JP2008208089A - Skin cleaner - Google Patents
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- JP2008208089A JP2008208089A JP2007048082A JP2007048082A JP2008208089A JP 2008208089 A JP2008208089 A JP 2008208089A JP 2007048082 A JP2007048082 A JP 2007048082A JP 2007048082 A JP2007048082 A JP 2007048082A JP 2008208089 A JP2008208089 A JP 2008208089A
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Abstract
Description
本発明は手洗い等に使用される皮膚用洗浄剤に関するものである。 The present invention relates to a skin cleanser used for hand washing and the like.
従来から手洗い等に使用される洗浄剤としては、界面活性剤水溶液に水不溶性粒子を分散させた組成物が提供されている。
上記水不溶性粒子としてはシラスバルーン等の軽量粒子が使用されている。
上記水不溶性粒子は界面活性剤の洗浄力に加えて擦過性を付与して落ちにくい汚れを研磨することによって落とす役目を有する。
上記水不溶性粒子は界面活性剤水溶液中に安定に分散されなければならない。そのために分散安定剤としてCMC等の水溶性高分子が添加されている。
Conventionally, as a cleaning agent used for hand washing, a composition in which water-insoluble particles are dispersed in an aqueous surfactant solution is provided.
Light-weight particles such as shirasu balloons are used as the water-insoluble particles.
In addition to the detergency of the surfactant, the water-insoluble particles have a role of removing scratches by polishing dirt that is difficult to remove.
The water-insoluble particles must be stably dispersed in the aqueous surfactant solution. For this purpose, a water-soluble polymer such as CMC is added as a dispersion stabilizer.
上記水不溶性粒子は排水管等に詰りを生じさせないためには、水に浮く軽量なものであることが望ましい。しかし従来の水溶性高分子では分散安定性が充分でなく、水不溶性粒子が浮上分離して来るおそれがあり、該粒子の浮上分離を防ぐために多量添加すると、洗浄剤の展延性が劣り、また皮張りが生ずると云う問題点があった。 The water-insoluble particles are desirably light-weight particles that float on water so as not to cause clogging in the drain pipe or the like. However, conventional water-soluble polymers have insufficient dispersion stability, and there is a possibility that water-insoluble particles may float and separate. When added in a large amount to prevent the particles from floating and separating, the spreadability of the cleaning agent is inferior. There was a problem that skinning occurred.
本発明は上記従来の課題を解決するための手段として、界面活性剤と、油除去剤と、アクリル酸−メタクリル酸共重合体とを含有する水溶液に水浮上性無機中空体粒子を分散させた皮膚用洗浄剤を提供するものである。
上記洗浄剤にあっては、上記界面活性剤5〜20質量%、上記油除去剤5〜15質量%、上記アクリル酸−メタクリル酸共重合体0.1〜0.5質量%、上記水浮上性無機中空体粒子3〜15質量%が含有されることが望ましい。
In the present invention, as a means for solving the above-described conventional problems, water-floating inorganic hollow particles are dispersed in an aqueous solution containing a surfactant, an oil removing agent, and an acrylic acid-methacrylic acid copolymer. A skin cleanser is provided.
In the cleaning agent, the surfactant is 5 to 20% by mass, the oil removing agent is 5 to 15% by mass, the acrylic acid-methacrylic acid copolymer is 0.1 to 0.5% by mass, and the water floating is performed. It is desirable that 3 to 15% by mass of the inorganic inorganic hollow particle is contained.
