JP2004307259A - Slaked lime based coating material composition - Google Patents
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【０００１】
【発明の属する技術分野】
本発明は、消石灰系左官材料の作業性、耐亀裂性、下地との付着性を改善した塗材組成物に関する。
【０００２】
【従来の技術】
消石灰系左官材料、すなわち漆喰は消石灰に糊としてつのまた、ふのり、銀杏草などの天然海藻やすさ等の繊維を加えて水で練ったものであり、古来より壁、屋根、塀等に鏝などを用いて施工する建築材料である。
【０００３】
漆喰に用いるすさは、わら、麻、和紙、しゅろ、パルプ等の植物繊維を短く裁断し、もみほぐしたものを使用し、漆喰塗り付け時の材料の落下を防ぎ、塗布後の乾燥収縮による亀裂を防ぐ効果がある。特に和紙は漆喰の質感を損なうことなく、繊維が細く、強度が高いことから好ましいとされている。その他石綿、岩石綿、ガラス繊維等の無機繊維およびポリアミド繊維、ポリエステル繊維、ポリプロピレン繊維、ビニロン繊維等の合成繊維も使用されている。
たとえば、わらすさ、もみすさ、マニラ麻すさ、アクリルやポリエステル製の合成繊維、ガラス繊維等の使用が提案されている（例えば、特許文献１および特許文献２参照）。
【０００４】
【特許文献１】
特開２００１−１９２２５５号公報
【特許文献２】
特開２００２−１２４６０号公報
【０００５】
【発明が解決しようとする課題】
しかし、わら、麻、和紙などの植物繊維は引張り強度が低いので消石灰に繊維を混合して硬化体を補強するには十分ではなく、特に塗り厚を厚くした場合、硬化体の乾燥収縮が大きくなるので亀裂の発生が問題である。また、これらの繊維は嵩高いので消石灰系粉体への分散性、混合性が悪く、添加量も消石灰系１００質量部に対して、４質量部前後に制限されるので、厚塗りの場合の耐亀裂性については課題を有している。また、これらの植物繊維の主成分はセルロースであるので、経年変化により、強度的に劣化が進行することから、耐亀裂性の持続に問題を有している。
【０００６】
一方、植物繊維は調湿性に優れるが、吸湿・乾燥に伴う寸法変化があるため住宅等の内外装材として施工した場合、隙間や亀裂等が発生する恐れがある。また、材料の施工性については鏝塗りでは問題なく施工できるが、ローラー塗り、刷毛塗りでは繊維が絡み合い、施工が困難である。
【０００７】
その他ガラス繊維等の無機繊維やビニロン等の合成繊維は消石灰系の強アルカリ性に材料自身が耐えられなかったり、漆喰基材であるマトリックスとのなじみが悪く、十分な繊維補強効果を挙げられない。
【０００８】
本発明の目的は、従来の問題を解決し、耐亀裂性、作業性が優れ、経時的な劣化を引き起こすことなく、しかも施工中垂れることもなく作業性に優れ、鏝塗り性も良いので極めて平滑な仕上げ面が得られるなど消石灰系左官材料として具備すべき性能を備えた消石灰系塗材組成物を提供することである。
【０００９】
【課題を解決するための手段】
本発明者等は前記課題を解決するため鋭意研究した結果、水酸化カルシウムまたは水酸化カルシウムと水酸化マグネシウムの混合物に、ウォラストナイト（珪灰石）を混合した粉末で、使用に際し水で混練してなる消石灰系塗材組成物、あるいは水酸化カルシウムまたは水酸化カルシウムと水酸化マグネシウムの混合物に、ウォラストナイトを混合したもので、あらかじめ水で混練してペースト状とした消石灰系塗材組成物が耐亀裂性、作業性が優れ、前述の問題を解決し得るものであることを見い出し、本発明を完成させるに至った。
【００１０】
すなわち、前記課題を解決するための本発明の請求項１の消石灰系塗材組成物は、水酸化カルシウムまたは水酸化カルシウムと水酸化マグネシウムの混合物に、ウォラストナイトを混合した粉末で、使用に際し水で混練してなることを特徴とする。
【００１１】
本発明の消石灰系塗材組成物は、使用に際し水で混練して用いるものであり、ウォラストナイトは消石灰系との混合、分散性に優れ、目的の塗り厚に応じて所定の量のウォラストナイトを添加でき、亀裂防止効果と塗材の強度増進をもたらし、また、ウォラストナイトは消石灰系のアルカリ下でも化学的に安定であるので経時的な劣化を引き起こすことなく、しかも消石灰、施工後空気中の炭酸ガスを吸収して生じる炭酸カルシウムとの親和性が高いので永続的な亀裂防止効果を示すばかりでなく、施工中垂れることもなく作業性に優れ、鏝塗り性も良いので極めて平滑な仕上げ面が得られるなど消石灰系左官材料として具備すべき性能を備えている。
【００１２】
本発明の請求項２の消石灰系塗材組成物は、水酸化カルシウムまたは水酸化カルシウムと水酸化マグネシウムの混合物に、ウォラストナイトを混合した粉末で、あらかじめ水で混練してペースト状としたことを特徴とする。
【００１３】
本発明の消石灰系塗材組成物は、あらかじめ水で混練してペースト状としたものであるので使用に際し水で混練しなくてもよく、ウォラストナイトは消石灰系との混合、分散性に優れ、目的の塗り厚に応じて所定の量のウォラストナイトを添加でき、亀裂防止効果と塗材の強度増進をもたらし、また、ウォラストナイトは消石灰系のアルカリ下でも化学的に安定であるので経時的な劣化を引き起こすことなく、しかも消石灰、施工後空気中の炭酸ガスを吸収して生じる炭酸カルシウムとの親和性が高いので永続的な亀裂防止効果を示すばかりでなく、施工中垂れることもなく作業性に優れ、鏝塗り性も良いので極めて平滑な仕上げ面が得られるなど消石灰系左官材料として具備すべき性能を備えている。
【００１４】
本発明の請求項３の消石灰系塗材組成物は、請求項１あるいは請求項２に記載の消石灰系塗材組成物において、水酸化カルシウムまたは水酸化カルシウムと水酸化マグネシウムの混合物１００質量部に対してウォラストナイトを５質量部〜２５０質量部加えてなることを特徴とする。
【００１５】
この範囲であれば、作業性、耐亀裂性および硬化体強度に優れ、塗り厚みを厚くしても亀裂は生じない。
【００１６】
本発明の請求項４の消石灰系塗材組成物は、請求項１、請求項２または請求項３に記載の消石灰系塗材組成物において、ウォラストナイトが平均繊維径１０〜７０μｍ且つ平均繊維長１４０〜５００μｍであることを特徴とする。
【００１７】
この範囲において、耐亀裂性、混練時の分散状態、寸法収縮低減効果に優れ、混練時にダマが発生せず、材料強度にバラツキが生じない。
【００１８】
