JP2008089395A - Photocatalyst meter, optical power measuring method and sensor head used therein - Google Patents

Photocatalyst meter, optical power measuring method and sensor head used therein Download PDF

Info

Publication number
JP2008089395A
JP2008089395A JP2006270320A JP2006270320A JP2008089395A JP 2008089395 A JP2008089395 A JP 2008089395A JP 2006270320 A JP2006270320 A JP 2006270320A JP 2006270320 A JP2006270320 A JP 2006270320A JP 2008089395 A JP2008089395 A JP 2008089395A
Authority
JP
Japan
Prior art keywords
indicator
laser
measurement
fiber
light
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
JP2006270320A
Other languages
Japanese (ja)
Inventor
Junichi Honda
順一 本多
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HONDA INSTR SERVICE CO Ltd
HONDA INSTRUMENT SERVICE CO Ltd
Original Assignee
HONDA INSTR SERVICE CO Ltd
HONDA INSTRUMENT SERVICE CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by HONDA INSTR SERVICE CO Ltd, HONDA INSTRUMENT SERVICE CO Ltd filed Critical HONDA INSTR SERVICE CO Ltd
Priority to JP2006270320A priority Critical patent/JP2008089395A/en
Publication of JP2008089395A publication Critical patent/JP2008089395A/en
Ceased legal-status Critical Current

Links

Images

Landscapes

  • Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
  • Investigating Or Analysing Materials By The Use Of Chemical Reactions (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide a photocatalyst meter for precisely measuring the concentration of titanium dioxide by hermetically closing an indicator in a light transmissible container without coloring a measuring target to prevent the oxidation of the indicator. <P>SOLUTION: The photocatalyst meter is constituted using a sensor head composed of an indicator housing container for hermetically closing the indicator, the housing part for holding the indicator housing container, a holder having a first through-hole for permitting a UV fiber to pass, a second through-hole for permitting a laser beam to pass and a third through-hole for permitting a light detection fiber detecting the reflected beam of a laser to pass and a contact member provided with a window and coming into contact with the measuring target at the time of measurement. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

本発明は、塗料などに二酸化チタン(TiO2)を添加・混合・複合させた塗料等の中の二酸化チタン濃度を測定する光触媒計及び二酸化チタンの光触媒(殺菌)能力を測定する光触媒能力評価方法並びにそれに用いるセンサヘッドに関する。   The present invention relates to a photocatalyst meter for measuring the titanium dioxide concentration in a paint or the like in which titanium dioxide (TiO2) is added to, mixed with, or combined with a paint, a photocatalytic ability evaluation method for measuring the photocatalytic (sterilization) ability of titanium dioxide, and The present invention relates to a sensor head used therefor.

従来の光触媒計として、特許文献1に、光触媒機能膜の層を有し該膜の表面を着色した被測定材の載置部分に透孔を形成した基台と、該被測定材に対し基台と反対方向の位置に配置したブラックライト・ランプを備え、発光素子又は受光素子を着脱自在に収容するケースを、該被測定材の表面に垂直な軸線上であって該被測定材の表裏に対向して1対設けると共に該被測定材の表面の反射光軸上に対向して1対設けたことを特徴とする光触媒機能評価装置が公開されている。
特開000−62120号公報
As a conventional photocatalyst meter, Patent Document 1 discloses a base having a layer of a photocatalytic functional film and a through-hole formed in a mounting portion of a material to be measured in which the surface of the film is colored, and a base for the material to be measured. A case having a black light lamp arranged at a position opposite to the base and detachably receiving a light emitting element or a light receiving element is disposed on an axis perpendicular to the surface of the material to be measured and on the front and back of the material to be measured A photocatalyst function evaluation apparatus is disclosed in which a pair is provided so as to be opposed to each other and a pair is provided so as to be opposed to the reflected optical axis of the surface of the material to be measured.
Japanese Unexamined Patent Publication No. 000-62120

光触媒能力測定方法として、特許文献2に、 光触媒応用材料の評価試験方法であって、ゼリー状物質又はゼリー状テープからなる粘着体3内にメチレンブルー4を混合させて指示薬2を構成し、この指示薬2を光触媒応用材料からなる評価対象物1の表面に粘着し、この指示薬2のメチレンブルー4の呈色の変化により評価対象物1の光触媒反応性を評価する。評価対象物1が多孔質のものであっても、吸水性が高いものであっても、傾斜していても、光触媒反応を評価することができる。評価対象物1の表面に指示薬2を粘着するだけでよいので、評価対象物1から試験体を切り取る必要がなく、非破壊状態で評価対象物1の光触媒性能を評価することができる光触媒応用材料の評価試験方法が公開されている。
特開2006−3105号公報
As a method for measuring the photocatalytic ability, Patent Document 2 discloses an evaluation test method for photocatalyst applied materials, in which methylene blue 4 is mixed in an adhesive 3 made of a jelly-like substance or a jelly-like tape to constitute an indicator 2, and this indicator 2 is adhered to the surface of the evaluation object 1 made of a photocatalyst-applied material, and the photocatalytic reactivity of the evaluation object 1 is evaluated by a change in coloration of methylene blue 4 of the indicator 2. The photocatalytic reaction can be evaluated regardless of whether the evaluation object 1 is porous, has high water absorption, or is inclined. Since it is only necessary to stick the indicator 2 to the surface of the evaluation object 1, it is not necessary to cut out the specimen from the evaluation object 1, and the photocatalyst application material that can evaluate the photocatalytic performance of the evaluation object 1 in a non-destructive state The evaluation test method is published.
JP 2006-3105 A

しかしながら、特許文献1、2に記載の光触媒機能評価装置、光触媒応用材料の評価試験方法では、測定対象に直接指示薬を着色することをようし、指示薬が空気と触れ、酸化し精度よく、二酸化チタン濃度、光触媒能力を測定することができなかった。   However, in the photocatalyst function evaluation apparatus and the photocatalyst application material evaluation test method described in Patent Documents 1 and 2, the indicator is directly colored with the indicator, and the indicator touches the air and oxidizes with high accuracy. Concentration and photocatalytic ability could not be measured.

そこで、本発明は、測定対象に着色することなく、また指示薬を光透過性の容器に密閉することで、指示薬の酸化を防止し、二酸化チタン濃度、光触媒能力を精度よく測定する光触媒計及び光触媒能力測定方法並びにそれに用いるセンサヘッドを提供することを目的とするものである。   Therefore, the present invention provides a photocatalyst meter and a photocatalyst that accurately measure the titanium dioxide concentration and the photocatalytic ability by preventing the indicator from being oxidized without coloring the measurement object and sealing the indicator in a light-transmitting container. It is an object of the present invention to provide a capability measuring method and a sensor head used therefor.

