、本発明の粒状肥料組成物の製造方法では、粒状肥料原料の混合工程と同時に又は混合工程終了後に、被覆工程を行う。本発明の粒状肥料組成物の製造方法では、粒状肥料原料ごとに被覆工程を行う必要がなく、1回の被覆工程で各粒状肥料原料に対してまとめて被覆を設ける。そのため、必要な工程数が少なく、工業生産に特に適している。また、本発明の粒状肥料組成物の製造方法では被覆工程を最後に行うので、混合工程で被覆粒状肥料同士が擦れても、最終製品において被覆欠陥が生じる確率はきわめて低いものとなる。   The present invention relates to a method for producing a granular fertilizer composition containing two or more kinds of coated granular fertilizers, and the two or more kinds of granular fertilizer raw materials are mixed or mixed and then coated on the granular fertilizer raw materials. It is characterized by providing. That is, in the manufacturing method of the granular fertilizer composition of this invention, a coating process is performed simultaneously with the mixing process of a granular fertilizer raw material, or after completion | finish of a mixing process. In the manufacturing method of the granular fertilizer composition of this invention, it is not necessary to perform a coating process for every granular fertilizer raw material, and it coat | covers with respect to each granular fertilizer raw material in one coating process. Therefore, the number of necessary processes is small and it is particularly suitable for industrial production. Moreover, in the manufacturing method of the granular fertilizer composition of this invention, since a coating process is performed at the end, even if coated granular fertilizers are rubbed in a mixing process, the probability that a coating defect will arise in a final product will become very low.

なお本発明における「組成物」は均一な混合物を含む概念であり、「粒状肥料組成物」には複数種の粒状肥料の均一な混合物が含まれる。   The “composition” in the present invention is a concept including a uniform mixture, and the “granular fertilizer composition” includes a uniform mixture of a plurality of types of granular fertilizers.

ここで「粒状肥料原料」とは、粒状肥料組成物を構成する被覆粒状肥料の原料として使用され、被覆が設けられる対象となる粒状肥料をいう。被覆が設けられる対象である限り、全ての粒状肥料はそのまま粒状肥料原料となり得る。   Here, the “granular fertilizer raw material” refers to a granular fertilizer that is used as a raw material for the coated granular fertilizer that constitutes the granular fertilizer composition, and to which a coating is provided. All granular fertilizers can be directly used as raw materials for granular fertilizers as long as the coating is provided.

また、本発明では「2種類以上の粒状肥料原料」を用いるが、粒状肥料原料の種類については、肥料成分の違い、量の違い、粒径の違い、等により区別される。本発明で製造される粒状肥料組成物が含有する「2種類以上の被覆粒状肥料」における被覆粒状肥料の種類については、前述した肥料成分の違い、量の違い、粒径の違い等に加えて、被覆の素材の違い、厚さの違い、被覆率の違い、層数の違い(単一層か複数層か)、等により区別される。   In the present invention, “two or more types of granular fertilizer raw materials” are used, and the types of granular fertilizer raw materials are distinguished by differences in fertilizer components, amounts, particle sizes, and the like. About the kind of coated granular fertilizer in "two or more kinds of coated granular fertilizer" which the granular fertilizer composition manufactured by this invention contains, in addition to the difference of the fertilizer component mentioned above, the difference in quantity, the difference in particle size, etc. They are distinguished by differences in coating materials, thicknesses, coverage, differences in the number of layers (single layer or multiple layers), and the like.

請求項2に記載の発明は、粒状肥料原料の少なくとも1種類は、非被覆粒状肥料原料であることを特徴とする請求項1記載の粒状肥料組成物の製造方法である。   The invention according to claim 2 is the method for producing a granular fertilizer composition according to claim 1, wherein at least one of the granular fertilizer raw materials is an uncoated granular fertilizer raw material.

かかる構成により、単一層からなる被覆が設けられた被覆粒状肥料を少なくとも1種類含有する粒状肥料組成物を製造することができる。ここで「非被覆粒状肥料原料」とは、非被覆粒状肥料からなる粒状肥料原料をいう。すなわち、非被覆粒状肥料原料は母核と同義である。   With this configuration, it is possible to produce a granular fertilizer composition containing at least one type of coated granular fertilizer provided with a single layer coating. Here, “uncoated granular fertilizer raw material” refers to a granular fertilizer raw material made of uncoated granular fertilizer. That is, an uncoated granular fertilizer raw material is synonymous with a mother nucleus.

請求項3に記載の発明は、粒状肥料原料の少なくとも1種類は、被覆粒状肥料原料であることを特徴とする請求項1又は2記載の粒状肥料組成物の製造方法である。   The invention according to claim 3 is the method for producing a granular fertilizer composition according to claim 1 or 2, wherein at least one of the granular fertilizer raw materials is a coated granular fertilizer raw material.

かかる構成により、複数層からなる被覆が設けられた被覆粒状肥料を少なくとも1種類含有する粒状肥料組成物を製造することができる。ここで「被覆粒状肥料原料」とは、被覆粒状肥料からなる粒状肥料原料をいう。   With this configuration, a granular fertilizer composition containing at least one type of coated granular fertilizer provided with a coating composed of a plurality of layers can be produced. Here, “coated granular fertilizer raw material” refers to a granular fertilizer raw material made of coated granular fertilizer.

請求項4に記載の発明は、粒状肥料原料の少なくとも2種類が被覆粒状肥料原料であり、当該被覆粒状肥料原料は、被覆の厚さが互いに異なるものであることを特徴とする請求項3記載の粒状肥料組成物の製造方法である。   The invention according to claim 4 is characterized in that at least two kinds of granular fertilizer raw materials are coated granular fertilizer raw materials, and the coated granular fertilizer raw materials have different coating thicknesses. It is a manufacturing method of the granular fertilizer composition.

かかる構成により、被覆の厚さが互いに異なる2種類以上の被覆粒状肥料を含有する粒状肥料組成物を製造することができる。   With this configuration, a granular fertilizer composition containing two or more types of coated granular fertilizers having different coating thicknesses can be produced.

請求項5に記載の発明は、被覆粒状肥料原料が有する被覆の素材と同一の素材からなる被覆を、前記被覆粒状肥料原料に対して設けることを特徴とする請求項3又は4記載の粒状肥料組成物の製造方法である。   Invention of Claim 5 provides the coating which consists of the raw material same as the raw material of the covering which a covering granular fertilizer raw material has with respect to the said covering granular fertilizer raw material, The granular fertilizer of Claim 3 or 4 characterized by the above-mentioned. It is a manufacturing method of a composition.

かかる構成により、同一素材からなる複数層の被覆が設けられた被覆粒状肥料を含有する粒状肥料組成物を製造することができる。   With such a configuration, it is possible to produce a granular fertilizer composition containing a coated granular fertilizer provided with a plurality of coating layers made of the same material.