〔作用〕
界面活性剤は本発明の洗浄剤に洗浄性を与える主役である。しかし油汚れに対しては油除去剤を添加して油性汚染物に対しての洗浄性を強化する。
無機中空体粒子は本発明の洗浄剤に研磨性を与え、皮膚に強固に付着した汚染物を擦り落とす。該無機中空体粒子は軽量で水に浮くので、排水管等を詰らせない。
アクリル酸−メタクリル酸共重合体は本発明の洗浄剤に非ニュートン粘性を付与して少量の使用でも上記水不溶性粒子の浮上分離を防止する。そして上記アクリル酸−メタクリル酸共重合体は展延性に優れた粘性を洗浄剤に与えるから、洗浄剤の使用感が良好になる。
[Action]
The surfactant is the main role of imparting detergency to the cleaning agent of the present invention. However, an oil remover is added to oil stains to enhance the cleaning performance against oily contaminants.
The inorganic hollow body particles impart abrasiveness to the cleaning agent of the present invention, and scrub off contaminants firmly attached to the skin. Since the inorganic hollow body particles are light and float in water, they do not clog drain pipes and the like.
The acrylic acid-methacrylic acid copolymer imparts non-Newtonian viscosity to the cleaning agent of the present invention and prevents the water-insoluble particles from floating and separating even when used in a small amount. And since the said acrylic acid-methacrylic acid copolymer gives the viscosity excellent in spreadability to a cleaning agent, the usability | use_condition of a cleaning agent becomes favorable.
〔効果〕
本発明では、皮膚についた汚れを効率良く除去し、しかも排水管等に詰らせない洗浄剤が提供される。
〔effect〕
The present invention provides a cleaning agent that efficiently removes dirt on the skin and does not clog a drain pipe or the like.
本発明を以下に詳細に説明する
〔界面活性剤〕
本発明に使用する界面活性剤としては、ノニオン性界面活性剤、アニオン性界面活性剤、カチオン性界面活性剤が挙げられ、望ましい界面活性剤としては、皮膚に対する刺激性の少ないノニオン性界面活性剤である。
ノニオン性界面活性剤としては、ポリオキシエチレンアルキルエーテル、ポリオキシエチレンアルキルフェノールエーテル、ポリオキシエチレンアルキルエステル、ポリオキシエチレンアルキルアミン、ポリオキシエチレンアルキロールアミン、ポリオキシエチレンアルキルアマイド、ソルビタンアルキルエステル、ポリオキシエチレンソルビタンアルキルエステル等が挙げられる。
アニオン性界面活性剤としては、高級アルコールサルフェート(Na塩またはアミン塩)、アルキルアリルスルフォン酸塩(Na塩またはアミン塩)、アルキルナフタレンスルフォン酸塩(Na塩またはアミン塩)、アルキルナフタレンスルフォン酸塩縮合物、アルキルフォスフェート、ジアルキルスルフォサクシネート、ロジン石鹸、脂肪酸塩(Na塩またはアミン塩)等が挙げられる。
カチオン性界面活性剤としては、オクタデシルアミンアセテート、イミダゾリン誘導体アセテート、ポリアルキレンポリアミン誘導体またはその塩、オクタデシルトリメチルアンモニウムクロライド、トリメチルアミノエチルアルキルアミドハロゲニド、アルキルピリジニウム硫酸塩、アルキルトリメチルアンモニウムハロゲニド等が挙げられる。
The present invention is described in detail below [Surfactant]
Examples of the surfactant used in the present invention include nonionic surfactants, anionic surfactants, and cationic surfactants. Desirable surfactants include nonionic surfactants that are less irritating to the skin. It is.
Nonionic surfactants include polyoxyethylene alkyl ether, polyoxyethylene alkyl phenol ether, polyoxyethylene alkyl ester, polyoxyethylene alkyl amine, polyoxyethylene alkylol amine, polyoxyethylene alkyl amide, sorbitan alkyl ester, polyoxyethylene alkyl ester, Examples thereof include oxyethylene sorbitan alkyl ester.
Examples of the anionic surfactant include higher alcohol sulfate (Na salt or amine salt), alkyl allyl sulfonate (Na salt or amine salt), alkyl naphthalene sulfonate (Na salt or amine salt), alkyl naphthalene sulfonate. Examples include condensates, alkyl phosphates, dialkylsulfosuccinates, rosin soaps, fatty acid salts (Na salts or amine salts), and the like.