本発明は、上記の課題を解決するために、指示薬7を入れるスリット3cを有する透過性セル3a及び前記透過性セル3aを密閉する栓3bよりなる指示薬収納容器3と、前記指示薬収納容器3を保持する収納部2f、前記指示薬7に向け、紫外線4fを照射するUVファイバ4aを前記収納部2fまで挿通する第1貫通孔2b、レーザー4gを照射するレーザーファイバ4bを前記収納部2fまで挿通する第2貫通孔2c、レーザー4gの反射光4hを受光する受光ファイバ4cを前記収納部2fまで挿通する第3貫通孔2dを有するホルダー2a及び前記ホルダー2aの測定対象8a側に取り付けられ、照射された紫外線4f、レーザー4gを通す窓2iを設けた測定時に測定対象8aに接触する接触部材2hよりなるセンサヘッド2と、前記指示薬収納容器3を透過し測定対象8aに照射される紫外線4fを生成する紫外線生成部5p、前記指示薬7に照射されるレーザー4gを発生させるレーザー発生部5q、前記指示薬7から反射した反射光4hを検出する光検知部5r、前記光検知部5rで検出した光強度及び検量線データから測定対象8a中の二酸化チタンの濃度を計算し、各構成の動作を制御する制御部5s、前記制御部5sで求められた測定値を表示する表示部5bよりなる計測本体5と、前記紫外線生成部5p、レーザー発生部5qからの紫外線4f、レーザー4g、指示薬7からの反射光4hをそれぞれ通すUVファイバ4a、レーザーファイバ4b、受光ファイバ4cよりなるケーブル4と、からなることを特徴とする光触媒計1の構成とし、
前記透過性セル3aが、石英セルであることを特徴とする前記光触媒計の構成とし、
前記ホルダー2aに設けられたネジ穴2jに支持体6を取り付け、測定時センサヘッド2を固定することを特徴とする前記光触媒計1の構成とし、
二酸化チタンが混合された測定対象8aに、指示薬7が注入され、密閉された石英セルを接触させ、指示薬7入り石英セルを透過させ、測定対象8aに紫外線4fを照射するとともに、レーザー4gを指示薬7に照射し、指示薬7からのレーザー4gの反射光4hを検出し、その反射光4hより得られる測定値を既知濃度の二酸化チタンによる光触媒能力である基準値に照合し、測定対象8a中の二酸化チタンの濃度を測定することを特徴とする光触媒能力測定方法の構成とし、
前記石英セルが、指示薬7を入れるスリット3cを有し、栓3bより密封された指示薬収納容器3であり、前記指示薬収納容器3を保持する収納部2f、前記指示薬7に向け、紫外線4fを照射するUVファイバ4aを前記収納部2fまで挿通する第1貫通孔2b、レーザー4gを照射するレーザーファイバ4bを前記収納部2fまで挿通する第2貫通孔2c、レーザー4gの反射光4hを受光する受光ファイバ4cを前記収納部2fまで挿通する第3貫通孔2dを有するホルダー2a及び前記ホルダー2aの測定対象8a側に取り付けられ、照射された紫外線4f、レーザー4gを通す窓2iを設けた測定時に測定対象8aに接触する接触部材2hよりなるセンサヘッド2に収納され、前記UVファイバ4aから紫外線4fを照射し、前記レーザーファイバ4bからレーザー4gを照射し、前記受光ファイバ4cにより指示薬7からの反射光4hを受光し、反射光4hより測定値を得ることを特徴とする前記光触媒能力測定方法の構成とし、
指示薬収納容器3を保持する収納部2f、前記指示薬7に向け、紫外線4fを照射するUVファイバ4aを前記収納部2fまで挿通する第1貫通孔2b、レーザー4gを照射するレーザーファイバ4bを前記収納部2fまで挿通する第2貫通孔2c、レーザー4gの反射光4hを受光する受光ファイバ4cを前記収納部2fまで挿通する第3貫通孔2dを有するホルダー2a及び前記ホルダー2aの測定対象8a側に取り付けられ、照射された紫外線4f、レーザー4gを通す窓2iを設けた測定時に測定対象8aに接触する接触部材2hよりなる前記光触媒能力測定の測定に用いられるセンサヘッド2の構成とした。
In order to solve the above-mentioned problem, the present invention comprises an indicator storage container 3 comprising a permeable cell 3a having a slit 3c into which an indicator 7 is inserted, and a plug 3b for sealing the permeable cell 3a, and the indicator storage container 3. To the holding portion 2f to be held, the indicator 7, the first through hole 2b through which the UV fiber 4a for irradiating the ultraviolet ray 4f is inserted to the storage portion 2f, and the laser fiber 4b for irradiating the laser 4g to the storage portion 2f. The second through hole 2c, the holder 2a having a third through hole 2d for inserting the light receiving fiber 4c for receiving the reflected light 4h of the laser 4g to the housing portion 2f, and the measurement object 8a side of the holder 2a are attached and irradiated. A sensor head 2 comprising a contact member 2h that comes into contact with the measuring object 8a during measurement, provided with a window 2i through which the ultraviolet ray 4f and laser 4g pass. An ultraviolet light generator 5p that generates ultraviolet light 4f that passes through the indicator container 3 and is irradiated to the measurement target 8a, a laser generator 5q that generates a laser 4g that is irradiated to the indicator 7, and a reflected light reflected from the indicator 7 A light detection unit 5r for detecting 4h, a control unit 5s for calculating the concentration of titanium dioxide in the measurement object 8a from the light intensity and calibration curve data detected by the light detection unit 5r, and controlling the operation of each component, the control UV that transmits the measurement main body 5 including the display unit 5b that displays the measurement value obtained by the unit 5s, the ultraviolet ray generation unit 5p, the ultraviolet ray 4f from the laser generation unit 5q, the laser 4g, and the reflected light 4h from the indicator 7. The configuration of the photocatalyst meter 1 is characterized by comprising a cable 4 comprising a fiber 4a, a laser fiber 4b, and a light receiving fiber 4c.
The permeable cell 3a is a quartz cell, and has a configuration of the photocatalyst meter,
The structure of the photocatalyst meter 1 is characterized in that the support 6 is attached to the screw hole 2j provided in the holder 2a, and the sensor head 2 is fixed during measurement.
The indicator 7 is injected into the measuring object 8a mixed with titanium dioxide, the sealed quartz cell is brought into contact therewith, the quartz cell containing the indicator 7 is transmitted, the measuring object 8a is irradiated with the ultraviolet rays 4f, and the laser 4g is used as the indicator. 7, the reflected light 4 h of the laser 4 g from the indicator 7 is detected, and the measurement value obtained from the reflected light 4 h is collated with a reference value which is a photocatalytic ability of titanium dioxide having a known concentration, and the measurement object 8 a The photocatalytic ability measuring method is characterized by measuring the concentration of titanium dioxide,
The quartz cell is an indicator storage container 3 having a slit 3c for inserting the indicator 7 and sealed from the stopper 3b. The storage portion 2f for holding the indicator storage container 3 and the indicator 7 are irradiated with ultraviolet rays 4f. The first through-hole 2b through which the UV fiber 4a is inserted to the housing part 2f, the second through-hole 2c through which the laser fiber 4b for irradiating the laser 4g to the housing part 2f is received, and the received light that receives the reflected light 4h of the laser 4g Measured at the time of measurement with a holder 2a having a third through hole 2d through which the fiber 4c is inserted to the housing portion 2f and a window 2i through which the irradiated ultraviolet light 4f and laser 4g are attached, attached to the measurement object 8a side of the holder 2a. It is housed in a sensor head 2 made of a contact member 2h that comes into contact with the object 8a, irradiated with ultraviolet rays 4f from the UV fiber 4a, and Irradiating a laser to 4g over Heather fiber 4b, receives reflected light 4h from the indicator 7 by the receiving fiber 4c, a structure of the photocatalyst ability measuring method characterized by obtaining a measured value from the reflected light 4h,
The housing 2f for holding the indicator storage container 3, the UV fiber 4a for irradiating the ultraviolet rays 4f toward the indicator 7, the first through hole 2b for inserting the UV fiber 4a to the housing 2f, and the laser fiber 4b for irradiating the laser 4g are stored. A holder 2a having a second through-hole 2c inserted through the portion 2f, a third through-hole 2d through which the light-receiving fiber 4c receiving the reflected light 4h of the laser 4g is received up to the storage portion 2f, and the measurement object 8a side of the holder 2a The sensor head 2 is used for the measurement of the photocatalytic ability measurement, which includes the contact member 2h that comes into contact with the measurement target 8a at the time of measurement provided with the window 2i through which the attached ultraviolet light 4f and laser 4g are passed.