請求項6に記載の発明は、被覆粒状肥料原料が有する被覆の素材と異なる素材からなる被覆を、前記被覆粒状肥料原料に対して設けることを特徴とする請求項3又は4記載の粒状肥料組成物の製造方法である。   The invention according to claim 6 is a granular fertilizer composition according to claim 3 or 4, characterized in that a coating made of a material different from the coating material of the coated granular fertilizer raw material is provided on the coated granular fertilizer raw material. It is a manufacturing method of a thing.

かかる構成により、互いに異なる素材からなる複数層の被覆が設けられた被覆粒状肥料を含有する粒状肥料組成物を製造することができる。   With such a configuration, a granular fertilizer composition containing a coated granular fertilizer provided with a plurality of layers of coatings made of different materials can be produced.

請求項7に記載の発明は、被覆粒状肥料原料が有する被覆の素材は、熱硬化性樹脂又は熱可塑性樹脂であることを特徴とする請求項3〜6のいずれかに記載の粒状肥料組成物の製造方法である。   The invention according to claim 7 is the granular fertilizer composition according to any one of claims 3 to 6, wherein the coating material of the coated granular fertilizer raw material is a thermosetting resin or a thermoplastic resin. It is a manufacturing method.

また請求項8に記載の発明は、粒状肥料原料に対して設けられる被覆の素材は、熱硬化性樹脂又は熱可塑性樹脂であることを特徴とする請求項1〜7のいずれかに記載の粒状肥料組成物の製造方法である。   The invention according to claim 8 is the granular material according to any one of claims 1 to 7, wherein the coating material provided for the granular fertilizer raw material is a thermosetting resin or a thermoplastic resin. It is a manufacturing method of a fertilizer composition.

かかる構成により、熱硬化性樹脂あるいは熱可塑性樹脂の優れた特性を備えた被覆、さらには熱硬化性樹脂と熱可塑性樹脂の両方の特性が組み合わされた被覆が設けられた被覆粒状肥料を含有する粒状肥料組成物を製造することができる。   With such a structure, it contains a coated granular fertilizer provided with a coating having excellent characteristics of a thermosetting resin or a thermoplastic resin, and further a coating combining the characteristics of both a thermosetting resin and a thermoplastic resin. A granular fertilizer composition can be produced.

熱硬化性樹脂が、ウレタン樹脂、ウレア樹脂、アルキド樹脂、エポキシ樹脂、不飽和ポリエステル樹脂、フェノール樹脂、ウレア・メラミン樹脂、尿素樹脂、及びシリコン樹脂からなる群より選ばれた少なくとも1種のものである構成が推奨される(請求項9)。熱可塑性樹脂が、ポリオレフィン、ポリエステル、ビニル重合物、ジエン系重合物、ポリオレフィン共重合物、及び塩化ビニル共重合物からなる群より選ばれた少なくとも1種のものである構成も推奨される(請求項10)。   The thermosetting resin is at least one selected from the group consisting of urethane resin, urea resin, alkyd resin, epoxy resin, unsaturated polyester resin, phenol resin, urea / melamine resin, urea resin, and silicon resin. A configuration is recommended (claim 9). A configuration in which the thermoplastic resin is at least one selected from the group consisting of polyolefin, polyester, vinyl polymer, diene polymer, polyolefin copolymer, and vinyl chloride copolymer is also recommended. Item 10).

請求項11に記載の発明は、粒状肥料原料の肥料成分は、1種類であることを特徴とする請求項1〜10のいずれかに記載の粒状肥料組成物の製造方法である。   Invention of Claim 11 is a manufacturing method of the granular fertilizer composition in any one of Claims 1-10, wherein the fertilizer component of a granular fertilizer raw material is 1 type.

かかる構成により、肥料成分が1種類で被覆の種類(厚さや素材など)が互いに異なる被覆粒状肥料を含有する粒状肥料組成物を製造することができる。   With such a configuration, it is possible to produce a granular fertilizer composition containing coated granular fertilizers having one type of fertilizer component and different types of coating (thickness, material, etc.).

請求項12に記載の発明は、粒状肥料原料の肥料成分は、2種類以上であることを特徴とする請求項1〜10のいずれかに記載の粒状肥料組成物の製造方法である。   Invention of Claim 12 is a manufacturing method of the granular fertilizer composition in any one of Claims 1-10 characterized by the fertilizer component of a granular fertilizer raw material being 2 or more types.

かかる構成により、肥料成分が異なる2種類以上の被覆粒状肥料を含有する粒状肥料組成物を製造することができる。   With such a configuration, a granular fertilizer composition containing two or more types of coated granular fertilizers having different fertilizer components can be produced.

肥料成分の少なくとも1種類が尿素である構成が推奨される(請求項13)。   A configuration in which at least one of the fertilizer components is urea is recommended (claim 13).

請求項14に記載の発明は、粒状肥料原料に対して被覆を設ける工程を、2回以上繰り返すことを特徴とする請求項1〜13のいずれかに記載の粒状肥料組成物の製造方法である。   Invention of Claim 14 is a manufacturing method of the granular fertilizer composition in any one of Claims 1-13 which repeats the process which provides a coating | cover with respect to a granular fertilizer raw material twice or more. .

かかる構成により、所望の素材や厚さ等からなる複数層の被覆が設けられた被覆粒状肥料を含有する粒状肥料組成物を製造することができる。   With this configuration, it is possible to produce a granular fertilizer composition containing a coated granular fertilizer provided with a plurality of layers of coatings made of a desired material and thickness.

請求項15に記載の発明は、請求項1〜14のいずれかに記載の粒状肥料組成物の製造方法によって得ることができる粒状肥料組成物である。   Invention of Claim 15 is a granular fertilizer composition which can be obtained by the manufacturing method of the granular fertilizer composition in any one of Claims 1-14.

本発明は粒状肥料組成物にかかるものであり、本発明の粒状肥料組成物の製造方法によって得ることができるものである。本発明の粒状肥料組成物においては、被覆欠陥が極めて少ないので、多様な肥効持続期間や溶出パターンを確実に実現することができ、作物に対してより好適に肥料成分を供給することが可能となる。   The present invention relates to a granular fertilizer composition, and can be obtained by the method for producing a granular fertilizer composition of the present invention. In the granular fertilizer composition of the present invention, since there are very few coating defects, various fertilization durations and elution patterns can be reliably realized, and fertilizer components can be more suitably supplied to crops. It becomes.

本発明の粒状肥料組成物によれば、1回の被覆工程で各粒状肥料原料に対してまとめて被覆を設けるので、必要な工程数が少なく、工業生産に特に適している。また被覆工程を最後に行うので、混合工程で被覆粒状肥料同士が擦れても、最終製品において被覆欠陥が生じる確率はきわめて低いものとなる。   According to the granular fertilizer composition of the present invention, since the coating is collectively provided for each granular fertilizer raw material in a single coating process, the number of necessary processes is small and it is particularly suitable for industrial production. Moreover, since the coating process is performed last, even if the coated granular fertilizers are rubbed together in the mixing process, the probability that a coating defect will occur in the final product is extremely low.

