GB2289841A - Oral care products containing chlorites - Google Patents

Oral care products containing chlorites Download PDF

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Publication number
GB2289841A
GB2289841A GB9410406A GB9410406A GB2289841A GB 2289841 A GB2289841 A GB 2289841A GB 9410406 A GB9410406 A GB 9410406A GB 9410406 A GB9410406 A GB 9410406A GB 2289841 A GB2289841 A GB 2289841A
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GB
United Kingdom
Prior art keywords
product
oral care
chlorite
sodium
sodium chlorite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB9410406A
Other versions
GB2289841B (en
GB9410406D0 (en
Inventor
Ahmet Ersal Mehmet
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JANINA INTERNATIONAL
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JANINA INTERNATIONAL
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by JANINA INTERNATIONAL filed Critical JANINA INTERNATIONAL
Priority to GB9410406A priority Critical patent/GB2289841B/en
Publication of GB9410406D0 publication Critical patent/GB9410406D0/en
Publication of GB2289841A publication Critical patent/GB2289841A/en
Application granted granted Critical
Publication of GB2289841B publication Critical patent/GB2289841B/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/22Peroxides; Oxygen; Ozone
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q11/00Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • General Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Chemical & Material Sciences (AREA)
  • Emergency Medicine (AREA)
  • Oral & Maxillofacial Surgery (AREA)
  • Cosmetics (AREA)

Abstract

An oral care product, such as a mouthwash or spray or a toothpaste contains an oxidising agent in the form of Group I alkali metal chlorite, preferably sodium chlorite. The product may contain up to 5% by volume of the chlorite and optionally up to 8% w/v of bromelain.

Description

Oral care products This invention relates to oral care products, a term which includes mouthwashes, toothpastes and oral sprays. Mouthwashes are liquid preparations intended to improve users' oral hygiene. In use they are decanted into a user's mouth, but not swallowed. They are dispersed in the mouth by violent agitation, so that the liquid passes over all the internal surfaces of the mouth, including the teeth and gums. The usual mouthwash contains a disinfecting agent, to cleanse the skin surfaces, and an agent intended to freshen the breath. Toothpastes are particularly employed to clean teeth by application to the bristles of a brush which is then used to remove food debris from between the teeth, and by gently abrading the teeth to remove stains and adherent films, such as of plaque. Mouthsprays are liquids which are sprayed under pressure in a fine spray into the open mouth to become deposited on the exposed surfaces of the cheeks, gums and teeth. The sprays become diluted by the saliva naturally present in the mouth, which saliva acts as a vehicle to bathe all the surfaces with the spray ingredients.
The present invention aims at providing an oral care product which, in addition to cleansing the internal surfaces of the mouth, also has a brightening or whitening effect on the teeth.
Accordingly, the present invention provides an oral care product which includes an oxidising agent in the form of a chlorite salt of a Group I alkali metal ion, such as sodium chlorite.
In its preferred ready-for-use form, the oral care product is a liquid or paste containing up to a inXirtL1m of 5.08 by volume or weight of sodium chlorite.
The product in its liquid form may be sold in such a diluted form as to be ready for use as sold. Alternatively, it may be concentrated to a greater extent, for either dilution prior to being used as usual, or for being sprayed in its undiluted form into the mouth so that the spray becomes diluted by saliva in order to ensure that the concentration of sodium chlorite in the mouth remains below a maximum level.
It has been found that incorporation of this oxidising agent has a surprising effect on the teeth, in that it results in the teeth becoming whiter. This is thought to be the result of any deposits of dark or yellowish material on the teeth, such as plaque, being removed or bleached, so that the natural colour of the teeth can be seen more easily. The plaque and any food debris in the mouth are thought to be partially dissolved by the sodium chlorite solution, by chemical interaction therewith.
In practice the product would contain additional ingredients to give it enhanced properties. In its commercial form, it is envisaged that the product would have the following composition: Ingredient Percentages Rancre Praferred Sodium chlorite 0.01 - 5.0 0.2 Sodium bicarbonate 0.2 - 12.0 4.0 Sodium fluoride 0.01 - 1.0 0.32 Zinc citrate 0.01 - 2.0 0.8 Bromelain up to 8.0 0.5 Papain up to 8.0 0.125 Triclosan up to 1.0 0.3 Xylitol up to 6.0 2.0 When the product is a liquid, the percentages are by weight or volume, whereas when the product is a solid (as a paste), the percentages are weight over weight.
When the product is in its liquid form, as either a mouthwash or spray, then the above composition would have deionized water added to it to bring it to the desired concentration.
The hydrogen ion concentration (pH) value of the mouthwash form of the invention is about 6.5, to ensure stability before use. When the mouthwash is used, it is believed that the sodium chlorite reacts under the usual acidic conditions in the mouth to generate chlorine dioxide, which is itself a powerful oxidising and anti-bacterial agent. Both chlorites and chlorine dioxide oxidise malodorous thiol compounds which are responsible for halitosis, so that use of the product of the present invention tends to lead to sweeter breath.
In its liquid form, the present invention provides a mouthwash with disinfectant and cleansing properties, and with the additional advantage of improving the appearance of the teeth significantly, and without brushing.
In either its paste or liquid form, it has also been found that sodium chlorite reacts with any nicotine stains on the teeth, or elsewhere in the mouth, both to remove or bleach the stains and to release substances which taste so disagreeable as to deter smokers from continuing to use the mouthwash if they wish to continue smoking. It can therefore form an effective component in any aversion-therapy course for smokers.

