GB547853A - New perylene derivatives - Google Patents
New perylene derivativesInfo
- Publication number
- GB547853A GB547853A GB336141A GB336141A GB547853A GB 547853 A GB547853 A GB 547853A GB 336141 A GB336141 A GB 336141A GB 336141 A GB336141 A GB 336141A GB 547853 A GB547853 A GB 547853A
- Authority
- GB
- United Kingdom
- Prior art keywords
- perylene
- sodium
- tetracarboxy
- treated
- tetrazotized
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B5/00—Dyes with an anthracene nucleus condensed with one or more heterocyclic rings with or without carbocyclic rings
- C09B5/62—Cyclic imides or amidines of peri-dicarboxylic acids of the anthracene, benzanthrene, or perylene series
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
- Paper (AREA)
Abstract
547,853. Dyes. HADDOCK, N. H., and IMPERIAL CHEMICAL INDUSTRIES, Ltd. March 12, 1941, No. 3361. [Class 2 (iii)] Perylene derivatives. Thiocyano and xanthic ester derivatives of perylene-3:4:9:10-tetracarboxy-di-(phenylimide) are obtained by treating with thiocyanates or xanthates tetrazotized perylene-3:4:9:10-tetracarboxy-di-(m- or paminophenylimides) (cf. Specification 201,786, [Class 2 (iii)]), in which the phenylene nuclei may carry alkyl or alkoxy groups containing not more than 4 carbon atoms. The products are hydrolyzed by sodium sulphide to the corresponding mercaptans and are applicable for dyeing cotton, from a sodium sulphide vat, bright red shades, specially fast to light, chemick and boiling soap solution. The disulphides obtainable by oxidation of the mercaptans, e.g. with air or with sodium m-nitrobenzenesulphonate, are similarly applicable. In examples, (1) perylene-3:4:9:10- tetracarboxy - di - (m - aminophenylimide) is tetrazotized with sodium nitrite and sulphuric acid and the resulting diazonium sulphate is treated with an aqueous solution of sodium thiocyanate and warmed to 95‹C.; (2) the corresponding di-(p-aminophenylimide) is simiarly treated; (3) the diazonium sulphate of (1) is treated with an aqueous solution of potassium ethyl xanthate or the corresponding isopropyl or n-butyl esters and warmed to 50‹C. with addition of sodium carbonate ; (4) perylene- 3:4:9:10 - tetracarboxy - di - (m - amino - p - methylphenylimide) is tetrazotized with sodium nitrite and sulphuric acid and the solution is treated with an aqueous solution of sodium thiocyanate and slowly heated to boiling ; (5) perylene - 3:4:9:10 - tetracarboxy - di - (m - amino - p - methoxyphenylimide) is similarly converted into the di-(m-thiocyano) derivative ; (6) perylene - 3:4:9:10 - tetracarboxy - di - (m - aminophenylimide) is tetrazotized with sodium nitrite and hydrochloric acid and the solution is treated with an aqueous solution at 60-80‹C. containing potassium isopropyl xanthate and sodium carbonate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB336141A GB547853A (en) | 1941-03-12 | 1941-03-12 | New perylene derivatives |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB336141A GB547853A (en) | 1941-03-12 | 1941-03-12 | New perylene derivatives |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB547853A true GB547853A (en) | 1942-09-15 |
Family
ID=9756850
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB336141A Expired GB547853A (en) | 1941-03-12 | 1941-03-12 | New perylene derivatives |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB547853A (en) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2418816A (en) * | 1944-04-13 | 1947-04-15 | Du Pont | Black sulfur dyes and processes for manufacturing the same |
| US9852846B2 (en) | 2015-02-26 | 2017-12-26 | Capacitor Sciences Incorporated | Self-healing capacitor and methods of production thereof |
| US9899150B2 (en) | 2014-05-12 | 2018-02-20 | Capacitor Sciences Incorporated | Energy storage device and method of production thereof |
| US9916931B2 (en) | 2014-11-04 | 2018-03-13 | Capacitor Science Incorporated | Energy storage devices and methods of production thereof |
