GB870024A - Improvements relating to organosilicon compounds - Google Patents
Improvements relating to organosilicon compoundsInfo
- Publication number
- GB870024A GB870024A GB25152/59A GB2515259A GB870024A GB 870024 A GB870024 A GB 870024A GB 25152/59 A GB25152/59 A GB 25152/59A GB 2515259 A GB2515259 A GB 2515259A GB 870024 A GB870024 A GB 870024A
- Authority
- GB
- United Kingdom
- Prior art keywords
- dimethyl
- hydrolysed
- polysiloxane
- solution
- curing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000003961 organosilicon compounds Chemical class 0.000 title 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 6
- -1 p-dimethylchlorosilylphenyl Chemical group 0.000 abstract 5
- 229920001296 polysiloxane Polymers 0.000 abstract 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 abstract 2
- 239000000945 filler Substances 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 150000002978 peroxides Chemical class 0.000 abstract 2
- 229920000642 polymer Chemical group 0.000 abstract 2
- 239000005871 repellent Substances 0.000 abstract 2
- 239000007787 solid Substances 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 abstract 1
- MWJSKDHMQHQUNH-UHFFFAOYSA-N bis(4-bromophenyl)-dimethylsilane Chemical compound C=1C=C(Br)C=CC=1[Si](C)(C)C1=CC=C(Br)C=C1 MWJSKDHMQHQUNH-UHFFFAOYSA-N 0.000 abstract 1
- BPRXPIOCYMTGDI-UHFFFAOYSA-N bis(6-bromosilyl-1,4-dimethylcyclohexa-2,4-dien-1-yl)-dimethylsilane Chemical class CC1(C(C=C(C=C1)C)[SiH2]Br)[Si](C)(C)C1(C(C=C(C=C1)C)[SiH2]Br)C BPRXPIOCYMTGDI-UHFFFAOYSA-N 0.000 abstract 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052794 bromium Inorganic materials 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 125000001309 chloro group Chemical group Cl* 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000004020 conductor Substances 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- LIKFHECYJZWXFJ-UHFFFAOYSA-N dimethyldichlorosilane Chemical compound C[Si](C)(Cl)Cl LIKFHECYJZWXFJ-UHFFFAOYSA-N 0.000 abstract 1
- GKOZKEKDBJADSV-UHFFFAOYSA-N disilanol Chemical compound O[SiH2][SiH3] GKOZKEKDBJADSV-UHFFFAOYSA-N 0.000 abstract 1
- 239000006185 dispersion Substances 0.000 abstract 1
- 229920001971 elastomer Polymers 0.000 abstract 1
- 239000000806 elastomer Substances 0.000 abstract 1
- 239000004744 fabric Substances 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 230000007062 hydrolysis Effects 0.000 abstract 1
- 238000006460 hydrolysis reaction Methods 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 238000011065 in-situ storage Methods 0.000 abstract 1
- 239000011777 magnesium Substances 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 239000012047 saturated solution Substances 0.000 abstract 1
- 150000004756 silanes Chemical class 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 abstract 1
- 235000017557 sodium bicarbonate Nutrition 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
- 239000004753 textile Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/12—Organo silicon halides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Silicon Polymers (AREA)
Abstract
The invention comprises silylarylene compounds having the formula: <FORM:0870024/IV (a)/1> where X is chlorine, bromine or hydroxyl, and polymers derived therefrom having the recurring unit: <FORM:0870024/IV (a)/2> A mixture of bis (p-dimethylchlorosilylphenyl) dimethyl and bis (p-dimethylbromosilylphenyl) dimethyl silanes is prepared by reacting dimethyl-dichlorosilane with dimethyl-di-(p-bromophenyl) silane in the presence of magnesium in ether. The product also probably contains the mixed bromochloro derivative. These silanes are hydrolysed with a saturated solution of sodium bicarbonate to the disilanol which is then hydrolysed with aqueous KOH to give a solid elastic polysiloxane. This polymer can be mixed with finely divided silica and benzoyl or other peroxide and heated to form a cured elastomer. The curing may be effected in situ on a base such as cloth or a copper conductor by applying a solution of the uncured mixture in a solvent such as benzene or toluene. The halosilanes may also be applied to such materials as masonry, textiles and paper, where they are hydrolysed by atmospheric moisture to give a water-repellent surface. The disilanols may be co-condensed with other siloxanes, e.g. methyl and phenyl cyclic tetrasiloxanes.ALSO:A copper core is provided with a heat-resisting polysiloxane insulating coating by passing it through a solution-dispersion of a polysiloxane (see below), filler and curing agent, in a solvent such as benzene or toluene, and heating to cure. The siloxane has the repeating unit <FORM:0870024/III/1> Suitable fillers are finely divided silicas, and the curing agents are peroxides. Water-repellent films of the siloxane may also be provided on solid bodies, e.g. masonry, by applying the corresponding halosilanes and allowing hydrolysis to occur by atmospheric moisture.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US870024XA | 1958-08-15 | 1958-08-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB870024A true GB870024A (en) | 1961-06-07 |
Family
ID=22202271
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB25152/59A Expired GB870024A (en) | 1958-08-15 | 1959-07-22 | Improvements relating to organosilicon compounds |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB870024A (en) |
-
1959
- 1959-07-22 GB GB25152/59A patent/GB870024A/en not_active Expired
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