【発明の実施の形態】
以下、本発明について詳細に説明する。
本発明で用いるウォラストナイトとは、ＣａＳｉＯ３ で表されるカルシウム珪酸塩鉱物であり、天然には石灰岩と花崗岩との接触により変性したもので、繊維状や細い柱状結晶の集合体として産出される。これを粉砕・解砕して針状とするが、解砕の程度により径１０〜１００μｍ、長さ１００〜５００μｍ程度の針状として得られる。
【００１９】
ウォラストナイトはモース硬度４．５〜５．０、比重２．９３、粉砕・解砕物の嵩比重０．８〜１．０程度であり、消石灰系との混合、分散性に優れ、目的の塗り厚に応じて所定の量のウォラストナイトを添加でき、亀裂防止効果と塗材の強度増進をもたらす。
また、ウォラストナイトは消石灰系のアルカリ下でも化学的に安定であるので経時的な劣化を引き起こすことなく、しかも消石灰、施工後空気中の炭酸ガスを吸収して生じる炭酸カルシウムとの親和性が高いので永続的な亀裂防止効果を示すばかりでなく、施工中垂れることもなく作業性に優れ、鏝塗り性も良いので極めて平滑な仕上げ面が得られる。
【００２０】
ウォラストナイトは消石灰系１００質量部に対し、５〜２５０質量部添加すると耐亀裂性に優れ、この範囲において添加量を多めにすれば、塗り厚みを厚くしても亀裂は生じない。ウォラストナイトの添加量は目的の塗り厚に応じて所定の量を添加すればよいが、塗り厚が２ｍｍ以下の場合、添加量は消石灰系１００質量部に対し、５〜３０質量部、塗り厚が２〜５ｍｍの場合、添加量は３０〜１５０質量部、塗り厚が５ｍｍ以上と比較的厚塗りする場合、添加量は１５０〜２５０質量部と塗り厚とともに添加量を増加させることで、硬化後の永続的な亀裂防止効果を示すばかりでなく、消石灰系塗材組成物が施工中垂れることもなく作業性に優れ、鏝塗り性も良いので極めて平滑な仕上げ面が得られる。
一方、ウォラストナイトの添加量が５質量部未満の場合、亀裂が生じやすく、添加効果が十分でない。また、２５０質量部を超えて使用した場合、消石灰系ペーストはボソボソ感があり、作業性が低下し、また硬化体強度も低下する。
【００２１】
ウォラストナイトは平均繊維径１０〜７０μｍ且つ平均繊維長１４０〜５００μｍに粒度調整したものを使用するのがよい。平均繊維径１０μｍ未満であると耐亀裂性が弱くなり、平均繊維径が７０μｍを超えると混練時の分散状態が悪くなるので好ましくない。さらに、平均繊維長１４０μｍ未満であると塗材の寸法収縮低減効果が低い。また平均繊維長５００μｍを超えると消石灰粉体への均一分散がしにくく、混練時にダマが発生し、材料強度にバラツキが生じるので好ましくない。
消石灰系へ添加するウォラストナイトの形状は、上述の範囲であれば問題ないが、薄塗りの場合は繊維長が短いもの、厚塗りの場合は繊維長が長いものを選定することで、硬化後の亀裂防止効果、施工中の垂れ防止効果、作業性、鏝塗り性をより向上させることができるので、塗り厚に応じた形状を選定するのが好ましい。
【００２２】
本発明で使用される消石灰系としては水酸化カルシウムを主成分とする消石灰と水酸化カルシウムと水酸化マグネシウムからなるドロマイトプラスターが挙げられる。
【００２３】
ドロマイトプラスターは、日本工業規格（ＪＩＳ）Ａ ６９０３に規定されるものである。即ち、ドロマイトを焼成して酸化カルシウムと酸化マグネシウムにした後、水酸化カルシウムと水酸化マグネシウムとなるまで十分に消化したものをボールミルその他で粉砕して、エアセパレータなどで分級したものである。
【００２４】
消石灰系化合物は（ＪＩＳ）Ａ ６９０２ 左官用消石灰、（ＪＩＳ）Ａ ６９０３ ドロマイトプラスターが望ましいが、工業用消石灰、軽焼ドロマイト水和物（主成分；水酸化カルシウム、水酸化マグネシウム）でも使用できる。
【００２５】
本発明の消石灰系塗材組成物には必要に応じて公知の水硬性組成物を添加してもよい。該水硬性組成物としては石膏、普通ポルトランドセメント、早強ポルトランドセメント、アルミナセメント、高炉セメント、フライアッシュセメント、着色セメントなどが挙げられる。
【００２６】
また、混和剤としてメチルセロースやエチルセルロース、ヒドロキシプロピルセルロース、ヒドロキシエチルセルロース、ヒドロキシエチルメチルセルロース、ヒドロキシプロピルメチルセルロース等のセルロース誘導体、つのまた、ふのり、銀杏藻等の天然海藻類、ポリビニルアルコール、ポリアクリルアミドなどの水溶性高分子化合物やアクリル系高分子エマルジョン、酢酸ビニル高分子エマルジョン、エチレン−酢酸ビニル系高分子エマルジョン、ＳＢＲ系高分子エマルジョン、エポキシ樹脂エマルジョンなどを添加してもよい。また、骨材として、川砂、山砂、珪砂、寒水砂、軽量骨材等を配合しても差し支えない。
【００２７】
消石灰系と本発明で使用されるウォラストナイトを混合させる装置は、両者を均一に混合攪拌できる装置であれば良く、装置の種類を問わず利用できる。
【００２８】
本発明の塗材組成物は使用に際して水を加えてよく混練し、作業に適したペースト状にして施工する。
また、本発明の塗材組成物は水酸化カルシウム、水酸化マグネシウム由来のアルカリ下で安定なペースト状を長期間保持できるので、予め水を加えて練った消石灰系ペーストの水分が蒸発しないように缶、ポリ容器等に密封しておけば、開封後、そのまま施工できる。
いずれもの場合も、施工法は問わず、例えば鏝塗り、刷毛塗り、ローラー塗り、スプレーガン等による吹きつけ工法などが採用される。
【００２９】
【実施例】
以下、実施例および比較例により本発明の製造方法の具体例及びその効果を説明するが、本発明は下記の実施例に限定されるものではない。
【００３０】
なお、実施例で使用した消石灰は（ＪＩＳ）Ａ ６９０２に合格する左官用消石灰、ドロマイトプラスターは（ＪＩＳ）Ａ ６９０３に合格するドロマイトプラスターである。また、消石灰系ペーストは（ＪＩＳ）Ｒ ５２０１に規定するビカー針装置を用いて一定の標準軟度に調整したものを使用し、標準軟度の加水量を標準混水量（％）とした。
【００３１】
（実施例１）
左官用消石灰１００質量部、メチルセルロース（信越化学株式会社製、商品名；メトローズ９０ＳＨ−４０００）０．５質量部、平均繊維径１２μｍ、平均繊維長１４０μｍのウォラストナイト（川鉄鉱業株式会社製、商品名；ＫＨ−３０）を１０質量部添加し、均一混合して水で練ったペーストを得た。標準混水量は７８．６％であった。
