JP2005264370A - Method for modifying and printing fabric - Google Patents
Method for modifying and printing fabric Download PDFInfo
- Publication number
- JP2005264370A JP2005264370A JP2004077617A JP2004077617A JP2005264370A JP 2005264370 A JP2005264370 A JP 2005264370A JP 2004077617 A JP2004077617 A JP 2004077617A JP 2004077617 A JP2004077617 A JP 2004077617A JP 2005264370 A JP2005264370 A JP 2005264370A
- Authority
- JP
- Japan
- Prior art keywords
- chitosan
- printing
- fabric
- paste
- concentration
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Coloring (AREA)
Abstract
Description
本発明は、布帛に複雑な捺染模様を付与する方法に関する。 The present invention relates to a method for imparting a complex printed pattern to a fabric.
従来から布帛に連続的に短時間で多量の模様を形成する機械捺染方法として、フラットスクリ−ン捺染機、ロ−タリ−スクリ−ン捺染機、ロ−ラ−捺染機を用いて、染料を含む着色捺染糊を印捺する方法が知られているが、この方法では、捺染機に搭載される型数により表現可能な模様の色数が限定される問題がある。例えば、搭載可能な型数が１０の場合には、通常の直接捺染方法での模様は１０色の表現となるが、防染法の特殊な方法の一例として、最初に染料を含まない無色の捺染糊を模様状に印捺した後、印捺部分と未印捺部分の上に染料を含む着色捺染糊を印捺する方法を採ると、染料を含まない無色の捺染糊を印捺した模様部分は無色の捺染糊を印捺していない模様部分に比べて淡い色となり、最大９色の濃淡で１８色の模様表現が可能となることが知られている。この方法の応用として、樹脂皮膜を模様状に形成してから着色する方法（特許文献１参照。）が開示されている。しかしながら、この防染法を利用した方法では染料の有効活用が計られず、洗浄時の脱落染料が増えるので染色排水の負荷が増える問題が派生する。 Conventionally, as a mechanical printing method for forming a large amount of pattern continuously in a short time on a fabric, a dye is obtained by using a flat screen printing machine, a rotary screen printing machine, or a roller printing machine. There is known a method for printing a colored printing paste including the above, but this method has a problem that the number of colors of a pattern that can be expressed is limited by the number of molds mounted on the printing machine. For example, when the number of types that can be mounted is 10, the pattern in the normal direct printing method is expressed in 10 colors. After printing the printing paste in a pattern, if you take a method of printing a colored printing paste containing dye on the printed and unprinted parts, a pattern printed with a colorless printing paste that does not contain the dye It is known that the portion has a lighter color than the pattern portion that is not printed with colorless printing paste, and that it is possible to express a pattern of 18 colors with a maximum of 9 colors. As an application of this method, a method of forming a resin film in a pattern and coloring it (see Patent Document 1) is disclosed. However, in this method using the anti-dyeing method, effective utilization of the dye cannot be achieved, and the problem of an increase in the load of the dyeing waste water arises because the amount of the dropping dye during washing increases.
又、カチオン化剤を模様状に形成してから着色する方法（特許文献２参照。）が開示されており、この方法によるアルカリ、尿素、反応染料を含有する着色捺染糊を使用すれば、カチオン化改質された模様部分は濃い色となり、未改質の模様部分は淡い色の模様表現となる。しかしながら、この方法では触媒として強アルカリを使用するためカチオン化剤を含む捺染糊の劣化が早いので、均一の品質を維持するための生産管理上の制約があり、加えて、カチオン化改質した部分の残っている染色座席を封鎖するための正電荷の封鎖剤を用いたマスキング処理を実施し洗浄時の汚染防止を計る等品質維持のための制約がある。この問題の解決策として、カチオン化剤と重合開始触媒を含むｐＨ７．５〜１２又はｐＨ３〜６．５の捺染糊を印捺し、熱処理後、アニオン性染料を含む色糊を印捺し、固着処理を行う方法（特許文献３参照。）が開示されている。しかしながら、この方法では捺染糊の劣化という均一の品質を維持するための生産管理上の制約を解決できても、洗浄時の汚染防止のためのマスキング処理の実施という品質上の制約を解決できていない。 Further, there is disclosed a method of coloring after forming a cationizing agent into a pattern (see Patent Document 2). If a colored printing paste containing an alkali, urea, or reactive dye is used, a cation can be obtained. The modified pattern portion becomes a dark color, and the unmodified pattern portion becomes a light color pattern expression. However, since this method uses a strong alkali as a catalyst, the printing paste containing the cationizing agent is rapidly deteriorated, so there are restrictions on production control for maintaining uniform quality, and in addition, cationization modification is performed. There is a restriction for quality maintenance, such as performing a masking process using a positively-charged blocking agent to block the remaining dyed seat, and preventing contamination during cleaning. As a solution to this problem, printing paste of pH 7.5 to 12 or pH 3 to 6.5 containing a cationizing agent and a polymerization initiation catalyst is printed, and after heat treatment, a color paste containing an anionic dye is printed and fixed. Is disclosed (see Patent Document 3). However, even though this method can solve the production control restriction to maintain uniform quality, which is the deterioration of printing paste, it can solve the quality restriction of masking treatment to prevent contamination during cleaning. Absent.
また、布地等にインクジェットプリンタによる印刷を可能とする印刷適性を付与する処理方法としてキチン・キトサンが０．２〜５重量％、ポリシロキサンが０．５〜５重量％を原液として布地等の繊維材質に応じて水で特定濃度に希釈して処理する方法（特許文献４参照。）が開示されている。しかしながら、用いられた印捺適正剤は布地上に付与されたものであり、繰り返し洗濯し着用にされる実用衣料に要求される品質を満たすことはできない。
本発明は、キトサン酸性溶液を含む処理液を用いて布帛を部分的に前処理して改質した後に捺染することにより、従来の防染法におけるように洗浄時の脱落染料による染色排水の負荷を増加させず、また、カチオン化改質で行われている洗浄時の汚染防止のためのマスキング処理を省略可能であって、しかも、複雑な模様を捺染できる方法を提供することを目的とする。 The present invention provides a load of dyeing wastewater due to a drop-off dye at the time of washing as in the conventional anti-dyeing method, by printing after the fabric is partially pretreated and modified using a treatment liquid containing an acidic solution of chitosan. It is an object of the present invention to provide a method capable of omitting the masking treatment for preventing contamination at the time of washing, which is performed by cationization modification, and capable of printing a complicated pattern. .
