JP2005246294A5 - - Google Patents
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- JP2005246294A5 JP2005246294A5 JP2004062160A JP2004062160A JP2005246294A5 JP 2005246294 A5 JP2005246294 A5 JP 2005246294A5 JP 2004062160 A JP2004062160 A JP 2004062160A JP 2004062160 A JP2004062160 A JP 2004062160A JP 2005246294 A5 JP2005246294 A5 JP 2005246294A5
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- 239000001301 oxygen Substances 0.000 claims description 121
- 229910052760 oxygen Inorganic materials 0.000 claims description 121
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 120
- 239000002101 nanobubble Substances 0.000 claims description 78
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 55
- 239000007864 aqueous solution Substances 0.000 claims description 48
- 150000002500 ions Chemical class 0.000 claims description 21
- 238000004519 manufacturing process Methods 0.000 claims description 16
- 239000003792 electrolyte Substances 0.000 claims description 11
- 238000007906 compression Methods 0.000 claims description 10
- 230000000638 stimulation Effects 0.000 claims description 8
- -1 hydrogen ions Chemical class 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 239000001257 hydrogen Substances 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 230000001965 increased Effects 0.000 claims description 3
- 238000009792 diffusion process Methods 0.000 claims description 2
- 230000002401 inhibitory effect Effects 0.000 claims description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 12
- 230000005684 electric field Effects 0.000 description 6
- 229910052742 iron Inorganic materials 0.000 description 6
- 241000251468 Actinopterygii Species 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 4
- PWHULOQIROXLJO-UHFFFAOYSA-N manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 4
- 229910052748 manganese Inorganic materials 0.000 description 4
- 239000011572 manganese Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 230000001488 breeding Effects 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 201000009910 diseases by infectious agent Diseases 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 235000014102 seafood Nutrition 0.000 description 3
- KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 230000000087 stabilizing Effects 0.000 description 3
- 241000269908 Platichthys flesus Species 0.000 description 2
- 241000700605 Viruses Species 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 230000002708 enhancing Effects 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 229910001425 magnesium ion Inorganic materials 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 230000001766 physiological effect Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 235000015170 shellfish Nutrition 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 210000001519 tissues Anatomy 0.000 description 2
- 229940064005 Antibiotic throat preparations Drugs 0.000 description 1
- 229940083879 Antibiotics FOR TREATMENT OF HEMORRHOIDS AND ANAL FISSURES FOR TOPICAL USE Drugs 0.000 description 1
- 229940042052 Antibiotics for systemic use Drugs 0.000 description 1
- 229940042786 Antitubercular Antibiotics Drugs 0.000 description 1
- 241000252233 Cyprinus carpio Species 0.000 description 1
- 241000287828 Gallus gallus Species 0.000 description 1
- 229940093922 Gynecological Antibiotics Drugs 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 241001600436 Plectroglyphidodon leucozonus Species 0.000 description 1
- 241000276427 Poecilia reticulata Species 0.000 description 1
- 241001529596 Pontinus kuhlii Species 0.000 description 1
- 210000003491 Skin Anatomy 0.000 description 1
- 208000006641 Skin Disease Diseases 0.000 description 1
- 229940024982 Topical Antifungal Antibiotics Drugs 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 230000000844 anti-bacterial Effects 0.000 description 1
- 238000009360 aquaculture Methods 0.000 description 1
- 244000144974 aquaculture Species 0.000 description 1
- 230000001174 ascending Effects 0.000 description 1
- 230000000975 bioactive Effects 0.000 description 1
- 230000003115 biocidal Effects 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 229910052803 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000035622 drinking Effects 0.000 description 1
- 235000021271 drinking Nutrition 0.000 description 1
- 238000002296 dynamic light scattering Methods 0.000 description 1
- 230000004634 feeding behavior Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229940079866 intestinal antibiotics Drugs 0.000 description 1
- 229910001607 magnesium mineral Inorganic materials 0.000 description 1
- 229940005935 ophthalmologic Antibiotics Drugs 0.000 description 1
- 230000003287 optical Effects 0.000 description 1
- 150000002926 oxygen Chemical class 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000002269 spontaneous Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
Images
Description
本発明は、あらゆる技術分野にその有用性が潜在し、特に動植物に対しての生理活性効果を顕在化した酸素ナノバブル水に関するものである。 The present invention relates to oxygen nanobubble water that has potential utility in all technical fields, and in particular, has manifested bioactive effects on animals and plants.