本発明は、以上の構成であるから以下の効果が得られる。第1に、指示薬を入れるスリットを有する透過性セル及び前記透過性セルを密閉する栓よりなる指示薬収納容器を採用することから、指示薬の酸化が防ぐことができる。また、センサヘッドと本体をケーブルで、接続し、分離したことで測定現場での測定が容易である。   Since this invention is the above structure, the following effects are acquired. 1stly, since the indicator storage container which consists of a permeable cell which has a slit which puts an indicator, and the stopper which seals the said permeable cell is employ | adopted, the oxidation of an indicator can be prevented. Further, since the sensor head and the main body are connected and separated by a cable, measurement at the measurement site is easy.

第2に、透過性セルを石英セルとすることで、透過率を向上させ、測定精度を上げ、より低エネルギーレベルの紫外線で、短時間であっても、精度よく二酸化チタン濃度、光触媒能力を測定することができる。従って、光触媒計をコンパクト、安価に製造できる。   Second, by making the permeable cell a quartz cell, the transmittance is improved, the measurement accuracy is improved, and the titanium dioxide concentration and the photocatalytic ability are accurately obtained even in a short time with a lower energy level of ultraviolet rays. Can be measured. Therefore, the photocatalyst meter can be manufactured in a compact and inexpensive manner.

第3に、カメラ、ビデオ用三脚などの支持体にセンサヘッドを取り付けることができるため、測定点を固定することができ、測定精度が高い。   Third, since the sensor head can be attached to a support such as a camera or a video tripod, the measurement point can be fixed and the measurement accuracy is high.

第4に、センサヘッドに指示薬容器を収納し、光ファイバにより、紫外線、レーザーを照射することから、外部の太陽光、蛍光灯などの光の遮断することができ、外部光の影響を抑え、精度よく測定対象の二酸化チタン濃度、光触媒能力を測定することができる。また、測定対象と接する接触部材2hをゴムなどの弾力がある素材で作成することで、測定対象が平坦でなく、凹凸があっても測定可能である。   Fourthly, the indicator container is housed in the sensor head, and ultraviolet light and laser are irradiated by the optical fiber, so that it is possible to block light such as external sunlight and fluorescent light, and suppress the influence of external light, It is possible to accurately measure the titanium dioxide concentration and the photocatalytic ability of the measurement target. In addition, by creating the contact member 2h in contact with the measurement target with a material having elasticity such as rubber, measurement is possible even if the measurement target is not flat and has unevenness.

光触媒計を提唱するという目的を、指示薬7を入れるスリット3cを有する石英セル及び前記石英セルを密閉する栓3bよりなる指示薬収納容器3と、前記指示薬収納容器3を保持する収納部2f、前記指示薬7に向け、紫外線4fを照射するUVファイバ4aを前記収納部2fまで挿通する第1貫通孔2b、レーザー4gを照射するレーザーファイバ4bを前記収納部2fまで挿通する第2貫通孔2c、レーザー4gの反射光4hを受光する受光ファイバ4cを前記収納部2fまで挿通する第3貫通孔2d、支持体6を取り付けるネジ穴2jを有するホルダー2a及び前記ホルダー2aの測定対象8a側に取り付けられ、照射された紫外線4f、レーザー4gを通す窓2iを設けた測定時に測定対象8aに接触する接触部材2hよりなるセンサヘッド2と、前記指示薬収納容器3を透過し測定対象8aに照射される紫外線4fを生成する紫外線生成部5p、前記指示薬7に照射されるレーザー4gを発生させるレーザー発生部5q、前記指示薬7から反射した反射光4hを検出する光検知部5r、前記光検知部5rで検出した光強度及び検量線データから測定対象8a中の二酸化チタンの濃度を計算し、各構成の動作を制御する制御部5s、前記制御部5sで求められた測定値を表示する表示部5bよりなる計測本体5と、前記紫外線生成部5p、レーザー発生部5qからの紫外線4f、レーザー4g、指示薬7からの反射光4hをそれぞれ通すUVファイバ4a、レーザーファイバ4b、受光ファイバ4cよりなるケーブル4と、からなることを特徴とする光触媒計1の構成とすることで実現した。   For the purpose of proposing a photocatalyst meter, an indicator storage container 3 comprising a quartz cell having a slit 3c for inserting an indicator 7 and a plug 3b for sealing the quartz cell, a storage portion 2f for holding the indicator storage container 3, and the indicator 7, the first through hole 2b through which the UV fiber 4a for irradiating the ultraviolet ray 4f is inserted to the housing part 2f, the second through hole 2c through which the laser fiber 4b for irradiating the laser 4g to the housing part 2f, and the laser 4g. The light receiving fiber 4c that receives the reflected light 4h is inserted into the third through hole 2d through which the receiving portion 2f is inserted, the holder 2a having the screw hole 2j for attaching the support 6 and the measurement object 8a side of the holder 2a. The window 2i through which the ultraviolet ray 4f and the laser 4g are passed is provided with a contact member 2h that comes into contact with the measurement object 8a at the time of measurement. From the head 2, the ultraviolet ray generation unit 5 p that generates the ultraviolet ray 4 f that passes through the indicator storage container 3 and is irradiated to the measurement target 8 a, the laser generation unit 5 q that generates the laser 4 g that is irradiated to the indicator 7, and the indicator 7 A light detection unit 5r that detects the reflected light 4h that has been reflected, and a control unit that calculates the concentration of titanium dioxide in the measurement object 8a from the light intensity and calibration curve data detected by the light detection unit 5r, and controls the operation of each component. 5s, a measurement main body 5 comprising a display unit 5b for displaying the measurement value obtained by the control unit 5s, the ultraviolet ray generation unit 5p, the ultraviolet ray 4f from the laser generation unit 5q, the laser 4g, and the reflected light 4h from the indicator 7. A configuration of the photocatalyst meter 1 including a cable 4 including a UV fiber 4a, a laser fiber 4b, and a light receiving fiber 4c, It was realized in Rukoto.

以下、添付図面に基づき本発明である光触媒計及び光触媒能力測定方法並びにセンサヘッドについて詳細に説明する。   Hereinafter, a photocatalyst meter, a photocatalytic ability measuring method, and a sensor head according to the present invention will be described in detail with reference to the accompanying drawings.