本発明者等は上記課題を解決すべく鋭意検討した結果、キトサン酸性溶液とエマルジョン糊の混合液を布帛上に印捺し熱処理することにより印捺された部分が改質され、改質された布帛に、更に反応染料を含む着色捺染糊を印捺すると改質部分が濃い濃度に染着され、未改質の部分が淡く染着されるか、又は、染着されないことを見出し本発明に至った。
即ち、本発明は、布帛にキトサン酸性溶液を含む処理液を模様状に印捺し、熱処理した後、処理後の布帛を反応染料を含む着色捺染糊で模様状に印捺し、処理する布帛の捺染方法である。キトサン酸性溶液を含む処理液中のキトサン濃度は、０．３〜６．０％重量％であることが好ましい。
As a result of intensive studies to solve the above-mentioned problems, the present inventors have modified the printed portion by imprinting a mixed solution of chitosan acidic solution and emulsion paste on the fabric and heat-treating the modified fabric. Further, when a colored printing paste containing a reactive dye is further printed, the modified portion is dyed at a high density, and the unmodified portion is dyed lightly or not, leading to the present invention. It was.
That is, the present invention prints a treatment liquid containing a chitosan acidic solution on a fabric in a pattern, heat-treats the fabric, and then prints the treated fabric in a pattern with a colored printing paste containing a reactive dye to process the fabric. Is the method. The chitosan concentration in the treatment liquid containing the chitosan acidic solution is preferably 0.3 to 6.0% by weight.
本発明では布帛の表面部分を部分的に改質し、改質部分と未改質部分の染着性に差を持たせ、その後捺染することにより、濃く染着される部分、淡く染着される部分、染着されない部分が混在しその外観は複雑に表現され、改質される模様によってはジャガ−ド織物のプリント加工品の如き外観を呈し、或いは又、ゴブラン織物の外観を呈する非常に妙味のある模様を形成することができる。 In the present invention, the surface portion of the fabric is partially modified so that there is a difference in the dyeing property between the modified portion and the unmodified portion, and then the portion to be dyed is darkly dyed by printing. The appearance is complicated and the appearance is complicated, and depending on the pattern to be modified, it may look like a printed product of Jaguar fabric, or it may have the appearance of Gobelin fabric. A delicious pattern can be formed.
本発明でいう布帛とは、その素材が綿、羊毛、絹等の天然繊維、レ−ヨン、ポリノジック、アセテ−ト等の再生繊維、ポリエステル、ナイロン、アクリル等の合成繊維で、これらから選ばれた単一素材の紡績糸の編織物或いは２種以上を混繊した紡績糸の編織物であっても、２種以上の単一素材の紡績糸を交編織したものでもよく、用途に応じて好適に用いることができる。 The fabric referred to in the present invention is selected from natural fibers such as cotton, wool and silk, regenerated fibers such as rayon, polynosic and acetate, and synthetic fibers such as polyester, nylon and acrylic. It may be a single material spun yarn knitted fabric or a spun yarn knitted fabric in which two or more types are mixed, and two or more single material spun yarns may be knitted and woven. It can be used suitably.
本発明で用いるキトサン酸性溶液は、溶質材料であるキトサンが脱アセチル化度７５％以上のもので、平均分子量が１万から３０万の範囲のものから任意に選択できる。キトサンの平均分子量は被染物の染着性には影響を与えない。溶媒に用いる酸は蟻酸、酢酸、乳酸、クエン酸、アジピン酸、グルコン酸、酒石酸などの有機酸から選ばれるが酢酸を用いるのが一般的である。上述のキトサンと有機酸を用いて定法に従ってキトサン酸性溶液を得ることができる。 The acidic solution of chitosan used in the present invention can be arbitrarily selected from those having a deacetylation degree of 75% or more and an average molecular weight in the range of 10,000 to 300,000 as a solute material. The average molecular weight of chitosan does not affect the dyeing property of the article. The acid used for the solvent is selected from organic acids such as formic acid, acetic acid, lactic acid, citric acid, adipic acid, gluconic acid and tartaric acid, but acetic acid is generally used. A chitosan acidic solution can be obtained according to a conventional method using the above-mentioned chitosan and organic acid.
本発明のキトサン酸性溶液を含む処理液は、キトサン酸性溶液とエマルジョン糊の混合物を用いる。キトサン酸性溶液の粘度が３万センチポイズ未満の場合にはミネラルタ−ペンと界面活性剤と水からなるエマルジョン糊を用いるが、キトサン酸性溶液の粘度が３万センチポイズ以上になるとキトサンの流動性が劣り捺染性も低下するので、更に糊剤を添加してキトサン酸性溶液を含む処理液の流動性を変え捺染性を向上させる。
このとき用いる糊剤はｐＨ３．５〜４．５の範囲で相溶性の優れた糊剤で、例えば、カルボキシメチルセルロ−ス、グア−ガム、ブリテイッシュガム、トラガントガム、メチルセルロ−ス、ヒドロキシオキシエチルセルロ−ス等の中から布帛の素材に応じた糊剤を用いることができる。
又、エマルジョン糊に用いる界面活性剤は、水とミネラルタ−ペンを乳化するのに用いる一般の捺染用乳化剤から選ぶことができる。
The treatment liquid containing the chitosan acidic solution of the present invention uses a mixture of a chitosan acidic solution and an emulsion paste. When the viscosity of the chitosan acidic solution is less than 30,000 centipoise, an emulsion paste consisting of mineral tapen, surfactant and water is used. However, when the viscosity of the chitosan acidic solution exceeds 30,000 centipoise, the chitosan fluidity is poor and printing is performed. Therefore, the paste is further added to change the fluidity of the treatment liquid containing the chitosan acidic solution to improve the printing property.
The paste used at this time is a paste having excellent compatibility in the range of pH 3.5 to 4.5. For example, carboxymethyl cellulose, guar gum, British gum, tragacanth gum, methyl cellulose, hydroxyoxyethyl A paste suitable for the material of the fabric can be used from cellulose or the like.
The surfactant used for the emulsion paste can be selected from general emulsifiers for printing used to emulsify water and mineral tapen.
本発明のキトサン酸性溶液を含む処理液中のキトサン濃度は、用いるキトサンの平均分子量にかかわらず０．３〜６．０％の範囲で、処理液による改質部分と未改質部分の所望の染着性差に応じて適宜設定することができる。キトサン濃度が０．３％未満では、用いる反応染料の濃度が低くなると改質部分と未改質部分の染着性差が小さくなるので好ましくなく、又、キトサン濃度を６．０％より高濃度にしても改質部分と未改質部分の染着性の差が大きくならない。 The chitosan concentration in the treatment liquid containing the acidic solution of chitosan of the present invention is in the range of 0.3 to 6.0% regardless of the average molecular weight of the chitosan used, and the desired portions of the modified portion and unmodified portion by the treatment liquid are desired. It can set suitably according to a dyeing property difference. If the chitosan concentration is less than 0.3%, it is not preferable if the concentration of the reactive dye used is low, because the difference in dyeing properties between the modified portion and the unmodified portion becomes small, and the chitosan concentration should be higher than 6.0%. However, the difference in dyeing property between the modified part and the unmodified part does not increase.