Examples of the cationic surfactant include octadecylamine acetate, imidazoline derivative acetate, polyalkylene polyamine derivative or a salt thereof, octadecyltrimethylammonium chloride, trimethylaminoethylalkylamide halide, alkylpyridinium sulfate, alkyltrimethylammonium halide, and the like. It is done.
〔油除去剤〕
本発明に使用する油除去剤としては、ベンジルアルコール、流動パラフィン、プロピレングリコール、エチレングリコール、グリセリン、オレンジオイル、リモネン等の皮膚を刺激しない高沸点の有機溶剤がある。
[Oil remover]
Examples of the oil removing agent used in the present invention include high-boiling organic solvents that do not irritate the skin, such as benzyl alcohol, liquid paraffin, propylene glycol, ethylene glycol, glycerin, orange oil, and limonene.
〔アクリル酸−メタクリル酸共重合体〕
本発明において使用するアクリル酸−メタクリル酸共重合体は通常アクリル酸:メタクリル酸質量比が10:90〜90:10、望ましくは20:80〜80:20、更に望ましくは30:70〜70:30の共重合体であって、水溶性を阻害しない程度にアクリル酸エステルおよび/またはメタクリル酸エステルが共重合されてもよい。
上記アクリル酸エステルまたはメタクリル酸エステルとしては、(メタ)アクリル酸メチル、(メタ)アクリル酸エチル、(メタ)アクリル酸イソプロピル、(メタ)アクリル酸イソブチル、(メタ)アクリル酸ノルマルブチル等の炭素数4以下のアルキル基を有するエステルが望ましい。またジビニルベンゼン、ジアリルフタレート、リン酸トリアリルエステル、テトラアリロキシエタン、グルコース(メタ)アクリルエステル、ショ糖(メタ)アクリルエステル等の重合可能なビニル基を一分子中に二個以上含有する多官能ビニル化合物を架橋剤として水溶性を阻害しない程度に若干添加してもよい。
[Acrylic acid-methacrylic acid copolymer]
The acrylic acid-methacrylic acid copolymer used in the present invention usually has an acrylic acid: methacrylic acid mass ratio of 10:90 to 90:10, preferably 20:80 to 80:20, more preferably 30:70 to 70: 30 copolymers and acrylic acid ester and / or methacrylic acid ester may be copolymerized to such an extent that water solubility is not inhibited.
As said acrylic acid ester or methacrylic acid ester, carbon number such as methyl (meth) acrylate, ethyl (meth) acrylate, isopropyl (meth) acrylate, isobutyl (meth) acrylate, normal butyl (meth) acrylate, etc. Esters having 4 or fewer alkyl groups are desirable. In addition, it contains many polymerized vinyl groups such as divinylbenzene, diallyl phthalate, triallyl phosphate, tetraallyloxyethane, glucose (meth) acrylic ester, and sucrose (meth) acrylic ester in one molecule. A slightly functional vinyl compound may be added as a crosslinking agent to the extent that water solubility is not impaired.
本発明の洗浄剤においては、上記共重合体は塩の状態で存在していてもよい。上記共重合体を塩とするには、例えばカセイソーダ、カセイカリ、炭酸ソーダ等の無機アルカリ、ジエチルアミン、トリエチルアミン、ジイソプロピルアミン、トリイソプロピルアミン、ジエタノールアミン、トリエタノールアミン、ジイソプロパノールアミン、トリイソプロパノールアミン等の有機アルカリが使用される。上記共重合体を塩型にすれば水溶性が向上する。上記共重合体は予め塩型にしておいてから水溶液に添加してもよいし、水溶液中に添加してから上記アルカリによって中和してもよい。 In the cleaning agent of the present invention, the copolymer may exist in a salt state. In order to make the copolymer into a salt, for example, inorganic alkali such as caustic soda, caustic potash, sodium carbonate, etc., organic such as diethylamine, triethylamine, diisopropylamine, triisopropylamine, diethanolamine, triethanolamine, diisopropanolamine, triisopropanolamine Alkali is used. If the copolymer is made into a salt form, water solubility is improved. The copolymer may be added to the aqueous solution after having been made into a salt form in advance, or may be added to the aqueous solution and then neutralized with the alkali.
