GB854432A - New triazine azo dyestuffs - Google Patents

New triazine azo dyestuffs

Info

Publication number
GB854432A
GB854432A GB704258A GB704258A GB854432A GB 854432 A GB854432 A GB 854432A GB 704258 A GB704258 A GB 704258A GB 704258 A GB704258 A GB 704258A GB 854432 A GB854432 A GB 854432A
Authority
GB
United Kingdom
Prior art keywords
dyes
specified
residues
azo
radical
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB704258A
Inventor
Herbert Francis Andrew
Alan Metcalf Wooler
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB704258A priority Critical patent/GB854432A/en
Publication of GB854432A publication Critical patent/GB854432A/en
Priority to GB103769A priority patent/GB1260582A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
    • C09B62/02—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group directly attached to a heterocyclic ring
    • C09B62/04—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group directly attached to a heterocyclic ring to a triazine ring
    • C09B62/043—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group directly attached to a heterocyclic ring to a triazine ring containing two or more triazine rings linked together by a non-chromophoric link

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Coloring (AREA)

Abstract

The invention comprises dyes of formula: <FORM:0854432/IV (c)/1> where Z is Hlg, X is an alkylene radical of at least 2 C atoms or an unsubstituted or substituted phenylene or diphenylene radical, R and R1 are H or alkyl and A and A1 are residues of watersoluble azo dyes free from complexly-bound metal and from atomic-groupings which may lead to the formation of metal complexes. The dyes may be made by treating one mol of diamine corresponding to X with 2 mols of appropriate triazine dyes or by treating 2 mols of dyes of the formula AN(H)R with 1 mol of an appropriate ditriazine derivative. Z is specified as bromine or Cl, the latter being preferred. Specified residues corresponding to X are ethylene, propylene, isopropylene and hexamethylene. R and R1 are preferably lower alkyl groups, e.g. methyl, ethyl, propyl and butyl groups. Preferably A and A1 are monoazo residues of the phenylazo-naphthalene and -pyrazolone series. Representative of specified diamines are propylene-, hexamethylene- and pphenylenediamines, 1, 3- phenylenediamine -4- sulphonic acid, benzidine, #stolidine and benzidine-2, 21- sulphonic acid. Indicated as azo dyes are those of Specifications 774,925, 785,120, 785,222, 826,405 and 838,340. The dyes colour cellulose textile materials by the processes of Specifications 797,946, 819,585 and 820,470. They will also colour fibres of wool, nylon and silk and unions of these with cellulosic fibres. Examples are provided of the preparation of the dyes and their use in dyeing processes. In the Provisional Specification X is a divalent radical of at least 2 C atoms many values additional to those given above, e.g. benzyl, xylylene, naphthalene, anthraquinone, fluorene, diphenyl sulphide, azo benzene, diphenyloxadiazole, 2, 4- diphenyl-amino -striazine and 1, 2- bis-(phenylcarbamyl) ethane, being specified.
GB704258A 1958-03-05 1958-03-05 New triazine azo dyestuffs Expired GB854432A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
GB704258A GB854432A (en) 1958-03-05 1958-03-05 New triazine azo dyestuffs
GB103769A GB1260582A (en) 1958-03-05 1969-01-07 New reactive dyestuffs

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB704258A GB854432A (en) 1958-03-05 1958-03-05 New triazine azo dyestuffs

Publications (1)

Publication Number Publication Date
GB854432A true GB854432A (en) 1960-11-16

Family

ID=9825527

Family Applications (1)

Application Number Title Priority Date Filing Date
GB704258A Expired GB854432A (en) 1958-03-05 1958-03-05 New triazine azo dyestuffs

Country Status (1)

Country Link
GB (1) GB854432A (en)

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3251844A (en) * 1961-09-23 1966-05-17 Bayer Ag Anthraquinonyl-dichloroquinoxaline dyestuffs
US3362948A (en) * 1961-05-19 1968-01-09 Ici Ltd Monoazo dyestuffs containing both triazine and pyrimidine groups
US4038267A (en) * 1973-05-24 1977-07-26 Sumitomo Chemical Company, Limited Triazine reactive dyes
US4228071A (en) 1975-01-08 1980-10-14 Ciba-Geigy Corporation Triazine containing fiber-reactive disazo dyestuffs
JPS58104957A (en) * 1981-12-11 1983-06-22 サンド・アクチエンゲゼルシヤフト Organic base material dyeing or printing method
DE3244999A1 (en) * 1981-12-11 1983-06-23 Sandoz-Patent-GmbH, 7850 Lörrach Dyeing method using direct dyes and after-treatment of the dyeings with cationic auxiliaries
US4502866A (en) * 1979-12-06 1985-03-05 Sandoz Ltd. Symmetrical unsubstituted and substituted 2-halo-4-(4'-(trisulfonaphthylazo)phenylamino)-1,3,5-triazin-6-ylamino compounds
US4670547A (en) * 1981-08-08 1987-06-02 Sandoz Ltd. Tetrakisazo compounds having two 1-hydroxy-3- or 4-sulfo-6- or 7-amino- or substituted amino-naphthalene coupling component radicals the amino or substituted amino groups of which are linked 1,3,5-triazine rings
US4925927A (en) * 1987-07-03 1990-05-15 Ciba-Geigy Corporation Reactive dyes containing a vinylsulfonylaminocarbonyl group bound to bis-(triazenylamino)-benzene as bridging member of two chromophoric systems
US5059681A (en) * 1986-08-15 1991-10-22 Imperial Chemical Industries Plc Bis-azotriazinyl reactive dyes having an n-alkyl-phenylenediamine link
US5196033A (en) * 1986-08-15 1993-03-23 Imperial Chemical Industries Plc BIS-azotriazinyl reactive dyes having an N-alkyl-phenylenediamine link for cellulose textiles
EP0625549A1 (en) * 1993-05-17 1994-11-23 Ciba-Geigy Ag Reactive dyes, process for their preparation and the use thereof
US5395925A (en) * 1980-10-07 1995-03-07 Sandoz Ltd. Asymmetric sulfo group-containing disazo compounds containing two 6-halo-1,3,5-triazinyl groups
US5456728A (en) * 1991-12-04 1995-10-10 Bayer Aktiengesellschaft Reactive dyestuff mixture having improved properties in combination
US5925746A (en) * 1997-07-02 1999-07-20 Ciba Specialty Chemicals Corporation Azo dyes, processes for their preparation and the use thereof
EP1514905A1 (en) * 2003-09-12 2005-03-16 DyStar Textilfarben GmbH &amp; Co. Deutschland KG High light fastness reactive red dyes

