GB2289841A - Oral care products containing chlorites - Google Patents
Oral care products containing chlorites Download PDFInfo
- Publication number
- GB2289841A GB2289841A GB9410406A GB9410406A GB2289841A GB 2289841 A GB2289841 A GB 2289841A GB 9410406 A GB9410406 A GB 9410406A GB 9410406 A GB9410406 A GB 9410406A GB 2289841 A GB2289841 A GB 2289841A
- Authority
- GB
- United Kingdom
- Prior art keywords
- product
- oral care
- chlorite
- sodium
- sodium chlorite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/22—Peroxides; Oxygen; Ozone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q11/00—Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- General Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Chemical & Material Sciences (AREA)
- Emergency Medicine (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Cosmetics (AREA)
Abstract
An oral care product, such as a mouthwash or spray or a toothpaste contains an oxidising agent in the form of Group I alkali metal chlorite, preferably sodium chlorite. The product may contain up to 5% by volume of the chlorite and optionally up to 8% w/v of bromelain.
Description
Oral care products
This invention relates to oral care products, a term which includes mouthwashes, toothpastes and oral sprays. Mouthwashes are liquid preparations intended to improve users' oral hygiene. In use they are decanted into a user's mouth, but not swallowed. They are dispersed in the mouth by violent agitation, so that the liquid passes over all the internal surfaces of the mouth, including the teeth and gums. The usual mouthwash contains a disinfecting agent, to cleanse the skin surfaces, and an agent intended to freshen the breath. Toothpastes are particularly employed to clean teeth by application to the bristles of a brush which is then used to remove food debris from between the teeth, and by gently abrading the teeth to remove stains and adherent films, such as of plaque. Mouthsprays are liquids which are sprayed under pressure in a fine spray into the open mouth to become deposited on the exposed surfaces of the cheeks, gums and teeth. The sprays become diluted by the saliva naturally present in the mouth, which saliva acts as a vehicle to bathe all the surfaces with the spray ingredients.
The present invention aims at providing an oral care product which, in addition to cleansing the internal surfaces of the mouth, also has a brightening or whitening effect on the teeth.
Accordingly, the present invention provides an oral care product which includes an oxidising agent in the form of a chlorite salt of a Group I alkali metal ion, such as sodium chlorite.
In its preferred ready-for-use form, the oral care product is a liquid or paste containing up to a inXirtL1m of 5.08 by volume or weight of sodium chlorite.
The product in its liquid form may be sold in such a diluted form as to be ready for use as sold. Alternatively, it may be concentrated to a greater extent, for either dilution prior to being used as usual, or for being sprayed in its undiluted form into the mouth so that the spray becomes diluted by saliva in order to ensure that the concentration of sodium chlorite in the mouth remains below a maximum level.
It has been found that incorporation of this oxidising agent has a surprising effect on the teeth, in that it results in the teeth becoming whiter. This is thought to be the result of any deposits of dark or yellowish material on the teeth, such as plaque, being removed or bleached, so that the natural colour of the teeth can be seen more easily. The plaque and any food debris in the mouth are thought to be partially dissolved by the sodium chlorite solution, by chemical interaction therewith.
In practice the product would contain additional ingredients to give it enhanced properties. In its commercial form, it is envisaged that the product would have the following composition: Ingredient Percentages
Rancre Praferred
Sodium chlorite 0.01 - 5.0 0.2
Sodium bicarbonate 0.2 - 12.0 4.0
Sodium fluoride 0.01 - 1.0 0.32
Zinc citrate 0.01 - 2.0 0.8
Bromelain up to 8.0 0.5
Papain up to 8.0 0.125
Triclosan up to 1.0 0.3
Xylitol up to 6.0 2.0
When the product is a liquid, the percentages are by weight or volume, whereas when the product is a solid (as a paste), the percentages are weight over weight.
When the product is in its liquid form, as either a mouthwash or spray, then the above composition would have deionized water added to it to bring it to the desired concentration.
