JP2001522326A - 成分の均質化を利用する立体物の形成方法 - Google Patents
成分の均質化を利用する立体物の形成方法Info
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- JP2001522326A JP2001522326A JP54726498A JP54726498A JP2001522326A JP 2001522326 A JP2001522326 A JP 2001522326A JP 54726498 A JP54726498 A JP 54726498A JP 54726498 A JP54726498 A JP 54726498A JP 2001522326 A JP2001522326 A JP 2001522326A
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C26/00—Coating not provided for in groups C23C2/00 - C23C24/00
- C23C26/02—Coating not provided for in groups C23C2/00 - C23C24/00 applying molten material to the substrate
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/09—Mixtures of metallic powders
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/12—Metallic powder containing non-metallic particles
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
- B29C64/10—Processes of additive manufacturing
- B29C64/165—Processes of additive manufacturing using a combination of solid and fluid materials, e.g. a powder selectively bound by a liquid binder, catalyst, inhibitor or energy absorber
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y10/00—Processes of additive manufacturing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
- B33Y70/10—Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C12/00—Alloys based on antimony or bismuth
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C28/00—Alloys based on a metal not provided for in groups C22C5/00 - C22C27/00
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C26/00—Coating not provided for in groups C23C2/00 - C23C24/00
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F10/00—Additive manufacturing of workpieces or articles from metallic powder
- B22F10/20—Direct sintering or melting
- B22F10/28—Powder bed fusion, e.g. selective laser melting [SLM] or electron beam melting [EBM]
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F10/00—Additive manufacturing of workpieces or articles from metallic powder
- B22F10/30—Process control
- B22F10/32—Process control of the atmosphere, e.g. composition or pressure in a building chamber
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F12/00—Apparatus or devices specially adapted for additive manufacturing; Auxiliary means for additive manufacturing; Combinations of additive manufacturing apparatus or devices with other processing apparatus or devices
- B22F12/40—Radiation means
- B22F12/41—Radiation means characterised by the type, e.g. laser or electron beam
- B22F12/43—Radiation means characterised by the type, e.g. laser or electron beam pulsed; frequency modulated
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F12/00—Apparatus or devices specially adapted for additive manufacturing; Auxiliary means for additive manufacturing; Combinations of additive manufacturing apparatus or devices with other processing apparatus or devices
- B22F12/40—Radiation means
- B22F12/44—Radiation means characterised by the configuration of the radiation means
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F12/00—Apparatus or devices specially adapted for additive manufacturing; Auxiliary means for additive manufacturing; Combinations of additive manufacturing apparatus or devices with other processing apparatus or devices
- B22F12/60—Planarisation devices; Compression devices
- B22F12/67—Blades
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/0058—Liquid or visquous
- B29K2105/0064—Latex, emulsion or dispersion
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/0088—Blends of polymers
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/25—Process efficiency
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Organic Chemistry (AREA)
- Metallurgy (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Composite Materials (AREA)
- Structural Engineering (AREA)
- Civil Engineering (AREA)
- Ceramic Engineering (AREA)
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Powder Metallurgy (AREA)
- Sampling And Sample Adjustment (AREA)
- Detergent Compositions (AREA)
- Solid State Image Pick-Up Elements (AREA)