先ず、本発明である光触媒計について詳細に説明する。図1は、本発明である光触媒計の全体模式図である。   First, the photocatalyst meter according to the present invention will be described in detail. FIG. 1 is an overall schematic diagram of a photocatalyst meter according to the present invention.

光触媒計1は、指示薬7を入れるスリット3cを有する透過性セル3a及び前記透過性セル3aを密閉する栓3bよりなる指示薬収納容器3と、センサヘッド2と、計測本体5と、センサヘッド2内部に挿通し、計測本体5と接続するUVファイバ4a、レーザーファイバ4b、受光ファイバ4cよりなるケーブル4からなる。   The photocatalyst meter 1 includes a permeable cell 3a having a slit 3c for inserting an indicator 7 and an indicator storage container 3 comprising a plug 3b for sealing the permeable cell 3a, a sensor head 2, a measurement main body 5, and the inside of the sensor head 2. The cable 4 is composed of a UV fiber 4a, a laser fiber 4b, and a light receiving fiber 4c.

センサヘッド2は、略円柱状で、前記指示薬収納容器3を保持する収納部2f、前記指示薬7に向け、紫外線4fを照射するUVファイバ4aを前記収納部2fまで挿通する第1貫通孔2b、レーザー4gを照射するレーザーファイバ4bを前記収納部2fまで挿通する第2貫通孔2c、レーザー4gの反射光4hを受光する受光ファイバ4cを前記収納部2fまで挿通する第3貫通孔2dを有するホルダー2a及び前記ホルダー2aの測定対象8a側に取り付けられ、照射された紫外線4f、レーザー4gを通す窓2iを設けた測定時に測定対象8aに接触する接触部材2hよりなる。計測本体5は、家庭用100Vにプラグ5aを接続し、電源の供給を受ける。   The sensor head 2 has a substantially cylindrical shape, a storage part 2f for holding the indicator storage container 3, a first through hole 2b for inserting a UV fiber 4a for irradiating ultraviolet light 4f toward the indicator 7 to the storage part 2f, A holder having a second through hole 2c through which the laser fiber 4b for irradiating the laser 4g is inserted to the housing portion 2f, and a third through hole 2d through which the light receiving fiber 4c for receiving the reflected light 4h of the laser 4g is inserted to the housing portion 2f. 2a and a contact member 2h that is attached to the measurement object 8a side of the holder 2a and that is provided with a window 2i through which the irradiated ultraviolet ray 4f and laser 4g pass, and that contacts the measurement object 8a during measurement. The measurement main body 5 connects the plug 5a to a household 100V and receives power supply.

ホルダー2aより少し指示薬収納容器3を突出させるため、一部切り込んだ切欠部2eを設けると、指示薬収納容器3出し入れが容易になる。また、収納部2fをセンサヘッド2の図1に示すように上下まで削り、ストッパ2gを貼り付けると容易に作成することができる。ホルダー2aは、アルミニウムを加工すればよい。   In order to make the indicator storage container 3 protrude slightly from the holder 2a, if the cutout portion 2e cut in part is provided, the indicator storage container 3 can be easily put in and out. Further, the housing portion 2f can be easily created by shaving up and down as shown in FIG. 1 of the sensor head 2 and attaching the stopper 2g. The holder 2a may be made of aluminum.

接触部材2hは、ゴムなどの弾力がある素材で作成すると、測定対象に凹凸が合っても、外部光を遮断し、精度よく、光触媒能力を測定することができる。   When the contact member 2h is made of a material having elasticity such as rubber, even if the measurement object is uneven, the external light is blocked and the photocatalytic ability can be measured with high accuracy.

支持体6は、カメラ、ビデオなどに一般に使用される三脚でよい。ネジ6aをホルダー2aに設けられたネジ穴2jにネジ込み、センサヘッド2を固定することで、測定対象の一点を固定して測定することができる。   The support 6 may be a tripod generally used for cameras, videos, and the like. By screwing the screw 6a into the screw hole 2j provided in the holder 2a and fixing the sensor head 2, it is possible to fix and measure one point of the measurement object.

計測本体5は、指示薬収納容器3を透過し測定対象8aに照射される紫外線4fを生成する紫外線生成部5p、前記指示薬7に照射されるレーザー4gを発生させるレーザー発生部5q、前記指示薬7から反射した反射光4hを検出する光検知部5r、前記光検知部5rで検出した光強度及び検量線データから測定対象8a中の二酸化チタンの濃度を計算し、各構成の動作を制御する制御部5s、前記制御部5sで求められた測定値を表示する表示部5bよりなる。また計測本体5は、家庭用100Vコンセントに接続し、電源の供給を受けることができる。これにより、測定場所で容易に測定が可能で、かつコンパクトな構成であるから、落ち運びが容易である。   The measurement main body 5 includes an ultraviolet ray generation unit 5p that generates ultraviolet rays 4f that pass through the indicator storage container 3 and irradiate the measurement target 8a, a laser generation unit 5q that generates a laser 4g that irradiates the indicator 7, and the indicator 7 A light detection unit 5r that detects the reflected light 4h that has been reflected, and a control unit that calculates the concentration of titanium dioxide in the measurement target 8a from the light intensity and calibration curve data detected by the light detection unit 5r, and controls the operation of each component. 5s, and a display unit 5b for displaying the measurement value obtained by the control unit 5s. Moreover, the measurement main body 5 can be connected to a household 100V outlet and can be supplied with power. As a result, the measurement can be easily performed at the measurement place, and since it has a compact configuration, it can be easily moved down.

ケーブル4は、前記紫外線生成部5p、レーザー発生部5qからの紫外線4f、レーザー4g、指示薬7からの反射光4hをそれぞれ通すUVファイバ4a、レーザーファイバ4b、受光ファイバ4cよりなる。ケーブル4で、センサヘッド2と、計測本体5を接続することで、測定位置に制限されることなく、容易に測定点を手でもって測定、三脚固定して測定することができる。   The cable 4 includes a UV fiber 4a, a laser fiber 4b, and a light receiving fiber 4c through which the ultraviolet ray 4f, laser 4g, and reflected light 4h from the indicator 7 pass, respectively. By connecting the sensor head 2 and the measurement main body 5 with the cable 4, the measurement point can be easily measured by hand and fixed to a tripod without being limited to the measurement position.

図2は、本発明である光触媒計を構成するセンサヘッドの正面図である。第1〜第3貫通孔2b〜2dが見え、透過性セル3aより狭い窓2iが接触部材2hに設けられている。なお、ホルダー2a、接触部材2h、ストッパ2gを一体として、成型し、収納部2fを設けて良い。なお、一点破線A−Aは、図8に示す断面位置を表す。   FIG. 2 is a front view of a sensor head constituting the photocatalyst meter according to the present invention. The first to third through holes 2b to 2d are visible, and a window 2i narrower than the permeable cell 3a is provided in the contact member 2h. Note that the holder 2a, the contact member 2h, and the stopper 2g may be integrally molded to provide the storage portion 2f. A dashed line AA represents the cross-sectional position shown in FIG.

