JP2006333904A - Volatile substance-carrying sheet - Google Patents

Volatile substance-carrying sheet Download PDF

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JP2006333904A
JP2006333904A JP2005158772A JP2005158772A JP2006333904A JP 2006333904 A JP2006333904 A JP 2006333904A JP 2005158772 A JP2005158772 A JP 2005158772A JP 2005158772 A JP2005158772 A JP 2005158772A JP 2006333904 A JP2006333904 A JP 2006333904A
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fragrance
sheet
impregnated
volatile substance
day
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Akihiko Ito
彰彦 伊藤
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AOI TECHNO KK
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AOI TECHNO KK
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a volatile substance-carrying sheet effective for a long period of time by slowly releasing an easy-to-volatilize fragrance in an air sending type fragrance device for aromatherapy capable of selecting the fragrance corresponding to preferences from day to day. <P>SOLUTION: Impregnation with or application of waxes to the weight of a sheet after the impregnation or application is 5% or more. Since the sheet which is impregnated with or applied with 5% or more of waxes can slowly release an easy-to-volatilize fragrance, it can be used as the volatile substance carrying sheet of the easy-to-volatilize fragrance when using the air sending type fragrance device capable of selecting the fragrance according to preferences from day to day. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

本発明は、送風式芳香器の揮散性物質担持シートに関する。更に詳しくは揮散しやすい芳香剤を徐放する揮散性物質担持シートに関する。    The present invention relates to a volatile substance-carrying sheet for a blower type aroma. More specifically, the present invention relates to a volatile material-carrying sheet that gradually releases a fragrance that is volatile.

送風式芳香器は装置が安価でメンテナンスが簡便であるため、アロマテラピー用とし
広く使われている。この装置では好みのエッセンシャルオイル(以下芳香剤と略記する)
を揮散性物質担持シートに滴下して、送風により芳香剤を強制的に揮散させるようになっている。そして、芳香剤として多くの種類が用いられている。
The blower-type aroma device is widely used for aromatherapy because of its low cost and easy maintenance. In this device, favorite essential oil (hereinafter abbreviated as fragrance)
Is dropped onto the volatile substance-carrying sheet, and the fragrance is forcibly volatilized by blowing air. Many kinds of fragrances are used.

しかしながら,芳香剤には揮散性が著しく速いものがあり、これらを用いた場合には短時間で、芳香剤の揮散が完了してしまうという問題があった。    However, some fragrances have extremely fast volatility, and when these are used, there has been a problem that the volatile agents are completely volatilized in a short time.

この問題点を解決するために、芳香器の構造を改造する方法が提案されている(特許文献1)。これは送風機で起こした風を直接揮散性担持シートに当てないようにすると共に、送風機の前面に設けられた担持シート支持部を覆うように空気流出孔を有するカバーを設けて、送風機から生じた風により担持シート支持部とカバーとの間の空間に空気の滞留を起こすことにより芳香剤を徐放する方法である。しかしながら、この方法を用いても改善効果は十分ではない。
特開2001−252343号公報
In order to solve this problem, a method of remodeling the structure of an aroma device has been proposed (Patent Document 1). This prevents the wind generated by the blower from directly hitting the volatile support sheet and provides a cover having an air outflow hole so as to cover the support sheet support provided on the front surface of the blower. In this method, the fragrance is gradually released by causing air to stay in the space between the carrier sheet supporting portion and the cover by wind. However, even if this method is used, the improvement effect is not sufficient.
JP 2001-252343 A

また、揮散性物質の遅散調整剤を用いるいろいろな方法が提案されている(特許文献2〜5)。例えば、特許文献2は揮散性調整物質がワックスであるが、ワックス自身が担持体であり、これと芳香剤を前処理して成型するものである。従って、日により好みの芳香剤を選択して用いることはできない。
特開2003−55104号公報
In addition, various methods using a retarder for controlling volatile substances have been proposed (Patent Documents 2 to 5). For example, in Patent Document 2, the volatility adjusting substance is a wax, but the wax itself is a carrier, and this is pretreated with a fragrance and molded. Therefore, a favorite fragrance cannot be selected and used depending on the day.
JP 2003-55104 A