The hydrogen ion concentration (pH) value of the mouthwash form of the invention is about 6.5, to ensure stability before use. When the mouthwash is used, it is believed that the sodium chlorite reacts under the usual acidic conditions in the mouth to generate chlorine dioxide, which is itself a powerful oxidising and anti-bacterial agent. Both chlorites and chlorine dioxide oxidise malodorous thiol compounds which are responsible for halitosis, so that use of the product of the present invention tends to lead to sweeter breath.
In its liquid form, the present invention provides a mouthwash with disinfectant and cleansing properties, and with the additional advantage of improving the appearance of the teeth significantly, and without brushing.
In either its paste or liquid form, it has also been found that sodium chlorite reacts with any nicotine stains on the teeth, or elsewhere in the mouth, both to remove or bleach the stains and to release substances which taste so disagreeable as to deter smokers from continuing to use the mouthwash if they wish to continue smoking. It can therefore form an effective component in any aversion-therapy course for smokers.
Claims (5)
1 An oral care product comprising an oxidising agent in the form of a chlorite of a Group I alkali metal ion, such as sodium chlorite.
2 A product as claimed in claim 1, containing up to 5.0 percent by volume of sodium chlorite.
3 A product as claimed in claim 1 or 2, containing bromelain, up to a maximum of about 8.08 w/v.
4 A product as claimed in claim 1, having the composition:
Ingredient percentage Sodium chlorite 0.01 - 5.0
Sodium bicarbonate 0.2 - 12.0
Sodium fluoride 0.01 - 1.0
Zinc citrate 0.01 - 2.0
Bromelain up to 8.0
Papain up to 8.0
Triclosan up to 1.0
Xylitol up to 6.0.
5 A product as claimed in claim 4, of composition:
Ingredient percentage
Sodium chlorite 0.2
Sodium bicarbonate 4.0
Sodium fluoride 0.32
Zinc citrate 0.8 Bromelain 0.5
Papain 0.125
Triclosan 0.3
Xylitol 2.0 6 A product as claimed in any preceding claim, made into a mouthwash by being dissolved in deionised water.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB9410406A GB2289841B (en) | 1994-05-23 | 1994-05-23 | Oral care products |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB9410406A GB2289841B (en) | 1994-05-23 | 1994-05-23 | Oral care products |
Publications (3)
Publication Number | Publication Date |
---|---|
GB9410406D0 GB9410406D0 (en) | 1994-07-13 |
GB2289841A true GB2289841A (en) | 1995-12-06 |
GB2289841B GB2289841B (en) | 1998-04-15 |
Family
ID=10755645
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB9410406A Expired - Fee Related GB2289841B (en) | 1994-05-23 | 1994-05-23 | Oral care products |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB2289841B (en) |
Cited By (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5944528A (en) * | 1996-07-29 | 1999-08-31 | Idex Dental Sciences, Inc. | Chlorine dioxide tooth whitening compositions |
WO1999043295A1 (en) * | 1998-02-27 | 1999-09-02 | The Procter & Gamble Company | Oral care compositions comprising chlorite |
WO1999043290A1 (en) * | 1998-02-27 | 1999-09-02 | The Procter & Gamble Company | Oral care compositions comprising chlorite and methods |
US6017515A (en) * | 1995-02-24 | 2000-01-25 | Diamond White A.V.V. | Method for preparing a preparation for bleaching teeth or for treating skin complaints and mucous membrane disorders |