図3は、センサヘッドに指示薬収納容器を収納したときの平面図である。点線で、UVファイバ4a、レーザーファイバ4b、受光ファイバ4cを示した。なお、第1〜第3貫通孔2b〜2dは、ここでは、背面から収納部2fに向け貫通しているが、側面から収納部2fまで設けてもよい。但し、測定対象8aに向け、紫外線、レーザーが垂直に照射されることが望ましい。   FIG. 3 is a plan view when the indicator storage container is stored in the sensor head. The dotted line indicates the UV fiber 4a, the laser fiber 4b, and the light receiving fiber 4c. In addition, although the 1st-3rd through-holes 2b-2d penetrated toward the accommodating part 2f here from the back, you may provide from the side to the accommodating part 2f. However, it is desirable to irradiate the measurement object 8a vertically with ultraviolet rays and a laser.

図4は、センサヘッドの側面図である。なお、一点破線B−Bは、図8に示す断面位置を表す。図5は、センサヘッドの底面図である。ホルダー2aの底面には、三脚などの支持体6と連結固定するネジ穴2jが設けられている。また、三脚などを安定して固定できるように、底面に切欠部2kを設けてもよい。図6は、センサヘッドの背面図である。   FIG. 4 is a side view of the sensor head. A dashed line BB represents the cross-sectional position shown in FIG. FIG. 5 is a bottom view of the sensor head. On the bottom surface of the holder 2a, a screw hole 2j for connecting and fixing to a support 6 such as a tripod is provided. Further, a notch 2k may be provided on the bottom surface so that a tripod or the like can be stably fixed. FIG. 6 is a rear view of the sensor head.

図7は、センサヘッドに指示薬収納容器を収納したときのセンサヘッドの一部分解正面図である。図7Aは、接触部材2hを除いた、センサヘッド2の正面図である。図7Bは、接触部材2h、指示薬収納容器3を除いたときのセンサヘッド2(ホルダー2a)の正面図である。接触部材2h、ストッパ2gは接着材で、ホルダー2aに貼付け、収納部2fを形成し、指示薬収納容器3を保持する。   FIG. 7 is a partially exploded front view of the sensor head when the indicator storage container is stored in the sensor head. FIG. 7A is a front view of the sensor head 2 excluding the contact member 2h. FIG. 7B is a front view of the sensor head 2 (holder 2a) when the contact member 2h and the indicator storage container 3 are removed. The contact member 2h and the stopper 2g are adhesives and are affixed to the holder 2a to form a storage portion 2f and hold the indicator storage container 3.

図8は、センサヘッドの断面図である。図8Aは図2に示す一点破線A−A位置、図8Bは図4に示す一点破線BーB位置の断面である。透過性セル3aには、指示薬7を入れるスリット3cが形成され、栓3bによって指示薬7が密閉される。指示薬は、メチレンブルーが最適であるが、紫外線により変色するものであればよい。UVファイバ4a、レーザーファイバ4b、受光ファイバ4cは、被覆材4eによって被覆されている。   FIG. 8 is a cross-sectional view of the sensor head. 8A is a cross-sectional view taken along the dashed line AA shown in FIG. 2, and FIG. 8B is a cross-sectional view taken along the dashed line BB shown in FIG. In the permeable cell 3a, a slit 3c for inserting the indicator 7 is formed, and the indicator 7 is sealed by the stopper 3b. The indicator is optimally methylene blue, but any indicator that changes color by ultraviolet rays may be used. The UV fiber 4a, the laser fiber 4b, and the light receiving fiber 4c are covered with a covering material 4e.

図9は、本発明である光触媒計を構成する本体の正面図である。主電源5cにより、光触媒計1は起動し、計測開始スイッチ5dにより、レーザーを照射すると共に、指示薬7に反射した反射光をカウントする。紫外線照射開始スイッチ5fにより、紫外線を測定対象8aに照射し、その紫外線強度は、紫外線強度切換スイッチ5gにより変更できる。また、中断スイッチ5eにより、照射、カウントが中断できる。   FIG. 9 is a front view of a main body constituting the photocatalyst meter according to the present invention. The photocatalyst meter 1 is activated by the main power source 5c, and the measurement start switch 5d irradiates the laser and counts the reflected light reflected on the indicator 7. The ultraviolet ray irradiation start switch 5f irradiates the measurement object 8a with ultraviolet rays, and the ultraviolet ray intensity can be changed by the ultraviolet ray intensity changeover switch 5g. Further, irradiation and counting can be interrupted by the interruption switch 5e.

計測本体5で生成され、測定対象8aに照射する紫外線を取り出し、UVファイバ4aが接続される紫外線照射口部5h、及び指示薬7に照射するレーザー、その反射光を受光する受光ファイバ4cが接続されるレーザー照射受光口部5iがある。   The ultraviolet ray that is generated in the measurement main body 5 and irradiates the measurement object 8a is extracted, and the ultraviolet irradiation port 5h to which the UV fiber 4a is connected, the laser that irradiates the indicator 7, and the light receiving fiber 4c that receives the reflected light are connected. There is a laser irradiation receiving portion 5i.

また、カウントされたレーザーの反射光を表示、或いは予め入力された二酸化チタンの光触媒能力と比較し、計算された二酸化チタンの濃度を表示する表示部5bがある。   In addition, there is a display unit 5b that displays the counted reflected light of the laser or compares it with the photocatalytic ability of titanium dioxide input in advance and displays the calculated concentration of titanium dioxide.

図10は、本発明である光触媒計を構成する本体の背面図である。電源として、12VACアダプタからの電源、家庭用100V電源を使用できることから、直流12VACアダプタからの電源を差し込む直流12V差込部5n、家庭用100V電源を差し込む、100V差込部5mがある。   FIG. 10 is a rear view of the main body constituting the photocatalyst meter according to the present invention. Since a power source from a 12 VAC adapter and a household 100 V power source can be used as the power source, there are a DC 12 V plug-in portion 5 n into which a power source from a DC 12 VAC adapter is plugged in and a 100 V plug-in portion 5 m into which a home 100 V power source is plugged.

内部に、紫外線生成用のランプ、レーザー発生部があり、計測本体5内部の温度を冷却するために、換気ファン5kと、送風口が設けられている。また、測定されたデータは、USBポートからパーソナルコンピューターに送ることができ、測定値を計算、管理することができる。   There are a lamp for generating ultraviolet rays and a laser generator inside, and a ventilation fan 5k and an air outlet are provided in order to cool the temperature inside the measurement main body 5. The measured data can be sent from the USB port to the personal computer, and the measured values can be calculated and managed.