近年、地球環境全般の汚染により、様々な化学物質の蓄積を通して人間の身体が組織レベルで酸素不足になることが知られるようになった。 In recent years, it has become known that due to pollution of the global environment in general, the human body becomes oxygen deficient at the tissue level through the accumulation of various chemical substances.
この問題を解決するために、例えば特許文献１では、通常の気泡とは異なった性質を持つ直径が５０μｍ以下の気泡（微小気泡）中の気体に酸素を溶存させることにより、生理活性機能を有する微小気泡について提案している。
In order to solve this problem, for example,
しかしながら、人間の生理活性機能を高めるには微小気泡を組織レベルで作用させなければならず、全身に十分な量の酸素を供給するためには、大掛りな装置が必要となり、コスト等の面で問題があった。
本発明は上述したような実情に鑑みてなされたものであり、酸素ナノバブル水であって、長期間水溶液中に酸素が存在し、生物に対する活性効果等を有する酸素ナノバブル水およびその製造方法を提供することを目的とする。 The present invention has been made in view of the above-described circumstances, and provides oxygen nanobubble water, in which oxygen is present in an aqueous solution for a long period of time, and has an active effect on living organisms, and a method for producing the same. The purpose is to do.
本発明の上記目的は、気泡の直径が５０〜５００ｎｍであって、前記気泡内に酸素を含有する酸素ナノバブルが含まれる水溶液からなることによって達成される。 The object of the present invention is achieved by comprising an aqueous solution having a bubble diameter of 50 to 500 nm and containing oxygen nanobubbles containing oxygen in the bubble.
また、本発明の上記目的は、気泡の直径が５０〜５００ｎｍであって、前記気泡内に酸素を含有する酸素ナノバブルが含まれる水溶液であって、前記水溶液は、塩分濃度が０．０１〜３．５％の範囲に設定されていることによって効果的に達成される。 The object of the present invention is an aqueous solution having a bubble diameter of 50 to 500 nm and containing oxygen nanobubbles containing oxygen in the bubble, wherein the aqueous solution has a salinity of 0.01 to 3. It can be effectively achieved by setting in the range of 5%.
さらに、本発明の上記目的は、水溶液中に含まれる酸素を含有する微小気泡に物理的刺激を加えることにより、前記微小気泡の気泡径を急激に縮小させ、酸素ナノバブルを製造することによって達成される。 Further, the above object of the present invention is achieved by producing oxygen nanobubbles by applying a physical stimulus to oxygen-containing microbubbles contained in an aqueous solution, thereby rapidly reducing the bubble diameter of the microbubbles. The
本発明の上記目的は、前記微小気泡を急激に縮小させる過程において、気泡径が５０〜５００ｎｍまで縮小すると前記微小気泡表面の電荷密度が上昇し、静電気的な反発力が生じることによって、前記微小気泡の縮小が停止することによって、或いは前記微小気泡を急激に縮小させる過程において、気液界面に吸着したイオンと静電気的な引力により、前記界面近傍の前記水溶液中に引き寄せられた反対符号を持つ両方のイオンが微小な体積の中に高濃度に濃縮することにより、前記微小気泡周囲を取り囲む殻の働きをし、前記微小気泡内の前記酸素の前記水溶液への拡散を阻害することによって、前記酸素ナノバブルを安定化させることによって、或いは前記気液界面に吸着したイオンは、水素イオンや水酸化物イオンであり、前記界面近傍に引き寄せられたイオンとして水溶液中の電解質イオンを利用することにより前記酸素ナノバブルを安定化させることによって、或いは前記微小気泡を急激に縮小させる過程において、断熱的圧縮によって前記微小気泡内温度が急激に上昇することにより、前記微小気泡の周囲に超高温度に伴う物理化学的な変化を与えることで前記酸素ナノバブルを安定化させることによってより効果的に達成される。 In the process of rapidly reducing the microbubbles, the object of the present invention is to increase the charge density on the surface of the microbubbles when the bubble diameter is reduced to 50 to 500 nm, thereby generating an electrostatic repulsive force. It has an opposite sign drawn into the aqueous solution in the vicinity of the interface by stopping the contraction of the bubbles or in the process of abruptly reducing the microbubbles due to ions adsorbed on the gas-liquid interface and electrostatic attraction. By concentrating both ions in a small volume to a high concentration, it acts as a shell surrounding the microbubbles, and by inhibiting diffusion of the oxygen in the microbubbles into the aqueous solution, The ions adsorbed on the gas-liquid interface by stabilizing the oxygen nanobubbles are hydrogen ions or hydroxide ions, and are close to the interface. In the process of stabilizing the oxygen nanobubbles by using electrolyte ions in an aqueous solution as ions attracted to the surface or abruptly shrinking the microbubbles, the temperature inside the microbubbles is rapidly increased by adiabatic compression. Ascending, it is achieved more effectively by stabilizing the oxygen nanobubbles by giving a physicochemical change accompanying ultra-high temperature around the microbubbles.