また、特許文献3においてはパッドに揮散調整物質を塗布又は含浸しているが、水性べース液体薬剤の初期の揮散調整用であり、これも日により好みに応じて芳香剤を選択して用いることはできない。
特開2003−159317号公報
In Patent Document 3, the padding or impregnating substance is applied to the pad, but it is used for the initial volatilization adjustment of the aqueous base liquid medicine. Cannot be used.
JP 2003-159317 A

更に、特許文献4は界面活性剤と芳香剤とが分子錯体を形成することに基づいた揮散速度の抑制法であるが、予め結晶化させて用いる方法であり、操作がわずらわしく、且つ日により好みに応じて芳香剤を選択して用いることはできない。
特開2001−302576号公報
Furthermore, Patent Document 4 is a method for suppressing the volatilization rate based on the formation of a molecular complex between a surfactant and a fragrance, but it is a method that is used after crystallization, which is cumbersome to operate and is liable depending on the day. It is not possible to select and use a fragrance according to the condition.
JP 2001-302576 A

更に、特許文献5は香料を含有した生分解性樹脂組成物であり、これも日により好みに応じて芳香剤を選択して用いることはできない。
特開平11−106629号公報
Furthermore, patent document 5 is a biodegradable resin composition containing a fragrance | flavor, and also this cannot select and use a fragrance | flavor according to liking by day.
JP-A-11-106629

前述のように、日により好みに応じて芳香剤を選択する送風式芳香器において、揮散速度の速い芳香剤を除放する方法は知られていない。 As described above, there is no known method for releasing a fragrance having a high volatilization rate in a blower type fragrance that selects a fragrance according to preference according to the day.

本発明は上記に鑑みなされたもので、日により好みに応じて芳香剤を選択する送風式芳香器において、揮散速度の速い芳香剤を除放する揮散性物質担持シートを提供することを目的とするものである。 The present invention has been made in view of the above, and it is an object of the present invention to provide a volatile substance-carrying sheet that releases a fragrance having a high volatilization rate in a blower-type fragrance that selects a fragrance according to preference according to the day. To do.

本発明者は、上記目的を達成するため鋭意検討した結果、ワックス類をシートに含浸又は塗布することにより、揮散速度の速い芳香剤を徐放することができることを見出し、本発明を完成するに至った。
即ち、本発明は、含浸又は塗布後のシートの全重量に対しワックス類を5%以上含浸又は塗布してなる、揮散速度の速い芳香剤を除放する揮散性物質担持シート、を提供するものである。
As a result of intensive studies to achieve the above object, the present inventor has found that a fragrance having a high volatilization rate can be gradually released by impregnating or applying a wax to a sheet, thereby completing the present invention. It came.
That is, the present invention provides a volatile substance-carrying sheet that releases a fragrance having a high volatilization rate, which is impregnated or coated with 5% or more of waxes based on the total weight of the sheet after impregnation or coating. It is.

本発明は、日により好みに応じて芳香剤を選択する送風式芳香器において、含浸又は塗布後のシートの全重量に対しワックス類を5%以上含浸又は塗布してなる、揮散性物質担持シートを用いることにより、揮散速度の速い芳香剤を除放するという効果を奏する。    The present invention relates to a volatile substance-carrying sheet obtained by impregnating or applying 5% or more of waxes with respect to the total weight of the sheet after impregnation or application in a blower-type aroma device that selects a fragrance according to taste depending on the day. By using, there is an effect of releasing a fragrance having a high volatilization rate.

以下、本発明を詳細に説明する。
本発明に用いられるワックス類とは石油系のパラフィンワックス及びマイクロクリスタリンワックス、あるいは植物系のカルナウバワックス、キャンデリラワックス及び木蝋、あるいは動物系のビーズワックス及び鯨ロウ、更には鉱物系のモンタンワックスや合成系のポリエチレンワックス等を言う。
Hereinafter, the present invention will be described in detail.
The waxes used in the present invention are petroleum-based paraffin wax and microcrystalline wax, plant-based carnauba wax, candelilla wax and wood wax, animal-based bees wax and whale wax, and mineral-based montan wax. And synthetic polyethylene wax.