上記共重合体において、アクリル酸成分は洗浄剤に好ましい展延性を与え、メタクリル酸成分は洗浄剤に非ニュートン粘性を与えて後述する水浮上性無機中空体粒子の浮上分離を効率的に阻止する。また皮膚に対する悪影響は殆ど無い。 In the above copolymer, the acrylic acid component imparts favorable spreading properties to the cleaning agent, and the methacrylic acid component imparts non-Newtonian viscosity to the cleaning agent to effectively prevent the floating separation of the water-floating inorganic hollow particles described later. . There is almost no adverse effect on the skin.
〔水浮上性無機中空体粒子〕
本発明において使用される水浮上性無機中空体粒子としては、例えばシリカバルーン、シラスバルーン、ガラスバルーン、バーライト等があり、上記粒子は水に浮上するよう水よりも見掛け比重が小さいものであり、数平均粒径が40μm〜300μmの範囲のものが望ましい。
なお、シラスバルーンのような天然素材は、例えばポリエチレン粉末等のような人工素材に比べ、皮膚に対してアレルギー反応などを起こしづらく、無毒、無害であるため、皮膚用洗浄剤に使用される水浮上性無機中空体粒子として望ましい。また、人工素材からなる水浮上性無機中空体粒子の表面が凹凸を有するいびつなものであることに比べ、天然素材からなる水浮上性無機中空体粒子は、その表面が滑らかであるため、例えば下水管の内面に引っ掛かったりして詰まったり等しづらく、環境保護の観点からも望ましい。
[Water-floating inorganic hollow particles]
Examples of the water-floating inorganic hollow particles used in the present invention include silica balloons, shirasu balloons, glass balloons, barlites, etc., and the particles have an apparent specific gravity smaller than water so that they float on water. The number average particle size is preferably in the range of 40 μm to 300 μm.
In addition, natural materials such as Shirasu Balloon are less toxic and harmless than artificial materials such as polyethylene powder, and are non-toxic and harmless. Desirable as a floating inorganic hollow body particle. In addition, since the surface of the water-floating inorganic hollow body particles made of an artificial material is irregular, the surface of the water-floating inorganic hollow body particles made of a natural material has a smooth surface. From the viewpoint of environmental protection, it is difficult to get stuck on the inner surface of the sewer pipe.
〔その他の成分〕
その他の成分としては、例えばエタノール、イソプロパノール等の水溶性有機溶剤、光触媒作用を有する酸化チタン、防腐剤、防カビ剤、香料、色素等が添加されてもよい。
[Other ingredients]
As other components, for example, a water-soluble organic solvent such as ethanol and isopropanol, a titanium oxide having a photocatalytic action, an antiseptic, an antifungal agent, a fragrance, and a pigment may be added.
〔配合〕
本発明の洗浄剤にあっては、通常水溶液中に上記界面活性剤5〜20質量、上記油除去剤5〜15質量%、上記共重合体0.1〜0.5質量%、上記無機中空体粒子3〜15質量%が配合される。
上記界面活性剤はこの範囲において充分な洗浄力を発揮し、この範囲を超えた量では洗浄効果は飽和する。
上記油除去剤はこの範囲において充分な油性汚染物除去効果を発揮するが、この範囲を超えた量では除去効果は飽和し、また皮膚を荒らすおそれがある。
上記共重合体はこの範囲において充分な分散効果を発揮し、この範囲を超えた量では分散効果は飽和し、また洗浄剤の展延性を悪化させたり皮張りを発生させたりするおそれがある。
上記無機中空体粒子はこの範囲において充分な研磨効果を示すが、この範囲を越えた量では洗浄剤にざらつき感を与えるおそれがある。
[Combination]
In the cleaning agent of the present invention, the surfactant is usually 5 to 20 mass%, the oil removing agent is 5 to 15 mass%, the copolymer is 0.1 to 0.5 mass%, and the inorganic hollow is in an aqueous solution. 3-15 mass% of body particles are mix | blended.