また、本発明の上記目的は、前記物理的刺激は、放電発生装置を用いて前記微小気泡に放電することであることによって、或いは前記物理的刺激は、前記水溶液が入った容器内に取り付けた回転体を作動させることにより前記水溶液を流動させ、前記流動時に生じる圧縮、膨張および渦流を利用することであるによって、或いは前記物理的刺激は、前記容器に循環回路を形成した場合において、前記容器内の前記微小気泡が含まれる前記溶液を前記循環回路へ前記微小気泡が含まれる前記溶液を取り入れた後、前記循環系回路内に備えつけられた単一若しくは多数の孔を持つオリフィスもしくは多孔板を通過させることで圧縮、膨張および渦流を生じさせることによってより効果的に達成される。 The above-described object of the present invention, said physical stimulation, by using a discharge generating device is to discharge the microbubbles, some have the said physical stimulus, vessel where the aqueous solution containing By operating the attached rotating body to flow the aqueous solution, utilizing compression, expansion and vortex generated during the flow, or when the physical stimulation forms a circulation circuit in the container, After the solution containing the microbubbles in the container is taken into the circulation circuit, the orifice or porous having single or multiple holes provided in the circulation system circuit More effectively achieved by causing compression, expansion and vortex flow through the plate.
本発明に係る酸素ナノバブル水およびその製造方法によれば、酸素ナノバブル水中の酸素は、気泡径が５０〜５００ｎｍの大きさのナノバブルとして含まれており、１月以上の長期に渡って酸素を水溶液中に溶存させることができるようになった。これにより、医療現場や魚介類の畜養、養殖、陸上生物の飼育現場等において、酸素による生理活性効果を高める目的で利用が可能となった。 According to the oxygen nanobubble water and the method for producing the same according to the present invention, oxygen in the oxygen nanobubble water is contained as nanobubbles having a bubble diameter of 50 to 500 nm, and oxygen is used as an aqueous solution for a long period of one month or longer. It can be dissolved inside. As a result, it has become possible to use it for the purpose of enhancing the physiological activity effect of oxygen in medical sites, seafood breeding and aquaculture, terrestrial life breeding sites, and the like.
また、本発明に係る酸素ナノバブル水を生物の体内に取りこむことにより、疾病が急速に快復したり、細菌やウイルス等による感染症も予防できるようになった。皮膚に本発明に係る酸素ナノバブル水を塗布することにより、皮膚病の快復を促すことも可能となった。 In addition, by incorporating oxygen nanobubble water according to the present invention into the body of a living organism, it has become possible to quickly recover from diseases and to prevent infections caused by bacteria and viruses. By applying the oxygen nanobubble water according to the present invention to the skin, it has become possible to promote the recovery of skin diseases.
さらに、本発明に係る酸素ナノバブル水の塩分濃度を０．５〜１．５％の範囲に調節することにより、淡水性および海水性の魚介類を一つの水槽で共存させることが可能となり、この酸素ナノバブル水に衰弱した魚介類を入れると、衰弱した魚介類を快復させることも可能となった。 Furthermore, by adjusting the salt concentration of oxygen nanobubble water according to the present invention in the range of 0.5 to 1.5%, it becomes possible to coexist freshwater and seawater fish and shellfish in one aquarium. When weakened seafood was put into oxygen nanobubble water, it became possible to recover the weakened seafood.