本発明のキトサン酸性溶液を含む処理液の調液方法は、先ずミネラルタ−ペンと捺染用乳化剤と水でエマルジョン糊を製造した後、所定の濃度に見合うキトサン酸性溶液にエマルジョン糊を加えて撹拌して改質糊として完成させる。糊剤を用いる時は、所定の濃度に見合うキトサン酸性溶液に５〜１５％の予め調整済みの糊剤溶解溶液とエマルジョン糊を加えて撹拌して完成させる。 The preparation method of the treatment liquid containing the chitosan acidic solution according to the present invention is as follows. First, an emulsion paste is produced with a mineral taper, an emulsifier for printing, and water, and then the emulsion paste is added to the chitosan acidic solution suitable for a predetermined concentration and stirred. And finished as modified glue. When the paste is used, 5 to 15% of a preliminarily prepared paste solution and emulsion paste are added to a chitosan acidic solution corresponding to a predetermined concentration and stirred to complete.
本発明の布帛の捺染方法は先ず、前処理として布帛にキトサン酸性溶液を含む処理液を模様状に印捺した後、乾燥し、次いで熱処理を実施する。印捺はフラットスクリ−ン捺染機、ロ−タリ−スクリ−ン捺染機、ロ−ラ−捺染機を用いる機械捺染でも手捺染でもよく、目的に応じて用いることができる。機械捺染の場合は熱処理工程に進み、手捺染の場合には乾燥終了後、熱処理工程に進む。熱処理は、温度１００〜１１０℃、時間１０〜１５分間の条件で、ル−プスチ−マ−等の一般の機械捺染に用いられる熱処理機等を用いることができる。熱処理が終了した時点で布帛への改質が終了し、前処理が完了する。
印捺時の地張り剤に溶剤性感圧型、または、溶剤性感熱型パ−マネント型地張剤を用いた場合は、改質糊が印捺された布帛の裏面に地張り剤の残留がないので、洗浄、乾燥、幅出しの工程を省略して直ぐに、着色捺染工程に進めることができる。キトサン酸性溶液を含む処理液が残留していても染着には殆ど影響を与えない。
印捺時の地張り剤に水溶性の地張剤を用いる場合は、前述の工程省略を行うと、キトサン酸性溶液を含む処理液が印捺された布帛の裏面に地張り剤が残留するので、引続き実施される着色捺染が均一に出来ない為、洗浄して水溶性地張剤を洗い流し、乾燥した後、幅出しを行ってから着色捺染を行う。
In the textile printing method of the present invention, first, as a pretreatment, a treatment liquid containing a chitosan acidic solution is printed in a pattern on the cloth, followed by drying and then heat treatment. The printing may be mechanical printing using a flat screen printing machine, a rotary screen printing machine, a roller printing machine, or hand printing, and can be used according to the purpose. In the case of mechanical printing, the process proceeds to a heat treatment process. In the case of hand printing, after the drying is completed, the process proceeds to the heat treatment process. For the heat treatment, a heat treatment machine used for general mechanical printing such as a loop steamer can be used under conditions of a temperature of 100 to 110 ° C. and a time of 10 to 15 minutes. When the heat treatment is completed, the modification to the fabric is completed, and the pretreatment is completed.
When solvent-based pressure-sensitive type or solvent-based heat-sensitive permanent type base material is used as the base material during printing, there is no residual adhesive on the back side of the fabric on which the modified glue is printed. Therefore, the process of washing, drying, and tentering can be omitted and the process can be proceeded immediately to the color printing process. Even if the treatment liquid containing the chitosan acidic solution remains, the dyeing is hardly affected.
If a water-soluble adhesive is used as the adhesive at the time of printing, if the above process is omitted, the adhesive remains on the back surface of the fabric on which the treatment liquid containing the chitosan acidic solution is printed. Subsequently, since the colored printing to be carried out cannot be performed uniformly, the washing is performed to wash away the water-soluble base material, and after drying, the tentering is performed and then the colored printing is performed.
本発明の反応染料を含む着色捺染糊は、ほとんどの場合反応染料と、ミネラルタ−ペンと界面活性剤と水からなるエマルジョン糊と水との混合物を用いる。その調液方法は先ずミネラルタ−ペンと捺染用乳化剤と水でエマルジョン糊を製造した後、着色捺染糊全量の６５〜７５％のエマルジョン糊と所定量の反応染料を加えて撹拌しながら残量の水を加えて１００％として完成させる。
スキ−ジ裏の着色捺染糊のたれあとによる捺染斑である糊たれ（雨ふり）の発生を防ぐ為の反応染料を含む着色捺染糊の場合には、ミネラルタ−ペンと界面活性剤と糊剤と水からなるエマルジョン糊と水との混合物を用いる。その調液方法は、着色捺染糊全量の５５〜６５％のエマルジョン糊と５〜１５％の予め調整済みの糊剤溶解溶液を加えた後、所定量の反応染料を加えて撹拌しながら残量の水を加えて１００％として完成させる。
In most cases, the colored printing paste containing the reactive dye of the present invention uses a mixture of reactive dye, emulsion paste composed of mineral turpentine, surfactant and water, and water. The preparation method is as follows. First, an emulsion paste is produced with a mineral taper, a printing emulsifier and water, and then 65 to 75% of the total amount of the colored printing paste and a predetermined amount of reactive dye are added and the remaining amount of the mixture is stirred. Add water to complete 100%.
In the case of colored printing pastes containing reactive dyes to prevent the occurrence of paste (rainfall), which is a printing spot due to dripping of the colored printing paste on the back of the squeegee, a mineral tape, surfactant and paste A mixture of water-based emulsion paste and water is used. The preparation method involves adding 55 to 65% of the emulsion paste and 5 to 15% of the pre-adjusted sizing solution, and then adding the predetermined amount of reactive dye to the remaining amount while stirring. Add 100% of water to complete 100%.
着色捺染糊の印捺はフラットスクリ−ン捺染機、ロ−タリ−スクリ−ン捺染機、ロ−ラ−捺染機を用いる機械捺染でも手捺染でもよく、目的に応じて用いることができる。手捺染の場合には乾燥終了後、熱処理工程に進む。着色捺染後の熱処理は温度１００〜１１０℃、時間１０分間の条件、ル−プスチ−マ−等の一般の機械捺染に使用される熱処理機等を用いることができる。
熱処理後の洗浄、乾燥は、通常の反応染料の洗浄法に従い拡布状で洗浄処理でき、一般の機械捺染に使用される水洗機等を用いることができる。
また、着色捺染の工程では直接捺染法に限らず、防染法や抜染法も併用可能である。
捺染工程が終了した被染物は仕上げ油剤処理等の工程に移るが、これらの工程は特に限定されるものではなく一般的に用いられている方法で行うことができる。
The printing of the colored printing paste may be either a flat screen printing machine, a rotary screen printing machine, a machine printing using a roller printing machine, or a hand printing, and may be used according to the purpose. In the case of hand-printing, the process proceeds to a heat treatment step after drying. The heat treatment after the color printing can be performed at a temperature of 100 to 110 ° C. for 10 minutes, a heat treatment machine used for general mechanical printing such as a loop steamer.