本発明の粒状肥料組成物は被覆欠陥が極めて少ないものであるので、多様な肥効持続期間や溶出パターンを確実に実現することができ、作物に対してより好適に肥料成分を供給することが可能となる。   Since the granular fertilizer composition of the present invention has very few coating defects, it can reliably realize various fertilization durations and elution patterns, and more suitably supply fertilizer components to crops. It becomes possible.

以下、本発明を実施するための最良の形態について説明する。
本発明の1つの様相は、2種類以上の被覆粒状肥料を含有する粒状肥料組成物の製造方法であって、2種類以上の粒状肥料原料を混合しながら又は混合した後に、前記粒状肥料原料に対して被覆を設けることを特徴とする粒状肥料組成物の製造方法である。すなわち本発明の粒状肥料組成物の製造方法は、2種類以上の粒状肥料原料を混合する混合工程と、当該粒状肥料原料に対して被覆を設ける被覆工程とを包含するが、混合工程と同時に又は混合工程終了後に被覆工程を行うこと特徴としている。
Hereinafter, the best mode for carrying out the present invention will be described.
One aspect of the present invention is a method for producing a granular fertilizer composition containing two or more types of coated granular fertilizers, and while mixing or mixing two or more types of granular fertilizer raw materials, It is a manufacturing method of the granular fertilizer composition characterized by providing a coating | cover with respect. That is, the method for producing a granular fertilizer composition of the present invention includes a mixing step of mixing two or more types of granular fertilizer raw materials and a coating step of providing a coating on the granular fertilizer raw materials, or simultaneously with the mixing step or The coating step is performed after the mixing step.

混合工程を行うための手法としては、粉流体の混合操作に用いられている公知の手法をそのまま採用することができる。例えば、V型混合機や二重円錐型混合機といった代表的な混合機を用いて、2種類以上の粒状肥料原料を混合すればよい。一方、被覆工程を行うための手法としても、粒状肥料の被覆操作に用いられている公知の手法をそのまま採用することができ、例えば、パンコーティング法、流動コーティング法のいずれもが使用可能である。なお、上記した特許文献3(特開2002−362991号公報)や特開平10−158084号公報に開示されているような、肥料粒子を噴流として流動させながら被覆材を付着乾燥させる噴流方式による手法、特許文献4(特開2005−89258号公報)に開示されているようなコンクリートミキサ型の転動装置による手法、あるいは、特開平9−208355号公報に開示されているような、傾斜パン型転動造粒機を用いて一定の粒径の粒状肥料を攪拌装置自身の回転により転動させながら、樹脂を添加し、粒状肥料の表面上にて樹脂被膜を形成する手法によれば、混合工程と同時に被覆工程を行えるので、本発明の粒状肥料組成物の製造方法を実施するのに好適である。   As a method for performing the mixing step, a known method used for the mixing operation of the powder fluid can be employed as it is. For example, two or more types of granular fertilizer raw materials may be mixed using a typical mixer such as a V-type mixer or a double cone mixer. On the other hand, as a technique for performing the coating process, a known technique used for the coating operation of the granular fertilizer can be employed as it is, and for example, any of a pan coating method and a fluid coating method can be used. . In addition, as disclosed in the above-mentioned Patent Document 3 (Japanese Patent Laid-Open No. 2002-362991) and Japanese Patent Laid-Open No. 10-158084, a method using a jet method in which a coating material is attached and dried while flowing fertilizer particles as a jet. A method using a concrete mixer type rolling device as disclosed in Patent Document 4 (Japanese Patent Laid-Open No. 2005-89258), or an inclined pan type as disclosed in Japanese Patent Laid-Open No. 9-208355. According to the technique of adding resin and forming a resin film on the surface of the granular fertilizer while rolling the granular fertilizer with a constant particle size by the rotation of the stirring device itself using a rolling granulator Since a coating process can be performed simultaneously with a process, it is suitable for implementing the manufacturing method of the granular fertilizer composition of this invention.

被覆工程については1回のみ行ってもよいが、2回以上繰り返して行うこともできる。これにより、複数層からなる被覆を設けることができる。この際、被覆の素材として同一のものを毎回使用すれば、所望の厚みを有する被覆を設けることができる。一方、被覆の素材を途中で変えれば、複数種類の素材からなる被覆を設けることができ、多様な溶出パターン等を発揮させるのに有用である。   The coating process may be performed only once, but may be repeated twice or more. Thereby, the coating consisting of a plurality of layers can be provided. At this time, if the same material is used every time, a coating having a desired thickness can be provided. On the other hand, if the coating material is changed in the middle, a coating made of a plurality of types of materials can be provided, which is useful for exhibiting various elution patterns.

なお、混合工程・被覆工程に供するための粒状肥料原料については一般的な造粒技術により調製すればよく、市販されている被覆粒状肥料や非被覆粒状肥料をそのまま使用してもよい。   In addition, what is necessary is just to prepare with the general granulation technique about the granular fertilizer raw material used for a mixing process and a coating process, and you may use the commercially available coated granular fertilizer and uncoated granular fertilizer as it is.

本発明で用いられる粒状肥料原料は、非被覆粒状肥料原料と被覆粒状肥料原料のいずれでもよい。より具体的には、2種類以上の粒状肥料原料を、非被覆粒状肥料原料のみで構成してもよいし、被覆粒状肥料原料のみで構成してもよい。さらに、非被覆粒状肥料原料と被覆粒状肥料原料の両方を組み合わせて、2種類以上の粒状肥料原料を構成してもよい。   The granular fertilizer raw material used in the present invention may be either an uncoated granular fertilizer raw material or a coated granular fertilizer raw material. More specifically, two or more types of granular fertilizer raw materials may be composed of only uncoated granular fertilizer raw materials, or may be composed of only coated granular fertilizer raw materials. Furthermore, you may comprise two or more types of granular fertilizer raw materials combining both an uncoated granular fertilizer raw material and a coated granular fertilizer raw material.

1つの実施形態では、粒状肥料原料の少なくとも2種類が被覆粒状肥料原料であり、当該被覆粒状肥料原料は、被覆の厚さが互いに異なるものである。例えば、被覆の厚さが互いに異なる2種類以上の被覆粒状肥料原料を用い、これらの被覆粒状肥料原料に対して被覆を設けることにより粒状肥料組成物を製造することができる。本実施形態においては、被覆の厚さに加えて素材等も互いに異なる2種類以上の被覆粒状肥料原料を用いてもよい。   In one embodiment, at least two types of granular fertilizer raw materials are coated granular fertilizer raw materials, and the coated granular fertilizer raw materials have different coating thicknesses. For example, a granular fertilizer composition can be produced by using two or more types of coated granular fertilizer raw materials having different coating thicknesses and providing a coating on these coated granular fertilizer raw materials. In the present embodiment, two or more kinds of coated granular fertilizer raw materials that are different from each other in addition to the thickness of the coating may be used.

