JP2008100946A - Fungicidal and insecticidal composition - Google Patents
Fungicidal and insecticidal composition Download PDFInfo
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- JP2008100946A JP2008100946A JP2006284626A JP2006284626A JP2008100946A JP 2008100946 A JP2008100946 A JP 2008100946A JP 2006284626 A JP2006284626 A JP 2006284626A JP 2006284626 A JP2006284626 A JP 2006284626A JP 2008100946 A JP2008100946 A JP 2008100946A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
- A01N37/50—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids the nitrogen atom being doubly bound to the carbon skeleton
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
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- Agricultural Chemicals And Associated Chemicals (AREA)
- Breeding Of Plants And Reproduction By Means Of Culturing (AREA)
- Pretreatment Of Seeds And Plants (AREA)
Abstract
Description
本発明は殺菌殺虫組成物に関する。詳しくは、育苗箱に施用する殺菌殺虫組成物に関し、副次作用として植物生長促進作用を有する該組成物にも関する。 The present invention relates to a bactericidal insecticidal composition. Specifically, it relates to a fungicidal insecticidal composition applied to a seedling box, and also relates to the composition having a plant growth promoting action as a secondary action.
水稲箱育苗において、播種時に、長期残効性殺虫剤および殺菌剤を処理する方法は、本田生育期間中の防除回数を低減できるため、水稲栽培の省力化・低コスト化に有効な手段として普及が進み、既に日本の各地で広く行われている。 In paddy rice box seedlings, the method of treating long-lasting insecticides and fungicides at the time of sowing can be used as an effective means for labor saving and cost reduction of paddy rice cultivation because it can reduce the number of times of control during the growing season of Honda. Has already been promoted and is already widely practiced in various parts of Japan.
本発明の組成物に含まれるそれぞれの有効成分は、通常の栽培条件下で播種時に単独で処理した場合、イネの生育に影響はないが、湛水育苗（通称プール育苗）や、異常高温、低温、乾燥などの条件によっては、根部の生育が多少遅延する場合がある。 Each active ingredient contained in the composition of the present invention, when treated alone at the time of sowing under normal cultivation conditions, does not affect the growth of rice, but it is a flooded seedling (commonly called pool raising), abnormally high temperature, Depending on conditions such as low temperature and drying, the growth of the root may be somewhat delayed.
殺菌性化合物の３，４−ジクロロ−Ｎ−（２−シアノフェニル）イソチアゾール−５−カルボキサミドと公知殺虫剤との混合組成物はすでに知られている（特許文献１）。
本発明者らは、下記に示す組み合わせが、本田移植後の水稲の病害虫に対し、優れた防除効果を現わすと共に、根の生育を促進して育苗期間を短縮し、通常と異なる条件においても、安定した水稲苗の根部の良好な生育をもたらすことを見出し、本発明を完成した。 The present inventors have shown that the combination shown below has an excellent control effect against pests of rice after transplanting to Honda, and promotes root growth to shorten the seedling raising period, even under different conditions. As a result, the present inventors have found that stable root growth of paddy rice seedlings can be achieved and the present invention has been completed.
かくして、本発明は
（ａ）３，４−ジクロロ−Ｎ−（２−シアノフェニル）イソチアゾール−５−カルボキサミド（以下、イソチアニルと略記する）と、
（ｂ）フィプロニル又はエチプロールを組み合わせて含んでなる殺菌殺虫組成物を提供するものである。
Thus, the present invention provides (a) 3,4-dichloro-N- (2-cyanophenyl) isothiazole-5-carboxamide (hereinafter abbreviated as isothianyl);
(B) A fungicidal insecticidal composition comprising a combination of fipronil or etiprol is provided.
また、本発明は、育苗箱に水稲種子を播種し、上記組成物を覆土前に施用することからなる、本田移植後の病害虫を防除する方法、並びに、育苗箱の床土、又は水稲種子を覆土する土に同じく上記組成物を混合することからなる、本田移植後の病害虫を防除する方法を提供するものでもある。 The present invention also includes a method for controlling pests after transplanting to Honda, comprising seeding paddy rice seeds in a seedling box and applying the composition before covering the soil, as well as floor soil of the seedling box or paddy rice seeds. The present invention also provides a method for controlling pests after transplanting to Honda, which comprises mixing the above composition with the soil to be covered.
本発明によれば、上記（ａ）のイソチアニルと（ｂ）のフィプロニル又はエチプロールを組み合わせてなる組成物に具体的に特定された記載も、該組成物の具体的な生物効果も本願出願日前の刊行物には開示されていない。そして驚くべきことに、本発明の（ａ）のイソチアニルと（ｂ）のフィプロニル又はエチプロールを組み合わせて含んでなる殺菌殺虫組成物は水稲の病害虫に対し、優れた防除効果を現わすと共に、該組成物を施用しない場合に比べて、水稲苗の根の生育を極めて良好に促進するという植物生長促進作用を示すことができ、その結果、水稲苗の育苗期間の短縮をもたらし、通常と異なる条件下でも安定な根部の生育を達成させることができる。従って、本発明の組成物は、病害虫防除と育苗期間の短縮という生産性の両面で極めて有利で有用なものである。 According to the present invention, the description specifically identified in the composition comprising the combination of isotianil of (a) and fipronil or etiprole of (b), the specific biological effect of the composition, It is not disclosed in the publication. Surprisingly, the bactericidal insecticidal composition comprising the combination of (i) isotianil of (a) and fipronil or etiprole of (b) of the present invention exhibits an excellent control effect against rice pests and the composition. Compared to the case where no plant is applied, the plant growth promoting action of promoting the root growth of paddy rice seedlings can be shown very well. However, stable root growth can be achieved. Therefore, the composition of the present invention is extremely advantageous and useful in terms of both productivity of pest control and shortening of the seedling raising period.