Washing and drying after the heat treatment can be carried out in a spread form according to a usual reactive dye washing method, and a washing machine used for general mechanical printing can be used.
Further, in the color printing process, not only the direct printing method but also an anti-dyeing method or a discharging method can be used in combination.
The article to be dyed after the printing process is transferred to a process such as finishing oil treatment, but these processes are not particularly limited and can be performed by a generally used method.
以下、本発明について実施例により具体的に説明するが、本発明はこの範囲に限定されるものではない。
・染色性の測定方法
染色した試料を捺染ＣＣＭシステム〔型式：ＡＵＣＯＬＯＲ−ＮＦ２、倉敷紡績株式会社製〕を用いて測定し、最大吸収波長における光学濃度Ｋ／Ｓ値を求めた。
EXAMPLES Hereinafter, although an Example demonstrates this invention concretely, this invention is not limited to this range.
-Measuring method of dyeing | staining property The dyed sample was measured using the printing CCM system [model: AUCOLOR-NF2, Kurashiki Boseki Co., Ltd.], and the optical density K / S value in the maximum absorption wavelength was calculated | required.
〔実施例１〕
脱アセチル化度８０％、平均分子量１万のキトサンを用いて、キトサン濃度が２０．０重量％となるように１０重量％の酢酸水溶液に溶解してキトサン酢酸水溶液１０００ｇを調整した。
ミネラルタ−ペン〔商品名：ペガゾ−ル３０４０、エクソンモ−ビル有限会社製〕２５００ｍｌ、界面活性剤〔商品名：ビスコンＤＮ−６０、新中村化学工業株式会社製〕２５０ｇ、界面活性剤〔商品名：ダイナモックＥＲ、大日精化工業株式会社製〕１００ｇに水を加え撹拌しながら５０００ｍｌのエマルジョン糊を製造した。次いで、このエマルジョン糊７００ｇにキトサン酢酸塩水溶液３００ｇを加えて撹拌し、キトサン酢酸水溶液を含む処理液１０００ｇを製造した。処理液中のキトサン濃度は６．０重量％であった。
[Example 1]
Using chitosan having a degree of deacetylation of 80% and an average molecular weight of 10,000, 1000 g of chitosan acetic acid aqueous solution was prepared by dissolving in 10% acetic acid aqueous solution so that the chitosan concentration was 20.0% by weight.
Mineral tape [trade name: Pegasol 3040, manufactured by ExxonMobil Co., Ltd.] 2500 ml, surfactant [trade name: Viscon DN-60, manufactured by Shin-Nakamura Chemical Co., Ltd.] 250 g, surfactant [trade name: Dynamoc ER, manufactured by Dainichi Seika Kogyo Co., Ltd.] Water was added to 100 g, and 5000 ml of emulsion paste was produced with stirring. Next, 300 g of chitosan acetate aqueous solution was added to 700 g of this emulsion paste and stirred to produce 1000 g of a treatment solution containing the chitosan acetic acid aqueous solution. The chitosan concentration in the treatment liquid was 6.0% by weight.
ＪＩＳ Ｌ−０８０３染色堅牢度試験用添付白布に記載されている多繊交織布に、１０００メシュの試験用フラットスクリ−ン型枠を用いて上記キトサンを含有する処理液を用いて全面ベタ柄模様を印捺し、均一に改質した後、シリンダ−乾燥し、試験用スチマ−〔モデル：ＥＰＳ−９００、辻井染機工業株式会社製〕を用い温度１０９℃で１０分間熱処理した後、洗浄し、乾燥した。 Using a processing solution containing chitosan on a multifilament woven fabric described in the attached white fabric for JIS L-0803 dyeing fastness test, using a treatment liquid containing chitosan as described above, a solid pattern pattern After being uniformly modified, cylinder-dried, heat-treated for 10 minutes at a temperature of 109 ° C. using a tester [Model: EPS-900, manufactured by Sakurai Dyeing Machine Co., Ltd.], washed, Dried.
別に、エマルジョン糊７０ｇと黒色反応染料〔商品名：カヤシオン ブラック Ｐ−ＧＳ リキッド４０、日本化薬株式会社製〕８ｇに水を加え１００ｇとし、撹拌して黒色捺染糊を製造した。
同様に、エマルジョン糊７０ｇと赤色反応染料〔商品名：ＫＰ ＣＩＯＮ ＲＥＤ Ｐ−４Ｂ ２５％ ＬＩＱＵＩＤ、紀和化学工業株式会社製〕４ｇに水を加え１００ｇとし、撹拌して赤色捺染糊を製造した。
同様に、エマルジョン糊７０ｇと青色反応染料〔商品名：ＫＰ ＣＩＯＮ ＢＬＵＥ
Ｐ−３ＲＨ、紀和化学工業株式会社製〕４ｇに水を加え１００ｇとし、撹拌して青色捺
染糊を製造した。
キトサンを含有する処理液を用いて全面ベタ柄模様を印捺することにより前処理した多繊交織布に、１０００メシュの試験用フラットスクリ−ン型枠を用いて幅３ｃｍの横ストライプ柄模様を、上記三色の捺染糊を使用して夫々印捺した。印捺後の多繊交織布は、シリンダ−乾燥した後、試験用スチマ−用い温度１０９℃で１０分間熱処理した後、洗浄し、乾燥した。
Separately, 70 g of emulsion paste and black reactive dye [trade name: Kayashion Black P-GS Liquid 40, Nippon Kayaku Co., Ltd.] 8 g were added with water to 100 g, and stirred to produce a black printing paste.
Similarly, water was added to 100 g of emulsion paste 70 g and red reactive dye [trade name: KP CION RED P-4B 25% LIQUID, manufactured by Kiwa Chemical Industry Co., Ltd.] to 100 g and stirred to produce a red printing paste.
Similarly, 70 g of emulsion paste and blue reactive dye [trade name: KP CION BLUE
P-3RH, manufactured by Kiwa Chemical Industry Co., Ltd.] Water was added to 4 g to 100 g, and stirred to produce a blue printing paste.
A multi-mesh woven fabric pretreated by printing a solid pattern with a treatment liquid containing chitosan was used to form a horizontal stripe pattern with a width of 3 cm using a 1000 mesh test flat screen mold. Each of the above three color printing pastes was used for printing. After printing, the multifilament woven fabric was cylinder-dried and then heat-treated at 109 ° C. for 10 minutes using a tester, washed and dried.