本発明に用いられる揮散性物質担持シートとはパルプを主体として乾式法又は湿式法で作製された通気性のある厚手のシートを言う。パルプとしては木材パルプである広葉樹あるいは針葉樹のクラフトパルプ又は亜硫酸パルプ、更には非木材パルプがある。パルプ以外の繊維として合成繊維、化学繊維、あるいは天然繊維を含むことができる。また、製紙助剤を含んでも良い。ワックスを水系で含浸する場合にはシート作製時に湿潤紙力を付与しておく必要がある。湿式法で作製する場合は、通常、湿潤紙力剤を内添する。    The volatile substance-carrying sheet used in the present invention refers to a thick sheet having air permeability produced by a dry method or a wet method mainly using pulp. Pulp includes hardwood or softwood kraft pulp or sulfite pulp, which is wood pulp, and non-wood pulp. Synthetic fibers, chemical fibers, or natural fibers can be included as fibers other than pulp. Moreover, a papermaking auxiliary may be included. When the wax is impregnated with an aqueous system, it is necessary to give wet paper strength during sheet preparation. When producing by a wet method, a wet paper strength agent is usually added internally.

本発明において、ワックス類を含浸又は塗布するには、ワックスのエマルジョンあるいは溶液を用いるか、ワックスを溶融してそのまま塗布してもよい。含浸方法としては、ディピング法、サイズプレス法、あるいはスプレー法等を用いることができる。塗布方法としては、ロールコート法、ブレードコート法、ナイフコート法、エアーナイフコート法、あるいはワイヤーバーコート法等を用いることができる。   In the present invention, in order to impregnate or apply the wax, a wax emulsion or solution may be used, or the wax may be melted and applied as it is. As the impregnation method, a dipping method, a size press method, a spray method, or the like can be used. As a coating method, a roll coating method, a blade coating method, a knife coating method, an air knife coating method, a wire bar coating method, or the like can be used.

本発明において、ワックスエマルジョンをシートに含浸する場合に、浸透時間が長くかかる時には浸透促進剤として少量の界面活性剤を用いればよい。 In the present invention, when a sheet is impregnated with a wax emulsion, a small amount of surfactant may be used as a penetration enhancer when the permeation time is long.

本発明において、含浸又は塗布するワックス類の比率は含浸又は塗布後のシートの全重量に対し5%以上が必要である。5%未満では十分な徐放効果が得られない。含浸率は高い方が徐放効果は高くなる。目標とする徐放性能を考慮して含浸率を設定すればよい。 In the present invention, the ratio of the waxes to be impregnated or applied should be 5% or more with respect to the total weight of the sheet after impregnation or application. If it is less than 5%, a sufficient sustained release effect cannot be obtained. The higher the impregnation rate, the higher the sustained release effect. What is necessary is just to set an impregnation rate in consideration of the target sustained release performance.

以下に実施例を挙げて本発明を具体的に説明する。
実施例1及び比較例1
The present invention will be specifically described below with reference to examples.
Example 1 and Comparative Example 1

タッピ離解機でLBSP(サルファテート)を離解し、その後、湿潤紙力剤(荒川化学工業製AF−255)を対パルプ0.5%添加し、坪量850g/m2の手漉きシートを作製した。このシートにパラフィンワックスエマルジョン(荒川化学工業製SPW−116H)を含浸し含浸率30%のシートを得た。送風式芳香器(アルタコーポレーション製アロマブリーズ フレンズ)にこのパラフィンワックスエマルジョン含浸シートと未含浸シートを揮散性物質担持シートとして用い、芳香剤ユーカリプタス(GAIA社製精油)を約0.2g滴下して、送風を開始した。芳香剤の揮散率を重量減少で追跡して表1の結果を得た。パラフィンワックスエマルジョン未含浸シートを用いた場合は芳香剤が20分でおよそ70%が揮散してしまったが、パラフィンワックスエマルジョン含浸シートを用いた場合は70%が揮散するまでに3時間を要し十分な徐放効果を示した。 LBSP (sulfate) was disaggregated with a tapi disaggregator, and then a wet paper strength agent (AF-255 manufactured by Arakawa Chemical Industries) was added to pulp 0.5% to prepare a handsheet having a basis weight of 850 g / m2. This sheet was impregnated with a paraffin wax emulsion (SPW-116H manufactured by Arakawa Chemical Industries) to obtain a sheet having an impregnation ratio of 30%. Using the paraffin wax emulsion impregnated sheet and the non-impregnated sheet as a volatile substance-carrying sheet, about 0.2 g of the fragrance eucalyptus (GAIA essential oil) was dropped on a blower-type aromatizer (Aroma Breeze Friends manufactured by Alta Corporation), Blowing started. The results of Table 1 were obtained by tracking the volatilization rate of the fragrance by weight reduction. When the paraffin wax emulsion non-impregnated sheet was used, about 70% of the fragrance was volatilized in 20 minutes. However, when the paraffin wax emulsion-impregnated sheet was used, it took 3 hours for 70% to volatilize. Sufficient sustained release effect was shown.