本発明は、更に、上記（ａ）と（ｂ）の二成分の組み合わせに加えて、（ｃ）のイミダクロプリド、チアクロプリド、クロチアニジン、ジノテフラン、チアメトキサム、スピノサド、チフルザミド、フラメトピル、オリサストロビン及びＢＹＦ１４１８２より成る群から選ばれる少なくとも１種を含んでなる組成物も提供するものであり、そして、この（ａ）、（ｂ）及び（ｃ）の各成分を組み合わせてなる組成物も、上記した病害虫防除と生産性の両面で極めて有利且つ有用なものである。 In addition to the combination of the two components (a) and (b) above, the present invention further comprises the group consisting of imidacloprid, thiacloprid, clothianidin, dinotefuran, thiamethoxam, spinosad, tifluzamide, flametopyr, orisatrobin and BYF14182. A composition comprising at least one selected from the above is also provided, and a composition comprising a combination of the components (a), (b) and (c) is also used for controlling the above-mentioned pests and productivity. It is extremely advantageous and useful in both aspects.
本発明における（ａ）のイソチアニルは、特表２００１−５２２８４０号公報に示される病害防除剤の一つであり、（ｂ）のフィプロニル及びエチプロール、また（ｃ）の前記各成分の内、オリサストロビンとＢＹＦ１４１８２を除き、Ｐｅｓｔｉｃｉｄｅ Ｍａｎｕａｌ（２００３年 １３版 ＢＣＰＣ発行）に記載される化合物である。オリサストロビンは独公開特許第１９５３９３２４号に記載の化合物である。ＢＹＦ１４１８２はＷＯ ２００６／０９２２９１公報に記載の化合物である。 The isotianil of (a) in the present invention is one of the disease control agents disclosed in JP-T-2001-522840, and fipronil and etiprole of (b), and among the above components of (c), Except BYF14182, these compounds are described in Pesticide Manual (2003 13th edition, issued by BCPC). Orisatrobin is a compound described in German Patent No. 19539324. BYF14182 is a compound described in WO 2006/092921.
本発明の組み合わせ組成物において、各有効成分の混合比は、限定的に制限されるものではなく、混合する活性化合物の種類、病害虫の発生予察等に応じて相対的に広い範囲にわたり変えることができる。一般には、混合比は、例えば、（ａ）のイソチアニル １重量部に対して、（ｂ）のフィプロニル又はエチプロールは０．０２〜３重量部、好ましくは、０．０５〜２．５重量部の範囲、そして（ｃ）成分を加えてなる場合には、（ｃ）成分は、０．５〜２重量部、好ましくは、１〜１．５重量部の範囲内で使用することができる。 In the combination composition of the present invention, the mixing ratio of each active ingredient is not limited and can be varied over a relatively wide range depending on the type of active compound to be mixed, the occurrence of pests, etc. it can. In general, the mixing ratio is, for example, 0.02 to 3 parts by weight, preferably 0.05 to 2.5 parts by weight of fipronil or etiprole (b) with respect to 1 part by weight of isotianil (a). When the range and (c) component are added, the (c) component can be used in the range of 0.5 to 2 parts by weight, preferably 1 to 1.5 parts by weight.
本発明の組み合わせ組成物を使用するに当たっては、育苗箱に水稲種子を播種し、当該組成物を覆土前に施用する方法か、又は育苗箱の床土又は水稲種子を覆土する土に、当該組成物を混合する方法により、本田移植後の病害虫の防除を的確に行なうことができる。 In using the combination composition of the present invention, the seeds are sown in a seedling box and the composition is applied before the soil covering, or the floor soil of the seedling box or the soil covering the rice seeds is used. By the method of mixing things, it is possible to accurately control pests after transplanting Honda.
本発明の組み合わせ組成物が防除の対照とする病害虫としては、以下のものを例示することができるが、これらに限定されるものではない。 Examples of the pests that are controlled by the combination composition of the present invention include the following, but are not limited thereto.
水稲害虫として
半翅目：ツマグロヨコバイ（Ｎｅｐｈｏｔｅｔｔｉｘ ｃｉｎｃｔｉｃｅｐｓ）、トビイロウンカ（Ｎｉｌａｐａｒｖａｔａ ｌｕｇｅｎｓ）、ヒメトビウンカ（Ｌａｏｄｅｌｐｈａｘ ｓｔｒｉａｔｅｌｌｕｓ（Ｆａｌｌｅｎ））、セジロウンカ（Ｓｏｇａｔｅｌｌａ ｆｕｒｃｉｆｅｒａ（Ｈｏｒｖａｔｈ））など。
As paddy rice pest
Hemiptera : Nephotettix cinchetics, Japanese brown planthopper (Nilaparvata lugens), Japanese brown planthopper (Laodelfax striellatus (Fallen)), White-leaf planter (SogatellafurH), etc.
甲虫目：イネドロオイムシ（Ｏｕｌｅｍａ ｏｒｙｚａｅ（Ｋｕｗａｙａｍａ））、イネミズゾウムシ（Ｌｉｓｓｏｒｈｏｐｔｒｕｓ ｏｒｙｚｏｐｈｉｌｕｓ Ｋｕｓｃｈｅｌ）など。 Coleoptera : Rice beetle (Oulema oryzae (Kuwayama)), rice weevil (Lissorhoptrus oryzophilus Kuschel), etc.