粒状肥料原料として被覆粒状肥料原料を採用する実施形態においては、被覆粒状肥料原料が有する被覆の素材と同一の素材からなる被覆を、被覆粒状肥料原料に対して設けることができる。この実施形態では、同一の素材からなる複数層の被覆が設けられた粒状肥料組成物を製造することができる。また逆に、被覆粒状肥料原料が有する被覆の素材と異なる素材からなる被覆を、被覆粒状肥料原料に対して設けてもよい。   In the embodiment in which the coated granular fertilizer raw material is employed as the granular fertilizer raw material, a coating made of the same material as the coating material of the coated granular fertilizer raw material can be provided on the coated granular fertilizer raw material. In this embodiment, a granular fertilizer composition provided with a plurality of layers of the same material can be produced. Conversely, a coating made of a material different from the coating material of the coated granular fertilizer material may be provided for the coated granular fertilizer material.

用いる被覆粒状肥料原料が有する被覆や、粒状肥料原料に対して設ける被覆の素材については特に限定はないが、好ましくは熱硬化性樹脂あるいは熱可塑性樹脂である。すなわち、熱硬化性樹脂や熱可塑性樹脂が有する特性を考慮し、これらを適宜組み合わせることで所望の溶出パターン等を発揮する粒状肥料組成物を製造することができる。   There is no particular limitation on the coating of the coated granular fertilizer raw material to be used or the coating material provided on the granular fertilizer raw material, but a thermosetting resin or a thermoplastic resin is preferable. That is, in consideration of the properties of thermosetting resins and thermoplastic resins, a granular fertilizer composition that exhibits a desired elution pattern or the like can be produced by appropriately combining them.

熱硬化性樹脂としては特に限定はなく、公知の熱硬化性樹脂をそのまま採用することができる。熱硬化性樹脂の例としては、ウレタン樹脂、ウレア樹脂、アルキド樹脂、エポキシ樹脂、不飽和ポリエステル樹脂、フェノール樹脂、ウレア・メラミン樹脂、尿素樹脂、シリコン樹脂等が挙げられる。なお、熱硬化性樹脂については1種のみを用いてもよいし、2種以上を組み合わせて用いてもよい。   There is no limitation in particular as a thermosetting resin, A well-known thermosetting resin can be employ | adopted as it is. Examples of thermosetting resins include urethane resins, urea resins, alkyd resins, epoxy resins, unsaturated polyester resins, phenol resins, urea / melamine resins, urea resins, silicone resins, and the like. In addition, about a thermosetting resin, only 1 type may be used and it may be used in combination of 2 or more type.

熱可塑性樹脂としては特に限定はなく、公知の熱可塑性樹脂をそのまま採用することができる。熱可塑性樹脂の例としては、ポリエチレン、ポリプロピレン、ポリブテン、ポリスチレンなどのポリオレフィン;熱可塑性ポリエステル等のポリエステル;ポリ酢酸ビニル、ポリ塩化ビニル、ポリ塩化ビニリデン、ポリアクリル酸、ポリメタアクリル酸、ポリアクリル酸エステル、ポリメタクリル酸エステルなどのビニル重合物;ブタジエン重合物、イソプレン重合物、クロロプレン重合物、ブタジエン−スチレン共重合物、エチレン−プロピレン−ジエン共重合物、スチレン−イソプレン共重合物などのジエン系重合物;エチレン−プロピレン共重合物、ブテン−エチレン共重合物、ブテン−プロピレン共重合物、エチレン−酢酸ビニル共重合物、エチレン−アクリル酸共重合物、エチレン−メタアクリル酸共重合物、エチレン−メタアクリル酸エステル共重合物、エチレン−一酸化炭素共重合物、エチレン−酢酸ビニル−一酸化炭素共重合物などのポリオレフィン共重合物;塩化ビニル−ビニルアセテート共重合物、塩化ビニリデン−塩化ビニル共重合物などの塩化ビニル共重合物、等が挙げられる。なお、熱可塑性樹脂については1種のみを用いてもよいし、2種以上を組み合わせて用いてもよい。   There is no limitation in particular as a thermoplastic resin, A well-known thermoplastic resin can be employ | adopted as it is. Examples of thermoplastic resins include polyolefins such as polyethylene, polypropylene, polybutene and polystyrene; polyesters such as thermoplastic polyesters; polyvinyl acetate, polyvinyl chloride, polyvinylidene chloride, polyacrylic acid, polymethacrylic acid, polyacrylic acid Vinyl polymers such as esters and polymethacrylates; butadiene polymers, isoprene polymers, chloroprene polymers, butadiene-styrene copolymers, ethylene-propylene-diene copolymers, diene systems such as styrene-isoprene copolymers Polymer: ethylene-propylene copolymer, butene-ethylene copolymer, butene-propylene copolymer, ethylene-vinyl acetate copolymer, ethylene-acrylic acid copolymer, ethylene-methacrylic acid copolymer, ethylene -Metaact Polyolefin copolymers such as oxalate copolymer, ethylene-carbon monoxide copolymer, ethylene-vinyl acetate-carbon monoxide copolymer; vinyl chloride-vinyl acetate copolymer, vinylidene chloride-vinyl chloride copolymer And vinyl chloride copolymers such as products. In addition, about a thermoplastic resin, only 1 type may be used and it may be used in combination of 2 or more type.

用いる粒状肥料原料の肥料成分は、1種類のみでもよいし、2種類以上でもよい。肥料成分としては特に限定はなく、一般に用いられている成分をそのまま採用できるが、主として窒素成分を含有するものが好ましく採用される。窒素成分を含有する肥料成分の具体例としては、尿素、硝酸アンモニウム、硝酸苦土アンモニウム、塩化アンモニウム、硫酸アンモニウム、リン酸アンモニウム、硝酸ソーダ、硝酸カルシウム、硝酸カリウム、石灰窒素、ホルムアルデヒド加工尿素肥料(UF)、アセトアルデヒド加工尿素肥料(CDU)、イソブチルアルデヒド加工尿素肥料(IBDU)、グアニール尿素(GU)等が挙げられるが、尿素が特に好ましく採用される。   Only one type of fertilizer component of the granular fertilizer raw material to be used may be used, or two or more types may be used. The fertilizer component is not particularly limited, and commonly used components can be employed as they are, but those mainly containing nitrogen components are preferably employed. Specific examples of fertilizer components containing a nitrogen component include urea, ammonium nitrate, ammonium nitrate, ammonium chloride, ammonium sulfate, ammonium phosphate, sodium nitrate, calcium nitrate, potassium nitrate, lime nitrogen, formaldehyde processed urea fertilizer (UF), Examples include acetaldehyde-processed urea fertilizer (CDU), isobutyraldehyde-processed urea fertilizer (IBDU), guanine urea (GU), and urea is particularly preferably employed.