下地に対する付着強度についてはコンクリート板に接着増強材としてエチレン−酢酸ビニル系共重合樹脂エマルジョン（村樫石灰工業株式会社製、商品名；フジプライマー、固形分；４５％）の３倍清水希釈液を刷毛で塗布後、十分に乾燥させてからこのペーストを２ｍｍ厚に塗った。
室内で静置、養生を行い２８日目に建研式接着力試験機を用いて接着力試験（付着力試験）を行った。測定に際し、表面に速硬性エポキシ樹脂で金具（接着面積；４０ｍｍ×４０ｍｍ）を接着し、電動カッターで金具四辺に切りこみを入れ、試験に供した。耐亀裂性については１８ｃｍ×１８ｃｍの石膏ボードに上記接着増強材を塗布後、十分に乾燥させてからこのペーストを２、４、６、８、１０ｍｍ塗布し、室内で静置、養生を行い７日目に塗布表面を目視観察した（耐亀裂性評価基準；◎：亀裂なし ○：亀裂小さい ×：亀裂大きい）。
作業性については鏝塗りによる官能試験で評価した（作業性評価基準；◎：優れている ○：良い △：普通 ×：劣る）。結果を表１に示す。
【００３２】
（実施例２）
左官用消石灰１００質量部、メチルセルロース０．５質量部、実施例１のウォラストナイト２０質量部添加し、均一混合して水で練ったペーストを得た。標準混水量は８２．３％であった。付着強度、耐亀裂性、作業性についての試験を実施例１と同様に行った。結果を表１に示す。
【００３３】
（実施例３）
実施例２で調製したペーストの一部を缶に密封し、室温で１カ月経過後開缶し、付着強度、耐亀裂性、作業性についての試験を実施例１と同様に行った。結果を表１に示す。
【００３４】
（実施例４）
左官用消石灰１００質量部、メチルセルロース０．５質量部、実施例１のウォラストナイトを５０質量部添加し、均一混合して水で練ったペーストを得た。標準混水量は７６．４％であった。付着強度、耐亀裂性、作業性についての試験を実施例１と同様に行った。結果を表１に示す。
【００３５】
（実施例５）
左官用消石灰１００質量部、メチルセルロース０．５質量部、実施例１のウォラストナイトを１００質量部添加し、均一混合して水で練ったペーストを得た。標準混水量は７４．２％であった。付着強度、耐亀裂性、作業性についての試験を実施例１と同様に行った。結果を表１に示す。
【００３６】
（実施例６）
左官用消石灰１００質量部、メチルセルロース０．５質量部、実施例１のウォラストナイトを１５０質量部添加し、均一混合して水で練ったペーストを得た。標準混水量は７３．４％であった。付着強度、耐亀裂性、作業性についての試験を実施例１と同様に行った。結果を表１に示す。
【００３７】
（実施例７）
左官用消石灰１００質量部、メチルセルロース０．５質量部、実施例１のウォラストナイトを２００質量部添加し、均一混合して水で練ったペーストを得た。標準混水量は７０．４％であった。付着強度、耐亀裂性、作業性についての試験を実施例１と同様に行った。結果を表１に示す。
【００３８】
（実施例８）
左官用消石灰１００質量部、メチルセルロース０．５質量部、実施例１のウォラストナイトを２５０質量部添加し、均一混合して水で練ったペーストを得た。標準混水量は６８．８％であった。付着強度、耐亀裂性、作業性についての試験を実施例１と同様に行った。結果を表１に示す。
【００３９】
（実施例９）
左官用消石灰１００質量部、メチルセルロース０．５質量部、ウォラストナイト（川鉄鉱業株式会社製、商品名；ＫＨ−１２０）を２０質量部添加し、均一混合して水で練ったペーストを得た。標準混水量は７８．２％であった。付着強度、耐亀裂性、作業性についての試験を実施例１と同様に行った。結果を表１に示す。
【００４０】
（実施例１０）
実施例９で調製したペーストの一部を缶に密封し、室温で１カ月経過後開缶し、付着強度、耐亀裂性、作業性についての試験を実施例１と同様に行った。結果を表１に示す。
【００４１】
（実施例１１）
左官用消石灰１００質量部、メチルセルロース０．５質量部、実施例９のウォラストナイトを５０質量部添加し、均一混合して水で練ったペーストを得た。標準混水量は６０．６％であった。付着強度、耐亀裂性、作業性についての試験を実施例１と同様に行った。結果を表１に示す。
【００４２】
（実施例１２）
左官用消石灰１００質量部、メチルセルロース０．５質量部、実施例９のウォラストナイトを１００質量部添加し、均一混合して水で練ったペーストを得た。標準混水量は５７．４％であった。付着強度、耐亀裂性、作業性についての試験を実施例１と同様に行った。結果を表１に示す。
【００４３】
（実施例１３）
左官用消石灰１００質量部、メチルセルロース０．５質量部、実施例９のウォラストナイトを１５０質量部添加し、均一混合して水で練ったペーストを得た。標準混水量は５３．３％であった。付着強度、耐亀裂性、作業性についての試験を実施例１と同様に行った。結果を表１に示す。
【００４４】
（実施例１４）
左官用消石灰１００質量部、メチルセルロース０．５質量部、実施例９のウォラストナイトを２００質量部添加し、均一混合して水で練ったペーストを得た。標準混水量は５０．７％であった。付着強度、耐亀裂性、作業性についての試験を実施例１と同様に行った。結果を表１に示す。
【００４５】
（実施例１５）
左官用消石灰１００質量部、メチルセルロース０．５質量部、実施例９のウォラストナイトを２５０質量部添加し、均一混合して水で練ったペーストを得た。標準混水量は４８．４％であった。付着強度、耐亀裂性、作業性についての試験を実施例１と同様に行った。結果を表１に示す。
【００４６】
（実施例１６）
ドロマイトプラスター１００質量部、メチルセルロース０．５質量部、実施例１のウォラストナイトを５０質量部添加し、均一混合して水で練ったペーストを得た。標準混水量は７８．３％であった。付着強度、耐亀裂性、作業性についての試験を実施例１と同様に行った。結果を表１に示す。
【００４７】
（比較例１）
左官用消石灰１００質量部、メチルセルロース０．５質量部、実施例１のウォラストナイトを３質量部添加し、均一混合して水で練ったペーストを得た。標準混水量は８６．０％であった。付着強度、耐亀裂性、作業性についての試験を実施例１と同様に行った。結果を表１に示す。
【００４８】
（比較例２）
左官用消石灰１００質量部、メチルセルロース（信越化学社製、商品名；９０ＳＨ−４０００）０．５質量部、実施例１のウォラストナイトを３００質量部添加し、均一混合して水で練ったペーストを得た。標準混水量は６５．６％であった。付着強度、耐亀裂性、作業性についての試験を実施例１と同様に行った。結果を表１に示す。
【００４９】
（比較例３）