鱗翅目：ニカメイチュウ（Ｃｈｉｌｏ ｓｕｐｐｒｅｓｓａｌｉｓ（Ｗａｌｋｅｒ））、コブノメイガ（Ｃｎａｐｈａｌｏｃｒｏｃｉｓ ｍｅｄｉｎａｌｉｓ（Ｇｕｅｎｅｅ））、イネツトムシ（Ｐａｒｎａｒａ ｇｕｔｔａｔａ（Ｂｒｅｍｅｘ ｅｔ Ｇｒｅｙ））など。 Lepidoptera : Chilo suppressalis (Walker), Cnaphalocrosis medinalis (Guenee), Parrot guttata (Brex et Grey) and the like.
水稲病害として、イモチ病（Ｐｙｒｉｃｕｌａｒｉａ ｏｒｙｚａｅ）、紋枯病（Ｐｅｌｌｉｃｕｌａｒｉａ ｓａｓａｋｉｉ）など。 Examples of paddy rice diseases include tuberculosis (Pyricularia oryzae) and blight (Pellicularia sasakii).
本発明の組み合わせ組成物は、水稲病害虫の防除のために使用するに際して、通常の製剤形態にすることができる。 When the combination composition of the present invention is used for controlling paddy rice pests, it can be converted into a usual preparation form.
その製剤形態としては、例えば、液剤、エマルジョン、水和剤、フロアブル剤、顆粒水和剤、粒剤、重合体物質中のマイクロカプセル等を挙げることができる。 Examples of the preparation form include liquids, emulsions, wettable powders, flowable powders, granular wettable powders, granules, and microcapsules in a polymer substance.
これらの製剤はそれ自体既知の方法によって調製することができる。例えば、前記の各有効成分を、固体又は液体の担体又は希釈剤、必要な場合には、界面活性剤やその他の製剤用補助剤と混合することによって本発明に従う製剤を調製することができる。 These preparations can be prepared by methods known per se. For example, a formulation according to the present invention can be prepared by mixing each of the above active ingredients with a solid or liquid carrier or diluent, if necessary, a surfactant or other formulation adjuvant.
本発明の組成物の製剤化に際して用い得る固体担体及び／又は固体希釈剤としては、例えば、クレー、カオリン、タルク、炭酸カルシウム、珪藻土、ゼオライト、ベントナイト、酸性白土、活性白土、アタパルガスクレー、バーミキューライト、パーライト、軽石、硅砂、硅石等の鉱石を原料とする無機物質；
親水性シリカ、疎水性シリカ、ケイ酸カルシウム等のホワイトカーボン、合成ゼオライト、二酸化チタン等の合成品；
大豆粉、タバコ粉、トウモロコシ穂軸粉、クルミ粉、小麦粉、木粉、でんぷん、結晶セルロース等の植物性有機物質；
クマロン樹脂、石油樹脂、アルキッド樹脂、ポリアルキレングリコール、ケトン樹脂、エステルガム等の合成又は天然の高分子化合物；
カルナバロウ、蜜ロウ等のワックス類；
尿素、乳糖、ショ糖、硫酸アンモニウム、塩化カリウム等の水溶性物質が例示できる。
Examples of the solid carrier and / or solid diluent that can be used in formulating the composition of the present invention include clay, kaolin, talc, calcium carbonate, diatomaceous earth, zeolite, bentonite, acidic clay, activated clay, attapulgous clay, Inorganic substances made from ores such as vermiculite, perlite, pumice, cinnabar, and meteorites;
Synthetic products such as hydrophilic carbon, hydrophobic silica, white carbon such as calcium silicate, synthetic zeolite, titanium dioxide;
Plant organic substances such as soy flour, tobacco powder, corn cob flour, walnut flour, wheat flour, wood flour, starch, crystalline cellulose;
Synthetic or natural polymer compounds such as coumarone resin, petroleum resin, alkyd resin, polyalkylene glycol, ketone resin, ester gum;
Waxes such as carnauba wax and beeswax;
Water-soluble substances such as urea, lactose, sucrose, ammonium sulfate and potassium chloride can be exemplified.
適当な液体担体及び／又は液体希釈剤としては、例えば、
ヤシ油、菜種油、コーン油、大豆油、米ぬか油等の油脂類；
ケロシン、鉱油、スピンドル油、ホワイトオイル、ノルマルパラフィン、イソパラフィン、ナフテン等のパラフィン系もしくはナフテン系炭化水素系溶剤；
キシレン、アルキルベンゼン、アルキルナフタレン等の芳香族炭化水素系溶剤；
エタノール、ベンジルアルコール、イソプロパノール、シクロヘキサノール等のアルコール類；
エチレングリコール、ジエチレングリコール、プロピレングリコール、ポリエチレングリコール等の多価アルコール類；
エチレングリコールエチルエーテル、エチレングリコールフェニルエーテル、ジエチレングリコールエチルエーテル、ジエチレングリコールブチルエーテル等のエーテルアルコール類；
メチルエチルケトン、ジイソブチルケトン、シクロヘキサノン、アセトフェノン、イソホロン、γ−ブチロラクトン等のケトン類；
ヤシ油脂肪酸メチルエステル等の脂肪酸メチルエステル、コハク酸ジメチルエステル、グリタミン酸ジメチルエステルやアジピン酸ジメチルエステル等の二塩基酸メチルエステル、酢酸エチル、酢酸アミル、エチレングリコールアセテート、ジエチレングリコールアセテート等のエステル類；
ジオキサン、テトラヒドロフラン等のエーテル類；
ジメチルホルムアミド、ジメチルアセトアミド、ジメチルスルホキシド、Ｎ−アルキルピロリドン等の極性溶媒あるいは水等が例示できる。
Suitable liquid carriers and / or liquid diluents include, for example,
Fats and oils such as coconut oil, rapeseed oil, corn oil, soybean oil, rice bran oil;
Paraffinic or naphthenic hydrocarbon solvents such as kerosene, mineral oil, spindle oil, white oil, normal paraffin, isoparaffin, naphthene;
Aromatic hydrocarbon solvents such as xylene, alkylbenzene, alkylnaphthalene;
Alcohols such as ethanol, benzyl alcohol, isopropanol, cyclohexanol;
Polyhydric alcohols such as ethylene glycol, diethylene glycol, propylene glycol, polyethylene glycol;
Ether alcohols such as ethylene glycol ethyl ether, ethylene glycol phenyl ether, diethylene glycol ethyl ether, diethylene glycol butyl ether;
Ketones such as methyl ethyl ketone, diisobutyl ketone, cyclohexanone, acetophenone, isophorone, γ-butyrolactone;
Fatty acid methyl esters such as coconut oil fatty acid methyl ester, dimethyl succinate, dibasic acid methyl ester such as dimethyl glutamate and dimethyl adipate, esters such as ethyl acetate, amyl acetate, ethylene glycol acetate, diethylene glycol acetate;
Ethers such as dioxane and tetrahydrofuran;
Examples include polar solvents such as dimethylformamide, dimethylacetamide, dimethylsulfoxide, N-alkylpyrrolidone, water, and the like.