窒素成分以外の肥料成分の例としては、リン酸、カリウム、珪酸、マグネシウム、カルシウム、マンガン、ホウ素、鉄等が挙げられる。具体的には、過リン酸石灰、重過リン酸石灰、苦土過リン酸、苦土リン酸、硫リン安、リン硝安カリウム、塩リン安等のリン酸質肥料;塩化カリウム、硫酸カリウム、硫酸カリソーダ、硫酸カリ苦土、重炭酸カリウム、リン酸カリウム等のカリウム質肥料;珪酸カルシウム等の珪酸質肥料;硫酸マグネシウム、塩化マグネシウム等のマグネシウム質肥料;生石灰、消石灰、炭酸カルシウム等のカルシウム質肥料;硫酸マンガン、硫酸苦土マンガン、鉱さいマンガン等のマンガン質肥料;ホウ酸、ホウ酸塩等のホウ素質肥料;鉄鋼スラグ等の含鉄肥料等の肥料取締法に定められる普通肥料(複合肥料を含む)、が挙げられる。   Examples of fertilizer components other than the nitrogen component include phosphoric acid, potassium, silicic acid, magnesium, calcium, manganese, boron, iron and the like. Specifically, phosphate fertilizers such as superphosphate lime, heavy superphosphate, bitumen superphosphate, bitter phosphate, ammonium sulfate, potassium phosphate ammonium, ammonium phosphate phosphate; potassium chloride, potassium sulfate , Potassium fertilizer such as potassium sulfate, potassium sulfate, potassium bicarbonate and potassium phosphate; siliceous fertilizer such as calcium silicate; magnesium fertilizer such as magnesium sulfate and magnesium chloride; calcium such as quick lime, slaked lime and calcium carbonate Fertilizers; Manganese fertilizers such as manganese sulfate, sulfated sulfated manganese, and slag manganese; Boron fertilizers such as boric acid and borate; Including).

本発明の粒状肥料組成物の製造方法において、粒状肥料原料に対して設ける被覆の量については、製造される粒状肥料組成物が所望の肥効を発揮できる量であれば特に限定はないが、例えば、最終的な被覆の量(粒状肥料原料が有する被覆の量と、被覆工程で設けられる被覆の量の和)が母核の量に対して2〜20重量%、より特定すれば5〜16重量%の範囲内となるように設ければよい。なお一般に、被覆の量が少なすぎると被覆の厚みを均一に保つのが困難となり、被覆欠陥を生じる懸念が増大する。一方、被覆の量が多すぎると肥料成分の量が相対的に減少するので、必要な施肥量が増して有益ではない。   In the method for producing a granular fertilizer composition of the present invention, the amount of coating provided on the granular fertilizer raw material is not particularly limited as long as the produced granular fertilizer composition can exhibit a desired fertilization effect, For example, if the final coating amount (the sum of the coating amount of the granular fertilizer raw material and the coating amount provided in the coating step) is 2 to 20% by weight relative to the amount of the mother nucleus, more specifically 5 What is necessary is just to provide so that it may exist in the range of 16 weight%. In general, if the amount of coating is too small, it is difficult to keep the coating thickness uniform, increasing the risk of causing coating defects. On the other hand, if the amount of the coating is too large, the amount of the fertilizer component is relatively decreased.

本発明の粒状肥料組成物の製造方法において、混合工程および被覆工程に供される粒状肥料原料の平均粒径としては特に限定はなく、例えば、被覆粒状肥料の最終的な平均粒径が1〜10mm、より特定すれば1〜5mmの範囲内となるように選択すればよい。粒状肥料原料の粒径を選択する基準の1つの例として、混合工程および被覆工程で2種類以上の粒状肥料原料が均一に混合および被覆される粒径であることが挙げられる。   In the method for producing a granular fertilizer composition of the present invention, the average particle size of the granular fertilizer raw material used in the mixing step and the coating step is not particularly limited. For example, the final average particle size of the coated granular fertilizer is 1 to What is necessary is just to select so that it may become in the range of 1-5 mm, more specifically 10 mm. One example of a criterion for selecting the particle size of the granular fertilizer raw material is a particle size at which two or more types of granular fertilizer raw materials are uniformly mixed and coated in the mixing step and the coating step.

本発明の粒状肥料組成物の製造方法では、さらに各種の添加剤等を含有する粒状肥料組成物を製造することができる。当該添加剤の例としては、タルク、炭酸カルシウム、金属酸化物等の無機質粉末;耐候性改良剤;着色剤;結合剤;界面活性剤、等が挙げられる。これらの添加剤等は、粒状肥料原料の母核、被覆粒状肥料原料が有する被覆、被覆工程で設ける被覆のいずれに含有させてもよく、具体的には、造粒工程、混合工程、被覆工程のいずれの工程で添加してもよい。   In the method for producing a granular fertilizer composition of the present invention, a granular fertilizer composition further containing various additives and the like can be produced. Examples of the additive include inorganic powders such as talc, calcium carbonate, and metal oxides; weather resistance improvers; colorants; binders, surfactants, and the like. These additives and the like may be contained in any of the mother core of the granular fertilizer raw material, the coating of the coated granular fertilizer raw material, and the coating provided in the coating step. Specifically, the granulation step, the mixing step, the coating step You may add at any of these processes.

本発明の粒状肥料組成物の製造方法では、さらに作物の生育以外の効果に関係する成分、例えば、殺虫剤、除草剤、殺菌剤、植物生長調整剤等の生理活性物質、有機質肥料、等を含有する粒状肥料組成物を製造することもできる。これらの成分についても、粒状肥料原料の母核、被覆粒状肥料原料が有する被覆、被覆工程で設ける被覆のいずれに含有させてもよく、具体的には、造粒工程、混合工程、被覆工程のいずれの工程で添加してもよい。   In the method for producing a granular fertilizer composition of the present invention, further components related to effects other than the growth of crops, for example, bioactive substances such as insecticides, herbicides, fungicides, plant growth regulators, organic fertilizers, etc. The granular fertilizer composition to contain can also be manufactured. These components may also be included in any of the parent of the granular fertilizer raw material, the coating of the coated granular fertilizer raw material, and the coating provided in the coating step. Specifically, the granulation step, the mixing step, and the coating step You may add in any process.