Figure 2006333904
実施例2及び比較例2
Figure 2006333904
Example 2 and Comparative Example 2

実施例1及び比較例1においてパラフィンワックスエマルジョンの含浸率を12%とし、芳香剤をオレンジスイート(GAIA社製精油)とした以外は同様に行い、表2の結果を得た。パラフィンワックスエマルジョン未含浸シートを用いた場合は芳香剤が20分でおよそ80%が揮散してしまったが、パラフィンワックスエマルジョン含浸シートを用いた場合は80%が揮散するまでにおよそ2.5時間を要し、十分な徐放効果を示した。 The results of Table 2 were obtained in the same manner as in Example 1 and Comparative Example 1 except that the impregnation ratio of the paraffin wax emulsion was 12% and the fragrance was orange sweet (essential oil manufactured by GAIA). When the paraffin wax emulsion non-impregnated sheet was used, about 80% of the fragrance was volatilized in 20 minutes, but when the paraffin wax emulsion-impregnated sheet was used, about 2.5 hours until 80% was volatilized. Therefore, it showed a sufficient sustained release effect.

Figure 2006333904
実施例3及び比較例3
Figure 2006333904
Example 3 and Comparative Example 3

送風式芳香器(アルタコーポレーション製アロマブリーズ エコミニ)と備え付けのシート及びこれにパラフィンワックスエマルジョンを50%含浸したシートを用い、芳香剤レモン(GAIA社製精油)を約0.15g滴下して、揮散率を追跡し、表3の結果を得た。備え付けシートをそのまま用いた場合は芳香剤が20分でおよそ60%が揮散してしまったが、パラフィンワックスエマルジョン含浸シートを用いた場合は60%が揮散するまでにおよそ4時間を要し、十分な徐放効果を示した。 Ventilation aromatizer (Aroma Breeze Ecomini manufactured by Alta Corporation) and a sheet provided with 50% paraffin wax emulsion impregnated in this, about 0.15 g of fragrance lemon (GAIA essential oil) was dropped and volatilized. The rate was followed and the results in Table 3 were obtained. When the installed sheet was used as it was, about 60% of the fragrance was volatilized in 20 minutes. However, when the paraffin wax emulsion impregnated sheet was used, it took about 4 hours to evaporate, Showed a sustained release effect.

Figure 2006333904
実施例4及び比較例4
Figure 2006333904
Example 4 and Comparative Example 4

揮散性物質担持シートとして乾式パルプ不織布(王子キノクロス社製TDSハトシート)坪量1kg/m2にカルナウバワックスエマルジョン(日本精鑞製EMUSTAR-0413)を含浸して含浸率40%のシートを得た。この含浸シートと未含浸シートを揮散性物質担持シートとして用いた以外は、実施例1及び比較例1の方法を用いて揮散率を測定追跡し、表4の結果を得た。カルナウバワックスエマルジョン未含浸シートを用いた場合は芳香剤が20分で50%強、40分で90%強が揮散してしまったが、カルナウバワックスエマルジョン含浸シートを用いた場合は90%強が揮散するまでに4時間を要し、十分な徐放効果を示した。    As a volatile substance-carrying sheet, a dry pulp nonwoven fabric (TDS pigeon sheet manufactured by Oji Kinocross Co., Ltd.) having a basis weight of 1 kg / m 2 was impregnated with carnauba wax emulsion (EMUSTAR-0413 manufactured by Nippon Seiki) to obtain a sheet having an impregnation rate of 40%. Except for using this impregnated sheet and non-impregnated sheet as the volatile substance-carrying sheet, the volatilization rate was measured and tracked using the methods of Example 1 and Comparative Example 1, and the results shown in Table 4 were obtained. When the carnauba wax emulsion non-impregnated sheet was used, the fragrance was slightly over 50% in 20 minutes and over 90% in 40 minutes, but over 90% when the carnauba wax emulsion-impregnated sheet was used. It took 4 hours to volatilize and showed a sufficient sustained release effect.