Abstract
Description
Claims (1)
- 【特許請求の範囲】 1. 成分AおよびBを有する分散物に、放射物を照射することによって、三 次元一体型目的物を製造するための方法であって、 成分AおよびBを有する分散物を提供するステップ(c)、 分散物で層を形成するステップ(b)、 放射物を照射することによって、分散物を均質化し、成分AおよびBを有する アロイを形成するステップ(c)、および 分散物の既存の層の上に、分散物の後続の層を適用することによって前記ステ ップ(a)〜(c)を反復し、均質化された一体型の三次元目的物を形成するた めに、新たな均質化領域を、既存の均質化領域と統合するステップ(d)を有す る方法。 2. 一体型目的物と分散物とを分離するステップを、さらに有する請求の範 囲第1項に記載の方法。 3. 一体型目的物を有するアロイは、成分AおよびBを有する分散物とは異 なる融点を有している請求の範囲第1項に記載の方法。 4. 成分AおよびBは、ポリマー、金属あるいはセラミックである請求の範 囲第1項に記載の方法。 5. 成分AおよびBは、ポリマーであり、放射物の照射により形成されるア ロイは、ポリマーアロイである請求の範囲第1項に記載の方法。 6. ポリマー成分の一方は、液体であり、ポリマー成分の他方は、粒状であ る請求の範囲第5項に記載の方法。 7. 成分AおよびBは、金属であり、放射物の照射により形成されるアロイ は、金属アロイである請求の範囲第1項に記載の方法。 8. アロイは、金属セラミックである請求の範囲第1項に記載の方 法。 9. 成分Aは、固体であり、成分Bは、液体である請求の範囲第1項に記載 の方法。 10. 成分Aは、粒状である請求の範囲第9項に記載の方法。 11. 成分Aは、結晶性である請求の範囲第9項に記載の方法。 12. 成分Aは、シート形状あるいは粉末形状である請求の範囲第9項に記載 の方法。 13. 成分Aおよび成分Bは、密度が異なり、分散物の温度は、成分の分離を 抑制あるいは防止するように維持されている請求の範囲第9項に記載の方法。 14. 成分Aおよび成分Bは、密度が異なり、成分AおよびBを有する分散物 は、液状成分Bに分散している成分AおよびBを有する固相アロイを有する請求 の範囲第9項に記載の方法。 15. 分散物は、熱染料を、さらに有する請求の範囲第1項に記載の方法。 16. 成分Aは、融点MpAを有し、成分Bは、融点MpBを有し、融点Mp Aは、融点MpBよりも高く、均質化によって、MpBとは異なる融点を有する 共融物を有するアロイを形成する請求の範囲第1項に記載の方法。 17. 一体型目的物は、融点の違いに基づいて、分散物から分離される請求の 範囲第16項に記載の方法。 18. 一体型目的物は、融点の違いに基づいて、分散物から分離される請求の 範囲第16項に記載の方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/846,271 US5980812A (en) | 1997-04-30 | 1997-04-30 | Solid imaging process using component homogenization |
US08/846,271 | 1997-04-30 | ||
PCT/US1998/008490 WO1998048993A1 (en) | 1997-04-30 | 1998-04-28 | Solid imaging process using component homogenization |
Publications (3)
Publication Number | Publication Date |
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JP2001522326A true JP2001522326A (ja) | 2001-11-13 |
JP2001522326A5 JP2001522326A5 (ja) | 2005-12-02 |
JP4766723B2 JP4766723B2 (ja) | 2011-09-07 |
Family
ID=25297407
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP54726498A Expired - Fee Related JP4766723B2 (ja) | 1997-04-30 | 1998-04-28 | 成分の均質化を利用する立体物の形成方法 |
Country Status (9)
Country | Link |
---|---|
US (2) | US5980812A (ja) |
EP (1) | EP1015213B1 (ja) |
JP (1) | JP4766723B2 (ja) |
AT (1) | ATE430648T1 (ja) |
AU (1) | AU7261298A (ja) |
CA (1) | CA2288153C (ja) |
DE (2) | DE98919933T1 (ja) |
ES (1) | ES2325696T3 (ja) |
WO (1) | WO1998048993A1 (ja) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2007010598A1 (ja) * | 2005-07-19 | 2007-01-25 | Homs Engineering Inc. | ステントの製造方法及び粉体焼結加工装置 |
KR20180077199A (ko) * | 2015-10-30 | 2018-07-06 | 쇠라 테크널러지스 인코포레이티드 | 적층식 제조 시스템 및 방법 |
WO2018193744A1 (ja) * | 2017-04-19 | 2018-10-25 | 三菱電機株式会社 | 三次元造形装置 |
JP2018199864A (ja) * | 2017-05-25 | 2018-12-20 | 東邦塗料工業股▲分▼有限公司Donbon Paints Industrial Co.,Ltd | レーザ焼結造形用金属コロイドの作製方法 |
CN109070403A (zh) * | 2016-02-26 | 2018-12-21 | 特里奥实验室公司 | 利用原位注入来实体自由成形制造物体的方法和装置 |
JP2019502028A (ja) * | 2015-11-06 | 2019-01-24 | イノマック 21 ソシエダ リミターダ | 金属部品の経済的な製造方法 |
KR20220073678A (ko) * | 2020-11-26 | 2022-06-03 | 에스에이에스 쓰리디세람-신토 | 세라믹 또는 금속 소재로부터의 친환경 부품 제조기 |
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DE19846478C5 (de) * | 1998-10-09 | 2004-10-14 | Eos Gmbh Electro Optical Systems | Laser-Sintermaschine |
US6547552B1 (en) * | 2000-02-08 | 2003-04-15 | Efrem V. Fudim | Fabrication of three-dimensional objects by irradiation of radiation-curable materials |
WO2003000480A1 (en) * | 2001-06-22 | 2003-01-03 | The Regents Of The University Of Michigan | Methods of designing and fabricating molds |
US6927018B2 (en) * | 2001-10-29 | 2005-08-09 | Hewlett-Packard Development Company, L.P. | Three dimensional printing using photo-activated building materials |
US6865949B2 (en) * | 2003-01-31 | 2005-03-15 | Hewlett-Packard Development Company, L.P. | Transducer-based sensor system |
US6913794B2 (en) * | 2002-01-14 | 2005-07-05 | Coherent, Inc. | Diode-laser curing of liquid epoxide encapsulants |
US7306758B2 (en) | 2003-03-13 | 2007-12-11 | Hewlett-Packard Development Company, L.P. | Methods and systems for controlling printhead temperature in solid freeform fabrication |