以下に、本発明の粒状肥料組成物の製造方法によって製造可能な粒状肥料組成物の具体的構成について、粒状肥料原料の種類、被覆粒状肥料原料が有する被覆の種類、及び被覆工程で設ける被覆の種類の組み合わせと対比させながら説明する。以下の例において、a,b,cは粒状肥料原料の母核の種類、A,Bは被覆の種類を指すものとする。また、母核aの表面に被覆A(単一層)が設けられた被覆粒状肥料または被覆粒状肥料原料を「a/A」、母核aの表面に被覆Aが2重に設けられた被覆粒状肥料または被覆粒状肥料原料を「a/AA」、母核aの表面に被覆Aが3重に設けられた被覆粒状肥料または被覆粒状肥料原料を「a/AAA」、母核aの表面に被覆A、当該被覆Aの表面(最表面)に被覆Bが設けられた被覆粒状肥料または被覆粒状肥料原料を「a/AB」のように表す。単なる「a」は母核aのみからなる非被覆粒状肥料原料を表す。   Below, about the specific composition of the granular fertilizer composition which can be manufactured by the manufacturing method of the granular fertilizer composition of the present invention, the type of granular fertilizer raw material, the type of coating of the coated granular fertilizer raw material, and the coating provided in the coating step The explanation will be made in comparison with the combination of types. In the following examples, a, b, and c indicate the type of mother nucleus of the granular fertilizer material, and A and B indicate the type of coating. Further, the coated granular fertilizer or the coated granular fertilizer raw material provided with the coating A (single layer) on the surface of the mother nucleus a is “a / A”, and the coated granules in which the coating A is provided on the surface of the mother nucleus a. "A / AA" for fertilizer or coated granular fertilizer raw material, "a / AAA" for coated granular fertilizer or coated granular fertilizer raw material with three coatings A on the surface of mother nucleus a, coated on the surface of mother nucleus a A, a coated granular fertilizer or a coated granular fertilizer raw material in which a coating B is provided on the surface (outermost surface) of the coating A is expressed as “a / AB”. Simply “a” represents an uncoated granular fertilizer raw material consisting only of the mother nucleus a.

〔例1〕
粒状肥料原料として「a」(非被覆粒状肥料原料)、並びに、「a/A」、「a/AA」及び「a/AAA」(いずれも被覆粒状肥料原料)の4種類を選択する。これらの粒状肥料原料に対して被覆Aを設けると、「a/A」、「a/AA」、「a/AAA」及び「a/AAAA」の4種類の被覆粒状肥料を含有する粒状肥料組成物を製造することができる。
この例は、粒状肥料原料の少なくとも2種類が被覆粒状肥料原料であり(「a/A」、「a/AA」及び「a/AAA」)、当該被覆粒状肥料原料は、被覆の厚さが互いに異なるものである実施形態に相当する。
[Example 1]
As the granular fertilizer raw material, four types of “a” (uncoated granular fertilizer raw material) and “a / A”, “a / AA”, and “a / AAA” (all coated granular fertilizer raw materials) are selected. When coating A is applied to these granular fertilizer raw materials, a granular fertilizer composition containing four types of coated granular fertilizers “a / A”, “a / AA”, “a / AAA”, and “a / AAAAA” Can be manufactured.
In this example, at least two types of granular fertilizer raw materials are coated granular fertilizer raw materials (“a / A”, “a / AA” and “a / AAA”), and the coated granular fertilizer raw material has a coating thickness of This corresponds to an embodiment that is different from each other.

なお、この例の粒状肥料組成物を従来の方法で製造する場合には、被覆工程の回数が多くなり煩雑である。すなわち従来の方法では、母核「a」に被覆Aを設けて「a/A」、「a/AA」、「a/AAA」及び「a/AAAA」の4種類の被覆粒状肥料を個別に調製し、これらを最後に混合する。このときに必要とされる被覆工程の回数は、
「a」→「a/A」:1回
「a」→「a/AA」:2回
「a」→「a/AAA」:3回
「a」→「a/AAAA」:4回
であり、計10回となる。実生産において、1回の被覆工程で被覆率1%の被覆を設けるような工程を組み、被覆Aの被覆率を2%に設定すると、必要な回数は2倍の20回となる。
一方、この例に示した方法では、各粒状肥料原料の調製に必要な被覆工程の回数は、
「a」:0回
「a」→「a/A」:1回
「a」→「a/AA」:2回
「a」→「a/AAA」:3回
であり、これらを混合しながら又は混合した後に、最終の被覆工程を1回行う。その結果、被覆工程の回数は計7回となり、従来の方法(10回)と比較して回数が少なくて済む。上述した条件の実生産を行う場合には被覆工程の回数が計14回となり、従来の方法(20回)との回数の差はさらに大きくなる。
In addition, when manufacturing the granular fertilizer composition of this example by the conventional method, the frequency | count of a coating process increases and is complicated. That is, in the conventional method, the coating A is provided on the mother core “a”, and four types of coated granular fertilizers “a / A”, “a / AA”, “a / AAA”, and “a / AAAAA” are individually provided. Prepare and mix them last. The number of coating steps required at this time is
“A” → “a / A”: once “a” → “a / AA”: twice “a” → “a / AAA”: three times “a” → “a / AAAAA”: four times A total of 10 times. In actual production, if a process of providing a coating with a coverage of 1% in one coating process is combined and the coverage of coating A is set to 2%, the required number of times is doubled to 20 times.
On the other hand, in the method shown in this example, the number of coating steps necessary to prepare each granular fertilizer raw material is
“A”: 0 times “a” → “a / A”: 1 time “a” → “a / AA”: 2 times “a” → “a / AAA”: 3 times, while mixing these Or, after mixing, the final coating process is performed once. As a result, the total number of coating steps is 7, which is less than the conventional method (10 times). When actual production is performed under the above-described conditions, the number of coating steps is 14 in total, and the difference in the number of times with the conventional method (20 times) is further increased.

〔例2〕
粒状肥料原料として「a/A」と「a/B」の2種類の被覆粒状肥料原料を選択する。これらの粒状肥料原料に対して被覆Bを設けると、「a/AB」と「a/BB」の2種類の被覆粒状肥料を含有する粒状肥料組成物を製造することができる。
なお、「a/AB」は被覆粒状肥料原料が有する被覆(A)の素材と異なる素材からなる被覆(B)を、被覆粒状肥料原料に対して設けたものに相当する。「a/BB」は被覆粒状肥料原料が有する被覆(B)の素材と同一の素材からなる被覆(B)を、被覆粒状肥料原料に対して設けたものに相当する。
[Example 2]
Two types of coated granular fertilizer raw materials “a / A” and “a / B” are selected as granular fertilizer raw materials. When coating B is provided for these granular fertilizer raw materials, a granular fertilizer composition containing two types of coated granular fertilizers “a / AB” and “a / BB” can be produced.
Note that “a / AB” corresponds to a coating (B) made of a material different from the material of the coating (A) of the coated granular fertilizer material provided on the coated granular fertilizer material. “A / BB” corresponds to a coating (B) made of the same material as the coating (B) of the coated granular fertilizer material, provided on the coated granular fertilizer material.