Figure 2006333904
実施例5及び比較例5
Figure 2006333904
Example 5 and Comparative Example 5

実施例1で作製した手漉きシートにマイクロクリスタリンワックスエマルジョン(日本精鑞製EMUSTAR-042X)を含浸し含浸率30%のシートを得た。送風式芳香器(アルタコーポレーション製アロマブリーズ エコミニ)にこのシート及び未含浸シートを用い、芳香剤スイートオレンジ(GAIA社製精油)を約0.15g滴下して、揮散率を追跡し、表5の結果を得た。未含浸シート用いた場合は芳香剤が20分で90%弱が揮散してしまったが、マイクロクリスタリンワックスエマルジョン含浸シートを用いた場合は90%弱が揮散するまでにおよそ6時間を要し十分な徐放効果を示した。 The handsheet prepared in Example 1 was impregnated with a microcrystalline wax emulsion (EMUSTAR-042X manufactured by Nippon Seiki) to obtain a sheet with an impregnation rate of 30%. Using this sheet and an unimpregnated sheet to a blower-type aromatizer (Aroma Breeze Ecomini manufactured by Alta Corporation), about 0.15 g of a fragrance sweet orange (GAIA essential oil) was dropped and the volatilization rate was traced. The result was obtained. When the unimpregnated sheet was used, 90% of the fragrance was volatilized in 20 minutes, but when the microcrystalline wax emulsion impregnated sheet was used, it took about 6 hours to evaporate. Showed a sustained release effect.

Figure 2006333904
Figure 2006333904

以上説明してきたように、本発明のワックス類を5%以上含浸又は塗布したシートは揮散しやすい芳香剤を徐放することができるので、日により好みに応じて芳香剤を選択することができる送風式芳香器を用いる際に、揮散しやすい芳香剤の揮散性物質担持シートとして用いることができる。

As described above, since a sheet impregnated or coated with 5% or more of the wax of the present invention can release a fragrance that tends to volatilize, the fragrance can be selected according to taste depending on the day. When using a blower-type aroma, it can be used as a volatile substance-supporting sheet for a fragrance that is easy to volatilize.

Claims (1)

ワックス類が含浸又は塗布後のシートの全重量に対し5%以上含浸又は塗布された送風式芳香器用揮散性物質担持シート。
Volatile substance-carrying sheet for blower-type fragrance, in which wax is impregnated or coated with 5% or more of the total weight of the sheet after impregnation or coating.
JP2005158772A 2005-05-31 2005-05-31 Volatile substance-carrying sheet Pending JP2006333904A (en)

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US9381266B2 (en) 2004-06-24 2016-07-05 Enviroscent, Inc. Scent devices and methods
US9694097B2 (en) 2014-09-29 2017-07-04 Enviroscent, Inc. Coating providing modulated release of volatile compositions
USD800286S1 (en) 2015-07-31 2017-10-17 Enviroscent, Inc. Collection of scent-infused wound sheets
US10596290B2 (en) 2015-06-09 2020-03-24 Enviroscent, Inc. Formed three-dimensional matrix and associated coating providing modulated release of volatile compositions
US10953125B2 (en) 2016-09-30 2021-03-23 Enviroscent, Inc. Articles formed of pulp base materials with modulated scent release

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US9381266B2 (en) 2004-06-24 2016-07-05 Enviroscent, Inc. Scent devices and methods
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