DE19854349A1 (en) * | 1998-11-25 | 2000-05-31 | Up To Dent Ag Balzers | Agent for mouth care based on chlorine dioxide and zinc salt or peroxide, useful for prevention of caries, gingivitis and parodontitis and for treatment and control of halitosis |
US6077502A (en) * | 1998-02-27 | 2000-06-20 | The Procter & Gamble Company | Oral care compositions comprising chlorite and methods |
US6312670B1 (en) * | 1995-09-25 | 2001-11-06 | R. Eric Montgomery | Tooth bleaching compositions |
WO2002002061A2 (en) * | 2000-06-30 | 2002-01-10 | The Procter & Gamble Company | Oral care compositions comprising chlorite |
US6375933B1 (en) * | 2001-01-03 | 2002-04-23 | Colgate Palmolive Company | Dual component dentifrice for reducing mouth odors |
US6432388B1 (en) * | 1997-11-14 | 2002-08-13 | Biocosmetics, S.L. | Whitening anti-plaque and anti-tartar low abrasivity tooth paste |
US6582682B2 (en) | 2000-10-30 | 2003-06-24 | Noville, Inc. | Oral care compositions comprising stabilized chlorine dioxide |
US6696047B2 (en) | 2001-09-13 | 2004-02-24 | The Procter & Gamble Company | Stable oral care compositions comprising chlorite |
US6929790B2 (en) | 1996-10-23 | 2005-08-16 | The Research Foundation Of State University Of New York | Compositions to control oral microbial oxidation-reduction (Eh) levels |
WO2006038802A1 (en) * | 2004-10-07 | 2006-04-13 | Ngen Pharmaceuticals N.V. | Stabilised oxygen releasing composition |
WO2006130040A1 (en) * | 2005-05-23 | 2006-12-07 | 'wds' Company | Formulation for prophylaxis of oral cavity diseases |
NO20082820L (en) * | 2005-11-25 | 2008-06-25 | Wds Company | Legendary and prophylactic composition for oral cavity care |
ITMI20081529A1 (en) * | 2008-08-21 | 2010-02-22 | Biotrading Di Mannone Maurizio Gius Eppe | METHOD FOR TEETH FLUOROPROPHYLASSES USING THE USE OF A FLUORINE-BASED SPRAY COMPOSITION |
US20130034507A1 (en) * | 2009-02-04 | 2013-02-07 | Basf Corporation | Chlorine Dioxide Treatment for Biological Tissue |
WO2022192453A1 (en) * | 2021-03-11 | 2022-09-15 | Benova Rx LLC | Compositions and methods of use thereof for antiseptic mouth rinses |
EP3952828A4 (en) * | 2019-04-10 | 2023-06-07 | Black Tulip Management, Inc. | Oral rinse compositions for reducing pathogens underlying tooth decay, periodontitis and oral malodor |
EP3952827A4 (en) * | 2019-04-10 | 2023-06-07 | Black Tulip Management, Inc. | Oral rinse compositions for reducing pathogens underlying and for treating periodontal disease and oral malodor in the canine |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2730729A1 (en) | 2008-07-15 | 2010-01-21 | Basf Corporation | Non-cytotoxic chlorine dioxide fluids |
Citations (7)
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---|---|---|---|---|
EP0081017A1 (en) * | 1981-12-07 | 1983-06-15 | Alcide Company Limited Partnership | Germ-killing composition |
WO1985004107A1 (en) * | 1984-03-21 | 1985-09-26 | Alcide Corporation | Disinfection method and composition therefor |
EP0287074A2 (en) * | 1987-04-14 | 1988-10-19 | Alcide Corporation | Disinfecting compositions |
WO1989005135A1 (en) * | 1987-12-01 | 1989-06-15 | C.Hedward.Medi-Team Ab | Preparation for dental treatment and method for production of the preparation |
EP0344701A2 (en) * | 1988-06-01 | 1989-12-06 | The Procter & Gamble Company | Oral compositions |
US5200171A (en) * | 1990-11-20 | 1993-04-06 | Micropure, Inc. | Oral health preparation and method |
US5281412A (en) * | 1991-12-30 | 1994-01-25 | The Procter & Gamble Company | Oral compositions |