左官用消石灰１００質量部、メチルセルロース０．５質量部、平均繊維径５μｍ、平均繊維長５０μｍのウォラストナイトを２０質量部添加し、均一混合して水で練ったペーストを得た。標準混水量は９６．６％であった。付着強度、耐亀裂性、作業性についての試験を実施例１と同様に行った。結果を表１に示す。
【００５０】
（比較例４）
左官用消石灰１００質量部、メチルセルロース０．５質量部、平均繊維径１００μｍ、平均繊維長６００μｍのウォラストナイトを２０質量部添加し、均一混合して水で練ったペーストを得た。標準混水量は６０．３％であった。付着強度、耐亀裂性、作業性についての試験を実施例１と同様に行った。結果を表１に示す。
【００５１】
（比較例５）
左官用消石灰１００質量部、メチルセルロース０．５質量部、植物繊維の麻すさ（松崎建材株式会社製）を４質量部添加し、均一混合して水で練ったペーストを得た。標準混水量は８７．３％であった。付着強度、耐亀裂性、作業性についての試験を実施例１と同様に行った。このペーストは繊維とローラー面が絡み合いローラーでの塗布は困難であった。結果を表１に示す。
【００５２】
（比較例６）
左官用消石灰１００質量部、メチルセルロース０．５質量部を均一混合して水で練ったペーストを得た。標準混水量は８４．６％であった。付着強度、耐亀裂性、作業性についての試験を実施例１と同様に行った。結果を表１に示す。
【００５３】
（比較例７）
ドロマイトプラスター１００質量部、メチルセルロース０．５質量部を均一混合して水で練ったペーストを得た。標準混水量は８７．６％であった。付着強度、耐亀裂性、作業性についての試験を実施例１と同様に行った。結果を表１に示す。
【００５４】
【表１】
表１に示したように本発明の消石灰系塗材組成物は硬化後の強度発現、下地との接着性も良好であり、作業性が優れることが分かる。
耐亀裂性については添加量が少なく厚塗りした場合は亀裂が生じやすくなる傾向が認められるが、消石灰系１００質量部に対し、ウォラストナイト５０質量部添加（実施例４）では塗り厚を６ｍｍとしても亀裂は生じず、耐亀裂性が優れることが分かる。また、本発明の消石灰系塗材は使用に際し、水を加えて練って施工してもよく、予め水を加えて練り置きしたものを施工してもよい。
【００５６】
一方、ウォラストナイトの添加量が消石灰系１００質量部に対し、５質量部以下の場合（比較例１）では付着強度、耐亀裂性、作業性の改善が認められなかった。
ウォラストナイトの添加量が消石灰系１００質量部に対し、２５０質量部以上の場合（比較例２）では付着強度、耐亀裂性は優れるものの、ペーストはボソボソ感があり、塗り付けが困難で、作業性は著しく劣った。
平均繊維径が１０μｍ未満、平均繊維長が１４０μｍ未満のウォラストナイトを使用した場合（比較例３）では耐亀裂性、作業性の改善が認められなかった。
平均繊維径が７０μｍ以上、平均繊維長が５００μｍ以上のウォラストナイトを使用した場合（比較例４）では混練時の分散状態が悪く、付着強度、耐亀裂性、作業性は著しく劣った。麻すさを使用した場合（比較例５）では耐亀裂性、作業性は優れるものの、厚塗りした際の耐亀裂性は低かった。
ウォラストナイトを添加しない消石灰系（比較例６、７）では付着強度、耐亀裂性、作業性は著しく劣った。
【００５７】
【発明の効果】
本発明の請求項１の消石灰系塗材組成物は、水酸化カルシウムまたは水酸化カルシウムと水酸化マグネシウムの混合物に、ウォラストナイトを混合した粉末で、使用に際し水で混練してなることを特徴とするものであり、ウォラストナイトは消石灰系との混合、分散性に優れ、目的の塗り厚に応じて所定の量のウォラストナイトを添加でき、亀裂防止効果と塗材の強度増進をもたらし、また、ウォラストナイトは消石灰系のアルカリ下でも化学的に安定であるので経時的な劣化を引き起こすことなく、しかも消石灰、施工後空気中の炭酸ガスを吸収して生じる炭酸カルシウムとの親和性が高いので永続的な亀裂防止効果を示すばかりでなく、施工中垂れることもなく作業性に優れ、鏝塗り性も良いので極めて平滑な仕上げ面が得られるなど消石灰系左官材料として具備すべき性能を備えているという顕著な効果を奏する。
【００５８】
本発明の請求項２の消石灰系塗材組成物は、水酸化カルシウムまたは水酸化カルシウムと水酸化マグネシウムの混合物に、ウォラストナイトを混合した粉末で、あらかじめ水で混練してペースト状としたことを特徴とするものであり、あらかじめ水で混練して安定なペースト状としたものであるので使用に際し水で混練しなくてもよく、ウォラストナイトは消石灰系との混合、分散性に優れ、目的の塗り厚に応じて所定の量のウォラストナイトを添加でき、亀裂防止効果と塗材の強度増進をもたらし、また、ウォラストナイトは消石灰系のアルカリ下でも化学的に安定であるので経時的な劣化を引き起こすことなく、しかも消石灰、施工後空気中の炭酸ガスを吸収して生じる炭酸カルシウムとの親和性が高いので永続的な亀裂防止効果を示すばかりでなく、施工中垂れることもなく作業性に優れ、鏝塗り性も良いので極めて平滑な仕上げ面が得られるなど消石灰系左官材料として具備すべき性能を備えているという顕著な効果を奏する。
【００５９】
本発明の請求項３の消石灰系塗材組成物は、請求項１あるいは請求項２に記載の消石灰系塗材組成物において、水酸化カルシウムまたは水酸化カルシウムと水酸化マグネシウムの混合物１００質量部に対してウォラストナイトを５質量部〜２５０質量部加えてなることを特徴とするものであり、この範囲であれば、作業性、耐亀裂性および硬化体強度に優れ、塗り厚みを厚くしても亀裂は生じないというさらなる顕著な効果を奏する。
【００６０】
本発明の請求項４の消石灰系塗材組成物は、請求項１、請求項２または請求項３に記載の消石灰系塗材組成物において、ウォラストナイトが平均繊維径１０〜７０μｍ且つ平均繊維長１４０〜５００μｍであることを特徴とするものであり、この範囲において、耐亀裂性、混練時の分散状態、寸法収縮低減効果に優れ、混練時にダマが発生せず、材料強度にバラツキが生じないというさらなる顕著な効果を奏する。[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention relates to a coating material composition in which the workability, crack resistance, and adhesion to a ground of a slaked lime-based plastering material are improved.