その他に有効成分の乳化、分散、湿潤、拡展、分解防止、効力増強等の目的及び／又は製剤物性の改良（崩壊性調節、流動性改善、凍結防止、耐雨性付与等）の目的で、界面活性剤、結合剤及びその他の補助剤を使用することができる。使用し得る界面活性剤としては、非イオン性、陰イオン性、陽イオン性及び両性イオン性のいずれのタイプの化合物でも使用し得るが、通常は非イオン性及び／又は陰イオン性の化合物が使用される。適当な非イオン性界面活性剤としては、例えば、ソルビタン脂肪酸エステル、ポリオキシアルキレンソルビタン脂肪酸エステル、ショ糖脂肪酸エステル；ポリオキシアルキレン脂肪酸エステル、ポリオキシアルキレン樹脂酸エステル、ポリオキシアルキレン脂肪酸ジエステル；ポリオキシアルキレンひまし油、ポリオキシアルキレン硬化ひまし油；ポリオキシアルキレンアルキルエーテル；ポリオキシアルキレンアルキルフェニルエーテル、ポリオキシアルキレンジアルキルフェニルエーテル、ポリオキシアルキレンアルキルフェニルエーテルホルマリン縮合物；ポリオキシエチレン・ポリオキシプロピレンブロックポリマー、アルキルポリオキシエチレン・ポリオキシプロピレンブロックポリマーエーテル、アルキルフェニルポリオキシエチレン・ポリオキシプロピレンブロックポリマーエーテル；ポリオキシアルキレンアルキルアミン、ポリオキシアルキレン脂肪酸アミド；ポリオキシアルキレンベンジルフェニル（又はフェニルフェニル）エーテル、ポリオキシアルキレンスチリルフェニル（又はフェニルフェニル）エーテル；ポリオキシアルキレンエーテル及びエステル型シリコン及びフッ素系界面活性剤等を挙げることができる。 In addition, for the purpose of emulsifying, dispersing, wetting, spreading, preventing degradation, enhancing efficacy, etc. and / or improving the physical properties of the formulation (controlling disintegration, improving fluidity, preventing freezing, imparting rain resistance, etc.) Surfactants, binders and other adjuvants can be used. As the surfactant that can be used, any type of nonionic, anionic, cationic and zwitterionic compounds can be used, but usually nonionic and / or anionic compounds are used. used. Suitable nonionic surfactants include, for example, sorbitan fatty acid esters, polyoxyalkylene sorbitan fatty acid esters, sucrose fatty acid esters; polyoxyalkylene fatty acid esters, polyoxyalkylene resin acid esters, polyoxyalkylene fatty acid diesters; polyoxy Alkylene castor oil, polyoxyalkylene hydrogenated castor oil; polyoxyalkylene alkyl ether; polyoxyalkylene alkyl phenyl ether, polyoxyalkylene dialkyl phenyl ether, polyoxyalkylene alkyl phenyl ether formalin condensate; polyoxyethylene / polyoxypropylene block polymer, alkyl Polyoxyethylene / polyoxypropylene block polymer ether, alkylphenyl polyoxye Polyoxyalkylene alkylamine, polyoxyalkylene fatty acid amide; polyoxyalkylene benzylphenyl (or phenylphenyl) ether, polyoxyalkylene styrylphenyl (or phenylphenyl) ether; polyoxyalkylene ether and Examples include ester type silicon and fluorine-based surfactants.
