GB2448605A - Copy-Protected documents - Google Patents
Copy-Protected documents Download PDFInfo
- Publication number
- GB2448605A GB2448605A GB0806996A GB0806996A GB2448605A GB 2448605 A GB2448605 A GB 2448605A GB 0806996 A GB0806996 A GB 0806996A GB 0806996 A GB0806996 A GB 0806996A GB 2448605 A GB2448605 A GB 2448605A
- Authority
- GB
- United Kingdom
- Prior art keywords
- tpp
- document
- colour
- visible
- image
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G21/00—Arrangements not provided for by groups G03G13/00 - G03G19/00, e.g. cleaning, elimination of residual charge
- G03G21/04—Preventing copies being made of an original
- G03G21/043—Preventing copies being made of an original by using an original which is not reproducible or only reproducible with a different appearence, e.g. originals with a photochromic layer or a colour background
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/20—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof characterised by a particular use or purpose
- B42D25/29—Securities; Bank notes
-
- B42D15/0013—
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F17/00—Compounds of rare earth metals
- C01F17/20—Compounds containing only rare earth metals as the metal element
- C01F17/206—Compounds containing only rare earth metals as the metal element oxide or hydroxide being the only anion
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/06—Luminescent, e.g. electroluminescent, chemiluminescent materials containing organic luminescent materials
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/40—Agents facilitating proof of genuineness or preventing fraudulent alteration, e.g. for security paper
- D21H21/44—Latent security elements, i.e. detectable or becoming apparent only by use of special verification or tampering devices or methods
- D21H21/48—Elements suited for physical verification, e.g. by irradiation
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
- C09K2211/10—Non-macromolecular compounds
- C09K2211/1018—Heterocyclic compounds
- C09K2211/1025—Heterocyclic compounds characterised by ligands
- C09K2211/1074—Heterocyclic compounds characterised by ligands containing more than three nitrogen atoms as heteroatoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
- C09K2211/18—Metal complexes
- C09K2211/187—Metal complexes of the iron group metals, i.e. Fe, Co or Ni
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
- C09K2211/18—Metal complexes
- C09K2211/188—Metal complexes of other metals not provided for in one of the previous groups
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G2215/00—Apparatus for electrophotographic processes
- G03G2215/00172—Apparatus for electrophotographic processes relative to the original handling
- G03G2215/00206—Original medium
- G03G2215/00299—Confidential, e.g. secret documents
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Accounting & Taxation (AREA)
- General Chemical & Material Sciences (AREA)
- General Physics & Mathematics (AREA)
- Business, Economics & Management (AREA)
- Geology (AREA)
- Finance (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Wood Science & Technology (AREA)
- Luminescent Compositions (AREA)
- Glass Compositions (AREA)
- Cleaning In Electrography (AREA)
- Facsimile Scanning Arrangements (AREA)
- Printing Methods (AREA)
- Developing Agents For Electrophotography (AREA)
Abstract
The invention relates to documents of value incorporating features that prevent them being accurately copied by image reproduction means such as a scanner or photocopier. A document of value (10) bears an image comprising a material comprising a TPP (tetraphenyl porphine) wherein the image has a first appearance under daylight and has a second appearance under synthetic white light. A copy (14) of the original document (10) is not colour identical to the original document. One example of such TPP exhibits a change from a yellow/green colour in visible light to yellow when scanned on a fluorescent scanner, and a change from yellow/green to almost white when reproduction is attempted on an LED scanner. An appropriate printing ink is also disclosed.
Description
Title: Copy-Protected Documents
Field of the Invention
This invention relates to documents incorporating features that prevent them from being accurately copied by an image reproduction means, such as a scanner or photocopier.
Background to the Invention
Documents of value, such as banknotes and bank drafts, incorporate a variety of security features which are difficult to replicate. Image reproduction means, such as photocopiers or scanners, have the capability to replicate an image to a fair degree of accuracy. Documents of value are protected from copying by incorporating features that do not reproduce when the original document is copied by an image reproduction means. These copy-protected documents rely on a number of different features to prevent copying, some of which are based around the use of variable line spacing and variable colour density. When copied, the resolution of the image production means is not sufficient to copy the features accurately, and in some cases the copy reveals a hidden message warning of the non-authenticity of the document. However, image reproduction means are operating to ever improving resolution making these features less effective.