[0002]
[Prior art]
Slaked lime-based plastering material, that is, plaster, is a mixture of slaked lime with glue, fibers of natural seaweed such as seaweed and ginkgo, etc., and kneaded with water.Since ancient times, irons have been used on walls, roofs, fences, etc. It is a building material constructed using.
[0003]
The soup used for stucco is made by cutting plant fibers such as straw, hemp, washi, shoji, pulp, etc. into short pieces and using a crushed one to prevent the material from falling off when plastering, and by drying shrinkage after application. It has the effect of preventing cracks. In particular, Japanese paper is considered to be preferable because the fibers are fine and the strength is high without impairing the texture of the plaster. In addition, inorganic fibers such as asbestos, rock asbestos, and glass fibers and synthetic fibers such as polyamide fibers, polyester fibers, polypropylene fibers, and vinylon fibers are also used.
For example, the use of straw, rice, manila hemp, acrylic or polyester synthetic fiber, glass fiber, and the like has been proposed (for example, see Patent Documents 1 and 2).
[0004]
[Patent Document 1]
JP 2001-192255 A [Patent Document 2]
JP-A-2002-12460 [0005]
[Problems to be solved by the invention]
However, vegetable fibers such as straw, hemp, and Japanese paper have low tensile strength, so it is not enough to mix fibers with slaked lime to reinforce the hardened body, especially when the coating thickness is increased, the drying shrinkage of the hardened body is large. Therefore, the generation of cracks is a problem. Further, since these fibers are bulky, dispersibility and mixing properties in slaked lime-based powder are poor, and the amount of addition is limited to about 4 parts by mass with respect to 100 parts by mass of slaked lime-based powder. There is an issue regarding crack resistance. In addition, since the main component of these plant fibers is cellulose, the strength deteriorates due to aging, and there is a problem in maintaining the crack resistance.
[0006]
On the other hand, vegetable fibers are excellent in humidity control properties, but may have gaps and cracks when used as interior and exterior materials for houses and the like due to dimensional changes due to moisture absorption and drying. In addition, the workability of the material can be performed without any problem by trowel coating, but it is difficult to perform the process by roller coating and brush coating because the fibers are entangled.
[0007]
In addition, inorganic fibers such as glass fibers and synthetic fibers such as vinylon cannot withstand the strong alkaline property of slaked lime, or have poor compatibility with the matrix which is a plaster base material, and cannot provide a sufficient fiber reinforcing effect.
[0008]
The object of the present invention is to solve the conventional problems, crack resistance, excellent workability, without causing deterioration over time, without dripping during construction, excellent workability, iron coating is also very good It is an object of the present invention to provide a slaked lime-based coating material composition having performances to be provided as a slaked lime-based plastering material, such as obtaining a smooth finished surface.
[0009]
[Means for Solving the Problems]
The inventors of the present invention have conducted intensive studies to solve the above-mentioned problems. As a result, a powder obtained by mixing wollastonite (wollastonite) with calcium hydroxide or a mixture of calcium hydroxide and magnesium hydroxide was kneaded with water before use. Slaked lime-based coating material composition, or a mixture of calcium hydroxide or a mixture of calcium hydroxide and magnesium hydroxide, mixed with wollastonite, and previously kneaded with water to form a paste-hydrated lime-based coating material composition Have excellent crack resistance and workability and can solve the above-mentioned problems, and have completed the present invention.
[0010]
That is, the slaked lime-based coating composition according to claim 1 of the present invention for solving the above-mentioned problem is a powder obtained by mixing wollastonite with calcium hydroxide or a mixture of calcium hydroxide and magnesium hydroxide. It is characterized by being kneaded with water.
[0011]
The slaked lime-based coating material composition of the present invention is used by kneading with water when used, and wollastonite is excellent in mixing and dispersibility with slaked lime, and has a predetermined amount of water depending on the target coating thickness. Adds lastonite, which prevents cracking and increases the strength of coating materials.Wollastonite is chemically stable even under slaked lime-based alkali, so it does not cause deterioration over time. Since it has a high affinity with calcium carbonate generated by absorbing carbon dioxide in the air afterwards, it not only shows a permanent crack prevention effect, it also has excellent workability without dripping during construction, and it has a good iron coatability It has the properties to be provided as a slaked lime plastering material, such as obtaining a smooth finished surface.
[0012]
The slaked lime-based coating material composition according to claim 2 of the present invention is a powder obtained by mixing wollastonite with calcium hydroxide or a mixture of calcium hydroxide and magnesium hydroxide, and previously kneaded with water to form a paste. It is characterized by.
[0013]
Since the slaked lime-based coating material composition of the present invention is kneaded with water in advance to form a paste, it does not have to be kneaded with water when used, and wollastonite is excellent in mixing and dispersibility with slaked lime-based. Depending on the desired coating thickness, a predetermined amount of wollastonite can be added, resulting in a crack prevention effect and an increase in the strength of the coating material, and because wollastonite is chemically stable even under slaked lime-based alkali. Highly compatible with slaked lime and calcium carbonate generated by absorbing carbon dioxide gas in the air after construction without causing deterioration over time. It is excellent in workability and troweling property, so that it has a performance that should be provided as a slaked lime plastering material, such as obtaining an extremely smooth finished surface.
[0014]
The slaked lime-based coating material composition according to claim 3 of the present invention is the same as the slaked lime-based coating material composition according to claim 1 or 2, and is based on 100 parts by mass of calcium hydroxide or a mixture of calcium hydroxide and magnesium hydroxide. On the other hand, 5 to 250 parts by mass of wollastonite is added.
[0015]
Within this range, workability, crack resistance, and strength of the cured product are excellent, and cracks do not occur even when the coating thickness is increased.
[0016]
The slaked lime-based coating material composition according to claim 4 of the present invention is the slaked lime-based coating material composition according to claim 1, 2 or 3, wherein wollastonite has an average fiber diameter of 10 to 70 µm and an average fiber length. The length is 140 to 500 μm.
[0017]
Within this range, it is excellent in crack resistance, dispersion state at the time of kneading, and reduction effect of dimensional shrinkage, does not generate lumps at the time of kneading, and does not vary in material strength.
[0018]
BEST MODE FOR CARRYING OUT THE INVENTION
Hereinafter, the present invention will be described in detail.
The wollastonite used in the present invention is a calcium silicate mineral represented by CaSiO 3 , which is naturally modified by contact between limestone and granite, and is produced as an aggregate of fibrous or thin columnar crystals. You. This is pulverized and crushed to obtain a needle-like shape. Depending on the degree of crushing, a needle-like shape having a diameter of 10 to 100 μm and a length of about 100 to 500 μm is obtained.
[0019]
Wollastonite has a Mohs hardness of 4.5 to 5.0, a specific gravity of 2.93, and a bulk specific gravity of the pulverized / crushed material of about 0.8 to 1.0, and is excellent in mixing and dispersibility with slaked lime-based materials. A predetermined amount of wollastonite can be added according to the coating thickness, which results in a crack preventing effect and an increase in the strength of the coating material.
