GB994377A - Substituted ammonium humate and process of making same - Google Patents
Substituted ammonium humate and process of making sameInfo
- Publication number
- GB994377A GB994377A GB9114/62A GB911462A GB994377A GB 994377 A GB994377 A GB 994377A GB 9114/62 A GB9114/62 A GB 9114/62A GB 911462 A GB911462 A GB 911462A GB 994377 A GB994377 A GB 994377A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alkyl
- humate
- carbon atoms
- ammonium
- humic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08H—DERIVATIVES OF NATURAL MACROMOLECULAR COMPOUNDS
- C08H99/00—Subject matter not provided for in other groups of this subclass, e.g. flours, kernels
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
- C07D233/04—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
- C07D233/06—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to ring carbon atoms
- C07D233/08—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to ring carbon atoms with alkyl radicals, containing more than four carbon atoms, directly attached to ring carbon atoms
- C07D233/12—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to ring carbon atoms with alkyl radicals, containing more than four carbon atoms, directly attached to ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
- C07D233/14—Radicals substituted by oxygen atoms
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/02—Well-drilling compositions
- C09K8/03—Specific additives for general use in well-drilling compositions
- C09K8/035—Organic additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/02—Well-drilling compositions
- C09K8/32—Non-aqueous well-drilling compositions, e.g. oil-based
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/60—Compositions for stimulating production by acting on the underground formation
- C09K8/84—Compositions based on water or polar solvents
- C09K8/86—Compositions based on water or polar solvents containing organic compounds
- C09K8/88—Compositions based on water or polar solvents containing organic compounds macromolecular compounds
- C09K8/90—Compositions based on water or polar solvents containing organic compounds macromolecular compounds of natural origin, e.g. polysaccharides, cellulose
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
- F02B3/00—Engines characterised by air compression and subsequent fuel addition
- F02B3/06—Engines characterised by air compression and subsequent fuel addition with compression ignition
Abstract
The invention comprises substituted ammonium humates of the formula R1R2R3R4N+ Hu-, wherein Huis the anion of humic acid, at least one of the R's is an alkyl or alkenyl radical having from 12 to 22 carbon atoms in a straight chain and those R's which do not have 12 to 22 carbon atoms in a straight chain represent hydrogen, alkyl radicals having fewer than 12 carbon atoms, phenyl or benzyl, or two of the R's form a carbon ring including N heterocyclically and bearing said 12 to 22 carbon atom alkyl or alkenyl radical, and wherein when two of the R's form a nitrogen-containing heterocyclic ring one of the remaining R's additionally may be hydroxyalkyl or phenyl-substituted hydroxyalkyl. They may be prepared by causing an appropriate ammonium ion of the formula R1R2R3R4N+ to react wit a humate ion, for example by reacting an alkyl ammonium compound in its basic form with humic acid or by reacting the alkyl ammonium compound in its salt form with an alkali salt of humic acid. Quaternary substituted ammonium salts or hydroxides may be reacted directly with humic acid, preferably in the presence of a base. The examples illustrate the preparation of dimethyldioctadecyl-, lauryl-and dimethyldi (hydrogenated tallow alkyl)-ammonium humate using sodium humate obtained from lignite.ALSO:Well-working fluids comprise an oily liquid and a substituted ammonium humate of the general formula R1 R2R3R4N+Hu-, wherein Huis the anion of humic acid, at least one of the R's is an alkyl or alkenyl radical having from 12 to 22 carbon atoms in a straight chain and those R's which do not have 12 to 22 carbon atoms in a straight chain represent hydrogen, alkyl radicals having fewer than 12 carbon atoms, phenyl or benzyl, or two of the R's from a carbon ring including N heterocyclically and bearing said 12 to 22 carbon atoms alkyl or alkenyl radical, and wherein when two of the R's form a nitrogen-containing heterocyclic ring one of the remaining R's additionally may be hydroxyalkyl or phenyl-substituted hydroxyalkyl. The oily liquid is most desirably diesel oil but may be any available crude oil, topped or untopped, or various fractions of crude oil, e.g. kerosene and fuel oil. Generally 2 to 50 lbs. of humate are added per barrel of well-working fluid. Said fluid may also contain weighting materials, e.g. finely ground clay, limestone, silica, barite and celestite; propping agents, e.g. sand, aluminium spheres and walnut shells; thickening agents, e.g. asphalts and soaps; and 1 to 30% by volume of water. In the examples well-working fluids are produced from diesel oil and dimethyldioctadecylammonium humate (Example 4) and diesel oil, dimethyl-(hydrogenated tallow alkyl) ammonium humate, sulphurized tall oil, caustic soda and calcium chloride (Example 8).