本発明に係る酸素ナノバブル水について詳細に説明する。 The oxygen nanobubble water according to the present invention will be described in detail.
本発明に係る酸素ナノバブル水とは、水溶液中の酸素がナノバブルとして保持されている。ナノバブルとは図１の粒径分布が示すように気泡径が５０〜５００ｎｍの大きさを持っている気泡のことをいい、１月以上の長期に渡って酸素が水溶液中に溶存することを特徴とする。本発明に係る酸素ナノバブル水の保存方法は、特に限定されるものではなく、通常の容器に入れて保存しても、１月以上酸素が水溶液中から消滅することはない。 In the oxygen nanobubble water according to the present invention, oxygen in an aqueous solution is held as nanobubbles. A nanobubble is a bubble having a bubble diameter of 50 to 500 nm as shown in the particle size distribution in FIG. 1, and is characterized by oxygen being dissolved in an aqueous solution over a long period of one month or more. And The method for storing oxygen nanobubble water according to the present invention is not particularly limited, and oxygen does not disappear from the aqueous solution for more than one month even if stored in a normal container.
本発明に係る酸素ナノバブル水の酸素が酸素ナノバブルとしての存在するメカニズムを図２に示す。酸素微小気泡の場合には、小さな気泡ほど内部の酸素の溶解効率が高く、存在が不安定となり瞬時に消滅する。酸素ナノバブルの場合、気液界面に極めて高濃度の電荷が濃縮しているため、球の反対側同士の電荷間に働く静電気的な反発力により球（気泡）が収縮することを妨げている。また、濃縮した高電場の作用により、水溶液中に含まれる鉄等の電解質イオンを主体とした無機質の殻を気泡周囲に形成し、これが内部の酸素の散逸を防止している。この殻は界面活性剤や有機物の殻とは異なるため、細菌等の他の物質と酸素ナノバブルが接触した時に生じる気泡周囲の電荷の逸脱により、殻自体が簡単に崩壊する。殻が崩壊したときには、内部に含まれる酸素は簡単に水溶液中に放出される。 FIG. 2 shows a mechanism in which oxygen of oxygen nanobubble water according to the present invention exists as oxygen nanobubbles. In the case of oxygen microbubbles, the smaller the bubbles, the higher the internal oxygen dissolution efficiency, and the presence becomes unstable and disappears instantly. In the case of oxygen nanobubbles, an extremely high concentration of electric charge is concentrated at the gas-liquid interface, which prevents the sphere (bubble) from contracting due to an electrostatic repulsive force acting between the charges on opposite sides of the sphere. In addition, due to the action of the concentrated high electric field, an inorganic shell mainly composed of electrolyte ions such as iron contained in the aqueous solution is formed around the bubbles, which prevents the dissipation of oxygen inside. Since this shell is different from the surfactant or organic shell, the shell itself easily collapses due to the deviation of the charge around the bubble that occurs when oxygen nanobubbles come into contact with other substances such as bacteria. When the shell collapses, the oxygen contained inside is easily released into the aqueous solution.
また、濃縮した高電場の作用により鉄等の電解質イオンを主体とした無機質の殻を気泡周囲に形成し、これが内部の酸素の散逸を防止している。この殻は界面活性剤や有機物の殻とは異なるため、細菌等の他の物質と酸素ナノバブルが接触した時に生じる気泡周囲の電荷の逸脱により、殻自体が簡単に崩壊する傾向を持っている。殻が崩壊したときには内部に含まれる酸素は簡単に水溶液中に放出される。 Also, an inorganic shell mainly composed of electrolyte ions such as iron is formed around the bubbles by the action of the concentrated high electric field, which prevents the dissipation of oxygen inside. Since this shell is different from the surfactant or organic shell, the shell itself tends to collapse easily due to the deviation of the charge around the bubble that occurs when oxygen nanobubbles come into contact with other substances such as bacteria. When the shell collapses, the oxygen contained inside is easily released into the aqueous solution.