〔例3〕
粒状肥料原料として「a/A」、「b/A」及び「c/A」の3種類の被覆粒状肥料原料を選択する。これらの粒状肥料原料に対して被覆Aを設けると、「a/AA」、「b/AA」及び「c/AA」の3種類の被覆粒状肥料を含有する粒状肥料組成物を製造することができる。
母核a,b,cが互いに肥料成分が異なるものであれば、この例は粒状肥料原料の肥料成分が2種類以上である実施形態に相当する。
[Example 3]
Three types of coated granular fertilizer raw materials “a / A”, “b / A”, and “c / A” are selected as the granular fertilizer raw materials. When coating A is provided for these granular fertilizer raw materials, a granular fertilizer composition containing three types of coated granular fertilizers “a / AA”, “b / AA”, and “c / AA” can be produced. it can.
If the mother cores a, b, and c have different fertilizer components, this example corresponds to an embodiment in which there are two or more fertilizer components of the granular fertilizer raw material.

〔例4〕
粒状肥料原料として「a」、「b」及び「c」の3種類の非被覆粒状肥料原料を選択する。これらの粒状肥料原料に対して被覆Aを設けると、「a/A」、「b/A」及び「c/A」の3種類の被覆粒状肥料を含有する粒状肥料組成物を製造することができる。
母核(非被覆粒状肥料原料)a,b,cが互いに肥料成分が異なるものであれば、この例は粒状肥料原料の肥料成分が2種類以上である実施形態に相当する。
[Example 4]
Three types of uncoated granular fertilizer raw materials “a”, “b”, and “c” are selected as the granular fertilizer raw materials. When coating A is provided for these granular fertilizer raw materials, a granular fertilizer composition containing three types of coated granular fertilizers “a / A”, “b / A”, and “c / A” can be produced. it can.
If the mother cores (uncoated granular fertilizer raw materials) a, b, and c have different fertilizer components, this example corresponds to an embodiment in which the fertilizer components of the granular fertilizer raw material are two or more.

〔例5〕
粒状肥料原料として「a/A」、「b/A」及び「c/A」の3種類の被覆粒状肥料原料を選択する。これらの粒状肥料原料に対して被覆Bを設けると、「a/AB」、「b/AB」及び「c/AB」の3種類の被覆粒状肥料を含有する粒状肥料組成物を製造することができる。
母核a,b,cが互いに肥料成分が異なるものであれば、この例は粒状肥料原料の肥料成分が2種類以上である実施形態に相当する。
また「a/AB」、「b/AB」及び「c/AB」はいずれも被覆粒状肥料原料が有する被覆(A)の素材と異なる素材からなる被覆(B)を、被覆粒状肥料原料に対して設けたものに相当する。
[Example 5]
Three types of coated granular fertilizer raw materials “a / A”, “b / A”, and “c / A” are selected as the granular fertilizer raw materials. When coating B is provided for these granular fertilizer raw materials, a granular fertilizer composition containing three types of coated granular fertilizers “a / AB”, “b / AB”, and “c / AB” can be produced. it can.
If the mother cores a, b, and c have different fertilizer components, this example corresponds to an embodiment in which there are two or more fertilizer components of the granular fertilizer raw material.
In addition, “a / AB”, “b / AB”, and “c / AB” are all coated with a coating (B) made of a material different from the coating (A) of the coated granular fertilizer material. It corresponds to what was provided.

〔例6〕
粒状肥料原料として「a」(非被覆粒状肥料原料)、並びに、「b/A」及び「c/AA」(いずれも被覆粒状肥料原料)の3種類を選択する。これらの粒状肥料原料に対して被覆Aを設けると、「a/A」、「b/AA」及び「c/AAA」の3種類の被覆粒状肥料を含有する粒状肥料組成物を製造することができる。
この例は、粒状肥料原料の少なくとも2種類が被覆粒状肥料原料であり(「a/A」と「a/AA」)、当該被覆粒状肥料原料は、被覆の厚さが互いに異なるものである実施形態に相当する。
また母核a,b,cが互いに肥料成分が異なるものであれば、この例は粒状肥料原料の肥料成分が2種類以上である実施形態に相当する。
[Example 6]
Three types of “a” (uncoated granular fertilizer raw material) and “b / A” and “c / AA” (all coated granular fertilizer raw materials) are selected as the granular fertilizer raw material. When coating A is provided for these granular fertilizer raw materials, a granular fertilizer composition containing three types of coated granular fertilizers “a / A”, “b / AA”, and “c / AAA” can be produced. it can.
In this example, at least two types of granular fertilizer raw materials are coated granular fertilizer raw materials (“a / A” and “a / AA”), and the coated granular fertilizer raw materials have different coating thicknesses. Corresponds to form.
If the mother nuclei a, b, c are different from each other in fertilizer components, this example corresponds to an embodiment in which the fertilizer components of the granular fertilizer raw material are two or more types.

〔例7〕
粒状肥料原料として「a」(非被覆粒状肥料原料)、並びに、「b/A」及び「c/AA」(いずれも被覆粒状肥料原料)の3種類を選択する。これらの粒状肥料原料に対して被覆Bを設けると、「a/B」、「b/AB」及び「c/AAB」の3種類の被覆粒状肥料を含有する粒状肥料組成物を製造することができる。
また母核a,b,cが互いに肥料成分が異なるものであれば、この例は粒状肥料原料の肥料成分が2種類以上である実施形態に相当する。
また、「b/AB」と「c/AAB」はいずれも被覆粒状肥料原料が有する被覆(A)の素材と異なる素材からなる被覆(B)を、被覆粒状肥料原料に対して設けたものに相当する。
[Example 7]
Three types of “a” (uncoated granular fertilizer raw material) and “b / A” and “c / AA” (all coated granular fertilizer raw materials) are selected as the granular fertilizer raw material. When coating B is provided for these granular fertilizer raw materials, a granular fertilizer composition containing three types of coated granular fertilizers “a / B”, “b / AB”, and “c / AAB” can be produced. it can.
If the mother nuclei a, b, c are different from each other in fertilizer components, this example corresponds to an embodiment in which the fertilizer components of the granular fertilizer raw material are two or more types.
In addition, “b / AB” and “c / AAB” are both provided with a coating (B) made of a material different from the material of the coating (A) of the coated granular fertilizer material on the coated granular fertilizer material. Equivalent to.

本発明の他の様相は、上述した本発明の粒状肥料組成物の製造方法によって得ることができる粒状肥料組成物である。本発明の粒状肥料組成物については、上述した本発明の粒状肥料組成物の製造方法にかかる実施形態と同じ構成をもって具体的に実施することができる。   The other aspect of this invention is the granular fertilizer composition which can be obtained with the manufacturing method of the granular fertilizer composition of this invention mentioned above. About the granular fertilizer composition of this invention, it can specifically carry out with the same structure as embodiment concerning the manufacturing method of the granular fertilizer composition of this invention mentioned above.