Claims (5)

Clains
1 An oral care product comprising an oxidising agent in the form of a chlorite of a Group I alkali metal ion, such as sodium chlorite.
2 A product as claimed in claim 1, containing up to 5.0 percent by volume of sodium chlorite.
3 A product as claimed in claim 1 or 2, containing bromelain, up to a maximum of about 8.08 w/v.
4 A product as claimed in claim 1, having the composition: Ingredient percentage Sodium chlorite 0.01 - 5.0 Sodium bicarbonate 0.2 - 12.0 Sodium fluoride 0.01 - 1.0 Zinc citrate 0.01 - 2.0 Bromelain up to 8.0 Papain up to 8.0 Triclosan up to 1.0 Xylitol up to 6.0.
5 A product as claimed in claim 4, of composition: Ingredient percentage Sodium chlorite 0.2 Sodium bicarbonate 4.0 Sodium fluoride 0.32 Zinc citrate 0.8 Bromelain 0.5 Papain 0.125 Triclosan 0.3 Xylitol 2.0 6 A product as claimed in any preceding claim, made into a mouthwash by being dissolved in deionised water.
GB9410406A 1994-05-23 1994-05-23 Oral care products Expired - Fee Related GB2289841B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB9410406A GB2289841B (en) 1994-05-23 1994-05-23 Oral care products

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB9410406A GB2289841B (en) 1994-05-23 1994-05-23 Oral care products

Publications (3)

Publication Number Publication Date
GB9410406D0 GB9410406D0 (en) 1994-07-13
GB2289841A true GB2289841A (en) 1995-12-06
GB2289841B GB2289841B (en) 1998-04-15

Family

ID=10755645

Family Applications (1)

Application Number Title Priority Date Filing Date
GB9410406A Expired - Fee Related GB2289841B (en) 1994-05-23 1994-05-23 Oral care products

Country Status (1)

Country Link
GB (1) GB2289841B (en)

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5944528A (en) * 1996-07-29 1999-08-31 Idex Dental Sciences, Inc. Chlorine dioxide tooth whitening compositions
WO1999043295A1 (en) * 1998-02-27 1999-09-02 The Procter & Gamble Company Oral care compositions comprising chlorite
WO1999043290A1 (en) * 1998-02-27 1999-09-02 The Procter & Gamble Company Oral care compositions comprising chlorite and methods
US6017515A (en) * 1995-02-24 2000-01-25 Diamond White A.V.V. Method for preparing a preparation for bleaching teeth or for treating skin complaints and mucous membrane disorders
DE19854349A1 (en) * 1998-11-25 2000-05-31 Up To Dent Ag Balzers Agent for mouth care based on chlorine dioxide and zinc salt or peroxide, useful for prevention of caries, gingivitis and parodontitis and for treatment and control of halitosis
US6077502A (en) * 1998-02-27 2000-06-20 The Procter & Gamble Company Oral care compositions comprising chlorite and methods
US6312670B1 (en) * 1995-09-25 2001-11-06 R. Eric Montgomery Tooth bleaching compositions
WO2002002061A2 (en) * 2000-06-30 2002-01-10 The Procter & Gamble Company Oral care compositions comprising chlorite
US6375933B1 (en) * 2001-01-03 2002-04-23 Colgate Palmolive Company Dual component dentifrice for reducing mouth odors
US6432388B1 (en) * 1997-11-14 2002-08-13 Biocosmetics, S.L. Whitening anti-plaque and anti-tartar low abrasivity tooth paste
US6582682B2 (en) 2000-10-30 2003-06-24 Noville, Inc. Oral care compositions comprising stabilized chlorine dioxide
US6696047B2 (en) 2001-09-13 2004-02-24 The Procter & Gamble Company Stable oral care compositions comprising chlorite
US6929790B2 (en) 1996-10-23 2005-08-16 The Research Foundation Of State University Of New York Compositions to control oral microbial oxidation-reduction (Eh) levels
WO2006038802A1 (en) * 2004-10-07 2006-04-13 Ngen Pharmaceuticals N.V. Stabilised oxygen releasing composition
WO2006130040A1 (en) * 2005-05-23 2006-12-07 'wds' Company Formulation for prophylaxis of oral cavity diseases
NO20082820L (en) * 2005-11-25 2008-06-25 Wds Company Legendary and prophylactic composition for oral cavity care
ITMI20081529A1 (en) * 2008-08-21 2010-02-22 Biotrading Di Mannone Maurizio Gius Eppe METHOD FOR TEETH FLUOROPROPHYLASSES USING THE USE OF A FLUORINE-BASED SPRAY COMPOSITION
US20130034507A1 (en) * 2009-02-04 2013-02-07 Basf Corporation Chlorine Dioxide Treatment for Biological Tissue
WO2022192453A1 (en) * 2021-03-11 2022-09-15 Benova Rx LLC Compositions and methods of use thereof for antiseptic mouth rinses
EP3952828A4 (en) * 2019-04-10 2023-06-07 Black Tulip Management, Inc. Oral rinse compositions for reducing pathogens underlying tooth decay, periodontitis and oral malodor
EP3952827A4 (en) * 2019-04-10 2023-06-07 Black Tulip Management, Inc. Oral rinse compositions for reducing pathogens underlying and for treating periodontal disease and oral malodor in the canine