The surfactant exhibits a sufficient detergency in this range, and the cleaning effect is saturated at an amount exceeding this range.
The oil removing agent exhibits a sufficient effect of removing oily contaminants within this range, but if the amount exceeds this range, the removal effect is saturated and the skin may be roughened.
The copolymer exhibits a sufficient dispersing effect in this range. If the amount exceeds this range, the dispersing effect is saturated, and the spreadability of the cleaning agent may be deteriorated or skinning may occur.
The inorganic hollow body particles exhibit a sufficient polishing effect in this range, but if the amount exceeds this range, the cleaning agent may be roughened.
〔実施例〕
表1に示す配合量で配合1および配合2の皮膚用洗浄剤を調製する。
(*1)No.1共重合体組成
アクリル酸 90質量部
メタクリル酸メチル 10質量部
アクリル酸グルコースエステル 0.01質量部
(*2)No.2共重合体組成
メタクリル酸 80質量部
アクリル酸エチル 20質量部
アクリル酸ショ糖エステル 0.02質量部
〔Example〕
The skin cleansing agents of Formulation 1 and Formulation 2 are prepared with the blending amounts shown in Table 1.
(* 1) No. 1 Copolymer composition Acrylic acid 90 parts by weight Methyl methacrylate 10 parts by weight Acrylic acid glucose ester 0.01 parts by weight (* 2) No. 1 2 Copolymer composition Methacrylic acid 80 parts by weight Ethyl acrylate 20 parts by weight Acrylic acid sucrose ester 0.02 parts by weight
〔比較例〕
表2に示す配合量で、比較配合1から比較配合3の皮膚用洗浄剤を調製する。
(*1)No.1共重合体組成
アクリル酸 90質量部
メタクリル酸メチル 10質量部
アクリル酸グルコースエステル 0.01質量部
[Comparative example]
The skin cleansing agents of Comparative Formulation 1 to Comparative Formulation 3 are prepared with the blending amounts shown in Table 2.
(* 1) No. 1 Copolymer composition Acrylic acid 90 parts by weight Methyl methacrylate 10 parts by weight Acrylic acid glucose ester 0.01 parts by weight
〔分散安定性試験〕
上記配合1,2による洗浄剤を密閉容器に充填し、室温にて3ヶ月放置した。さらに、比較配合1にシラスバルーンを配合1又は配合2と同じ配合量となるように配合してなる洗浄剤を密閉容器に充填し、室温にて3ヶ月放置した。そして、これらの洗浄剤について、
シラスバルーンの浮上分離の有無を観察した。結果を表3に示す。
[Dispersion stability test]
The cleaning agents according to Formulas 1 and 2 were filled in a sealed container and left at room temperature for 3 months. Furthermore, the cleaning agent which mix | blended Shirasu balloon with the comparison compounding 1 so that it might become the same compounding quantity as the compounding 1 or the compounding 2 was filled in the airtight container, and it was left to stand at room temperature for 3 months. And about these cleaning agents,
The presence or absence of floating separation of the shirasu balloon was observed. The results are shown in Table 3.
〔洗浄性試験〕
手の甲に油性ペン(黒色)で1cm径の点を画き、該点を汚れとして、その汚れに若干量の試料を垂らして指で擦ることにより、汚れの落ち具合を観察した。結果を表4に示す。
[Detergency test]
A point of 1 cm diameter was drawn on the back of the hand with an oil pen (black), the point was made dirty, a small amount of sample was hung on the dirt and rubbed with a finger, and the degree of dirt was observed. The results are shown in Table 4.