It is an aim of the present invention to provide copy-protected documents with improved security features.
Summary of the Invention
In accordance with the present invention, there is provided a document of value bearing an image comprising a 5, 10, 15, 20-tetra phenyl-2 1H,23H-porphine (TPP) wherein the image has a first appearance under daylight and has a second appearance under synthetic white light, wherein the first and second appearances are different.
It is known that synthetic white light, as generated by an image reproduction means, typically has a spectra which is quite different to that of daylight. However for most documents this difference in spectra does not produce any noticeable differences in colour between the original and the copy. The present inventors have discovered that TPPs can appear as a different colour under synthetic white light and that this property can be used to indicate that copying has taken place.
Thus, attempts to copy such a document by use of a device which illuminates the document with synthetic white light (e.g. photocopiers and scanners) will result in the image being reproduced as a different colour to that in the original. Copies can therefore be detected by visible inspection of the document without the need for a detection apparatus.
At least one of the first and second appearances is as a visible colour, one of the appearances possibly being non-visible. However, preferably the first appearance is a first visible colour and the second appearance is a second visible colour. The first and second colours are different colours and enable the image to be visible under daylight and synthetic white light respectively. The first and second colours may each be any visible colour, including white or black, provided only that the image contrasts with the surrounding part of the document so that it is visible. For example a white image on a green document is a visible image, whereas a white image on a white background is not a visible image.
The change in appearance may arise directly from the change in emission of the TPP.
Alternatively the TPP may be added to a substance to produce different colour changes than those exhibited by the TPP on its own. In this way a TPP exhibiting one colour change can be used to produce a range of colour changes. For example a TPP changing from yellow to transparent mixed with a substance coloured blue gives a green to blue colour change but when added to a substance coloured red gives an orange to red colour change.
The change in the colour of light emitted by the TPPs is due to selective absorption of light.
Absorption of light at or around a main excitation radiation wavelength of synthetic white light can have the effect of the TPP, and therefore the image it is present in, having a different appearance, e.g. having a different colour.
Therefore, preferably the TPP has an absorption band maximum at a first wavelength in the visible spectrum and an associated emission band maximum at a second wavelength in the visible spectrum, different to the first wavelength.
Daylight includes radiation at significant levels at all frequencies in the visible spectrum and beyond. Typical light emitting diode (LED) scanners produce synthetic white light having main excitation wavelengths around 465, 525 and 635nm, which when combined produce a synthetic white light. Photocopiers and scanners operating with fluorescent light have main excitation radiation wavelengths at around 436nrri, 490nm, 546nm, 587nm and 613nm, again resulting in a synthetic white light. The synthetic white light may be TL83 or TL84.
The TPP according to the invention is preferably responsive to LED scanners and reproduction means based on cold cathode fluorescent light or ultraviolet light to produce the colour change, i.e. by absorbing light at one or more of the main excitation wavelengths.
In order to exploit these main excitation radiation wavelengths in this way, preferably the TPP has an absorption band maximum to within lOnm, preferably within 5nm, of one of the wavelengths 465nm, 525nm and 635nm. Alternatively, the TPP may have an absorption band maximum to within I Onm, preferably within Snm, of one of the wavelengths 436nm, 490nm, 546nm, 587nm and 613nm.
The following TPP-type materials have been found to exhibit a colour change under synthetic white light: 5,10,15,20 tetrakis(4-methoxy-phenyl)..2 1 H porphine cobalt(I); 5,10,15,20 tetraphenyl-2 1 H,23H porphine copper(II); 5,10,15,20 tetraphenyl-2 I H,23H porphine iron(III) chloride; 5,10,15,20 tetraphenyl-2 1 H,23H porphine manganese(III) chloride; 5,10,15,20 tetraphenyl-2 1 H,23H porphine nickel(II); 5,10,15,20 tetrakis(4-methoxy-phenyl)2 I H porphine.
Preferably the TPP is incorporated in a printing ink, for ease of placement on the document of value. Preferably the TPP is water insoluble.