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US9579361A | 1961-03-15 | 1961-03-15 | |
| US1181707XA | 1961-03-15 | 1961-03-15 | |
| US95794A US3168475A (en) | 1961-03-15 | 1961-03-15 | Well-working fluids |
| FR891107A FR1323782A (en) | 1962-03-14 | 1962-03-14 | Substituted ammonium humate and its preparation process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB994377A true GB994377A (en) | 1965-06-10 |
Family
ID=32475540
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB9114/62A Expired GB994377A (en) | 1961-03-15 | 1962-03-09 | Substituted ammonium humate and process of making same |
Country Status (2)
| Country | Link |
|---|---|
| GB (1) | GB994377A (en) |
| NL (1) | NL121082C (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2137262A (en) * | 1983-03-25 | 1984-10-03 | Dow Chemical Co | Fracturing fluids containing buoyant inorganic diverting agent in using hydraulic fracturing of sub-terranean formations |
| GB2170807A (en) * | 1985-02-08 | 1986-08-13 | Union Camp Corp | Substituted-ammonium humate fluid loss control agents for oil-based drilling muds |
| GB2360534A (en) * | 2000-03-06 | 2001-09-26 | Bj Services Co | Formation treatment using deformable particles and a proppant |
| US6364018B1 (en) | 1996-11-27 | 2002-04-02 | Bj Services Company | Lightweight methods and compositions for well treating |
| US6439309B1 (en) | 2000-12-13 | 2002-08-27 | Bj Services Company | Compositions and methods for controlling particulate movement in wellbores and subterranean formations |
| US6508305B1 (en) | 1999-09-16 | 2003-01-21 | Bj Services Company | Compositions and methods for cementing using elastic particles |
| US6749025B1 (en) | 1996-11-27 | 2004-06-15 | Bj Services Company | Lightweight methods and compositions for sand control |
| US6772838B2 (en) | 1996-11-27 | 2004-08-10 | Bj Services Company | Lightweight particulate materials and uses therefor |
| US6877560B2 (en) | 2002-07-19 | 2005-04-12 | Halliburton Energy Services | Methods of preventing the flow-back of particulates deposited in subterranean formations |
-
0
- NL NL121082D patent/NL121082C/xx active
-
1962
- 1962-03-09 GB GB9114/62A patent/GB994377A/en not_active Expired
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2137262A (en) * | 1983-03-25 | 1984-10-03 | Dow Chemical Co | Fracturing fluids containing buoyant inorganic diverting agent in using hydraulic fracturing of sub-terranean formations |
| GB2170807A (en) * | 1985-02-08 | 1986-08-13 | Union Camp Corp | Substituted-ammonium humate fluid loss control agents for oil-based drilling muds |
| US6330916B1 (en) | 1996-11-27 | 2001-12-18 | Bj Services Company | Formation treatment method using deformable particles |
| US6364018B1 (en) | 1996-11-27 | 2002-04-02 | Bj Services Company | Lightweight methods and compositions for well treating |
| US6749025B1 (en) | 1996-11-27 | 2004-06-15 | Bj Services Company | Lightweight methods and compositions for sand control |
| US6772838B2 (en) | 1996-11-27 | 2004-08-10 | Bj Services Company | Lightweight particulate materials and uses therefor |
| US6508305B1 (en) | 1999-09-16 | 2003-01-21 | Bj Services Company | Compositions and methods for cementing using elastic particles |
| GB2360534A (en) * | 2000-03-06 | 2001-09-26 | Bj Services Co | Formation treatment using deformable particles and a proppant |
| GB2360534B (en) * | 2000-03-06 | 2004-09-29 | Bj Services Co | Formation treatment method using deformable particles |
| US6439309B1 (en) | 2000-12-13 | 2002-08-27 | Bj Services Company | Compositions and methods for controlling particulate movement in wellbores and subterranean formations |
| US6877560B2 (en) | 2002-07-19 | 2005-04-12 | Halliburton Energy Services | Methods of preventing the flow-back of particulates deposited in subterranean formations |
Also Published As
| Publication number | Publication date |
|---|---|
| NL121082C (en) |
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