次に、本発明である光触媒能力測定方法について詳細に説明する。図11は、本発明である光触媒計で二酸化チタン濃度を測定するときのセンサヘッド部の断面図である。本発明である光触媒能力測定方法は、二酸化チタンが混合された測定対象8a、例えば、壁などの被塗装材8に塗布された塗料、ガラス、建築建材の内塗装、建築外壁材、木材、樹脂、自動車などに使用される各パネル、コンクリート素材、磁気、タイルなどの表面の測定対象8aに、指示薬7が注入され、密閉された透過性セル3aを接触させ、指示薬7入り透過性セル3aを透過させ、測定対象8aに紫外線4fを照射するとともに、レーザー4gを指示薬7に照射し、指示薬7からのレーザー4gの反射光4hを検出し、その反射光4hより得られる測定値を既知濃度の二酸化チタンによる光触媒能力である基準値に照合し、測定対象8a中の二酸化チタンの濃度を測定することを特徴とする。   Next, the photocatalytic ability measuring method according to the present invention will be described in detail. FIG. 11 is a cross-sectional view of the sensor head when the titanium dioxide concentration is measured with the photocatalyst meter according to the present invention. The photocatalytic ability measuring method according to the present invention includes a measuring object 8a mixed with titanium dioxide, for example, a paint, glass, an inner coating of a building material, an outer wall material of a building, wood, a resin applied to a material to be coated 8 such as a wall. The indicator 7 is injected into the measurement object 8a on the surface of each panel, concrete material, magnetism, tile, etc. used for automobiles, and the sealed permeable cell 3a is brought into contact with the permeable cell 3a containing the indicator 7. The measurement object 8a is irradiated with ultraviolet light 4f, the laser 4g is irradiated onto the indicator 7, the reflected light 4h of the laser 4g from the indicator 7 is detected, and the measurement value obtained from the reflected light 4h is obtained with a known concentration. It is characterized in that the concentration of titanium dioxide in the measurement object 8a is measured by collating with a reference value that is the photocatalytic ability of titanium dioxide.

図11は、本発明である光触媒計の測定原理を示す図である。計測本体5内部に設置された制御部で、各構成である 表示部5b、紫外線生成部5p、レーザー発生部5q、反射光4hを受光する光検知部5rを制御し、測定された反射光4hを表示部5bに表示する。また、前記光検知部5rで検出した光強度(カウント数)及び検量線データから測定対象中の二酸化チタンの濃度を計算し、表示部5bで表示することもできる。さらに、USBポート5oから一定時間の光触媒作用による指示薬の色変化を表す反射光4hのカウント数をPC5t(パーソナルコンピューター)に送信し、PC5tで二酸化チタン濃度を計算することもできる。    FIG. 11 is a diagram showing the measurement principle of the photocatalyst meter according to the present invention. The control unit installed inside the measurement main body 5 controls the display unit 5b, the ultraviolet ray generation unit 5p, the laser generation unit 5q, and the light detection unit 5r that receives the reflected light 4h, and the measured reflected light 4h. Is displayed on the display unit 5b. Further, the concentration of titanium dioxide in the measurement target can be calculated from the light intensity (count number) detected by the light detection unit 5r and the calibration curve data, and can be displayed on the display unit 5b. Furthermore, the count number of the reflected light 4h representing the color change of the indicator due to the photocatalytic action for a predetermined time from the USB port 5o can be transmitted to the PC 5t (personal computer), and the titanium dioxide concentration can be calculated by the PC 5t.

図13は、二酸化チタン濃度を計測するために用いられる検量線の一例である。図13Aは、一定濃度のメチレンブルーなどの指示薬7に、既知の二酸化チタンを溶解し、一定時間、一定量の紫外線を照射したときの指示薬7からのレーザーの反射光を測定したデータである。図13Bは、その時のグラフ(検量線グラフ)である。横軸が指示薬7中の二酸化チタン濃度(g/ml)、縦軸か光検知器でカウントされた反射光のカウント数である。   FIG. 13 is an example of a calibration curve used for measuring the titanium dioxide concentration. FIG. 13A shows data obtained by measuring the reflected light of the laser from the indicator 7 when a known titanium dioxide is dissolved in the indicator 7 such as methylene blue at a constant concentration and irradiated with a certain amount of ultraviolet rays for a certain period of time. FIG. 13B is a graph (calibration curve graph) at that time. The horizontal axis represents the titanium dioxide concentration (g / ml) in the indicator 7, and the vertical axis or the number of reflected light counted by the photodetector.

従って、図11Bの検量線グラフと、本発明である光触媒計、及び光触媒能力測定方法で測定した、反射光4hのカウント数を比較することで、測定対象8a中の二酸化チタン濃度を計算することができる。これらは、光触媒能力の基準値として、測定結果と比較してもよいし、制御部5sの基礎データーベースに予め入力し、制御部5sで計算し、測定対象8aの二酸化チタン濃度を表示部5bに表示してもよい。   Therefore, the titanium dioxide concentration in the measurement object 8a is calculated by comparing the calibration curve graph of FIG. 11B with the count number of the reflected light 4h measured by the photocatalyst meter according to the present invention and the photocatalytic ability measurement method. Can do. These may be compared with the measurement result as a reference value of the photocatalytic capacity, or input in advance into the basic database of the control unit 5s and calculated by the control unit 5s, and the titanium dioxide concentration of the measurement target 8a is displayed on the display unit 5b. May be displayed.

本発明である光触媒計の全体模式図である。It is a whole schematic diagram of the photocatalyst meter which is the present invention. 本発明である光触媒計を構成するセンサヘッドの正面図である。It is a front view of the sensor head which comprises the photocatalyst meter which is this invention. センサヘッドに指示薬収納容器を収納したときの平面図である。It is a top view when the indicator storage container is stored in the sensor head. センサヘッドの側面図である。It is a side view of a sensor head. センサヘッドの底面図である。It is a bottom view of a sensor head. センサヘッドの背面図である。It is a rear view of a sensor head. センサヘッドに指示薬収納容器を収納したときのセンサヘッドの一部分解正面図である。It is a partial exploded front view of a sensor head when the indicator storage container is stored in the sensor head. センサヘッドの断面図である。It is sectional drawing of a sensor head. 本発明である光触媒計を構成する本体の正面図である。It is a front view of the main body which comprises the photocatalyst meter which is this invention. 本発明である光触媒計を構成する本体の背面図である。It is a rear view of the main body which comprises the photocatalyst meter which is this invention. 本発明である光触媒計で二酸化チタン濃度を測定するときのセンサヘッド部の断面図である。It is sectional drawing of a sensor head part when measuring a titanium dioxide density | concentration with the photocatalyst meter which is this invention. 本発明である光触媒計の測定原理を示す図である。It is a figure which shows the measurement principle of the photocatalyst meter which is this invention. 二酸化チタン濃度を計測するために用いられる検量線の一例である。It is an example of the calibration curve used in order to measure a titanium dioxide density | concentration.