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2730729A1 (en) 2008-07-15 2010-01-21 Basf Corporation Non-cytotoxic chlorine dioxide fluids

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0081017A1 (en) * 1981-12-07 1983-06-15 Alcide Company Limited Partnership Germ-killing composition
WO1985004107A1 (en) * 1984-03-21 1985-09-26 Alcide Corporation Disinfection method and composition therefor
EP0287074A2 (en) * 1987-04-14 1988-10-19 Alcide Corporation Disinfecting compositions
WO1989005135A1 (en) * 1987-12-01 1989-06-15 C.Hedward.Medi-Team Ab Preparation for dental treatment and method for production of the preparation
EP0344701A2 (en) * 1988-06-01 1989-12-06 The Procter & Gamble Company Oral compositions
US5200171A (en) * 1990-11-20 1993-04-06 Micropure, Inc. Oral health preparation and method
US5281412A (en) * 1991-12-30 1994-01-25 The Procter & Gamble Company Oral compositions

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0081017A1 (en) * 1981-12-07 1983-06-15 Alcide Company Limited Partnership Germ-killing composition
WO1985004107A1 (en) * 1984-03-21 1985-09-26 Alcide Corporation Disinfection method and composition therefor
EP0287074A2 (en) * 1987-04-14 1988-10-19 Alcide Corporation Disinfecting compositions
EP0565134A1 (en) * 1987-04-14 1993-10-13 Alcide Corporation Disinfecting compositions and methods therefor
WO1989005135A1 (en) * 1987-12-01 1989-06-15 C.Hedward.Medi-Team Ab Preparation for dental treatment and method for production of the preparation
EP0344701A2 (en) * 1988-06-01 1989-12-06 The Procter & Gamble Company Oral compositions
US5200171A (en) * 1990-11-20 1993-04-06 Micropure, Inc. Oral health preparation and method
US5281412A (en) * 1991-12-30 1994-01-25 The Procter & Gamble Company Oral compositions