| US9932358B2 (en) | 2015-05-21 | 2018-04-03 | Capacitor Science Incorporated | Energy storage molecular material, crystal dielectric layer and capacitor |
| US9941051B2 (en) | 2015-06-26 | 2018-04-10 | Capactor Sciences Incorporated | Coiled capacitor |
| US9978517B2 (en) | 2016-04-04 | 2018-05-22 | Capacitor Sciences Incorporated | Electro-polarizable compound and capacitor |
| US10026553B2 (en) * | 2015-10-21 | 2018-07-17 | Capacitor Sciences Incorporated | Organic compound, crystal dielectric layer and capacitor |
| US10153087B2 (en) | 2016-04-04 | 2018-12-11 | Capacitor Sciences Incorporated | Electro-polarizable compound and capacitor |
| US10305295B2 (en) | 2016-02-12 | 2019-05-28 | Capacitor Sciences Incorporated | Energy storage cell, capacitive energy storage module, and capacitive energy storage system |
| US10340082B2 (en) | 2015-05-12 | 2019-07-02 | Capacitor Sciences Incorporated | Capacitor and method of production thereof |
| US10347423B2 (en) | 2014-05-12 | 2019-07-09 | Capacitor Sciences Incorporated | Solid multilayer structure as semiproduct for meta-capacitor |
| US10395841B2 (en) | 2016-12-02 | 2019-08-27 | Capacitor Sciences Incorporated | Multilayered electrode and film energy storage device |
-
1941
- 1941-03-12 GB GB336141A patent/GB547853A/en not_active Expired
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2418816A (en) * | 1944-04-13 | 1947-04-15 | Du Pont | Black sulfur dyes and processes for manufacturing the same |
| US9899150B2 (en) | 2014-05-12 | 2018-02-20 | Capacitor Sciences Incorporated | Energy storage device and method of production thereof |
| US10685782B2 (en) | 2014-05-12 | 2020-06-16 | Capacitor Sciences Incorporated | Capacitor and method of production thereof |
| US10347424B2 (en) | 2014-05-12 | 2019-07-09 | Capacitor Sciences Incorporated | Energy storage device and method of production thereof |
| US10347423B2 (en) | 2014-05-12 | 2019-07-09 | Capacitor Sciences Incorporated | Solid multilayer structure as semiproduct for meta-capacitor |
| US9916931B2 (en) | 2014-11-04 | 2018-03-13 | Capacitor Science Incorporated | Energy storage devices and methods of production thereof |
| US9852846B2 (en) | 2015-02-26 | 2017-12-26 | Capacitor Sciences Incorporated | Self-healing capacitor and methods of production thereof |
| US10340082B2 (en) | 2015-05-12 | 2019-07-02 | Capacitor Sciences Incorporated | Capacitor and method of production thereof |
| US9932358B2 (en) | 2015-05-21 | 2018-04-03 | Capacitor Science Incorporated | Energy storage molecular material, crystal dielectric layer and capacitor |
| US10672561B2 (en) | 2015-06-26 | 2020-06-02 | Capacitor Sciences Incorporated | Coiled capacitor |
| US9941051B2 (en) | 2015-06-26 | 2018-04-10 | Capactor Sciences Incorporated | Coiled capacitor |
| US10854386B2 (en) | 2015-06-26 | 2020-12-01 | Capacitor Sciences Incorporated | Coiled capacitor |
| US10026553B2 (en) * | 2015-10-21 | 2018-07-17 | Capacitor Sciences Incorporated | Organic compound, crystal dielectric layer and capacitor |
| US10305295B2 (en) | 2016-02-12 | 2019-05-28 | Capacitor Sciences Incorporated | Energy storage cell, capacitive energy storage module, and capacitive energy storage system |
| US10153087B2 (en) | 2016-04-04 | 2018-12-11 | Capacitor Sciences Incorporated | Electro-polarizable compound and capacitor |
| US9978517B2 (en) | 2016-04-04 | 2018-05-22 | Capacitor Sciences Incorporated | Electro-polarizable compound and capacitor |
| US10672560B2 (en) | 2016-04-04 | 2020-06-02 | Capacitor Sciences Incorporated | Electro-polarizable compound and capacitor |
| US10707019B2 (en) | 2016-04-04 | 2020-07-07 | Capacitor Science Incorporated | Electro-polarizable compound and capacitor |
| US10395841B2 (en) | 2016-12-02 | 2019-08-27 | Capacitor Sciences Incorporated | Multilayered electrode and film energy storage device |
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