符号の説明Explanation of symbols

1 光触媒計
2 センサヘッド
2a ホルダー
2b 第1貫通孔
2c 第2貫通孔
2d 第3貫通孔
2e 切欠部
2f 収納部
2g ストッパ
2h 接触部材
2i 窓
2j ネジ穴
2k 切欠部
3 指示薬収納容器
3a 透過性セル
3b 栓
4 ケーブル
4a UVファイバ
4b レーザーファイバ
4c 受光ファイバ
4e 被覆材
4f 紫外線
4g レーザー
4h 反射光
5 計測本体
5a プラグ
5b 表示部
5c 主電源
5d 計測開始スイッチ
5e 中断スイッチ
5f 紫外線照射開始スイッチ
5g 紫外線強度切換スイッチ
5h 紫外線照射口部
5i レーザー照射受光口部
5j スタンバイランプ
5k 換気ファン
5l フューズ
5m 100V差込部
5n 直流12V差込部
5o USBポート
5p 紫外線生成部
5q レーザー発生部
5r 光検知部
5s 制御部
5t PC
6 支持体
6a ネジ
7 指示薬
8 被塗装材
8a 測定対象
DESCRIPTION OF SYMBOLS 1 Photocatalyst meter 2 Sensor head 2a Holder 2b 1st through-hole 2c 2nd through-hole 2d 3rd through-hole 2e Notch part 2f Storage part 2g Stopper 2h Contact member 2i Window 2j Screw hole 2k Notch part 3 Indicator storage container 3a Permeability cell 3b Plug 4 Cable 4a UV fiber 4b Laser fiber 4c Light receiving fiber 4e Coating material 4f Ultraviolet 4g Laser 4h Reflected light 5 Measurement body 5a Plug 5b Display unit 5c Main power supply 5d Measurement start switch 5e Interrupt switch 5f UV irradiation start switch 5g UV intensity switch Switch 5h Ultraviolet irradiation port 5i Laser irradiation light receiving port 5j Standby lamp 5k Ventilation fan 5l Fuse
5m 100V insertion part 5n DC 12V insertion part 5o USB port 5p UV generation part 5q Laser generation part 5r Light detection part 5s Control part 5t PC
6 Support body 6a Screw 7 Indicator 8 Material to be coated 8a Measurement object

Claims (6)

指示薬を入れるスリットを有する透過性セル及び前記透過性セルを密閉する栓よりなる指示薬収納容器と、
前記指示薬収納容器を保持する収納部、前記指示薬に向け、紫外線を照射するUVファイバを前記収納部まで挿通する第1貫通孔、レーザーを照射するレーザーファイバを前記収納部まで挿通する第2貫通孔、レーザーの反射光を受光する受光ファイバを前記収納部まで挿通する第3貫通孔を有するホルダー及び前記ホルダーの測定対象側に取り付けられ、照射された紫外線、レーザーを通す窓を設けた測定時に測定対象に接触する接触部材よりなるセンサヘッドと、
前記指示薬収納容器を透過し測定対象に照射される紫外線を生成する紫外線生成部、前記指示薬に照射されるレーザーを発生させるレーザー発生部、前記指示薬から反射した反射光を検出する光検知部、前記光検知部で検出した光強度及び検量線データから測定対象中の二酸化チタンの濃度を計算し、各構成の動作を制御する制御部、前記制御部で求められた測定値を表示する表示部よりなる計測本体と、
前記紫外線生成部、レーザー発生部からの紫外線、レーザー、指示薬からの反射光をそれぞれ通すUVファイバ、レーザーファイバ、受光ファイバよりなるケーブルと、
からなることを特徴とする光触媒計。
An indicator storage container comprising a permeable cell having a slit for inserting an indicator and a stopper for sealing the permeable cell;
A storage part for holding the indicator storage container, a first through hole for inserting a UV fiber for irradiating ultraviolet rays toward the indicator toward the storage part, a second through hole for inserting a laser fiber for irradiating a laser to the storage part Measured at the time of measurement provided with a holder having a third through-hole through which a receiving fiber for receiving the reflected light of the laser is inserted to the housing and a measurement target side of the holder, and a window through which the irradiated ultraviolet light and laser are passed. A sensor head comprising a contact member that contacts the object;
An ultraviolet ray generator that generates ultraviolet rays that pass through the indicator storage container and irradiate a measurement target; a laser generator that generates a laser that is applied to the indicator; a light detector that detects reflected light reflected from the indicator; From the light intensity detected by the light detection unit and the calibration curve data, the concentration of titanium dioxide in the measurement target is calculated, and the control unit that controls the operation of each component, from the display unit that displays the measurement value obtained by the control unit Measuring body,
A UV fiber, a laser fiber, a cable made of a light receiving fiber, each of which passes the reflected light from the ultraviolet ray generation unit, the laser generation unit, the ultraviolet ray, the laser, and the indicator;
A photocatalyst meter comprising:
前記透過性セルが、石英セルであることを特徴とする請求項1に記載の光触媒計。   The photocatalytic meter according to claim 1, wherein the permeable cell is a quartz cell. 前記ホルダーに設けられたネジ穴に支持体を取り付け、測定時センサヘッドを固定することを特徴とする請求項1又は請求項2に記載の光触媒計。   The photocatalyst meter according to claim 1 or 2, wherein a support is attached to a screw hole provided in the holder, and the sensor head is fixed during measurement. 二酸化チタンが混合された測定対象に、指示薬が注入され、密閉された石英セルを接触させ、指示薬入り石英セルを透過させ、測定対象に紫外線を照射するとともに、レーザーを指示薬に照射し、指示薬からのレーザーの反射光を検出し、その反射光より得られる測定値を既知濃度の二酸化チタンによる光触媒能力である基準値に照合し、測定対象中の二酸化チタンの濃度を測定することを特徴とする光触媒能力測定方法。   An indicator is injected into the measurement target mixed with titanium dioxide, the sealed quartz cell is brought into contact, the quartz cell containing the indicator is transmitted, the measurement target is irradiated with ultraviolet light, and the indicator is irradiated with a laser. It is characterized by detecting the reflected light of the laser and comparing the measured value obtained from the reflected light with a reference value which is the photocatalytic ability of titanium dioxide of known concentration, and measuring the concentration of titanium dioxide in the measurement object Photocatalytic ability measurement method. 前記石英セルが、指示薬を入れるスリットを有し、栓より密封された指示薬収納容器であり、
前記指示薬収納容器を保持する収納部、前記指示薬に向け、紫外線を照射するUVファイバを前記収納部まで挿通する第1貫通孔、レーザーを照射するレーザーファイバを前記収納部まで挿通する第2貫通孔、レーザーの反射光を受光する受光ファイバを前記収納部まで挿通する第3貫通孔を有するホルダー及び前記ホルダーの測定対象側に取り付けられ、照射された紫外線、レーザーを通す窓を設けた測定時に測定対象に接触する接触部材よりなるセンサヘッドに収納され、
前記UVファイバから紫外線を照射し、前記レーザーファイバからレーザーを照射し、前記受光ファイバにより指示薬からの反射光を受光し、反射光より測定値を得ることを特徴とする請求項4に記載の光触媒能力測定方法。
The quartz cell is an indicator storage container having a slit for inserting an indicator and sealed from a stopper,
A storage part for holding the indicator storage container, a first through hole for inserting a UV fiber for irradiating ultraviolet rays toward the indicator toward the storage part, a second through hole for inserting a laser fiber for irradiating a laser to the storage part Measured at the time of measurement provided with a holder having a third through-hole through which a receiving fiber for receiving the reflected light of the laser is inserted to the housing and a measurement target side of the holder, and a window through which the irradiated ultraviolet light and laser are passed. It is housed in a sensor head made of a contact member that comes into contact with the object,
5. The photocatalyst according to claim 4, wherein ultraviolet light is emitted from the UV fiber, laser is emitted from the laser fiber, reflected light from the indicator is received by the light receiving fiber, and a measurement value is obtained from the reflected light. Ability measurement method.
指示薬収納容器を保持する収納部、前記指示薬に向け、紫外線を照射するUVファイバを前記収納部まで挿通する第1貫通孔、レーザーを照射するレーザーファイバを前記収納部まで挿通する第2貫通孔、レーザーの反射光を受光する受光ファイバを前記収納部まで挿通する第3貫通孔を有するホルダー及び前記ホルダーの測定対象側に取り付けられ、照射された紫外線、レーザーを通す窓を設けた測定時に測定対象に接触する接触部材よりなる光触媒能力測定の測定に用いられるセンサヘッド。   A storage part for holding an indicator storage container, a first through hole through which a UV fiber for irradiating ultraviolet rays is directed to the storage part toward the indicator, a second through hole through which a laser fiber for irradiating a laser is inserted to the storage part, Measurement target at the time of measurement provided with a holder having a third through-hole through which a light receiving fiber for receiving the reflected light of the laser is inserted to the housing part and a measurement target side of the holder, and a window through which the irradiated ultraviolet light and laser are passed A sensor head used for measurement of photocatalytic ability measurement comprising a contact member in contact with.
JP2006270320A 2006-10-02 2006-10-02 Photocatalyst meter, optical power measuring method and sensor head used therein Ceased JP2008089395A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2006270320A JP2008089395A (en) 2006-10-02 2006-10-02 Photocatalyst meter, optical power measuring method and sensor head used therein