-
1994
- 1994-05-23 GB GB9410406A patent/GB2289841B/en not_active Expired - Fee Related
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0081017A1 (en) * | 1981-12-07 | 1983-06-15 | Alcide Company Limited Partnership | Germ-killing composition |
WO1985004107A1 (en) * | 1984-03-21 | 1985-09-26 | Alcide Corporation | Disinfection method and composition therefor |
EP0287074A2 (en) * | 1987-04-14 | 1988-10-19 | Alcide Corporation | Disinfecting compositions |
EP0565134A1 (en) * | 1987-04-14 | 1993-10-13 | Alcide Corporation | Disinfecting compositions and methods therefor |
WO1989005135A1 (en) * | 1987-12-01 | 1989-06-15 | C.Hedward.Medi-Team Ab | Preparation for dental treatment and method for production of the preparation |
EP0344701A2 (en) * | 1988-06-01 | 1989-12-06 | The Procter & Gamble Company | Oral compositions |
US5200171A (en) * | 1990-11-20 | 1993-04-06 | Micropure, Inc. | Oral health preparation and method |
US5281412A (en) * | 1991-12-30 | 1994-01-25 | The Procter & Gamble Company | Oral compositions |
Cited By (40)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6017515A (en) * | 1995-02-24 | 2000-01-25 | Diamond White A.V.V. | Method for preparing a preparation for bleaching teeth or for treating skin complaints and mucous membrane disorders |
US6312670B1 (en) * | 1995-09-25 | 2001-11-06 | R. Eric Montgomery | Tooth bleaching compositions |
US5944528A (en) * | 1996-07-29 | 1999-08-31 | Idex Dental Sciences, Inc. | Chlorine dioxide tooth whitening compositions |
US6929790B2 (en) | 1996-10-23 | 2005-08-16 | The Research Foundation Of State University Of New York | Compositions to control oral microbial oxidation-reduction (Eh) levels |
US6432388B1 (en) * | 1997-11-14 | 2002-08-13 | Biocosmetics, S.L. | Whitening anti-plaque and anti-tartar low abrasivity tooth paste |
US6077502A (en) * | 1998-02-27 | 2000-06-20 | The Procter & Gamble Company | Oral care compositions comprising chlorite and methods |
US6235269B1 (en) | 1998-02-27 | 2001-05-22 | The Procter & Gamble Company | Oral care compositions comprising chlorite and methods |
US6251372B1 (en) | 1998-02-27 | 2001-06-26 | The Procter & Gamble Company | Oral care compositions comprising chlorite and methods |
US6264924B1 (en) | 1998-02-27 | 2001-07-24 | The Procter & Gamble Company | Oral care compositions comprising chlorite and methods |
WO1999043290A1 (en) * | 1998-02-27 | 1999-09-02 | The Procter & Gamble Company | Oral care compositions comprising chlorite and methods |
US6350438B1 (en) | 1998-02-27 | 2002-02-26 | The Procter & Gamble Company | Oral care compositions comprising chlorite and methods |
US6132702A (en) * | 1998-02-27 | 2000-10-17 | The Procter & Gamble Company | Oral care compositions comprising chlorite and methods |
WO1999043295A1 (en) * | 1998-02-27 | 1999-09-02 | The Procter & Gamble Company | Oral care compositions comprising chlorite |
DE19854349A1 (en) * | 1998-11-25 | 2000-05-31 | Up To Dent Ag Balzers | Agent for mouth care based on chlorine dioxide and zinc salt or peroxide, useful for prevention of caries, gingivitis and parodontitis and for treatment and control of halitosis |
WO2002002061A2 (en) * | 2000-06-30 | 2002-01-10 | The Procter & Gamble Company | Oral care compositions comprising chlorite |
WO2002002061A3 (en) * | 2000-06-30 | 2002-06-27 | Procter & Gamble | Oral care compositions comprising chlorite |