また、適当な陰イオン性界面活性剤としては、例えば、アルキルサルフェート塩、ポリオキシアルキレンアルキルエーテルサルフェート塩、ポリオキシアルキレンアルキルフェニルエーテルサルフェート塩、ポリオキシアルキレンベンジル（又はスチリル）フェニル（又はフェニルフェニル）エーテルサルフェート塩、ポリオキシエチレン・ポリオキシプロピレンブロックポリマーサルフェート塩；パラフィン（アルカン）スルホネート塩、アルファオレフィンスルホネート塩、ジアルキルスルホサクシネート塩、アルキルベンゼンスルホネート塩、モノ又はジアルキルナフタレンスルホネート塩、ナフタレンスルホネート・ホルマリン縮合物塩、アルキルジフェニルエーテルジスルホネート塩、リグニンスルホネート塩、ポリオキシアルキレンアルキルフェニルエーテルスルホネート塩、ポリオキシアルキレンエーテルスルホコハク酸ハーフエステル塩；脂肪酸塩、Ｎメチル脂肪酸サルコシネート、樹脂酸塩；ポリオキシアルキレンアルキルエーテルホスフェート塩、ポリオキシアルキレンモノ又はジアルキルフェニルエーテルホスフェート塩、ポリオキシアルキレンベンジル（又はスチリル）化フェニル（又はフェニルフェニル）エーテルホスフェート塩、ポリオキシエチレン・ポリオキシプロピレンブロックポリマーホスフェート塩；ポリアクリル酸塩、ポリカルボン酸塩等を挙げることができる。 Suitable anionic surfactants include, for example, alkyl sulfate salts, polyoxyalkylene alkyl ether sulfate salts, polyoxyalkylene alkyl phenyl ether sulfate salts, polyoxyalkylene benzyl (or styryl) phenyl (or phenylphenyl). Ether sulfate salt, polyoxyethylene / polyoxypropylene block polymer sulfate salt: paraffin (alkane) sulfonate salt, alpha olefin sulfonate salt, dialkyl sulfosuccinate salt, alkylbenzene sulfonate salt, mono or dialkyl naphthalene sulfonate salt, naphthalene sulfonate / formalin condensation Salt, alkyl diphenyl ether disulfonate, lignin sulfonate, polyoxyalkyl Alkyl phenyl ether sulfonate salt, polyoxyalkylene ether sulfosuccinic acid half ester salt; fatty acid salt, N-methyl fatty acid sarcosinate, resin acid salt; polyoxyalkylene alkyl ether phosphate salt, polyoxyalkylene mono- or dialkyl phenyl ether phosphate salt, polyoxy Examples thereof include alkylene benzyl (or styryl) phenyl (or phenylphenyl) ether phosphate salt, polyoxyethylene / polyoxypropylene block polymer phosphate salt; polyacrylate, polycarboxylate and the like.
陽イオン性界面活性剤としてはアルキルトリメチルアンモニウムクロライド、メチル・ポリオキシエチレン・アルキルアンモニウムクロライド、アルキル・Ｎメチルピリジニウムブロマイド、モノ又はジアルキルメチル化アンモニウムクロライド、アルキルペンタメチルプロピレンジアミンジクロライド等のアンモニウム型；アルキルジメチルベンザルコニウムクロライド、ベンゼトニウムクロライド等のベンザルコニウム型を挙げることができる。 Examples of cationic surfactants include ammonium types such as alkyltrimethylammonium chloride, methyl-polyoxyethylene-alkylammonium chloride, alkyl-N-methylpyridinium bromide, mono- or dialkylmethylated ammonium chloride, alkylpentamethylpropylenediamine dichloride; alkyl Benzalkonium types such as dimethylbenzalkonium chloride and benzethonium chloride can be exemplified.
両イオン性界面活性剤としてはジアルキルジアミノエチルベタイン、アルキルジメチルベンジルベタイン等のベタイン型を挙げることができる。 Examples of amphoteric surfactants include betaine types such as dialkyldiaminoethylbetaine and alkyldimethylbenzylbetaine.
また、結合剤としてはベントナイト、カゼイン、ゼラチン、デンプン、デキストリン、リグニンスルホン酸塩、アルギン酸塩、アラビアゴム、キサンタンガム、カルボキシメチルセルロース、メチルセルロース、ポリビニルアルコール、ポリビニルピロリドン等を例示することができる。 Examples of the binder include bentonite, casein, gelatin, starch, dextrin, lignin sulfonate, alginate, gum arabic, xanthan gum, carboxymethyl cellulose, methyl cellulose, polyvinyl alcohol, polyvinyl pyrrolidone and the like.
その他の補助剤として、崩壊性調製剤、凍結防止剤、防腐剤、流動性改良材、消泡剤、保湿剤、拡展剤、耐雨性付与剤、着色剤等を挙げることができる。 Examples of other adjuvants include disintegrating preparation agents, antifreezing agents, preservatives, fluidity improvers, antifoaming agents, moisturizing agents, spreading agents, rain resistance imparting agents, and coloring agents.
上記の担体及び界面活性剤、結合剤や種々の補助剤は、製剤の剤型、適用場面等を考慮して、目的に応じてそれぞれ単独で又は組み合わせて適宜使用することができる。 The above carriers, surfactants, binders and various adjuvants can be appropriately used singly or in combination depending on the purpose in consideration of the dosage form of the preparation, application scene, and the like.
製剤は、一般に、各有効成分の合計で０．１〜９５重量％、好ましくは０．５〜９０重量％の濃度で含有することができる。 In general, the preparation can be contained at a concentration of 0.1 to 95% by weight, preferably 0.5 to 90% by weight in total of each active ingredient.
本発明の組み合わせ組成物は、使用に際して、そのままあるいはその製剤の形態で使用することができ、また、使用時に各有効成分をタンク混合することも可能である。 The combination composition of the present invention can be used as it is or in the form of its preparation when used, and each active ingredient can be mixed in a tank at the time of use.
本発明の組み合わせ組成物は、そのまま、あるいは前記した製剤の形態で、又は該製剤から更に希釈して調製した施用形態、例えば、散布用調製液（ｒｅａｄｙ−ｔｏ−ｕｓｅ ｓｏｌｕｔｉｏｎ）の形態で使用することができる。これらの形態のものは通常の方法、例えば、液剤散布（ｗａｔｅｒｉｎｇ）、噴霧（ｓｐｒａｙｉｎｇ，ａｔｏｍｉｚｉｎｇ）、散粒等の方法で育苗箱に施用することができる。 The combination composition of the present invention is used as it is, in the form of the above-mentioned preparation, or in the form of application prepared by further diluting from the preparation, for example, in the form of a ready-to-use solution. be able to. The thing of these forms can be applied to a nursery box by the usual methods, for example, liquid agent watering (watering), spraying (spraying, atomizing), a method such as particle size.