発明者等は鋭意研究の結果、本発明に係る酸素ナノバブル水を生物の体内に取りこむと疾病が急速に快復したり、細菌やウイルス等の感染症を予防できることを見出した。理由については定かでないが、酸素ナノバブルが生体の体内に浸透して入りこみ、細胞を活性化することが予測される。 As a result of intensive studies, the inventors have found that when the oxygen nanobubble water according to the present invention is taken into the body of a living organism, the disease can be recovered rapidly or infectious diseases such as bacteria and viruses can be prevented. Although the reason is not clear, it is predicted that oxygen nanobubbles penetrate into the body of the living body and activate cells.
また、理由については今後の研究を待たねばならないが、発明者等は酸素ナノバブル水の塩分濃度を０．５〜１．５％に調節すると、淡水性および海水性の魚介類を一つの水槽で共存させることができることを見出した。 In addition, we have to wait for future research on the reason. However, the inventors adjusted the salt concentration of oxygen nanobubble water to 0.5 to 1.5%, so that freshwater and seawater fish and shellfish can be contained in one tank. It was found that they can coexist.
次に、本発明に係る酸素ナノバブル水の製造方法について詳細に説明する。 Next, the method for producing oxygen nanobubble water according to the present invention will be described in detail.
本発明に係る酸素ナノバブル水の製造方法においては、直径が１０〜５０μｍの酸素微小気泡を物理的な刺激によって急速に縮小させる。酸素微小気泡が含まれる水溶液中の電気伝導度が３００μＳ／ｃｍ以上となるように鉄、マンガン、カルシウム、ナトリウム、マグネシウムイオン、その他ミネラル類のイオン等の電解質を混入させると、これらの静電気的な反発力により気泡の縮小を阻害する。この静電気的な反発力とは、球形をした微小気泡において縮小に伴い球の曲率が増加することにより、球の反対面に存在する同符号のイオン同士に作用する静電気力のことである。縮小した酸素微小気泡は加圧されているため、酸素微小気泡が縮小するほど、より縮小しようとする傾向が強まるが、気泡径が５００ｎｍよりも小さくなるとこの静電気的な反発力が顕在化してきて、気泡の縮小が停止する。 In the method for producing oxygen nanobubble water according to the present invention, oxygen microbubbles having a diameter of 10 to 50 μm are rapidly reduced by physical stimulation. When electrolytes such as iron, manganese, calcium, sodium, magnesium ions and other mineral ions are mixed so that the electric conductivity in an aqueous solution containing oxygen microbubbles is 300 μS / cm or more, Inhibits the reduction of bubbles by the repulsive force. This electrostatic repulsive force is an electrostatic force that acts on ions of the same sign existing on the opposite surface of the sphere by increasing the curvature of the sphere as it shrinks in a spherical microbubble. Since the reduced oxygen microbubbles are pressurized, the smaller the oxygen microbubbles, the greater the tendency to shrink. However, when the bubble diameter becomes smaller than 500 nm, this electrostatic repulsion force has become apparent. , The bubble shrinkage stops.
水溶液中に電気伝導度が３ｍＳ／ｃｍ以上になるように鉄、マンガン、カルシウム、ナトリウム、マグネシウムイオン、ミネラル類のイオン等の電解質を混入させると、この静電気的な反発力が十分に強く働き、気泡は縮小する力と反発力のバランスを取って安定化する。この安定化したときの気泡径（ナノバブルの気泡径）は電解質イオンの濃度や種類により異なるが、図１に示すように、５０〜５００ｎｍの大きさである。 When an electrolyte such as iron, manganese, calcium, sodium, magnesium ions, or mineral ions is mixed in the aqueous solution so that the electric conductivity is 3 mS / cm or more, this electrostatic repulsive force works sufficiently strongly. Bubbles stabilize by balancing the shrinking force and the repulsive force. The bubble diameter when stabilized (bubble diameter of nanobubbles) varies depending on the concentration and type of electrolyte ions, but is 50 to 500 nm as shown in FIG.