Alternatively the TPP may be on or incorporated into a substrate of the document of value by any means, such as inclusion of fibres, planchettes, particles, threads, foils or pieces of polymer incorporating the TPP and carried on or within the document of value.
The invention also lies in a printing ink incorporating a TPP wherein the ink has a first appearance under daylight and has a second appearance under synthetic white light.
Where the TPP is used in printing ink, preferably the TPP has a particle size of 5 microns or less, more preferably 0.9 -0.001 microns.
Such an ink may be printed as a series of dots within a region of colour matched to that of the ink but without the TPP, so producing a very visible speckled effect when replication of the document is attempted by an image reproduction means. The visual effect of the colour change on scanning is then apparent over a larger area without needing to use large amounts of the TPP.
Alternatively, the image may comprise the TPP colour matched to a colour pigment when irradiated. Thus before radiation, the document may show a speckled region resulting from printing separately with colour pigment and ink including the TPP. On irradiation, the TPP appears as the same colour as the pigment, such that the copy then shows a solid block of colour over the relevant area.
The invention will now be described, by way of example, and with reference to the accompanying drawings in which: Figure 1 shows a schematic diagram of a first embodiment of a copy-protected document in accordance with the present invention and its image as replicated by an image reproduction means; and Figure 2 shows a second embodiment.
Description
Figure 1 shows a simplified document of value 10, incorporating a plurality of coloured rectangles 12, wherein an ink pigment used to print the coloured rectangles incorporates an TPP which is visible in daylight as a first colour, shown as grey scale in Figure 1 daylight.
When reproduction of the genuine document 10 is attempted in a photocopier, scanner or other reproduction means, the TPP appears as a different colour during scanning by radiation emitted by the scanner or photocopier, such that a copy 14 originating from the scanner is visually very different to the authentic document 10. The rectangular areas on the copy 14 show as a different colour, which for the sake of easy illustration is shown as black in this example. The genuine document 10 only exhibits a colour change during the scanning process: once it is no longer irradiated by the scanner, the TPP displays its usual daylight colour.
The TPP thus prevents a visually identical copy being reproduced and the copy has such major visible features of difference that it would be readily apparent to any party that the document of value was not authentic. Whilst most commercial establishments receiving money have detectors to check for more complex security features that are invisible under normal daylight, the general public does not have such facilities available to them. However, where documents are protected against simple colour graphic reproduction in accordance with the present invention, the public is readily alerted to the lack of validity of the copy document.
Figure 2 shows an alternative embodiment where the TPP is printed onto the document of value 10 with an ink pigment which has been colour matched with the body colour of the TPP such that when the document of value is viewed under daylight, there is an area 20 of one colour. When replication of the document of value 10 is attempted in a colour scanner or photocopier, the pattern of the active colour changing substance within the colour-matched pigment becomes apparent. In this case, on the copy 14 black stripes become apparent next to grey stripes, the non-active pigment being reproduced as its original on the copy 14.
The person skilled in the art will understand that the schematic representations given are purely by way of example and that generally more complex graphical images would be used on the document of value. The examples given here are for illustration of the general concept of the technique. The colours of grey and black are for the purposes of illustration. Typical colour changes, by way of example, include yellow/green to yellow, orange to pink and purple to pale green.
The colour variation exhibited between the authentic document and the copied document will vary depending on the TPP used and also the radiation used by the scanner or photocopier.
For incorporation into ink pigments, ideally the TPPs have a particle size of around 5 microns as this range of particle sizes remains suspended within the ink and prints more effectively than larger particle sizes. Sub-micron particle sizes are also appropriate, although generally less desirable.
Incorporation of the materials referred to above in documents of value can assist in automatic verification of documents of value Machines that automatically detect the presence of genuine documents of value are widely used. These machines may interrogate documents at any rate of speed by manual or automatic insertion of single or bunches of documents. The materials described in this specification offer an additional means for validating the authenticity of such documents of value when used with these machines.