本発明の組み合わせ組成物を育苗箱に施用するに際して、育苗箱の床土又は水稲種子を覆土する土に、該組成物を混合することができる。また、他の方法として、予め播種前に水稲種子を本発明の組み合わせ組成物で種子処理、例えば粉衣、コーティング等を行なっておき、育苗箱に播種し育苗し、本田移植後の病害虫防除を行なうという体系的な方法も、本発明は包含するものである。 When the combined composition of the present invention is applied to a seedling box, the composition can be mixed with the floor soil of the seedling box or the soil covering the rice seeds. As another method, rice seeds are treated with the combination composition of the present invention in advance before sowing, for example, dressing, coating, etc., seeded in a seedling box and grown, and pest control after transplanting to Honda is carried out. The present invention also includes a systematic method of performing.
本発明の組み合わせ組成物の施用量を実質的な範囲で変えることができる。そして、その施用量は、概して、各有効成分の合計量として、育苗箱（３０ｃｍ×６０ｃｍ×３ｃｍ）当たり、１ｇ〜６ｇ、好ましくは、１．０５ｇ〜５ｇの範囲内とすることができる。 The application rate of the combination composition of the invention can be varied within a substantial range. The application amount can be generally in the range of 1 to 6 g, preferably 1.05 to 5 g per seedling box (30 cm × 60 cm × 3 cm) as the total amount of each active ingredient.
本発明による組み合わせ組成物の優れた効果を以下の実施例により更に具体的に説明する。しかし、本発明はこれらのみに限定されるべきものではない。 The excellent effects of the combination composition according to the present invention will be described more specifically with reference to the following examples. However, the present invention should not be limited to these.
試験例１ 水稲苗の強度及び生育試験
方法
水稲用標準育苗箱（３０ｃｍ×６０ｃｍ×３ｃｍ）に育苗用人口培土を約２．５ｌ敷き詰め、催芽した種籾（品種・コシヒカリ）を播種した。潅水後、直ちに所定濃度になるように予め調製された各有効成分の粒状物を箱あたり５０ｇ均一に散粒し、育苗用人工培土１ｌにより覆土した。その後、育苗箱を加温出芽器に入れ、約３０度で２日間保持した。出芽後、育苗用ビニールハウスに移動し、継続的に苗の生育程度を肉眼観察した。播種３週間後（移植適期）に、茎葉部および根部（いわゆるマット形成程度、特に箱底面、側面の発根量）を肉眼観察した。更に、箱苗の一部（１０ｃｍ×１０ｃｍ）を切り出し、この苗片の破断限界値を測定することで箱苗の強度を評価した。即ち、苗片の一方を固定し、もう一方をメカニカルフォースゲージを用い箱苗を徐々に引っ張り、苗片が破断した時の値を破断限界値（＝引張強度）として測定した。肉眼観察による評価は３反復の平均値、破断限界値測定用苗片（１０ｃｍ×１０ｃｍ）は、各反復２ケ所ずつ合計６片を測定した平均の結果を第１表に示した。
肉眼観察の評価基準：
１＝健全
２＝極軽微な根の生育遅延がみられる
３＝軽微な根の生育遅延がみられるが実用上問題なし
４＝実用上やや問題となる根の生育遅延
５＝実用上問題となる根の生育遅延
箱苗強度の評価基準：
無処理区におけるメカニカルフォースゲージによる引っ張り強度の平均値を１００として、
１＝９５以上
２＝９０以上９５未満
３＝７０以上９０未満
４＝５０以上７０未満
５＝５０未満
Test Example 1 Strength and growth test of paddy rice seedling Method About 2.5 liters of artificial soil for seedling was spread in a standard seedling box for paddy rice (30 cm × 60 cm × 3 cm), and the sown seed pod (cultivar Koshihikari) was sown. Immediately after irrigation, 50 g of each active ingredient granular material prepared in advance so as to have a predetermined concentration was uniformly dispersed per box and covered with 1 l of artificial soil for raising seedlings. Thereafter, the seedling box was placed in a warm germination device and held at about 30 degrees for 2 days. After emergence, the seedlings were transferred to a nursery greenhouse, and the degree of seedling growth was continuously observed with the naked eye. Three weeks after sowing (suitable transplantation period), the foliage and roots (so-called mat formation degree, particularly the amount of rooting on the bottom and side surfaces of the box) were visually observed. Further, a portion (10 cm × 10 cm) of the box seedling was cut out, and the strength of the box seedling was evaluated by measuring the fracture limit value of the seedling. That is, one seedling piece was fixed, and the other seedling was gradually pulled using a mechanical force gauge, and the value when the seedling piece broke was measured as a breaking limit value (= tensile strength). Table 1 shows the average results of the macroscopic observation, and the average value of three repetitions, and the average value obtained by measuring a total of 6 pieces of the seeds for fracture limit value measurement (10 cm × 10 cm) at two repeated locations.
Evaluation criteria for visual observation:
1 = Healthy 2 = Slightly delayed root growth 3 = Slightly delayed root growth but no practical problem 4 = Slightly problematic root growth delay 5 = Practical problem Evaluation criteria for root growth delay seedling strength:
Assuming that the average value of tensile strength by mechanical force gauge in the untreated section is 100,
1 = 95 or more 2 = 90 or more and less than 95 3 = 70 or more and less than 90 4 = 50 or more and less than 70 5 = less than 50
試験例２ イネツトムシに対する防除効果試験
方法
水稲用標準育苗箱で栽培した移植適期のイネ（品種コシヒカリ）にイソチアニル２％（ｗ／ｗ）とフィプロニル１％（ｗ／ｗ）を含む粒剤組成物を箱あたり５０ｇ散布し、軽く潅水後直ちに田植え機を用いて移植した。現地の慣行に従って栽培管理し、移植７０日後に各区６００株について被害株数を計数した。
結果を第２表に示す。
Test Example 2 Control Effect Test Method for Rice Bugs A granule composition containing 2% (w / w) isothianyl and 1% fipronil (w / w) in rice (variety Koshihikari) in an appropriate time for transplantation cultivated in a standard nursery box for rice 50 g per box was sprayed, and after light irrigation, the plants were transplanted using a rice planting machine. Cultivation management was carried out according to local practice, and the number of damaged strains was counted for 600 strains in each ward 70 days after transplantation.