酸素ナノバブルの特徴は、酸素を内部に加圧された状態で維持しているのみでなく、濃縮した表面電荷により極めて強い電場を形成していることである。この強い電場は、気泡内部の酸素や周囲の水溶液に強力な影響を与える力を持っており、生理的な活性効果や殺菌効果、化学的な反応性等を有するようになる。 The feature of oxygen nanobubbles is that not only oxygen is maintained in a pressurized state but also an extremely strong electric field is formed by the concentrated surface charge. This strong electric field has a strong influence on oxygen in the bubbles and the surrounding aqueous solution, and has a physiological activity effect, a bactericidal effect, a chemical reactivity, and the like.
図３は放電装置を用いて酸素ナノバブル水を製造する装置の側面図である。 FIG. 3 is a side view of an apparatus for producing oxygen nanobubble water using a discharge device.
微小気泡発生装置３は取水口３１によって容器１内の水溶液を取り込み、微小気泡発生装置３内に酸素微小気泡を製造するための酸素を注入する注入口（図示せず）から酸素が注入され、取水口３１によって取り込んだ水溶液と混合させて、酸素ナノバブル含有水溶液排出口３２から微小気泡発生装置３で製造した酸素微小気泡を容器１内へ送る。これにより容器１内に酸素微小気泡が存在するようになる。容器１内には、陽極２１と陰極２２があり、陽極２１と陰極２２は放電発生装置２に接続されている。
The
まず、水溶液の入った容器１内に微小気泡発生装置３を用いて酸素微小気泡を発生させる。
First, oxygen microbubbles are generated in the
次に鉄、マンガン、カルシウムその他ミネラル類の電解質を加えて水溶液の電気伝導度が３ｍＳ／ｃｍ以上になるように電解質を加える。 Next, an electrolyte of iron, manganese, calcium and other minerals is added, and the electrolyte is added so that the electric conductivity of the aqueous solution becomes 3 mS / cm or more.
放電発生装置２を用いて、容器１内の酸素微小気泡が含まれる水溶液に水中放電を行う。より効率的に酸素ナノバブルを製造させるため、容器１内の酸素微小気泡の濃度が飽和濃度の５０％以上に達している場合が好ましい。また、水中放電の電圧は２０００〜３０００Ｖが好ましい。
Using the
水中放電に伴う衝撃波の刺激（物理的刺激）により、水中の酸素微小気泡は急速に縮小され、ナノレベルの気泡となる。この時に気泡周囲に存在しているイオン類は、縮小速度が急速なため、周囲の水中に逸脱する時間が無く、気泡の縮小に伴って急速に濃縮する。濃縮されたイオン類は気泡周囲に極めて強い高電場を形成する。この高電場の存在のもとで気液界面に存在する水素イオンや水酸化物イオンは気泡周囲に存在する反対符号を持つ電解質イオンと結合関係を持ち、気泡周囲に無機質の殻を形成する。この殻は気泡内の酸素の水溶液中への自然溶解を阻止するため、酸素ナノバブルは溶解することなく安定的に水溶液中に含まれる。なお、製造される酸素ナノバブルは５０〜５００ｎｍ程度の極めて微小な気泡であるため、水中における浮力をほとんど受けることが無く、通常の気泡で認められる水表面での破裂は皆無に近い。 Oxygen microbubbles in water are rapidly reduced into nano-level bubbles by shock wave stimulation (physical stimulation) accompanying underwater discharge. At this time, the ions present around the bubbles have a rapid reduction speed, so that they do not have time to deviate into the surrounding water and are rapidly concentrated as the bubbles are reduced. Concentrated ions form a very strong high electric field around the bubbles. In the presence of this high electric field, hydrogen ions and hydroxide ions present at the gas-liquid interface have a binding relationship with electrolyte ions having opposite signs existing around the bubbles, and form an inorganic shell around the bubbles. Since this shell prevents spontaneous dissolution of oxygen in the bubbles in the aqueous solution, the oxygen nanobubbles are stably contained in the aqueous solution without dissolving. Since the produced oxygen nanobubbles are extremely fine bubbles of about 50 to 500 nm, they hardly receive buoyancy in water, and there is almost no rupture on the water surface observed for normal bubbles .
次に、渦流を起こすことにより、酸素ナノバブル水を製造する方法について説明する。なお、放電による酸素ナノバブル水を製造する方法及び超音波照射による酸素ナノバブル水を製造する方法と重複する個所については説明を省略する。 In the following, by causing vortex, it describes a method of producing oxygen nanobubble water. In addition, description is abbreviate | omitted about the location which overlaps with the method of manufacturing oxygen nano bubble water by discharge, and the method of manufacturing oxygen nano bubble water by ultrasonic irradiation.