There are many types of machines that automatically validate documents of value. Machines that use reflected and or transmitted light with a silicon detector or a camera as a means of interrogation are particularly relevant. These machines normally consist of a synthetic visible light source and a means of detecting either reflected and or transmitted visible light which is first incident on the surface of a document. If the light source chosen to interrogate the document is one that a TPP within or on the document of value responds to and the detector used is one that is responsive to the reflected and or transmitted light from the TPP, the machine will be able to detect a unique response from the TPP on the document as it passes the sensor. Alternatively, by switching the light source on and off at a selected scanning rate, the machine would be able to detect the occurrence of the colour change itself.
Typically the synthetic light source used in the validation machine will be that as used in image reproduction means, such as scanners and photocopiers, for example cold cathode fluorescent light or LEDs. Where LEDs are used, there may be a combination of different colour LEDs to ensure the colour change occurs. Using LEDs with different emission characteristics ensures that the colour change can be stimulated, and so validity of the document assessed, even where there are a variety of documents of value incorporating different TPPs and responsive to different wavelengths.
Claims (15)
- claims I. A document of value bearing an image comprising a TPP whereinthe image has a first appearance under daylight and has a second appearance under synthetic white light wherein the first and second appearances are different.
- 2. A document according to claim 1, wherein the first appearance is a first visible colour and the second appearance is a second visible colour.
- 3. A document according to claim I or claim 2, wherein the TPP has an absorption band maximum at a first wavelength in the visible spectrum and an associated emission band maximum at a second wavelength in the visible spectrum, different to the first wavelength.
- 4. A document according to any one of the preceding claims, wherein the synthetic white light is emitted by a plurality of LEDs.
- 5. A document according to any one of the preceding claims, wherein the synthetic white light is generated by an image reproduction means.
- 6. A document according to claim 5, wherein the image reproduction means is a photocopier or a scanner.
- 7. A document according to any one of the preceding claims, wherein the TPP is incorporated in a printing ink.
- 8. A document according to any one of claims 3 to 7, wherein the TPP has an absorption band maximum to within lOnni, preferably within 5nm, of one of the wavelengths 436nm, 490nm, 546nm, 587nm and 613nm.
- 9. A document according to any one of claims 3 to 7, wherein the TPP has an absorption band maximum to within lOnm, preferably within 5nm, of one of the wavelengths, 465nm, 525nm and 635mm
- 10. A printing ink incorporating a TPP, which has a first appearance under daylight and a second appearance under synthetic white light wherein the first and second appearances are different.
- 11. A document of value according to claim 10, wherein the TPP has a particle size less than 5 microns.
- 12. A printing ink in accordance with claim 11 wherein the particle size is in the range 0.9-0.001 microns.
- 13. A printing ink according to any of claims 10 to 12, wherein the TPP is combined with a coloured substance to produce different colour changes than those exhibited by the TPP alone.
- 14. A substrate for a document of value incorporating a TPP, which is visible as a first colour in daylight and is visible as a second colour in synthetic white light.
- 15. A document of value and a printing ink substantially as herein described with reference to the accompanying drawings.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB0707420.6A GB0707420D0 (en) | 2007-04-18 | 2007-04-18 | Copy-protected documents |
Publications (3)
Publication Number | Publication Date |
---|---|
GB0806996D0 GB0806996D0 (en) | 2008-05-21 |
GB2448605A true GB2448605A (en) | 2008-10-22 |