Claims (15)

2種類以上の被覆粒状肥料を含有する粒状肥料組成物の製造方法であって、2種類以上の粒状肥料原料を混合しながら又は混合した後に、前記粒状肥料原料に対して被覆を設けることを特徴とする粒状肥料組成物の製造方法。   A method for producing a granular fertilizer composition comprising two or more kinds of coated granular fertilizers, wherein two or more kinds of granular fertilizer raw materials are mixed or after mixing, and the granular fertilizer raw materials are provided with a coating. A method for producing a granular fertilizer composition. 粒状肥料原料の少なくとも1種類は、非被覆粒状肥料原料であることを特徴とする請求項1記載の粒状肥料組成物の製造方法。   The method for producing a granular fertilizer composition according to claim 1, wherein at least one of the granular fertilizer raw materials is an uncoated granular fertilizer raw material. 粒状肥料原料の少なくとも1種類は、被覆粒状肥料原料であることを特徴とする請求項1又は2記載の粒状肥料組成物の製造方法。   The method for producing a granular fertilizer composition according to claim 1 or 2, wherein at least one kind of the granular fertilizer raw material is a coated granular fertilizer raw material. 粒状肥料原料の少なくとも2種類が被覆粒状肥料原料であり、当該被覆粒状肥料原料は、被覆の厚さが互いに異なるものであることを特徴とする請求項3記載の粒状肥料組成物の製造方法。   The method for producing a granular fertilizer composition according to claim 3, wherein at least two kinds of granular fertilizer raw materials are coated granular fertilizer raw materials, and the coated granular fertilizer raw materials have different coating thicknesses. 被覆粒状肥料原料が有する被覆の素材と同一の素材からなる被覆を、前記被覆粒状肥料原料に対して設けることを特徴とする請求項3又は4記載の粒状肥料組成物の製造方法。   The method for producing a granular fertilizer composition according to claim 3 or 4, wherein a coating made of the same material as the coating material of the coated granular fertilizer material is provided on the coated granular fertilizer material. 被覆粒状肥料原料が有する被覆の素材と異なる素材からなる被覆を、前記被覆粒状肥料原料に対して設けることを特徴とする請求項3又は4記載の粒状肥料組成物の製造方法。   5. The method for producing a granular fertilizer composition according to claim 3, wherein a coating made of a material different from the coating material of the coated granular fertilizer raw material is provided on the coated granular fertilizer raw material. 被覆粒状肥料原料が有する被覆の素材は、熱硬化性樹脂又は熱可塑性樹脂であることを特徴とする請求項3〜6のいずれかに記載の粒状肥料組成物の製造方法。   The method for producing a granular fertilizer composition according to any one of claims 3 to 6, wherein the coated raw material of the coated granular fertilizer raw material is a thermosetting resin or a thermoplastic resin. 粒状肥料原料に対して設けられる被覆の素材は、熱硬化性樹脂又は熱可塑性樹脂であることを特徴とする請求項1〜7のいずれかに記載の粒状肥料組成物の製造方法。   The method for producing a granular fertilizer composition according to any one of claims 1 to 7, wherein the coating material provided for the granular fertilizer raw material is a thermosetting resin or a thermoplastic resin. 熱硬化性樹脂は、ウレタン樹脂、ウレア樹脂、アルキド樹脂、エポキシ樹脂、不飽和ポリエステル樹脂、フェノール樹脂、ウレア・メラミン樹脂、尿素樹脂、及びシリコン樹脂からなる群より選ばれた少なくとも1種のものであることを特徴とする請求項7又は8記載の粒状肥料組成物の製造方法。   The thermosetting resin is at least one selected from the group consisting of urethane resin, urea resin, alkyd resin, epoxy resin, unsaturated polyester resin, phenol resin, urea / melamine resin, urea resin, and silicon resin. The method for producing a granular fertilizer composition according to claim 7 or 8, wherein the composition is present. 熱可塑性樹脂は、ポリオレフィン、ポリエステル、ビニル重合物、ジエン系重合物、ポリオレフィン共重合物、及び塩化ビニル共重合物からなる群より選ばれた少なくとも1種のものであることを特徴とする請求項7又は8記載の粒状肥料組成物の製造方法。   The thermoplastic resin is at least one selected from the group consisting of polyolefin, polyester, vinyl polymer, diene polymer, polyolefin copolymer, and vinyl chloride copolymer. The manufacturing method of the granular fertilizer composition of 7 or 8. 粒状肥料原料の肥料成分は、1種類であることを特徴とする請求項1〜10のいずれかに記載の粒状肥料組成物の製造方法。   The fertilizer component of a granular fertilizer raw material is one type, The manufacturing method of the granular fertilizer composition in any one of Claims 1-10 characterized by the above-mentioned. 粒状肥料原料の肥料成分は、2種類以上であることを特徴とする請求項1〜10のいずれかに記載の粒状肥料組成物の製造方法。   The fertilizer component of a granular fertilizer raw material is 2 or more types, The manufacturing method of the granular fertilizer composition in any one of Claims 1-10 characterized by the above-mentioned. 肥料成分の少なくとも1種類は、尿素であることを特徴とする請求項11又は12記載の粒状肥料組成物の製造方法。   The method for producing a granular fertilizer composition according to claim 11 or 12, wherein at least one of the fertilizer components is urea. 粒状肥料原料に対して被覆を設ける工程を、2回以上繰り返すことを特徴とする請求項1〜13のいずれかに記載の粒状肥料組成物の製造方法。   The method for producing a granular fertilizer composition according to any one of claims 1 to 13, wherein the step of providing a coating on the granular fertilizer raw material is repeated twice or more. 請求項1〜14のいずれかに記載の粒状肥料組成物の製造方法によって得ることができる粒状肥料組成物。   The granular fertilizer composition which can be obtained by the manufacturing method of the granular fertilizer composition in any one of Claims 1-14.
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CN103044169A (en) * 2012-05-15 2013-04-17 山东农业大学 Controlled release fertilizer using unsaturated polyester resin to cover film and production method thereof
CN104072295A (en) * 2014-07-08 2014-10-01 句容谷歌庄园现代农业科技发展有限公司 Special fertilizer for sago cycas, and preparation method and application thereof
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JP2012020899A (en) * 2010-07-14 2012-02-02 Sumika Agrotech Co Ltd Mixed fertilizer and method of fertilization
CN103044169A (en) * 2012-05-15 2013-04-17 山东农业大学 Controlled release fertilizer using unsaturated polyester resin to cover film and production method thereof
CN103044169B (en) * 2012-05-15 2014-05-14 山东农业大学 Controlled release fertilizer using unsaturated polyester resin to cover film and production method thereof
CN104072295A (en) * 2014-07-08 2014-10-01 句容谷歌庄园现代农业科技发展有限公司 Special fertilizer for sago cycas, and preparation method and application thereof
JP2019170179A (en) * 2018-03-27 2019-10-10 島根県 Seedling raising method
JP7271863B2 (en) 2018-03-27 2023-05-12 島根県 Seedling method

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