In addition, wollastonite is chemically stable even under slaked lime-based alkali, so that it does not deteriorate with time, and has an affinity for slaked lime and calcium carbonate generated by absorbing carbon dioxide gas in the air after construction. Since it is high, it not only exhibits a permanent crack-preventing effect, but also has excellent workability without sagging during construction, and has a good iron coatability, so that an extremely smooth finished surface can be obtained.
[0020]
If wollastonite is added in an amount of 5 to 250 parts by mass with respect to 100 parts by mass of slaked lime, crack resistance is excellent, and if the addition amount is too large in this range, no crack occurs even when the coating thickness is increased. The addition amount of wollastonite may be a predetermined amount according to the desired coating thickness, but when the coating thickness is 2 mm or less, the addition amount is 5 to 30 parts by mass, based on 100 parts by mass of slaked lime. When the thickness is 2 to 5 mm, the addition amount is 30 to 150 parts by mass, and when the coating thickness is relatively thick as 5 mm or more, the addition amount is 150 to 250 parts by mass and by increasing the addition amount together with the coating thickness, In addition to exhibiting a permanent crack-preventing effect after curing, the slaked lime-based coating material composition has excellent workability without sagging during construction and good trowelability, so that an extremely smooth finished surface can be obtained.
On the other hand, if the added amount of wollastonite is less than 5 parts by mass, cracks are likely to occur, and the effect of adding is not sufficient. Further, when used in an amount exceeding 250 parts by mass, the slaked lime-based paste has a rough feeling, reduces workability, and lowers the strength of the cured product.
[0021]
Wollastonite having an average fiber diameter of 10 to 70 m and an average fiber length of 140 to 500 m is preferably used. If the average fiber diameter is less than 10 μm, the crack resistance becomes weak, and if the average fiber diameter exceeds 70 μm, the dispersion state during kneading deteriorates, which is not preferable. Further, when the average fiber length is less than 140 μm, the effect of reducing the dimensional shrinkage of the coating material is low. On the other hand, if the average fiber length exceeds 500 μm, it is difficult to uniformly disperse the powder in slaked lime powder, and lumps are generated at the time of kneading.
The shape of wollastonite to be added to slaked lime is not problematic as long as it is within the above range, but it is hardened by selecting a fiber with a short fiber length for thin coating and a fiber with a long fiber length for thick coating. It is preferable to select a shape according to the coating thickness, because the effect of preventing cracks later, the effect of preventing sagging during construction, workability, and troweling properties can be further improved.
[0022]
The slaked lime system used in the present invention includes slaked lime mainly composed of calcium hydroxide, dolomite plaster composed of calcium hydroxide and magnesium hydroxide.
[0023]
Dolomite plaster is specified in Japanese Industrial Standard (JIS) A 6903. That is, dolomite is calcined into calcium oxide and magnesium oxide, and then digested sufficiently to obtain calcium hydroxide and magnesium hydroxide, pulverized by a ball mill or the like, and classified by an air separator or the like.
[0024]
As the slaked lime-based compound, (JIS) A 6902 plastered slaked lime and (JIS) A 6903 dolomite plaster are preferable, but industrial slaked lime and light burnt dolomite hydrate (main components: calcium hydroxide and magnesium hydroxide) can also be used.
[0025]
If necessary, a known hydraulic composition may be added to the slaked lime-based coating material composition of the present invention. Examples of the hydraulic composition include gypsum, ordinary Portland cement, early-strength Portland cement, alumina cement, blast furnace cement, fly ash cement, colored cement and the like.
[0026]
In addition, as an admixture, cellulose derivatives such as methylcellose and ethylcellulose, hydroxypropylcellulose, hydroxyethylcellulose, hydroxyethylmethylcellulose, hydroxypropylmethylcellulose, sunflower, natural seaweeds such as Ginkgo biloba, water-soluble such as polyvinyl alcohol and polyacrylamide A polymer compound, an acrylic polymer emulsion, a vinyl acetate polymer emulsion, an ethylene-vinyl acetate polymer emulsion, an SBR polymer emulsion, an epoxy resin emulsion, or the like may be added. In addition, river sand, mountain sand, quartz sand, cold water sand, lightweight aggregate and the like may be mixed as the aggregate.
[0027]
The device for mixing slaked lime and wollastonite used in the present invention may be any device that can uniformly mix and stir both, and can be used regardless of the type of device.
[0028]
The coating material composition of the present invention is prepared by adding water at the time of use, kneading well, and forming a paste suitable for work.
In addition, since the coating material composition of the present invention can maintain a stable paste state for a long period of time under alkalis derived from calcium hydroxide and magnesium hydroxide, the water content of the slaked lime-based paste kneaded by adding water in advance is prevented from evaporating. If it is sealed in a can, plastic container, etc., it can be installed as it is after opening.
In any case, regardless of the construction method, for example, a trowel coating, a brush coating, a roller coating, a spraying method using a spray gun or the like is employed.
[0029]
【Example】
Hereinafter, specific examples of the production method of the present invention and effects thereof will be described with reference to Examples and Comparative Examples, but the present invention is not limited to the following Examples.
[0030]
Slaked lime used in the examples was plastered slaked lime that passed (JIS) A 6902, and dolomite plaster was dolomite plaster that passed (JIS) A 6903. The slaked lime paste used was adjusted to a constant standard softness using a Vicat needle device specified in (JIS) R5201, and the amount of water having the standard softness was defined as a standard water content (%).
[0031]
(Example 1)
100 parts by mass of slaked lime for plasterer, 0.5 parts by mass of methylcellulose (trade name: Metroose 90SH-4000, manufactured by Shin-Etsu Chemical Co., Ltd.), wollastonite having an average fiber diameter of 12 μm and an average fiber length of 140 μm (manufactured by Kawairon Mining Co., Ltd.) Name: KH-30) was added thereto, mixed uniformly, and a paste kneaded with water was obtained. The standard water mixture was 78.6%.
Regarding the adhesion strength to the substrate, a triple dilution of fresh water of an ethylene-vinyl acetate copolymer resin emulsion (trade name, Fuji Primer, solid content: 45%, manufactured by Murakashi Lime Industry Co., Ltd.) was used as an adhesion enhancer for the concrete plate. After applying with a brush, the paste was sufficiently dried, and then this paste was applied to a thickness of 2 mm.
After standing and curing in a room, an adhesion test (adhesion test) was performed on the 28th day using a Kenken-type adhesion tester. At the time of the measurement, a metal fitting (adhesive area; 40 mm × 40 mm) was adhered to the surface with a quick-setting epoxy resin, and four sides of the metal fitting were cut out with an electric cutter, and the test was performed. Regarding the crack resistance, after applying the above-mentioned adhesion enhancing material to a gypsum board of 18 cm × 18 cm and drying it sufficiently, this paste was applied at 2, 4, 6, 8 and 10 mm, and allowed to stand still and cure in a room. On the day, the coated surface was visually observed (crack resistance evaluation criteria; ：: no cracks ○: small cracks ×: large cracks).