The results are shown in Table 2.
試験例３ イネいもち病に対する防除効果試験
方法
水稲用標準育苗箱で栽培した移植適期のイネ（品種ひとめぼれ）に試験例２と同様の粒剤組成物を箱あたり５０ｇ散布し、軽く潅水後直ちに田植え機を用いて移植した。現地の慣行に従って栽培管理し、移植７２日後に各区１２０株について病斑面積率を調査した。結果を第３表に示す。
Test Example 3 Test Method for Control Effect on Rice Blast Disease 50g of the same granule composition as in Test Example 2 was sprayed on rice (variety Hitomebore) suitable for transplantation cultivated in a standard rice seedling box for paddy rice. Transplanted using a machine. Cultivation management was carried out according to local practices, and the lesion area rate was examined for 120 strains in each ward 72 days after transplantation. The results are shown in Table 3.
製剤例１（微粒剤）
０．２−０．７ｍｍの粒度分布を有する粘土鉱物粒 ８５．５重量部を容器回転型混合機に入れ、回転下に液体希釈剤 １０重量部とともにイソチアニル ２重量部、フィプロニル １重量部を噴霧し、ホワイトカーボン １．５重量部を加え、微粒剤とする。
Formulation Example 1 (fine granules)
Place 85.5 parts by weight of clay mineral particles having a particle size distribution of 0.2-0.7 mm in a rotating container mixer, and spray 10 parts by weight of liquid diluent and 2 parts by weight of isotianil and 1 part by weight of fipronil under rotation. Then, 1.5 parts by weight of white carbon is added to make a fine granule.
製剤例２（微粒剤）
０．２−０．７ｍｍの粒度分布を有する粘土鉱物粒 ８４．５重量部を容器回転型混合機に入れ、回転下に液体希釈剤 １０重量部とともにイソチアニル ２重量部、フィプロニル １重量部、イミダクロプリド １重量部を噴霧し、ホワイトカーボン １．５重量部を加え、微粒剤とする。
Formulation Example 2 (fine granules)
84.5 parts by weight of clay mineral particles having a particle size distribution of 0.2-0.7 mm are placed in a rotating container mixer, and 10 parts by weight of a liquid diluent under rotation, 2 parts by weight of isothianyl, 1 part by weight of fipronil, imidacloprid 1 part by weight is sprayed and 1.5 parts by weight of white carbon is added to form a fine granule.
製剤例３（顆粒状水和剤）
イソチアニル ３０重量部、フィプロニル １５重量部、リグニンスルホン酸ナトリウム塩 １５重量部、ナトリウムベントナイト（モンモリロナイト） １５重量部、焼成珪藻土粉末 １５重量部及びタルク １０重量部を充分に混合し、これにポリオキシアルキレントリスチリルフェニルエーテル硫酸ナトリウム塩 ５重量部を含む水を加えて混練した後、０．５ｍｍのスクリーンを装着した押し出し式造粒機で押出し、乾燥して顆粒状水和剤とする。
Formulation Example 3 (granular wettable powder)
30 parts by weight of isothianyl, 15 parts by weight of fipronil, 15 parts by weight of sodium lignin sulfonate, 15 parts by weight of sodium bentonite (montmorillonite), 15 parts by weight of calcined diatomaceous earth powder and 10 parts by weight of talc are sufficiently mixed, and this is polyoxyalkylene Water containing 5 parts by weight of tristyrylphenyl ether sulfate salt is added and kneaded, and then extruded with an extrusion granulator equipped with a 0.5 mm screen and dried to obtain a granular wettable powder.
Claims (8)
（ｂ）フィプロニル又はエチプロールを組み合わせて含んでなる殺菌殺虫組成物。 (A) 3,4-dichloro-N- (2-cyanophenyl) isothiazole-5-carboxamide;
(B) A bactericidal insecticidal composition comprising a combination of fipronil or etiprol.