US7540996B2 (en) * | 2003-11-21 | 2009-06-02 | The Boeing Company | Laser sintered titanium alloy and direct metal fabrication method of making the same |
KR100606457B1 (ko) * | 2004-11-11 | 2006-11-23 | 한국기계연구원 | 3차원 프린팅 조형시스템 |
DE102005022308B4 (de) * | 2005-05-13 | 2007-03-22 | Eos Gmbh Electro Optical Systems | Vorrichtung und Verfahren zum Herstellen eines dreidimensionalen Objekts mit einem beheizten Beschichter für pulverförmiges Aufbaumaterial |
DE102005035987A1 (de) * | 2005-07-28 | 2007-02-01 | "Stiftung Caesar" (Center Of Advanced European Studies And Research) | Verfahren zur Herstellung von dreidimensionalen Formkörpern |
DE102006005500A1 (de) * | 2006-02-07 | 2007-08-09 | Degussa Gmbh | Verwendung von Polymerpulver, hergestellt aus einer Dispersion, in einem formgebenden Verfahren und Formkörper, hergestellt aus diesem Polymerpulver |
DE102006023485A1 (de) * | 2006-05-18 | 2007-11-22 | Eos Gmbh Electro Optical Systems | Vorrichtung und Verfahren zum Herstellen eines dreidimensionalen Objekts |
DE102006049216A1 (de) * | 2006-10-18 | 2008-04-24 | Mtu Aero Engines Gmbh | Hochdruckturbinen-Rotor und Verfahren zur Herstellung eines Hochdruckturbinen-Rotors |
WO2008103985A2 (en) * | 2007-02-23 | 2008-08-28 | The Exone Company, Llc | Replaceable build box for three dimensional printer |
KR100847550B1 (ko) | 2007-04-27 | 2008-07-21 | 한국기계연구원 | 3차원 프린팅 조형시스템의 조형롤러 장치 |
WO2009128902A1 (en) | 2008-04-14 | 2009-10-22 | Rolls-Royce Corporation | Method for producing ceramic stereolithography parts |
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US8186414B2 (en) | 2009-08-21 | 2012-05-29 | Loughborough University | Method for forming an object |
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CH705662A1 (de) * | 2011-11-04 | 2013-05-15 | Alstom Technology Ltd | Prozess zur Herstellung von Gegenständen aus einer durch Gamma-Prime-Ausscheidung verfestigten Superlegierung auf Nickelbasis durch selektives Laserschmelzen (SLM). |
GB201209415D0 (en) * | 2012-05-28 | 2012-07-11 | Renishaw Plc | Manufacture of metal articles |
EP3102353A4 (en) * | 2014-02-03 | 2017-10-25 | North Carolina State University | Three-dimensional printing of metallic materials |
US11000992B2 (en) * | 2015-02-20 | 2021-05-11 | Carbon, Inc. | Methods and apparatus for continuous liquid interface printing with electrochemically supported dead zone |
US10744714B2 (en) | 2015-04-30 | 2020-08-18 | Hewlett-Packard Development Company, L.P. | Misalignment detection for a 3D printing device |
CN107206682B (zh) | 2015-04-30 | 2020-11-20 | 惠普发展公司,有限责任合伙企业 | 用于产生三维彩色功能部件的方法、系统和存储介质 |
US11478983B2 (en) | 2015-06-19 | 2022-10-25 | General Electric Company | Additive manufacturing apparatus and method for large components |
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US10220468B2 (en) * | 2015-10-15 | 2019-03-05 | Lockheed Martin Corporation | Direct manufacturing systems and methods utilizing active guides and passive molds |
TWI582885B (zh) * | 2015-12-30 | 2017-05-11 | 國立中央大學 | 低溫製造組織工程用支架的平台結構及低溫製造組織工程用支架的製造方法 |
DE102016113246A1 (de) * | 2016-07-19 | 2018-01-25 | GEFERTEC GmbH | Verfahren und Vorrichtung zur Erzeugung eines metallischen Werkstoffgemischs bei der additiven Fertigung |
US11766721B2 (en) * | 2019-08-23 | 2023-09-26 | Indium Corporation | Thermally decomposing build plate for facile release of 3D printed objects |
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JPH07205305A (ja) * | 1994-01-14 | 1995-08-08 | Nippon Telegr & Teleph Corp <Ntt> | 三次元立体モデルの製造方法および装置 |
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Also Published As
Publication number | Publication date |
---|---|
AU7261298A (en) | 1998-11-24 |
WO1998048993A1 (en) | 1998-11-05 |
EP1015213A1 (en) | 2000-07-05 |
ES2325696T3 (es) | 2009-09-14 |
EP1015213B1 (en) | 2009-05-06 |
DE69840812D1 (de) | 2009-06-18 |
ATE430648T1 (de) | 2009-05-15 |
EP1015213A4 (en) | 2005-11-30 |
USRE37875E1 (en) | 2002-10-15 |
CA2288153A1 (en) | 1998-11-05 |
CA2288153C (en) | 2007-09-04 |
US5980812A (en) | 1999-11-09 |
DE98919933T1 (de) | 2006-06-22 |
JP4766723B2 (ja) | 2011-09-07 |
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