染着した多繊交織布の経糸×緯糸が、（１）綿糸×ポリエステル紡績糸の部分、（２）ナイロンフラメント糸×ポリエステル紡績糸の部分、（３）アセテ−トフィラメント糸×ポリエステル紡績糸の部分、（４）梳毛糸×ポリエステル紡績糸の部分、（５）レ−ヨンフィラメント糸×ポリエステル紡績糸の部分、（６）アクリル紡績糸×ポリエステル紡績糸の部分、（７）生糸×ポリエステル紡績糸の部分及び（８）ポリエステル紡績糸×ポリエステル紡績糸の部分の（１）〜（８）の夫々の部分を、捺染ＣＣＭシステムを用いて測定し最大吸収波長における光学濃度Ｋ／Ｓ値を求め、その結果を表1に示した。 The dyed multifilament woven warp x weft is (1) cotton x polyester spun yarn, (2) nylon fragment x polyester spun yarn, (3) acetate filament yarn x polyester spun yarn (4) Wool yarn × Polyester spun yarn portion, (5) Rayon filament yarn × Polyester spun yarn portion, (6) Acrylic spun yarn × Polyester spun yarn portion, (7) Raw yarn × Polyester spun yarn Each part of (1) to (8) of the yarn portion and (8) polyester spun yarn × polyester spun yarn portion is measured using a printing CCM system to determine the optical density K / S value at the maximum absorption wavelength. The results are shown in Table 1.
〔実施例２〕
脱アセチル化度８０％、平均分子量３０万のキトサンを用いて、キトサン濃度が１．５重量％となるように０．７５重量％の酢酸水溶液に溶解してキトサン酢酸水溶液１０００ｇを調整した。
[Example 2]
Using chitosan having a degree of deacetylation of 80% and an average molecular weight of 300,000, 1000 g of an aqueous chitosanacetic acid solution was prepared by dissolving in a 0.75 wt% aqueous acetic acid solution so that the chitosan concentration was 1.5 wt%.
実施例１と同様に、エマルジョン糊を製造し、次いで、このエマルジョン糊7００ｇに予め水に溶解させた４％カルボキシメチルセルロ−ス溶液１００ｇとキトサン酢酸水溶液２００ｇを加えて撹拌し、キトサン酢酸水溶液を含む処理液Ａ（キトサン濃度：０．３重量％）を１０００ｇ製造した。
脱アセチル化度８０％、平均分子量８万のキトサンを用いて、キトサン濃度が６．０重量％となるように３．０重量％の酢酸水溶液に溶解してキトサン酢酸水溶液１０００ｇを調整した。
実施例１と同様のエマルジョン糊８００ｇにキトサン酢酸水溶液２００ｇを加えて撹拌し、キトサン酢酸水溶液を含む処理液Ｂ（キトサン濃度：１．２重量％）１０００ｇを製造した。
脱アセチル化度８０％、平均分子量４万のキトサンを用いて、キトサン濃度が８．０重量％となるように４．０重量％の酢酸水溶液に溶解してキトサン酢酸水溶液１０００ｇを調整した。
実施例１と同様のエマルジョン糊８００ｇにキトサン酢酸水溶液２００ｇを加えて撹拌し、キトサン酢酸水溶液を含む処理液Ｃ（キトサン濃度：１．２重量％）を１０００ｇ製造した。
脱アセチル化度８０％、平均分子量１万のキトサンを用いて、キトサン濃度が２０．０重量％となるように１０．０重量％の酢酸水溶液に溶解してキトサン酢酸水溶液１０００ｇを調整した。
実施例１と同様のエマルジョン糊９４０ｇにキトサン酢酸塩水溶液６０ｇを加えて撹拌し、キトサン酢酸水溶液を含む処理液Ｄ（キトサン濃度：１．２重量％）を１０００ｇ製造した。
脱アセチル化度８０％、平均分子量２３万のキトサンを用いて、キトサン濃度が２．０重量％となるように１０．０重量％の酢酸水溶液に溶解してキトサン酢酸水溶液１０００ｇを調整した。
実施例１と同様のエマルジョン糊３００ｇに予め水に溶解させた４％カルボキシメチルセルロ−ス溶液１００ｇとキトサン酢酸水溶液６００ｇを加えて撹拌し、キトサン酢酸水溶液を含む処理液Ｅ（キトサン濃度：１．２重量％）を１０００ｇ製造した。
前述の脱アセチル化度８０％、平均分子量１万のキトサンを用いたキトサン濃度が２０．０重量％のキトサン酢酸水溶液３００ｇと、実施例１と同様のエマルジョン糊７００ｇを加えて撹拌し、キトサン酢酸水溶液を含む処理液Ｆ（キトサン濃度：６．０重量％）を１０００ｇ製造した。
In the same manner as in Example 1, an emulsion paste was produced, and then 100 g of a 4% carboxymethyl cellulose solution and 200 g of a chitosan acetic acid aqueous solution previously dissolved in water were added to 700 g of the emulsion paste and stirred to obtain an aqueous chitosan acetic acid solution. 1000 g of the treatment liquid A containing (concentration of chitosan: 0.3% by weight) was produced.
Using chitosan having a degree of deacetylation of 80% and an average molecular weight of 80,000, 1000 g of chitosan acetic acid aqueous solution was prepared by dissolving in 3.0% acetic acid aqueous solution so that the chitosan concentration was 6.0% by weight.
200 g of chitosan acetic acid aqueous solution was added to 800 g of the same emulsion paste as in Example 1 and stirred to produce 1000 g of treatment liquid B (chitosan concentration: 1.2 wt%) containing the chitosan acetic acid aqueous solution.
Using chitosan having a degree of deacetylation of 80% and an average molecular weight of 40,000, 1000 g of chitosan acetic acid aqueous solution was prepared by dissolving in 4.0% acetic acid aqueous solution so that the chitosan concentration was 8.0% by weight.
200 g of chitosan acetic acid aqueous solution was added to 800 g of the same emulsion paste as in Example 1 and stirred to produce 1000 g of treatment liquid C (chitosan concentration: 1.2 wt%) containing the chitosan acetic acid aqueous solution.
Using chitosan having a degree of deacetylation of 80% and an average molecular weight of 10,000, 1000 g of chitosan acetic acid aqueous solution was prepared by dissolving in 10.0% acetic acid aqueous solution so that the chitosan concentration was 20.0% by weight.
60 g of chitosan acetate aqueous solution was added to 940 g of the same emulsion paste as in Example 1 and stirred to produce 1000 g of treatment liquid D (chitosan concentration: 1.2 wt%) containing the chitosan acetic acid aqueous solution.
Using chitosan having a degree of deacetylation of 80% and an average molecular weight of 230,000, 1000 g of chitosan acetic acid aqueous solution was prepared by dissolving in 10.0% acetic acid aqueous solution so that the chitosan concentration was 2.0% by weight.
100 g of a 4% carboxymethyl cellulose solution previously dissolved in water and 600 g of a chitosan acetic acid aqueous solution were added to 300 g of the same emulsion paste as in Example 1 and stirred, and a treatment solution E containing a chitosan acetic acid aqueous solution (chitosan concentration: 1. 2 g) was produced.
The chitosan acetic acid aqueous solution 300 g having a deacetylation degree of 80% and an average molecular weight of 10,000 chitosan having a concentration of 20.0% by weight and 700 g of the same emulsion paste as in Example 1 were added and stirred. 1000 g of treatment liquid F containing aqueous solution (chitosan concentration: 6.0% by weight) was produced.