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006284626A JP2008100946A (en) | 2006-10-19 | 2006-10-19 | Fungicidal and insecticidal composition |
| CN2007800387864A CN101528040B (en) | 2006-10-19 | 2007-10-06 | Fungicidal and insecticidal composition |
| JP2009532705A JP5346810B2 (en) | 2006-10-19 | 2007-10-06 | Bactericidal insecticidal composition |
| KR1020097007220A KR101466688B1 (en) | 2006-10-19 | 2007-10-06 | Fungicidal and insecticidal composition |
| PCT/EP2007/008688 WO2008046533A2 (en) | 2006-10-19 | 2007-10-06 | Fungicidal and insecticidal composition |
| MYPI20091395 MY151597A (en) | 2006-10-19 | 2007-10-06 | Fungicidal and insecticidal composition |
| TW096138947A TWI448246B (en) | 2006-10-19 | 2007-10-18 | Fungicidal and insecticidal composition |
Applications Claiming Priority (1)
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| JP2006284626A JP2008100946A (en) | 2006-10-19 | 2006-10-19 | Fungicidal and insecticidal composition |
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| JP2008100946A true JP2008100946A (en) | 2008-05-01 |
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| JP2006284626A Pending JP2008100946A (en) | 2006-10-19 | 2006-10-19 | Fungicidal and insecticidal composition |
| JP2009532705A Active JP5346810B2 (en) | 2006-10-19 | 2007-10-06 | Bactericidal insecticidal composition |
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| JP2009532705A Active JP5346810B2 (en) | 2006-10-19 | 2007-10-06 | Bactericidal insecticidal composition |
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| Country | Link |
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| JP (2) | JP2008100946A (en) |
| KR (1) | KR101466688B1 (en) |
| CN (1) | CN101528040B (en) |
| MY (1) | MY151597A (en) |
| TW (1) | TWI448246B (en) |
| WO (1) | WO2008046533A2 (en) |
Cited By (5)
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| JP2011506357A (en) * | 2007-12-11 | 2011-03-03 | バイエル・クロツプサイエンス・アクチエンゲゼルシヤフト | Use of active ingredient combinations to control animal parasites |
| JP2011506359A (en) * | 2007-12-11 | 2011-03-03 | バイエル・クロツプサイエンス・アクチエンゲゼルシヤフト | Active compound combinations |
| WO2012096214A1 (en) * | 2011-01-12 | 2012-07-19 | 日本農薬株式会社 | Plant growth regulator and method for using same |
| CN102726143A (en) * | 2011-04-08 | 2012-10-17 | 住友化学株式会社 | Rice cultivation method and promotion method for rice seed sprouting |
| JP2016531892A (en) * | 2013-10-04 | 2016-10-13 | エフ エム シー コーポレーションＦｍｃ Ｃｏｒｐｏｒａｔｉｏｎ | How to improve plant growth |
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| WO2009015763A1 (en) * | 2007-07-27 | 2009-02-05 | Bayer Cropscience Ag | Ternary active compound combinations |
| CN101480185B (en) * | 2009-01-05 | 2012-01-25 | 深圳诺普信农化股份有限公司 | Pesticide composition with synergistic insecticidal action and use thereof |
| JP6027442B2 (en) * | 2009-10-15 | 2016-11-16 | バイエル・クロップサイエンス・アクチェンゲゼルシャフト | Active compound combinations |
| CA2797216C (en) | 2010-04-27 | 2018-07-24 | Sumitomo Chemical Company, Limited | Pesticidal compositions comprising a carboxamide compound and diamide compound |
| CN102858168B (en) | 2010-04-27 | 2018-04-03 | 住友化学株式会社 | Composition pesticide and application thereof |
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| JP5712504B2 (en) * | 2010-04-27 | 2015-05-07 | 住友化学株式会社 | Pest control composition and use thereof |
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| JP5929482B2 (en) | 2011-05-10 | 2016-06-08 | 住友化学株式会社 | How to promote plant growth |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19750012A1 (en) * | 1997-11-12 | 1999-05-20 | Bayer Ag | Isothiazole carboxamides |
| DE10333373A1 (en) * | 2003-07-23 | 2005-02-10 | Bayer Ag | Fungicidal drug combinations |
| DE10333371A1 (en) * | 2003-07-23 | 2005-02-10 | Bayer Ag | Fungicidal drug combinations |
| JP2007161603A (en) * | 2005-12-09 | 2007-06-28 | Bayer Cropscience Kk | Pest-controlling agent for paddy field |
-
2006
- 2006-10-19 JP JP2006284626A patent/JP2008100946A/en active Pending
-
2007
- 2007-10-06 WO PCT/EP2007/008688 patent/WO2008046533A2/en active Application Filing
- 2007-10-06 MY MYPI20091395 patent/MY151597A/en unknown
- 2007-10-06 JP JP2009532705A patent/JP5346810B2/en active Active
- 2007-10-06 CN CN2007800387864A patent/CN101528040B/en active Active
- 2007-10-06 KR KR1020097007220A patent/KR101466688B1/en active IP Right Grant
- 2007-10-18 TW TW096138947A patent/TWI448246B/en active
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP2011506357A (en) * | 2007-12-11 | 2011-03-03 | バイエル・クロツプサイエンス・アクチエンゲゼルシヤフト | Use of active ingredient combinations to control animal parasites |
| JP2011506359A (en) * | 2007-12-11 | 2011-03-03 | バイエル・クロツプサイエンス・アクチエンゲゼルシヤフト | Active compound combinations |
| WO2012096214A1 (en) * | 2011-01-12 | 2012-07-19 | 日本農薬株式会社 | Plant growth regulator and method for using same |
| CN103313603A (en) * | 2011-01-12 | 2013-09-18 | 日本农药株式会社 | Plant growth regulator and method for using same |
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| CN102726143A (en) * | 2011-04-08 | 2012-10-17 | 住友化学株式会社 | Rice cultivation method and promotion method for rice seed sprouting |
| CN102726143B (en) * | 2011-04-08 | 2015-06-17 | 住友化学株式会社 | Rice cultivation method and promotion method for rice seed sprouting |
| JP2016531892A (en) * | 2013-10-04 | 2016-10-13 | エフ エム シー コーポレーションＦｍｃ Ｃｏｒｐｏｒａｔｉｏｎ | How to improve plant growth |
| JP2019172683A (en) * | 2013-10-04 | 2019-10-10 | エフ エム シー コーポレーションＦｍｃ Ｃｏｒｐｏｒａｔｉｏｎ | Methods for improving plant growth |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20090066290A (en) | 2009-06-23 |
| JP2010506866A (en) | 2010-03-04 |
| JP5346810B2 (en) | 2013-11-20 |
| CN101528040B (en) | 2013-01-02 |
| KR101466688B1 (en) | 2014-11-28 |
| TW200833250A (en) | 2008-08-16 |
| WO2008046533A2 (en) | 2008-04-24 |
| WO2008046533A3 (en) | 2009-01-22 |
| CN101528040A (en) | 2009-09-09 |
| TWI448246B (en) | 2014-08-11 |
| MY151597A (en) | 2014-06-13 |
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