図４は酸素ナノバブル水を製造するために圧縮、膨張および渦流を用いた場合の装置の側面図である。放電による酸素ナノバブル水の製造方法と同様に、微小気泡発生装置３、取水口３１および酸素ナノバブル含有水溶液排出口３２で微小気泡を製造し、酸素微小気泡を容器１内へ送る。容器１には容器１内の酸素微小気泡が含まれる水溶液を部分循環させるための循環ポンプ５が接続されており、循環ポンプ５が設置されている配管（循環配管）内には多数の孔を持つオリフィス（多孔板）６が接続され、容器１と連結している。容器１内の酸素微小気泡が含まれる水溶液は循環ポンプ５により循環配管内を流動させられ、オリフィス（多孔板）６を通過することで圧縮、膨張および渦流を生じさせる。
FIG. 4 is a side view of the apparatus when compression, expansion and vortex are used to produce oxygen nanobubble water. Like the oxygen nanobubbles water production how due to discharge, the
まず、電荷質イオンを含んだ水の入った容器１内に微小気泡発生装置３を用いて酸素微小気泡を発生させる。
First, oxygen microbubbles are generated in a
次に、この酸素微小気泡が含まれる水溶液を部分循環させるため、循環ポンプ５を作動させる。この循環ポンプ５により酸素微小気泡が含まれる水溶液が押し出され、オリフィス（多孔板）６を通過前及び通過後の配管内で圧縮、膨張及び渦流が発生する。通過時の微小気泡の圧縮や膨張により、および配管内で発生した渦流により電荷を持った酸素微小気泡が渦電流を発生させることにより酸素微小気泡は急激に縮小され酸素ナノバブルとして安定化する。なお、循環ポンプ５とオリフィス（多孔板）６の流路における順序は逆でもよい。
Next, the
オリフィス（多孔板）６は図５では単一であるが、複数設置してもよく、循環ポンプ５は必要に応じて省略してもよい。その場合、微小気泡発生装置２の水溶液に対する駆動力や高低差による水溶液の流動等を利用することも可能である。
Although the orifice (perforated plate) 6 is single in FIG. 5 , a plurality of orifices (circular plate) may be provided, and the
また、図５に示すように、容器１内に渦流を発生させるための回転体７を取り付けることによっても酸素ナノバブルを製造することができる。回転体７を５００〜１００００ｒｐｍで回転させることにより、効率よく渦流を容器１内で発生させることができる。
In addition, as shown in FIG. 5 , oxygen nanobubbles can also be produced by attaching a
本発明に係る酸素ナノバブル水を製造後、酸素ナノバブルを動的光散乱光学計により測定したところ、約１５０ｎｍを中心とする粒径分布を持っていた。この酸素ナノバブル水をガラス瓶に入れて蓋をして冷暗所において保存をした。１月後同様に測定すると、ほぼ同一の粒径分布を持っており、安定した状態を保っていた。 After the oxygen nanobubble water according to the present invention was produced, the oxygen nanobubbles were measured by a dynamic light scattering optical meter, and had a particle size distribution centered at about 150 nm. This oxygen nanobubble water was put in a glass bottle, covered, and stored in a cool and dark place. When measured in the same manner after one month, they had almost the same particle size distribution and remained stable.
酸素ナノバブル水におけるナノバブルの安定化には電解質イオンの作用が重要である。本発明に係る酸素ナノバブル水の水質を測定したところ、ｐＨ＝８．４、硬度＝１０００ｍｇ／Ｌ、鉄＝０．０３ｍｇ／Ｌ未満、マンガン＝０．０１６ｍｇ／Ｌ、ナトリウム＝２２００ｍｇ／Ｌ、塩化物イオン＝２１１０ｍｇ／Ｌであった。 The action of electrolyte ions is important for the stabilization of nanobubbles in oxygen nanobubble water. When the water quality of the oxygen nanobubble water according to the present invention was measured, pH = 8.4, hardness = 1000 mg / L, iron = 0.03 mg / L, manganese = 0.016 mg / L, sodium = 2200 mg / L, chloride. Product ion was 2110 mg / L.