通常の条件で毛焼・糊抜・精練・漂白・マ−セライズした綿１００％の平織物（１４．７５ｔｅｘ×１４．７５ｔｅｘ／９０本／インチ×１００本／インチ）を５０ｃｍ×５０ｃｍの大きさに３６枚切り取って、試料1〜３６とした。
試料１〜１８の夫々を溶剤性感熱型パ−マネント型地張剤〔商品名：ＭＣポリマ−ＰＳ、ＭＣポリマ−ＰＨ、村山研究所製〕１：１配合品を塗布した捺染ベルト上に貼付した後、１０００メシュの試験用フラットスクリ−ン型枠を用いて処理液Ａ〜Ｆで全面ペズリ線柄模様を印捺した後、シリンダ−乾燥し、次いで、試験用スチマ−を用い温度１０９℃で１０分間熱処理した。
50cm x 50cm size 100% cotton plain fabric (14.75 tex x 14.75 tex / 90 pcs / inch x 100 pcs / inch) that has been baked, scoured, scoured, bleached and mercerized under normal conditions 36 were cut out to give samples 1 to 36.
Each of Samples 1 to 18 is pasted on a printing belt coated with a solvent-based heat-sensitive permanent type surface-forming agent (trade name: MC Polymer-PS, MC Polymer-PH, manufactured by Murayama Laboratories) 1: 1 formulation. After that, using a 1000 mesh test flat screen mold, the entire surface was printed with a processing liquid A to F, and then the cylinder was dried, and then a test steamer was used at a temperature of 109 ° C. For 10 minutes.
実施例１と同様の染料を用い、同様の手順で染料濃度８．０％、２．０％及び０．５％の黒色捺染糊、染料濃度４．０％、１．０％及び０．２５％の赤色捺染糊、及び染料濃度４．０％、１．０％及び０．２５％の青色捺染糊を製造した。上記のように処理液Ａ〜Ｆで全面ペズリ線柄模様を印捺した試料1〜１８を溶剤性感熱型パ−ネント型地張剤を塗布した捺染ベルト上に貼付した後、３枚の１０００メシュの試験用フラットスクリ−ン型枠を用いて染料濃度の異なった黒色捺染糊、赤色捺染糊及び青色捺染糊の縦ストライプ柄模様を夫々印捺した後、シリンダ−乾燥し、試験用スチマ−を用い温度１０９℃で１０分間熱処理した後、洗浄し、乾燥した。 A black printing paste having a dye concentration of 8.0%, 2.0% and 0.5% and a dye concentration of 4.0%, 1.0% and 0.25 using the same dye as in Example 1 and the same procedure. % Red printing paste and blue printing paste with dye concentrations of 4.0%, 1.0% and 0.25% were produced. After the samples 1 to 18 on which the entire surface was printed with the treatment liquids A to F as described above were pasted on the printing belt coated with the solvent-based heat-sensitive part type paste, the three pieces of 1000 After printing vertical stripe patterns of black, red, and blue printing pastes with different dye concentrations using a flat screen mold for testing meshes, cylinders are dried, and testers are tested. Was used for 10 minutes at a temperature of 109 ° C., washed and dried.
その結果、全面ペズリ線柄模様の上に、黒色、赤色、青色各色の、濃色、中色、淡色、無色の４本の縦ストライプが交互に並んだ、ペズリ地紋を有する３色相の縦ストライプ柄とペズリ柄の合体した模様の被染物を得た。表２に試料番号、地張剤、処理液濃度、捺染糊の色を記載した。 As a result, three-color vertical stripes with a paizuri pattern, in which four vertical stripes of dark, medium, light, and colorless colors of black, red, and blue are alternately arranged on the entire paisley line pattern. A dyed product having a pattern in which the pattern and the pezuri pattern were combined was obtained. Table 2 shows the sample number, the surface tension agent, the treatment solution concentration, and the color of the printing paste.
試料１９〜３６を捺染ベルト上に水溶性地張剤〔商品名：Ｊポバ−ルＶ、日本酢ビ・ポバ−ル株式会社製〕の水溶液を用いて貼付した後、試料を乾燥させてから、同様に処理液Ａ〜Ｆの全面ペズリ線柄模様を印捺した後、シリンダ−乾燥し、試験用スチマ−を用い温度１０９℃で１０分間熱処理した後、洗浄し、乾燥した。更に、試料１〜１８と同様に染料濃度の異なった黒色捺染糊、赤色捺染糊及び青色捺染糊の縦ストライプ柄模様を夫々印捺し、全面ペズリ線柄模様の上に、黒色、赤色、青色各色の、濃色、中色、淡色、無色の４本の縦ストライプが交互に並んだ、ペズリ地紋を有する３色相の縦ストライプ柄とペズリ柄の合体した模様の被染物を得た。表３に試料番号、地張剤、処理液濃度、捺染糊の色を記載した。 Samples 19 to 36 were affixed on a textile belt using an aqueous solution of a water-soluble base material [trade name: J Poval V, manufactured by Nippon Vinegar Pover Co., Ltd.], and then the sample was dried. After that, the whole surface of the treatment liquids A to F was similarly printed with a paisley line pattern, then dried in a cylinder, heat-treated at 109 ° C. for 10 minutes using a test steamer, washed and dried. Furthermore, as in Samples 1 to 18, black stripes, red stripes, and blue stripes with different dye concentrations were printed with vertical stripe patterns, and black, red, and blue colors on the entire paisley line pattern. Thus, a dyed product having a pattern of three-colored vertical stripes having a pezuri pattern and a pezuri pattern in which four vertical stripes of dark, medium, light and colorless were alternately arranged. Table 3 shows the sample number, the surface tension agent, the treatment solution concentration, and the color of the printing paste.
得られたペズリ線柄模様の上に黒色濃淡３色と無色の縦ストライプ柄模様が重なった被染物は、改質した部分が濃く斑なく捺染され、未改質の部分は淡く捺染され、且つ、染料濃度の減少に伴い濃淡ペズリ線柄模様と縦ストライプ柄模様の外観濃度も漸減した。また、改質部分と未改質部分が無色の縦ストライプ柄は汚染がなく、外観品位に優れた被染物が得られた。 In the dyed product in which the black and light three colors and the colorless vertical stripe pattern are superimposed on the obtained pezuri line pattern, the modified part is printed with dark spots, the unmodified part is printed lightly, and As the dye concentration decreased, the appearance density of the light and dark paisley line pattern and the vertical stripe pattern decreased gradually. Further, the vertical stripe pattern in which the modified portion and the unmodified portion were colorless was not contaminated, and a dyed article excellent in appearance quality was obtained.