US6582682B2 (en) | 2000-10-30 | 2003-06-24 | Noville, Inc. | Oral care compositions comprising stabilized chlorine dioxide |
WO2002053116A2 (en) * | 2001-01-03 | 2002-07-11 | Colgate-Palmolive Company | Dual component dentifrice for reducing mouth odors |
US6375933B1 (en) * | 2001-01-03 | 2002-04-23 | Colgate Palmolive Company | Dual component dentifrice for reducing mouth odors |
WO2002053116A3 (en) * | 2001-01-03 | 2002-11-28 | Colgate Palmolive Co | Dual component dentifrice for reducing mouth odors |
US6696047B2 (en) | 2001-09-13 | 2004-02-24 | The Procter & Gamble Company | Stable oral care compositions comprising chlorite |
WO2006038802A1 (en) * | 2004-10-07 | 2006-04-13 | Ngen Pharmaceuticals N.V. | Stabilised oxygen releasing composition |
CN101365418B (en) * | 2005-05-23 | 2011-11-09 | “Wds”公司 | Formulation for prophylaxis of oral cavity diseases |
EP1895996A4 (en) * | 2005-05-23 | 2013-07-17 | Obschestvo S Ogranichennoy Otvetstvennostyu Vds | Formulation for prophylaxis of oral cavity diseases |
WO2006130040A1 (en) * | 2005-05-23 | 2006-12-07 | 'wds' Company | Formulation for prophylaxis of oral cavity diseases |
EP1895996A1 (en) * | 2005-05-23 | 2008-03-12 | Obschestvo S Ogranichennoy Otvetstvennostyu "VDS" | Formulation for prophylaxis of oral cavity diseases |
JP2008542264A (en) * | 2005-05-23 | 2008-11-27 | “ダブリューディーエス” カンパニー | Oral disease prevention formulation |
EA011229B1 (en) * | 2005-05-23 | 2009-02-27 | Общество С Ограниченной Ответственностью "Вдс" | Formulation for prophylaxis of oral cavity diseases |
EP1952801A1 (en) * | 2005-11-25 | 2008-08-06 | "WDS" Company | Oral cavity care curative and prophylactic composition |
JP2009517382A (en) * | 2005-11-25 | 2009-04-30 | “ダブリューディーエス” カンパニー | Oral care therapeutic and prophylactic compositions |
NO20082820L (en) * | 2005-11-25 | 2008-06-25 | Wds Company | Legendary and prophylactic composition for oral cavity care |
EP1952801A4 (en) * | 2005-11-25 | 2015-04-29 | Wds Company | Oral cavity care curative and prophylactic composition |
NO342401B1 (en) * | 2005-11-25 | 2018-05-14 | Wds Company | Legendary and prophylactic composition for oral cavity care |
ITMI20081529A1 (en) * | 2008-08-21 | 2010-02-22 | Biotrading Di Mannone Maurizio Gius Eppe | METHOD FOR TEETH FLUOROPROPHYLASSES USING THE USE OF A FLUORINE-BASED SPRAY COMPOSITION |
US20130034507A1 (en) * | 2009-02-04 | 2013-02-07 | Basf Corporation | Chlorine Dioxide Treatment for Biological Tissue |
US8703106B2 (en) * | 2009-02-04 | 2014-04-22 | Basf Corporation | Chlorine dioxide treatment for biological tissue |
EP3952828A4 (en) * | 2019-04-10 | 2023-06-07 | Black Tulip Management, Inc. | Oral rinse compositions for reducing pathogens underlying tooth decay, periodontitis and oral malodor |
EP3952827A4 (en) * | 2019-04-10 | 2023-06-07 | Black Tulip Management, Inc. | Oral rinse compositions for reducing pathogens underlying and for treating periodontal disease and oral malodor in the canine |
WO2022192453A1 (en) * | 2021-03-11 | 2022-09-15 | Benova Rx LLC | Compositions and methods of use thereof for antiseptic mouth rinses |
US11806420B2 (en) | 2021-03-11 | 2023-11-07 | Benova Rx LLC | Compositions and methods of use thereof for antiseptic mouth rinses |
Also Published As
Publication number | Publication date |
---|---|
GB2289841B (en) | 1998-04-15 |
GB9410406D0 (en) | 1994-07-13 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PCNP | Patent ceased through non-payment of renewal fee |
Effective date: 20130523 |