Workability was evaluated by a sensory test using troweling (workability evaluation criteria; ：: excellent ○: good △: normal ×: inferior). Table 1 shows the results.
[0032]
(Example 2)
100 parts by mass of slaked lime for plasterer, 0.5 parts by mass of methylcellulose and 20 parts by mass of wollastonite of Example 1 were added, uniformly mixed, and a paste kneaded with water was obtained. The standard water mixture was 82.3%. Tests for adhesion strength, crack resistance, and workability were performed as in Example 1. Table 1 shows the results.
[0033]
(Example 3)
A part of the paste prepared in Example 2 was sealed in a can, opened after one month at room temperature, and tested for adhesion strength, crack resistance and workability as in Example 1. Table 1 shows the results.
[0034]
(Example 4)
100 parts by mass of slaked lime for plasterer, 0.5 parts by mass of methylcellulose, and 50 parts by mass of wollastonite of Example 1 were added, uniformly mixed, and a paste kneaded with water was obtained. The standard water mixture was 76.4%. Tests for adhesion strength, crack resistance, and workability were performed as in Example 1. Table 1 shows the results.
[0035]
(Example 5)
100 parts by mass of plastered slaked lime, 0.5 part by mass of methylcellulose, and 100 parts by mass of wollastonite of Example 1 were added, mixed uniformly, and a paste kneaded with water was obtained. The standard water mixture was 74.2%. Tests for adhesion strength, crack resistance, and workability were performed as in Example 1. Table 1 shows the results.
[0036]
(Example 6)
100 parts by mass of slaked lime for plasterer, 0.5 parts by mass of methylcellulose and 150 parts by mass of wollastonite of Example 1 were added, uniformly mixed to obtain a paste kneaded with water. The standard water mixture was 73.4%. Tests for adhesion strength, crack resistance, and workability were performed as in Example 1. Table 1 shows the results.
[0037]
(Example 7)
100 parts by mass of slaked lime for plasterer, 0.5 parts by mass of methylcellulose, and 200 parts by mass of wollastonite of Example 1 were added, uniformly mixed, and a paste kneaded with water was obtained. The standard water mixture was 70.4%. Tests for adhesion strength, crack resistance, and workability were performed as in Example 1. Table 1 shows the results.
[0038]
(Example 8)
100 parts by mass of slaked lime for plasterer, 0.5 parts by mass of methylcellulose, and 250 parts by mass of wollastonite of Example 1 were added, uniformly mixed, and a paste kneaded with water was obtained. The standard water mixture was 68.8%. Tests for adhesion strength, crack resistance, and workability were performed as in Example 1. Table 1 shows the results.
[0039]
(Example 9)
100 parts by mass of slaked lime for plasterer, 0.5 parts by mass of methylcellulose, and 20 parts by mass of wollastonite (trade name: KH-120, manufactured by Kawatetsu Mining Co., Ltd.) were added, uniformly mixed, and a paste kneaded with water was obtained. . The standard water mixture was 78.2%. Tests for adhesion strength, crack resistance, and workability were performed as in Example 1. Table 1 shows the results.
[0040]
(Example 10)
A part of the paste prepared in Example 9 was sealed in a can, opened after one month at room temperature, and tested for adhesion strength, crack resistance and workability in the same manner as in Example 1. Table 1 shows the results.
[0041]
(Example 11)
100 parts by mass of slaked lime for plasterer, 0.5 parts by mass of methylcellulose, and 50 parts by mass of wollastonite of Example 9 were added, uniformly mixed, and a paste kneaded with water was obtained. The standard water mixture was 60.6%. Tests for adhesion strength, crack resistance, and workability were performed as in Example 1. Table 1 shows the results.
[0042]
(Example 12)
100 parts by mass of slaked lime for plasterer, 0.5 parts by mass of methylcellulose, and 100 parts by mass of wollastonite of Example 9 were added, uniformly mixed, and a paste kneaded with water was obtained. The standard water mixture was 57.4%. Tests for adhesion strength, crack resistance, and workability were performed as in Example 1. Table 1 shows the results.
[0043]
(Example 13)
100 parts by mass of slaked lime for plasterer, 0.5 parts by mass of methylcellulose and 150 parts by mass of wollastonite of Example 9 were added, uniformly mixed, and a paste kneaded with water was obtained. The standard water mixture was 53.3%. Tests for adhesion strength, crack resistance, and workability were performed as in Example 1. Table 1 shows the results.
[0044]
(Example 14)
100 parts by mass of slaked lime for plasterer, 0.5 parts by mass of methylcellulose, and 200 parts by mass of wollastonite of Example 9 were added, uniformly mixed, and a paste kneaded with water was obtained. The standard water mixture was 50.7%. Tests for adhesion strength, crack resistance, and workability were performed as in Example 1. Table 1 shows the results.
[0045]
(Example 15)
100 parts by mass of slaked lime for plasterer, 0.5 parts by mass of methylcellulose, and 250 parts by mass of wollastonite of Example 9 were added, uniformly mixed to obtain a paste kneaded with water. The standard water mixture was 48.4%. Tests for adhesion strength, crack resistance, and workability were performed as in Example 1. Table 1 shows the results.
[0046]
(Example 16)
100 parts by mass of dolomite plaster, 0.5 parts by mass of methylcellulose, and 50 parts by mass of wollastonite of Example 1 were added, uniformly mixed, and a paste kneaded with water was obtained. The standard water mixture was 78.3%. Tests for adhesion strength, crack resistance, and workability were performed as in Example 1. Table 1 shows the results.
[0047]
(Comparative Example 1)
100 parts by mass of slaked lime for plasterer, 0.5 parts by mass of methylcellulose, and 3 parts by mass of wollastonite of Example 1 were added, uniformly mixed, and a paste kneaded with water was obtained. The standard water mixture was 86.0%. Tests for adhesion strength, crack resistance, and workability were performed as in Example 1. Table 1 shows the results.
[0048]
(Comparative Example 2)
100 parts by mass of slaked lime for plasterer, 0.5 parts by mass of methylcellulose (trade name; 90SH-4000, manufactured by Shin-Etsu Chemical Co., Ltd.), and 300 parts by mass of wollastonite of Example 1 were added, and the paste was uniformly mixed and kneaded with water. Got. The standard water mixture was 65.6%. Tests for adhesion strength, crack resistance, and workability were performed as in Example 1. Table 1 shows the results.
[0049]
(Comparative Example 3)
100 parts by mass of slaked lime for plasterer, 0.5 parts by mass of methylcellulose, 20 parts by mass of wollastonite having an average fiber diameter of 5 μm and an average fiber length of 50 μm were added, uniformly mixed, and a paste kneaded with water was obtained. The standard water mixture was 96.6%. Tests for adhesion strength, crack resistance, and workability were performed as in Example 1. Table 1 shows the results.