改質剤であるキトサン酸性溶液の濃度が１．２％である、平均分子量８万のキトサンを用いた処理液Ｂ、平均分子量４万のキトサンを用いた処理液Ｃ、平均分子量１万のキトサンを用いた処理液Ｄ、平均分子量２３万のキトサンを用いた処理液Ｅのように、平均分子量の異なるキトサンを含む処理液を用いたにもかかわらず、キトサン平均分子量を変えても、改質された部分の染着濃度及び未改質の部分の染着濃度には差が認められなかった。キトサン酸性溶液の濃度が０．３％である処理液Ａで前処理された被染物は、キトサン酸性溶液の濃度が１．２％である処理液で前処理された被染物よりも染着濃度は低いものの、外観品位が劣ることなく濃淡差が認められ、キトサン酸性溶液の濃度が６．０％である処理液Ｆで前処理された被染物は、キトサン酸性溶液の濃度が１．２％である処理液で前処理された被染物よりも染着濃度は高いものの、濃度差４．８％に見合う程の染着差は認められなかった。 Treatment liquid B using chitosan with an average molecular weight of 80,000, treatment liquid C using chitosan with an average molecular weight of 40,000, chitosan with an average molecular weight of 10,000 Even if the chitosan average molecular weight is changed even though the treatment liquid containing chitosan having a different average molecular weight is used, such as the processing liquid D using chitosan and the processing liquid E using chitosan having an average molecular weight of 230,000 There was no difference between the dyeing density of the treated part and the dyeing density of the unmodified part. The dyed article pretreated with the treatment liquid A having a chitosan acidic solution concentration of 0.3% is more dyed than the dyed article pretreated with the treatment liquid having a chitosan acidic solution concentration of 1.2%. However, the density of the chitosan acidic solution is 1.2% in the dyed product pretreated with the processing solution F in which the concentration of the chitosan acidic solution is 6.0%. Although the dyeing density was higher than that of the article pretreated with the treatment liquid, a dyeing difference corresponding to the density difference of 4.8% was not recognized.
得られたペズリ線柄模様の上に赤色濃淡３色と無色の縦ストライプ柄模様が重なった被染物は、改質した部分は濃く斑なく捺染され、染料濃度４．０％と１．０％の未改質の部分は薄く捺染され、染料濃度０．５％の未改質の部分は白く残り、且つ、染料濃度の減少に伴い濃淡ペズリ線柄模様の外観濃度も漸減した。また、改質部分と未改質部分が無色の縦ストライプ柄は汚染がなく、外観品位に優れた被染物が得られた。更にまた、改質剤であるキトサン酸性溶液の濃度が１．２％である処理液Ｂ、処理液Ｃ、処理液Ｄ、処理液Ｅで前処理された被染物は、平均分子量の異なるキトサンを含む処理液を用いているにも係わらず、改質された部分の染着濃度及び未改質の部分の染着濃度には差が認められなかった。キトサン酸性溶液の濃度が０．３％である処理液Ａで前処理された被染物は、キトサン酸性溶液の濃度が１．２％である処理液で前処理された被染物よりも染着濃度は低いものの、外観品位が劣ることなく濃淡差が認められ、キトサン酸性溶液の濃度が６．０％である処理液Ｆで前処理された被染物は、キトサン酸性溶液の濃度が１．２％である処理液で前処理された被染物よりも染着濃度は高いものの、濃度差４．８％に見合う程の染着差は認められなかった。 In the dyed article in which the red and light three colors and the colorless vertical stripe pattern are overlapped on the obtained pezuri line pattern, the modified part is printed with dark spots, and the dye concentration is 4.0% and 1.0%. The unmodified portion was printed thinly, the unmodified portion having a dye concentration of 0.5% remained white, and the appearance density of the light and dark paisley line pattern gradually decreased as the dye concentration decreased. Further, the vertical stripe pattern in which the modified portion and the unmodified portion were colorless was not contaminated, and a dyed article excellent in appearance quality was obtained. Furthermore, the pre-treated with the treatment liquid B, the treatment liquid C, the treatment liquid D, and the treatment liquid E in which the concentration of the chitosan acidic solution as a modifier is 1.2% is different from chitosan having a different average molecular weight. Despite the use of the treatment liquid containing, no difference was observed in the dyeing concentration of the modified part and the dyeing density of the unmodified part. The dyed article pretreated with the treatment liquid A having a chitosan acidic solution concentration of 0.3% is more dyed than the dyed article pretreated with the treatment liquid having a chitosan acidic solution concentration of 1.2%. However, the density of the chitosan acidic solution is 1.2% in the dyed product pretreated with the processing solution F in which the concentration of the chitosan acidic solution is 6.0%. Although the dyeing density was higher than that of the article pretreated with the treatment liquid, a dyeing difference corresponding to the density difference of 4.8% was not recognized.
得られたペズリ線柄模様の上に青色濃淡３色と無色の縦ストライプ柄模様が重なった被染物は、改質した部分は濃く斑なく捺染され、染料濃度４．０％の未改質の部分は薄く捺染され、染料濃度１．０％と染料濃度０．５％の未改質の部分は白く残り、且つ、染料濃度の減少に伴い濃淡ペズリ線柄模様の外観濃度も漸減した。また、改質部分と未改質部分が無色の縦ストライプ柄は汚染がなく、外観品位に優れた被染物が得られた。更にまた、改質剤であるキトサン酸性溶液の濃度が１．２％であり、平均分子量の異なるキトサンを含む処理液Ｂ、処理液Ｃ、処理液Ｄ、処理液Ｅで前処理された被染物の改質された部分の染着濃度及び未改質の部分の染着濃度には差が認められなかった。キトサン酸性溶液の濃度が０．３％である処理液Ａで前処理された被染物は、キトサン酸性溶液の濃度が１．２％である処理液で前処理された被染物よりも染着濃度は低いものの、外観品位が劣ることなく濃淡差が認められ、キトサン酸性溶液の濃度が６．０％である処理液Ｆで前処理された被染物は、キトサン酸性溶液の濃度が１．２％である処理液で前処理された被染物よりも染着濃度は高いものの、濃度差４．８％に見合う程の染着差は認められなかった。 In the dyed product in which the three-colored blue and light color stripes and the colorless vertical stripe pattern are overlapped on the obtained pezuri line pattern, the modified part is printed darkly and without unevenness, and the unmodified with a dye concentration of 4.0%. The portion was printed thinly, the unmodified portions with a dye concentration of 1.0% and a dye concentration of 0.5% remained white, and as the dye concentration decreased, the appearance density of the light and dark paisley line pattern gradually decreased. Further, the vertical stripe pattern in which the modified portion and the unmodified portion were colorless was not contaminated, and a dyed article excellent in appearance quality was obtained. Furthermore, the density | concentration of the chitosan acidic solution which is a modifier is 1.2%, and the to-be-processed object pre-processed with the processing liquid B containing the chitosan from which average molecular weight differs, the processing liquid C, the processing liquid D, and the processing liquid E There was no difference between the dyeing concentration of the modified part and the dyeing density of the unmodified part. The dyed article pretreated with the treatment liquid A having a chitosan acidic solution concentration of 0.3% is more dyed than the dyed article pretreated with the treatment liquid having a chitosan acidic solution concentration of 1.2%. However, the density of the chitosan acidic solution is 1.2% in the dyed product pretreated with the processing solution F in which the concentration of the chitosan acidic solution is 6.0%. Although the dyeing density was higher than that of the article pretreated with the treatment liquid, a dyeing difference corresponding to the density difference of 4.8% was not recognized.