塩分濃度が淡水と海水の中間である酸素ナノバブル水に衰弱した鰯とメバルを入れたところ急速に快復した。 When weakened coral and rockfish were put into oxygen nanobubble water with a salinity between fresh water and seawater, it recovered rapidly.
また、水槽内に酸素ナノバブル水を入れると、鯛、カレイ、ヒラメ、アイナメ、竜宮ハゼ、ドンコ等の海水魚、およびコイ、金魚、鉄魚、鮎、イワナ等の淡水魚を同時に半年以上の期間に渡って生存させることができた。また、この間に稚魚の急速な成長を確認した。さらに熱帯魚については、海水系のコバルトや淡水系のグッピー等を同じ水槽内で、水温１５℃程度の条件でも数日間以上生存させることができた。 In addition, when oxygen nanobubble water is put into the aquarium, freshwater fish such as carp, flounder, flounder, ainame, Ryugu goby, donko, etc. I was able to survive across. Also, during this period, the rapid growth of fry was confirmed. Furthermore, with regard to tropical fish, seawater-based cobalt, freshwater-based guppy, etc. could survive several days or more in the same aquarium even under conditions of a water temperature of about 15 ° C.
鶏の飼育現場において、飲料用に酸素ナノバブル水を与えることにより、感染症に対する抵抗量が向上し、抗生物質の使用を大幅に低下させることができた。 By providing oxygen nanobubble water for drinking at chicken breeding sites, the amount of resistance against infectious diseases was improved and the use of antibiotics could be greatly reduced.
１ 容器
２ 放電発生装置
２１ 陽極
２２ 陰極
３ 微小気泡発生装置
３１ 取水口
３２ 酸素ナノバブル含有水溶液排出口
５ 循環ポンプ
６ オリフィス（多孔板）
７ 回転体
DESCRIPTION OF
7 Rotating body
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Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09276675A (en) * | 1996-04-17 | 1997-10-28 | Kankyo Kagaku Kogyo Kk | Gas-liquid contact apparatus |
| JP3397154B2 (en) * | 1997-12-30 | 2003-04-14 | 博文 大成 | Revolving microbubble generator |
| JP2000254483A (en) * | 1999-03-12 | 2000-09-19 | Babcock Hitachi Kk | Cavitation reactor |
| JP4101979B2 (en) * | 1999-06-24 | 2008-06-18 | 株式会社神戸製鋼所 | Underwater discharge method and equipment |
| JP2001225060A (en) * | 1999-12-08 | 2001-08-21 | Mitsubishi Heavy Ind Ltd | Water treatment method and its device |
| JP4309021B2 (en) * | 2000-05-10 | 2009-08-05 | 鈴木産業株式会社 | Wastewater treatment system |
| AU2001274610A1 (en) * | 2000-06-23 | 2002-01-02 | Ryosaku Fujisato | Fine air bubble generator and fine air bubble generating device with the generator |
| JP2002143885A (en) * | 2000-11-14 | 2002-05-21 | Hirobumi Onari | Micro bubble |
| JP3502363B2 (en) * | 2001-05-31 | 2004-03-02 | ジェイイーシー株式会社 | Wastewater treatment method and wastewater treatment equipment |
| JP2003245662A (en) * | 2002-02-21 | 2003-09-02 | Fm Ecology Kenkyusho:Kk | Waste water treatment system |
| JP2003245533A (en) * | 2002-02-22 | 2003-09-02 | Mori Kikai Seisakusho:Kk | Ultrafine air bubble generator |
| JP4016099B2 (en) * | 2002-05-20 | 2007-12-05 | 独立行政法人産業技術総合研究所 | How to create nanobubbles |
| JP2004121962A (en) * | 2002-10-01 | 2004-04-22 | National Institute Of Advanced Industrial & Technology | Method and apparatus for using nanometer-bubble |
-
2004
- 2004-03-05 JP JP2004062160A patent/JP4080440B2/en not_active Expired - Lifetime
-
2005
- 2005-02-28 WO PCT/JP2005/003809 patent/WO2005084786A1/en active Application Filing
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