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2006270320A JP2008089395A (en) 2006-10-02 2006-10-02 Photocatalyst meter, optical power measuring method and sensor head used therein

Publications (1)

Publication Number Publication Date
JP2008089395A true JP2008089395A (en) 2008-04-17

Family

ID=39373707

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2006270320A Ceased JP2008089395A (en) 2006-10-02 2006-10-02 Photocatalyst meter, optical power measuring method and sensor head used therein

Country Status (1)

Country Link
JP (1) JP2008089395A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2019078614A (en) * 2017-10-24 2019-05-23 溝渕 利明 Heat-insulation testing device of heating materials upon hardening
JP2020518787A (en) * 2016-12-23 2020-06-25 サントル ナシオナル ドゥ ラ ルシェルシェ シアンティフィクCentre National De La Recherche Scientifique Infrared detector
US11946851B2 (en) 2014-03-18 2024-04-02 The Regents Of The University Of California Parallel flow cytometer using radiofrequency multiplexing
US11971343B2 (en) 2020-06-26 2024-04-30 Becton, Dickinson And Company Dual excitation beams for irradiating a sample in a flow stream and methods for using same

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000162129A (en) * 1998-11-30 2000-06-16 Shinku Riko Kk Evaluating method and evaluating device of photocatalyst function
JP2002333401A (en) * 2001-05-08 2002-11-22 National Institute Of Advanced Industrial & Technology Measuring method of photocatalyst activity to thin membrane material and its device
JP2003050205A (en) * 2001-05-29 2003-02-21 Toto Ltd Measuring method for photocatalyst decomposition activity
JP2005143500A (en) * 2003-10-20 2005-06-09 Yamaha Motor Co Ltd Enzyme activity measuring apparatus and method for measuring enzyme activity, sample transfer apparatus and color measuring apparatus
JP2006003105A (en) * 2004-06-15 2006-01-05 Ohbayashi Corp Evaluation test method for photocatalyst application material

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000162129A (en) * 1998-11-30 2000-06-16 Shinku Riko Kk Evaluating method and evaluating device of photocatalyst function
JP2002333401A (en) * 2001-05-08 2002-11-22 National Institute Of Advanced Industrial & Technology Measuring method of photocatalyst activity to thin membrane material and its device
JP2003050205A (en) * 2001-05-29 2003-02-21 Toto Ltd Measuring method for photocatalyst decomposition activity
JP2005143500A (en) * 2003-10-20 2005-06-09 Yamaha Motor Co Ltd Enzyme activity measuring apparatus and method for measuring enzyme activity, sample transfer apparatus and color measuring apparatus
JP2006003105A (en) * 2004-06-15 2006-01-05 Ohbayashi Corp Evaluation test method for photocatalyst application material

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11946851B2 (en) 2014-03-18 2024-04-02 The Regents Of The University Of California Parallel flow cytometer using radiofrequency multiplexing
JP2020518787A (en) * 2016-12-23 2020-06-25 サントル ナシオナル ドゥ ラ ルシェルシェ シアンティフィクCentre National De La Recherche Scientifique Infrared detector
JP7248575B2 (en) 2016-12-23 2023-03-29 サントル ナシオナル ドゥ ラ ルシェルシェ シアンティフィク Infrared detector
JP2019078614A (en) * 2017-10-24 2019-05-23 溝渕 利明 Heat-insulation testing device of heating materials upon hardening
US11971343B2 (en) 2020-06-26 2024-04-30 Becton, Dickinson And Company Dual excitation beams for irradiating a sample in a flow stream and methods for using same

Similar Documents

Publication Publication Date Title
JP4933271B2 (en) Handheld device with a disposable element for chemical analysis of multiple specimens
EP2952881B1 (en) Spectrum measuring device, spectrum measuring method, and specimen container
US8821790B2 (en) Diagnostic measuring system
JP2008089395A (en) Photocatalyst meter, optical power measuring method and sensor head used therein
WO2016006362A1 (en) Automatic analysis device
KR20100078710A (en) Absorbance and fluorescence measuring apparatus
JP2008164550A (en) Fluorophotometer
US8077316B2 (en) Chlorine dioxide sensor
JP3839039B2 (en) Passive type diffuse flux sampler and flux measuring device
JP3809176B2 (en) Condensation sensor and method for managing condensed film in sealed space using the condensation sensor
JP2009520986A (en) Luminescent dissolved oxygen sensor for visual confirmation
WO2019127548A1 (en) Light mixing device, ultraviolet light source working indicator, and ultraviolet light source system
JP2007298328A (en) Photocatalyst activity evaluation device
KR101493645B1 (en) Optical dissolved oxygen sensor for safeguarding sensor membrane
JP5015183B2 (en) Antifogging evaluation device and antifogging evaluation method
JP2011185728A (en) Autoanalyzer
JP4080512B2 (en) Passive type flux sampler
JP2002514758A (en) Systems and methods for optical chemical detection
US20080133148A1 (en) Method For Checking Indoor Environment
JP2005121499A (en) Sample cell, optical measuring apparatus, and optical measurement method
JP2003149125A (en) Scattered light measuring device
KR20150001676A (en) External part for a device and device
JP2001514755A (en) Spectrophotometric cuvette
JP2019045149A (en) Functional water concentration sensor
JP2009244047A (en) Sample for ph measurement, ph measurement apparatus and ph measurement method

Legal Events

Date Code Title Description
A621 Written request for application examination

Effective date: 20091001

Free format text: JAPANESE INTERMEDIATE CODE: A621

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20110726

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20110727

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20110926

A131 Notification of reasons for refusal

Effective date: 20111020

Free format text: JAPANESE INTERMEDIATE CODE: A131

A521 Written amendment

Effective date: 20111020

Free format text: JAPANESE INTERMEDIATE CODE: A523

A131 Notification of reasons for refusal

Effective date: 20111108

Free format text: JAPANESE INTERMEDIATE CODE: A131

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20111228

A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20120123

A045 Written measure of dismissal of application

Effective date: 20120525

Free format text: JAPANESE INTERMEDIATE CODE: A045