〔展延性試験〕
手の甲に若干量の試料をとり、指で展延してその状態を観察した。結果を表5に示す。
[Extensibility test]
A small amount of sample was taken on the back of the hand, spread with fingers and observed. The results are shown in Table 5.
〔すすぎ性試験〕
展延性試験に続いて、手を水で洗い、試料の落ち具合を観察した。結果を表6に示す。
[Rinsability test]
Following the spreadability test, the hands were washed with water and the drop of the sample was observed. The results are shown in Table 6.
本発明の皮膚用洗浄剤は優れた洗浄性、研磨性を有し、皮膚に付着した強固な汚れも簡単に除去することが出来、更に良好なすすぎ性を有するから使用勝手も良く、また長期間安定に保存出来るから産業上利用可能である。
The skin cleanser of the present invention has excellent cleanability and abrasiveness, can easily remove strong dirt adhering to the skin, and also has good rinsing properties, so it is easy to use and long. Since it can be stored stably for a period, it can be used industrially.
Claims (2)
5 to 20% by mass of the surfactant, 5 to 15% by mass of the oil removing agent, 0.1 to 0.5% by mass of the acrylic acid-methacrylic acid copolymer, and 3 to 15 of the water-floating inorganic hollow body particles. The skin cleanser according to claim 1, containing a mass%.
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JP2007048082A JP5756946B2 (en) | 2007-02-27 | 2007-02-27 | Skin cleanser |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2014196275A (en) * | 2013-03-29 | 2014-10-16 | 富士フイルム株式会社 | Composition and cosmetics |
WO2016084615A1 (en) * | 2014-11-27 | 2016-06-02 | 株式会社マンダム | Liquid topical preparation for skin |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH11508533A (en) * | 1995-06-30 | 1999-07-27 | クロスフイールド リミテツド | Amorphous silica and oral composition |
JP2000044461A (en) * | 1998-07-31 | 2000-02-15 | Kumano Yushi Kk | Body cleaner and its use |
JP2000136125A (en) * | 1998-10-29 | 2000-05-16 | Kumano Yushi Kk | Hand cleaner |
JP2005206812A (en) * | 2003-12-25 | 2005-08-04 | Lion Corp | Liquid detergent composition |
JP2005213272A (en) * | 1996-08-23 | 2005-08-11 | Kao Corp | Water based skin cosmetic |
JP2006510638A (en) * | 2002-12-11 | 2006-03-30 | ユニリーバー・ナームローゼ・ベンノートシヤープ | Shampoo composition |
-
2007
- 2007-02-27 JP JP2007048082A patent/JP5756946B2/en active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH11508533A (en) * | 1995-06-30 | 1999-07-27 | クロスフイールド リミテツド | Amorphous silica and oral composition |
JP2005213272A (en) * | 1996-08-23 | 2005-08-11 | Kao Corp | Water based skin cosmetic |
JP2000044461A (en) * | 1998-07-31 | 2000-02-15 | Kumano Yushi Kk | Body cleaner and its use |
JP2000136125A (en) * | 1998-10-29 | 2000-05-16 | Kumano Yushi Kk | Hand cleaner |
JP2006510638A (en) * | 2002-12-11 | 2006-03-30 | ユニリーバー・ナームローゼ・ベンノートシヤープ | Shampoo composition |
JP2005206812A (en) * | 2003-12-25 | 2005-08-04 | Lion Corp | Liquid detergent composition |
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JP2014196275A (en) * | 2013-03-29 | 2014-10-16 | 富士フイルム株式会社 | Composition and cosmetics |
WO2016084615A1 (en) * | 2014-11-27 | 2016-06-02 | 株式会社マンダム | Liquid topical preparation for skin |
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JPWO2016084615A1 (en) * | 2014-11-27 | 2017-05-25 | 株式会社マンダム | Liquid skin preparation |
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