[0050]
(Comparative Example 4)
100 parts by mass of slaked lime for plasterer, 0.5 parts by mass of methylcellulose, 20 parts by mass of wollastonite having an average fiber diameter of 100 μm and an average fiber length of 600 μm were added, uniformly mixed to obtain a paste kneaded with water. The standard water mixture was 60.3%. Tests for adhesion strength, crack resistance, and workability were performed as in Example 1. Table 1 shows the results.
[0051]
(Comparative Example 5)
100 parts by mass of plastered slaked lime, 0.5 part by mass of methylcellulose, and 4 parts by mass of vegetable fiber hemp (manufactured by Matsuzaki Building Materials Co., Ltd.) were added, uniformly mixed, and a paste kneaded with water was obtained. The standard water mixture was 87.3%. Tests for adhesion strength, crack resistance, and workability were performed as in Example 1. This paste was entangled with the fiber and the roller surface, and was difficult to apply with a roller. Table 1 shows the results.
[0052]
(Comparative Example 6)
100 parts by mass of slaked lime for plasterer and 0.5 parts by mass of methylcellulose were uniformly mixed to obtain a paste kneaded with water. The standard water mixture was 84.6%. Tests for adhesion strength, crack resistance, and workability were performed as in Example 1. Table 1 shows the results.
[0053]
(Comparative Example 7)
100 parts by mass of dolomite plaster and 0.5 parts by mass of methylcellulose were uniformly mixed to obtain a paste kneaded with water. The standard water mixture was 87.6%. Tests for adhesion strength, crack resistance, and workability were performed as in Example 1. Table 1 shows the results.
[0054]
[Table 1]
As shown in Table 1, it can be seen that the slaked lime-based coating material composition of the present invention has excellent strength after curing, good adhesion to the base, and excellent workability.
Regarding the crack resistance, when the amount of addition is small and thick coating is applied, cracks tend to be easily formed. However, when 50 parts by weight of wollastonite is added to 100 parts by weight of slaked lime (Example 4), the coating thickness is 6 mm. No cracks were formed, indicating that the crack resistance was excellent. In addition, the slaked lime-based coating material of the present invention may be kneaded with water when used, or may be kneaded with water in advance.
[0056]
On the other hand, when the added amount of wollastonite was 5 parts by mass or less with respect to 100 parts by mass of slaked lime (Comparative Example 1), no improvement in adhesion strength, crack resistance and workability was observed.
When the added amount of wollastonite is 250 parts by mass or more with respect to 100 parts by mass of slaked lime (Comparative Example 2), although the adhesive strength and the crack resistance are excellent, the paste has a rough feeling and is difficult to apply. Workability was extremely poor.
When wollastonite having an average fiber diameter of less than 10 μm and an average fiber length of less than 140 μm was used (Comparative Example 3), no improvement in crack resistance and workability was observed.
When wollastonite having an average fiber diameter of 70 μm or more and an average fiber length of 500 μm or more was used (Comparative Example 4), the dispersion state during kneading was poor, and the adhesion strength, crack resistance, and workability were extremely poor. When the hemp was used (Comparative Example 5), the crack resistance and workability were excellent, but the crack resistance at the time of thick coating was low.
In the slaked lime system to which wollastonite was not added (Comparative Examples 6 and 7), the adhesion strength, crack resistance and workability were remarkably inferior.
[0057]
【The invention's effect】
The slaked lime-based coating material composition according to claim 1 of the present invention is a powder obtained by mixing wollastonite with calcium hydroxide or a mixture of calcium hydroxide and magnesium hydroxide, and kneaded with water when used. Wollastonite is excellent in mixing and dispersibility with slaked lime, and a predetermined amount of wollastonite can be added according to the target coating thickness, resulting in a crack prevention effect and an increase in the strength of the coating material. In addition, wollastonite is chemically stable even under slaked lime-based alkali, so it does not cause deterioration over time, and has an affinity for slaked lime and calcium carbonate generated by absorbing carbon dioxide in the air after construction. Not only shows a permanent crack prevention effect, but also has excellent workability without sagging during construction, and has a good iron coatability, so an extremely smooth finished surface can be obtained. A marked effect that has a performance to be provided as ash-plastering material.
[0058]
The slaked lime-based coating material composition according to claim 2 of the present invention is a powder obtained by mixing wollastonite with calcium hydroxide or a mixture of calcium hydroxide and magnesium hydroxide, and previously kneaded with water to form a paste. It is not necessary to knead with water for use because it is kneaded with water in advance and made into a stable paste, wollastonite is excellent in mixing and dispersibility with slaked lime, A predetermined amount of wollastonite can be added according to the desired coating thickness, which provides a crack prevention effect and increases the strength of the coating material.Wollastonite is chemically stable even under slaked lime-based alkali, so Highly compatible with slaked lime and calcium carbonate generated by absorbing carbon dioxide gas in the air after construction without permanent deterioration, showing a permanent crack prevention effect Not hunting, excellent workability without drooping in construction, achieves the remarkable effect that has a performance to be provided as a slaked lime-based plastering material such as very smooth finished surface is obtained because-resistant also good 鏝塗.
[0059]
The slaked lime-based coating material composition according to claim 3 of the present invention is the same as the slaked lime-based coating material composition according to claim 1 or 2, and is based on 100 parts by mass of calcium hydroxide or a mixture of calcium hydroxide and magnesium hydroxide. On the other hand, it is characterized by adding 5 parts by mass to 250 parts by mass of wollastonite, and within this range, the workability, the crack resistance and the strength of the cured body are excellent, and the coating thickness is increased. Has the further remarkable effect that cracks do not occur.
[0060]
The slaked lime-based coating material composition according to claim 4 of the present invention is the slaked lime-based coating material composition according to claim 1, 2 or 3, wherein wollastonite has an average fiber diameter of 10 to 70 µm and an average fiber length. It is characterized by having a length of 140 to 500 μm, and within this range, it is excellent in crack resistance, dispersion state at the time of kneading, and reduction effect of dimensional shrinkage, does not generate lumps at the time of kneading, and causes variation in material strength. There is a further remarkable effect that there is no.
Claims (4)
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007162355A (en) * | 2005-12-14 | 2007-06-28 | Panahome Corp | Hygroscopic wall-coating material, execution method therefor, and wall surface structure of building |
| KR20230076875A (en) | 2021-11-22 | 2023-06-01 | 한국석회석신소재연구재단 | CaO And Lime-based water-based exterior paint Using Oyster Shell And Manufacturing Method Thereof |
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2003
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007162355A (en) * | 2005-12-14 | 2007-06-28 | Panahome Corp | Hygroscopic wall-coating material, execution method therefor, and wall surface structure of building |
| KR20230076875A (en) | 2021-11-22 | 2023-06-01 | 한국석회석신소재연구재단 | CaO And Lime-based water-based exterior paint Using Oyster Shell And Manufacturing Method Thereof |
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