GB2448605B GB2448605B (en) | 2012-05-02 |
Family
ID=38116888
Family Applications (6)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GBGB0707420.6A Ceased GB0707420D0 (en) | 2007-04-18 | 2007-04-18 | Copy-protected documents |
GB0806998A Withdrawn GB2448606A (en) | 2007-04-18 | 2008-04-17 | Doped rare-earth oxides |
GB0806995.7A Expired - Fee Related GB2448604B (en) | 2007-04-18 | 2008-04-17 | Copy-protected documents |
GB0806994.0A Expired - Fee Related GB2448603B (en) | 2007-04-18 | 2008-04-17 | Copy-protected documents |
GB1200640.9A Expired - Fee Related GB2484233B (en) | 2007-04-18 | 2008-04-17 | Improvements in rare-earth-based materials |
GB0806996.5A Expired - Fee Related GB2448605B (en) | 2007-04-18 | 2008-04-17 | Copy-protected documents |
Family Applications Before (5)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GBGB0707420.6A Ceased GB0707420D0 (en) | 2007-04-18 | 2007-04-18 | Copy-protected documents |
GB0806998A Withdrawn GB2448606A (en) | 2007-04-18 | 2008-04-17 | Doped rare-earth oxides |
GB0806995.7A Expired - Fee Related GB2448604B (en) | 2007-04-18 | 2008-04-17 | Copy-protected documents |
GB0806994.0A Expired - Fee Related GB2448603B (en) | 2007-04-18 | 2008-04-17 | Copy-protected documents |
GB1200640.9A Expired - Fee Related GB2484233B (en) | 2007-04-18 | 2008-04-17 | Improvements in rare-earth-based materials |
Country Status (1)
Country | Link |
---|---|
GB (6) | GB0707420D0 (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB0918939D0 (en) * | 2009-10-29 | 2009-12-16 | Bank Of England | Security document |
CN116218525A (en) * | 2023-01-16 | 2023-06-06 | 海南大学 | Thermosensitive up-conversion luminescent material and preparation method thereof |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5271764A (en) * | 1992-02-12 | 1993-12-21 | Xerox Corporation | Ink compositions |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3758486A (en) * | 1969-05-13 | 1973-09-11 | Westinghouse Electric Corp | Rare earth niobate composition |
US4791449A (en) * | 1986-05-30 | 1988-12-13 | Xerox Corporation | System for prevention of unauthorized copying |
US4678322A (en) * | 1986-05-30 | 1987-07-07 | Xerox Corporation | Method and apparatus for the prevention of unauthorized copying of documents |
JP4378789B2 (en) * | 1999-05-21 | 2009-12-09 | 凸版印刷株式会社 | Anti-counterfeit printed matter |
US6483576B1 (en) * | 1999-12-10 | 2002-11-19 | Laser Lock Technologies, Inc. | Counterfeit detection system |
DE10036940A1 (en) * | 2000-07-28 | 2002-02-07 | Patent Treuhand Ges Fuer Elektrische Gluehlampen Mbh | Luminescence conversion LED |
US20050143249A1 (en) * | 2003-06-26 | 2005-06-30 | Ross Gary A. | Security labels which are difficult to counterfeit |
GB0314883D0 (en) * | 2003-06-26 | 2003-07-30 | Ncr Int Inc | Security labelling |
CN1239673C (en) * | 2003-10-23 | 2006-02-01 | 北京有色金属研究总院 | Red luminescent powder in use for LED, preparing method and electric light source produced |
WO2007041579A2 (en) * | 2005-10-03 | 2007-04-12 | Sun Chemical Corporation | Security pigments and the process of making thereof |
-
2007
- 2007-04-18 GB GBGB0707420.6A patent/GB0707420D0/en not_active Ceased
-
2008
- 2008-04-17 GB GB0806998A patent/GB2448606A/en not_active Withdrawn
- 2008-04-17 GB GB0806995.7A patent/GB2448604B/en not_active Expired - Fee Related
- 2008-04-17 GB GB0806994.0A patent/GB2448603B/en not_active Expired - Fee Related
- 2008-04-17 GB GB1200640.9A patent/GB2484233B/en not_active Expired - Fee Related
- 2008-04-17 GB GB0806996.5A patent/GB2448605B/en not_active Expired - Fee Related
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5271764A (en) * | 1992-02-12 | 1993-12-21 | Xerox Corporation | Ink compositions |
Also Published As
Publication number | Publication date |
---|---|
GB2448603B (en) | 2012-05-02 |
GB0707420D0 (en) | 2007-05-23 |
GB0806994D0 (en) | 2008-05-21 |
GB2484233A (en) | 2012-04-04 |
GB0806996D0 (en) | 2008-05-21 |
GB2448603A (en) | 2008-10-22 |
GB2448604A (en) | 2008-10-22 |
GB2448604B (en) | 2012-05-02 |
GB2484233B (en) | 2012-11-14 |
GB201200640D0 (en) | 2012-02-29 |
GB2448606A (en) | 2008-10-22 |
GB2448605B (en) | 2012-05-02 |
GB0806998D0 (en) | 2008-05-21 |
GB0806995D0 (en) | 2008-05-21 |
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