Cited By (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3362948A (en) * 1961-05-19 1968-01-09 Ici Ltd Monoazo dyestuffs containing both triazine and pyrimidine groups
US3251844A (en) * 1961-09-23 1966-05-17 Bayer Ag Anthraquinonyl-dichloroquinoxaline dyestuffs
US4038267A (en) * 1973-05-24 1977-07-26 Sumitomo Chemical Company, Limited Triazine reactive dyes
US4228071A (en) 1975-01-08 1980-10-14 Ciba-Geigy Corporation Triazine containing fiber-reactive disazo dyestuffs
US4502866A (en) * 1979-12-06 1985-03-05 Sandoz Ltd. Symmetrical unsubstituted and substituted 2-halo-4-(4'-(trisulfonaphthylazo)phenylamino)-1,3,5-triazin-6-ylamino compounds
US5395925A (en) * 1980-10-07 1995-03-07 Sandoz Ltd. Asymmetric sulfo group-containing disazo compounds containing two 6-halo-1,3,5-triazinyl groups
US4670547A (en) * 1981-08-08 1987-06-02 Sandoz Ltd. Tetrakisazo compounds having two 1-hydroxy-3- or 4-sulfo-6- or 7-amino- or substituted amino-naphthalene coupling component radicals the amino or substituted amino groups of which are linked 1,3,5-triazine rings
JPH0525910B2 (en) * 1981-12-11 1993-04-14 Sandoz Ag
JPS58104957A (en) * 1981-12-11 1983-06-22 サンド・アクチエンゲゼルシヤフト Organic base material dyeing or printing method
DE3244999A1 (en) * 1981-12-11 1983-06-23 Sandoz-Patent-GmbH, 7850 Lörrach Dyeing method using direct dyes and after-treatment of the dyeings with cationic auxiliaries
US4866163A (en) * 1981-12-11 1989-09-12 Sandoz, Ltd. Disazo compounds having two 4,8 Disulfonaphthyl-2 diazo component radicals and two triazine 1,3,5 triazine rings linked by a piperazinylene radical
US5059681A (en) * 1986-08-15 1991-10-22 Imperial Chemical Industries Plc Bis-azotriazinyl reactive dyes having an n-alkyl-phenylenediamine link
US5196033A (en) * 1986-08-15 1993-03-23 Imperial Chemical Industries Plc BIS-azotriazinyl reactive dyes having an N-alkyl-phenylenediamine link for cellulose textiles
US4925927A (en) * 1987-07-03 1990-05-15 Ciba-Geigy Corporation Reactive dyes containing a vinylsulfonylaminocarbonyl group bound to bis-(triazenylamino)-benzene as bridging member of two chromophoric systems
US5456728A (en) * 1991-12-04 1995-10-10 Bayer Aktiengesellschaft Reactive dyestuff mixture having improved properties in combination
EP0625549A1 (en) * 1993-05-17 1994-11-23 Ciba-Geigy Ag Reactive dyes, process for their preparation and the use thereof
US5552532A (en) * 1993-05-17 1996-09-03 Ciba-Geigy Corporation Reactive dyes, processes for their preparation and their use
US5684138A (en) * 1993-05-17 1997-11-04 Ciba Specialty Chemicals Corporation Asymmetrical reactive dyes containing two triazinyl radicals which are bridged via an aliphatic bridge member
US5925746A (en) * 1997-07-02 1999-07-20 Ciba Specialty Chemicals Corporation Azo dyes, processes for their preparation and the use thereof
EP1514905A1 (en) * 2003-09-12 2005-03-16 DyStar Textilfarben GmbH &amp; Co. Deutschland KG High light fastness reactive red dyes
US7026458B2 (en) 2003-09-12 2006-04-11 Dystar Textilfarben Gbmh & Co. Deutschland Kg High light fastness reactive red dyes
CN100365073C (en) * 2003-09-12 2008-01-30 德意志戴斯达纺织品及染料两合公司 High light fastness reactive red dyes

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