GB813980A - ª‡,ª‰,ª‰ trichloro-isobutyric acid and derivatives thereof - Google Patents
ª‡,ª‰,ª‰ trichloro-isobutyric acid and derivatives thereofInfo
- Publication number
- GB813980A GB813980A GB3838857A GB3838857A GB813980A GB 813980 A GB813980 A GB 813980A GB 3838857 A GB3838857 A GB 3838857A GB 3838857 A GB3838857 A GB 3838857A GB 813980 A GB813980 A GB 813980A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- esters
- salts
- alkali metal
- ammonium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- VDNLNBCOKMTAJG-UHFFFAOYSA-N 2,3,3-trichloro-2-methylpropanoic acid Chemical compound ClC(Cl)C(Cl)(C)C(O)=O VDNLNBCOKMTAJG-UHFFFAOYSA-N 0.000 title 1
- 239000011780 sodium chloride Substances 0.000 abstract 5
- KQNPFQTWMSNSAP-UHFFFAOYSA-N Isobutyric acid Chemical compound CC(C)C(O)=O KQNPFQTWMSNSAP-UHFFFAOYSA-N 0.000 abstract 4
- 239000002253 acid Substances 0.000 abstract 4
- -1 amine salts Chemical class 0.000 abstract 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical class OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 abstract 3
- 150000002148 esters Chemical class 0.000 abstract 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 abstract 3
- 150000003839 salts Chemical class 0.000 abstract 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 3
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-Amino-2-propanol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 abstract 2
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 abstract 2
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 abstract 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N Diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 abstract 2
- 229940102253 ISOPROPANOLAMINE Drugs 0.000 abstract 2
- 239000002202 Polyethylene glycol Substances 0.000 abstract 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Tris Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 abstract 2
- 229910052783 alkali metal Inorganic materials 0.000 abstract 2
- 150000001340 alkali metals Chemical class 0.000 abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 2
- 239000000969 carrier Substances 0.000 abstract 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N ethanolamine Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 abstract 2
- 229920001223 polyethylene glycol Polymers 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- XXJWXESWEXIICW-UHFFFAOYSA-N 2-(2-Ethoxyethoxy)ethanol Chemical group CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 abstract 1
- CODNYICXDISAEA-UHFFFAOYSA-N Bromine monochloride Chemical compound BrCl CODNYICXDISAEA-UHFFFAOYSA-N 0.000 abstract 1
- RBTARNINKXHZNM-UHFFFAOYSA-K Iron(III) chloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 abstract 1
- FAIAAWCVCHQXDN-UHFFFAOYSA-N Phosphorus trichloride Chemical compound ClP(Cl)Cl FAIAAWCVCHQXDN-UHFFFAOYSA-N 0.000 abstract 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 abstract 1
- 239000004141 Sodium laurylsulphate Substances 0.000 abstract 1
- 239000004480 active ingredient Substances 0.000 abstract 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 abstract 1
- 239000000908 ammonium hydroxide Substances 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N dimethylsulphoxide Chemical class CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N edta Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 abstract 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 1
- 150000002334 glycols Chemical class 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 150000002790 naphthalenes Chemical class 0.000 abstract 1
- 239000003921 oil Substances 0.000 abstract 1
- 235000019198 oils Nutrition 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 229920001281 polyalkylene Polymers 0.000 abstract 1
- 229920000136 polysorbate Polymers 0.000 abstract 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 239000011591 potassium Substances 0.000 abstract 1
- 239000003352 sequestering agent Substances 0.000 abstract 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 239000003784 tall oil Substances 0.000 abstract 1
- 235000015112 vegetable and seed oil Nutrition 0.000 abstract 1
- 239000008158 vegetable oil Substances 0.000 abstract 1
- 239000000080 wetting agent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
- C07C53/15—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen containing halogen
- C07C53/19—Acids containing three or more carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
- C07C51/363—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by introduction of halogen; by substitution of halogen atoms by other halogen atoms
Abstract
The invention comprises a ,b ,b 1-trichloroisobutyric acid, its alkali metal, ammonium and amine salts and its esters. The a ,b ,b 1-trichloroisobutyric acid may be prepared by directly chlorinating isobutyric acid below 180 DEG C. in the presence of a catalyst such as phosphorus trichloride, bromine or ferric chloride. The salts may be prepared by adding the acid to equivalent amounts of an aqueous solution of the alkali metal hydroxide, e.g. sodium or potassium hydroxide, ammonium hydroxide or amine, such as monoethanolamine, diethanolamine, triethanolamine or isopropanolamine. The acid may be esterified with e.g. methyl ethyl or butyl carbitol, mono butyl ether of ethylene glycol or polyethylene glycol.ALSO:The invention comprises compositions containing a ,b ,b 1-trichloro isobutyric acid, and/or its alkali metal, ammonium or amine salts and/or its esters. Salts specified are those of sodium and potassium and those prepared from monoethanolamine, diethanolamine, triethanolamine, or isopropanolamine, and the esters specified are the ethyl or butyl carbitol, monobutyl ether of ethylene glycol, or polyethylene glycol esters. The active ingredient may be dissolved, p dispersed, emulsified or otherwise distributed in a carrier such as water, organic solvents, or dusts, including wetting or dispersing agents, and/or penetrants and/or sequestrants and/or oils and co-solvents. Carriers specified are sulphonated vegetable oils, sodium lauryl sulphate, polyalkylene ether alcohols, polyoxyethylene sorbitan esters of tall oils, ethylene diamine tetra acetic acid, water soluble salts of citric acid, aromatic hydrocarbons, methylated naphthalenes, and dimethyl sulphoxide.
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB813980A true GB813980A (en) | 1959-05-27 |
Family
ID=1745246
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3838857A Expired GB813980A (en) | 1957-12-10 | ª‡,ª‰,ª‰ trichloro-isobutyric acid and derivatives thereof |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB813980A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10409140B2 (en) | 2017-09-21 | 2019-09-10 | Qioptiq Photonics Gmbh & Co. Kg | Method for multi-longitudinal mode continuous wave output based on multi-mode resonant OPO technology |
| US10756505B2 (en) | 2017-09-21 | 2020-08-25 | Qioptiq Photonics Gmbh & Co. Kg | Tunable light source with broadband output |
| CN117105769A (en) * | 2023-10-24 | 2023-11-24 | 山东顺成化学有限公司 | Preparation method of ethyl 2-bromopropionate |
-
1957
- 1957-12-10 GB GB3838857A patent/GB813980A/en not_active Expired
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10409140B2 (en) | 2017-09-21 | 2019-09-10 | Qioptiq Photonics Gmbh & Co. Kg | Method for multi-longitudinal mode continuous wave output based on multi-mode resonant OPO technology |
| US10409139B2 (en) | 2017-09-21 | 2019-09-10 | Qioptiq Photonics Gmbh & Co. Kg | Light source with multi-longitudinal mode continuous wave output based on multi-mode resonant OPO technology |
| US10756505B2 (en) | 2017-09-21 | 2020-08-25 | Qioptiq Photonics Gmbh & Co. Kg | Tunable light source with broadband output |
| CN117105769A (en) * | 2023-10-24 | 2023-11-24 | 山东顺成化学有限公司 | Preparation method of ethyl 2-bromopropionate |
| CN117105769B (en) * | 2023-10-24 | 2024-01-05 | 山东顺成化学有限公司 | Preparation method of ethyl 2-bromopropionate |
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