Cited By (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6017515A (en) * 1995-02-24 2000-01-25 Diamond White A.V.V. Method for preparing a preparation for bleaching teeth or for treating skin complaints and mucous membrane disorders
US6312670B1 (en) * 1995-09-25 2001-11-06 R. Eric Montgomery Tooth bleaching compositions
US5944528A (en) * 1996-07-29 1999-08-31 Idex Dental Sciences, Inc. Chlorine dioxide tooth whitening compositions
US6929790B2 (en) 1996-10-23 2005-08-16 The Research Foundation Of State University Of New York Compositions to control oral microbial oxidation-reduction (Eh) levels
US6432388B1 (en) * 1997-11-14 2002-08-13 Biocosmetics, S.L. Whitening anti-plaque and anti-tartar low abrasivity tooth paste
US6077502A (en) * 1998-02-27 2000-06-20 The Procter & Gamble Company Oral care compositions comprising chlorite and methods
US6235269B1 (en) 1998-02-27 2001-05-22 The Procter & Gamble Company Oral care compositions comprising chlorite and methods
US6251372B1 (en) 1998-02-27 2001-06-26 The Procter & Gamble Company Oral care compositions comprising chlorite and methods
US6264924B1 (en) 1998-02-27 2001-07-24 The Procter & Gamble Company Oral care compositions comprising chlorite and methods
WO1999043290A1 (en) * 1998-02-27 1999-09-02 The Procter & Gamble Company Oral care compositions comprising chlorite and methods
US6350438B1 (en) 1998-02-27 2002-02-26 The Procter & Gamble Company Oral care compositions comprising chlorite and methods
US6132702A (en) * 1998-02-27 2000-10-17 The Procter & Gamble Company Oral care compositions comprising chlorite and methods
WO1999043295A1 (en) * 1998-02-27 1999-09-02 The Procter & Gamble Company Oral care compositions comprising chlorite
DE19854349A1 (en) * 1998-11-25 2000-05-31 Up To Dent Ag Balzers Agent for mouth care based on chlorine dioxide and zinc salt or peroxide, useful for prevention of caries, gingivitis and parodontitis and for treatment and control of halitosis
WO2002002061A2 (en) * 2000-06-30 2002-01-10 The Procter & Gamble Company Oral care compositions comprising chlorite
WO2002002061A3 (en) * 2000-06-30 2002-06-27 Procter & Gamble Oral care compositions comprising chlorite
US6582682B2 (en) 2000-10-30 2003-06-24 Noville, Inc. Oral care compositions comprising stabilized chlorine dioxide
WO2002053116A2 (en) * 2001-01-03 2002-07-11 Colgate-Palmolive Company Dual component dentifrice for reducing mouth odors
US6375933B1 (en) * 2001-01-03 2002-04-23 Colgate Palmolive Company Dual component dentifrice for reducing mouth odors
WO2002053116A3 (en) * 2001-01-03 2002-11-28 Colgate Palmolive Co Dual component dentifrice for reducing mouth odors
US6696047B2 (en) 2001-09-13 2004-02-24 The Procter & Gamble Company Stable oral care compositions comprising chlorite
WO2006038802A1 (en) * 2004-10-07 2006-04-13 Ngen Pharmaceuticals N.V. Stabilised oxygen releasing composition
CN101365418B (en) * 2005-05-23 2011-11-09 “Wds”公司 Formulation for prophylaxis of oral cavity diseases
EP1895996A4 (en) * 2005-05-23 2013-07-17 Obschestvo S Ogranichennoy Otvetstvennostyu Vds Formulation for prophylaxis of oral cavity diseases
WO2006130040A1 (en) * 2005-05-23 2006-12-07 'wds' Company Formulation for prophylaxis of oral cavity diseases
EP1895996A1 (en) * 2005-05-23 2008-03-12 Obschestvo S Ogranichennoy Otvetstvennostyu "VDS" Formulation for prophylaxis of oral cavity diseases
JP2008542264A (en) * 2005-05-23 2008-11-27 “ダブリューディーエス” カンパニー Oral disease prevention formulation
EA011229B1 (en) * 2005-05-23 2009-02-27 Общество С Ограниченной Ответственностью "Вдс" Formulation for prophylaxis of oral cavity diseases
EP1952801A1 (en) * 2005-11-25 2008-08-06 "WDS" Company Oral cavity care curative and prophylactic composition
JP2009517382A (en) * 2005-11-25 2009-04-30 “ダブリューディーエス” カンパニー Oral care therapeutic and prophylactic compositions
NO20082820L (en) * 2005-11-25 2008-06-25 Wds Company Legendary and prophylactic composition for oral cavity care
EP1952801A4 (en) * 2005-11-25 2015-04-29 Wds Company Oral cavity care curative and prophylactic composition
NO342401B1 (en) * 2005-11-25 2018-05-14 Wds Company Legendary and prophylactic composition for oral cavity care
ITMI20081529A1 (en) * 2008-08-21 2010-02-22 Biotrading Di Mannone Maurizio Gius Eppe METHOD FOR TEETH FLUOROPROPHYLASSES USING THE USE OF A FLUORINE-BASED SPRAY COMPOSITION
US20130034507A1 (en) * 2009-02-04 2013-02-07 Basf Corporation Chlorine Dioxide Treatment for Biological Tissue
US8703106B2 (en) * 2009-02-04 2014-04-22 Basf Corporation Chlorine dioxide treatment for biological tissue
EP3952828A4 (en) * 2019-04-10 2023-06-07 Black Tulip Management, Inc. Oral rinse compositions for reducing pathogens underlying tooth decay, periodontitis and oral malodor
EP3952827A4 (en) * 2019-04-10 2023-06-07 Black Tulip Management, Inc. Oral rinse compositions for reducing pathogens underlying and for treating periodontal disease and oral malodor in the canine
WO2022192453A1 (en) * 2021-03-11 2022-09-15 Benova Rx LLC Compositions and methods of use thereof for antiseptic mouth rinses
US11806420B2 (en) 2021-03-11 2023-11-07 Benova Rx LLC Compositions and methods of use thereof for antiseptic mouth rinses

Also Published As

Publication number Publication date
GB2289841B (en) 1998-04-15
GB9410406D0 (en) 1994-07-13

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PCNP Patent ceased through non-payment of renewal fee

Effective date: 20130523