本発明の捺染方法で得られた被染物は、改質部分と未改質部分が濃淡差を持って染着され、その外観を複雑に表現することを可能とし、製品に高級感を与え捺染工業の発展に大いに寄与できる。 The to-be-dyed product obtained by the printing method of the present invention has a modified portion and an unmodified portion that are dyed with a difference in light and shade, making it possible to express the appearance in a complex manner, and giving the product a high-class feeling. It can greatly contribute to industrial development.
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004077617A JP2005264370A (en) | 2004-03-18 | 2004-03-18 | Method for modifying and printing fabric |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004077617A JP2005264370A (en) | 2004-03-18 | 2004-03-18 | Method for modifying and printing fabric |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2005264370A true JP2005264370A (en) | 2005-09-29 |
Family
ID=35089212
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004077617A Pending JP2005264370A (en) | 2004-03-18 | 2004-03-18 | Method for modifying and printing fabric |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2005264370A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100785701B1 (en) | 2006-05-12 | 2007-12-17 | (주)빗살무늬 | The pretreatment agent containing chitosan for cotton fiber in ink-jet printing and its treating method |
| CN102168385A (en) * | 2011-03-03 | 2011-08-31 | 上海嘉麟杰纺织品股份有限公司 | Method for dyeing chitosan fabrics by vegetable dyes |
| CN105019274A (en) * | 2015-08-18 | 2015-11-04 | 青岛大学 | Method for improving reactive dye ground color white resist printing effect of pure cotton fabric |
| CN112647319A (en) * | 2020-11-24 | 2021-04-13 | 长胜纺织科技发展(上海)有限公司 | Transfer dyeing reactive dye ink and application thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6385186A (en) * | 1986-09-24 | 1988-04-15 | 大同マルタ染工株式会社 | Dyeing of cellulosic fiber cloth |
| JPH04248151A (en) * | 1991-01-25 | 1992-09-03 | Hitachi Ltd | Magnetic recording and reproducing device |
| JPH05186945A (en) * | 1992-01-13 | 1993-07-27 | Fuji Spinning Co Ltd | Nonwoven fabric |
| JPH06207383A (en) * | 1993-01-08 | 1994-07-26 | Kanebo Ltd | Multicolor printed fabric and its production |
| JPH0813341A (en) * | 1994-06-27 | 1996-01-16 | Fuji Spinning Co Ltd | Method for processing cellulosic fabric |
| JPH0827675A (en) * | 1994-07-13 | 1996-01-30 | Fuji Spinning Co Ltd | Method for improving strike through of polynosic fabric |
| JP2001146688A (en) * | 1999-08-10 | 2001-05-29 | Hi-Tech Enterprise:Kk | Treatment of cloth or the like for improving printability and treatment solution for improving printability |
-
2004
- 2004-03-18 JP JP2004077617A patent/JP2005264370A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6385186A (en) * | 1986-09-24 | 1988-04-15 | 大同マルタ染工株式会社 | Dyeing of cellulosic fiber cloth |
| JPH04248151A (en) * | 1991-01-25 | 1992-09-03 | Hitachi Ltd | Magnetic recording and reproducing device |
| JPH05186945A (en) * | 1992-01-13 | 1993-07-27 | Fuji Spinning Co Ltd | Nonwoven fabric |
| JPH06207383A (en) * | 1993-01-08 | 1994-07-26 | Kanebo Ltd | Multicolor printed fabric and its production |
| JPH0813341A (en) * | 1994-06-27 | 1996-01-16 | Fuji Spinning Co Ltd | Method for processing cellulosic fabric |
| JPH0827675A (en) * | 1994-07-13 | 1996-01-30 | Fuji Spinning Co Ltd | Method for improving strike through of polynosic fabric |
| JP2001146688A (en) * | 1999-08-10 | 2001-05-29 | Hi-Tech Enterprise:Kk | Treatment of cloth or the like for improving printability and treatment solution for improving printability |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100785701B1 (en) | 2006-05-12 | 2007-12-17 | (주)빗살무늬 | The pretreatment agent containing chitosan for cotton fiber in ink-jet printing and its treating method |
| CN102168385A (en) * | 2011-03-03 | 2011-08-31 | 上海嘉麟杰纺织品股份有限公司 | Method for dyeing chitosan fabrics by vegetable dyes |
| CN105019274A (en) * | 2015-08-18 | 2015-11-04 | 青岛大学 | Method for improving reactive dye ground color white resist printing effect of pure cotton fabric |
| CN112647319A (en) * | 2020-11-24 | 2021-04-13 | 长胜纺织科技发展(上海)有限公司 | Transfer dyeing reactive dye ink and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Holme | Coloration of technical textiles | |
| US20210285154A1 (en) | Method facilitating textile preparation for direct-to-garment printing | |
| CN1297705C (en) | Process for patterning textile materials and fabrics made therefrom | |
| US6214417B1 (en) | Cloth for ink-jet printing, method of fabricating same, and method of ink-jet printing same | |
| JPH1181163A (en) | Fabric for ink-jet print dyeing, its production and printing thereof | |
| JP2006200045A (en) | Method for dyeing level dyed fabric | |
| KR100436525B1 (en) | The pretreating agent for polyester fiber in ink-jet printing and its treating method | |
| JP2005264370A (en) | Method for modifying and printing fabric | |
| JP2000096439A (en) | Etching agent for synthetic textile material and etching processing | |
| Hassabo et al. | Acrylic fabric printing with different techniques | |
| JP2015214778A (en) | Method of producing fiber product | |
| EP1905888A1 (en) | Printing process on textile products made of cotton, other natural cellulosic fibers and mixed thereof, and textile products thus obtained | |
| JPH0253976A (en) | Dyeing of cloth | |
| CN114687227A (en) | Cotton/polyamide fabric ink-jet printing treatment process and pretreating agent | |
| US20020138920A1 (en) | Process for printing textile material | |
| US4822376A (en) | Printed bleeding madras | |
| CN113699810A (en) | Method for improving permeability of ink-jet printing | |
| JP2005273108A (en) | Method for printing cellulosic fiber cloth | |
| JP5974051B2 (en) | Textile manufacturing method | |
| JPS6385186A (en) | Dyeing of cellulosic fiber cloth | |
| JP7456632B2 (en) | Automotive interior fabric and method for manufacturing automotive interior fabric | |
| JPH0247378A (en) | Method for improving appearance quality of printed fabric | |
| JPH09268484A (en) | Napped fabric for printing, its printing and printed material | |
| JPH055953B2 (en) | ||
| JP2959691B2 (en) | Inkjet printing method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20070112 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20100621 |
|
| A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20101021 |